title: Development of New Effective Sorbents Based on Nanomagnetite.
abstract: Magnetic hybrid nanocomposite material based on the kraft lignin was prepared by the co-precipitating method. Kraft lignin was modified by iron nanooxide in order to enhance its sorption properties towards heavy metal ions. The composite material was characterized by physicochemical methods such as BET N2, ATR-FTIR, TGA, DSC, pHpzc, XRD and SEM. Its adsorption behaviour was studied using the batch mode by varying different parameters like pH, initial concentration of metal ions and shaking time as well as the presence of interfering ions. Adsorption of Cu(II), Cd(II) and Pb(II) ions from the aqueous solutions was studied in comparison with the commercial kraft lignin. The adsorption capacity and kinetic sorption characteristics of the composite material were determined.
authors.affiliation: Department of Inorganic Chemistry, Faculty of Chemistry, Maria Curie Skłodowska University, M. Curie Skłodowska Sq. 2, 20-031, Lublin, Poland.
authors.forename: Dorota
authors.initials: D
authors.lastname: Kołodyńska
authors.affiliation: Department of Inorganic Chemistry, Faculty of Chemistry, Maria Curie Skłodowska University, M. Curie Skłodowska Sq. 2, 20-031, Lublin, Poland.
authors.forename: Marzena
authors.initials: M
authors.lastname: Gęca
authors.affiliation: Nanomaterials Department, Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine, 17 General Naumov Str., 03164, Kyiv, Ukraine. chemind@ukr.net.
authors.forename: Ievgen V
authors.identifier: http://orcid.org/0000-0001-5467-2839
authors.initials: IV
authors.lastname: Pylypchuk
authors.affiliation: Department of Inorganic Chemistry, Faculty of Chemistry, Maria Curie Skłodowska University, M. Curie Skłodowska Sq. 2, 20-031, Lublin, Poland.
authors.forename: Zbigniew
authors.initials: Z
authors.lastname: Hubicki
keywords: Adsorption; Heavy metals; Kraft lignin; Magnetite; Nanocomposite