title: Silver-Catalyzed 7-exo-dig Cyclization of Silylenolether-ynesulfonamides.
abstract: Cyclization of silylenolether-ynesulfonamides proceeds at ambient temperature under mild reaction conditions under silver catalysis. Bridged compounds were obtained exclusively through 7-exo-dig reactions. The protocol is applicable to a wide range of substrates, thus leading to azabicyclic frameworks.
authors.affiliation: Laboratoire de Chimie Organique Synthétique, Institut de Chimie, 1, rue Blaise Pascal, BP296/R8, 67008, Strasbourg, France.
authors.forename: Clément F
authors.identifier: http://orcid.org/0000-0003-0500-1734
authors.initials: CF
authors.lastname: Heinrich
authors.affiliation: Département de Chimie, Ecole Normale Supérieure-PSL Research University, Sorbonne Universités-UPMC Univ Paris 06, CNRS UMR 8640 PASTEUR, 24, rue Lhomond, 75005, Paris, France.
authors.forename: Indira
authors.initials: I
authors.lastname: Fabre
authors.affiliation: Laboratoire de Chimie Organique Synthétique, Institut de Chimie, 1, rue Blaise Pascal, BP296/R8, 67008, Strasbourg, France. lmiesch@unistra.fr.
authors.forename: Laurence
authors.identifier: http://orcid.org/0000-0002-0369-9908
authors.initials: L
authors.lastname: Miesch
keywords: cyclizations; heterocycles; silver; structure elucidation; synthetic methods