Vibrational Spectroscopy and Dynamics of Water.
We present an overview of recent static and time-resolved vibrational spectroscopic studies of liquid water from ambient conditions to the supercooled state, as well as of crystalline and amorphous ice forms. The structure and dynamics of the complex hydrogen-bond network formed by water molecules in the bulk and interphases are discussed, as well as the dissipation mechanism of vibrational energy throughout this network. A broad range of water investigations are addressed, from conventional infrared and Raman spectroscopy to femtosecond pump-probe, photon-echo, optical Kerr effect, sum-frequency generation, and two-dimensional infrared spectroscopic studies. Additionally, we discuss novel approaches, such as two-dimensional sum-frequency generation, three-dimensional infrared, and two-dimensional Raman terahertz spectroscopy. By comparison of the complementary aspects probed by various linear and nonlinear spectroscopic techniques, a coherent picture of water dynamics and energetics emerges. Furthermore, we outline future perspectives of vibrational spectroscopy for water researches.
SLAC National Accelerator Laboratory , 2575 Sand Hill Road, Menlo Park, California 94025, United States.
Fivos
F
Perakis
Department of Chemistry, Massachusetts Institute of Technology , 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States.|Department of Chemistry and James Franck Institute, University of Chicago , 929 East 57th Street, Chicago, Illinois 60637, United States.
Luigi De
LD
Marco
Department of Chemistry, University of Zurich , Winterthurerstrasse 190, CH-8057 Zurich, Switzerland.
Andrey
A
Shalit
International Center for Quantum Materials, Peking University , 5 Yiheyuan Road, Haidian, Beijing 100871, China.
Fujie
F
Tang
Theoretical Chemistry Institute and Department of Chemistry, University of Wisconsin , Madison, Wisconsin 53706, United States .
Zachary R
ZR
Kann
Department of Chemistry, University of Paderborn , Warburger Strasse 100, D-33098 Paderborn, Germany.
Thomas D
TD
Kühne
European Lab for Nonlinear Spectroscopy and Dipartimento di Fisica e Astronomia, Università di Firenze , Via Nello Carrara 1, Sesto Fiorentino (Firenze) I-50019, Italy.
Renato
R
Torre
Max Planck Institute for Polymer Research , Ackermannweg 10, 55128 Mainz, Germany.
Mischa
M
Bonn
Max Planck Institute for Polymer Research , Ackermannweg 10, 55128 Mainz, Germany.
Yuki
Y
Nagata