title: Addition of 4-(cyclohex-1-en-1-yl)morpholine on 3-nitroindole: an unprecedented dearomatizing process.
abstract: Nucleophilic enamines add spontaneously on heteroarenes 3-nitroindole and benzofuran to form a new C-C bond. With nitroindole and enamine , an unprecedented dearomatizing formal ene reaction occurs in a totally regio- and diastereo-selective manner. With 3-nitrobenzofuran and enamine , the reaction course is different and leads to the generation of a dienylphenol.
authors.affiliation: Normandie Univ, COBRA, UMR 6014 et FR 3038, Univ Rouen, CNRS, INSA Rouen, IRCOF, 1 rue Tesnière, 76821 Mont-Saint-Aignan Cedex, France. isabelle.chataigner@univ-rouen.fr.
authors.forename: Manuel
authors.initials: M
authors.lastname: Andreini
authors.affiliation: Normandie Univ, COBRA, UMR 6014 et FR 3038, Univ Rouen, CNRS, INSA Rouen, IRCOF, 1 rue Tesnière, 76821 Mont-Saint-Aignan Cedex, France. isabelle.chataigner@univ-rouen.fr.
authors.forename: Fabien
authors.initials: F
authors.lastname: Chapellas
authors.affiliation: Normandie Univ, COBRA, UMR 6014 et FR 3038, Univ Rouen, CNRS, INSA Rouen, IRCOF, 1 rue Tesnière, 76821 Mont-Saint-Aignan Cedex, France. isabelle.chataigner@univ-rouen.fr.
authors.forename: Sonia
authors.initials: S
authors.lastname: Diab
authors.affiliation: Normandie Univ, COBRA, UMR 6014 et FR 3038, Univ Rouen, CNRS, INSA Rouen, IRCOF, 1 rue Tesnière, 76821 Mont-Saint-Aignan Cedex, France. isabelle.chataigner@univ-rouen.fr.
authors.forename: Karine
authors.initials: K
authors.lastname: Pasturaud
authors.affiliation: Normandie Univ, COBRA, UMR 6014 et FR 3038, Univ Rouen, CNRS, INSA Rouen, IRCOF, 1 rue Tesnière, 76821 Mont-Saint-Aignan Cedex, France. isabelle.chataigner@univ-rouen.fr.
authors.forename: Serge R
authors.initials: SR
authors.lastname: Piettre
authors.affiliation: Normandie Univ, COBRA, UMR 6014 et FR 3038, Univ Rouen, CNRS, INSA Rouen, IRCOF, 1 rue Tesnière, 76821 Mont-Saint-Aignan Cedex, France. isabelle.chataigner@univ-rouen.fr.
authors.forename: Julien
authors.initials: J
authors.lastname: Legros
authors.affiliation: Normandie Univ, COBRA, UMR 6014 et FR 3038, Univ Rouen, CNRS, INSA Rouen, IRCOF, 1 rue Tesnière, 76821 Mont-Saint-Aignan Cedex, France. isabelle.chataigner@univ-rouen.fr.
authors.forename: Isabelle
authors.initials: I
authors.lastname: Chataigner