title: Diphosphane 2,2'-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation.
abstract: A convenient synthesis route to 2,2'-binaphtho[1,8-de][1,3,2]di-thiaphosphinine () was found. Its stable radical cation 3˙(+) was accessed easily through one-electron oxidation with NOBF4.
authors.affiliation: Department of Chemistry, Ludwig-Maximilians-University of Munich, Butenandtstr. 5-13 (D), 81377 Munich, Germany. konstantin.karaghiosoff@cup.uni-muenchen.de.
authors.forename: Christin
authors.initials: C
authors.lastname: Kirst
authors.affiliation: EastCHEM School of Chemistry, University of St. Andrews, Fife, KY16 9ST, UK. jdw3@st-andrews.ac.uk.
authors.forename: Bela E
authors.initials: BE
authors.lastname: Bode
authors.affiliation: EastCHEM School of Chemistry, University of St. Andrews, Fife, KY16 9ST, UK. jdw3@st-andrews.ac.uk.
authors.forename: David B
authors.initials: DB
authors.lastname: Cordes
authors.affiliation: EastCHEM School of Chemistry, University of St. Andrews, Fife, KY16 9ST, UK. jdw3@st-andrews.ac.uk.
authors.forename: Phillip S
authors.initials: PS
authors.lastname: Nejman
authors.affiliation: EastCHEM School of Chemistry, University of St. Andrews, Fife, KY16 9ST, UK. jdw3@st-andrews.ac.uk.
authors.forename: Alexandra M Z
authors.initials: AM
authors.lastname: Slawin
authors.affiliation: Department of Chemistry, Ludwig-Maximilians-University of Munich, Butenandtstr. 5-13 (D), 81377 Munich, Germany. konstantin.karaghiosoff@cup.uni-muenchen.de.
authors.forename: Konstantin
authors.initials: K
authors.lastname: Karaghiosoff
authors.affiliation: EastCHEM School of Chemistry, University of St. Andrews, Fife, KY16 9ST, UK. jdw3@st-andrews.ac.uk.
authors.forename: J Derek
authors.initials: JD
authors.lastname: Woollins