title: Atomic/Molecular Layer Deposition of Lithium Terephthalate Thin Films as High Rate Capability Li-Ion Battery Anodes.
abstract: We demonstrate the fabrication of high-quality electrochemically active organic lithium electrode thin films by the currently strongly emerging combined atomic/molecular layer deposition (ALD/MLD) technique using lithium terephthalate, a recently found anode material for lithium-ion battery (LIB), as a proof-of-the-concept material. Our deposition process for Li-terephthalate is shown to well comply with the basic principles of ALD-type growth including the sequential self-saturated surface reactions, a necessity when aiming at micro-LIB devices with three-dimensional architectures. The as-deposited films are found crystalline across the deposition temperature range of 200-280 °C, which is a trait highly desired for an electrode material but rather unusual for hybrid inorganic-organic thin films. Excellent rate capability is ascertained for the Li-terephthalate films with no conductive additives required. The electrode performance can be further enhanced by depositing a thin protective LiPON solid-state electrolyte layer on top of Li-terephthalate; this yields highly stable structures with capacity retention of over 97% after 200 charge/discharge cycles at 3.2 C.
authors.affiliation: Department of Chemistry, Aalto University , P.O. Box 16100, FI-00076 Espoo, Finland.
authors.forename: Mikko
authors.initials: M
authors.lastname: Nisula
authors.affiliation: Department of Chemistry, Aalto University , P.O. Box 16100, FI-00076 Espoo, Finland.
authors.forename: Maarit
authors.initials: M
authors.lastname: Karppinen
keywords: Atomic layer deposition; molecular layer deposition; organic electrode; thin film battery