title: Ynol Ethers: Synthesis and Reactivity.
abstract: Ynol ethers are highly valuable substrates offering a wide range of reactivity. These highly electron-rich heterosubstitued alkynes can be of great synthetic potential. In this mini-review, the different methods for the synthesis of ynol ethers are first presented, divided in three main approaches involving a β-elimination, a carbene rearrangement and a direct oxidation of an alkyne. Their reactivity is then summarized underlying their synthetic utility. This non-exhaustive review aims at presenting the intrinsic reactivity of these compounds, still underexploited in synthesis.
authors.affiliation: Université Grenoble Alpes, Département de Chimie Moléculaire (SERCO), UMR-5250 CNRS, IMCG FR-2607, 38041 Grenoble, France.
authors.forename: Charlie
authors.initials: C
authors.lastname: Verrier
authors.affiliation: Université Grenoble Alpes, Département de Chimie Moléculaire (SERCO), UMR-5250 CNRS, IMCG FR-2607, 38041 Grenoble, France.
authors.forename: Sébastien
authors.initials: S
authors.lastname: Carret
authors.affiliation: Université Grenoble Alpes, Département de Chimie Moléculaire (SERCO), UMR-5250 CNRS, IMCG FR-2607, 38041 Grenoble, France. jean-francois.poisson@univ-grenoble-alpes.fr.
authors.forename: Jean-François
authors.initials: JF
authors.lastname: Poisson