title: Hexa-BODIPY Linked-Triazole Based on a Cyclotriphosphazene Core as a Highly Selective and Sensitive Fluorescent Sensor for Fe(2+) Ions.
abstract: A new type of fluorescent chemosensor based on tethered hexa-borondipyrromethene cyclotriphosphazene platform (HBTC) linked via triazole groups was designed and synthesized. Its sensing behavior toward metal ions was investigated by ultraviolet-visible and fluorescence spectroscopies. Addition of a Fe(2+) ion to a tetrahydrofuran solution of HBTC gave a visual color change as well as a significantly quenched fluorescence emission, while other tested 19 metal ions induced no color or spectral changes. This compound was found to be highly selective and sensitive for Fe(2+) with a low limit of detection (2.03 μM) which is, to the best of our knowledge, the superior than the previously studied chemosensors for Fe(2+). Graphical Abstract ᅟ.
authors.affiliation: Department of Chemistry, Gebze Technical University, P.O.Box: 141, 41400, Gebze, Kocaeli, Turkey.
authors.forename: Seda
authors.initials: S
authors.lastname: Çetindere
authors.affiliation: Department of Chemistry, Gebze Technical University, P.O.Box: 141, 41400, Gebze, Kocaeli, Turkey.
authors.forename: Süreyya O
authors.initials: SO
authors.lastname: Tümay
authors.affiliation: Department of Chemistry, Gebze Technical University, P.O.Box: 141, 41400, Gebze, Kocaeli, Turkey.
authors.forename: Adem
authors.initials: A
authors.lastname: Kılıç
authors.affiliation: Department of Chemistry, Gebze Technical University, P.O.Box: 141, 41400, Gebze, Kocaeli, Turkey.
authors.forename: Mahmut
authors.initials: M
authors.lastname: Durmuş
authors.affiliation: Department of Chemistry, Gebze Technical University, P.O.Box: 141, 41400, Gebze, Kocaeli, Turkey. yesil@gtu.edu.tr.
authors.forename: Serkan
authors.initials: S
authors.lastname: Yeşilot
keywords: Borondipyrromethene; Cyclotriphosphazene; Fluorescent Sensor; Iron (II)