title: Robust and direct electrochemical sensing of arsenic using zirconia nanocubes.
abstract: The presence of heavy metal ions in the environment and in food items can severely harm human health. Thus, simple, reliable, sensitive, quick, and accurate methods for their detection must be developed as a means to improve healthcare worldwide. To this end, a robust method was developed for the direct sensing of arsenic(iii) in control and real environmental samples (at neutral pH) by a gold electrode that was modified with zirconia nanocubes synthesized via a facile hydrothermal route. This sensing system was used to build a sensing profile for arsenic ions after characterization of their elemental, optical, chemical, and morphological behavior. Electrochemical sensing of arsenic was achieved by cyclic voltammetry (CV) and chronoamperometry with an ultra-sensitivity of 550 nA cm(-2) ppb(-1) and a detection limit of 5 ppb (linear range of 5-60 ppb with a response time below 2 s). Although this system experienced small interference from Cd ions, the results of the real sample analysis were comparable to those of other standard techniques. The proposed method is advantageous and can be used to assess the toxicity of water, food, and other environmental samples without requiring any toxic solutions and/or gasses in any of the analytical steps. Moreover, due to its low price, portability, and easy mass production, it can be adopted for use in screen-printed electrodes.
authors.affiliation: Department of Bio and Nano Technology, Guru Jambheshwar University of Science and Technology, Hisar, Haryana 125001, India. ksandeep36@yahoo.com.
authors.forename: Gaurav
authors.initials: G
authors.lastname: Bhanjana
authors.affiliation: Department of Bio and Nano Technology, Guru Jambheshwar University of Science and Technology, Hisar, Haryana 125001, India. ksandeep36@yahoo.com.
authors.forename: Neeraj
authors.initials: N
authors.lastname: Dilbaghi
authors.affiliation: Department of Chemistry, Panjab University, Chandigarh, 160014, India.
authors.forename: Savita
authors.initials: S
authors.lastname: Chaudhary
authors.affiliation: Department of Civil & Environmental Engineering, Hanyang University, 222 Wangsimni-Ro, Seoul 133-791, Republic of Korea. kkim61@hanyang.ac.kr.
authors.forename: Ki-Hyun
authors.initials: KH
authors.lastname: Kim
authors.affiliation: Department of Bio and Nano Technology, Guru Jambheshwar University of Science and Technology, Hisar, Haryana 125001, India. ksandeep36@yahoo.com and Department of Civil & Environmental Engineering, Hanyang University, 222 Wangsimni-Ro, Seoul 133-791, Republic of Korea. kkim61@hanyang.ac.kr.
authors.forename: Sandeep
authors.initials: S
authors.lastname: Kumar