title: Assessment of dynamic surface leaching of monolithic surface road materials.
abstract: Construction materials have to satisfy, among others, health and environment requirements. To check the environmental compatibility of road construction materials, release of hazardous substances into water must be assessed. Literature mostly describes the leaching behaviour of recycled aggregates for potential use in base or sub-base layers of roads. But little is known about the release of soluble substances by materials mixed with binders and compacted for intended use on road surface. In the present study, we thus performed a diffusion test with sequential renewal of water during a 64 day period according to CEN/TS 16637-2 specifications, on asphalt concretes and hydraulically bound monoliths, two common surface road materials. It is shown that release of dangerous substances is limited in these hydrodynamic conditions. It was particularly true for asphalt concrete leachates where no metallic trace element, sulphate, chloride or fluoride ion could be quantified. This is because of the low hydraulic conductivity and the low polarity of the petroleum hydrocarbon binder of these specimens. For hydraulically bound materials around 20,000 mg/m(2) of sulphate diffused from the monoliths. It is one order of magnitude higher than chloride diffusion and two orders of magnitude higher than fluoride release. No metallic trace element, except small quantities of copper in the last eluate could be quantified. No adverse effect is to be expected for human and environmental health from the leachates of these compacted surface road construction materials, because all the measured parameters were below EU (Council Directive 98/83/EC) or WHO guidelines for drinking water standards.
authors.affiliation: Ecole Supérieure d'Ingénieurs des Travaux de la Construction, 28 Avenue du Président Wilson, 94234 Cachan, France. Electronic address: paulus@esitc-cachan.fr.
authors.forename: Hélène
authors.initials: H
authors.lastname: Paulus
authors.affiliation: Ecole Supérieure d'Ingénieurs des Travaux de la Construction, 28 Avenue du Président Wilson, 94234 Cachan, France.
authors.forename: Joachim
authors.initials: J
authors.lastname: Schick
authors.affiliation: COLAS, Campus Scientifique et Technique, 4 rue Jean Mermoz, 78772 Magny les Hameaux, France. Electronic address: poirier@campus.colas.fr.
authors.forename: Jean-Eric
authors.initials: JE
authors.lastname: Poirier
mesh_terms: D002244:Carbon / Q000737:chemistry; D002712:Chlorides / Q000032:analysis / Q000633:toxicity; D003252:Construction Materials / Q000032:analysis*; D003300:Copper / Q000032:analysis; D004058:Diffusion; D004784:Environmental Monitoring; D004785:Environmental Pollutants / Q000032:analysis / Q000633:toxicity; D005459:Fluorides / Q000032:analysis / Q000633:toxicity; D006838:Hydrocarbons / Q000032:analysis*; D006863:Hydrogen-Ion Concentration; D010578:Petroleum / Q000032:analysis; D013431:Sulfates / Q000032:analysis / Q000633:toxicity; D013499:Surface Properties
chemical_list: D002712:Chlorides; D004785:Environmental Pollutants; D006838:Hydrocarbons; D010578:Petroleum; D013431:Sulfates; D002244:Carbon; D003300:Copper; C006647:asphalt; D005459:Fluorides
keywords: Asphalt pavement; Concrete pavement; Dangerous substances; Diffusion test; Water