title: Phenyliodonium Diacetate Mediated Oxidative Functionalization of Styrenes with Molecular Oxygen: Synthesis of α-Oxygenated Ketones.
abstract: Synthesis of α-oxygenated ketones from styrenes mediated by phenyliodonium diacetate in the presence of molecular oxygen and N-hydroxyphthalimide or N-hydroxybenzotriazole has been described. Addition of carbonyl oxygen at the α-position and formation of C-O bond at the β-position of styrenes was achieved under metal-free conditions. The present method is applicable for wide range of styrenes with a variety of functional groups.
authors.affiliation: Academy of Scientific & Innovative Research, CSIR-Central Salt & Marine Chemicals Research Institute , G.B. Marg, Bhavnagar 364 002. Gujarat, India.
authors.forename: Supravat
authors.initials: S
authors.lastname: Samanta
authors.affiliation: Academy of Scientific & Innovative Research, CSIR-Central Salt & Marine Chemicals Research Institute , G.B. Marg, Bhavnagar 364 002. Gujarat, India.
authors.forename: Ramachandra Reddy
authors.initials: RR
authors.lastname: Donthiri
authors.affiliation: Academy of Scientific & Innovative Research, CSIR-Central Salt & Marine Chemicals Research Institute , G.B. Marg, Bhavnagar 364 002. Gujarat, India.
authors.forename: Chitrakar
authors.initials: C
authors.lastname: Ravi
authors.affiliation: Academy of Scientific & Innovative Research, CSIR-Central Salt & Marine Chemicals Research Institute , G.B. Marg, Bhavnagar 364 002. Gujarat, India.
authors.forename: Subbarayappa
authors.initials: S
authors.lastname: Adimurthy