title: Sorption of the herbicides diquat and difenzoquat from aqueous medium by polymeric resins in the presence of sodium dodecylsulfate: Kinetic and mechanistic study.
abstract: The goal of this work was to propose a novel method for the solid-phase extraction of the herbicides diquat (DQT(2+)) and difenzoquat (DFQT(+)) from aqueous medium using polymeric Amberlite XAD-2 and XAD-4 resins in the presence of sodium dodecylsulfate (SDS). The addition of SDS to the medium was of fundamental importance in order to allow the formation of a negatively charged surface able to sorb the cationic solutes. Several factors that could influence the sorption process, such as SDS concentration in the medium, sorbent mass, pH, ionic strength, and initial concentration of the solutes were investigated. Kinetic studies were also performed to model the system and to identify the mechanisms that operate the sorption process of the herbicides. SDS concentration in the medium presented remarkable influence on the extraction efficiency, achieving maximum values when the ratios [SDS]/[herbicide] were approximately 90, for XAD-2, and 22 and 11 for DQT(2+) and DFQT(+), respectively, for XAD-4. The sorption process followed a pseudo second-order kinetic in all cases studied. It was also found that an intraparticle diffusion process controlled exclusively the sorption of the herbicides by the Amberlite XAD-2 and XAD-4 resins in the first 15 min, becoming less active with time.
authors.affiliation: a Department of Analytical Chemistry , Fluminense Federal University , Niterói/RJ , Brazil.|b Department of Chemistry , Federal University of Viçosa , Viçosa/MG , Brazil.
authors.forename: Jonas O
authors.initials: JO
authors.lastname: Vinhal
authors.affiliation: b Department of Chemistry , Federal University of Viçosa , Viçosa/MG , Brazil.
authors.forename: Claudio F
authors.initials: CF
authors.lastname: Lima
authors.affiliation: a Department of Analytical Chemistry , Fluminense Federal University , Niterói/RJ , Brazil.
authors.forename: Ricardo J
authors.initials: RJ
authors.lastname: Cassella
mesh_terms: D000327:Adsorption; D004178:Diquat / Q000737:chemistry*; D052918:Environmental Restoration and Remediation / Q000379:methods*; D006540:Herbicides / Q000737:chemistry*; D007700:Kinetics; D011137:Polystyrenes / Q000737:chemistry*; D011145:Polyvinyls / Q000737:chemistry; D011720:Pyrazoles / Q000737:chemistry*; D012967:Sodium Dodecyl Sulfate / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000737:chemistry*
chemical_list: D006540:Herbicides; D011137:Polystyrenes; D011145:Polyvinyls; D011720:Pyrazoles; D014874:Water Pollutants, Chemical; D012967:Sodium Dodecyl Sulfate; C012101:XAD-4 resin; C031394:difenzoquat; C003771:Amberlite XAD-2 resin; D004178:Diquat
keywords: Diquat; difenzoquat; polymeric resins; sorption