title: Crystal structure of tris-(trans-1,2-di-amino-cyclo-hexane-κ(2) N,N')cobalt(III) trichloride monohydrate.
abstract: The synthesis of the title hydrated complex salt, [Co(C6H14N2)3]Cl3·H2O, from racemic trans-1,2-di-amino-cyclo-hexane and [CoCl(NH3)5]Cl2 and its structural characterization are presented in this paper. The product was synthesized in the inter-est of understanding the hydrogen-bonding patterns of coordination complexes. Previous characterizations of the product in the I-42d space group have not yielded coordinates; thus, this paper provides the first coordinates for this complex in this space group. The octahedrally coordinated cation adopts twofold rotation symmetry, with outer-sphere chloride counter-ions and solvent water mol-ecules forming a hydrogen-bonded network with amine H atoms.
authors: Department of Chemistry & Biochemistry, University of Notre Dame, Notre Dame, IN 46556-5670, USA.
authors: Megan K
authors: MK
authors: Gallagher
authors: Department of Chemistry & Biochemistry, University of Notre Dame, Notre Dame, IN 46556-5670, USA.
authors: Allen G
authors: AG
authors: Oliver
authors: Department of Chemistry & Biochemistry, University of Notre Dame, Notre Dame, IN 46556-5670, USA.
authors: A Graham
authors: AG
authors: Lappin
keywords: 1,2-di­amino­cyclo­hexa­ne; cobalt(III); coordination complex; crystal structure; hydrogen-bonding patterns