title: Characterisation of waste derived biochar added biocomposites: chemical and thermal modifications.
abstract: A step towards sustainability was taken by incorporating waste based pyrolysed biochar in wood and polypropylene biocomposites. The effect of biochar particles on the chemistry and thermal makeup of the composites was determined by characterising them through an array of characterisation techniques such as 3D optical profiling, X-ray diffraction, transmission electron microscopy, electron spin/nuclear magnetic resonance spectroscopy, and differential scanning calorimetry. It was observed that addition of biochar increased the presence of free radicals in the composite while also improving its thermal conductivity. Biochar particles did not interfere with the melting behaviour of polymer in the thermal regime. However, wood and biochar acted as nucleation agents consequently increasing the crystallisation temperature. The crystal structure of polypropylene was not disrupted by biochar inclusion in composite. Transmission electron microscopy images illustrated the aggregated nature of the biochar particles at higher loading levels. Nuclear magnetic resonance studies revealed the aromatic nature of biochar and the broadening of peak intensities of composites with increasing biochar levels due to its amorphous nature and presence of free radicals. Thus, this insight into the chemical and thermal modification of biochar added composites would allow effective engineering to optimise their properties while simultaneously utilising wastes.
authors.affiliation: Department of Civil and Environmental Engineering, University of Auckland, Auckland 1142, New Zealand.
authors.forename: Oisik
authors.initials: O
authors.lastname: Das
authors.affiliation: Department of Civil and Environmental Engineering, University of Auckland, Auckland 1142, New Zealand. Electronic address: a.sarmah@auckland.ac.nz.
authors.forename: Ajit K
authors.initials: AK
authors.lastname: Sarmah
authors.affiliation: School of Chemical Sciences, University of Auckland, Auckland 1142, New Zealand.
authors.forename: Zoran
authors.initials: Z
authors.lastname: Zujovic
authors.affiliation: Centre for Advanced Composite Materials, Department of Mechanical Engineering, University of Auckland, Auckland 1142, New Zealand.
authors.forename: Debes
authors.initials: D
authors.lastname: Bhattacharyya
keywords: Aromatic; Biochar; Composites; Polypropylene; Waste