title: Iron-Catalyzed Stereoselective Cross-Coupling Reactions of Stereodefined Enol Carbamates with Grignard Reagents.
abstract: A practical and highly stereoselective iron-catalyzed cross-coupling reaction of stereodefined enol carbamates and Grignard reagents to yield tri- and tetrasubstituted acrylates is reported. A facile method for the stereoselective generation of these enol carbamates has also been developed.
authors.affiliation: Department of Chemistry, The University of Texas at San Antonio, San Antonio, TX, 78249, USA.
authors.forename: Ana Cristina Parra
authors.initials: AC
authors.lastname: Rivera
authors.affiliation: Department of Chemistry, The University of Texas at San Antonio, San Antonio, TX, 78249, USA.
authors.forename: Raymond
authors.initials: R
authors.lastname: Still
authors.affiliation: Department of Chemistry, The University of Texas at San Antonio, San Antonio, TX, 78249, USA. doug.frantz@utsa.edu.
authors.forename: Doug E
authors.identifier: 0000-0002-4509-4579
authors.initials: DE
authors.lastname: Frantz
mesh_terms: D000179:Acrylates / Q000737:chemistry; D002219:Carbamates / Q000737:chemistry*; D002384:Catalysis; D007501:Iron / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D013237:Stereoisomerism
chemical_list: D000179:Acrylates; D002219:Carbamates; D007501:Iron
keywords: acrylates; cross-coupling; enol carbamates; iron catalysis; stereoselective synthesis