title: Copper-Catalyzed Regioselective 1,2-Alkylesterification of Dienes to Allylic Esters.
abstract: Copper catalyzed 1,2-alkylesterification of 1,3-dienes with diacyl peroxides affords branched allylic esters in excellent regioselectivity, including products with a newly generated fully substituted carbon center. The only byproduct is CO2. The reaction proceeds by a radical mechanism as suggested by spin trap and crossover experiments.
authors.affiliation: School of Chemistry and Chemical Engineering, Hefei University of Technology , 193 Tunxi Road, Hefei, 230009, China.
authors.forename: Yougui
authors.initials: Y
authors.lastname: Li
authors.affiliation: School of Chemistry and Chemical Engineering, Hefei University of Technology , 193 Tunxi Road, Hefei, 230009, China.|Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , 155 Yangqiao Road West, Fuzhou, 350002, P. R. China.
authors.forename: Yulong
authors.initials: Y
authors.lastname: Han
authors.affiliation: Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , 155 Yangqiao Road West, Fuzhou, 350002, P. R. China.
authors.forename: Haigen
authors.initials: H
authors.lastname: Xiong
authors.affiliation: Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , 155 Yangqiao Road West, Fuzhou, 350002, P. R. China.
authors.forename: Nengbo
authors.initials: N
authors.lastname: Zhu
authors.affiliation: Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , 155 Yangqiao Road West, Fuzhou, 350002, P. R. China.
authors.forename: Bo
authors.initials: B
authors.lastname: Qian
authors.affiliation: Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , 155 Yangqiao Road West, Fuzhou, 350002, P. R. China.
authors.forename: Changqing
authors.initials: C
authors.lastname: Ye
authors.affiliation: School of Chemistry and Chemical Engineering, Hefei University of Technology , 193 Tunxi Road, Hefei, 230009, China.
authors.forename: Eric Assen B
authors.initials: EA
authors.lastname: Kantchev
authors.affiliation: Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , 155 Yangqiao Road West, Fuzhou, 350002, P. R. China.
authors.forename: Hongli
authors.initials: H
authors.lastname: Bao