title: Crystal structure of aqua-(nitrato-κO)dioxido{2-[3-(pyridin-2-yl-κN)-1H-1,2,4-triazol-5-yl-κN (4)]phenolato-κO}uranium(VI) aceto-nitrile monosolvate monohydrate.
abstract: In the title compound, [U(C13H9N4O)(NO3)O2(H2O)]·CH3CN·H2O, the U(VI) atom is seven-coordinated in a distorted penta-gonal-bipyramidal N2O5 manner by one tridentate triazole ligand, one monodentate nitrate anion and one water mol-ecule in the equatorial plane and by two uran-yl(VI) O atoms in the axial positions. In the crystal, the U(VI) complex mol-ecule is linked to the water and aceto-nitrile solvent mol-ecules through N-H⋯N, O-H⋯O and O-H⋯N hydrogen bonds, forming a sheet structure parallel to the bc plane. The sheets are further linked by an additional O-H⋯O hydrogen bond, forming a three-dimensional network.
authors.affiliation: Department of Chemistry, Taras Shevchenko National University of Kyiv, 64/13, Volodymyrska Str., Kyiv, 01601, Ukraine.
authors.forename: Oleksandr
authors.initials: O
authors.lastname: Vashchenko
authors.affiliation: Department of Chemistry, Taras Shevchenko National University of Kyiv, 64/13, Volodymyrska Str., Kyiv, 01601, Ukraine.
authors.forename: Ilona
authors.initials: I
authors.lastname: Raspertova
authors.affiliation: STC "Institute for Single Crystals", National Academy of Science of Ukraine, 60 Lenina Ave., Kharkiv 61001, Ukraine.
authors.forename: Viktoriya
authors.initials: V
authors.lastname: Dyakonenko
authors.affiliation: STC "Institute for Single Crystals", National Academy of Science of Ukraine, 60 Lenina Ave., Kharkiv 61001, Ukraine.
authors.forename: Svitlana
authors.initials: S
authors.lastname: Shishkina
authors.affiliation: Department of Chemistry, Taras Shevchenko National University of Kyiv, 64/13, Volodymyrska Str., Kyiv, 01601, Ukraine.
authors.forename: Dmytro
authors.initials: D
authors.lastname: Khomenko
authors.affiliation: Department of Chemistry, Taras Shevchenko National University of Kyiv, 64/13, Volodymyrska Str., Kyiv, 01601, Ukraine.
authors.forename: Roman
authors.initials: R
authors.lastname: Doroschuk
authors.affiliation: Department of Chemistry, Taras Shevchenko National University of Kyiv, 64/13, Volodymyrska Str., Kyiv, 01601, Ukraine.
authors.forename: Rostislav
authors.initials: R
authors.lastname: Lampeka
keywords: 1,2,4-triazole; crystal structure; uran­yl(VI) ion