title: Hypervalent Iodine as a Terminal Oxidant in Wacker-Type Oxidation of Terminal Olefins to Methyl Ketones.
abstract: A mimic of the Wacker process for C═O bond formation in terminal olefins can be initiated by a combination of the Pd(II) and hypervalent iodine reagent, Dess-Martin periodinane to generate methyl ketones. This operationally simple and scalable method offers Markovnikov selectivity, has good functional group compatibility, and is mild and high yielding.
authors: Department of Chemistry, Indian Institute of Technology Bombay , Powai, Mumbai 400076, Maharashtra, India.
authors: Dipali A
authors: DA
authors: Chaudhari
authors: Department of Chemistry, Indian Institute of Technology Bombay , Powai, Mumbai 400076, Maharashtra, India.
authors: Rodney A
authors: RA
authors: Fernandes