title: Na-α'-GeGaON Solid Solution Analogous to α'-SiAlON: Synthesis, Crystal Structure, and Potentiality as a Photocatalyst.
abstract: We demonstrated, for the first time, formation of the Na-α'-GeGaON (NamGe12-(m+n)Gam+nOnN16-n) solid solution, an analogue of the well-established α'-SiAlON system. We successfully synthesized single-phase powder samples by reduction-nitridation of Na2CO3-GeO2-Ga2O3, in the solubility range of m ≈ 0.8-1.7 with n ≈ 0.2-0.3. The Rietveld refinement of powder X-ray diffraction data for Na-α'-GeGaON was conducted on the basis of the space group P31c of α'-SiAlON, and the refinement converged with RB = 1.78% and RF = 1.02% for the composition of Na1.26(1)Ge10.50Ga1.50O0.24(1)N15.76(1), indicating reliably the isomorphism between the SiAlON and GeGaON systems. The results of (23)Na solid-state nuclear magnetic resonance (NMR) spectroscopy clearly showed a single peak at the chemical shift of ∼ 16 ppm, further proving the accommodation of Na in the α'-GeGaON matrix with the expected coordination environment. The synthesized Na-α'-GeGaON exhibited stable photocatalytic activity for the evolution of H2 from water under ultraviolet irradiation, which was comparable to that attained by β-Ge3N4.
authors: SiAlON Unit, Environment and Energy Materials Division, National Institute for Materials Science , 1-1 Namiki, Tsukuba 305-0044, Japan.
authors: Takayuki
authors: T
authors: Suehiro
authors: High Field NMR Group, Nano Characterization Unit, National Institute for Materials Science , 3-13 Sakura, Tsukuba 305-0003, Japan.
authors: Masataka
authors: M
authors: Tansho
authors: High Field NMR Group, Nano Characterization Unit, National Institute for Materials Science , 3-13 Sakura, Tsukuba 305-0003, Japan.
authors: Tadashi
authors: T
authors: Shimizu