title: Selective recovery of pure copper nanopowder from indium-tin-oxide etching wastewater by various wet chemical reduction process: Understanding their chemistry and comparisons of sustainable valorization processes.
abstract: Sustainable valorization processes for selective recovery of pure copper nanopowder from Indium-Tin-Oxide (ITO) etching wastewater by various wet chemical reduction processes, their chemistry has been investigated and compared. After the indium recovery by solvent extraction from ITO etching wastewater, the same is also an environmental challenge, needs to be treated before disposal. After the indium recovery, ITO etching wastewater contains 6.11kg/m(3) of copper and 1.35kg/m(3) of aluminum, pH of the solution is very low converging to 0 and contain a significant amount of chlorine in the media. In this study, pure copper nanopowder was recovered using various reducing reagents by wet chemical reduction and characterized. Different reducing agents like a metallic, an inorganic acid and an organic acid were used to understand reduction behavior of copper in the presence of aluminum in a strong chloride medium of the ITO etching wastewater. The effect of a polymer surfactant Polyvinylpyrrolidone (PVP), which was included to prevent aggregation, to provide dispersion stability and control the size of copper nanopowder was investigated and compared. The developed copper nanopowder recovery techniques are techno-economical feasible processes for commercial production of copper nanopowder in the range of 100-500nm size from the reported facilities through a one-pot synthesis. By all the process reported pure copper nanopowder can be recovered with>99% efficiency. After the copper recovery, copper concentration in the wastewater reduced to acceptable limit recommended by WHO for wastewater disposal. The process is not only beneficial for recycling of copper, but also helps to address environment challenged posed by ITO etching wastewater. From a complex wastewater, synthesis of pure copper nanopowder using various wet chemical reduction route and their comparison is the novelty of this recovery process.
authors.affiliation: Institute for Advanced Engineering, Advanced Materials & Processing Center, Yongin, 449-863, Republic of Korea. Electronic address: swain@iae.re.kr.
authors.forename: Basudev
authors.initials: B
authors.lastname: Swain
authors.affiliation: Institute for Advanced Engineering, Advanced Materials & Processing Center, Yongin, 449-863, Republic of Korea.
authors.forename: Chinmayee
authors.initials: C
authors.lastname: Mishra
authors.affiliation: Sungshin University, Dept. of Interdisciplinary ECO Science, Seoul, 142-732, Republic of Korea.
authors.forename: Hyun Seon
authors.initials: HS
authors.lastname: Hong
authors.affiliation: Institute for Advanced Engineering, Advanced Materials & Processing Center, Yongin, 449-863, Republic of Korea.
authors.forename: Sung-Soo
authors.initials: SS
authors.lastname: Cho
mesh_terms: D003300:Copper / Q000302:isolation & purification*; D006863:Hydrogen-Ion Concentration; D007204:Indium / Q000032:analysis*; D007220:Industrial Waste / Q000032:analysis*; D053758:Nanoparticles; D010084:Oxidation-Reduction; D011208:Powders; D059027:Recycling / Q000379:methods*; D012996:Solutions; D017971:Tin Compounds / Q000032:analysis*; D062065:Wastewater / Q000737:chemistry*
chemical_list: D003300:Copper; D007204:Indium; D007220:Industrial Waste; D011208:Powders; D012996:Solutions; D017971:Tin Compounds; D062065:Wastewater; C047711:indium oxide; C045358:stannic oxide
keywords: Copper powder; Indium-Tin-Oxide etching waste; Selective Reduction; sustainable valorization processes