title: One-Pot Synthesis of CoSex -rGO Composite Powders by Spray Pyrolysis and Their Application as Anode Material for Sodium-Ion Batteries.
abstract: A simple one-pot synthesis of metal selenide/reduced graphene oxide (rGO) composite powders for application as anode materials in sodium-ion batteries was developed. The detailed mechanism of formation of the CoSe(x)-rGO composite powders that were selected as the first target material in the spray pyrolysis process was studied. The crumple-structured CoSe(x)-rGO composite powders prepared by spray pyrolysis at 800 °C had a crystal structure consisting mainly of Co0.85 Se with a minor phase of CoSe2. The bare CoSe(x) powders prepared for comparison had a spherical shape and hollow structure. The discharge capacities of the CoSe(x)-rGO composite and bare CoSe(x) powders in the 50th cycle at a constant current density of 0.3 A g(-1) were 420 and 215 mA h g(-1), respectively, and their capacity retentions measured from the second cycle were 80 and 46%, respectively. The high structural stability of the CoSe(x)-rGO composite powders for repeated sodium-ion charge and discharge processes resulted in superior sodium-ion storage properties compared to those of the bare CoSe(x) powders.
authors: Department of Materials Science and Engineering, Korea University, Anam-dong, Seongbuk-gu, Seoul, 136-713, Korea.
authors: Gi Dae
authors: GD
authors: Park
authors: Department of Materials Science and Engineering, Korea University, Anam-dong, Seongbuk-gu, Seoul, 136-713, Korea. yckang@korea.ac.kr.
authors: Yun Chan
authors: YC
authors: Kang
keywords: electrochemistry; graphene; metal selenides; nanostructures; sodium-ion batteries