title: The Halogen Bond.
abstract: The halogen bond occurs when there is evidence of a net attractive interaction between an electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic region in another, or the same, molecular entity. In this fairly extensive review, after a brief history of the interaction, we will provide the reader with a snapshot of where the research on the halogen bond is now, and, perhaps, where it is going. The specific advantages brought up by a design based on the use of the halogen bond will be demonstrated in quite different fields spanning from material sciences to biomolecular recognition and drug design.
authors.affiliation: Laboratory of Nanostructured Fluorinated Materials (NFMLab), Department of Chemistry, Materials and Chemical Engineering "Giulio Natta", Politecnico di Milano , Via L. Mancinelli 7, I-20131 Milano, Italy.
authors.forename: Gabriella
authors.initials: G
authors.lastname: Cavallo
authors.affiliation: Laboratory of Nanostructured Fluorinated Materials (NFMLab), Department of Chemistry, Materials and Chemical Engineering "Giulio Natta", Politecnico di Milano , Via L. Mancinelli 7, I-20131 Milano, Italy.|VTT-Technical Research Centre of Finland , Biologinkuja 7, 02150 Espoo, Finland.
authors.forename: Pierangelo
authors.initials: P
authors.lastname: Metrangolo
authors.affiliation: VTT-Technical Research Centre of Finland , Biologinkuja 7, 02150 Espoo, Finland.
authors.forename: Roberto
authors.initials: R
authors.lastname: Milani
authors.affiliation: Laboratory of Nanostructured Fluorinated Materials (NFMLab), Department of Chemistry, Materials and Chemical Engineering "Giulio Natta", Politecnico di Milano , Via L. Mancinelli 7, I-20131 Milano, Italy.
authors.forename: Tullio
authors.initials: T
authors.lastname: Pilati
authors.affiliation: Department of Chemistry and Bioengineering, Tampere University of Technology , Korkeakoulunkatu 8, FI-33101 Tampere, Finland.
authors.forename: Arri
authors.initials: A
authors.lastname: Priimagi
authors.affiliation: Laboratory of Nanostructured Fluorinated Materials (NFMLab), Department of Chemistry, Materials and Chemical Engineering "Giulio Natta", Politecnico di Milano , Via L. Mancinelli 7, I-20131 Milano, Italy.
authors.forename: Giuseppe
authors.initials: G
authors.lastname: Resnati
authors.affiliation: Laboratory of Nanostructured Fluorinated Materials (NFMLab), Department of Chemistry, Materials and Chemical Engineering "Giulio Natta", Politecnico di Milano , Via L. Mancinelli 7, I-20131 Milano, Italy.
authors.forename: Giancarlo
authors.initials: G
authors.lastname: Terraneo
mesh_terms: D006219:Halogens / Q000737:chemistry*; D006846:Hydrocarbons, Halogenated / Q000737:chemistry*; D015394:Molecular Structure
chemical_list: D006219:Halogens; D006846:Hydrocarbons, Halogenated
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