title: Triple Boron-Cored Chromophores Bearing Discotic 5,11,17-Triazatrinaphthylene-Based Ligands.
abstract: A series of novel chromophores fused with multiple boron cores have been successfully synthesized by the complexation of three difluoroboryl or diphenylboryl at the periphery of 5,11,17-triazatrinaphthylene derivative ligands. Their sterically congested molecular scaffolds with expanded π-conjugated discotic backbones render them with unique electronic properties including large Stokes shifts, tunable electrochemical behaviors, and low-lying LUMO energy levels up to -3.18 eV.
authors.affiliation: School of Chemical and Environmental Engineering, Shanghai Institute of Technology , Shanghai 201418, P. R. China.|School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University , Shanghai 200240, P. R. China.
authors.forename: Feng
authors.initials: F
authors.lastname: Qiu
authors.affiliation: School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University , Shanghai 200240, P. R. China.
authors.forename: Fan
authors.initials: F
authors.lastname: Zhang
authors.affiliation: School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University , Shanghai 200240, P. R. China.
authors.forename: Ruizhi
authors.initials: R
authors.lastname: Tang
authors.affiliation: Department of Chemistry and Food Chemistry & Center for Advancing Electronics Dresden (cfaed), Technische Universitaet Dresden , Dresden, Germany.
authors.forename: Yubin
authors.initials: Y
authors.lastname: Fu
authors.affiliation: School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University , Shanghai 200240, P. R. China.
authors.forename: Xinyang
authors.initials: X
authors.lastname: Wang
authors.affiliation: School of Chemical and Environmental Engineering, Shanghai Institute of Technology , Shanghai 201418, P. R. China.
authors.forename: Sheng
authors.initials: S
authors.lastname: Han
authors.affiliation: School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University , Shanghai 200240, P. R. China.
authors.forename: Xiaodong
authors.initials: X
authors.lastname: Zhuang
authors.affiliation: School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University , Shanghai 200240, P. R. China.|Department of Chemistry and Food Chemistry & Center for Advancing Electronics Dresden (cfaed), Technische Universitaet Dresden , Dresden, Germany.
authors.forename: Xinliang
authors.initials: X
authors.lastname: Feng