Improvement of anaerobic digestion of sewage sludge through microwave pre-treatment.
Sewage sludge generated in the activated sludge process is a polluting waste that must be treated adequately to avoid important environmental impacts. Traditional management methods, such as landfill disposal or incineration, are being ruled out due to the high content in heavy metal, pathogens, micropolluting compounds of the sewage sludge and the lack of use of resources. Anaerobic digestion could be an interesting treatment, but must be improved since the biomethanisation of sewage sludge entails low biodegradability and low methane production. A microwave pre-treatment at pilot scale is proposed to increase the organic matter solubilisation of sewage sludge and enhance the biomethanisation yield. The operational variables of microwave pre-treatment (power and specific energy applied) were optimised by analysing the physicochemical characteristics of sewage sludge (both total and soluble fraction) under different pre-treatment conditions. According to the variation in the sCOD and TN concentration, the optimal operation variables of the pre-treatment were fixed at 20,000 J/g TS and 700 W. A subsequent anaerobic digestion test was carried out with raw and pre-treated sewage sludge under different conditions (20,000 J/g TS and 700 W; 20,000 J/g TS and 400 W; and 30,000 J/g TS and 400 W). Although stability was maintained throughout the process, the enhancement in the total methane yield was not high (up to 17%). Nevertheless, very promising improvements were determined for the kinetics of the process, where the rG and the OLR increased by 43% and 39%, respectively, after carrying out a pre-treatment at 20,000 J/g TS and 700 W.
Department of Inorganic Chemistry and Chemical Engineering, University of Cordoba. Campus Universitario de Rabanales, Edificio Marie Curie (C-3). Ctra. N IV, km 396, 14071, Cordoba, Spain.
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Serrano
Department of Inorganic Chemistry and Chemical Engineering, University of Cordoba. Campus Universitario de Rabanales, Edificio Marie Curie (C-3). Ctra. N IV, km 396, 14071, Cordoba, Spain.
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Siles
Department of Inorganic Chemistry and Chemical Engineering, University of Cordoba. Campus Universitario de Rabanales, Edificio Marie Curie (C-3). Ctra. N IV, km 396, 14071, Cordoba, Spain. Electronic address: iq2masam@uco.es.
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Martín
Department of Inorganic Chemistry and Chemical Engineering, University of Cordoba. Campus Universitario de Rabanales, Edificio Marie Curie (C-3). Ctra. N IV, km 396, 14071, Cordoba, Spain.
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Chica
Empresa Metropolitana de Aguas de Sevilla, S.A. (EMASESA). C/ Escuelas Pías,1, 41008, Sevilla, Spain.
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Estévez-Pastor
Empresa Metropolitana de Aguas de Sevilla, S.A. (EMASESA). C/ Escuelas Pías,1, 41008, Sevilla, Spain.
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Toro-Baptista
D000693:Anaerobiosis; D019149:Bioreactors; D007700:Kinetics; D008697:Methane / Q000032:analysis / Q000737:chemistry; D008872:Microwaves; D012722:Sewage; D018505:Waste Management / Q000379:methods*
D012722:Sewage; D008697:Methane
Kinetics; Mesophilic anaerobic digestion; Microwave pre-treatment; Optimization; Sewage sludge; Specific energy applied