title: Unprecedented layered coordination polymers of dithiolene group 10 metals: magnetic and electrical properties.
abstract: One-pot reactions between Ni(ii), Pd(ii) or Pt(ii) salts and 3,6-dichloro-1,2-benzenedithiol (HSC6H2Cl2SH) in KOH medium under argon lead to a series of bis-dithiolene coordination polymers. X-ray analysis shows the presence of a common square planar complex [M(SC6H2Cl2S)2](2-) linked to potassium cations forming either a two-dimensional coordination polymer network for {[K2(μ-H2O)2(μ-thf)(thf)2][M(SC6H2Cl2S)2]}n [M = Ni () and Pd ()] or a one-dimensional coordination polymer for {[K2(μ-H2O)2(thf)6][Pt(SC6H2Cl2S)2]}n (). In the coordination environment of the potassium ions may slightly change leading to the two-dimensional coordination polymer {[K2(μ-H2O)(μ-thf)2][Pt(SC6H2Cl2S)2]}n () that crystallizes together with . The physical characterization of compounds show similar trends, they are diamagnetic and behave as semiconductors.
authors.affiliation: Departamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid, Spain. esther.delgado@uam.es.
authors.forename: Esther
authors.initials: E
authors.lastname: Delgado
authors.affiliation: Instituto de Ciencia Molecular. Universidad de Valencia. C/Catedrático José Beltrán, 2. 46980 Paterna, Valencia, Spain.
authors.forename: Carlos J
authors.initials: CJ
authors.lastname: Gómez-García
authors.affiliation: Departamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid, Spain. esther.delgado@uam.es.
authors.forename: Diego
authors.initials: D
authors.lastname: Hernández
authors.affiliation: Departamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid, Spain. esther.delgado@uam.es.
authors.forename: Elisa
authors.initials: E
authors.lastname: Hernández
authors.affiliation: Departamento de Química Inorgánica, Universidad de Alcalá. Campus Universitario, E-28871, Alcalá de Henares, Spain.
authors.forename: Avelino
authors.initials: A
authors.lastname: Martín
authors.affiliation: Departamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid, Spain. esther.delgado@uam.es and Instituto Madrileño de Estudios Avanzados en Nanociencia (IMDEA Nanociencia), Cantoblanco, 28049 Madrid, Spain.
authors.forename: Félix
authors.initials: F
authors.lastname: Zamora