title: Thermal Stability and Reactivity of Cathode Materials for Li-Ion Batteries.
abstract: The thermal stability of electrochemically delithiated Li0.1Ni0.8Co0.15Al0.05O2 (NCA), FePO4 (FP), Mn0.8Fe0.2PO4 (MFP), hydrothermally synthesized VOPO4, LiVOPO4, and electrochemically lithiated Li2VOPO4 is investigated by differential scanning calorimetry (DSC) and thermogravimetric analysis, coupled with mass spectrometry (TGA-MS). The thermal stability of the delithiated materials is found to be in the order of NCA < VOPO4 < MFP < FP. Unlike the layered oxides and MFP, VOPO4 does not evolve O2 on heating. Thus, VOPO4 is less likely to cause a thermal run-away phenomenon in batteries at elevated temperature and so is inherently safer. The lithiated materials LiVOPO4, Li2VOPO4, and LiNi0.8Co0.15Al0.05O2 are found to be stable in the presence of electrolyte, but sealed-capsule high-pressure experiments show a phase transformation of VOPO4 → HVOPO4 → H2VOPO4 when VOPO4 reacts with electrolyte (1 M LiPF6 in EC/DMC = 1:1) between 200 and 300 °C. Using first-principles calculations, we confirm that the charged VOPO4 cathode is indeed predicted to be marginally less stable than FP but significantly more stable than NCA in the absence of electrolyte. An analysis of the reaction equilibria between VOPO4 and EC using a multicomponent phase diagram approach yields products and reaction enthalpies that are highly consistent with the experiment results.
authors.affiliation: Chemistry and Materials and ‡Department of Geology, Binghamton University , Binghamton, New York 13902-6000, United States.|Materials Science and Engineering Program and ∥Department of NanoEngineering, University of California, San Diego , 9500 Gilman Drive, La Jolla, California 92093, United States.
authors.forename: Yiqing
authors.initials: Y
authors.lastname: Huang
authors.affiliation: Chemistry and Materials and ‡Department of Geology, Binghamton University , Binghamton, New York 13902-6000, United States.|Materials Science and Engineering Program and ∥Department of NanoEngineering, University of California, San Diego , 9500 Gilman Drive, La Jolla, California 92093, United States.
authors.forename: Yuh-Chieh
authors.initials: YC
authors.lastname: Lin
authors.affiliation: Chemistry and Materials and ‡Department of Geology, Binghamton University , Binghamton, New York 13902-6000, United States.|Materials Science and Engineering Program and ∥Department of NanoEngineering, University of California, San Diego , 9500 Gilman Drive, La Jolla, California 92093, United States.
authors.forename: David M
authors.initials: DM
authors.lastname: Jenkins
authors.affiliation: Chemistry and Materials and ‡Department of Geology, Binghamton University , Binghamton, New York 13902-6000, United States.|Materials Science and Engineering Program and ∥Department of NanoEngineering, University of California, San Diego , 9500 Gilman Drive, La Jolla, California 92093, United States.
authors.forename: Natasha A
authors.initials: NA
authors.lastname: Chernova
authors.affiliation: Chemistry and Materials and ‡Department of Geology, Binghamton University , Binghamton, New York 13902-6000, United States.|Materials Science and Engineering Program and ∥Department of NanoEngineering, University of California, San Diego , 9500 Gilman Drive, La Jolla, California 92093, United States.
authors.forename: Youngmin
authors.initials: Y
authors.lastname: Chung
authors.affiliation: Chemistry and Materials and ‡Department of Geology, Binghamton University , Binghamton, New York 13902-6000, United States.|Materials Science and Engineering Program and ∥Department of NanoEngineering, University of California, San Diego , 9500 Gilman Drive, La Jolla, California 92093, United States.
authors.forename: Balachandran
authors.initials: B
authors.lastname: Radhakrishnan
authors.affiliation: Chemistry and Materials and ‡Department of Geology, Binghamton University , Binghamton, New York 13902-6000, United States.|Materials Science and Engineering Program and ∥Department of NanoEngineering, University of California, San Diego , 9500 Gilman Drive, La Jolla, California 92093, United States.
authors.forename: Iek-Heng
authors.initials: IH
authors.lastname: Chu
authors.affiliation: Chemistry and Materials and ‡Department of Geology, Binghamton University , Binghamton, New York 13902-6000, United States.|Materials Science and Engineering Program and ∥Department of NanoEngineering, University of California, San Diego , 9500 Gilman Drive, La Jolla, California 92093, United States.
authors.forename: Jin
authors.initials: J
authors.lastname: Fang
authors.affiliation: Chemistry and Materials and ‡Department of Geology, Binghamton University , Binghamton, New York 13902-6000, United States.|Materials Science and Engineering Program and ∥Department of NanoEngineering, University of California, San Diego , 9500 Gilman Drive, La Jolla, California 92093, United States.
authors.forename: Qi
authors.initials: Q
authors.lastname: Wang
authors.affiliation: Chemistry and Materials and ‡Department of Geology, Binghamton University , Binghamton, New York 13902-6000, United States.|Materials Science and Engineering Program and ∥Department of NanoEngineering, University of California, San Diego , 9500 Gilman Drive, La Jolla, California 92093, United States.
authors.forename: Fredrick
authors.initials: F
authors.lastname: Omenya
authors.affiliation: Chemistry and Materials and ‡Department of Geology, Binghamton University , Binghamton, New York 13902-6000, United States.|Materials Science and Engineering Program and ∥Department of NanoEngineering, University of California, San Diego , 9500 Gilman Drive, La Jolla, California 92093, United States.
authors.forename: Shyue Ping
authors.initials: SP
authors.lastname: Ong
authors.affiliation: Chemistry and Materials and ‡Department of Geology, Binghamton University , Binghamton, New York 13902-6000, United States.|Materials Science and Engineering Program and ∥Department of NanoEngineering, University of California, San Diego , 9500 Gilman Drive, La Jolla, California 92093, United States.
authors.forename: M Stanley
authors.initials: MS
authors.lastname: Whittingham
keywords: Li-ion battery; cathode; electrolyte; oxides; phosphates; thermal stability