title: Crystal structure of nitridobis(tri-methyl-silanolato)[1,1,1-trimethyl-N-(tri-methyl-sil-yl)silanaminato]molybdenum(VI).
abstract: In the title compound, [Mo(C6H18NSi2)(C3H9OSi)2N], the Mo(VI) cation is located on a mirror plane and is coordinated by a nitride anion, a 1,1,1-trimethyl-N-(tri-methyl-sil-yl)silanaminate anion and two tri-methyl-silanolate anions in a distorted tetra-hedral geometry; the N atom and two Si atoms of the 1,1,1-trimethyl-N-(tri-methyl-sil-yl)silanaminato anionic ligand are also located on the mirror plane. The Mo N bond length of 1.633 (6) Å is much shorter than the Mo-N single-bond length of 1.934 (7) Å. No hydrogen bonding is observed in the crystal structure.
authors: College of Chemistry, Beijing Normal University, Beijing 100875, People's Republic of China.
authors: Caiwei
authors: C
authors: Geng
authors: Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, People's Republic of China.
authors: Xiang
authors: X
authors: Hao
authors: College of Chemistry, Beijing Normal University, Beijing 100875, People's Republic of China.
authors: Peng
authors: P
authors: Jiao
keywords: crystal structure; hexa­methyl­disilazide; molybdenum complex; nitride; tri­methyl­silyl oxide