title: Synthesis and characterization of [(HPO3)6Mo21O60(H2O)4](8-): a new redox active heteropoly blue cluster with layered shape containing a phosphite template that self-assembles under controlled microwave irradiation.
abstract: The microwave-driven synthesis of a heteropoly blue cluster yields a redox active cluster, [(HPO3)6Mo21O60(H2O)4](8-), templated by six phosphite anions whereby two phosphites template a tri-lucunary {Mo15} Dawson structure, and one templates a {Mo6} ring with two of the three remaining phosphites acting as bridging ligands connecting the ring to the {Mo15}.
authors: School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China. yanjun@csu.edu.cn.
authors: Xiang-xiao
authors: XX
authors: Jin
authors: School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China. yanjun@csu.edu.cn.
authors: Wei-dong
authors: WD
authors: Yu
authors: School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China. yanjun@csu.edu.cn.
authors: Yan-Mei
authors: YM
authors: Nie
authors: School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China. yanjun@csu.edu.cn.
authors: Meng-Shu
authors: MS
authors: Liu
authors: School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China. yanjun@csu.edu.cn.
authors: Jun
authors: J
authors: Yan