title: Ordered Silica Nanoparticles Grown on a Three-Dimensional Carbon Fiber Architecture Substrate with Siliconborocarbonitride Ceramic as a Thermal Barrier Coating.
abstract: Hierarchical structure consisting of ordered silica nanoparticles grown onto carbon fiber (CF) has been fabricated to improve the interfacial properties between the CFs and polymer matrix. To improve the reactivity of CFs, their surface was modified using poly(1,4-phenylene diisocyanate) (PPDI) via in situ polymerization, which also resulted in the distribution of numerous isocyanate groups on the surface of CFs. Silica nanoparticles were modified on the interface of CF-PPDI by chemical grafting method. The microstructure, chemical composition, and interfacial properties of CFs with ordered silica nanoparticles were comprehensively investigated by scanning electron microscopy, X-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy. Results indicated an obvious increase in the interfacial shear strength, compared to that of CF precursor, which was attributed to silica nanoparticles interacting with the epoxy resin. Furthermore, siliconborocarbonitride (SiBCN) ceramic was used as thermal barrier coating to enhance 3D CF architecture substrate antioxidant and ablation properties. Thermogravimetric results show that the thermal stability of the CF with SiBCN ceramic layer has a marked increase at high temperature.
authors.affiliation: National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Centre for Composite Materials and Structures, Harbin Institute of Technology , Harbin 150080, China.
authors.forename: Guangdong
authors.initials: G
authors.lastname: Zhao
authors.affiliation: National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Centre for Composite Materials and Structures, Harbin Institute of Technology , Harbin 150080, China.
authors.forename: Ping
authors.initials: P
authors.lastname: Hu
authors.affiliation: National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Centre for Composite Materials and Structures, Harbin Institute of Technology , Harbin 150080, China.
authors.forename: Shanbao
authors.initials: S
authors.lastname: Zhou
authors.affiliation: National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Centre for Composite Materials and Structures, Harbin Institute of Technology , Harbin 150080, China.
authors.forename: Guiqing
authors.initials: G
authors.lastname: Chen
authors.affiliation: National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Centre for Composite Materials and Structures, Harbin Institute of Technology , Harbin 150080, China.
authors.forename: Yumin
authors.initials: Y
authors.lastname: An
authors.affiliation: National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Centre for Composite Materials and Structures, Harbin Institute of Technology , Harbin 150080, China.
authors.forename: Yehong
authors.initials: Y
authors.lastname: Cheng
authors.affiliation: National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Centre for Composite Materials and Structures, Harbin Institute of Technology , Harbin 150080, China.
authors.forename: Jiadong
authors.initials: J
authors.lastname: An
authors.affiliation: National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Centre for Composite Materials and Structures, Harbin Institute of Technology , Harbin 150080, China.
authors.forename: Xinghong
authors.initials: X
authors.lastname: Zhang
authors.affiliation: National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Centre for Composite Materials and Structures, Harbin Institute of Technology , Harbin 150080, China.
authors.forename: Wenbo
authors.initials: W
authors.lastname: Han
keywords: carbon fiber; chemical grafting; interfacial properties; silica nanoparticles; thermal stability