title: Synthesis of a new 1,2,3,4,5-pentasubstituted cyclohexanol and determining its stereochemistry by NMR spectroscopy and quantum-chemical calculations.
abstract: The presence of substituents in cyclohexane can influence to the ratio of conformers; for some cases, the boat form is preferable. The new six-membered cyclohexanol derivative 2 has been obtained by the synthesis of (E)-1-(bromophenyl)-3-phenylpropen-2-one (1). The NMR and quantum-chemical conformational analysis for the 2 have carried out, and its possible mechanism of formation was given. Copyright © 2015 John Wiley & Sons, Ltd.
authors.affiliation: Chemical Faculty, NMR Laboratory, Baku State University, Z. Khalilov 23, Baku, Azerbaijan.
authors.forename: Ibrahim
authors.initials: I
authors.lastname: Mamedov
authors.affiliation: Department of Chemistry, Karadeniz Technical University, 61080, Trabzon, Turkey.
authors.forename: Rza
authors.initials: R
authors.lastname: Abbasoglu
authors.affiliation: Chemical Faculty, NMR Laboratory, Baku State University, Z. Khalilov 23, Baku, Azerbaijan.
authors.forename: Musa
authors.initials: M
authors.lastname: Bayramov
authors.affiliation: Chemical Faculty, NMR Laboratory, Baku State University, Z. Khalilov 23, Baku, Azerbaijan.
authors.forename: Abel
authors.initials: A
authors.lastname: Maharramov
keywords: NMR; chalcone; conformation; cyclohexanol