Snβ-zeolite catalyzed oxido-reduction cascade chemistry with biomass-derived molecules.
High activity of post-synthetically synthesized Sn-beta, producing novel caprolactone polymer building blocks, is demonstrated in Meerwein-Ponndorf-Verley (MPV), Oppenauer (OPO), Baeyer-Villiger (BV) and cascade reactions thereof with biomass-derived molecules.
Center for Surface Chemistry and Catalysis, KU Leuven, Celestijnenlaan 200F, 3001 Heverlee, Belgium. bert.sels@biw.kuleuven.be.
J
J
Dijkmans
Center for Surface Chemistry and Catalysis, KU Leuven, Celestijnenlaan 200F, 3001 Heverlee, Belgium. bert.sels@biw.kuleuven.be.
W
W
Schutyser
Center for Surface Chemistry and Catalysis, KU Leuven, Celestijnenlaan 200F, 3001 Heverlee, Belgium. bert.sels@biw.kuleuven.be.
M
M
Dusselier
Center for Surface Chemistry and Catalysis, KU Leuven, Celestijnenlaan 200F, 3001 Heverlee, Belgium. bert.sels@biw.kuleuven.be.
B F
BF
Sels
D018533:Biomass; D002208:Caproates / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D003512:Cyclohexanones / Q000737:chemistry*; D007783:Lactones / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010084:Oxidation-Reduction; D014001:Tin / Q000737:chemistry*; D017641:Zeolites / Q000737:chemistry*
D002208:Caproates; D003512:Cyclohexanones; D007783:Lactones; D017641:Zeolites; C121056:caprolactone; C036468:cyclohexanone; D014001:Tin