title: Safe P₄ reagent in a reusable porous coordination network.
abstract: P4 generated from red phosphorus via the gas phase was trapped into an interactive pore of a porous coordination network, showing weak interactions which stabilize the reactive P4 in a pore. The network is reusable as a safe container of P4. Furthermore, we found a size dependence of the P4 trapping amount: for 100-50 μm crystal, 27% occupancy of P4; and for <20 μm crystal, ca. 93% occupancy of P4.
authors.affiliation: The Division of Advanced Materials Science, Pohang University of Science and Technology (POSTECH), RIST Building 3-3390, 77 Cheongam-Ro, Nam-Gu, Pohang, South Korea. hotsu@postech.ac.kr mkawano@postech.ac.kr.
authors.forename: Wanuk
authors.initials: W
authors.lastname: Choi
authors.affiliation: The Division of Advanced Materials Science, Pohang University of Science and Technology (POSTECH), RIST Building 3-3390, 77 Cheongam-Ro, Nam-Gu, Pohang, South Korea. hotsu@postech.ac.kr mkawano@postech.ac.kr.
authors.forename: Hiroyoshi
authors.initials: H
authors.lastname: Ohtsu
authors.affiliation: Research Network and Facility Services Division, National Institute for Material Science (NIMS), Sengen 1-2-1, Tsukuba, Japan.
authors.forename: Yoshitaka
authors.initials: Y
authors.lastname: Matsushita
authors.affiliation: The Division of Advanced Materials Science, Pohang University of Science and Technology (POSTECH), RIST Building 3-3390, 77 Cheongam-Ro, Nam-Gu, Pohang, South Korea. hotsu@postech.ac.kr mkawano@postech.ac.kr and Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8550, Japan. mkawano@chem.titech.ac.jp.
authors.forename: Masaki
authors.initials: M
authors.lastname: Kawano