title: Chemical state determination of molecular gallium compounds using XPS.
abstract: A series of molecular gallium compounds were analyzed using X-ray photoelectron spectroscopy (XPS). Specifically, the Ga 2p3/2 and Ga 3d5/2 photoelectron binding energies and the Ga L3M45M45 Auger electron kinetic energies of compounds with gallium in a range of assigned oxidation numbers and with different stabilizing ligands were measured. Auger parameters were calculated and used to generate multiple chemical speciation (or Wagner) plots that were subsequently used to characterize the novel gallium-cryptand[2.2.2] complexes that possess ambiguous oxidation numbers for gallium. The results presented demonstrate the ability of widely accessible XPS instruments to experimentally determine the chemical state of gallium centers and, as a consequence, provide deeper insights into reactivity compared to assigned oxidation and valence numbers.
authors.affiliation: Department of Chemistry, University of Western Ontario, London, Ontario, CanadaN6A 5B7. kbaines2@uwo.ca.
authors.forename: Jeremy L
authors.initials: JL
authors.lastname: Bourque
authors.affiliation: Surface Science Western, University of Western Ontario, London, Ontario, CanadaN6G 0J3.
authors.forename: Mark C
authors.initials: MC
authors.lastname: Biesinger
authors.affiliation: Department of Chemistry, University of Western Ontario, London, Ontario, CanadaN6A 5B7. kbaines2@uwo.ca.
authors.forename: Kim M
authors.initials: KM
authors.lastname: Baines