title: An efficient one-pot synthesis of 1,4-disubstituted 1,2,3-triazoles at room temperature by green synthesized Cu NPs using Otostegia persica leaf extract.
abstract: In this study, copper nanoparticles (Cu NPs) were synthesized using a rapid, single step and completely green biosynthetic method by reduction of CuCl2 · 2H2O solution with aqueous extract of leaves of Otostegia persica containing flavonoid and other phenolics as a main factor which acts as reducing agent and efficient stabilizer. UV-vis spectra gave surface plasmon resonance (SPR) at 560 nm. The Cu NPs were characterized by transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD). A possible synthesis mechanism of Cu NPs was presented. In addition, we investigated the catalytic activity of Cu NPs for the one-pot synthesis of 1,4-disubstituted 1,2,3-triazoles under mild reaction conditions with good to excellent yields. The catalyst could be easily recovered by centrifugation and reused at least five recycles with no significant decreases in the yields.
authors.affiliation: Department of Chemistry, Faculty of Science, University of Qom, Qom 3716146611, Iran; Center of Environmental Researches, University of Qom, Qom, Iran. Electronic address: mahmoudnasr81@gmail.com.
authors.forename: Mahmoud
authors.initials: M
authors.lastname: Nasrollahzadeh
authors.affiliation: Department of Petroleum Geoscience, Faculty of Science, Soran University, PO Box 624, Soran, Kurdistan Regional Government, Iraq.
authors.forename: S Mohammad
authors.initials: SM
authors.lastname: Sajadi
authors.affiliation: Department of Biology, Faculty of Science, Soran University, PO Box 624, Soran, Kurdistan Regional Government, Iraq.
authors.forename: Yousef
authors.initials: Y
authors.lastname: Mirzaei
mesh_terms: D003300:Copper / Q000737:chemistry*; D019686:Lamiaceae / Q000737:chemistry*; D053768:Metal Nanoparticles / Q000737:chemistry*; D015394:Molecular Structure; D010316:Particle Size; D010936:Plant Extracts / Q000737:chemistry*; D018515:Plant Leaves / Q000737:chemistry*; D013499:Surface Properties; D013696:Temperature; D014230:Triazoles / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D010936:Plant Extracts; D014230:Triazoles; D003300:Copper
keywords: 1,4-Substituted 1,2,3-triazoles; Cu NPs; Green synthesis; Otostegia persica