title: A self-assembled, multicomponent water oxidation device.
abstract: Langmuir-Blodgett (LB) and drop-cast (DC) films prepared from [Ru(1)3][PF6]2 and Co4POM (1= 4,4'-bis((n)nonyl)-2,2'-bipyridine, Co4POM = K10[Co4(H2O)2(α-PW9O34)2]) have been evaluated as water oxidation catalysts and their electrocatalytic performances are reported; DC films evolve more O2 per unit area than LB films and the catalyst is stable on an FTO surface for ≈500-600 minutes.
authors.affiliation: Laboratory for High Performance Ceramics, Empa. Swiss Federal Laboratories for Materials Science and Technology, Uberlandstrasse 129, CH-8600, Dubendorf, Switzerland.
authors.forename: Rita
authors.initials: R
authors.lastname: Tóth
authors.affiliation: Department of Chemistry, University of Basel, Spitalstrasse 51, CH4056 Basel, Switzerland. edwin.constable@unibas.ch.
authors.forename: Roché M
authors.initials: RM
authors.lastname: Walliser
authors.affiliation: Department of Chemistry, University of Basel, Spitalstrasse 51, CH4056 Basel, Switzerland. edwin.constable@unibas.ch.
authors.forename: Niamh S
authors.initials: NS
authors.lastname: Murray
authors.affiliation: Laboratory for High Performance Ceramics, Empa. Swiss Federal Laboratories for Materials Science and Technology, Uberlandstrasse 129, CH-8600, Dubendorf, Switzerland.
authors.forename: Debajeet K
authors.initials: DK
authors.lastname: Bora
authors.affiliation: Laboratory for High Performance Ceramics, Empa. Swiss Federal Laboratories for Materials Science and Technology, Uberlandstrasse 129, CH-8600, Dubendorf, Switzerland.
authors.forename: Artur
authors.initials: A
authors.lastname: Braun
authors.affiliation: Protection and Physiology, Empa, Swiss Federal Laboratories for Materials Science and Technology, Lerchenfeldstr. 5, 9014 St. Gallen, Switzerland.
authors.forename: Guiseppino
authors.initials: G
authors.lastname: Fortunato
authors.affiliation: Department of Chemistry, University of Basel, Spitalstrasse 51, CH4056 Basel, Switzerland. edwin.constable@unibas.ch.
authors.forename: Catherine E
authors.initials: CE
authors.lastname: Housecroft
authors.affiliation: Department of Chemistry, University of Basel, Spitalstrasse 51, CH4056 Basel, Switzerland. edwin.constable@unibas.ch.
authors.forename: Edwin C
authors.initials: EC
authors.lastname: Constable
mesh_terms: D002384:Catalysis; D004563:Electrochemistry; D010084:Oxidation-Reduction; D014867:Water / Q000737:chemistry*
chemical_list: D014867:Water