title: Substituent-Controlled Chemoselective Cleavage of C═C or Csp(2)-C(CO) Bond in α,β-Unsaturated Carbonyl Compounds with H-Phosphonates Leading to β-Ketophosphonates.
abstract: An unprecedented substituent-controlled chemoselective cleavage of C═C double bond or C(sp(2))-C(CO) bond along with aerobic phosphorylation of α,β-unsaturated carbonyl compounds with H-phosphonates through a radical process has been disclosed. The current strategy provides an access to β-ketophosphonates under mild conditions with a wide substrate scope.
authors.affiliation: Institute of Next Generation Matter Transformation, College of Chemical Engineering, College of Materials Science & Engineering, Huaqiao University , 668 Jimei Blvd, Xiamen, Fujian 361021, P. R. China.
authors.forename: Yao
authors.initials: Y
authors.lastname: Zhou
authors.affiliation: Institute of Next Generation Matter Transformation, College of Chemical Engineering, College of Materials Science & Engineering, Huaqiao University , 668 Jimei Blvd, Xiamen, Fujian 361021, P. R. China.
authors.forename: Changqing
authors.initials: C
authors.lastname: Rao
authors.affiliation: Institute of Next Generation Matter Transformation, College of Chemical Engineering, College of Materials Science & Engineering, Huaqiao University , 668 Jimei Blvd, Xiamen, Fujian 361021, P. R. China.
authors.forename: Shaoyu
authors.initials: S
authors.lastname: Mai
authors.affiliation: Institute of Next Generation Matter Transformation, College of Chemical Engineering, College of Materials Science & Engineering, Huaqiao University , 668 Jimei Blvd, Xiamen, Fujian 361021, P. R. China.
authors.forename: Qiuling
authors.initials: Q
authors.lastname: Song