title: Iodobismuthates Containing One-Dimensional BiI4(-) Anions as Prospective Light-Harvesting Materials: Synthesis, Crystal and Electronic Structure, and Optical Properties.
abstract: Four iodobismuthates, LiBiI4·5H2O (1), MgBi2I8·8H2O (2), MnBi2I8·8H2O (3), and KBiI4·H2O (4), were prepared by a facile solution route and revealed thermal stability in air up to 120 °C. Crystal structures of compounds 1-4 were solved by a single crystal X-ray diffraction method. 1: space group C2/c, a = 12.535(2), b = 16.0294(18), c = 7.6214(9) Å, β = 107.189(11)°, Z = 4, R = 0.029. 2: space group P21/c, a = 7.559(2), b = 13.1225(15), c = 13.927(4) Å, β = 97.14(3)°, Z = 2, R = 0.031. 3: space group P21/c, a = 7.606(3), b = 13.137(3), c = 14.026(5) Å, β = 97.14(3)°, Z = 2, R = 0.056. 4: space group P21/n, a = 7.9050(16), b = 7.7718(16), c = 18.233(4) Å, β = 97.45(3)°, Z = 4, R = 0.043. All solid state structures feature one-dimensional (BiI4)(-) anionic chains built of [BiI6] octahedra that share two opposite edges in such a fashion that two iodine atoms in cis-positions remain terminal. The calculated electronic structures and observed optical properties confirmed that compounds 1-4 are semiconductors with direct band gaps of 1.70-1.76 eV, which correspond to their intense red color. It was shown that the cations do not affect the optical properties, and the optical absorption is primarily associated with the charge transfer from the I 5p orbitals at the top of the valence band to the Bi 6p orbitals at the bottom of the conduction band. Based on their properties and facile synthesis, the title compounds are proposed as promising light-harvesting materials for all-solid solar cells.
authors.affiliation: Department of Chemistry, Lomonosov Moscow State University , Moscow, 119991, Russia.
authors.forename: Natalie A
authors.initials: NA
authors.lastname: Yelovik
authors.affiliation: Department of Chemistry, Lomonosov Moscow State University , Moscow, 119991, Russia.
authors.forename: Andrei V
authors.initials: AV
authors.lastname: Mironov
authors.affiliation: Department of Chemistry, Lomonosov Moscow State University , Moscow, 119991, Russia.
authors.forename: Mikhail A
authors.initials: MA
authors.lastname: Bykov
authors.affiliation: Department of Chemistry, Lomonosov Moscow State University , Moscow, 119991, Russia.
authors.forename: Alexey N
authors.initials: AN
authors.lastname: Kuznetsov
authors.affiliation: Department of Materials Sciences, Lomonosov Moscow State University , Moscow, 119991, Russia.
authors.forename: Anastasia V
authors.initials: AV
authors.lastname: Grigorieva
authors.affiliation: Department of Chemistry, University at Albany , Albany, New York 12222, United States.
authors.forename: Zheng
authors.initials: Z
authors.lastname: Wei
authors.affiliation: Department of Chemistry, University at Albany , Albany, New York 12222, United States.
authors.forename: Evgeny V
authors.initials: EV
authors.lastname: Dikarev
authors.affiliation: Department of Chemistry, Lomonosov Moscow State University , Moscow, 119991, Russia.
authors.forename: Andrei V
authors.initials: AV
authors.lastname: Shevelkov