A C60-aryne building block: synthesis of a hybrid all-carbon nanostructure.
The synthesis of a [60]fullerene-benzyne building block and its further chemical cycloaddition reaction with graphene has resulted in a new all-carbon hybrid material which has been characterized by TGA, FTIR and Raman spectroscopies, XPS as well as AFM and TEM. Based on computational studies, the formation of both [2+2] and [4+2] cycloadducts on the graphene surface is feasible.
Centro de Investigación en Química Biolóxica e Materiais Moleculares (CIQUS) and Departamento de Química Orgánica, Universidade de Santiago de Compostela, Santiago de Compostela 15782, Spain. dolores.perez@usc.es.
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García
Departamento de Química Orgánica I, Facultad de Química, Universidad Complutense de Madrid, Avda. Complutense s/n, 28040 Madrid, Spain. nazmar@ucm.es.
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Rodríguez-Pérez
Departamento de Química Orgánica I, Facultad de Química, Universidad Complutense de Madrid, Avda. Complutense s/n, 28040 Madrid, Spain. nazmar@ucm.es.
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Herranz
Centro de Investigación en Química Biolóxica e Materiais Moleculares (CIQUS) and Departamento de Química Orgánica, Universidade de Santiago de Compostela, Santiago de Compostela 15782, Spain. dolores.perez@usc.es.
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Peña
Centro de Investigación en Química Biolóxica e Materiais Moleculares (CIQUS) and Departamento de Química Orgánica, Universidade de Santiago de Compostela, Santiago de Compostela 15782, Spain. dolores.perez@usc.es.
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Guitián
Physics Department, Lancaster University, LA1 4YB Lancaster, UK.
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Bailey
Physics Department, Lancaster University, LA1 4YB Lancaster, UK and Physics Department, College of Education, Al-Qadisiyah University, IRAQ.
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Al-Galiby
Physics Department, Lancaster University, LA1 4YB Lancaster, UK.
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Noori
Physics Department, Lancaster University, LA1 4YB Lancaster, UK.
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Lambert
Centro de Investigación en Química Biolóxica e Materiais Moleculares (CIQUS) and Departamento de Química Orgánica, Universidade de Santiago de Compostela, Santiago de Compostela 15782, Spain. dolores.perez@usc.es.
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Pérez
Departamento de Química Orgánica I, Facultad de Química, Universidad Complutense de Madrid, Avda. Complutense s/n, 28040 Madrid, Spain. nazmar@ucm.es and IMDEA-Nanociencia, c/Faraday 9, Campus Cantoblanco, 28049 Madrid, Spain.
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Martín