title: Assessment of Boron Doped Diamond Electrode Quality and Application to In Situ Modification of Local pH by Water Electrolysis.
abstract: Boron doped diamond (BDD) electrodes have shown considerable promise as an electrode material where many of their reported properties such as extended solvent window, low background currents, corrosion resistance, etc., arise from the catalytically inert nature of the surface. However, if during the growth process, non-diamond-carbon (NDC) becomes incorporated into the electrode matrix, the electrochemical properties will change as the surface becomes more catalytically active. As such it is important that the electrochemist is aware of the quality and resulting key electrochemical properties of the BDD electrode prior to use. This paper describes a series of characterization steps, including Raman microscopy, capacitance, solvent window and redox electrochemistry, to ascertain whether the BDD electrode contains negligible NDC i.e. negligible sp(2) carbon. One application is highlighted which takes advantage of the catalytically inert and corrosion resistant nature of an NDC-free surface i.e. stable and quantifiable local proton and hydroxide production due to water electrolysis at a BDD electrode. An approach to measuring the local pH change induced by water electrolysis using iridium oxide coated BDD electrodes is also described in detail.
authors.affiliation: Warwick Electrochemistry and Interfaces Group, Department of Chemistry, University of Warwick.
authors.forename: Tania L
authors.initials: TL
authors.lastname: Read
authors.affiliation: Warwick Electrochemistry and Interfaces Group, Department of Chemistry, University of Warwick; J.MacPherson@warwick.ac.uk.
authors.forename: Julie V
authors.initials: JV
authors.lastname: Macpherson
mesh_terms: D001895:Boron / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry; D018130:Diamond / Q000737:chemistry*; D004563:Electrochemistry; D004566:Electrodes; D004572:Electrolysis; D010084:Oxidation-Reduction; D013059:Spectrum Analysis, Raman; D014867:Water / Q000737:chemistry*
chemical_list: D014867:Water; D002244:Carbon; D018130:Diamond; D001895:Boron