title: Direct difunctionalization of activated alkynes via domino oxidative benzylation/1,4-aryl migration/decarboxylation reactions under metal-free conditions.
abstract: The oxidative difunctionalization of aryl alkynoates via benzyl radical initiated intramolecular 1,4-aryl migration and decarboxylation tandem process was developed in the presence of tert-butyl hydroperoxide as an oxidant, which provides a direct and selective route to a variety of trisubstituted alkenes from simple toluene derivatives and aryl alkynoates.
authors.affiliation: Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China. leiwang@chnu.edu.cn.
authors.forename: Tao
authors.initials: T
authors.lastname: Miao
authors.affiliation: Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China. leiwang@chnu.edu.cn.
authors.forename: Dong
authors.initials: D
authors.lastname: Xia
authors.affiliation: Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China. leiwang@chnu.edu.cn.
authors.forename: Yang
authors.initials: Y
authors.lastname: Li
authors.affiliation: Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China. leiwang@chnu.edu.cn.
authors.forename: Pinhua
authors.initials: P
authors.lastname: Li
authors.affiliation: Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China. leiwang@chnu.edu.cn and State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. China.
authors.forename: Lei
authors.initials: L
authors.lastname: Wang