title: Sulfentrazone dechlorination by iron-nickel bimetallic nanoparticles.
abstract: The sulfentrazone dechlorination using bimetallic nanoparticles of Fe/Ni was studied. Different variables that could influence the sulfentrazone conversion were investigated, such as nitrogen atmosphere, pH and dosage of the nanoparticles and initial concentration of sulfentrazone. The best results were obtained using controlled pH (pH 4.0) and 1.0 g L(-1) of nanomaterials, resulting in 100 % conversion in only 30 min. Kinetic studies were also conducted, evaluating the influence of different nanoparticle dosages (1.0 to 4.0 g L(-1)), system temperatures (20 to 35 °C) and nickel levels in the composition of the nanomaterials (0.025 to 0.10 gNi/gFe). The mechanism of sulfentrazone conversion has changed due a direct reduction on the catalytic activity sites and indirect reduction by atomic hydrogen. Both mechanisms have followed pseudo-first order models. The conversion rate improved when the dosage of the nanomaterials, system temperature and nickel content in the composition of the nanocomposites were increased. Finally, the conversion products were elucidated by mass spectrometry and toxicity assays were performed using Daphnia Similis. The results showed that the dechlorination product is less toxic than sulfentrazone.
authors.affiliation: Department of Chemistry, Federal University of Viçosa, Viçosa, MG, 36570-000, Brazil.
authors.forename: Mayra A
authors.initials: MA
authors.lastname: Nascimento
authors.affiliation: Department of Chemistry, Federal University of Viçosa, Viçosa, MG, 36570-000, Brazil. Electronic address: renata.plopes@ufv.br.
authors.forename: Renata P
authors.initials: RP
authors.lastname: Lopes
authors.affiliation: Department of Chemistry, Federal University of Viçosa, Viçosa, MG, 36570-000, Brazil.
authors.forename: Jean C
authors.initials: JC
authors.lastname: Cruz
authors.affiliation: Department of Crop Science, Federal University of Viçosa, Viçosa, MG, 36570-000, Brazil.
authors.forename: Antônio A
authors.initials: AA
authors.lastname: Silva
authors.affiliation: Department of Chemistry, Federal University of Viçosa, Viçosa, MG, 36570-000, Brazil.
authors.forename: Claudio F
authors.initials: CF
authors.lastname: Lima
mesh_terms: D054879:Halogenation; D007501:Iron / Q000737:chemistry*; D007700:Kinetics; D008956:Models, Chemical; D053758:Nanoparticles / Q000737:chemistry*; D049329:Nanostructures; D009532:Nickel / Q000737:chemistry*; D013449:Sulfonamides / Q000737:chemistry*; D014230:Triazoles / Q000737:chemistry*
chemical_list: D013449:Sulfonamides; D014230:Triazoles; D009532:Nickel; C475571:N-(2,4-dichloro-5-(4-(difluoromethyl)-4,5-dihydro-3-methyl-5-oxo-1H-1,2,4-triazol-1-yl)phenyl)methanesulfonamide; D007501:Iron
keywords: Bimetallic nanoparticles; Dechlorination; Fe–Ni; Sulfentrazone