title: Crystal structure of di-μ2-chlorido-bis-[(1-aza-4-azoniabi-cyclo-[2.2.2]octane-κN (1))di-chlorido-dicadmium].
abstract: In the structure of the binuclear title compound, [Cd2(C6H13N2)2Cl6], two Cd(II) atoms are bridged by two Cl(-) ligands, defining a centrosymmetric Cd2Cl2 motif. Each metal cation is additionally coordinated by two Cl(-) ligands and the N atom of a protonated 1,4-di-aza-bicyclo-[2.2.2]octane (H-DABCO)(+) ligand, leading to an overall trigonal-bipyramidal coordination environment with one of the bridging Cl(-) ligands and the N atom at the apical sites. In the crystal, the neutral dimers are linked via N-H⋯Cl hydrogen bonds, forming a two-dimensional network expanding parallel to (100).
authors: School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, People's Republic of China.
authors: Jing-Jing
authors: JJ
authors: Yan
authors: School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, People's Republic of China.
authors: Qi-Jian
authors: QJ
authors: Pan
authors: School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, People's Republic of China.
authors: Li-Zhuang
authors: LZ
authors: Chen
keywords: DABCO; cadmium; crystal structure; hydrogen bonding