title: Coordination and supramolecular assembly of {Cd2Ge8V12O48} building block and cucurbit[6] to form rotaxane-shaped hybrids.
abstract: Assembly of cucurbit[6] and a {Cd2Ge8V12O48} cluster produced two rotaxane-shaped and polyrotaxane-shaped solids by changing the ratio of starting precursors in the system. The high oxygen density of the polyoxoanion surface provides active sites to extend a single rotaxane-shaped hybrid 1 to a 1D polyrotaxane-shaped hybrid 2. This construction strategy may afford an entirely new methodology for polyoxometalate-based hybrid chemistry.
authors.affiliation: Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, P. R. China. zanghy100@nenu.edu.cn wangxl824@nenu.edu.cn.
authors.forename: Mei-Jie
authors.initials: MJ
authors.lastname: Wei
authors.affiliation: Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, P. R. China. zanghy100@nenu.edu.cn wangxl824@nenu.edu.cn.
authors.forename: Hong-Ying
authors.initials: HY
authors.lastname: Zang
authors.affiliation: Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, P. R. China. zanghy100@nenu.edu.cn wangxl824@nenu.edu.cn.
authors.forename: En-Long
authors.initials: EL
authors.lastname: Zhou
authors.affiliation: Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, P. R. China. zanghy100@nenu.edu.cn wangxl824@nenu.edu.cn.
authors.forename: Kui-Zhan
authors.initials: KZ
authors.lastname: Shao
authors.affiliation: Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, P. R. China. zanghy100@nenu.edu.cn wangxl824@nenu.edu.cn.
authors.forename: Bai-Qiao
authors.initials: BQ
authors.lastname: Song
authors.affiliation: Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, P. R. China. zanghy100@nenu.edu.cn wangxl824@nenu.edu.cn.
authors.forename: Xin-Long
authors.initials: XL
authors.lastname: Wang
authors.affiliation: Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, P. R. China. zanghy100@nenu.edu.cn wangxl824@nenu.edu.cn.
authors.forename: Zhong-Min
authors.initials: ZM
authors.lastname: Su