title: Copper-mediated aerobic (phenylsulfonyl)difluoromethylation of arylboronic acids with difluoromethyl phenyl sulfone.
abstract: A new method for the generation of the "PhSO2CF2Cu" species from readily available difluoromethyl phenyl sulfone (PhSO2CF2H) has been developed. The "PhSO2CF2Cu" reagent can be applied in (phenylsulfonyl)difluoromethylation of arylboronic acids, which affords a convenient approach to introducing the PhSO2CF2 group into aromatics.
authors: Key Laboratory of Advanced Materials, Institute of Fine Chemicals, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China. wanglimin@ecust.edu.cn and Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China. jinbohu@sioc.ac.cn.
authors: Xinjin
authors: X
authors: Li
authors: Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China. jinbohu@sioc.ac.cn.
authors: Jingwei
authors: J
authors: Zhao
authors: Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China. jinbohu@sioc.ac.cn.
authors: Mingyou
authors: M
authors: Hu
authors: Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China. jinbohu@sioc.ac.cn.
authors: Dingben
authors: D
authors: Chen
authors: Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China. jinbohu@sioc.ac.cn.
authors: Chuanfa
authors: C
authors: Ni
authors: Key Laboratory of Advanced Materials, Institute of Fine Chemicals, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China. wanglimin@ecust.edu.cn.
authors: Limin
authors: L
authors: Wang
authors: Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China. jinbohu@sioc.ac.cn.
authors: Jinbo
authors: J
authors: Hu
mesh_terms: D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D006845:Hydrocarbons, Fluorinated / Q000737:chemistry*; D008745:Methylation; D015394:Molecular Structure; D013450:Sulfones / Q000737:chemistry*
chemical_list: D001897:Boronic Acids; D006845:Hydrocarbons, Fluorinated; D013450:Sulfones; C000609890:difluoromethyl phenyl sulfone; D003300:Copper