title: Fluorescent Aromatic Tag-Functionalized MOFs for Highly Selective Sensing of Metal Ions and Small Organic Molecules.
abstract: By varying the fluorescent tags of resorcin[4]arene-based tetracarboxylic acids from phenyl to naphthyl, two highly luminescent metal-organic frameworks (MOFs), namely, [Zn2(TPC4A)(DMF)(H2O)4]·3H2O (1) and [(CH3)2NH2]2[Zn(TNC4A)]·4H2O (2), were successfully achieved (TPC4A = 2,8,14,20-tetra-phenyl-6,12,18,24-tetra-methoxy-4,10,16,22-tetra-carboxy-methoxy-resorcin[4]arene and TNC4A = 2,8,14,20-tetra-1-naphthal-6,12,18,24-tetra- methoxy-4,10,16,22-tetra-carboxy-methoxy-resorcin[4]arene). Compound 1 features a unique 2D network, while 2 exhibits a fascinating 3D framework. The highly selective detection of small organic molecules as well as Fe(2+) and Fe(3+) was performed for 1 and 2 as fluorescent sensors. Remarkably, luminescent 1 and 2 were used as sensory materials for the sensing of various amine vapors with high selectivity and rapid response. Most strikingly, clear fluorescence "on-off" switch-functions toward small organic molecules as well as amine vapors were also explored for luminescent 1 and 2.
authors.affiliation: Key Lab of Polyoxometalate Science, Department of Chemistry, Northeast Normal University , Changchun 130024, People's Republic of China.
authors.forename: Si-Si
authors.initials: SS
authors.lastname: Zhao
authors.affiliation: Key Lab of Polyoxometalate Science, Department of Chemistry, Northeast Normal University , Changchun 130024, People's Republic of China.
authors.forename: Jin
authors.initials: J
authors.lastname: Yang
authors.affiliation: Key Lab of Polyoxometalate Science, Department of Chemistry, Northeast Normal University , Changchun 130024, People's Republic of China.
authors.forename: Ying-Ying
authors.initials: YY
authors.lastname: Liu
authors.affiliation: Key Lab of Polyoxometalate Science, Department of Chemistry, Northeast Normal University , Changchun 130024, People's Republic of China.
authors.forename: Jian-Fang
authors.initials: JF
authors.lastname: Ma