title: Transparent Films from CO2 -Based Polyunsaturated Poly(ether carbonate)s: A Novel Synthesis Strategy and Fast Curing.
abstract: Transparent films were prepared by cross-linking polyunsaturated poly(ether carbonate)s obtained by the multicomponent polymerization of CO2 , propylene oxide, maleic anhydride, and allyl glycidyl ether. Poly(ether carbonate)s with ABXBA multiblock structures were obtained by sequential addition of mixtures of propylene oxide/maleic anhydride and propylene oxide/allyl glycidyl ether during the polymerization. The simultaneous addition of both monomer mixtures provided poly(ether carbonate)s with AXA triblock structures. Both types of polyunsaturated poly(ether carbonate)s are characterized by diverse functional groups, that is, terminal hydroxy groups, maleate moieties along the polymer backbone, and pendant allyl groups that allow for versatile polymer chemistry. The combination of double bonds substituted with electron-acceptor and electron-donor groups enables particularly facile UV- or redox-initiated free-radical curing. The resulting materials are transparent and highly interesting for coating applications.
authors.affiliation: CAT Catalytic Center, RWTH Aachen University, Worringerweg 2, 52074, Aachen, Germany.
authors.forename: Muhammad Afzal
authors.initials: MA
authors.lastname: Subhani
authors.affiliation: CAT Catalytic Center, RWTH Aachen University, Worringerweg 2, 52074, Aachen, Germany.
authors.forename: Burkhard
authors.initials: B
authors.lastname: Köhler
authors.affiliation: Covestro Deutschland AG, Building B103, Leverkusen, Germany.
authors.forename: Christoph
authors.initials: C
authors.lastname: Gürtler
authors.affiliation: Lehrstuhl für Technische Chemie und Petrolchemie, ITMC, RWTH Aachen University, Worringerweg 2, 52074, Aachen, Germany.
authors.forename: Walter
authors.initials: W
authors.lastname: Leitner
authors.affiliation: CAT Catalytic Center, RWTH Aachen University, Worringerweg 2, 52074, Aachen, Germany. thomas.mueller@catalyticcenter.rwth-aachen.de.|Covestro Deutschland AG, Building B103, Leverkusen, Germany. thomas.mueller@catalyticcenter.rwth-aachen.de.
authors.forename: Thomas E
authors.identifier: 0000-0002-9126-7653
authors.initials: TE
authors.lastname: Müller
keywords: CO2 utilization; copolymerization; multicomponent reactions; poly(ether carbonate); transparent materials