title: Computational Methods for MOF/Polymer Membranes.
abstract: Metal-organic framework (MOF)/polymer mixed matrix membranes (MMMs) have received significant interest in the last decade. MOFs are incorporated into polymers to make MMMs that exhibit improved gas permeability and selectivity compared with pure polymer membranes. The fundamental challenge in this area is to choose the appropriate MOF/polymer combinations for a gas separation of interest. Even if a single polymer is considered, there are thousands of MOFs that could potentially be used as fillers in MMMs. As a result, there has been a large demand for computational studies that can accurately predict the gas separation performance of MOF/polymer MMMs prior to experiments. We have developed computational approaches to assess gas separation potentials of MOF/polymer MMMs and used them to identify the most promising MOF/polymer pairs. In this Personal Account, we aim to provide a critical overview of current computational methods for modeling MOF/polymer MMMs. We give our perspective on the background, successes, and failures that led to developments in this area and discuss the opportunities and challenges of using computational methods for MOF/polymer MMMs.
authors: Chemical and Biological Engineering Department, Koc University Rumelifeneri Yolu, Sariyer, 34450, Istanbul, Turkey.
authors: Ilknur
authors: I
authors: Erucar
authors: Chemical and Biological Engineering Department, Koc University Rumelifeneri Yolu, Sariyer, 34450, Istanbul, Turkey.
authors: Seda
authors: S
authors: Keskin
keywords: computational chemistry; gas separation; membranes; metal-organic frameworks; polymers