title: Electrochemical Energy Storage Application and Degradation Analysis of Carbon-Coated Hierarchical NiCo2S4 Core-Shell Nanowire Arrays Grown Directly on Graphene/Nickel Foam.
abstract: We developed a new electrode comprising thin carbon layer coated hierarchical NiCo2S4 core-shell nanowire arrays (NiCo2S4@C CSNAs) on graphene/Ni foam (Ni@G) substrates. The electrode showed outstanding electrochemical characteristics including a high specific capacitance of 253 mAh g(-1) at 3 A g(-1), high rate capability of 163 mAh g(-1) at 50 A g(-1) (~64.4% of that at 3 A g(-1)), and long-term cycling stability with a capacity retention of 93.9% after 5000 cycles. Comparative studies on the degradation of hierarchical NiCo2S4 CSNA electrodes with and without carbon coatings revealed that the morphology pulverization, structural separation at core/shell interface, and irretrievably chemical composition change of NiCo2S4 CSNAs electrode are major factors that deteriorate the electrochemical performance of the electrodes without carbon coating. The favorable roles of carbon coatings on hierarchical NiCo2S4 CSNAs were further clarified: (1) serving as a physical buffering layer that suppresses the structural breakdown; (2) retarding the chemical composition conversion of the NiCo2S4 CSNAs; and (3) providing extra path for charge transition in addition to the NiCo2S4 core nanowires. Understanding of the degradation mechanisms and the significance of the surface carbon coatings would provide useful guidelines for the design of new electrode materials for high-performance electrochemical devices.
authors.affiliation: State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China.|Center of Super-Diamond and Advanced Films (COSDAF), Department of Physics and Materials Science, City University of Hong Kong, Hong Kong.
authors.forename: Rujia
authors.initials: R
authors.lastname: Zou
authors.affiliation: Center of Super-Diamond and Advanced Films (COSDAF), Department of Physics and Materials Science, City University of Hong Kong, Hong Kong.
authors.forename: Muk Fung
authors.initials: MF
authors.lastname: Yuen
authors.affiliation: State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China.
authors.forename: Li
authors.initials: L
authors.lastname: Yu
authors.affiliation: State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China.
authors.forename: Junqing
authors.initials: J
authors.lastname: Hu
authors.affiliation: Center of Super-Diamond and Advanced Films (COSDAF), Department of Physics and Materials Science, City University of Hong Kong, Hong Kong.
authors.forename: Chun-Sing
authors.initials: CS
authors.lastname: Lee
authors.affiliation: Center of Super-Diamond and Advanced Films (COSDAF), Department of Physics and Materials Science, City University of Hong Kong, Hong Kong.
authors.forename: Wenjun
authors.initials: W
authors.lastname: Zhang
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