title: Two novel μ6-O(2-) bridged Co14/Ni14 hydroxamate clusters packed in distorted face-centered cubic patterns.
abstract: Two novel clusters [Co(μ6-O(2-))(sbha)12(sba)2 (DMF)7(DMA)]·(DMF)8 (1) and [Ni(μ6-O(2-))(sbha)12(sba)2(DMF)8] (2) (sH2bha = 4-bromo-benzohydroximic acid; sHba = 4-bromobenzene carboxylic acid; DMF = N,N-dimethylformamide; DMA = dimethylamine) have been synthesized. The novel body-centred μ6-O(2-) bridged Co14 and Ni14 clusters are packed in distorted face-centered cubic (FCC) patterns with different symmetries. Magnetic studies confirmed the antiferromagnetic exchange interactions between magnetic centers.
authors.affiliation: Department of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, and Key Laboratory of Advanced Energy Materials Chemistry (MOE), Tianjin 300071, P. R. China. guwen68@nankai.edu.cn liuxin64@nankai.edu.cn.
authors.forename: Yanping
authors.initials: Y
authors.lastname: Zhang
authors.affiliation: Department of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, and Key Laboratory of Advanced Energy Materials Chemistry (MOE), Tianjin 300071, P. R. China. guwen68@nankai.edu.cn liuxin64@nankai.edu.cn.
authors.forename: Rui
authors.initials: R
authors.lastname: Lv
authors.affiliation: Department of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, and Key Laboratory of Advanced Energy Materials Chemistry (MOE), Tianjin 300071, P. R. China. guwen68@nankai.edu.cn liuxin64@nankai.edu.cn.
authors.forename: Jingyao
authors.initials: J
authors.lastname: Wang
authors.affiliation: Department of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, and Key Laboratory of Advanced Energy Materials Chemistry (MOE), Tianjin 300071, P. R. China. guwen68@nankai.edu.cn liuxin64@nankai.edu.cn.
authors.forename: Linyan
authors.initials: L
authors.lastname: Yang
authors.affiliation: Department of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, and Key Laboratory of Advanced Energy Materials Chemistry (MOE), Tianjin 300071, P. R. China. guwen68@nankai.edu.cn liuxin64@nankai.edu.cn.
authors.forename: Shengyun
authors.initials: S
authors.lastname: Liao
authors.affiliation: Department of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, and Key Laboratory of Advanced Energy Materials Chemistry (MOE), Tianjin 300071, P. R. China. guwen68@nankai.edu.cn liuxin64@nankai.edu.cn.
authors.forename: Jinlei
authors.initials: J
authors.lastname: Tian
authors.affiliation: Department of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, and Key Laboratory of Advanced Energy Materials Chemistry (MOE), Tianjin 300071, P. R. China. guwen68@nankai.edu.cn liuxin64@nankai.edu.cn.
authors.forename: Wen
authors.initials: W
authors.lastname: Gu
authors.affiliation: Department of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, and Key Laboratory of Advanced Energy Materials Chemistry (MOE), Tianjin 300071, P. R. China. guwen68@nankai.edu.cn liuxin64@nankai.edu.cn.
authors.forename: Xin
authors.initials: X
authors.lastname: Liu