title: Crystal structure of fac-tricarbon-yl(quinoline-2-carboxyl-ato-κ(2) N,O)(tri-phenyl-arsane-κAs)rhenium(I).
abstract: In the title compound, [Re(C10H6NO2)(CO)3{As(C6H5)3}], the coordination environment of Re(I) is that of a distorted octa-hedron. Three coordination sites are occupied by three carbonyl groups in a facial arrangement and the remaining three sites by tri-phenyl-arsane and deprotonated quinaldic acid in As-mono- and N,O-bidentate fashions, respectively. In the crystal, the complexes are linked through weak C-H⋯O hydrogen bonds, forming a three-dimensional network. It worth noting that, as far as we know, this complex is the first Re(I) tri-phenyl-arsane tricarbonyl compound to be reported.
authors.affiliation: Institute of Nuclear and Radiological Sciences and Technology, Energy and Safety, National Centre for Scientific Research "Demokritos", 15310 Athens, Greece.
authors.forename: Charalampos
authors.initials: C
authors.lastname: Triantis
authors.affiliation: Institute of Nuclear and Radiological Sciences and Technology, Energy and Safety, National Centre for Scientific Research "Demokritos", 15310 Athens, Greece.
authors.forename: Antonio
authors.initials: A
authors.lastname: Shegani
authors.affiliation: Institute of Nuclear and Radiological Sciences and Technology, Energy and Safety, National Centre for Scientific Research "Demokritos", 15310 Athens, Greece.
authors.forename: Christos
authors.initials: C
authors.lastname: Kiritsis
authors.affiliation: Institute of Nanoscience and Nanotechnology, National Centre for Scientific Research "Demokritos", 15310 Athens, Greece.
authors.forename: Catherine P
authors.initials: CP
authors.lastname: Raptopoulou
authors.affiliation: Institute of Nanoscience and Nanotechnology, National Centre for Scientific Research "Demokritos", 15310 Athens, Greece.
authors.forename: Vassilis
authors.initials: V
authors.lastname: Psycharis
authors.affiliation: Institute of Biosciences & Applications, National Centre for Scientific Research "Demokritos", 15310 Athens, Greece.
authors.forename: Maria
authors.initials: M
authors.lastname: Pelecanou
authors.affiliation: Institute of Nuclear and Radiological Sciences and Technology, Energy and Safety, National Centre for Scientific Research "Demokritos", 15310 Athens, Greece.
authors.forename: Ioannis
authors.initials: I
authors.lastname: Pirmettis
authors.affiliation: Institute of Nuclear and Radiological Sciences and Technology, Energy and Safety, National Centre for Scientific Research "Demokritos", 15310 Athens, Greece.
authors.forename: Minas
authors.initials: M
authors.lastname: Papadopoulos
keywords: crystal structure; rhenium(I) tricarbonyl complex; rhenium(I) tri­phenyl­arsane and quinaldic acid complex; trans influence