title: Synthesis of the C1-C10 Fragment of Madeirolide A.
abstract: The synthesis of a fully elaborated C1-C10 fragment of madeirolide A has been achieved via a strategy based on a series of stereospecific processes. The concise synthetic route also features an iridium-catalyzed visible light induced radical cyclization for construction of the THP ring and a palladium-catalyzed glycosylation for formation of the α-cineruloside linkage.
authors.affiliation: Department of Chemistry, Seoul National University , Seoul 08826, Republic of Korea.
authors.forename: Sunghyun
authors.initials: S
authors.lastname: Hwang
authors.affiliation: Department of Chemistry, Seoul National University , Seoul 08826, Republic of Korea.
authors.forename: Inhwan
authors.initials: I
authors.lastname: Baek
authors.affiliation: Department of Chemistry, Seoul National University , Seoul 08826, Republic of Korea.
authors.forename: Chulbom
authors.initials: C
authors.lastname: Lee