title: Competing Interactions between Various Entropic Forces toward Assembly of Pt3Ni Octahedra into a Body-Centered Cubic Superlattice.
abstract: Anisotropic nanocrystal assembled supercrystals with open superlattices (SLs) manifest novel and unique properties, but poor understanding of the nucleation/growth mechanisms limits their design and fabrication for practical applications. Using highly anisotropic Pt3Ni octahedral nanocrystals, we have grown large single supercrystals with an open body-centered cubic (bcc) superlattice that has a low filling factor of 26.8%. Synchrotron-based X-ray structural reconstruction fully revealed the coherence of translational and orientational orderings and determined that the constituent octahedra arrange themselves with the vertex-to-vertex and face-to-face configurations along the SL[100] and SL[111] directions, respectively. The large face-to-face separation and flexible vertex-to-vertex elastic contact provided the rattle space and supporting axis for local rotations of Pt3Ni octahedra within the bcc superlattice. Development of orientational disordering along with robust preservation of translational ordering during the heating process of a supercrystal in the oleic acid wetting environment confirmed the dominance of rotational entropy of hard octahedra in the formation of the open bcc superlattice. Ultimate achievement of dynamic equilibrium between the vertex-oriented elastic repulsions and the face-oriented attractions of surface-coating ligands governs the structural and mechanical stability of the supercrystal. This discovery provides significant insights into the design and control of geometrical shapes for the fabrication of highly anisotropic nanocrystals into desired open superlattices with tailored optical and electronic properties.
authors.affiliation: Cornell High Energy Synchrotron Source, Cornell University , Ithaca, New York 14850, United States.
authors.forename: Ruipeng
authors.initials: R
authors.lastname: Li
authors.affiliation: State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum , Qingdao 266580, China.
authors.forename: Jun
authors.initials: J
authors.lastname: Zhang
authors.affiliation: Department of Chemistry, Brown University , Providence, Rhode Island 02912, United States.
authors.forename: Rui
authors.initials: R
authors.lastname: Tan
authors.affiliation: Institute of Physical Chemistry, University of Hamburg , 20146 Hamburg, Germany.
authors.forename: Frauke
authors.initials: F
authors.lastname: Gerdes
authors.affiliation: Department of Chemistry and Physics, Fayetteville State University , Fayetteville, North Carolina 28301, United States.
authors.forename: Zhiping
authors.initials: Z
authors.lastname: Luo
authors.forename: Hongwu
authors.initials: H
authors.lastname: Xu
authors.forename: Jennifer A
authors.initials: JA
authors.lastname: Hollingsworth
authors.affiliation: Institute of Physical Chemistry, University of Hamburg , 20146 Hamburg, Germany.
authors.forename: Christian
authors.initials: C
authors.lastname: Klinke
authors.affiliation: Department of Chemistry, Brown University , Providence, Rhode Island 02912, United States.
authors.forename: Ou
authors.initials: O
authors.lastname: Chen
authors.affiliation: Cornell High Energy Synchrotron Source, Cornell University , Ithaca, New York 14850, United States.
authors.forename: Zhongwu
authors.initials: Z
authors.lastname: Wang
keywords: Pt3Ni Octahedron; body-centered cubic; nanocrystal assembly; open superlattice; repulsive and attractive forces; rotational and translational entropies