Mid-Infrared Pumped Laser-Induced Thermal Grating Spectroscopy for Detection of Acetylene in the Visible Spectral Range.
We present mid-infrared laser-induced thermal grating spectroscopy (IR-LITGS) using excitation radiation around 3 µm generated by a simple broadband optical parametric oscillator (OPO). Acetylene as a typical small hydrocarbon molecule is used as an example target species. A mid-infrared broadband OPO pumped by the fundamental output of a neodymium-doped yttrium aluminum garnet (Nd:YAG) laser was used to generate the pump beams, with pulse energies of 6-10 mJ depending on the wavelength. The line width of the OPO idler beam was ∼5 cm(-1), which is large enough to cover up to six adjacent acetylene lines. The probe beam was the radiation of a 532 nm cw solid state laser with 190 mW output power. Signals were generated in atmospheric pressure gas flows of N2, air, CO2 and Ar with small admixtures of C2H2 A detection limit of less than 300 ppm was found for a point measurement of C2H2 diluted in N2 As expected, the oscillation frequency of the IR-LITGS signal was found to have a large dependency on the buffer gas, which allows determination of the speed of sound. Moreover, the results reveal a very strong collisional energy exchange between C2H2 and CO2 compared to the other gases. This manifests as significant local heating. In summary, the MIR-LITGS technique enables spectroscopy of fundamental vibrational transitions in the infrared via detection in the visible spectral range.
Division of Combustion Physics, Lund University, Sweden.
Anna-Lena
AL
Sahlberg
Technische Thermodynamik, Universität Bremen, Germany School of Engineering, University of Aberdeen, UK Erlangen Graduate School in Advanced Optical Technologies, Universität Erlangen-Nürnberg, Germany jkiefer@uni-bremen.de.
Johannes
J
Kiefer
Division of Combustion Physics, Lund University, Sweden.
Marcus
M
Aldén
Division of Combustion Physics, Lund University, Sweden.
Zhongshan
Z
Li
Hydrocarbon detection; LITGS; acetylene; laser-induced gratings; nonlinear optical spectroscopy; quenching