title: Rate-dependent interface capture beyond the coffee-ring effect.
abstract: The mechanism of droplet drying is a widely concerned fundamental issue since controlling the deposition morphology of droplet has significant influence on printing, biology pattern, self-assembling and other solution-based devices fabrication. Here we reveal a striking different kinetics-controlled deposition regime beyond the ubiquitous coffee-ring effect that suspended particles tend to kinetically accumulate at the air-liquid interface and deposit uniformly. As the interface shrinkage rate exceeds the particle average diffusion rate, particles in vertical evaporation flow will be captured by the descending surface, producing surface particle jam and forming viscous quasi-solid layer, which dramatically prevents the trapped particles from being transported to drop edge and results in uniform deposition. This simple, robust drying regime will provide a versatile strategy to control the droplet deposition morphology, and a novel direction of interface assembling for fabricating superlattices and high quality photonic crystal patterns.
authors.affiliation: Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences (ICCAS), Beijing Engineering Research Center of Nanomaterials for Green Printing Technology, Beijing National Laboratory for Molecular Sciences (BNLMS), Beijing, 100190, P. R. China.|University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.
authors.forename: Yanan
authors.initials: Y
authors.lastname: Li
authors.affiliation: Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences (ICCAS), Beijing Engineering Research Center of Nanomaterials for Green Printing Technology, Beijing National Laboratory for Molecular Sciences (BNLMS), Beijing, 100190, P. R. China.|University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.
authors.forename: Qiang
authors.initials: Q
authors.lastname: Yang
authors.affiliation: Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences (ICCAS), Beijing Engineering Research Center of Nanomaterials for Green Printing Technology, Beijing National Laboratory for Molecular Sciences (BNLMS), Beijing, 100190, P. R. China.
authors.forename: Mingzhu
authors.initials: M
authors.lastname: Li
authors.affiliation: Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences (ICCAS), Beijing Engineering Research Center of Nanomaterials for Green Printing Technology, Beijing National Laboratory for Molecular Sciences (BNLMS), Beijing, 100190, P. R. China.
authors.forename: Yanlin
authors.initials: Y
authors.lastname: Song