title: A P-H Functionalized Al/P Frustrated Lewis Pair: Substrate Activation and Selective Hydrogen Transfer.
abstract: Hydroalumination of an alkynylphosphine gave an unprecedented P-H functionalized frustrated Lewis pair (FLP). The reactive P-H group does not influence the typical FLP properties, but the activation of substrates follows a new reaction pattern involving hydrogen transfer to yield unusual compounds with phosphaurea, iminophosphine, or phosphanyltriazene structural motifs.
authors.affiliation: Institut für Anorganische und Analytische Chemie, Westfälische Wilhelms-Universität Münster, Corrensstrasse 30, 48149, Münster, Germany.
authors.forename: Lukas
authors.initials: L
authors.lastname: Keweloh
authors.affiliation: Institut für Anorganische und Analytische Chemie, Westfälische Wilhelms-Universität Münster, Corrensstrasse 30, 48149, Münster, Germany.
authors.forename: Hans
authors.initials: H
authors.lastname: Klöcker
authors.affiliation: Organisch-chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstrasse 40, 48149, Münster, Germany.
authors.forename: Ernst-Ulrich
authors.initials: EU
authors.lastname: Würthwein
authors.affiliation: Institut für Anorganische und Analytische Chemie, Westfälische Wilhelms-Universität Münster, Corrensstrasse 30, 48149, Münster, Germany. uhlw@uni-muenster.de.
authors.forename: Werner
authors.identifier: http://orcid.org/0000-0002-7178-5517
authors.initials: W
authors.lastname: Uhl
keywords: aluminum; cooperativity; density functional calculations; frustrated Lewis pairs; insertion reactions