title: Weakly Polar Aprotic Ionic Liquids Acting as Strong Dissociating Solvent: A Typical "Ionic Liquid Effect" Revealed by Accurate Measurement of Absolute pKa of Ylide Precursor Salts.
abstract: Absolute pKas of selected salts with different counter-anions were measured with high precision in four aprotic ionic liquids (AILs), which enables a detailed examination of solvation effect of ILs on salts. Interestingly, the counter-anions of the ylide precursor salts, protic amine, and phenol salts of this study, though differing dramatically in size and electron dispersion, were found to have no effect on the respective pKas of the substrates. This indicates that the ionic species generated upon acidic dissociation of the salts in weakly polar AILs of low dielectric constant (ε: 10-15) are not ion-paired, or in other words, behave like "free ions" as if in strongly dissociating molecular solvents of high polarity (e.g., DMSO). This suggests that the widely assumed ion-pairing phenomenon, an issue of much debate, is not important in the AILs under our experimental conditions, presenting a typical "ionic-liquid effect" on the solvation of charged species in AILs.
authors.affiliation: Center of Basic Molecular Science (CBMS), Department of Chemistry, Tsinghua University , Beijing 100084, China.
authors.forename: Chong
authors.initials: C
authors.lastname: Mao
authors.affiliation: State Key Laboratory of Elemento-organic Chemistry, Collaborative Innovation Centre of Chemical Science and Engineering, Nankai University , Tianjin 300071, China.
authors.forename: Zedong
authors.initials: Z
authors.lastname: Wang
authors.affiliation: Center of Basic Molecular Science (CBMS), Department of Chemistry, Tsinghua University , Beijing 100084, China.
authors.forename: Zhen
authors.initials: Z
authors.lastname: Wang
authors.affiliation: Center of Basic Molecular Science (CBMS), Department of Chemistry, Tsinghua University , Beijing 100084, China.
authors.forename: Pengju
authors.initials: P
authors.lastname: Ji
authors.affiliation: Center of Basic Molecular Science (CBMS), Department of Chemistry, Tsinghua University , Beijing 100084, China.|State Key Laboratory of Elemento-organic Chemistry, Collaborative Innovation Centre of Chemical Science and Engineering, Nankai University , Tianjin 300071, China.
authors.forename: Jin-Pei
authors.initials: JP
authors.lastname: Cheng