title: Thin Film Formation and Morphology of Electrosprayed Polydimethylsiloxane.
abstract: Low-voltage dielectric actuators (DEAs) can be fabricated using submicrometer-thin polydimethylsiloxane (PDMS) films. The two established techniques, namely spin coating and molecular beam deposition, however, are inappropriate to produce multistack DEAs in an efficient way. Therefore, we propose an alternative deposition technique, i.e., the alternating current electrospray deposition (ACESD) of 5 vol % PDMS in ethyl acetate solution and subsequent ultraviolet light curing. Atomic force microscopy makes possible the three-dimensional analysis of cured droplet-like islands. These circular islands, prepared on 2 in. Si(100) wafers from four polymers with molecular masses between 800 and 62,700 g/mol, reveal a characteristic morphology with an increasing height-to-diameter ratio. Using the 6000 g/mol polymer for ACESD, the film morphology evolution was tracked by applying conventional optical microscopy and spectroscopic ellipsometry. When the deposition was terminated after 13 s, circular islands with a mean height of 30 nm were found, while terminating the deposition after about 155 s led to a confluent layer with a mean height of 91 ± 10 nm. Potential electrostatic interactions between the droplets could not be identified through the analysis of spatial island distribution. Nevertheless, ACESD is a budget-priced and competitive deposition technique that can be employed to fabricate submicrometer-thin PDMS films with true nanometer roughness.
authors.affiliation: Biomaterials Science Center, Department of Biomedical Engineering, University of Basel , Gewerbestrasse 14, 4123 Allschwil, Switzerland.|Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, 8600 Dübendorf, Switzerland.
authors.forename: Florian M
authors.initials: FM
authors.lastname: Weiss
authors.affiliation: Biomaterials Science Center, Department of Biomedical Engineering, University of Basel , Gewerbestrasse 14, 4123 Allschwil, Switzerland.
authors.forename: Tino
authors.initials: T
authors.lastname: Töpper
authors.affiliation: Biomaterials Science Center, Department of Biomedical Engineering, University of Basel , Gewerbestrasse 14, 4123 Allschwil, Switzerland.
authors.forename: Bekim
authors.initials: B
authors.lastname: Osmani
authors.affiliation: Biomaterials Science Center, Department of Biomedical Engineering, University of Basel , Gewerbestrasse 14, 4123 Allschwil, Switzerland.
authors.forename: Hans
authors.initials: H
authors.lastname: Deyhle
authors.affiliation: Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, 8600 Dübendorf, Switzerland.
authors.forename: Gabor
authors.initials: G
authors.lastname: Kovacs
authors.affiliation: Biomaterials Science Center, Department of Biomedical Engineering, University of Basel , Gewerbestrasse 14, 4123 Allschwil, Switzerland.
authors.forename: Bert
authors.initials: B
authors.lastname: Müller