title: New sandwich-type lanthanide complexes based on closed-macrocyclic Schiff base and phthalocyanine molecules.
abstract: Two new sandwich-type lanthanide complexes with the general formula [(Pc)2Ln3(L)(OAc)(OCH3)2] (Ln(3+) = Dy(3+) () and Er(3+) ()) were successfully synthesized and structurally characterized based on closed-macrocyclic Schiff base and phthalocyanine molecules. The magnetic properties and structure-property relationship in this multi-decker system were investigated. Interestingly, the corresponding dysprosium complex shows typical single-molecule magnetic behavior with ferromagnetic dipole-dipole interactions and the slow relaxation of magnetization.
authors.affiliation: School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou 221116, P. R. China. gaofeng_xz2002@163.com.
authors.forename: Feng
authors.initials: F
authors.lastname: Gao
authors.affiliation: School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou 221116, P. R. China. gaofeng_xz2002@163.com.
authors.forename: Xiaowan
authors.initials: X
authors.lastname: Feng
authors.affiliation: School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou 221116, P. R. China. gaofeng_xz2002@163.com.
authors.forename: Liu
authors.initials: L
authors.lastname: Yang
authors.affiliation: School of Safety, China University of Mining and Technology, Xuzhou 221116, P. R. China. drizzle13xy@126.com.
authors.forename: Xiaoyu
authors.initials: X
authors.lastname: Chen