title: Capture CO2 from Ambient Air Using Nanoconfined Ion Hydration.
abstract: Water confined in nanoscopic pores is essential in determining the energetics of many physical and chemical systems. Herein, we report a recently discovered unconventional, reversible chemical reaction driven by water quantities in nanopores. The reduction of the number of water molecules present in the pore space promotes the hydrolysis of CO3(2-) to HCO3(-) and OH(-). This phenomenon led to a nano-structured CO2 sorbent that binds CO2 spontaneously in ambient air when the surrounding is dry, while releasing it when exposed to moisture. The underlying mechanism is elucidated theoretically by computational modeling and verified by experiments. The free energy of CO3 (2-) hydrolysis in nanopores reduces with a decrease of water availability. This promotes the formation of OH(-), which has a high affinity to CO2 . The effect is not limited to carbonate/bicarbonate, but is extendable to a series of ions. Humidity-driven sorption opens a new approach to gas separation technology.
authors.affiliation: Department of Earth and Environmental Engineering, Columbia University, 905E Mudd, 500 West 120th Street, New York, NY, 10027, USA.
authors.forename: Xiaoyang
authors.initials: X
authors.lastname: Shi
authors.affiliation: Department of Earth and Environmental Engineering, Columbia University, 905E Mudd, 500 West 120th Street, New York, NY, 10027, USA.
authors.forename: Hang
authors.initials: H
authors.lastname: Xiao
authors.affiliation: School of Sustainable Engineering & Built Environment, Arizona State University, Tempe, AZ, 85287-9309, USA.
authors.forename: Klaus S
authors.initials: KS
authors.lastname: Lackner
authors.affiliation: Department of Earth and Environmental Engineering, Columbia University, 905E Mudd, 500 West 120th Street, New York, NY, 10027, USA. xichen@columbia.edu.
authors.forename: Xi
authors.initials: X
authors.lastname: Chen
keywords: CO2 capture; air-water interfaces; free energy; ion hydration; molecular dynamics