title: Simultaneous oxidation and adsorption of As(III) from water by cerium modified chitosan ultrafine nanobiosorbent.
abstract: Since most existing arsenic removal adsorbents are difficult to effectively remove arsenite (As(III)), an urgent need is to develop an efficient adsorbent for removing As(III) from contaminated water. In this study, a novel ultrafine nanobiosorbent of cerium modified chitosan (Ce-CNB) with simultaneous oxidation and adsorption As(III) performance has been successfully developed. The resulting Ce-CNB with or without As(III) adsorption was characterized by FTIR, XRD, SEM, EDS, TEM, EMI and XPS analysis. Batch of adsorption experiments were performed to investigate the effects of various conditions on the As(III) adsorption. The adsorption behaviors were well described by the Langmuir isotherm and the pseudo-second-order kinetic model, with the maximum adsorption capacities of 57.5 mg g(-1). The adsorption mechanisms for As(III) were (i) formed monodentate and bidentate complexes between hydroxyl groups and arsenite; and (ii) partial As(III) oxidized to As(V) followed by simultaneously adsorbed on the surface of Ce-CNB. This novel nanocomposite can be reused while maintaining a high removal efficiency and can be applied to treat 5.8L of As(III)-polluted water with the effluent concentration lower than the World Health Organization standard, which suggests its great potential to remove As(III) from contaminated water.
authors.affiliation: School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, PR China; Research Center of Analysis and Test, East China University of Science and Technology, Shanghai 200237, PR China.
authors.forename: Lingfan
authors.initials: L
authors.lastname: Zhang
authors.affiliation: School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, PR China.
authors.forename: Tianyi
authors.initials: T
authors.lastname: Zhu
authors.affiliation: School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, PR China. Electronic address: liuxin@ecust.edu.cn.
authors.forename: Xin
authors.initials: X
authors.lastname: Liu
authors.affiliation: School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, PR China. Electronic address: zhwqing@ecust.edu.cn.
authors.forename: Wenqing
authors.initials: W
authors.lastname: Zhang
mesh_terms: D000327:Adsorption; D001151:Arsenic / Q000737:chemistry*; D002563:Cerium / Q000737:chemistry*; D048271:Chitosan / Q000737:chemistry*; D053761:Nanocomposites / Q000737:chemistry*; D010084:Oxidation-Reduction; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D018508:Water Purification / Q000379:methods
chemical_list: D014874:Water Pollutants, Chemical; D002563:Cerium; D048271:Chitosan; D001151:Arsenic
keywords: Adsorption; Arsenic; Cerium; Chitosan; Nanobiosorbent