title: Rheology of κ/ι-hybrid carrageenan from Mastocarpus stellatus: Critical parameters for the gel formation.
abstract: The sol-gel diagrams of kappa/iota-hybrid carrageenan (KI) extracted from Mastocarpus stellatus powders with two different average particle sizes of the seaweed powders (117.0 μm and 77.5 μm) prior to the biopolymer extraction, are reported for the first time, together with rheological properties of obtained KI gels. Extraction yields for KI isolated from algae and average molecular weight of KI, determined by gel permeation chromatography, decreased with increasing the particle size of the powder. Rheological results indicated that tested samples exhibited stable and weak gel properties, except those prepared at 1.5% KI in 1.0 mol/L NaCl where stronger gels were found. Aqueous KI extracts with larger molecular weight led to stronger gels and also formed gels at lower biopolymer concentration in NaCl above 0.15 mol/L. All gels reached stability after 20 min of maturation. The data sets showed a strong temperature dependency. Gel setting temperatures significantly depended on the KI and NaCl content, whereas gel melting temperatures (68.0 ± 0.7 °C) were independent of both salt concentrations.
authors.affiliation: Department of Chemical Engineering, Universidade de Santiago de Compostela, Lope Gómez de Marzoa St, Santiago de Compostela E-15782, Spain. Electronic address: mariadolores.torres.perez@usc.es.
authors.forename: M D
authors.initials: MD
authors.lastname: Torres
authors.affiliation: Department of Chemical Engineering, Universidade de Santiago de Compostela, Lope Gómez de Marzoa St, Santiago de Compostela E-15782, Spain. Electronic address: francisco.chenlo@usc.es.
authors.forename: F
authors.initials: F
authors.lastname: Chenlo
authors.affiliation: Department of Chemical Engineering, Universidade de Santiago de Compostela, Lope Gómez de Marzoa St, Santiago de Compostela E-15782, Spain. Electronic address: ramon.moreira@usc.es.
authors.forename: R
authors.initials: R
authors.lastname: Moreira
mesh_terms: D002351:Carrageenan / Q000737:chemistry* / Q000302:isolation & purification; D005782:Gels; D007221:Industry; D012212:Rheology; D000461:Rhodophyta / Q000737:chemistry*
chemical_list: D005782:Gels; D002351:Carrageenan
keywords: Ionic strength; Particle size; Sol–gel transition