title: Periodically microstructured composite films made by electric- and magnetic-directed colloidal assembly.
abstract: Living organisms often combine soft and hard anisotropic building blocks to fabricate composite materials with complex microstructures and outstanding mechanical properties. An optimum design and assembly of the anisotropic components reinforces the material in specific directions and sites to best accommodate multidirectional external loads. Here, we fabricate composite films with periodic modulation of the soft-hard microstructure by simultaneously using electric and magnetic fields. We exploit forefront directed-assembly approaches to realize highly demanded material microstructural designs and showcase a unique example of how one can bridge colloidal sciences and composite technology to fabricate next-generation advanced structural materials. In the proof-of-concept experiments, electric fields are used to dictate the position of the anisotropic particles through dielectrophoresis, whereas a rotating magnetic field is used to control the orientation of the particles. By using such unprecedented control over the colloidal assembly process, we managed to fabricate ordered composite microstructures with up to 2.3-fold enhancement in wear resistance and unusual site-specific hardness that can be locally modulated by a factor of up to 2.5.
authors.affiliation: Complex Materials, Department of Materials, ETH Zurich, 8093 Zurich, Switzerland; ahmet.demiroers@mat.ethz.ch andre.studart@mat.ethz.ch.
authors.forename: Ahmet Faik
authors.initials: AF
authors.lastname: Demirörs
authors.affiliation: Laboratory for Nanometallurgy, Department of Materials, ETH Zurich, 8093 Zurich, Switzerland.
authors.forename: Diana
authors.initials: D
authors.lastname: Courty
authors.affiliation: Complex Materials, Department of Materials, ETH Zurich, 8093 Zurich, Switzerland;
authors.forename: Rafael
authors.initials: R
authors.lastname: Libanori
authors.affiliation: Complex Materials, Department of Materials, ETH Zurich, 8093 Zurich, Switzerland; ahmet.demiroers@mat.ethz.ch andre.studart@mat.ethz.ch.
authors.forename: André R
authors.initials: AR
authors.lastname: Studart
keywords: colloids; composites; dielectrophoresis; self-assembly; wear resistance