title: Pd-on-Si catalysts prepared via galvanic displacement for the selective hydrogenation of para-chloronitrobenzene.
abstract: The direct redox reaction (galvanic displacement) between Pd(2+) and substrate Si was used to deposit Pd on Si, and the Pd-Si catalysts enabled a chemoselective hydrogenation of para-chloronitrobenzene with the selectivity for para-chloroaniline higher than 99.9% at complete conversion of para-chloronitrobenzene.
authors.affiliation: Innovative Catalysis Program, Key Lab of Organic Optoelectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, China. kqsun@mail.tsinghua.edu.cn bqxu@mail.tsinghua.edu.cn.
authors.forename: Qian
authors.initials: Q
authors.lastname: Wei
authors.affiliation: Innovative Catalysis Program, Key Lab of Organic Optoelectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, China. kqsun@mail.tsinghua.edu.cn bqxu@mail.tsinghua.edu.cn.
authors.forename: Yu-Sheng
authors.initials: YS
authors.lastname: Shi
authors.affiliation: Innovative Catalysis Program, Key Lab of Organic Optoelectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, China. kqsun@mail.tsinghua.edu.cn bqxu@mail.tsinghua.edu.cn.
authors.forename: Ke-Qiang
authors.initials: KQ
authors.lastname: Sun
authors.affiliation: Innovative Catalysis Program, Key Lab of Organic Optoelectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, China. kqsun@mail.tsinghua.edu.cn bqxu@mail.tsinghua.edu.cn.
authors.forename: Bo-Qing
authors.initials: BQ
authors.lastname: Xu