title: Preparation of metal-ceramic composites by sonochemical synthesis of metallic nano-particles and in-situ decoration on ceramic powders.
abstract: Copper and nickel nanoparticles were synthesized using reducing agents in the presence of direct high energy ultra-sonication. The metallic nanoparticles were decorated on various ceramic substrates (e.g. α-Al2O3, and TiO2) leading to metal reinforced ceramics with up to 45% metallic content. Different parameters, such as the amount of precursor material or the substrate, as well as the intensity of ultrasound were examined, in order to evaluate the percentage of final metallic decoration on the composite materials. All products were characterized by means of Inductively Coupled Plasma Spectroscopy in order to investigate the loading with metallic particles. X-ray Diffraction and Scanning Electron Microscopy were also used for further sample characterization. Selected samples were examined using Transmission Electron Microscopy, while finally, some of the powders synthesized, were densified by means of Spark Plasma Sintering, followed by a SEM/EDX examination and an estimation of their porosity.
authors.affiliation: National Technical University of Athens, School of Chemical Engineering, Laboratory of Inorganic Materials Technology, 15780 Athens, Greece.
authors.forename: A
authors.initials: A
authors.lastname: Poulia
authors.affiliation: National Technical University of Athens, School of Chemical Engineering, Laboratory of Inorganic Materials Technology, 15780 Athens, Greece.
authors.forename: P M
authors.initials: PM
authors.lastname: Sakkas
authors.affiliation: National Technical University of Athens, School of Chemical Engineering, Laboratory of Inorganic Materials Technology, 15780 Athens, Greece.
authors.forename: D G
authors.initials: DG
authors.lastname: Kanellopoulou
authors.affiliation: Institut für Energieforschung und Physikalische Technologien, Clausthal University of Technology, Leibnizstr. 4, 38678 Clausthal-Zellerfeld, Germany; Clausthaler Zentrum für Materialforschung (CZM), Agricola Str. 2, 38678 Clausthal-Zellerfeld, Germany.
authors.forename: G
authors.initials: G
authors.lastname: Sourkouni
authors.affiliation: Université Paris-Sud 11, Institut de Chimie Moléculaire et des Matériaux, 91405 Orsay Cedex, France.
authors.forename: C
authors.initials: C
authors.lastname: Legros
authors.affiliation: National Technical University of Athens, School of Chemical Engineering, Laboratory of Inorganic Materials Technology, 15780 Athens, Greece; Institut für Energieforschung und Physikalische Technologien, Clausthal University of Technology, Leibnizstr. 4, 38678 Clausthal-Zellerfeld, Germany; Clausthaler Zentrum für Materialforschung (CZM), Agricola Str. 2, 38678 Clausthal-Zellerfeld, Germany. Electronic address: amca@chemeng.ntua.gr.
authors.forename: Chr
authors.initials: C
authors.lastname: Argirusis
keywords: Decoration; Metal–ceramic composites; Nanoparticles; Sonochemistry; Ultrasound