title: In situ generated polysiloxanes stabilizing μ3-oxo bridged Sb3 triangles.
abstract: The reaction of RSbO3H2 with t-butylsilanetriol has led to the isolation of organoantimony(v) based molecular triangles stabilized by siloxane frameworks. Depending on the reaction conditions employed or the substituents present on the antimony atom, either a combination of a disiloxane and a tetrasiloxane framework or a trisiloxane framework was generated in situ leading to the stabilization of the Sb3 triangle.
authors.affiliation: School of Chemistry, University of Hyderabad, Hyderabad 500046, Telangana, India. vbsc@uohyd.ernet.
authors.forename: M
authors.initials: M
authors.lastname: Santhana Raj Prabhu
authors.affiliation: School of Chemistry, University of Hyderabad, Hyderabad 500046, Telangana, India. vbsc@uohyd.ernet.
authors.forename: Uppara
authors.initials: U
authors.lastname: Ugandhar
authors.affiliation: School of Chemistry, University of Hyderabad, Hyderabad 500046, Telangana, India. vbsc@uohyd.ernet.
authors.forename: Viswanathan
authors.initials: V
authors.lastname: Baskar