title: Synthesis of 2-Alkenylquinoline by Reductive Olefination of Quinoline N-Oxide under Metal-Free Conditions.
abstract: Synthesis of 2-alkenylquinoline by reductive olefination of quinoline N-oxide under metal-free conditions is disclosed. Practically, the reaction could be performed with quinoline as starting material via a one-pot, two-step process. A possible mechanism is proposed that involves a sequential 1,3-dipolar cycloaddition and acid-assisted ring opening followed by a dehydration process.
authors.affiliation: School of Chemistry and Chemical Engineering, Sun Yat-Sen University , 135 Xingang West Road, Guangzhou 510275, China.|School of Chemistry and Chemical Engineering, State Key Lab of Oil and Gas Reservoir Geology and Expoitation, Southwest Petroleum University , Chengdu 610500, China.
authors.forename: Hong
authors.initials: H
authors.lastname: Xia
authors.affiliation: School of Chemistry and Chemical Engineering, Sun Yat-Sen University , 135 Xingang West Road, Guangzhou 510275, China.
authors.forename: Yuanhong
authors.initials: Y
authors.lastname: Liu
authors.affiliation: School of Chemistry and Chemical Engineering, Sun Yat-Sen University , 135 Xingang West Road, Guangzhou 510275, China.|School of Chemistry and Chemical Engineering, State Key Lab of Oil and Gas Reservoir Geology and Expoitation, Southwest Petroleum University , Chengdu 610500, China.
authors.forename: Peng
authors.initials: P
authors.lastname: Zhao
authors.affiliation: School of Chemistry and Chemical Engineering, State Key Lab of Oil and Gas Reservoir Geology and Expoitation, Southwest Petroleum University , Chengdu 610500, China.
authors.forename: Shaohua
authors.initials: S
authors.lastname: Gou
authors.affiliation: School of Chemistry and Chemical Engineering, Sun Yat-Sen University , 135 Xingang West Road, Guangzhou 510275, China.
authors.forename: Jun
authors.initials: J
authors.lastname: Wang