title: Molecular Epoxidation Reactions Catalyzed by Rhenium, Molybdenum, and Iron Complexes.
abstract: Epoxidations are of high relevance in many organic syntheses, both in industry and academia. In this personal account, the development of rhenium, molybdenum, and iron complexes in molecular epoxidation catalysis is presented. Methyltrioxorhenium (MTO) is the benchmark catalyst for these reactions, with a thoroughly investigated mechanism and reactivity profile. More recently, highly active molecular molybdenum and iron catalysts have emerged, challenging the extraordinary role of MTO in epoxidation catalysis with high turnover frequencies (TOFs). This development is highlighted in its use of cheaper, more readily available metals, and the challenges of using base metals in catalysis are discussed. These results show the promise that relatively cheap and abundant metals, such as molybdenum and iron, hold for the future of epoxidation catalysis.
authors.affiliation: Department of Chemistry and Catalysis Research Center, Technische Universität München (TUM), Lichtenbergstr. 4, D-85747, Garching bei München, Germany.
authors.forename: Jens W
authors.initials: JW
authors.lastname: Kück
authors.affiliation: Department of Chemistry and Catalysis Research Center, Technische Universität München (TUM), Lichtenbergstr. 4, D-85747, Garching bei München, Germany.
authors.forename: Robert M
authors.initials: RM
authors.lastname: Reich
authors.affiliation: Department of Chemistry and Catalysis Research Center, Technische Universität München (TUM), Lichtenbergstr. 4, D-85747, Garching bei München, Germany.
authors.forename: Fritz E
authors.initials: FE
authors.lastname: Kühn
keywords: complexes; epoxidation; iron; molybdenum; rhenium