title: Gold(I)-Catalyzed Hydroaminaloxylation and Petasis-Ferrier Rearrangement Cascade of Aminaloalkynes.
abstract: An efficient method has been developed to generate a diverse array of indolizidines and quinolizidines from readily available aminaloalkynes via a gold(I)-catalyzed hydroaminaloxylation and Petasis-Ferrier rearrangement cascade. The method enabled a formal synthesis of (±)-antofine.
authors.affiliation: Division of Organic Chemistry, CSIR-National Chemical Laboratory , Dr. Homi Bhabha Road, Pune - 411008, India.|Academy of Scientific and Innovative Research (AcSIR) , New Delhi 110025, India.
authors.forename: Amol B
authors.initials: AB
authors.lastname: Gade
authors.affiliation: Division of Organic Chemistry, CSIR-National Chemical Laboratory , Dr. Homi Bhabha Road, Pune - 411008, India.|Academy of Scientific and Innovative Research (AcSIR) , New Delhi 110025, India.
authors.forename: Nitin T
authors.initials: NT
authors.lastname: Patil
mesh_terms: D000480:Alkynes / Q000737:chemistry; D001669:Biochemical Phenomena; D002384:Catalysis; D006046:Gold / Q000737:chemistry*; D007211:Indoles / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010618:Phenanthrolines / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D000480:Alkynes; D007211:Indoles; D010618:Phenanthrolines; C473343:antofine; D006046:Gold