title: Efficient transformation of DDT by peroxymonosulfate activated with cobalt in aqueous systems: Kinetics, products, and reactive species identification.
abstract: Recently, sulfate radical ( [Formula: see text] ) based-advanced oxidation technologies (AOTs) have been attracted great attention in the remediation of contaminated soil and groundwater. In the present study, Co(2+) ions activated peroxymonosulfate (PMS) system was used to degrade 1, 1, 1-trichloro-2, 2'bis(p-chlorophenyl) ethane (DDT) in aqueous solutions. It was found that DDT was efficiently degraded in the PMS/Co(II) solutions within several hours, and the degradation efficiency of DDT was dependent on the concentrations of PMS and Co(II), and the optimum molar ratio of PMS and Co(II) was 50:1. The degradation kinetics of DDT were well described with pseudo-first-order equations over a range of temperature (10-40 °C), and the activation energy that was calculated with Arrhenius equation was 72.3 ± 2.6 kJ/mol. Electron paramagnetic resonance (EPR) and GC-MS techniques were applied to identify the intermediates and reactive species for DDT degradation. The results indicated that [Formula: see text] and OH were the main reactive species accounting for DDT degradation. Dichlorobenzophenone, 4-chlorobenzoic acid and benzylalcohol were the dominant intermediates for DDT degradation, and the likely degradation pathway of DDT was proposed on the basis of these identified products. Increasing pH inhibited the formation of [Formula: see text] and OH, and thus decreased the catalytic degradation of DDT. Cl(-) ion was found to significantly inhibit, while [Formula: see text] and dissolved oxygen had limited effects on DDT degradation.
authors.affiliation: Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, PR China; University of Chinese Academy of Sciences, Beijing 100049, PR China.
authors.forename: Wenxiu
authors.initials: W
authors.lastname: Qin
authors.affiliation: Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, PR China.
authors.forename: Guodong
authors.initials: G
authors.lastname: Fang
authors.affiliation: Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, PR China.
authors.forename: Yujun
authors.initials: Y
authors.lastname: Wang
authors.affiliation: Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, PR China; University of Chinese Academy of Sciences, Beijing 100049, PR China.
authors.forename: Tongliang
authors.initials: T
authors.lastname: Wu
authors.affiliation: Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, PR China; University of Chinese Academy of Sciences, Beijing 100049, PR China.
authors.forename: Changyin
authors.initials: C
authors.lastname: Zhu
authors.affiliation: Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, PR China. Electronic address: dmzhou@issas.ac.cn.
authors.forename: Dongmei
authors.initials: D
authors.lastname: Zhou
mesh_terms: D001577:Benzophenones / Q000032:analysis; D019905:Benzyl Alcohol / Q000032:analysis; D002384:Catalysis; D002723:Chlorobenzoates / Q000032:analysis; D003035:Cobalt / Q000737:chemistry*; D003634:DDT / Q000032:analysis* / Q000737:chemistry; D004578:Electron Spin Resonance Spectroscopy; D052918:Environmental Restoration and Remediation; D008401:Gas Chromatography-Mass Spectrometry; D007700:Kinetics; D008962:Models, Theoretical; D010084:Oxidation-Reduction; D010545:Peroxides / Q000737:chemistry*; D012996:Solutions; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000737:chemistry
chemical_list: D001577:Benzophenones; D002723:Chlorobenzoates; D010545:Peroxides; D012996:Solutions; D014874:Water Pollutants, Chemical; C038288:peroxymonosulfate; D003035:Cobalt; D003634:DDT; C040768:4-chlorobenzoic acid; D019905:Benzyl Alcohol
keywords: Catalytic degradation; DDT; Free radicals; Intermediates