title: Rotational Study of Dimethyl Ether-Chlorotrifluoroethylene: Lone Pair···π Interaction Links the Two Subunits.
abstract: The rotational spectra of two isotopologues of chlorotrifluoroethylene-dimethyl ether show that the two constituent molecules are held together by a lone pair···π interaction. The ether oxygen is linked to the (CF2) carbon atom, with a C-O distance of 2.908 Å.
authors.affiliation: Dipartimento di Chimica "G. Ciamician" dell'Università , Via Selmi 2, I-40126 Bologna, Italy.
authors.forename: Lorenzo
authors.initials: L
authors.lastname: Spada
authors.affiliation: Dipartimento di Chimica "G. Ciamician" dell'Università , Via Selmi 2, I-40126 Bologna, Italy.
authors.forename: Qian
authors.initials: Q
authors.lastname: Gou
authors.affiliation: Department of Chemistry, University of Antwerp , Groenenborgerlaan 171, 2020 Antwerp, Belgium.
authors.forename: Yannick
authors.initials: Y
authors.lastname: Geboes
authors.affiliation: Department of Chemistry, University of Antwerp , Groenenborgerlaan 171, 2020 Antwerp, Belgium.
authors.forename: Wouter A
authors.initials: WA
authors.lastname: Herrebout
authors.affiliation: Dipartimento di Chimica "G. Ciamician" dell'Università , Via Selmi 2, I-40126 Bologna, Italy.
authors.forename: Sonia
authors.initials: S
authors.lastname: Melandri
authors.affiliation: Dipartimento di Chimica "G. Ciamician" dell'Università , Via Selmi 2, I-40126 Bologna, Italy.
authors.forename: Walther
authors.initials: W
authors.lastname: Caminati