title: Enhanced Dechlorination of 1,2-Dichloroethane by Coupled Nano Iron-Dithionite Treatment.
abstract: 1,2-Dichloroethane (1,2-DCA) is a chlorinated solvent classified as a probable human carcinogen. Due to its extensive use in industrial applications, widespread contamination, and recalcitrance toward abiotic dechlorination, 1,2-DCA remains a challenging compound for the remediation community. Over the past decade, nano zerovalent iron (nZVI) has been efficiently used to treat many of the chlorinated compounds of concern. However, thus far, even nZVI (monometallic or bimetallic) has been unable to dechlorinate 1,2-DCA. Therefore, an alternative treatment coupling nZVI with dithionite to treat 1,2-DCA is proposed in this work. Coupled nZVI-dithionite was able to degrade >90% 1,2-DCA over the course of a year. The effects of dithionite and nZVI loadings, carboxymethyl cellulose (CMC) coating, addition of palladium, and other iron species as metal surfaces on the degradation kinetics were also investigated. Observed pseudo-first-order rate constants (kobs) ranged from 3.8 × 10(-3) to 7.8 × 10(-3) d(-1). Both nucleophilic substitution and reductive dechlorination are the proposed mechanisms for 1,2-DCA degradation by coupled nZVI-dithionite treatment. Characterization analysis of the nZVI-dithionite nanoparticles shows that most of the iron was still preserved in the zerovalent state even after more than one year of reactivity with some iron sulfide (FeS) formation. Scanning electron microscopy (SEM) analysis shows that the nanosized spherical particles were still present along with the FeS platelets. This novel treatment represents the first nZVI-based formulation to achieve nearly complete degradation of 1,2-DCA.
authors.affiliation: Civil and Environmental Engineering, Western University , 1151 Richmond Road, London, Ontario N6A 5B8, Canada.
authors.forename: Ariel
authors.initials: A
authors.lastname: Nunez Garcia
authors.affiliation: Civil and Environmental Engineering, Western University , 1151 Richmond Road, London, Ontario N6A 5B8, Canada.
authors.forename: Hardiljeet K
authors.initials: HK
authors.lastname: Boparai
authors.affiliation: Civil and Environmental Engineering, Western University , 1151 Richmond Road, London, Ontario N6A 5B8, Canada.
authors.forename: Denis M
authors.initials: DM
authors.lastname: O'Carroll
mesh_terms: D004227:Dithionite; D054879:Halogenation; D007501:Iron; D010165:Palladium; D013440:Sulfides
chemical_list: D013440:Sulfides; D004227:Dithionite; D010165:Palladium; D007501:Iron