title: Two-semiconductive-component hybrid coordination polymers with controllable photo-induced electron-transfer properties.
abstract: Two semiconductive inorganic-organic hybrid coordination polymers constructed from metal iodide clusters and naphthalene diimide semiconductive components, [Cu2I2(DPNDI)]n () and [PbI2(DPNDI)]n () (DPNDI = N,N'-di-(4-pyridyl)-1,4,5,8-naphthalene diimide), have been synthesized and characterized. Although possessing similar 2D heterostructures, hybrids exhibited different photo-induced electron-transfer properties. Due to the higher HOMO energy level of the [Cu2I2]n chain than that of the [PbI2]n cluster, only hybrid can easily undergo intramolecular electron transfer to form a long-lived charge separated state, which may be applied in artificial photosynthesis.
authors.affiliation: College of Chemistry, Fuzhou University, 350116, China. meijin_lin@fzu.edu.cn cchuang@fzu.edu.cn.
authors.forename: Jian-Jun
authors.initials: JJ
authors.lastname: Liu
authors.affiliation: College of Chemistry, Fuzhou University, 350116, China. meijin_lin@fzu.edu.cn cchuang@fzu.edu.cn.
authors.forename: Yong
authors.initials: Y
authors.lastname: Chen
authors.affiliation: College of Chemistry, Fuzhou University, 350116, China. meijin_lin@fzu.edu.cn cchuang@fzu.edu.cn and State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, CAS 350002, China.
authors.forename: Mei-Jin
authors.initials: MJ
authors.lastname: Lin
authors.affiliation: College of Chemistry, Fuzhou University, 350116, China. meijin_lin@fzu.edu.cn cchuang@fzu.edu.cn.
authors.forename: Chang-Cang
authors.initials: CC
authors.lastname: Huang
authors.affiliation: College of Chemistry, Fuzhou University, 350116, China. meijin_lin@fzu.edu.cn cchuang@fzu.edu.cn.
authors.forename: Wen-Xin
authors.initials: WX
authors.lastname: Dai