title: Enantioselective Oxidative Rearrangements with Chiral Hypervalent Iodine Reagents.
abstract: A stereoselective hypervalent iodine-promoted oxidative rearrangement of 1,1-disubstituted alkenes has been developed. This practically simple protocol provides access to enantioenriched α-arylated ketones without the use of transition metals from readily accessible alkenes.
authors.affiliation: School of Chemistry, Cardiff University, Park Place, Main Building, Cardiff, CF10 3AT, UK.
authors.forename: Michael
authors.initials: M
authors.lastname: Brown
authors.affiliation: School of Chemistry, Cardiff University, Park Place, Main Building, Cardiff, CF10 3AT, UK.
authors.forename: Ravi
authors.initials: R
authors.lastname: Kumar
authors.affiliation: Organische Chemie, Universität Hamburg, Martin-Luther-King-Platz 6, 20146, Hamburg, Germany.
authors.forename: Julia
authors.initials: J
authors.lastname: Rehbein
authors.affiliation: School of Chemistry, Cardiff University, Park Place, Main Building, Cardiff, CF10 3AT, UK. wirth@cf.ac.uk.
authors.forename: Thomas
authors.initials: T
authors.lastname: Wirth
keywords: alkenes; arylation; hypervalent iodine; oxidation; rearrangement