title: Catalytic Enantioselective Assembly of Homoallylic Alcohols from Dienes, Aryldiazonium Salts, and Aldehydes.
abstract: A highly selective multicomponent carbonyl allylation reaction of 1,3-butadienes, aryldiazonium tetrafluoroborates, and aldehydes has been established under the combined catalysis of palladium acetate and chiral anion phase transfer to render the favorable assembly of chiral Z-configured homoallylic alcohols in high yields and with excellent levels of enantioselectivity.
authors.affiliation: Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China.
authors.forename: Zhong-Lin
authors.initials: ZL
authors.lastname: Tao
authors.affiliation: Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China.
authors.forename: Alafate
authors.initials: A
authors.lastname: Adili
authors.affiliation: Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China.
authors.forename: Hong-Cheng
authors.initials: HC
authors.lastname: Shen
authors.affiliation: Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China.
authors.forename: Zhi-Yong
authors.initials: ZY
authors.lastname: Han
authors.affiliation: Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China. gonglz@ustc.edu.cn.|Collaborative Innovation Center of Chemical Science and Engineering, Tianjin, China. gonglz@ustc.edu.cn.|High Magnetic Field Laboratory, Hefei Institutes of Physical Science, CAS, Hefei, 230031, China. gonglz@ustc.edu.cn.
authors.forename: Liu-Zhu
authors.initials: LZ
authors.lastname: Gong
keywords: allylic compounds; asymmetric catalysis; multicomponent reactions; palladium; phase-transfer catalysis