title: Efficiency enhancement of cubic perovskite BaSnO3 nanostructures based dye sensitized solar cells.
abstract: Cubic perovskite BaSnO3 (BSO) is an important photoelectron transporting material due to its electronic structure that competes with TiO2 in dye-sensitized solar cells (DSCs). Separately, BSO/TiCl4 treated and BSO/scattering layer photoelectrodes have been used in DSCs that effectively increase the photoexcited charge carriers collection resulting in superior photovoltaic performance. In the present work, the different TiCl4 treatment time (1, 3 and 5 min), different scattering layer (tetragonal anatase TiO2 and hexagonal wurtzite ZnO) and different combinations thereof are successfully used on BSO nanocuboids/nanoparticle morphological structure photoelectrodes, and then we systematically inspected their performance in DSCs. Under the optimized conditions, a power conversion efficiency (PCE) of 3.88% is obtained by a BSO/TiCl4 treated photoanode. Furthermore, the BSO photoanodes made using a scattering layer such as anatase TiO2 and hexagonal ZnO i.e., BSO/anatase TiO2 and BSO/hexagonal ZnO, exhibited PCEs of 1.14% and 1.25% respectively. In the end, one of the highest PCEs (5.68%) was achieved using BSO/TiCl4 treated/TiO2 scattering layer photoanode. Another photoelectrode such as BSO/TiCl4 treated/ZnO scattering layer exhibited a PCE of 4.28% that is also higher than the BSO/TiCl4 treated/BSO scattering layer photoanodes. Electron lifetime versus current density studies illustrate the stability of the BSO photoelectrode in DSCs. From the observed results, it is realized that BSO is one of the most important future technological materials.
authors.affiliation: Conn Center for Renewable Research and Department of Chemical Engineering, University of Louisville, Louisville, KY 40292, USA and School of Physics, Madurai Kamaraj University, Madurai 625021, TN, India. nrajamku@gmail.com.
authors.forename: N
authors.initials: N
authors.lastname: Rajamanickam
authors.affiliation: School of Physics, Madurai Kamaraj University, Madurai 625021, TN, India. nrajamku@gmail.com.
authors.forename: P
authors.initials: P
authors.lastname: Soundarrajan
authors.affiliation: Conn Center for Renewable Research and Department of Chemical Engineering, University of Louisville, Louisville, KY 40292, USA.
authors.forename: Venkat K
authors.initials: VK
authors.lastname: Vendra
authors.affiliation: Conn Center for Renewable Research and Department of Chemical Engineering, University of Louisville, Louisville, KY 40292, USA.
authors.forename: Jacek B
authors.initials: JB
authors.lastname: Jasinski
authors.affiliation: Conn Center for Renewable Research and Department of Chemical Engineering, University of Louisville, Louisville, KY 40292, USA.
authors.forename: Mahendra K
authors.initials: MK
authors.lastname: Sunkara
authors.affiliation: School of Physics, Madurai Kamaraj University, Madurai 625021, TN, India. nrajamku@gmail.com.
authors.forename: K
authors.initials: K
authors.lastname: Ramachandran