title: Selective adsorption of arsenate and the reversible structure transformation of the mesoporous metal-organic framework MIL-100(Fe).
abstract: Here we describe a highly porous metal-organic framework MIL-100(Fe), which is initially used as an arsenate adsorbent in water. An appropriate mesoporous size allows AsO4(3-) to enter unrestrained and then be captured successfully, furthermore resulting in the damage of long-range order of uniform mesopores. Moreover, the porous framework could also make AsO4(3-) be reversibly desorbed without structural changes and the long-range order of mesopores be recovered again.
authors.affiliation: Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China. jiangli@iccas.ac.cn and University of Chinese Academy of Sciences, Beijing 100049, P. R. China.
authors.forename: Jianhua
authors.initials: J
authors.lastname: Cai
authors.affiliation: Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China. jiangli@iccas.ac.cn and University of Chinese Academy of Sciences, Beijing 100049, P. R. China.
authors.forename: Xueyun
authors.initials: X
authors.lastname: Wang
authors.affiliation: Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China. jiangli@iccas.ac.cn and University of Chinese Academy of Sciences, Beijing 100049, P. R. China.
authors.forename: Yue
authors.initials: Y
authors.lastname: Zhou
authors.affiliation: Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China. jiangli@iccas.ac.cn.
authors.forename: Li
authors.initials: L
authors.lastname: Jiang
authors.affiliation: Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China. jiangli@iccas.ac.cn.
authors.forename: Chunru
authors.initials: C
authors.lastname: Wang