title: Crystal structure of aqua-bis-(hepta-fluoro-butano-ato-κO)(1,10'-phenanthroline-κ(2) N,N')copper(II).
abstract: The title compound, [Cu(C4F7O2)2(C12H8N2)(H2O)], is mononuclear and contains a penta-coordinated Cu(II) ion. The geometry of Cu(II) ion can be described as distorted square-pyramidal with two O atoms of two butano-ate anions and two N atoms of the o-phenanthroline ligand occupying the basal plane, and a water O atom located at the axial position. In the crystal, C-H⋯(O,F) and O-H⋯(O,F) hydrogen bonds and π-π inter-actions [centroid-to-centroid distance 3.533 (2) Å] link the mol-ecules into a three-dimensional supra-molecular structure.
authors: Anadolu University, Faculty of Sciences, Department of Chemistry, 26470 Eskişehir, Turkey.
authors: Ibrahim
authors: I
authors: Kani
keywords: copper(II) complex; crystal structure; hepta­fluoro­butanoic acid; hydrogen bonding; o-phenanthroline