title: Preparation of titanate nanosheets and nanoribbons by exfoliation of amine intercalated titanates.
abstract: Amine intercalated titanates were synthesized by direct exchange of potassium ions of K2Ti4O9 by alkyl ammonium ions of various alkyl chain lengths. These intercalated solids exfoliate well in alcohols of different alkyl chain lengths and non-polar solvents such as toluene and hexane to yield colloidal dispersions of titanate nanosheets. The longer the alkyl chain of the intercalated amine the better the exfoliation of the intercalated titanate in long chain alcohols and non-polar solvents. While non-uniform rectangular nanosheets were obtained when aggressive sonication was employed for exfoliating the solids, nanoribbons were obtained when the exfoliation was carried out by gently stirring the solids in the solvent.
authors.affiliation: Materials Research Group, Department of Chemistry, St. Joseph's College, 36 Lalbagh Road, Bangalore 560027, India. mikerajamathi@rediffmail.com.
authors.forename: A Anto
authors.initials: AA
authors.lastname: Jeffery
authors.forename: A
authors.initials: A
authors.lastname: Pradeep
authors.forename: Michael
authors.initials: M
authors.lastname: Rajamathi