title: Thermochemical valorization and characterization of household biowaste.
abstract: Valorization of municipal solid waste (MSW), by means of energy and material recovery, is considered to be a crucial step for sustainable waste management. A significant fraction of MSW is comprised from food waste, the treatment of which is still a challenge. Therefore, the conventional disposal of food waste in landfills is being gradually replaced by recycling aerobic treatment, anaerobic digestion and waste-to-energy. In principle, thermal processes like combustion and gasification are preferred for the recovery of energy due to the higher electrical efficiency and the significantly less time required for the process to be completed when compared to biological process, i.e. composting, anaerobic digestion and transesterification. Nonetheless, the high water content and the molecular structure of biowaste are constraining factors in regard to the application of thermal conversion pathways. Investigating alternative solutions for the pre-treatment and more energy efficient handling of this waste fraction may provide pathways for the optimization of the whole process. In this study, by means of utilizing drying/milling as an intermediate step, thermal treatment of household biowaste has become possible. Household biowaste has been thermally processed in a bench scale reactor by means of torrefaction, carbonization and high temperature pyrolysis. According to the operational conditions, fluctuating fractions of biochar, bio-oil (tar) and syngas were recovered. The thermochemical properties of the feedstock and products were analyzed by means of Simultaneous Thermal Analysis (STA), Ultimate and Proximate analysis and Attenuated Total Reflectance (ATR). The analysis of the products shows that torrefaction of dried household biowaste produces an energy dense fuel and high temperature pyrolysis produces a graphite-like material with relatively high yield.
authors.affiliation: Free University of Bolzano, Faculty of Science and Technology, Piazza Università 5, 39100 Bolzano, Italy. Electronic address: stergios.vakalis@outlook.com.
authors.forename: S
authors.initials: S
authors.lastname: Vakalis
authors.affiliation: National Technical University of Athens, School of Chemical Engineering, Unit of Environmental Science & Technology, 9 Iroon Polytechniou Str., Zographou Campus, GR-15780 Athens, Greece. Electronic address: angeluoi81@gmail.com.
authors.forename: A
authors.initials: A
authors.lastname: Sotiropoulos
authors.affiliation: National Technical University of Athens, School of Chemical Engineering, Unit of Environmental Science & Technology, 9 Iroon Polytechniou Str., Zographou Campus, GR-15780 Athens, Greece. Electronic address: konmoust@central.ntua.gr.
authors.forename: K
authors.initials: K
authors.lastname: Moustakas
authors.affiliation: National Technical University of Athens, School of Chemical Engineering, Unit of Environmental Science & Technology, 9 Iroon Polytechniou Str., Zographou Campus, GR-15780 Athens, Greece. Electronic address: malamis.dimitris@gmail.com.
authors.forename: D
authors.initials: D
authors.lastname: Malamis
authors.affiliation: EcoVRS, Vekkos Recycling Solutions, Sokratous 1, Melissia, GR-15127 Athens, Greece. Electronic address: info@ecovrs.com.
authors.forename: K
authors.initials: K
authors.lastname: Vekkos
authors.affiliation: Free University of Bolzano, Faculty of Science and Technology, Piazza Università 5, 39100 Bolzano, Italy. Electronic address: marco.baratieri@unibz.it.
authors.forename: M
authors.initials: M
authors.lastname: Baratieri
mesh_terms: D005191:Family Characteristics; D006358:Hot Temperature; D059027:Recycling; D012037:Refuse Disposal; D062611:Solid Waste; D018505:Waste Management
chemical_list: D062611:Solid Waste
keywords: Biowaste; Carbonization; Heavy metals; Thermal analysis; Torrefaction; Waste-to-energy