title: A photosensitizing decatungstate-based MOF as heterogeneous photocatalyst for the selective C-H alkylation of aliphatic nitriles.
abstract: The efficient photosensitizing of decatungstate-based MOF with 1D channels was achieved via in situ synthesis under solvothermal conditions for light driven acceleration of β- or γ-site C-H alkylation of aliphatic nitriles. The high catalytic efficiency, excellent size selectivity, high stability and good recyclability of the photocatalyst offer an environmentally-friendly route for widening the scope of accessible nitriles in both laboratory and industry.
authors.affiliation: State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, P. R. China. cyduan@dlut.edu.cn.
authors.forename: Dongying
authors.initials: D
authors.lastname: Shi
authors.affiliation: State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, P. R. China. cyduan@dlut.edu.cn.
authors.forename: Cheng
authors.initials: C
authors.lastname: He
authors.affiliation: State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, P. R. China. cyduan@dlut.edu.cn.
authors.forename: Wenlong
authors.initials: W
authors.lastname: Sun
authors.affiliation: State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, P. R. China. cyduan@dlut.edu.cn.
authors.forename: Zheng
authors.initials: Z
authors.lastname: Ming
authors.affiliation: State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, P. R. China. cyduan@dlut.edu.cn.
authors.forename: Changgong
authors.initials: C
authors.lastname: Meng
authors.affiliation: State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, P. R. China. cyduan@dlut.edu.cn.
authors.forename: Chunying
authors.initials: C
authors.lastname: Duan