Polyoxometalate Cluster-Incorporated Metal-Organic Framework Hierarchical Nanotubes.
A simple method to prepare metal-organic framework (MOF) nanotubes is developed by employing polyoxometalates (POMs) as modulators. The local structure of the MOF nanotubes is investigated combining XANES and EXAFS studies. These nanotubes show both an excellent catalytic performance in the detoxification of sulfur compounds in O2 atmosphere and a remarkable cycling stability as the anode material for lithium-ion batteries.
Key Lab of Organic Optoelectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing, 100084, P. R. China.
Xiaobin
X
Xu
National Synchrotron Radiation Laboratory, Hefei Science Center CAS, University of Science and Technology of China, Hefei Anhui, 230029, P. R. China.
Shuangming
S
Chen
School of Medicine and Tsinghua-Peking Joint Centers for Life Science, Tsinghua University, Beijing, 100084, P. R. China.
Yifeng
Y
Chen
Beijing National Center for Electron Microscopy, School of Materials Science and Engineering, The State Key Laboratory of New Ceramics and Fine Processing, Key Laboratory of Advanced Materials (MOE), Tsinghua University, Beijing, 100084, P. R. China.
Hongyu
H
Sun
National Synchrotron Radiation Laboratory, Hefei Science Center CAS, University of Science and Technology of China, Hefei Anhui, 230029, P. R. China.
Li
L
Song
School of Medicine and Tsinghua-Peking Joint Centers for Life Science, Tsinghua University, Beijing, 100084, P. R. China.
Wei
W
He
Key Lab of Organic Optoelectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing, 100084, P. R. China.
Xun
X
Wang
catalysis; hierarchical structures; lithium-ion batteries; metal-organic frameworks