title: Stability and self-passivation of copper vanadate photoanodes under chemical, electrochemical, and photoelectrochemical operation.
abstract: Deployment of solar fuels technology requires photoanodes with long term stability, which can be accomplished using light absorbers that self-passivate under operational conditions. Several copper vanadates have been recently reported as promising photoanode materials, and their stability and self-passivation is demonstrated through a combination of Pourbaix calculations and combinatorial experimentation.
authors.affiliation: Joint Center for Artificial Photosynthesis, California Institute of Technology, Pasadena, CA 91125, USA. gregoire@caltech.edu.
authors.forename: Lan
authors.initials: L
authors.lastname: Zhou
authors.forename: Qimin
authors.initials: Q
authors.lastname: Yan
authors.forename: Jie
authors.initials: J
authors.lastname: Yu
authors.forename: Ryan J R
authors.initials: RJ
authors.lastname: Jones
authors.forename: Natalie
authors.initials: N
authors.lastname: Becerra-Stasiewicz
authors.forename: Santosh K
authors.initials: SK
authors.lastname: Suram
authors.forename: Aniketa
authors.initials: A
authors.lastname: Shinde
authors.forename: Dan
authors.initials: D
authors.lastname: Guevarra
authors.forename: Jeffrey B
authors.initials: JB
authors.lastname: Neaton
authors.forename: Kristin A
authors.initials: KA
authors.lastname: Persson
authors.forename: John M
authors.initials: JM
authors.lastname: Gregoire