title: Visible light-induced intramolecular dearomative cyclization of α-bromo-N-benzyl-alkylamides: efficient construction of 2-azaspiro[4.5]decanes.
abstract: An efficient intramolecular dearomative cyclization via visible light-induced photoredox catalysis allows for a highly regioselective dearomative cyclization of α-bromo-N-benzyl-alkylamides to construct 2-azaspiro[4.5]decanes in the presence of an iridium catalyst.
authors: School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China. zhaoguo@sjtu.edu.cn.
authors: Bei
authors: B
authors: Hu
authors: College of Chemistry and Molecular Engineering and College of Environment and Safety Engineering, Qingdao University of Science and Technology, 53 Zhengzhou Road, Qingdao 266042, China.
authors: Yuyuan
authors: Y
authors: Li
authors: School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China. zhaoguo@sjtu.edu.cn.
authors: Wuheng
authors: W
authors: Dong
authors: School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China. zhaoguo@sjtu.edu.cn.
authors: Kai
authors: K
authors: Ren
authors: School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China. zhaoguo@sjtu.edu.cn.
authors: Xiaomin
authors: X
authors: Xie
authors: College of Chemistry and Molecular Engineering and College of Environment and Safety Engineering, Qingdao University of Science and Technology, 53 Zhengzhou Road, Qingdao 266042, China.
authors: Jun
authors: J
authors: Wan
authors: School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China. zhaoguo@sjtu.edu.cn and Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China.
authors: Zhaoguo
authors: Z
authors: Zhang
mesh_terms: D000577:Amides / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D006842:Hydrocarbons, Brominated / Q000737:chemistry*; D015394:Molecular Structure; D013141:Spiro Compounds / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000577:Amides; D006842:Hydrocarbons, Brominated; D013141:Spiro Compounds