title: A noble and single source precursor for the synthesis of metal-rich sulphides embedded in an N-doped carbon framework for highly active OER electrocatalysts.
abstract: Here, we demonstrate a green and environment-friendly pyrolysis route for the synthesis of metal-rich sulphide embedded in an N-doped carbon (NC) framework in the absence of sulphide ions (S(2-)). The metal-chelate complex (tris(ethylenediamine) metal(ii) sulfate) serves as a new and single source precursor for the synthesis of earth abundant and non-precious hybrid structures such as metal-rich sulphides Co9S8@NC and Ni3S2@NC when M(II) = Co(2+) and Ni(2+) and counter sulphate (SO4(2-)) ions are the source of S. Both the hybrids show superior OER activity as compared to commercial RuO2.
authors.affiliation: Materials Research Centre, Indian Institute of Science, Bangalore-560012, India. nanda@mrc.iisc.ernet.in barunbarman@mrc.iisc.ernet.in.
authors.forename: Barun Kumar
authors.initials: BK
authors.lastname: Barman
authors.affiliation: Materials Research Centre, Indian Institute of Science, Bangalore-560012, India. nanda@mrc.iisc.ernet.in barunbarman@mrc.iisc.ernet.in.
authors.forename: Karuna Kar
authors.initials: KK
authors.lastname: Nanda