title: Modifying glass fiber surface with grafting acrylamide by UV-grafting copolymerization for preparation of glass fiber reinforced PVDF composite membrane.
abstract: Experimental design and response surface methodology (RSM) were used to optimize the modification of conditions for glass surface grafting with acrylamide (AM) monomer for preparation of a glass fiber reinforced poly(vinylidene fluoride) (PVDF) composite membrane (GFRP-CM). The factors considered for experimental design were the UV (ultraviolet)-irradiation time, the concentrations of the initiator and solvent, and the kinds and concentrations of the silane coupling agent. The optimum operating conditions determined were UV-irradiation time of 25 min, an initiator concentration of 0-0.25 wt.%, solvent of N-Dimethylacetamide (DMAC), and silane coupling agent KH570 with a concentration of 7 wt.%. The obtained optimal parameters were located in the valid region and the experimental confirmation tests conducted showed good accordance between predicted and experimental values. Under these optimal conditions, the water absorption of the grafted modified glass fiber was improved from 13.6% to 23%; the tensile strength was enhanced and the peeling strength of the glass fiber reinforced PVDF composite membrane was improved by 23.7% and 32.6% with an AM concentration at 1 wt.% and 2 wt.%. The surface composition and microstructure of AM grafted glass fiber were studied via several techniques including Field Emission Scanning Electron Microscopy (FESEM), Fourier transform infrared spectroscopy-attenuated total reflectance (FTIR-ATR) and energy dispersive X-ray spectroscopy (EDX). The analysis of the EDX and FTIR-ATR results confirmed that the AM was grafted to the glass fiber successfully by detecting and proving the existence of nitrogen atoms in the GFRP-CM.
authors.affiliation: Group of Membrane Separation Technique, Department of Water Pollution Control Technology, Research Center for Eco-Environmental Sciences (RCEES), Chinese Academy of Sciences (CAS), Beijing 100085, China; State Key Joint Laboratory of Environmental Simulation and Pollution Control, Research Center for Eco-Environmental Sciences (RCEES), Chinese Academy of Sciences (CAS), Beijing 100085, China. Electronic address: luonan_87@163.com.
authors.forename: Nan
authors.initials: N
authors.lastname: Luo
authors.affiliation: Group of Membrane Separation Technique, Department of Water Pollution Control Technology, Research Center for Eco-Environmental Sciences (RCEES), Chinese Academy of Sciences (CAS), Beijing 100085, China; State Key Joint Laboratory of Environmental Simulation and Pollution Control, Research Center for Eco-Environmental Sciences (RCEES), Chinese Academy of Sciences (CAS), Beijing 100085, China.
authors.forename: Hui
authors.initials: H
authors.lastname: Zhong
authors.affiliation: Group of Membrane Separation Technique, Department of Water Pollution Control Technology, Research Center for Eco-Environmental Sciences (RCEES), Chinese Academy of Sciences (CAS), Beijing 100085, China; State Key Joint Laboratory of Environmental Simulation and Pollution Control, Research Center for Eco-Environmental Sciences (RCEES), Chinese Academy of Sciences (CAS), Beijing 100085, China.
authors.forename: Min
authors.initials: M
authors.lastname: Yang
authors.affiliation: Group of Membrane Separation Technique, Department of Water Pollution Control Technology, Research Center for Eco-Environmental Sciences (RCEES), Chinese Academy of Sciences (CAS), Beijing 100085, China; State Key Joint Laboratory of Environmental Simulation and Pollution Control, Research Center for Eco-Environmental Sciences (RCEES), Chinese Academy of Sciences (CAS), Beijing 100085, China.
authors.forename: Xing
authors.initials: X
authors.lastname: Yuan
authors.affiliation: Group of Membrane Separation Technique, Department of Water Pollution Control Technology, Research Center for Eco-Environmental Sciences (RCEES), Chinese Academy of Sciences (CAS), Beijing 100085, China; State Key Joint Laboratory of Environmental Simulation and Pollution Control, Research Center for Eco-Environmental Sciences (RCEES), Chinese Academy of Sciences (CAS), Beijing 100085, China. Electronic address: ybfan@rcees.ac.cn.
authors.forename: Yaobo
authors.initials: Y
authors.lastname: Fan
mesh_terms: D020106:Acrylamide / Q000737:chemistry*; D005898:Glass / Q000737:chemistry*; D055595:Mechanical Phenomena; D008567:Membranes, Artificial; D008956:Models, Chemical; D055668:Photochemical Processes; D011145:Polyvinyls / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry; D012997:Solvents / Q000737:chemistry; D013499:Surface Properties; D013997:Time Factors; D014466:Ultraviolet Rays; D005465:Fluorocarbon Polymers
chemical_list: D020106:Acrylamide; D008567:Membranes, Artificial; D011145:Polyvinyls; D012821:Silanes; D012997:Solvents; C009753:fiberglass; C024865:polyvinylidene fluoride; D005465:Fluorocarbon Polymers
keywords: Coupling agents; Glass fibers; Interfacial strength; Polymer-matrix composites; UV-grafting copolymerization