title: Self-Assembly of Amphiphilic Anthracene-Functionalized β-Cyclodextrin (CD-AN) through Multi-Micelle Aggregation.
abstract: Multi-micelle aggregation (MMA) mechanism is widely acknowledged to explicate large spherical micelles self-assembly, but the process of MMA during self-assembly is hard to observe. Herein, a novel kind of strong, regular microspheres fabricated from self-assembly of amphiphilic anthracene-functionalized β-cyclodextrin (CD-AN) via Cu(I)-catalyzed azide-alkyne click reactions is reported. The obtained CD-AN amphiphiles can self-assemble in water from primary core-shell micelles to secondary aggregates with the diameter changing from several tens nm to around 600-700 nm via MMA process according to the images of scanning electron microscopy, transmission electron microscopy, and atomic force microscopy as well as the dynamic light scattering measurements, followed by further crosslinking through photo-dimerization of anthracene. What merits special attention is that such photo-crosslinked self-assemblies are able to disaggregate reversibly into primary nanoparticles when changing the solution conditions, which is benefited from the designed regular structure of CD-AN and the rigid ranging of anthracene during assembly, thus confirming the process of MMA.
authors.affiliation: Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, State Key Laboratory for Metal Matrix Composite Materials, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, P. R. China.
authors.forename: Yuannan
authors.initials: Y
authors.lastname: Zhang
authors.affiliation: Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, State Key Laboratory for Metal Matrix Composite Materials, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, P. R. China.
authors.forename: Hongjie
authors.initials: H
authors.lastname: Xu
authors.affiliation: Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, State Key Laboratory for Metal Matrix Composite Materials, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, P. R. China.
authors.forename: Xiaodong
authors.initials: X
authors.lastname: Ma
authors.affiliation: Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, State Key Laboratory for Metal Matrix Composite Materials, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, P. R. China.
authors.forename: Zixing
authors.initials: Z
authors.lastname: Shi
authors.affiliation: Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, State Key Laboratory for Metal Matrix Composite Materials, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, P. R. China.
authors.forename: Jie
authors.initials: J
authors.lastname: Yin
authors.affiliation: Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, State Key Laboratory for Metal Matrix Composite Materials, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, P. R. China.
authors.forename: Xuesong
authors.initials: X
authors.lastname: Jiang
mesh_terms: D000873:Anthracenes / Q000737:chemistry*; D008823:Micelles; D015394:Molecular Structure; D010316:Particle Size; D013499:Surface Properties; D013501:Surface-Active Agents / Q000138:chemical synthesis* / Q000737:chemistry; D047392:beta-Cyclodextrins / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D000873:Anthracenes; D008823:Micelles; D013501:Surface-Active Agents; D047392:beta-Cyclodextrins; C034020:anthracene; C031215:betadex
keywords: anthracenes; cyclodextrins; multi-micelle aggregations; self-assemblies