title: K(+)-Induced in situ self-assembly of near-infrared luminescent membrane material armored with bigger Yb(III) complex crystallites.
abstract: A semi-rigid ligand could capture effectively Yb(3+) ions to form a stable Yb(3+) complex and provide a potential cavity to accommodate alkali metal ions. Only K(+) ions could induce the Yb(3+) complex to form a 1D coordination polymer and promote the in situ formation of an NIR membrane coated with bigger Yb(3+) complex crystallites under mild conditions.
authors.affiliation: Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province and State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Special Function Materials and Structure Design, Ministry of Education, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, 730000, China. tangxiaol@lzu.edu.cn liuws@lzu.edu.cn.
authors.forename: Wanmin
authors.initials: W
authors.lastname: Chen
authors.forename: Xiaoliang
authors.initials: X
authors.lastname: Tang
authors.forename: Wei
authors.initials: W
authors.lastname: Dou
authors.forename: Zhenghua
authors.initials: Z
authors.lastname: Ju
authors.forename: Benhua
authors.initials: B
authors.lastname: Xu
authors.forename: Wenxuan
authors.initials: W
authors.lastname: Xu
authors.forename: Weisheng
authors.initials: W
authors.lastname: Liu
mesh_terms: D002412:Cations / Q000737:chemistry; D056831:Coordination Complexes / Q000737:chemistry*; D003460:Crystallization; D008024:Ligands; D049449:Luminescence; D049408:Luminescent Agents / Q000737:chemistry*; D008567:Membranes, Artificial; D008958:Models, Molecular; D011188:Potassium / Q000737:chemistry*; D019265:Spectroscopy, Near-Infrared; D015018:Ytterbium / Q000737:chemistry*
chemical_list: D002412:Cations; D056831:Coordination Complexes; D008024:Ligands; D049408:Luminescent Agents; D008567:Membranes, Artificial; D015018:Ytterbium; D011188:Potassium