title: A 3D MOF constructed from dysprosium(III) oxalate and capping ligands: ferromagnetic coupling and field-induced two-step magnetic relaxation.
abstract: A novel 3D MOF based on dysprosium(iii) oxalate and 1,10-phenanthroline (phen), {[Dy(C2O4)1.5phen]·0.5H2O}n (1), has been hydrothermally synthesized. The Dy(3+) ion acts as a typical Y-shaped node, linking to each other to generate an interesting 3D topology structure. Complex 1 is the first 3D DyMOF displaying both ferromagnetic coupling and field-induced two-step magnetic relaxation.
authors.affiliation: Beijing National Laboratory for Molecular Sciences, Center for Molecular Science, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China. cmliu@iccas.ac.cn.
authors.forename: Cai-Ming
authors.initials: CM
authors.lastname: Liu
authors.forename: De-Qing
authors.initials: DQ
authors.lastname: Zhang
authors.forename: Dao-Ben
authors.initials: DB
authors.lastname: Zhu