title: Redox-Active Metal-Organic Composites for Highly Selective Oxygen Separation Applications.
abstract: A redox-active metal-organic composite material shows improved and selective O2 adsorption over N2 with respect to individual components (MIL-101 and ferrocene). The O2 sensitivity of the composite material arises due to the formation of maghemite nanoparticles with the pore of the metal-organic framework material.
authors.affiliation: Physical & Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, WA, 99352, USA.
authors.forename: Wen
authors.initials: W
authors.lastname: Zhang
authors.affiliation: Physical & Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, WA, 99352, USA.
authors.forename: Debasis
authors.initials: D
authors.lastname: Banerjee
authors.affiliation: Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, WA, 99354, USA.
authors.forename: Jian
authors.initials: J
authors.lastname: Liu
authors.affiliation: Physical & Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, WA, 99352, USA.
authors.forename: Herbert T
authors.initials: HT
authors.lastname: Schaef
authors.affiliation: Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, WA, 99354, USA.
authors.forename: Jarrod V
authors.initials: JV
authors.lastname: Crum
authors.affiliation: Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, WA, 99354, USA.
authors.forename: Carlos A
authors.initials: CA
authors.lastname: Fernandez
authors.affiliation: Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA, 99354, USA.
authors.forename: Ravi K
authors.initials: RK
authors.lastname: Kukkadapu
authors.affiliation: Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, WA, 99354, USA.
authors.forename: Zimin
authors.initials: Z
authors.lastname: Nie
authors.affiliation: Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, WA, 99354, USA.
authors.forename: Satish K
authors.initials: SK
authors.lastname: Nune
authors.affiliation: Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, WA, 99354, USA.
authors.forename: Radha K
authors.initials: RK
authors.lastname: Motkuri
authors.affiliation: X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, IL, 60439, USA.
authors.forename: Karena W
authors.initials: KW
authors.lastname: Chapman
authors.affiliation: Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA, 99354, USA.
authors.forename: Mark H
authors.initials: MH
authors.lastname: Engelhard
authors.affiliation: National Security Directorate, Pacific Northwest National Laboratory, Richland, WA, 99352, USA.
authors.forename: James C
authors.initials: JC
authors.lastname: Hayes
authors.affiliation: National Security Directorate, Pacific Northwest National Laboratory, Richland, WA, 99352, USA.
authors.forename: Kurt L
authors.initials: KL
authors.lastname: Silvers
authors.affiliation: Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam, The Netherlands.
authors.forename: Rajamani
authors.initials: R
authors.lastname: Krishna
authors.affiliation: Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, WA, 99354, USA.
authors.forename: B Peter
authors.initials: BP
authors.lastname: McGrail
authors.affiliation: Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, WA, 99354, USA.
authors.forename: Jun
authors.initials: J
authors.lastname: Liu
authors.affiliation: Physical & Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, WA, 99352, USA.
authors.forename: Praveen K
authors.initials: PK
authors.lastname: Thallapally
keywords: composite materials; oxygen sensors; oxygen separation; redox-active, metal-organic frameworks