title: Flow-dependent separation selectivity for organic molecules on metal-organic frameworks containing adsorbents.
abstract: A new flow-dependent separation selectivity (FDSS) effect was discovered in isocratic HPLC. Significant changes in chromatographic selectivity were achieved by simple variation of the mobile phase flow rate. The FDSS effect was observed for a core-shell stationary phase using silica particles as a core and a Zr-based metal-organic framework (UiO-66) as a shell.
authors.affiliation: Australian Centre for Research on Separation Science, University of Tasmania, Private Bag 75, Hobart, TAS 7001, Australia. Dario.Arrua@utas.edu.au Dario.Arrua@unisa.edu.au.
authors.forename: Anton
authors.initials: A
authors.lastname: Peristyy
authors.forename: Pavel N
authors.initials: PN
authors.lastname: Nesterenko
authors.forename: Anita
authors.initials: A
authors.lastname: Das
authors.forename: Deanna M
authors.initials: DM
authors.lastname: D'Alessandro
authors.forename: Emily F
authors.initials: EF
authors.lastname: Hilder
authors.forename: R Dario
authors.initials: RD
authors.lastname: Arrua