title: Gold(i) operational in synergistic catalysis for the intermolecular α-addition reaction of aldehydes across allenamides.
abstract: The intermolecular reaction of allenamides with aldehydes is reported. The designed approach relies on gold(i) and organocatalysis for activating the allenamides and the aldehydes respectively. Conditions to achieve an enantioselective version of this intermolecular reaction are defined.
authors.affiliation: Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica "Enrique Moles", Universidad de Oviedo. C/ Julián Clavería 8, 33006 Oviedo, Spain. jmgd@uniovi.es.
authors.forename: Alberto
authors.initials: A
authors.lastname: Ballesteros
authors.affiliation: Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica "Enrique Moles", Universidad de Oviedo. C/ Julián Clavería 8, 33006 Oviedo, Spain. jmgd@uniovi.es.
authors.forename: Pablo
authors.initials: P
authors.lastname: Morán-Poladura
authors.affiliation: Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica "Enrique Moles", Universidad de Oviedo. C/ Julián Clavería 8, 33006 Oviedo, Spain. jmgd@uniovi.es.
authors.forename: Jose M
authors.initials: JM
authors.lastname: González