title: Studies toward the synthesis of linear triazole linked pseudo oligosaccharides and the use of ferrocene as analytical probe.
abstract: Three different building blocks have been synthesised and used for the synthesis of linear triazole linked pseudo oligosaccharides with copper(I)-catalysed cycloaddition (CuAAC). Ethynylferrocene has been used as analytical probe to improve the UV/Vis properties and HPLC methods have been used and optimised for the analysis of the pseudo oligosaccharides. The smallest ones have been isolated and characterised by analytical HPLC, NMR, ESI-MS and elemental analysis.
authors.affiliation: MCAT GmbH, Hermann-von-Vicari-Str. 23, 78464 Konstanz, Germany. Electronic address: schmidt@mcat.de.
authors.forename: Magnus S
authors.initials: MS
authors.lastname: Schmidt
authors.affiliation: Department of Chemistry, University of Konstanz, Konstanz, Germany.
authors.forename: Kathrin H
authors.initials: KH
authors.lastname: Götz
authors.affiliation: Department of Chemistry, University of Konstanz, Konstanz, Germany.
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Koch
authors.affiliation: Department of Chemistry, University of Konstanz, Konstanz, Germany.
authors.forename: Tanja
authors.initials: T
authors.lastname: Grimm
authors.affiliation: MCAT GmbH, Hermann-von-Vicari-Str. 23, 78464 Konstanz, Germany.
authors.forename: Markus
authors.initials: M
authors.lastname: Ringwald
mesh_terms: D005296:Ferrous Compounds / Q000737:chemistry*; D008968:Molecular Conformation; D015335:Molecular Probes / Q000737:chemistry*; D009844:Oligosaccharides / Q000032:analysis* / Q000138:chemical synthesis* / Q000737:chemistry; D014230:Triazoles / Q000737:chemistry*
chemical_list: D005296:Ferrous Compounds; D015335:Molecular Probes; D009844:Oligosaccharides; D014230:Triazoles; C480779:ethynylferrocene
keywords: Carbohydrates; Click chemistry; Ferrocene; Glycoconjugates; Triazoles, oligosaccharides