Adsorption of methyl violet from aqueous solution using gum xanthan/Fe3O4 based nanocomposite hydrogel.
This research paper reports the utilization of gum xanthan-grafted-polyacrylic acid and Fe3O4 magnetic nanoparticles based nanocomposite hydrogel (NCH) for the highly effective adsorption of methyl violet (MV) from aqueous solution. Synthesized NCH was characterized using various techniques, such as FTIR, XRD, SEM-EDS, TEM and BET. Adsorption behavior of NCH was studied for the adsorption of MV and it was found to remove 99% dye from the solution. Adsorption process followed Langmuir isotherm model (qe=642mg/g) and pseudo-second-order kinetics model. Thermodynamic studies suggested that the adsorption process was endothermic and spontaneous. Moreover, the adsorbent was successfully utilized for successive five cycles of adsorption-desorption.
Department of Applied Chemistry, University of Johannesburg, Doornfontein 2028, Johannesburg, South Africa; DST-CSIR National Centre for Nanostructured Materials, Council for Scientific and Industrial Research, Pretoria 0001, South Africa. Electronic address: mittal.hemant5@gmail.com.
H
H
Mittal
Department of Applied Sciences, CT Group of Institutions, Jalandhar, Punjab, India.
Vaneet
V
Kumar
Department of Chemistry, NIT Jalandhar, Punjab, India.
Saruchi
Department of Applied Chemistry, University of Johannesburg, Doornfontein 2028, Johannesburg, South Africa; DST-CSIR National Centre for Nanostructured Materials, Council for Scientific and Industrial Research, Pretoria 0001, South Africa. Electronic address: rsuprakas@csir.co.za.
Suprakas Sinha
SS
Ray
D000327:Adsorption; D004058:Diffusion; D005290:Ferric Compounds / Q000737:chemistry*; D005840:Gentian Violet / Q000302:isolation & purification*; D020136:Hydrogel, Polyethylene Glycol Dimethacrylate / Q000138:chemical synthesis / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D008962:Models, Theoretical; D053761:Nanocomposites / Q000737:chemistry / Q000648:ultrastructure; D011135:Polysaccharides, Bacterial / Q000737:chemistry*; D012996:Solutions; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature; D014961:X-Ray Diffraction
D005290:Ferric Compounds; D011135:Polysaccharides, Bacterial; D012996:Solutions; C000499:ferric oxide; D020136:Hydrogel, Polyethylene Glycol Dimethacrylate; D005840:Gentian Violet; C002563:xanthan gum
Adsorption; Gum xanthan; Isotherms; Kinetics; Methyl violet; Nanocomposite hydrogel