title: Selection of oxidant doses for in situ chemical oxidation of soils contaminated by polycyclic aromatic hydrocarbons (PAHs): A review.
abstract: In situ chemical oxidation (ISCO) is a promising alternative to thermal desorption for the remediation of soils contaminated with organic compounds such as polycyclic aromatic hydrocarbons (PAHs). For field application, one major issue is the selection of the optimal doses of the oxidizing solution, i.e. the oxidant and appropriate catalysts and/or additives. Despite an extensive scientific literature on ISCO, this choice is very difficult because many parameters differ from one study to another. The present review identifies the critical factors that must be taken into account to enable comparison of these various contributions. For example, spiked soils and aged, polluted soils cannot be compared; PAHs freshly spiked into a soil are fully available for degradation unlike a complex mixture of pollutants trapped in a soil for many years. Another notable example is the high diversity of oxidation conditions employed during batch experiments, although these affect the representativeness of the system. Finally, in this review a methodology is also proposed based on a combination of the stoichiometric oxidant demand of the organic pollutants and the design of experiments (DOE) in order to allow a better comparison of the various studies so far reported.
authors.affiliation: Université de Lorraine, Laboratoire Interdisciplinaire des Environnements Continentaux, UMR 7360, Site Aiguillette, 54506 Vandœuvre-lès-Nancy cedex, France; CNRS, Laboratoire Interdisciplinaire des Environnements Continentaux, UMR 7360, Site Aiguillettes, 54506 Vandœuvre-lès-Nancy cedex, France; ICF Environnement, 14 à 30 rue Alexandre, 92635 Gennevilliers, France; Université de Lorraine, Laboratoire Réactions et Génie des Procédés, UMR 7274, 1 rue Grandville, 54001 Nancy cedex, France; CNRS, Laboratoire Réactions et Génie des Procédés, UMR 7274, 1 rue Grandville, 54001 Nancy cedex, France.
authors.forename: B
authors.initials: B
authors.lastname: Ranc
authors.affiliation: Université de Lorraine, Laboratoire Interdisciplinaire des Environnements Continentaux, UMR 7360, Site Aiguillette, 54506 Vandœuvre-lès-Nancy cedex, France; CNRS, Laboratoire Interdisciplinaire des Environnements Continentaux, UMR 7360, Site Aiguillettes, 54506 Vandœuvre-lès-Nancy cedex, France.
authors.forename: P
authors.initials: P
authors.lastname: Faure
authors.affiliation: ICF Environnement, 14 à 30 rue Alexandre, 92635 Gennevilliers, France.
authors.forename: V
authors.initials: V
authors.lastname: Croze
authors.affiliation: Université de Lorraine, Laboratoire Réactions et Génie des Procédés, UMR 7274, 1 rue Grandville, 54001 Nancy cedex, France; CNRS, Laboratoire Réactions et Génie des Procédés, UMR 7274, 1 rue Grandville, 54001 Nancy cedex, France. Electronic address: marie-odile.simonnot@univ-lorraine.fr.
authors.forename: M O
authors.initials: MO
authors.lastname: Simonnot
keywords: Design of experiments (DOE); In situ chemical oxidation (ISCO); Oxidant dose; PAH-contaminated soil; Stoichiometric oxidant demand