title: Intermolecular Three-Component Arylsilylation of Alkynes under Palladium/Copper Cooperative Catalysis.
abstract: An intermolecular three-component arylsilylation of alkynes has been developed under mild palladium/copper cooperative catalysis. The reaction proceeds through syn-addition of an aryl group and a silyl group across the carbon-carbon triple bond of an alkyne. This represents the first transition-metal-catalyzed fully intermolecular arylsilylation of alkynes, and transformations of the resulting products have also been demonstrated.
authors.affiliation: Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
authors.forename: Ryo
authors.initials: R
authors.lastname: Shintani
authors.affiliation: Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
authors.forename: Hiroki
authors.initials: H
authors.lastname: Kurata
authors.affiliation: Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
authors.forename: Kyoko
authors.initials: K
authors.lastname: Nozaki