title: Detailed Investigation of Separation Performance of a MMM for Removal of Higher Hydrocarbons under Varying Operating Conditions.
abstract: Mixed-matrix membranes (MMMs) are promising candidates to improve the competitiveness of membrane technology against energy-intensive conventional technologies. In this work, MMM composed of poly(octylmethylsiloxane) (POMS) and activated carbon (AC) were investigated with respect to separation of higher hydrocarbons (C3+) from permanent gas streams. Membranes were prepared as thin film composite membranes on a technical scale and characterized via scanning electron microscopy (SEM) and permeation measurements with binary mixtures of n-C₄H10/CH₄ under varying operating conditions (feed and permeate pressure, temperature, feed gas composition) to study the influence on separation performance. SEM showed good contact and absence of defects. Lower permeances but higher selectivities were found for MMM compared to pure POMS membrane. Best results were obtained at high average fugacity and activity of n-C₄H10 with the highest selectivity estimated to be 36.4 at n-C₄H10 permeance of 12 mN³/(m²·h·bar). Results were complemented by permeation of a multi-component mixture resembling a natural gas application, demonstrating the superior performance of MMM.
authors.affiliation: Institute of Polymer Research, Helmholtz-Zentrum Geesthacht, Geesthacht 21502, Germany. heike.mushardt@tuhh.de.
authors.forename: Heike
authors.initials: H
authors.lastname: Mushardt
authors.affiliation: Institute of Polymer Research, Helmholtz-Zentrum Geesthacht, Geesthacht 21502, Germany. marcus.mueller86@gmx.de.
authors.forename: Marcus
authors.initials: M
authors.lastname: Müller
authors.affiliation: Institute of Polymer Research, Helmholtz-Zentrum Geesthacht, Geesthacht 21502, Germany. sergey.shishatskiy@hzg.de.
authors.forename: Sergey
authors.initials: S
authors.lastname: Shishatskiy
authors.affiliation: Institute of Polymer Research, Helmholtz-Zentrum Geesthacht, Geesthacht 21502, Germany. jan.wind@hzg.de.
authors.forename: Jan
authors.initials: J
authors.lastname: Wind
authors.affiliation: Institute of Polymer Research, Helmholtz-Zentrum Geesthacht, Geesthacht 21502, Germany. torsten.brinkmann@hzg.de.
authors.forename: Torsten
authors.initials: T
authors.lastname: Brinkmann
keywords: activated carbon; gas permeation; mixed matrix membrane; multi-component mixture; n-butane/methane separation; operating conditions