title: Ruthenium-Catalyzed Intermolecular Direct Silylation of Unreactive C(sp(3))-H Bonds.
abstract: A Ru-catalyzed intermolecular silylation of unreactive, aliphatic C(sp(3))-H bonds has been described for the first time. This protocol features low catalyst loading, a relatively broad substrate spectrum, good functional group tolerance, and no sensitivity to air, which provides a convenient and practical pathway for the construction of C-Si bonds.
authors: Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University , 29 Wangjiang Road, Chengdu 610064, P. R. China.
authors: Wei
authors: W
authors: Li
authors: Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University , 29 Wangjiang Road, Chengdu 610064, P. R. China.
authors: Xiaolei
authors: X
authors: Huang
authors: Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University , 29 Wangjiang Road, Chengdu 610064, P. R. China.
authors: Jingsong
authors: J
authors: You