title: Spontaneous Formation of Eutectic Crystal Structures in Binary and Ternary Charged Colloids due to Depletion Attraction.
abstract: Crystallization of colloids has extensively been studied for past few decades as models to study phase transition in general. Recently, complex crystal structures in multi-component colloids, including alloy and eutectic structures, have attracted considerable attention. However, the fabrication of 2D area-filling colloidal eutectics has not been reported till date. Here, we report formation of eutectic structures in binary and ternary aqueous colloids due to depletion attraction. We used charged particles + linear polyelectrolyte systems, in which the interparticle interaction could be represented as a sum of the electrostatic, depletion, and van der Waals forces. The interaction was tunable at a lengthscale accessible to direct observation by optical microscopy. The eutectic structures were formed because of interplay of crystallization of constituent components and accompanying fractionation. An observed binary phase diagram, defined by a mixing ratio and inverse area fraction of the particles, was analogous to that for atomic and molecular eutectic systems. This new method also allows the adjustment of both the number and wavelengths of Bragg diffraction peaks. Furthermore, these eutectic structures could be immobilized in polymer gel to produce self-standing materials. The present findings will be useful in the design of the optical properties of colloidal crystals.
authors.affiliation: Faculty of Pharmaceutical Sciences, Graduate School of Nagoya City University, 3-1 Tanabe, Mizuho, Nagoya, Aichi 467-8603, Japan.|JST, PRESTO, 4-1-8 Honcho, Kawaguch, Saitama, 332-0012, Japan.
authors.forename: Akiko
authors.initials: A
authors.lastname: Toyotama
authors.affiliation: Faculty of Pharmaceutical Sciences, Graduate School of Nagoya City University, 3-1 Tanabe, Mizuho, Nagoya, Aichi 467-8603, Japan.
authors.forename: Tohru
authors.initials: T
authors.lastname: Okuzono
authors.affiliation: Faculty of Pharmaceutical Sciences, Graduate School of Nagoya City University, 3-1 Tanabe, Mizuho, Nagoya, Aichi 467-8603, Japan.
authors.forename: Junpei
authors.initials: J
authors.lastname: Yamanaka