title: NiCo2S4 nanotube arrays grown on flexible nitrogen-doped carbon foams as three-dimensional binder-free integrated anodes for high-performance lithium-ion batteries.
abstract: Binary metal sulfides, especially NiCo2S4, hold great promise as anode materials for high-performance lithium-ion batteries because of their excellent electronic conductivity and high capacity compared to mono-metal sulfides and oxides. Here, NiCo2S4 nanotube arrays are successfully grown on flexible nitrogen-doped carbon foam (NDCF) substrates with robust adhesion via a facile surfactant-assisted hydrothermal route and the subsequent sulfurization treatment. The obtained NiCo2S4/NDCF composites show unique three-dimensional architectures, in which NiCo2S4 nanotubes of ∼5 μm in length and 100 nm in width are uniformly grown on the NDCF skeletons to form arrays. When used directly as integrated anodes for lithium-ion batteries without any conductive additives and binders, the NiCo2S4/NDCF composites exhibit a high reversible capacity of 1721 mA h g(-1) at a high current density of 500 mA g(-1), enhanced cycling performance with the capacity maintained at 1182 mA h g(-1) after 100 cycles, and a remarkable rate capability. The excellent lithium storage performances of the composites could be attributed to the unique material composition, a rationally designed hollow nanostructure and an integrated smart architecture, which offer fast electron transport and ion diffusion, enhanced material/-electrolyte contact area and facile accommodation of strains during the lithium insertion and extraction process.
authors.affiliation: Key Laboratory of Aerospace Advanced Materials and Performance of Ministry of Education, School of Materials Science and Engineering, Beihang University, Beijing, 100191, China. songmei_li@buaa.edu.cn.
authors.forename: Xiaoyu
authors.initials: X
authors.lastname: Wu
authors.affiliation: Key Laboratory of Aerospace Advanced Materials and Performance of Ministry of Education, School of Materials Science and Engineering, Beihang University, Beijing, 100191, China. songmei_li@buaa.edu.cn.
authors.forename: Songmei
authors.initials: S
authors.lastname: Li
authors.affiliation: Key Laboratory of Aerospace Advanced Materials and Performance of Ministry of Education, School of Materials Science and Engineering, Beihang University, Beijing, 100191, China. songmei_li@buaa.edu.cn.
authors.forename: Bo
authors.initials: B
authors.lastname: Wang
authors.affiliation: Key Laboratory of Aerospace Advanced Materials and Performance of Ministry of Education, School of Materials Science and Engineering, Beihang University, Beijing, 100191, China. songmei_li@buaa.edu.cn.
authors.forename: Jianhua
authors.initials: J
authors.lastname: Liu
authors.affiliation: Key Laboratory of Aerospace Advanced Materials and Performance of Ministry of Education, School of Materials Science and Engineering, Beihang University, Beijing, 100191, China. songmei_li@buaa.edu.cn.
authors.forename: Mei
authors.initials: M
authors.lastname: Yu