title: N-Iodosuccinimide-Promoted Cascade Trifunctionalization of Alkynoates: Access to 1,1-Diiodoalkenes.
abstract: An efficient cascade trifunctioalization reaction of alkynoates with N-iodosuccinimide has been developed which proceeds through iodination, aryl migration, decarboxylation, and second iodination. This reaction represents an example of 1,1-difunctionalization of the acetylene bond and also provides a new strategy for the preparation of 1,1-diiodoalkenes.
authors: School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Nanjing University , Nanjing 210093, China.
authors: Shengyang
authors: S
authors: Ni
authors: School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Nanjing University , Nanjing 210093, China.
authors: Wanxing
authors: W
authors: Sha
authors: School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Nanjing University , Nanjing 210093, China.
authors: Lijun
authors: L
authors: Zhang
authors: School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Nanjing University , Nanjing 210093, China.
authors: Chen
authors: C
authors: Xie
authors: School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Nanjing University , Nanjing 210093, China.|MaAnShan High-Tech Research Institute of Nanjing University , MaAnShan 238200, China.
authors: Haibo
authors: H
authors: Mei
authors: School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Nanjing University , Nanjing 210093, China.|MaAnShan High-Tech Research Institute of Nanjing University , MaAnShan 238200, China.
authors: Jianlin
authors: J
authors: Han
authors: School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Nanjing University , Nanjing 210093, China.|MaAnShan High-Tech Research Institute of Nanjing University , MaAnShan 238200, China.
authors: Yi
authors: Y
authors: Pan