title: Polyoxovanadate-based organic-inorganic hybrids: from {V5O9Cl} clusters to nanosized octahedral cages.
abstract: Three polyoxovanadate-based metal-organic polyhedra (denoted as VMOP-1, -2, and -3), adopting isostructural discrete octahedral cage geometries, were successfully synthesized under solvothermal conditions. These structures are all built up from the same pentavanadate {V5O9Cl} cluster connected by linear bidentate ligands (H2L1 = H2BDC, H2L2 = H2BDC-NH2, H2L3 = H2BDC-Br), respectively.
authors: Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, People's Republic of China. wangxl824@nenu.edu.cn zmsu@nenu.edu.cn.
authors: Yu-Teng
authors: YT
authors: Zhang
authors: Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, People's Republic of China. wangxl824@nenu.edu.cn zmsu@nenu.edu.cn.
authors: Xin-Long
authors: XL
authors: Wang
authors: Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, People's Republic of China. wangxl824@nenu.edu.cn zmsu@nenu.edu.cn.
authors: En-Long
authors: EL
authors: Zhou
authors: Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, People's Republic of China. wangxl824@nenu.edu.cn zmsu@nenu.edu.cn.
authors: Xue-Song
authors: XS
authors: Wu
authors: Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, People's Republic of China. wangxl824@nenu.edu.cn zmsu@nenu.edu.cn.
authors: Bai-Qiao
authors: BQ
authors: Song
authors: Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, People's Republic of China. wangxl824@nenu.edu.cn zmsu@nenu.edu.cn.
authors: Kui-Zhan
authors: KZ
authors: Shao
authors: Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, People's Republic of China. wangxl824@nenu.edu.cn zmsu@nenu.edu.cn.
authors: Zhong-Min
authors: ZM
authors: Su