title: Fabrication of multifunctional cellulose nanocrystals/poly(lactic acid) nanocomposites with silver nanoparticles by spraying method.
abstract: The poly (lactic acid) (PLA)/functionalized cellulose nanocrystals formates (CNFs) were prepared by solution casting and then the binary films were sprayed with silver ammonia aqueous solution to fabricate PLA/CNF/Ag ternary nanocomposites. It was found that both deposited silver (Ag) nanoparticles and CNFs showed efficient reinforcing effect on the thermal, mechanical, barrier properties and antibacterial activity of PLA matrix. Especially, the maximum decomposition temperature (Tmax) and Young's modulus of PLA/CNF/Ag(6) nanocomposite film increased by 15.5°C and 48.7%, respectively. Meanwhile an obvious reduction in the water vapor permeability was detected. Furthermore, the migration levels of the ternary nanocomposite films were well below the permitted limits in both non-polar and polar food simulants (60mgkg(-1)), and they showed a significant antibacterial activity influenced by the Ag contents. This study reveals that the novel nanocomposite films will offer a good perspective for food packaging applications.
authors.affiliation: The Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Ministry of Education, College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018, China; State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China. Electronic address: phdyu@zstu.edu.cn.
authors.forename: Hou-Yong
authors.initials: HY
authors.lastname: Yu
authors.affiliation: The Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Ministry of Education, College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018, China.
authors.forename: Xing-Yuan
authors.initials: XY
authors.lastname: Yang
authors.affiliation: The Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Ministry of Education, College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018, China.
authors.forename: Fang-Fang
authors.initials: FF
authors.lastname: Lu
authors.affiliation: The Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Ministry of Education, College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018, China.
authors.forename: Guo-Yin
authors.initials: GY
authors.lastname: Chen
authors.affiliation: The Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Ministry of Education, College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018, China; National Engineering Lab for Textile Fiber Materials & Processing Technology, Zhejiang Sci-Tech University, Hangzhou 310018, China. Electronic address: yaoj@zstu.edu.cn.
authors.forename: Ju-Ming
authors.initials: JM
authors.lastname: Yao
mesh_terms: D000900:Anti-Bacterial Agents / Q000737:chemistry* / Q000494:pharmacology; D002482:Cellulose / Q000737:chemistry* / Q000494:pharmacology; D004926:Escherichia coli / Q000187:drug effects; D018857:Food Packaging; D006860:Hydrogen Bonding; D055595:Mechanical Phenomena; D053768:Metal Nanoparticles / Q000737:chemistry*; D053761:Nanocomposites / Q000737:chemistry*; D036103:Nanotechnology / Q000379:methods*; D055620:Optical Phenomena; D011091:Polyesters / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D013211:Staphylococcus aureus / Q000187:drug effects; D013227:Steam; D013696:Temperature
chemical_list: D000900:Anti-Bacterial Agents; D011091:Polyesters; D013227:Steam; D012834:Silver; C033616:poly(lactide); D002482:Cellulose
keywords: Cellulose nanocrystals; Nanocomposite; Poly(lactic acid); Silver nanoparticles