title: Tuning the mechanical properties of vertical graphene sheets through atomic layer deposition.
abstract: We report the fabrication and characterization of graphene nanostructures with mechanical properties that are tuned by conformal deposition of alumina. Vertical graphene (VG) sheets, also called carbon nanowalls (CNWs), were grown on copper foil substrates using a radio-frequency plasma-enhanced chemical vapor deposition (RF-PECVD) technique and conformally coated with different thicknesses of alumina (Al2O3) using atomic layer deposition (ALD). Nanoindentation was used to characterize the mechanical properties of pristine and alumina-coated VG sheets. Results show a significant increase in the effective Young's modulus of the VG sheets with increasing thickness of deposited alumina. Deposition of only a 5 nm thick alumina layer on the VG sheets nearly triples the effective Young's modulus of the VG structures. Both energy absorption and strain recovery were lower in VG sheets coated with alumina than in pure VG sheets (for the same peak force). This may be attributed to the increase in bending stiffness of the VG sheets and the creation of connections between the sheets after ALD deposition. These results demonstrate that the mechanical properties of VG sheets can be tuned over a wide range through conformal atomic layer deposition, facilitating the use of VG sheets in applications where specific mechanical properties are needed.
authors.affiliation: Department of Mechanical Engineering and Applied Mechanics, University of Pennsylvania, Philadelphia, PA 19104, USA. Department of Mechanical Engineering, Widener University, One University Place, Chester, PA 19013, USA.
authors.forename: Keivan
authors.initials: K
authors.lastname: Davami
authors.forename: Yijie
authors.initials: Y
authors.lastname: Jiang
authors.forename: John
authors.initials: J
authors.lastname: Cortes
authors.forename: Chen
authors.initials: C
authors.lastname: Lin
authors.forename: Mehrdad
authors.initials: M
authors.lastname: Shaygan
authors.forename: Kevin T
authors.initials: KT
authors.lastname: Turner
authors.forename: Igor
authors.initials: I
authors.lastname: Bargatin