title: Ferromagnetic ordering of -[Sm(iii)-radical]n- coordination polymers.
abstract: [Sm(hfac)3(boaDTDA)]n is the first coordination compound of a thiazyl-based neutral radical ligand to exhibit ferromagnetic ordering; TC = 3 K. The [Sm(iii)-radical]n species is soluble in common organic solvents and can be sublimed quantitatively. A McConnell I mechanism is implicated in local exchange pathways that contribute to cooperative magnetic properties.
authors.affiliation: Department of Chemistry, University of Guelph, Guelph, Ontario N1G 2W1, Canada. kpreuss@uoguelph.ca.
authors.forename: Elisabeth M
authors.initials: EM
authors.lastname: Fatila
authors.affiliation: Department of Chemistry, University of Guelph, Guelph, Ontario N1G 2W1, Canada. kpreuss@uoguelph.ca.
authors.forename: Adam C
authors.initials: AC
authors.lastname: Maahs
authors.affiliation: Department of Chemistry, University of Guelph, Guelph, Ontario N1G 2W1, Canada. kpreuss@uoguelph.ca.
authors.forename: Michelle B
authors.initials: MB
authors.lastname: Mills
authors.affiliation: CNRS, CRPP, UPR 8641, F-33600 Pessac, France. clerac@crpp-bordeaux.cnrs.fr and Univ. Bordeaux, CRPP, UPR 8641, F-33600 Pessac, France.
authors.forename: Mathieu
authors.initials: M
authors.lastname: Rouzières
authors.affiliation: Department of Chemistry, University of Guelph, Guelph, Ontario N1G 2W1, Canada. kpreuss@uoguelph.ca.
authors.forename: Dmitriy V
authors.initials: DV
authors.lastname: Soldatov
authors.affiliation: CNRS, CRPP, UPR 8641, F-33600 Pessac, France. clerac@crpp-bordeaux.cnrs.fr and Univ. Bordeaux, CRPP, UPR 8641, F-33600 Pessac, France.
authors.forename: Rodolphe
authors.initials: R
authors.lastname: Clérac
authors.affiliation: Department of Chemistry, University of Guelph, Guelph, Ontario N1G 2W1, Canada. kpreuss@uoguelph.ca.
authors.forename: Kathryn E
authors.initials: KE
authors.lastname: Preuss