title: Excitation-emission matrix scan analysis of raw fish oil from coastal New Jersey menhaden collected before and after Hurricane Sandy.
abstract: The impact of Hurricane Sandy (October 29, 2012) on PAH exposure was investigated in adult Atlantic menhaden (Brevoortia tyrannus) collected along the NJ coast. Collections were made in August, September and/or October of 2011, 2012 and 2013. PAHs were monitored in raw fish oil using excitation-emission matrix (EEM) spectroscopy. Results showed that raw fish oils had relatively high levels of high molecular weight, PAH-like compounds (173 to 24,421ng/mL) compared to values reported for bile in other species. EEM profiles resembled that of crude oil and excluded matrix interference by some common biological molecules that also fluoresce. Concentrations and EEM profiles varied by collection; however, collection ship, month, year and fish size did not account for the data. Replicates showed that fish from the same catch had similar PAH exposure. Overall, Hurricane Sandy did not alter body burdens of PAHs in raw fish oil of menhaden.
authors: Department of Biological Science, Seton Hall University, 400 South Orange Avenue, South Orange, NJ 07079, United States. Electronic address: carolyn.bentivegna@shu.edu.
authors: Carolyn S
authors: CS
authors: Bentivegna
authors: Department of Biological Science, Seton Hall University, 400 South Orange Avenue, South Orange, NJ 07079, United States. Electronic address: chelsea.defelice@student.shu.edu.
authors: Chelsea R
authors: CR
authors: DeFelice
authors: Department of Chemistry and Biochemistry, Seton Hall University, 400 South Orange Avenue, South Orange, NJ 07079, United States. Electronic address: wyatt.murphy@shu.edu.
authors: Wyatt R
authors: WR
authors: Murphy
mesh_terms: D000818:Animals; D001646:Bile / Q000737:chemistry; D001822:Body Burden; D055867:Cyclonic Storms; D004784:Environmental Monitoring / Q000379:methods*; D005395:Fish Oils / Q000737:chemistry*; D005399:Fishes / Q000378:metabolism*; D009515:New Jersey; D059392:Petroleum Pollution / Q000032:analysis; D011084:Polycyclic Aromatic Hydrocarbons / Q000032:analysis; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000378:metabolism
chemical_list: D005395:Fish Oils; D011084:Polycyclic Aromatic Hydrocarbons; D014874:Water Pollutants, Chemical
keywords: Excitation–emission matrix spectroscopy; Hurricane Sandy; Menhaden; PAH; Raw fish oil