title: Luminescent Iridium(III) Cyclometalated Complexes with 1,2,3-Triazole "Click" Ligands.
abstract: A series of cyclometalated iridium(III) complexes with either 4-(2-pyridyl)-1,2,3-triazole or 1-(2-picolyl)-1,2,3-triazole ancillary ligands to give complexes with either 5- or 6-membered chelate rings were synthesized and characterized by a combination of X-ray crystallography, electron spin ionization-high-resolution mass spectroscopy (ESI-HRMS), and nuclear magnetic resonance (NMR) spectroscopy. The electronic properties of the complexes were probed using absorption and emission spectroscopy, as well as cyclic voltammetry. The relative stability of the complexes formed from each ligand class was measured, and their excited-state properties were compared. The emissive properties are, with the exception of complexes that contain a nitroaromatic substituent, insensitive to functionalization of the ancillary pyridyl-1,2,3-triazole ligand but tuning of the emission maxima was possible by modification of the cyclometalating ligands. It is possible to prepare a wide range of optimally substituted pyridyl-1,2,3-triazoles using copper Cu(I)-catalyzed azide alkyne cycloaddition, which is a commonly used "click" reaction, and this family of ligands represent an useful alternative to bipyridine ligands for the preparation of luminescent iridium(III) complexes.
authors.affiliation: School of Chemistry and ‡Bio21 Molecular Science and Biotechnology Institute, The University of Melbourne , Melbourne, Victoria 3010, Australia.
authors.forename: Timothy U
authors.initials: TU
authors.lastname: Connell
authors.affiliation: School of Chemistry and ‡Bio21 Molecular Science and Biotechnology Institute, The University of Melbourne , Melbourne, Victoria 3010, Australia.
authors.forename: Jonathan M
authors.initials: JM
authors.lastname: White
authors.affiliation: School of Chemistry and ‡Bio21 Molecular Science and Biotechnology Institute, The University of Melbourne , Melbourne, Victoria 3010, Australia.
authors.forename: Trevor A
authors.initials: TA
authors.lastname: Smith
authors.affiliation: School of Chemistry and ‡Bio21 Molecular Science and Biotechnology Institute, The University of Melbourne , Melbourne, Victoria 3010, Australia.
authors.forename: Paul S
authors.initials: PS
authors.lastname: Donnelly