title: Pd-grafted open metal site copper-benzene-1,4-dicarboxylate metal organic frameworks (Cu-BDC MOF's) as promising interfacial catalysts for sustainable Suzuki coupling.
abstract: In this work, open metal site metal-organic framework of Cu-BDC was selected as a support for the multi-step grafting of palladium. The palladium ions was coordinated onto the Schiff base-decorated Cu-BDC pore cage, that this bifunctional Pd@Cu-BDC/Py-SI catalyst was successfully applied for Suzuki cross-coupling reaction. Recyclability test for the Pd@Cu-BDC/Py-SI catalyst showed a successful reusability for 7 runs.
authors.affiliation: Organic and Nano Group (ONG), Department of Chemistry, Faculty of Science, University of Maragheh, P.O. Box. 55181-83111, Maragheh, Iran. Electronic address: srostamnia@gmail.com.
authors.forename: Sadegh
authors.initials: S
authors.lastname: Rostamnia
authors.affiliation: Organic and Nano Group (ONG), Department of Chemistry, Faculty of Science, University of Maragheh, P.O. Box. 55181-83111, Maragheh, Iran.
authors.forename: Hassan
authors.initials: H
authors.lastname: Alamgholiloo
authors.affiliation: Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China. Electronic address: liuxiao71@tju.edu.cn.
authors.forename: Xiao
authors.initials: X
authors.lastname: Liu
keywords: Metal-organic framework; Open metal site MOF; Pd@Cu-BDC; Suzuki reaction