title: N-Tosyl-1,5,2,6-dithiadiazocane: a waste-free electrophilic sulfur reagent for the efficient synthesis of medium-ring S,N-heterocycles.
abstract: We report on the application of an eight-membered C2-symmetric sulfenamide derivative as a new convenient and highly reactive electrophilic sulfur-nucleophilic nitrogen synthon for the concise synthesis of medium-ring S,N-heterocyclic systems.
authors.affiliation: Department of Organic Chemistry, Vilnius University, Naugarduko 24, 03225 Vilnius, Lithuania. edvinas.orentas@chf.vu.lt.
authors.forename: Tomas
authors.initials: T
authors.lastname: Javorskis
authors.affiliation: Department of Polymer Chemistry and Technology, Kaunas University of Technology, Radvilėnų pl. 19, 50254 Kaunas, Lithuania.
authors.forename: Gintautas
authors.initials: G
authors.lastname: Bagdžiūnas
authors.affiliation: Department of Organic Chemistry, Vilnius University, Naugarduko 24, 03225 Vilnius, Lithuania. edvinas.orentas@chf.vu.lt.
authors.forename: Edvinas
authors.initials: E
authors.lastname: Orentas
mesh_terms: D006571:Heterocyclic Compounds / Q000138:chemical synthesis*; D013455:Sulfur / Q000737:chemistry*; D014105:Tosyl Compounds / Q000737:chemistry*
chemical_list: D006571:Heterocyclic Compounds; D014105:Tosyl Compounds; D013455:Sulfur