title: Enhanced adsorption of Cr(VI) from water by guar gum based composite hydrogels.
abstract: Composite hydrogels were prepared by in situ incorporation of a natural macromolecule guar gum and nano sized bentonite clay in an acrylic network during copolymerization of acrylic acid, N,N-methylenebisacrylamide (MBA) and hydroxyethyl methacrlylate (HEMA) in water. The structure of the hydrogels was characterized and the hydrogels showing the best results in mechanical and swelling properties were used for the removal of low (5-50mg/L) and high (100-800mg/L) concentration of Cr(VI) ions from water. The composite hydrogel showed a high removal of 97.8% (4.89mg/g gel) and 91.4% (182.4mg/g gel) at an initial feed metal ion concentration of 5mg/L and 200mg/L, respectively.
authors.affiliation: Department of Polymer Science and Technology, University of Calcutta, 92, A.P.C, Road, Kolkata, 700009, India.
authors.forename: Jayabrata
authors.initials: J
authors.lastname: Maity
authors.affiliation: Department of Polymer Science and Technology, University of Calcutta, 92, A.P.C, Road, Kolkata, 700009, India. Electronic address: samitcu2@yahoo.co.in.
authors.forename: Samit Kumar
authors.initials: SK
authors.lastname: Ray
mesh_terms: D000178:Acrylamides / Q000737:chemistry; D000179:Acrylates / Q000737:chemistry; D000327:Adsorption; D001546:Bentonite / Q000737:chemistry; D002857:Chromium / Q000302:isolation & purification*; D005685:Galactans / Q000737:chemistry*; D006801:Humans; D020100:Hydrogels / Q000737:chemistry*; D007700:Kinetics; D008351:Mannans / Q000737:chemistry*; D008689:Methacrylates / Q000737:chemistry; D053761:Nanocomposites / Q000737:chemistry* / Q000648:ultrastructure; D053149:Plant Gums / Q000737:chemistry*; D062065:Wastewater / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods
chemical_list: D000178:Acrylamides; D000179:Acrylates; D001546:Bentonite; D002857:Chromium; D005685:Galactans; D020100:Hydrogels; D008351:Mannans; D008689:Methacrylates; D053149:Plant Gums; D062065:Wastewater; D014874:Water Pollutants, Chemical; C005044:hydroxyethyl methacrylate; C007894:guar gum; C021221:N,N'-methylenebisacrylamide; C036658:acrylic acid
keywords: Composite gel; Cr(VI) adsorption; Guar gum