title: Immobilization of ionic liquids to covalent organic frameworks for catalyzing the formylation of amines with CO2 and phenylsilane.
abstract: We presented the immobilization of ionic liquids on the channel walls of COFs using a post-synthetic strategy. The ionic [Et4NBr]50%-Py-COF afforded a high CO2 adsorption capacity of 164.6 mg g(-1) (1 bar, 273 K) and was developed as an effective heterogeneous catalyst for the transformation of CO2 into value-added formamides under ambient conditions.
authors.affiliation: Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China. ygao@dicp.ac.cn.
authors.forename: Bin
authors.initials: B
authors.lastname: Dong
authors.forename: Liangying
authors.initials: L
authors.lastname: Wang
authors.forename: Shang
authors.initials: S
authors.lastname: Zhao
authors.forename: Rile
authors.initials: R
authors.lastname: Ge
authors.forename: Xuedan
authors.initials: X
authors.lastname: Song
authors.forename: Yu
authors.initials: Y
authors.lastname: Wang
authors.forename: Yanan
authors.initials: Y
authors.lastname: Gao