title: Composites reinforced via mechanical interlocking of surface-roughened microplatelets within ductile and brittle matrices.
abstract: Load-bearing reinforcing elements in a continuous matrix allow for improved mechanical properties and can reduce the weight of structural composites. As the mechanical performance of composite systems are heavily affected by the interfacial properties, tailoring the interactions between matrices and reinforcing elements is a crucial problem. Recently, several studies using bio-inspired model systems suggested that interfacial mechanical interlocking is an efficient mechanism for energy dissipation in platelet-reinforced composites. While cheap and effective solutions are available at the macroscale, the modification of surface topography in micron-sized reinforcing elements still represents a challenging task. Here, we report a simple method to create nanoasperities with tailored sizes and densities on the surface of alumina platelets and investigate their micromechanical effect on the energy dissipation mechanisms of nacre-like materials. Composites reinforced with roughened platelets exhibit improved mechanical properties for both organic ductile epoxy and inorganic brittle cement matrices. Mechanical interlocking increases the modulus of toughness (area under the stress-strain curve) by 110% and 56% in epoxy and cement matrices, respectively, as compared to those reinforced with flat platelets. This interlocking mechanism can potentially lead to a significant reduction in the weight of mechanical components while retaining the structural performance required in the application field.
authors.affiliation: Joint Research Network on Advanced Materials and Systems (JONAS), BASF, Germany. Complex Materials, Department of Materials, ETH Zürich, 8093 Zürich, Switzerland.
authors.forename: R
authors.initials: R
authors.lastname: Libanori
authors.forename: D
authors.initials: D
authors.lastname: Carnelli
authors.forename: N
authors.initials: N
authors.lastname: Rothfuchs
authors.forename: M R
authors.initials: MR
authors.lastname: Binelli
authors.forename: M
authors.initials: M
authors.lastname: Zanini
authors.forename: L
authors.initials: L
authors.lastname: Nicoleau
authors.forename: B
authors.initials: B
authors.lastname: Feichtenschlager
authors.forename: G
authors.initials: G
authors.lastname: Albrecht
authors.forename: A R
authors.initials: AR
authors.lastname: Studart
mesh_terms: D000818:Animals; D040761:Biomimetic Materials / Q000138:chemical synthesis; D055119:Elastic Modulus; D006244:Hardness; D008420:Manufactured Materials / Q000032:analysis; D008422:Materials Testing; D053768:Metal Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure*; D060734:Nacre / Q000737:chemistry*; D053761:Nanocomposites / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D012822:Silicon Dioxide / Q000737:chemistry*; D013314:Stress, Mechanical; D013499:Surface Properties
chemical_list: D060734:Nacre; D012822:Silicon Dioxide