title: Construction of Covalent Organic Frameworks Bearing Three Different Kinds of Pores through the Heterostructural Mixed Linker Strategy.
abstract: It is very important to create novel topologies and improve structural complexity for covalent organic frameworks (COFs) that might lead to unprecedented properties and applications. Despite the progress achieved over the past decade, the structural diversity and complexity of COFs are quite limited. In this Communication, we report the construction of COFs bearing three different kinds of pores through the heterostructural mixed linker strategy involving the condensation of a D2h-symmetric tetraamine and two C2-symmetric dialdehydes of different lengths. The complicated structures of the triple-pore COFs have been confirmed by powder X-ray diffraction and pore size distribution analyses.
authors.affiliation: Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Road, Shanghai 200032, China.
authors.forename: Zhong-Fu
authors.initials: ZF
authors.lastname: Pang
authors.affiliation: Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Road, Shanghai 200032, China.
authors.forename: Shun-Qi
authors.initials: SQ
authors.lastname: Xu
authors.affiliation: Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Road, Shanghai 200032, China.
authors.forename: Tian-You
authors.initials: TY
authors.lastname: Zhou
authors.affiliation: Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Road, Shanghai 200032, China.
authors.forename: Rong-Ran
authors.initials: RR
authors.lastname: Liang
authors.affiliation: Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Road, Shanghai 200032, China.
authors.forename: Tian-Guang
authors.initials: TG
authors.lastname: Zhan
authors.affiliation: Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Road, Shanghai 200032, China.
authors.forename: Xin
authors.initials: X
authors.lastname: Zhao