Revealing heterogeneous nucleation of primary Si and eutectic Si by AlP in hypereutectic Al-Si alloys.
The heterogeneous nucleation of primary Si and eutectic Si can be attributed to the presence of AlP. Although P, in the form of AlP particles, is usually observed in the centre of primary Si, there is still a lack of detailed investigations on the distribution of P within primary Si and eutectic Si in hypereutectic Al-Si alloys at the atomic scale. Here, we report an atomic-scale experimental investigation on the distribution of P in hypereutectic Al-Si alloys. P, in the form of AlP particles, was observed in the centre of primary Si. However, no significant amount of P was detected within primary Si, eutectic Si and the Al matrix. Instead, P was observed at the interface between the Al matrix and eutectic Si, strongly indicating that P, in the form of AlP particles (or AlP 'patch' dependent on the P concentration), may have nucleated on the surface of the Al matrix and thereby enhanced the heterogeneous nucleation of eutectic Si. The present investigation reveals some novel insights into heterogeneous nucleation of primary Si and eutectic Si by AlP in hypereutectic Al-Si alloys and can be used to further develop heterogeneous nucleation mechanisms based on adsorption.
Institute of Casting Research, Montanuniversität Leoben, Leoben, A-8700, Austria.
Jiehua
J
Li
SuperSTEM Laboratory, SciTech Daresbury Campus, Keckwick Lane, Daresbury, WA4 4AD, UK.
Fredrik S
FS
Hage
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, School of Materials Science and Engineering, Shandong University, Jinan 250061, China.
Xiangfa
X
Liu
SuperSTEM Laboratory, SciTech Daresbury Campus, Keckwick Lane, Daresbury, WA4 4AD, UK.
Quentin
Q
Ramasse
Institute of Casting Research, Montanuniversität Leoben, Leoben, A-8700, Austria.|Austrian Foundry Research Institute, Leoben, A-8700, Austria.
Peter
P
Schumacher