title: Uniform deposition of uranium hexafluoride (UF6): Standardized mass deposits and controlled isotopic ratios using a thermal fluorination method.
abstract: We report a convenient method for the generation of volatile uranium hexafluoride (UF6) from solid uranium oxides and other U compounds, followed by uniform deposition of low levels of UF6 onto sampling coupons. Under laminar flow conditions, UF6 is shown to interact with surfaces within a fixed reactor geometry to a highly predictable degree. We demonstrate the preparation of U deposits that range between approximately 0.01 and 500ngcm(-2). The data suggest the method can be extended to creating depositions at the sub-picogramcm(-2) level. The isotopic composition of the deposits can be customized by selection of the U source materials and we demonstrate a layering technique whereby two U solids, each with a different isotopic composition, are employed to form successive layers of UF6 on a surface. The result is an ultra-thin deposit that bears an isotopic signature that is a composite of the two U sources. The reported deposition method has direct application to the development of unique analytical standards for nuclear safeguards and forensics. Further, the method allows access to very low atomic or molecular coverages of surfaces.
authors.affiliation: Pacific Northwest National Laboratory, 902 Battelle Blvd., PO Box 999, Richland, WA 99352, United States. Electronic address: Bruce.McNamara@pnnl.gov.
authors.forename: Bruce K
authors.initials: BK
authors.lastname: McNamara
authors.affiliation: Pacific Northwest National Laboratory, 902 Battelle Blvd., PO Box 999, Richland, WA 99352, United States.
authors.forename: Matthew J
authors.initials: MJ
authors.lastname: O'Hara
authors.affiliation: Pacific Northwest National Laboratory, 902 Battelle Blvd., PO Box 999, Richland, WA 99352, United States.
authors.forename: Andrew M
authors.initials: AM
authors.lastname: Casella
authors.affiliation: Pacific Northwest National Laboratory, 902 Battelle Blvd., PO Box 999, Richland, WA 99352, United States.
authors.forename: Jennifer C
authors.initials: JC
authors.lastname: Carter
authors.affiliation: Pacific Northwest National Laboratory, 902 Battelle Blvd., PO Box 999, Richland, WA 99352, United States.
authors.forename: R Shane
authors.initials: RS
authors.lastname: Addleman
authors.affiliation: Pacific Northwest National Laboratory, 902 Battelle Blvd., PO Box 999, Richland, WA 99352, United States.
authors.forename: Paul J
authors.initials: PJ
authors.lastname: MacFarlan
keywords: Fluorination; Nuclear forensics; Nuclear safeguards; UF(6); UO(2); UO(2)F(2)