title: Addition of silylated nucleophiles to α-oxoketenes.
abstract: A general evaluation of silylated nucleophiles to intercept transient α-oxoketenes generated by microwave-assisted Wolff rearrangement of 2-diazo-1,3-dicarbonyl compounds is presented. Original scaffolds and synthetic intermediates are accessed in a rapid, efficient and easy-to-handle way. Mechanistic studies by DFT calculations and some post-functionalizations are discussed.
authors.affiliation: Aix Marseille Université, Centrale Marseille, CNRS, iSm2 UMR 7313, 13397, Marseille, France. yoann.coquerel@univ-amu.fr xavier.bugaut@univ-amu.fr thierry.constantieux@univ-amu.fr.
authors.forename: Yohan
authors.initials: Y
authors.lastname: Dudognon
authors.affiliation: Aix Marseille Université, Centrale Marseille, CNRS, iSm2 UMR 7313, 13397, Marseille, France. yoann.coquerel@univ-amu.fr xavier.bugaut@univ-amu.fr thierry.constantieux@univ-amu.fr.
authors.forename: Marc
authors.initials: M
authors.lastname: Presset
authors.affiliation: Aix Marseille Université, Centrale Marseille, CNRS, iSm2 UMR 7313, 13397, Marseille, France. yoann.coquerel@univ-amu.fr xavier.bugaut@univ-amu.fr thierry.constantieux@univ-amu.fr.
authors.forename: Jean
authors.initials: J
authors.lastname: Rodriguez
authors.affiliation: Aix Marseille Université, Centrale Marseille, CNRS, iSm2 UMR 7313, 13397, Marseille, France. yoann.coquerel@univ-amu.fr xavier.bugaut@univ-amu.fr thierry.constantieux@univ-amu.fr.
authors.forename: Yoann
authors.initials: Y
authors.lastname: Coquerel
authors.affiliation: Aix Marseille Université, Centrale Marseille, CNRS, iSm2 UMR 7313, 13397, Marseille, France. yoann.coquerel@univ-amu.fr xavier.bugaut@univ-amu.fr thierry.constantieux@univ-amu.fr.
authors.forename: Xavier
authors.initials: X
authors.lastname: Bugaut
authors.affiliation: Aix Marseille Université, Centrale Marseille, CNRS, iSm2 UMR 7313, 13397, Marseille, France. yoann.coquerel@univ-amu.fr xavier.bugaut@univ-amu.fr thierry.constantieux@univ-amu.fr.
authors.forename: Thierry
authors.initials: T
authors.lastname: Constantieux