title: Phosphorescent columnar hybrid materials containing polyionic inorganic nanoclusters.
abstract: The ternary polyionic inorganic compound Cs2Mo6Br14 and 18-crown-6 ethers bearing two o-terphenyl units have been combined to design phosphorescent columnar liquid crystalline hybrid materials. The obtained host-guest complexes are very stable even at high temperatures. Depending on their surrounding atmosphere, these hybrids switch reversibly from a high-to-low luminescence state and show a very stable emission intensity up to 140 °C.
authors.affiliation: Université de Rennes 1 - CNRS UMR 6226 "Institut des Sciences Chimiques de Rennes", Campus de Beaulieu, CS 74205, 35042 Rennes Cedex, France. yann.molard@univ-rennes1.fr.
authors.forename: S K
authors.initials: SK
authors.lastname: Nayak
authors.affiliation: Université de Rennes 1 - CNRS UMR 6226 "Institut des Sciences Chimiques de Rennes", Campus de Beaulieu, CS 74205, 35042 Rennes Cedex, France. yann.molard@univ-rennes1.fr.
authors.forename: M
authors.initials: M
authors.lastname: Amela-Cortes
authors.affiliation: Institute of Organic Chemistry, University of Stuttgart, Pfaffendwaldring 55, 70569, Stuttgart, Germany. Sabine.Laschat@oc.uni-stuttgart.de.
authors.forename: M M
authors.initials: MM
authors.lastname: Neidhardt
authors.affiliation: Institute of Organic Chemistry, University of Stuttgart, Pfaffendwaldring 55, 70569, Stuttgart, Germany. Sabine.Laschat@oc.uni-stuttgart.de.
authors.forename: S
authors.initials: S
authors.lastname: Beardsworth
authors.affiliation: Institute of Organic Chemistry, University of Stuttgart, Pfaffendwaldring 55, 70569, Stuttgart, Germany. Sabine.Laschat@oc.uni-stuttgart.de.
authors.forename: J
authors.initials: J
authors.lastname: Kirres
authors.affiliation: Institute of Organic Chemistry, University of Stuttgart, Pfaffendwaldring 55, 70569, Stuttgart, Germany. Sabine.Laschat@oc.uni-stuttgart.de.
authors.forename: M
authors.initials: M
authors.lastname: Mansueto
authors.affiliation: Université de Rennes 1 - CNRS UMR 6226 "Institut des Sciences Chimiques de Rennes", Campus de Beaulieu, CS 74205, 35042 Rennes Cedex, France. yann.molard@univ-rennes1.fr.
authors.forename: S
authors.initials: S
authors.lastname: Cordier
authors.affiliation: Institute of Organic Chemistry, University of Stuttgart, Pfaffendwaldring 55, 70569, Stuttgart, Germany. Sabine.Laschat@oc.uni-stuttgart.de.
authors.forename: S
authors.initials: S
authors.lastname: Laschat
authors.affiliation: Université de Rennes 1 - CNRS UMR 6226 "Institut des Sciences Chimiques de Rennes", Campus de Beaulieu, CS 74205, 35042 Rennes Cedex, France. yann.molard@univ-rennes1.fr.
authors.forename: Y
authors.initials: Y
authors.lastname: Molard