title: Iron/ABNO-Catalyzed Aerobic Oxidation of Alcohols to Aldehydes and Ketones under Ambient Atmosphere.
abstract: We report a new Fe(NO3)3·9H2O/9-azabicyclo[3.3.1]nonan-N-oxyl catalyst system that enables efficient aerobic oxidation of a broad range of primary and secondary alcohols to the corresponding aldehydes and ketones at room temperature with ambient air as the oxidant. The catalyst system exhibits excellent activity and selectivity for primary aliphatic alcohol oxidation. This procedure can also be scaled up. Kinetic analysis demonstrates that C-H bond cleavage is the rate-determining step and that cationic species are involved in the reaction.
authors: Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian National Laboratory for Clean Energy , Dalian 116023, China.
authors: Lianyue
authors: L
authors: Wang
authors: Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian National Laboratory for Clean Energy , Dalian 116023, China.|Graduate School of the Chinese Academy of Sciences , Beijing 100049, China.
authors: SenSen
authors: S
authors: Shang
authors: Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian National Laboratory for Clean Energy , Dalian 116023, China.
authors: Guosong
authors: G
authors: Li
authors: Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian National Laboratory for Clean Energy , Dalian 116023, China.|Graduate School of the Chinese Academy of Sciences , Beijing 100049, China.
authors: Lanhui
authors: L
authors: Ren
authors: Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian National Laboratory for Clean Energy , Dalian 116023, China.
authors: Ying
authors: Y
authors: Lv
authors: Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian National Laboratory for Clean Energy , Dalian 116023, China.
authors: Shuang
authors: S
authors: Gao