title: Constructing π-Electron-Conjugated Diarylbutadiyne-Based Polydiacetylene under Molecular Framework Controlled by Hydrogen Bond and Side-Chain Substituent Position.
abstract: Diarylbutadiyne derivatives are ideal monomers for providing the π-electron-conjugated system of polydiacetylenes (PDAs). The geometrical parameters for diacetylene topochemical polymerization are known. However, control of the molecules under these parameters is yet to be addressed. This work shows that by simply tailoring diarylbutadiyne with amide side-chain substituents, the arrangement of the substituents and the resulting hydrogen bond framework allows formation of π-electron-conjugated PDA.
authors.affiliation: The Petroleum and Petrochemical College, Chulalongkorn University, Bangkok, 10330, Thailand.
authors.forename: Pimsai
authors.initials: P
authors.lastname: Tanphibal
authors.affiliation: Department of Future Industry-oriented Basic Science and Materials, Toyota Technological Institute, Tempaku, Nagoya, 468-8511, Japan.
authors.forename: Kohji
authors.initials: K
authors.lastname: Tashiro
authors.affiliation: The Petroleum and Petrochemical College, Chulalongkorn University, Bangkok, 10330, Thailand.|Center for Petroleum and Petrochemical, and Advanced Materials, Chulalongkorn University, Bangkok, 10330, Thailand.
authors.forename: Suwabun
authors.initials: S
authors.lastname: Chirachanchai
mesh_terms: D000577:Amides / Q000737:chemistry; D053280:Diynes / Q000737:chemistry; D004583:Electrons; D006860:Hydrogen Bonding; D015394:Molecular Structure; D000078789:Polyacetylene Polymer; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry; D053279:Polyynes / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D000577:Amides; D053280:Diynes; D000078789:Polyacetylene Polymer; D011108:Polymers; D053279:Polyynes; C082361:polydiacetylene
keywords: conductive polymers; diarylbutadiynes; molecular frameworks; polydiacetylenes; topochemical polymerization