title: Catalytic Kinetics of Different Types of Surface Atoms on Shaped Pd Nanocrystals.
abstract: To understand the catalytic properties or roles of different types of surface atoms on metal nanocatalysts, the catalytic kinetics and dynamics of the different types of surface atoms (plane and edge) were revealed for the first time by a statistical quantitative deconvolution of observables obtained from traditional single-molecule nanocatalysis of Pd nanocrystals.It was found that the edge and plane of Pd nanocubes show similar size-dependent product formation processes, but inverse product dissociation processes. This work helps push the traditional single-molecule nanocatalysis method towards the sub-particle level.
authors.affiliation: State Key Laboratory of Electroanalytical Chemistry and, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry, Chinese Academy of Science, 5625 Renmin Street, Changchun, 130022, P.R. China.|University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.
authors.forename: Tao
authors.initials: T
authors.lastname: Chen
authors.affiliation: Hefei National Laboratory for Physical Sciences at the Microscale and Collaborative Innovation Center of Suzhou Nano Science and Technology, Center of Advanced Nanocatalysis (CAN-USTC) and, Department of Chemical Physics, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China.
authors.forename: Sheng
authors.initials: S
authors.lastname: Chen
authors.affiliation: State Key Laboratory of Electroanalytical Chemistry and, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry, Chinese Academy of Science, 5625 Renmin Street, Changchun, 130022, P.R. China.
authors.forename: Yuwei
authors.initials: Y
authors.lastname: Zhang
authors.affiliation: Hefei National Laboratory for Physical Sciences at the Microscale and Collaborative Innovation Center of Suzhou Nano Science and Technology, Center of Advanced Nanocatalysis (CAN-USTC) and, Department of Chemical Physics, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China.
authors.forename: Yifeng
authors.initials: Y
authors.lastname: Qi
authors.affiliation: Hefei National Laboratory for Physical Sciences at the Microscale and Collaborative Innovation Center of Suzhou Nano Science and Technology, Center of Advanced Nanocatalysis (CAN-USTC) and, Department of Chemical Physics, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China.
authors.forename: Yuzhou
authors.initials: Y
authors.lastname: Zhao
authors.affiliation: State Key Laboratory of Electroanalytical Chemistry and, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry, Chinese Academy of Science, 5625 Renmin Street, Changchun, 130022, P.R. China. weilinxu@ciac.ac.cn.
authors.forename: Weilin
authors.initials: W
authors.lastname: Xu
authors.affiliation: Hefei National Laboratory for Physical Sciences at the Microscale and Collaborative Innovation Center of Suzhou Nano Science and Technology, Center of Advanced Nanocatalysis (CAN-USTC) and, Department of Chemical Physics, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China. zengj@ustc.edu.cn.
authors.forename: Jie
authors.initials: J
authors.lastname: Zeng
keywords: fluorescence microscopy; nanocatalysis; nanocrystals; single molecules