title: Ultrasonically assisted hydrothermal synthesis of activated carbon-HKUST-1-MOF hybrid for efficient simultaneous ultrasound-assisted removal of ternary organic dyes and antibacterial investigation: Taguchi optimization.
abstract: Activated carbon (AC) composite with HKUST-1 metal organic framework (AC-HKUST-1 MOF) was prepared by ultrasonically assisted hydrothermal method and characterized by FTIR, SEM and XRD analysis and laterally was applied for the simultaneous ultrasound-assisted removal of crystal violet (CV), disulfine blue (DSB) and quinoline yellow (QY) dyes in their ternary solution. In addition, this material, was screened in vitro for their antibacterial actively against Methicillin-resistant Staphylococcus aureus (MRSA) and Pseudomonas aeruginosa (PAO1) bacteria. In dyes removal process, the effects of important variables such as initial concentration of dyes, adsorbent mass, pH and sonication time on adsorption process optimized by Taguchi approach. Optimum values of 4, 0.02 g, 4 min, 10 mg L(-1) were obtained for pH, AC-HKUST-1 MOF mass, sonication time and the concentration of each dye, respectively. At the optimized condition, the removal percentages of CV, DSB and QY were found to be 99.76%, 91.10%, and 90.75%, respectively, with desirability of 0.989. Kinetics of adsorption processes follow pseudo-second-order model. The Langmuir model as best method with high applicability for representation of experimental data, while maximum mono layer adsorption capacity for CV, DSB and QY on AC-HKUST-1 estimated to be 133.33, 129.87 and 65.37 mg g(-1) which significantly were higher than HKUST-1 as sole material with Qm to equate 59.45, 57.14 and 38.80 mg g(-1), respectively.
authors.affiliation: Chemistry Department, Yasouj University, Yasouj 75918-74831, Iran.
authors.forename: F Nasiri
authors.initials: FN
authors.lastname: Azad
authors.affiliation: Chemistry Department, Yasouj University, Yasouj 75918-74831, Iran. Electronic address: m_ghaedi@mail.yu.ac.ir.
authors.forename: M
authors.initials: M
authors.lastname: Ghaedi
authors.affiliation: Chemistry Department, Yasouj University, Yasouj 75918-74831, Iran.
authors.forename: K
authors.initials: K
authors.lastname: Dashtian
authors.affiliation: Department of Physics, Yasouj University, Yasouj 75918-74831, Iran.
authors.forename: S
authors.initials: S
authors.lastname: Hajati
authors.affiliation: Cellular and Molecular Research Center, Yasouj University on Medical Sciences, Yasouj, Iran.
authors.forename: V
authors.initials: V
authors.lastname: Pezeshkpour
mesh_terms: D000327:Adsorption; D000900:Anti-Bacterial Agents / Q000494:pharmacology*; D004396:Coloring Agents / Q000302:isolation & purification* / Q000494:pharmacology; D007700:Kinetics; D008826:Microbial Sensitivity Tests; D046529:Microscopy, Electron, Transmission; D017550:Spectroscopy, Fourier Transform Infrared; D014465:Ultrasonics
chemical_list: D000900:Anti-Bacterial Agents; D004396:Coloring Agents
keywords: Antibacterial; Crystal violet; Disulfine blue; Metal organic framework; Quinoline yellow; Ultrasonically assisted hydrothermal synthesis