title: Construction of a 2D Graphene-Like MoS2/C3N4 Heterojunction with Enhanced Visible-Light Photocatalytic Activity and Photoelectrochemical Activity.
abstract: A novel graphene-like MoS2 /C3N4 (GL-MoS2/C3N4) composite photocatalyst has been synthesized by a facile ethylene glycol (EG)-assisted solvothermal method. The structure and morphology of this GL-MoS2/C3N4 photocatalyst have been investigated by a wide range of characterization methods. The results showed that GL-MoS2 was uniformly distributed on the surface of GL-C3N4 forming a heterostructure. The obtained composite exhibited strong absorbing ability in the ultraviolet (UV) and visible regions. When irradiated with visible light, the composite photocatalyst showed high activity superior to those of the respective individual components GL-MoS2 and GL-C3N4 in the degradation of methyl orange. The enhanced photocatalytic activity of the composite may be attributed to the efficient separation of electron-hole pairs as a result of the matching band potentials between GL-MoS2 and GL-C3N4. Furthermore, a photocatalytic mechanism for the composite material has been proposed, and the photocatalytic reaction kinetics has been measured. Moreover, GL-MoS2/C3N4 could serve as a novel sensor for trace amounts of Cu(2+) since it exhibited good selectivity for Cu(2+) detection in water.
authors.affiliation: School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, P. R. China.
authors.forename: Jia
authors.initials: J
authors.lastname: Yan
authors.affiliation: School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, P. R. China.
authors.forename: Zhigang
authors.initials: Z
authors.lastname: Chen
authors.affiliation: School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, P. R. China.
authors.forename: Haiyan
authors.initials: H
authors.lastname: Ji
authors.affiliation: School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, 639798, Singapore.
authors.forename: Zheng
authors.initials: Z
authors.lastname: Liu
authors.affiliation: School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, P. R. China.
authors.forename: Xin
authors.initials: X
authors.lastname: Wang
authors.affiliation: School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, P. R. China.
authors.forename: Yuanguo
authors.initials: Y
authors.lastname: Xu
authors.affiliation: School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, P. R. China.
authors.forename: Xiaojie
authors.initials: X
authors.lastname: She
authors.affiliation: School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, P. R. China.
authors.forename: Liying
authors.initials: L
authors.lastname: Huang
authors.affiliation: Institute for Energy Research, Jiangsu University, Zhenjiang, 212013, P. R. China.
authors.forename: Li
authors.initials: L
authors.lastname: Xu
authors.affiliation: School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, P. R. China. xh@ujs.edu.cn.|Institute for Energy Research, Jiangsu University, Zhenjiang, 212013, P. R. China. xh@ujs.edu.cn.
authors.forename: Hui
authors.initials: H
authors.lastname: Xu
authors.affiliation: School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, P. R. China. lihm@mail.ujs.edu.cn.|Institute for Energy Research, Jiangsu University, Zhenjiang, 212013, P. R. China. lihm@mail.ujs.edu.cn.
authors.forename: Huaming
authors.initials: H
authors.lastname: Li
keywords: charge transfer; graphene-like MoS2/C3N4; photocatalysis; photoelectrochemical activity; trace analysis