title: Enhanced Resonance Energy Transfer and White-Light Emission from Organic Fluorophores and Lanthanides in Dendron-based Hybrid Hydrogel.
abstract: In this paper, we have investigated the use of poly(aryl ether) dendron-based gel as a medium for resonance energy transfer (RET) from organic donors (phenanthrene, naphthalene, and pyrene) to lanthanide [Eu(III) and Tb(III)] ions. The gel has been prepared through self-assembly of glucose-cored poly(aryl ether) dendrons in a dimethyl sulfoxide/water mixture (1:9 v/v). The efficiency of RET was calculated by metal-centered emission quantum yield measurements in the gel medium. While there was no resonance energy transfer observed between the donor-acceptor pairs in solution, efficient RET has been observed in the gel medium. The metal-centered quantum yield values were 11.9% for phenanthrene-Eu(III), 3.9% for naphthalene-Eu(III), and 3.6% for pyrene-Eu(III) systems. Partial RET in the system has been utilized to generate white-light emission from the gel by incorporating an additional lanthanide ion, Tb(III), along with the organic donors and Eu(III). The CIE (Commission Internationale d'Eclairage) coordinates obtained for gels formed by phenanthrene-Tb(III)-Eu(III) (PTE), naphthalene-Tb(III)-Eu(III) (NTE), and pyrene-Tb(III)-Eu(III) (PyTE) were (0.33, 0.32) for PTE, (0.35, 0.37) for NTE, and (0.35, 0.33) for PyTE. The correlated color temperatures (CCT) for white-light-emitting gels were calculated, and the values (5520 K for PTE, 4886 K for NTE, and 4722 K for PyTE) suggest that the system generates cool white light.
authors.affiliation: Department of Chemistry, Indian Institute of Technology Madras , Chennai, Tamil Nadu 600 036, India.
authors.forename: Prashant
authors.initials: P
authors.lastname: Kumar
authors.affiliation: Department of Chemistry, Indian Institute of Technology Madras , Chennai, Tamil Nadu 600 036, India.
authors.forename: Sivalingam
authors.initials: S
authors.lastname: Soumya
authors.affiliation: Department of Chemistry, Indian Institute of Technology Madras , Chennai, Tamil Nadu 600 036, India.
authors.forename: Edamana
authors.initials: E
authors.lastname: Prasad
keywords: hybrid hydrogel; lanthanides; poly(aryl ether) dendron; resonance energy transfer; white-light-emitting gel