title: Water-Stable Anionic Metal-Organic Framework for Highly Selective Separation of Methane from Natural Gas and Pyrolysis Gas.
abstract: A 3D water-stable anionic metal-organic framework [Zn4(hpdia)2]·[NH2(CH3)2]·3DMF·4H2O (FJI-C4) was constructed based on an elaborate phosphorus-containing ligand 5,5'-(hydroxyphosphoryl)diisophthalic acid (H5hpdia). FJI-C4 with narrow one-dimensional (1D) pore channels exhibits high selectivity of C3H8/CH4 and C2H2/CH4. It is the first time for the MOF which contains phosphorus for selective separation of methane from natural gas and pyrolysis gas.
authors.affiliation: Department of Chemistry, University of Science and Technology of China , Hefei, Anhui 230026, P. R. China.|State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, P. R. China.
authors.forename: Lan
authors.initials: L
authors.lastname: Li
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, P. R. China.
authors.forename: Xusheng
authors.initials: X
authors.lastname: Wang
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, P. R. China.
authors.forename: Jun
authors.initials: J
authors.lastname: Liang
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, P. R. China.
authors.forename: Yuanbiao
authors.initials: Y
authors.lastname: Huang
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, P. R. China.
authors.forename: Hongfang
authors.initials: H
authors.lastname: Li
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, P. R. China.
authors.forename: Zujin
authors.initials: Z
authors.lastname: Lin
authors.affiliation: Department of Chemistry, University of Science and Technology of China , Hefei, Anhui 230026, P. R. China.|State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, P. R. China.
authors.forename: Rong
authors.initials: R
authors.lastname: Cao
keywords: MOFs; adsorption; light hydrocarbons; phosphorus; selectivity; water-stable