title: Hot foam for weed control-Do alkyl polyglucoside surfactants used as foaming agents affect the mobility of organic contaminants in soil?
abstract: Use of alkyl polyglucosides (APGs) as a foaming agent during hot water weed control may influence the environmental fate of organic contaminants in soil. We studied the effects of the APG-based foaming agent NCC Spuma (C8-C10) on leaching of diuron, glyphosate, and polycyclic aromatic hydrocarbons (PAHs) in sand columns. We also examined how APG concentration affected the apparent water solubility and adsorption of the herbicides and of the PAHs acenaphthene, acenaphthylene and fluorene. Application of APGs at the recommended concentration of 0.3% did not significantly affect leaching of any of the compounds studied. However, at a concentration of 1.5%, leaching of both diuron and glyphosate was significantly increased. The increased leaching corresponded to an increase in apparent water solubility of diuron and a decrease in glyphosate adsorption to the sand. However, APG addition did not significantly affect the mobility of PAHs even though their apparent water solubility was increased. These results suggest that application of APG-based foam during hot water weed control does not significantly affect the mobility of organic contaminants in soil if used according to recommendations. Moreover, they suggest that APGs could be useful for soil bioremediation purposes if higher concentrations are used.
authors.affiliation: Swedish University of Agricultural Sciences, Uppsala BioCenter, Department of Microbiology, Box 7025, Uppsala, Sweden. Electronic address: harald.cederlund@slu.se.
authors.forename: H
authors.initials: H
authors.lastname: Cederlund
authors.affiliation: Swedish University of Agricultural Sciences, Uppsala BioCenter, Department of Microbiology, Box 7025, Uppsala, Sweden.
authors.forename: E
authors.initials: E
authors.lastname: Börjesson
mesh_terms: D000327:Adsorption; D004237:Diuron / Q000737:chemistry; D005960:Glucosides / Q000737:chemistry*; D005998:Glycine / Q000031:analogs & derivatives / Q000737:chemistry; D006358:Hot Temperature; D011084:Polycyclic Aromatic Hydrocarbons / Q000737:chemistry; D012989:Soil Pollutants / Q000737:chemistry*; D012995:Solubility; D013501:Surface-Active Agents / Q000737:chemistry*; D014867:Water / Q000737:chemistry; D058728:Weed Control / Q000379:methods*; D000097797:Glyphosate
chemical_list: D004237:Diuron; D005960:Glucosides; D005998:Glycine; D011084:Polycyclic Aromatic Hydrocarbons; D012989:Soil Pollutants; D013501:Surface-Active Agents; D014867:Water; D000097797:Glyphosate
keywords: Alkyl polyglucosides (APGs); Diuron; Glyphosate; Leaching; Polycyclic aromatic hydrocarbons (PAHs)