title: Numerical simulation of electrochemical desalination.
abstract: We present an effective numerical approach to simulate electrochemically mediated desalination of seawater. This new membraneless, energy efficient desalination method relies on the oxidation of chloride ions, which generates an ion depletion zone and local electric field gradient near the junction of a microchannel branch to redirect sea salt into the brine stream, consequently producing desalted water. The proposed numerical model is based on resolution of the 3D coupled Navier-Stokes, Nernst-Planck, and Poisson equations at non-uniform spatial grids. The model is implemented as a parallel code and can be employed to simulate mass-charge transport coupled with surface or volume reactions in 3D systems showing an arbitrarily complex geometrical configuration.
authors.affiliation: Department of Chemistry, Philipps-Universität Marburg, Hans-Meerwein-Strasse 4, 35032 Marburg, Germany.
authors.forename: D
authors.initials: D
authors.lastname: Hlushkou
authors.forename: K N
authors.initials: KN
authors.lastname: Knust
authors.forename: R M
authors.initials: RM
authors.lastname: Crooks
authors.forename: U
authors.initials: U
authors.lastname: Tallarek
mesh_terms: D004563:Electrochemistry; D004566:Electrodes; D004579:Electron Transport; D057446:Hydrodynamics; D008956:Models, Chemical; D016012:Poisson Distribution; D012492:Salts / Q000737:chemistry* / Q000302:isolation & purification*; D014867:Water / Q000737:chemistry*
chemical_list: D012492:Salts; D014867:Water