title: The concentration and changes in freely dissolved polycyclic aromatic hydrocarbons in biochar-amended soil.
abstract: The presence of polycyclic aromatic hydrocarbons (PAHs) in biochars hinders their environmental use. The aim of this study was to determine the freely dissolved (Cfree) PAH content in soil amended with biochar in a long-term (851 days) field experiment. Biochar was added to the soil at a rate of 30 and 45 t/ha. The addition of biochar to the soil resulted in a decrease in Σ13 Cfree PAHs by 25 and 22%, in the soil with the addition of biochar at the rate of 30 and 45 t/ha, respectively. As far as individual PAHs are concerned, in most cases a reduction in Cfree was also observed (from 3.6 to 66%, depending on the biochar rate). During the first 105 days of the experiment, the content of Σ13 Cfree in the biochar-amended soil significantly decreased by 26% (30 t/ha) and 36% (45 t/ha). After this period of time until the end of the experiment, no significant changes in Cfree were observed, regardless of the biochar rate. However, the behavior of individual PAH groups differed depending on the number of rings and experimental treatment. Ultimately, after 851 days of the experiment the content of Σ13 Cfree PAHs was lower by 29% (30 t/ha) and 35% (45 t/ha) compared to the beginning of the study as well as lower by 40% (30 t/ha) and 42% (45 t/ha) than in the control soil. The log KTOC coefficients calculated for the biochar-amended soils were higher immediately after adding biochar and subsequently they gradually decreased, indicating the reduced strength of the interaction between biochar and the studied PAHs. The obtained results show that the addition of biochar to soil does not create a risk in terms of the content of Cfree PAHs.
authors.affiliation: Department of Environmental Chemistry, Faculty of Chemistry, 3 Maria Curie-Skłodowska Square, 20-031 Lublin, Poland. Electronic address: patryk.oleszczuk@poczta.umcs.lublin.pl.
authors.forename: Patryk
authors.initials: P
authors.lastname: Oleszczuk
authors.affiliation: Department of Environmental Chemistry, Faculty of Chemistry, 3 Maria Curie-Skłodowska Square, 20-031 Lublin, Poland.
authors.forename: Marcin
authors.initials: M
authors.lastname: Kuśmierz
authors.affiliation: Department of Environmental Chemistry, Faculty of Chemistry, 3 Maria Curie-Skłodowska Square, 20-031 Lublin, Poland.
authors.forename: Paulina
authors.initials: P
authors.lastname: Godlewska
authors.affiliation: Department of Agricultural Ecology, University of Life Sciences in Lublin, ul. Akademicka 13, 20-950 Lublin, Poland.
authors.forename: Piotr
authors.initials: P
authors.lastname: Kraska
authors.affiliation: Department of Agricultural Ecology, University of Life Sciences in Lublin, ul. Akademicka 13, 20-950 Lublin, Poland.
authors.forename: Edward
authors.initials: E
authors.lastname: Pałys
mesh_terms: D002606:Charcoal / Q000737:chemistry*; D003247:Conservation of Natural Resources / Q000379:methods*; D004784:Environmental Monitoring / Q000379:methods*; D011044:Poland; D011084:Polycyclic Aromatic Hydrocarbons / Q000032:analysis*; D012987:Soil / Q000737:chemistry* / Q000592:standards; D012989:Soil Pollutants / Q000032:analysis*
chemical_list: D011084:Polycyclic Aromatic Hydrocarbons; D012987:Soil; D012989:Soil Pollutants; C540010:biochar; D002606:Charcoal
keywords: Amendment; Biochar; Environmental risk; Freely dissolved content; PAHs; Soil