title: Solid state reconstructive phase transition from porous supramolecular network to porous coordination polymer.
abstract: Herein, we present an exceptional structural transformation from a porous supramolecular network to a porous coordination polymer. The transformation involves a change of interpenetrating dimensionality from 6-fold to 5-fold. Simultaneously, the spin state of nickel(ii) is altered from S = 0 to S = 1, which is concomitant with the formation of the Ni-O(carboxylate) coordination bonds.
authors.affiliation: Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China. kouhz@mail.tsinghua.edu.cn.
authors.forename: Xiang
authors.initials: X
authors.lastname: Jiang
authors.affiliation: Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China. kouhz@mail.tsinghua.edu.cn.
authors.forename: Hui-Zhong
authors.initials: HZ
authors.lastname: Kou