title: Designed Functional Systems for High-Performance Lithium-Ion Batteries Anode: From Solid to Hollow, and to Core-Shell NiCo2O4 Nanoparticles Encapsulated in Ultrathin Carbon Nanosheets.
abstract: Binary metal oxides have been considered as ideal and promising anode materials, which can ameliorate and enhance the electrochemical performances of the single metal oxides, such as electronic conductivity, reversible capacity, and structural stability. In this research, we report a rational method to synthesize some novel sandwich-like NiCo2O4@C nanosheets arrays for the first time. The nanostructures exhibit the unique features of solid, hollow, and even core-shell NiCo2O4 nanoparticles encapsulated inside and a graphitized carbon layers coating outside. Compared to the previous reports, these composites demonstrate more excellent electrochemical performances, including superior rate capability and excellent cycling capacity. Therefore, the final conclusion would be given that these multifarious sandwich-like NiCo2O4@C composites could be highly qualified candidates for lithium-ion battery anodes in some special field, in which good capability and high capacity are urgently required.
authors.affiliation: The State Key Laboratory of Mechanical Transmissions and School of Chemistry and Chemical Engineering, Chongqing University , Chongqing 400044, China.
authors.forename: Liang
authors.initials: L
authors.lastname: Peng
authors.affiliation: The State Key Laboratory of Mechanical Transmissions and School of Chemistry and Chemical Engineering, Chongqing University , Chongqing 400044, China.
authors.forename: Huijuan
authors.initials: H
authors.lastname: Zhang
authors.affiliation: The State Key Laboratory of Mechanical Transmissions and School of Chemistry and Chemical Engineering, Chongqing University , Chongqing 400044, China.
authors.forename: Ling
authors.initials: L
authors.lastname: Fang
authors.affiliation: The State Key Laboratory of Mechanical Transmissions and School of Chemistry and Chemical Engineering, Chongqing University , Chongqing 400044, China.
authors.forename: Yuanjuan
authors.initials: Y
authors.lastname: Bai
authors.affiliation: The State Key Laboratory of Mechanical Transmissions and School of Chemistry and Chemical Engineering, Chongqing University , Chongqing 400044, China.
authors.forename: Yu
authors.initials: Y
authors.lastname: Wang
keywords: binary metal oxides; core−shell; encapsulation; energy storage; ultrathin carbon