Alkenylation of Arenes and Heteroarenes with Alkynes.
This review is focused on the analysis of current data on new methods of alkenylation of arenes and heteroarenes with alkynes by transition metal catalyzed reactions, Bronsted/Lewis acid promoted transformations, and others. The synthetic potential, scope, limitations, and mechanistic problems of the alkenylation reactions are discussed. The insertion of an alkenyl group into aromatic and heteroaromatic rings by inter- or intramolecular ways provides a synthetic route to derivatives of styrene, stilbene, chalcone, cinnamic acid, various fused carbo- and heterocycles, etc.
Institute of Chemistry, Saint Petersburg State University , Universitetskaya nab., 7/9, Saint Petersburg 199034, Russia.
Vadim P
VP
Boyarskiy
Institute of Chemistry, Saint Petersburg State University , Universitetskaya nab., 7/9, Saint Petersburg 199034, Russia.|Department of Chemistry, Saint Petersburg State Forest Technical University , Institutsky per. 5, Saint Petersburg 194021, Russia.
Dmitry S
DS
Ryabukhin
Institute of Chemistry, Saint Petersburg State University , Universitetskaya nab., 7/9, Saint Petersburg 199034, Russia.
Nadezhda A
NA
Bokach
Institute of Chemistry, Saint Petersburg State University , Universitetskaya nab., 7/9, Saint Petersburg 199034, Russia.|Department of Chemistry, Saint Petersburg State Forest Technical University , Institutsky per. 5, Saint Petersburg 194021, Russia.
Aleksander V
AV
Vasilyev
D000480:Alkynes / Q000737:chemistry*; D001572:Benzofurans / Q000138:chemical synthesis / Q000737:chemistry; D002384:Catalysis; D006571:Heterocyclic Compounds / Q000737:chemistry*; D007211:Indoles / Q000138:chemical synthesis / Q000737:chemistry; D019216:Metals, Heavy / Q000737:chemistry; D011804:Quinolines / Q000138:chemical synthesis / Q000737:chemistry; D028561:Transition Elements / Q000737:chemistry
D000480:Alkynes; D001572:Benzofurans; D006571:Heterocyclic Compounds; D007211:Indoles; D019216:Metals, Heavy; D011804:Quinolines; D028561:Transition Elements; C105430:benzofuran