title: Solid state synthesis of starch-capped silver nanoparticles.
abstract: The present research addresses the establishment of a technique which is solely devoted to environmentally friendly one-pot green synthesis of dry highly stable powdered silver nanoparticles (AgNPs) using starch as both reductant and stabilizing agent in the presence of sodium hydroxide. It is believed that the sodium hydroxide can improve the reduction potential of starch. Thus when the alkali treated starch is submitted to addition of silver nitrate (AgNO3), the alkali treated starch induces the well-established dual role of starch; reduction of silver ions (Ag(+)) to AgNPs and capping the as-formed AgNPs to prevent them from further growth and agglomeration. Beside assessment of AgNPs formation, structural and morphological characteristics of AgNPs are investigated by making use of UV-vis spectroscopy, transmission electron microscopy (TEM), dynamic light scattering (DLS), zeta potential, FT-IR and X-ray diffraction (XRD) analysis. Research outputs signify (a) the absorbance around 410-420nm in the UV-vis spectra of AgNPs appears most, probably owing to the presence of nanosized silver particles and the intensity of this peak increases by increasing AgNO3 concentration; (b) that highly stable AgNPs with well-dispersed particle are successfully prepared using the present research-based innovation; (c) that the size of AgNPs does not exceed 30nm with sphere-like morphology even at the highest Ag(+) concentration employed during synthesis operation; (d) that the XRD and FT-IR confirm the successful preparation of pure AgNPs without noticeable impurities; (d) and that the one-pot synthesis of powdered AgNPs in large scale is clean and easily operated and easily transportation which may be applied as per demands of industries such as textile and painting industry.
authors.affiliation: Textile Research Division, National Research Centre (Affiliation ID: 60014618), Dokki, Cairo, Egypt.
authors.forename: A
authors.initials: A
authors.lastname: Hebeish
authors.affiliation: Textile Research Division, National Research Centre (Affiliation ID: 60014618), Dokki, Cairo, Egypt.
authors.forename: Th I
authors.initials: TI
authors.lastname: Shaheen
authors.affiliation: Textile Research Division, National Research Centre (Affiliation ID: 60014618), Dokki, Cairo, Egypt. Electronic address: Mehrezchem@yahoo.com.
authors.forename: Mehrez E
authors.initials: ME
authors.lastname: El-Naggar
mesh_terms: D060326:Chemistry Techniques, Synthetic; D053758:Nanoparticles / Q000737:chemistry*; D036103:Nanotechnology; D010316:Particle Size; D012834:Silver / Q000737:chemistry*; D012835:Silver Nitrate / Q000737:chemistry; D013213:Starch / Q000737:chemistry*
chemical_list: D012834:Silver; D013213:Starch; D012835:Silver Nitrate
keywords: Chemical reduction method; One pot green synthesis; Powdered silver nanoparticles