title: Pt(ii) coordination complexes as visible light photocatalysts for the oxidation of sulfides using batch and flow processes.
abstract: A new catalytic system for the photooxidation of sulfides based on Pt(ii) complexes is presented. The catalyst is capable of oxidizing a large number of sulfides containing aryl, alkyl, allyl, benzyl, as well as more complex structures such as heterocycles and methionine amino acid, with complete chemoselectivity. In addition, the first sulfur oxidation in a continuous flow process has been developed.
authors.affiliation: Departamento de Química Inorgánica (Módulo 7), Facultad de Ciencias, Universidad Autónoma de Madrid, 28049-Madrid, Spain. silvia.cabrera@uam.es.
authors.forename: Antonio
authors.initials: A
authors.lastname: Casado-Sánchez
authors.affiliation: Departamento de Química Orgánica (Módulo 1), Facultad de Ciencias, Universidad Autónoma de Madrid, 28049-Madrid, Spain. jose.aleman@uam.es.
authors.forename: Rocío
authors.initials: R
authors.lastname: Gómez-Ballesteros
authors.affiliation: Synthelia Organics Labs, C/Faraday 7. Labs 2.05 and 0.03, Parque Científico de Madrid, 28049 Madrid, Spain.
authors.forename: Francisco
authors.initials: F
authors.lastname: Tato
authors.affiliation: Synthelia Organics Labs, C/Faraday 7. Labs 2.05 and 0.03, Parque Científico de Madrid, 28049 Madrid, Spain.
authors.forename: Francisco J
authors.initials: FJ
authors.lastname: Soriano
authors.affiliation: Synthelia Organics Labs, C/Faraday 7. Labs 2.05 and 0.03, Parque Científico de Madrid, 28049 Madrid, Spain.
authors.forename: Gustavo
authors.initials: G
authors.lastname: Pascual-Coca
authors.affiliation: Departamento de Química Inorgánica (Módulo 7), Facultad de Ciencias, Universidad Autónoma de Madrid, 28049-Madrid, Spain. silvia.cabrera@uam.es.
authors.forename: Silvia
authors.initials: S
authors.lastname: Cabrera
authors.affiliation: Departamento de Química Orgánica (Módulo 1), Facultad de Ciencias, Universidad Autónoma de Madrid, 28049-Madrid, Spain. jose.aleman@uam.es.
authors.forename: José
authors.initials: J
authors.lastname: Alemán