title: Correlations between thixotropic and structural properties of molecular gels with crystalline networks.
abstract: This review focuses on correlations between the thixotropic and structural properties of molecular gels having crystalline fibrillar networks (SAFINs). Formation of thixotropic molecular gels and their recovery after the application of destructive strain depends on the strength and type of intermolecular interactions in the SAFINs of the gelator molecules. Here, we limit our discussion to gelator molecules with simple structures in order to dissect more easily the important contributors to the thixotropic behaviors. Possible mechanisms to explain the thixotropic phenomena, involving the transformation of the SAFINs into unattached objects, and their reassembly into 3-dimensional networks, are advanced. The data are analyzed to provide insights into the rational design of thixotropic molecular gelators.
authors.affiliation: Department of Chemistry, Georgetown University, Washington DC 20057-1227, USA. weissr@georgetown.edu.
authors.forename: V
authors.initials: V
authors.lastname: Ajay Mallia
authors.affiliation: Department of Chemistry, Georgetown University, Washington DC 20057-1227, USA. weissr@georgetown.edu and Institute for Soft Matter Synthesis and Metrology, Georgetown University, Washington DC 20057-1227, USA.
authors.forename: Richard G
authors.initials: RG
authors.lastname: Weiss