title: Multilayer Dye Adsorption in Activated Carbons-Facile Approach to Exploit Vacant Sites and Interlayer Charge Interaction.
abstract: Altering the textural properties of activated carbons (ACs) via physicochemical techniques to increase their specific surface area and/or to manipulate their pore size is a common practice to enhance their adsorption capacity. Instead, this study proposes the utilization of the vacant sites remaining unoccupied after dye uptake saturation by removing the steric hindrance and same-charge repulsion phenomena via multilayer adsorption. Herein, it has been shown that the adsorption capacity of the fresh AC is a direct function of the dye molecular size. As the cross-sectional area of the dye molecule increases, the steric hindrance effect exerted on the neighboring adsorbed molecules increases, and the geometrical packing efficiency is constrained. Thus, ACs saturated with larger dye molecules render higher concentrations of vacant adsorption sites which can accommodate an additional layer of dye molecules on the exhausted adsorbent through interlayer attractive forces. The second layer adsorption capacity (60-200 mg·g(-1)) has been demonstrated to have a linear relationship with the uncovered surface area of the exhausted AC, which is, in turn, inversely proportional to the adsorbate molecular size. Unlike the second layer adsorption, the third layer adsorption is a direct function of the charge density of the second layer.
authors.affiliation: Chemical and Biomolecular Engineering Department, Hong Kong University of Science and Technology , Clear Water Bay Road, Hong Kong, Hong Kong SAR.
authors.forename: Pejman
authors.initials: P
authors.lastname: Hadi
authors.affiliation: School of Energy and Environment, City University of Hong Kong , Tat Chee Avenue, Kowloon Tong, Hong Kong SAR.
authors.forename: Jiaxin
authors.initials: J
authors.lastname: Guo
authors.affiliation: Chemical and Biomolecular Engineering Department, Hong Kong University of Science and Technology , Clear Water Bay Road, Hong Kong, Hong Kong SAR.
authors.forename: John
authors.initials: J
authors.lastname: Barford
authors.affiliation: Division of Sustainability, College of Science and Engineering, Hamad Bin Khalifa University, Qatar Foundation , Doha, Qatar.
authors.forename: Gordon
authors.initials: G
authors.lastname: McKay
mesh_terms: D000327:Adsorption; D002606:Charcoal / Q000737:chemistry*
chemical_list: D002606:Charcoal