title: Regio- and Stereoselective Copper(II)-Catalyzed Hydrosilylation of Activated Allenes in Water: Access to Vinylsilanes.
abstract: By using catalytic amounts of copper(II), 4-picoline, and dimethylphenylsilylpinacol borane, a series of allenoates were silylated on the β carbon in good to excellent yields and high (E)-selectivity. The mild and efficient silylation method is conducted in water under atmospheric conditions to afford vinylsilanes.
authors.affiliation: Department of Chemistry, Virginia Tech , Blacksburg, Virginia 24061, United States.
authors.forename: Srinath
authors.initials: S
authors.lastname: Pashikanti
authors.affiliation: Department of Chemistry, Virginia Tech , Blacksburg, Virginia 24061, United States.
authors.forename: Joseph A
authors.initials: JA
authors.lastname: Calderone
authors.affiliation: Department of Chemistry, Virginia Tech , Blacksburg, Virginia 24061, United States.
authors.forename: Matthew K
authors.initials: MK
authors.lastname: Nguyen
authors.affiliation: Department of Chemistry, Virginia Tech , Blacksburg, Virginia 24061, United States.
authors.forename: Christopher D
authors.initials: CD
authors.lastname: Sibley
authors.affiliation: Department of Chemistry, Virginia Tech , Blacksburg, Virginia 24061, United States.
authors.forename: Webster L
authors.initials: WL
authors.lastname: Santos