Exceptionally water stable heterometallic gyroidal MOFs: tuning the porosity and hydrophobicity by doping metal ions.
A strategy to improve the framework porosity and hydrophobicity of the pore surface by doping metal ions (Cu(2+), Cd(2+), or Fe(2+)) into a gyroidal MOF STU-1 has been developed. It is found that the obtained heterometallic MOFs are exceptionally water stable.
Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Guangdong 515063, P. R. China. zhouxp@stu.edu.cn dli@stu.edu.cn.
Xiao-Wei
XW
Zhu
Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Guangdong 515063, P. R. China. zhouxp@stu.edu.cn dli@stu.edu.cn.
Xiao-Ping
XP
Zhou
Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Guangdong 515063, P. R. China. zhouxp@stu.edu.cn dli@stu.edu.cn.
Dan
D
Li
D000327:Adsorption; D002413:Cations, Divalent; D057927:Hydrophobic and Hydrophilic Interactions; D000073396:Metal-Organic Frameworks / Q000138:chemical synthesis / Q000737:chemistry*; D019216:Metals, Heavy / Q000737:chemistry*; D016062:Porosity; D014867:Water / Q000737:chemistry*
D002413:Cations, Divalent; D000073396:Metal-Organic Frameworks; D019216:Metals, Heavy; D014867:Water