title: Synthesis and evaluation of a novel cationic konjac glucomannan-based flocculant.
abstract: A novel cationic flocculant of konjac glucomannan-graft-poly-(2-methacryloyloxyethyl)trimethyl ammonium chloride (KGM-g-PDMC), was successfully synthesized by using acidic ammonium cerium (IV) nitrate (CAN) as initiator in homogeneous aqueous solution. The graft copolymer was characterized using Fourier-transform infrared (FT-IR) spectroscopy, (1)H nuclear magnetic resonance ((1)H NMR), thermogravimetric analysis (TGA) and elemental analysis. The influences of degree of substitution (DS) of KGM, concentration of NaCl and pH value on turbidity removal rate of the cationic flocculant were investigated. The results demonstrated that the flocculant exhibited excellent flocculating ability in the presence of salt and a wide range of pH (1<pH<9). With DS of 0.2, the turbidity removal rate of flocculant to 0.1% kaolin suspension could reach more than 90% at pH 7.0. The flocculation mechanisms were investigated by screening effect and means of zeta potential. Holding the positive charge, the KGM-g-PDMC could efficiently remove the negatively charged contaminants such as kaolin suspension.
authors.affiliation: College of Chemistry and Material Science, South Centre University for Nationalities, Hubei, Wuhan 430074, People's Republic of China.
authors.forename: Wen-jing
authors.initials: WJ
authors.lastname: Ren
authors.affiliation: College of Chemistry and Material Science, South Centre University for Nationalities, Hubei, Wuhan 430074, People's Republic of China. Electronic address: aiqingzhang_2000@sina.com.
authors.forename: Ai-qing
authors.initials: AQ
authors.lastname: Zhang
authors.affiliation: College of Chemistry and Material Science, South Centre University for Nationalities, Hubei, Wuhan 430074, People's Republic of China.
authors.forename: Si-yong
authors.initials: SY
authors.lastname: Qin
authors.affiliation: College of Chemistry and Material Science, South Centre University for Nationalities, Hubei, Wuhan 430074, People's Republic of China.
authors.forename: Zhen-ke
authors.initials: ZK
authors.lastname: Li
mesh_terms: D002563:Cerium / Q000737:chemistry; D060326:Chemistry Techniques, Synthetic; D005427:Flocculation; D006863:Hydrogen-Ion Concentration; D008351:Mannans / Q000138:chemical synthesis* / Q000737:chemistry*; D008689:Methacrylates / Q000737:chemistry; D011109:Polymethacrylic Acids / Q000737:chemistry; D000644:Quaternary Ammonium Compounds / Q000737:chemistry; D012965:Sodium Chloride / Q000737:chemistry
chemical_list: C120889:2-(trimethylammonio)ethyl methacrylate; D008351:Mannans; D008689:Methacrylates; D011109:Polymethacrylic Acids; D000644:Quaternary Ammonium Compounds; C543347:poly(2-(methacryoyloxy)ethyl)trimethylammonium chloride; C032786:cerium nitrate; D002563:Cerium; C022901:(1-6)-alpha-glucomannan; D012965:Sodium Chloride
keywords: Cationic konjac glucomannan; Flocculation; Flocculation mechanism; Grafting synthesis; Kaolin