title: Redox mediated synthesis of hierarchical Bi2O3/MnO2 nanoflowers: a non-enzymatic hydrogen peroxide electrochemical sensor.
abstract: Uniform hierarchical Bi2O3/MnO2 nanoflowers (BM NFs) are fabricated via a reaction strategy by combining redox reaction and hydrothermal treatment. This wet chemical method reports for the first time a one pot synthesis of Bi2O3/MnO2 nanoflowers via a thermodynamically allowed galvanic reaction between Bi(0) and KMnO4 in aqueous solution under modified hydrothermal (MHT) conditions. The Bi2O3/MnO2 NF composites are then applied as a catalyst for electrochemical hydrogen peroxide detection. Exceedingly high H2O2 detection sensitivity (0.914 μA μM(-1) cm(-2)) lies in a wide linear range of 0.2-290 μM and the detection limit goes down to 0.05 μM (S/N = 3) for non-enzymatic detection of H2O2 in solution. This prototype sensor demonstrates an admirable analytical performance considering its long-term stability, good reproducibility and acceptable selectivity against common interfering species. The employment of the stable nanocomposite for real sample analysis makes it a deliverable for H2O2 sensing.
authors: Department of Chemistry, Indian Institute of Technology, Kharagpur - 721302, India. tpal@chem.iitkgp.ernet.in.
authors: Chaiti
authors: C
authors: Ray
authors: Soumen
authors: S
authors: Dutta
authors: Anindita
authors: A
authors: Roy
authors: Ramkrishna
authors: R
authors: Sahoo
authors: Tarasankar
authors: T
authors: Pal