title: The transformation of polyoxometalates in the formation of intercluster compound [Ag41(α-SiW(10)O37)((t)BuC≡C)27(CH3CN)3][β-SiW(12)O40].
abstract: We report a unique intercluster compound comprising a Ag41 cage encapsulating a divacant [α-SiW(10)O37](10-) anion and a complete [β-SiW(12)O40](4-) anion as a counteranion. Two electro-redox centers associated with the inner and outer POM anions show interesting electrochemical behaviours, because the stable Ag41 cage acts as an electron transfer mediator.
authors: State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, 361005, P. R. China. kshi@xmu.edu.cn linyum@xmu.edu.cn.
authors: Kuan-Guan
authors: KG
authors: Liu
authors: State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, 361005, P. R. China. kshi@xmu.edu.cn linyum@xmu.edu.cn.
authors: Xi-Yan
authors: XY
authors: Liu
authors: State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, 361005, P. R. China. kshi@xmu.edu.cn linyum@xmu.edu.cn.
authors: Zong-Jie
authors: ZJ
authors: Guan
authors: State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, 361005, P. R. China. kshi@xmu.edu.cn linyum@xmu.edu.cn.
authors: Kang
authors: K
authors: Shi
authors: State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, 361005, P. R. China. kshi@xmu.edu.cn linyum@xmu.edu.cn.
authors: Yu-Mei
authors: YM
authors: Lin
authors: State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, 361005, P. R. China. kshi@xmu.edu.cn linyum@xmu.edu.cn.
authors: Quan-Ming
authors: QM
authors: Wang