title: Vanadium Oxyfluoride/Few-Layer Graphene Composite as a High-Performance Cathode Material for Lithium Batteries.
abstract: Metal oxyfluoride compounds are gathering significant interest as cathode materials for lithium ion batteries at the moment because of their high theoretical capacity and resulting high energy density. In this regard, a new and direct approach is presented to synthesize phase-pure vanadium oxyfluoride (VO2F). The structure of VO2F was identified by Rietveld refinement of the powder X-ray diffraction (XRD) pattern. It crystallizes in a perovskite-type structure with disorder of the oxide and fluoride ions. The as-synthesized VO2F was tested as a cathode material for lithium ion batteries after being surface-coated with few-layer graphene. The VO2F delivered a first discharge capacity of 254 mA h g(-1) and a reversible capacity of 208 mA h g(-1) at a rate of C/20 for the first 20 cycles with an average discharge voltage of 2.84 V, yielding an energy density of 591 W h kg(-1). Improved rate capability that outperforms the previous report has been achieved, showing a discharge capacity of 150 mA h g(-1) for 1 C. The structural changes during lithium insertion and extraction were monitored by ex-situ XRD analysis of the electrodes discharged and charged to various stages. Lithium insertion results in an irreversible structural change of the anion lattice from (3)/4 cubic close packing to hexagonal close packing to accommodate the inserted lithium ions while keeping the overall space-group symmetry. For the first time we have revealed a structural change for the ReO3-type structure of as-prepared VO2F to the RhF3 structure after lithiation/delithiation, with structural changes that have not been observed in previous reports. Furthermore, the new synthetic approach described here would be a platform for the synthesis of new oxyfluoride compounds.
authors.affiliation: Helmholtz Institute Ulm for Electrochemical Energy Storage (HIU) , Helmholtzstr. 11, 89081 Ulm, Germany.
authors.forename: Musa Ali
authors.initials: MA
authors.lastname: Cambaz
authors.affiliation: Helmholtz Institute Ulm for Electrochemical Energy Storage (HIU) , Helmholtzstr. 11, 89081 Ulm, Germany.
authors.forename: B P
authors.initials: BP
authors.lastname: Vinayan
authors.affiliation: Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT) , P.O. Box 3640, 76021 Karlsruhe, Germany.|Joint Research Laboratory Nanomaterials, Technische Universität Darmstadt , Jovanka-Bontschits-Straße 2, 64287 Darmstadt, Germany.
authors.forename: Oliver
authors.initials: O
authors.lastname: Clemens
authors.affiliation: Helmholtz Institute Ulm for Electrochemical Energy Storage (HIU) , Helmholtzstr. 11, 89081 Ulm, Germany.
authors.forename: Anji Reddy
authors.initials: AR
authors.lastname: Munnangi
authors.affiliation: Helmholtz Institute Ulm for Electrochemical Energy Storage (HIU) , Helmholtzstr. 11, 89081 Ulm, Germany.
authors.forename: Venkata Sai Kiran
authors.initials: VS
authors.lastname: Chakravadhanula
authors.affiliation: Helmholtz Institute Ulm for Electrochemical Energy Storage (HIU) , Helmholtzstr. 11, 89081 Ulm, Germany.|Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT) , P.O. Box 3640, 76021 Karlsruhe, Germany.
authors.forename: Christian
authors.initials: C
authors.lastname: Kübel
authors.affiliation: Helmholtz Institute Ulm for Electrochemical Energy Storage (HIU) , Helmholtzstr. 11, 89081 Ulm, Germany.|Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT) , P.O. Box 3640, 76021 Karlsruhe, Germany.
authors.forename: Maximilian
authors.initials: M
authors.lastname: Fichtner