title: Formation of a highly-ordered rigid multichromophoric 3D supramolecular network by combining ionic and coordination-driven self-assembly.
abstract: We present here the self-assembly of a green-emitting metallosupramolecular rhomboid into a rigid, highly-ordered 3D multichromophoric network through the mediation of a tetra-anionic violet-blue molecular emitter. Control was obtained on the spatial topology, the electronic energy landscape and the fluorescence polarization of the interacting dipoles.
authors.affiliation: NCSR "Demokritos" Institute of Nanoscience and Nanotechnology, 153 10 Athens, Greece. g.pistolis@inn.demokritos.gr.
authors.forename: Antonia
authors.initials: A
authors.lastname: Kaloudi-Chantzea
authors.affiliation: NCSR "Demokritos" Institute of Nanoscience and Nanotechnology, 153 10 Athens, Greece. g.pistolis@inn.demokritos.gr.
authors.forename: Elisabeth
authors.initials: E
authors.lastname: Martinou
authors.affiliation: Department of Physics, University of Patras, 26500 Patras, Greece.
authors.forename: Kostas
authors.initials: K
authors.lastname: Seintis
authors.affiliation: NCSR "Demokritos" Institute of Nanoscience and Nanotechnology, 153 10 Athens, Greece. g.pistolis@inn.demokritos.gr.
authors.forename: Nikolaos
authors.initials: N
authors.lastname: Karakostas
authors.affiliation: Hellenic Pasteur Inst, Dept Neurobiol, 11521 Athens, Greece.
authors.forename: Petros
authors.initials: P
authors.lastname: Giastas
authors.affiliation: Inst. of Legal Medicine and Core Facility Metabolomics, Medical Univ. of Innsbruck, Müllerstraße 44, 6020 Innsbruck, Austria.
authors.forename: Florian
authors.initials: F
authors.lastname: Pitterl
authors.affiliation: Inst. of Legal Medicine and Core Facility Metabolomics, Medical Univ. of Innsbruck, Müllerstraße 44, 6020 Innsbruck, Austria.
authors.forename: Herbert
authors.initials: H
authors.lastname: Oberacher
authors.affiliation: Department of Physics, University of Patras, 26500 Patras, Greece.
authors.forename: Mihalis
authors.initials: M
authors.lastname: Fakis
authors.affiliation: NCSR "Demokritos" Institute of Nanoscience and Nanotechnology, 153 10 Athens, Greece. g.pistolis@inn.demokritos.gr.
authors.forename: George
authors.initials: G
authors.lastname: Pistolis
mesh_terms: D007477:Ions; D015394:Molecular Structure; D066244:Proton Magnetic Resonance Spectroscopy; D013050:Spectrometry, Fluorescence
chemical_list: D007477:Ions