title: Nanoplasmonics tuned "click chemistry".
abstract: Nanoplasmonics is a growing field of optical condensed matter science dedicated to optical phenomena at the nanoscale level in metal systems. Extensive research on noble metallic nanoparticles (NPs) has emerged within the last two decades due to their ability to keep the optical energy concentrated in the vicinity of NPs, in particular, the ability to create optical near-field enhancement followed by heat generation. We have exploited these properties in order to induce a localised "click" reaction in the vicinity of gold nanostructures under unfavourable experimental conditions. We demonstrate that this reaction can be controlled by the plasmonic properties of the nanostructures and we propose two physical mechanisms to interpret the observed plasmonic tuning of the "click" chemistry.
authors.affiliation: Université Paris13, Sorbonne Paris Cité, Laboratoire CSPBAT, CNRS, (UMR7244), 74 rue Marcel Cachin, 93017 Bobigny, France. marc.lamydelachapelle@univ-paris13.fr.
authors.forename: I
authors.initials: I
authors.lastname: Tijunelyte
authors.affiliation: Université Paris13, Sorbonne Paris Cité, Laboratoire CSPBAT, CNRS, (UMR7244), 74 rue Marcel Cachin, 93017 Bobigny, France. marc.lamydelachapelle@univ-paris13.fr.
authors.forename: E
authors.initials: E
authors.lastname: Guenin
authors.affiliation: Université Paris13, Sorbonne Paris Cité, Laboratoire CSPBAT, CNRS, (UMR7244), 74 rue Marcel Cachin, 93017 Bobigny, France. marc.lamydelachapelle@univ-paris13.fr.
authors.forename: N
authors.initials: N
authors.lastname: Lidgi-Guigui
authors.affiliation: IFREMER, Centre de Brest, Interfaces and Sensors and Group, BP 70, 29280 Plouzané, France.
authors.forename: F
authors.initials: F
authors.lastname: Colas
authors.affiliation: Université de Technologie de Troyes, Laboratoire de Nanotechnologie et d'Instrumentation Optique, Institut Charles Delaunay, FRE 2848, 12 rue Marie Curie, 10004 Troyes, France.
authors.forename: J
authors.initials: J
authors.lastname: Ibrahim
authors.affiliation: Université de Technologie de Troyes, Laboratoire de Nanotechnologie et d'Instrumentation Optique, Institut Charles Delaunay, FRE 2848, 12 rue Marie Curie, 10004 Troyes, France.
authors.forename: T
authors.initials: T
authors.lastname: Toury
authors.affiliation: Université Paris13, Sorbonne Paris Cité, Laboratoire CSPBAT, CNRS, (UMR7244), 74 rue Marcel Cachin, 93017 Bobigny, France. marc.lamydelachapelle@univ-paris13.fr.
authors.forename: M
authors.initials: M
authors.lastname: Lamy de la Chapelle