title: Thermally Cured Dual Functional Viologen-Based All-in-One Electrochromic Devices with Panchromatic Modulation.
abstract: Vinyl benzyl viologen (VBV) was synthesized and utilized to obtain all-in-one thermally cured electrochromic devices (ECDs). The vinyl moiety of VBV monomer could react with methyl methacrylate (MMA) to yield bulky VBV/poly(methyl methacrylate) (PMMA) chains and even cross-linked network without the assistance of additional cross-linker. Both the bulky VBV/PMMA chains and the resulting polymer network can hinder the aggregation of the viologens and reduce the possibility of dimerization, rendering enhanced cycling stability. Large transmittance changes (ΔT) over 60% at both 570 and 615 nm were achieved when the VBV-based ECD was switched from 0 V to a low potential bias of 0.5 V. Ultimately, the dual functional of VBV molecules, serving simultaneously as a promising electrochromic material and a cross-linker, is fully utilized in the proposed electrochromic system, making its fabrication process much easier. Negligible decays in ΔT at both wavelengths were observed for the cured ECD after being subjected to 1000 repetitive cycles, while 17.1% and 22.0% decays were noticed at 570 and 615 nm, respectively, for the noncured ECD. In addition, the low voltage-driven feature of the VBV-based ECD enables it to be incorporated with phenyl viologen (PV), further expanding the absorption range of the ECD. Panchromatic characteristic of the proposed PV/VBV-based ECD was demonstrated while exhibiting ΔT over 60% at both wavelengths. Only 5.3% and 6.9% decays, corresponding at 570 and 615 nm, respectively, were observed in the PV/VBV-based ECD after 10 000 continuous cycles at bleaching/coloring voltages of 0/0.5 V with an interval of 10 s for both bleaching and coloring processes.
authors.affiliation: Department of Chemical Engineering and ‡Institute of Polymer Science and Engineering, National Taiwan University , No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan.
authors.forename: Sheng-Yuan
authors.initials: SY
authors.lastname: Kao
authors.affiliation: Department of Chemical Engineering and ‡Institute of Polymer Science and Engineering, National Taiwan University , No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan.
authors.forename: Hsin-Che
authors.initials: HC
authors.lastname: Lu
authors.affiliation: Department of Chemical Engineering and ‡Institute of Polymer Science and Engineering, National Taiwan University , No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan.
authors.forename: Chung-Wei
authors.initials: CW
authors.lastname: Kung
authors.affiliation: Department of Chemical Engineering and ‡Institute of Polymer Science and Engineering, National Taiwan University , No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan.
authors.forename: Hsin-Wei
authors.initials: HW
authors.lastname: Chen
authors.affiliation: Department of Chemical Engineering and ‡Institute of Polymer Science and Engineering, National Taiwan University , No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan.
authors.forename: Ting-Hsiang
authors.initials: TH
authors.lastname: Chang
authors.affiliation: Department of Chemical Engineering and ‡Institute of Polymer Science and Engineering, National Taiwan University , No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan.
authors.forename: Kuo-Chuan
authors.initials: KC
authors.lastname: Ho
keywords: N,N,N′,N′-tetramethyl-p-phenylenediamine (TMPD); electrochromic device (ECD); low driving voltage; panchromatic; phenyl viologen; thermal curing