title: Mechanistic Aspects of the Palladium-Catalyzed Isomerization of Allenic Sulfones to 1-Arylsulfonyl 1,3-Dienes.
abstract: When an allenic sulfone is treated under palladium catalysis in the presence of a weak acid, isomerization to a 1-arylsulfonyl 1,3-diene occurs. Investigations of the mechanistic aspects of this isomerization were performed, leading to the mechanism proposed herein. Some further studies of reaction parameters are reported.
authors.affiliation: Department of Chemistry, University of Missouri-Columbia , Columbia, Missouri 65211, United States.
authors.forename: Carissa S
authors.initials: CS
authors.lastname: Hampton
authors.affiliation: Department of Chemistry, University of Missouri-Columbia , Columbia, Missouri 65211, United States.
authors.forename: Michael
authors.initials: M
authors.lastname: Harmata