title: Efficient Pd-Catalyzed Dehydrogenative Coupling of P(O)H with RSH: A Precise Construction of P(O)-S Bonds.
abstract: A Pd-catalyzed dehydrogenative phosphorylation of thiols is developed. A variety of thiols dehydrogenatively couple readily with all three kinds of P(O)-H compounds, i.e., H-phosphonates, H-phosphinates, and secondary phosphine oxides, providing a general access to the valuable phosphorothioates including the P-chiral compounds. A plausible mechanism is proposed.
authors.affiliation: State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University , Changsha 410082, China.
authors.forename: Yueyue
authors.initials: Y
authors.lastname: Zhu
authors.affiliation: State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University , Changsha 410082, China.
authors.forename: Tieqiao
authors.initials: T
authors.lastname: Chen
authors.affiliation: State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University , Changsha 410082, China.
authors.forename: Shan
authors.initials: S
authors.lastname: Li
authors.affiliation: National Institute of Advanced Industrial Science and Technology (AIST) , Tsukuba, Ibaraki 305-8565, Japan.
authors.forename: Shigeru
authors.initials: S
authors.lastname: Shimada
authors.affiliation: National Institute of Advanced Industrial Science and Technology (AIST) , Tsukuba, Ibaraki 305-8565, Japan.
authors.forename: Li-Biao
authors.initials: LB
authors.lastname: Han