Bis-phosphine allene ligand: coordination chemistry and preliminary applications in catalysis.
A 1,3-bis-diphenylphosphine allene can give rise to new coordination complexes with palladium, platinum and gold metals. These complexes were fully characterized by NMR, HRMS and X-ray diffraction analysis. For gold(i), the corresponding dinuclear complex has been used in a series of diagnostic catalytic reactions and gave promising preliminary results in asymmetric catalysis.
Sorbonne Universités UPMC Univ Paris 06, CNRS, UMR 8232, Institut Parisien de Chimie Moléculaire, 4 place Jussieu, C.229, F-75005 Paris, France.
Avassaya
A
Vanitcha
Cecilia
C
Damelincourt
Geoffrey
G
Gontard
Nicolas
N
Vanthuyne
Virginie
V
Mouriès-Mansuy
Louis
L
Fensterbank
D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D056831:Coordination Complexes / Q000737:chemistry*; D008024:Ligands; D010720:Phosphines / Q000737:chemistry*
D000475:Alkenes; D056831:Coordination Complexes; D008024:Ligands; D010720:Phosphines; C044646:phosphine