title: Usefulness of Mesoporous Silica as a Template for the Preparation of Bundles of Bi Nanowires with Precisely Controlled Diameter Below 10 nm.
abstract: The reduction of the diameter of Bi nanowires below 10 nm has been an important target because of the theoretical prediction with regard to significant enhancement in thermoelectric performance by size reduction. In this study, we have demonstrated the usefulness of mesoporous silica with tunable pore size as a template for the preparation of thin Bi nanowires with diameters below 10 nm. Bi was deposited within the templates through a liquid phase deposition using hexane and 1,1,3,3-tetramethyldisiloxane as a solvent and reducing agent, respectively. Bundles of thin Bi nanowires with non-crystalline frameworks were successfully obtained after the template removal. The diameter was precisely controlled between about 6 nm and 9 nm. The judicious choices of mesoporous silica and deposition conditions are critical for the successful preparation. The reliable formation of such thin Bi nanowires reported here opens up exciting new possibilities.
authors.affiliation: Department of Applied Chemistry, Faculty of Science and Engineering, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo, 169-8555, Japan), Fax: (+81) 3-5286-3199.
authors.forename: Masaki
authors.initials: M
authors.lastname: Kitahara
authors.affiliation: Department of Applied Chemistry, Faculty of Science and Engineering, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo, 169-8555, Japan), Fax: (+81) 3-5286-3199.
authors.forename: Hasbuna
authors.initials: H
authors.lastname: Kamila
authors.affiliation: Department of Applied Chemistry, Faculty of Science and Engineering, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo, 169-8555, Japan), Fax: (+81) 3-5286-3199.
authors.forename: Atsushi
authors.initials: A
authors.lastname: Shimojima
authors.affiliation: Department of Applied Chemistry, Faculty of Science and Engineering, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo, 169-8555, Japan), Fax: (+81) 3-5286-3199.
authors.forename: Hiroaki
authors.initials: H
authors.lastname: Wada
authors.affiliation: National Institute for Materials Science (NIMS), International Center for Materials Nanoarchitechtonics (MANA), Namiki-1, Tsukuba, Ibaraki, 305-0044, Japan.
authors.forename: Takao
authors.initials: T
authors.lastname: Mori
authors.affiliation: Department of Physics, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi, 464-8602, Japan.
authors.forename: Ichiro
authors.initials: I
authors.lastname: Terasaki
authors.affiliation: Department of Applied Chemistry, Faculty of Science and Engineering, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo, 169-8555, Japan), Fax: (+81) 3-5286-3199. kuroda@waseda.jp.|Kagami Memorial Research Institute for Materials Science and Technology, Waseda University, Nishiwaseda-2, Shinjuku-ku, Tokyo, 169-0051, Japan. kuroda@waseda.jp.
authors.forename: Kazuyuki
authors.initials: K
authors.lastname: Kuroda
keywords: bismuth; mesoporous materials; nanowires; template synthesis; thermoelectric materials