Dual Catalysis Strategies in Photochemical Synthesis.
The interaction between an electronically excited photocatalyst and an organic molecule can result in the genertion of a diverse array of reactive intermediates that can be manipulated in a variety of ways to result in synthetically useful bond constructions. This Review summarizes dual-catalyst strategies that have been applied to synthetic photochemistry. Mechanistically distinct modes of photocatalysis are discussed, including photoinduced electron transfer, hydrogen atom transfer, and energy transfer. We focus upon the cooperative interactions of photocatalysts with redox mediators, Lewis and Brønsted acids, organocatalysts, enzymes, and transition metal complexes.
Department of Chemistry, University of Wisconsin-Madison , 1101 University Avenue, Madison, Wisconsin 53706, United States.
Kazimer L
KL
Skubi
Department of Chemistry, University of Wisconsin-Madison , 1101 University Avenue, Madison, Wisconsin 53706, United States.
Travis R
TR
Blum
Department of Chemistry, University of Wisconsin-Madison , 1101 University Avenue, Madison, Wisconsin 53706, United States.
Tehshik P
TP
Yoon
D000143:Acids / Q000737:chemistry; D002384:Catalysis; D004735:Energy Transfer; D004798:Enzymes / Q000737:chemistry; D010084:Oxidation-Reduction; D055668:Photochemical Processes; D028561:Transition Elements / Q000737:chemistry
D000143:Acids; D004798:Enzymes; D028561:Transition Elements