title: A Perylene-Based Microporous Coordination Polymer Interacts Selectively with Electron-Poor Aromatics.
abstract: The design, synthesis, and properties of the new microporous coordination polymer UMCM-310 are described. The unique electronic character of the perylene-based linker enables selective interaction with electron-poor aromatics leading to efficient separation of nitroaromatics. UMCM-310 possesses high surface area and large pore size and thus permits the separation of large organic molecules based on adsorption rather than size exclusion.
authors: Department of Chemistry, University of Michigan, 930 N. University Ave, Ann Arbor, MI, 48109, USA.
authors: Ly D
authors: LD
authors: Tran
authors: Department of Chemistry, University of Michigan, 930 N. University Ave, Ann Arbor, MI, 48109, USA.
authors: Jialiu
authors: J
authors: Ma
authors: Department of Chemistry, University of Michigan, 930 N. University Ave, Ann Arbor, MI, 48109, USA.
authors: Antek G
authors: AG
authors: Wong-Foy
authors: Department of Chemistry, University of Michigan, 930 N. University Ave, Ann Arbor, MI, 48109, USA. matzger@umich.edu.|Department of Macromolecular Science and Engineering, University of Michigan, Ann Arbor, MI, 48109, USA. matzger@umich.edu.
authors: Adam J
authors: AJ
authors: Matzger
keywords: adsorption; host-guest systems; liquid chromatography; metal-organic frameworks; microporous materials