title: Temperature-Dependent Double Isocyanide Insertion Reaction To Construct a Polycyclic Skeleton.
abstract: A novel strategy to furnish selective double insertion of isocyanides with the aid of potassium tetrachloroaurate(III) has been disclosed. This strategy provides quick access to approach a complex polycyclic skeleton in an efficient manner. Unexpected oxygen migration was also observed when the reaction was conducted at a lower temperature.
authors: Department of Chemistry, Innovative Drug Research Center, Shanghai University , 99 Shangda Road, Shanghai 200444, China.
authors: Yaming
authors: Y
authors: Tian
authors: Department of Chemistry, Innovative Drug Research Center, Shanghai University , 99 Shangda Road, Shanghai 200444, China.
authors: Lumin
authors: L
authors: Tian
authors: Department of Chemistry, Innovative Drug Research Center, Shanghai University , 99 Shangda Road, Shanghai 200444, China.
authors: Chunju
authors: C
authors: Li
authors: Department of Chemistry, Innovative Drug Research Center, Shanghai University , 99 Shangda Road, Shanghai 200444, China.|State Key Laboratory of Applied Organic Chemistry, Lanzhou University , Lanzhou 730000, China.
authors: Xueshun
authors: X
authors: Jia
authors: Department of Chemistry, Innovative Drug Research Center, Shanghai University , 99 Shangda Road, Shanghai 200444, China.
authors: Jian
authors: J
authors: Li
mesh_terms: D002384:Catalysis; D003486:Cyanides / Q000737:chemistry*; D003500:Cyclization; D015394:Molecular Structure; D011084:Polycyclic Aromatic Hydrocarbons / Q000138:chemical synthesis* / Q000737:chemistry; D013696:Temperature
chemical_list: D003486:Cyanides; D011084:Polycyclic Aromatic Hydrocarbons