title: Groundwater fluoride enrichment in an active rift setting: Central Kenya Rift case study.
abstract: Groundwater is used extensively in the Central Kenya Rift for domestic and agricultural demands. In these active rift settings groundwater can exhibit high fluoride levels. In order to address water security and reduce human exposure to high fluoride in drinking water, knowledge of the source and geochemical processes of enrichment are required. A study was therefore carried out within the Naivasha catchment (Kenya) to understand the genesis, enrichment and seasonal variations of fluoride in the groundwater. Rocks, rain, surface and groundwater sources were sampled for hydrogeochemical and isotopic investigations, the data was statistically and geospatially analyzed. Water sources have variable fluoride concentrations between 0.02-75 mg/L. 73% exceed the health limit (1.5mg/L) in both dry and wet seasons. F(-) concentrations in rivers are lower (0.2-9.2mg/L) than groundwater (0.09 to 43.6 mg/L) while saline lake waters have the highest concentrations (0.27-75 mg/L). The higher values are confined to elevations below 2000 masl. Oxygen (δ(18)O) and hydrogen (δD) isotopic values range from -6.2 to +5.8‰ and -31.3 to +33.3‰, respectively, they are also highly variable in the rift floor where they attain maximum values. Fluoride base levels in the precursor vitreous volcanic rocks are higher (between 3750-6000 ppm) in minerals such as cordierite and muscovite while secondary minerals like illite and kaolinite have lower remnant fluoride (<1000 ppm). Thus, geochemical F(-) enrichment in regional groundwater is mainly due to a) rock alteration, i.e. through long residence times and natural discharge and/or enhanced leakages of deep seated geothermal water reservoirs, b) secondary concentration fortification of natural reservoirs through evaporation, through reduced recharge and/or enhanced abstraction and c) through additional enrichment of fluoride after volcanic emissions. The findings are useful to help improve water management in Naivasha as well as similar active rift setting environments.
authors.affiliation: Department of Geology, University of Nairobi, P.O Box 30197, Nairobi, Kenya. Electronic address: lydiaolaka@gmail.com.
authors.forename: Lydia A
authors.initials: LA
authors.lastname: Olaka
authors.affiliation: Geoforschungs Zentrum, Telegrafenberg, 14473 Potsdam, Germany.
authors.forename: Franziska D H
authors.initials: FD
authors.lastname: Wilke
authors.affiliation: Department of Geology, University of Nairobi, P.O Box 30197, Nairobi, Kenya.
authors.forename: Daniel O
authors.initials: DO
authors.lastname: Olago
authors.affiliation: Department of Geology, University of Nairobi, P.O Box 30197, Nairobi, Kenya.
authors.forename: Eric O
authors.initials: EO
authors.lastname: Odada
authors.affiliation: Senckenberg Biodiversity and Climate Research Centre, Senckenberganlage 25, 60325 Frankfurt, Germany; Institut für Geowissenschaften, Goethe Universität Frankfurt, Altenhöferallee 1, 60438 Frankfurt, Germany.
authors.forename: Andreas
authors.initials: A
authors.lastname: Mulch
authors.affiliation: UFZ-Helmholtz-Centre for Environmental Research, Department of Hydrogeology, Permoserstr. 15, 04318 Leipzig, Germany.
authors.forename: Andreas
authors.initials: A
authors.lastname: Musolff
keywords: Central Kenya Rift; Chloride; Fluoride; Groundwater; Isotopes; Water–rock interaction