Facile Synthesis of Carbon-Coated Silicon/Graphite Spherical Composites for High-Performance Lithium-Ion Batteries.
A high-performance Si/carbon/graphite composite in which Si nanoparticles are attached onto the surface of natural graphite by carbonization of coal-tar pitch is proposed for use in lithium-ion batteries. This multicomponent structure is favorable for improving Li(+) storage capability because the amorphous carbon layer encapsulating Si nanoparticles offers sufficient electric conductivity and strong elasticity to facilitate relaxation of strain caused by electrochemical reaction of Si during cycles. The Si/carbon/graphite composite exhibits a specific capacity of 712 mAh g(-1) at a constant current density of 130 mA g(-1), and maintains more than 80% of its initial capacity after 100 cycles. Moreover, it shows a high capacity retention of approximately 88% even at a high current density of 5 C (3250 mA g(-1)). On the basis of electrochemical and structural analyses, we suggest that a rational design of the Si/carbon/graphite composite is mainly responsible for delivering a high reversible capacity and stable cycle performance. Furthermore, the proposed synthetic route for the Si/carbon/graphite composite is simple and cost-effective for mass production.
Advanced Batteries Research Center, Korea Electronic Technology Institute , 68 Yatap-dong, Bundang-gu, Seongnam 463-816, Republic of Korea.
So Yeun
SY
Kim
Advanced Batteries Research Center, Korea Electronic Technology Institute , 68 Yatap-dong, Bundang-gu, Seongnam 463-816, Republic of Korea.
Jaewoo
J
Lee
Division of Science Education, Daegu University , 201 Daegudae-ro, Gyeongsan-si, Gyeongbuk-do 712-714, Republic of Korea.
Bo-Hye
BH
Kim
Advanced Batteries Research Center, Korea Electronic Technology Institute , 68 Yatap-dong, Bundang-gu, Seongnam 463-816, Republic of Korea.
Young-Jun
YJ
Kim
Department of Polymer Engineering, Graduate School & Alan G. MacDiarmid Energy Research Institute, Chonnam National University , 77 Yongbong-ro, Buk-gu, Gwangju 500-757, Republic of Korea.
Kap Seung
KS
Yang
Advanced Batteries Research Center, Korea Electronic Technology Institute , 68 Yatap-dong, Bundang-gu, Seongnam 463-816, Republic of Korea.|Department of Advanced Materials Engineering for Information and Electronics, Kyung Hee University , 1732 Deogyeong-daero, Giheung-gu, Yongin 17104, Republic of Korea.
Min-Sik
MS
Park
Li-ion batteries; anode; composite; electrochemistry; silicon