title: tert-Butanesulfinamides as Nitrogen Nucleophiles in Carbon-Nitrogen Bond Forming Reactions.
abstract: The use of tert-butanesulfinamides as nitrogen nucleophiles in carbon-nitrogen bond forming reactions is reviewed. This field has grown in the shadow of the general interest in N-tert-butanesulfinyl imines for asymmetric synthesis and occupies now an important place in its own right in the chemistry of the chiral amine reagent tert-butanesulfinamide. This article provides an overview of the area and emphasizes recent contributions wherein the tert-butanesulfinamides act as chiral auxiliaries or perform as nitrogen donors in metal-catalyzed amination reactions.
authors.affiliation: Sorbonne Universités, UPMC Univ Paris 06, UMR CNRS 8232, Institut Parisien de Chimie Moléculaire, F-75005, Paris, France.
authors.forename: Johana
authors.initials: J
authors.lastname: Ramirez Hernandez
authors.affiliation: Sorbonne Universités, UPMC Univ Paris 06, UMR CNRS 8232, Institut Parisien de Chimie Moléculaire, F-75005, Paris, France.
authors.forename: Fabrice
authors.initials: F
authors.lastname: Chemla
authors.affiliation: Sorbonne Universités, UPMC Univ Paris 06, UMR CNRS 8232, Institut Parisien de Chimie Moléculaire, F-75005, Paris, France.
authors.forename: Franck
authors.initials: F
authors.lastname: Ferreira
authors.affiliation: Sorbonne Universités, UPMC Univ Paris 06, UMR CNRS 8232, Institut Parisien de Chimie Moléculaire, F-75005, Paris, France.
authors.forename: Olivier
authors.initials: O
authors.lastname: Jackowski
authors.affiliation: Sorbonne Universités, UPMC Univ Paris 06, UMR CNRS 8232, Institut Parisien de Chimie Moléculaire, F-75005, Paris, France.
authors.forename: Julie
authors.initials: J
authors.lastname: Oble
authors.affiliation: Sorbonne Universités, UPMC Univ Paris 06, UMR CNRS 8232, Institut Parisien de Chimie Moléculaire, F-75005, Paris, France. alejandro.perez_luna@upmc.fr.
authors.forename: Alejandro
authors.initials: A
authors.lastname: Perez-Luna
authors.affiliation: Sorbonne Universités, UPMC Univ Paris 06, UMR CNRS 8232, Institut Parisien de Chimie Moléculaire, F-75005, Paris, France.
authors.forename: Giovanni
authors.initials: G
authors.lastname: Poli