title: Linear Supramolecular Polymers via Connecting Telechelic Polycaprolactone through Alkynylplatinum(II) Terpyridine Molecular Tweezer/Pyrene Recognition Motif.
abstract: By anchoring alkynylplatinum(II) terpyridine molecular tweezer/pyrene recognition motif on the chain-ends of telechelic polycaprolactone, high-molecular-weight supramolecular polymers have been successfully constructed via noncovalent chain extension, which demonstrate fascinating rheological and thermal properties. Moreover, the resulting assemblies exhibit interesting temperature- and solvent-responsive behaviors, which are promising for the development of adaptive functional materials.
authors.affiliation: Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China.
authors.forename: Huaqing
authors.initials: H
authors.lastname: Liu
authors.affiliation: Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China.
authors.forename: Xiaohang
authors.initials: X
authors.lastname: Han
authors.affiliation: Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China.
authors.forename: Zongchun
authors.initials: Z
authors.lastname: Gao
authors.affiliation: Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China.
authors.forename: Zhao
authors.initials: Z
authors.lastname: Gao
authors.affiliation: Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China.
authors.forename: Feng
authors.initials: F
authors.lastname: Wang
mesh_terms: D015394:Molecular Structure; D011091:Polyesters / Q000737:chemistry*; D058105:Polymerization; D011108:Polymers / Q000138:chemical synthesis*; D011721:Pyrenes / Q000737:chemistry
chemical_list: D011091:Polyesters; D011108:Polymers; D011721:Pyrenes; C016240:polycaprolactone
keywords: host-guest recognition; molecular tweezers; stimuli-responsiveness; supramolecular polymers; telechelic polymers