title: Metal-Organic Framework Templated Synthesis of Copper Azide as the Primary Explosive with Low Electrostatic Sensitivity and Excellent Initiation Ability.
abstract: A powerful yet safe primary explosive, embedded in a conductive carbon scaffold, is prepared by using a metal-organic framework as precursor. It simultaneously possesses low electrostatic sensitivity, good flame sensitivity, and excellent initiation ability. This method is simple, scalable, and provides a new platform for the development of energetic materials especially those employed in miniaturized explosive systems.
authors.affiliation: Key Laboratory of Explosion Science and Technology of China, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081, P. R. China.
authors.forename: Qianyou
authors.initials: Q
authors.lastname: Wang
authors.affiliation: Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081, P. R. China.
authors.forename: Xiao
authors.initials: X
authors.lastname: Feng
authors.affiliation: Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081, P. R. China.
authors.forename: Shan
authors.initials: S
authors.lastname: Wang
authors.affiliation: Key Laboratory of Explosion Science and Technology of China, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081, P. R. China.
authors.forename: Naimeng
authors.initials: N
authors.lastname: Song
authors.affiliation: Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081, P. R. China.
authors.forename: Yifa
authors.initials: Y
authors.lastname: Chen
authors.affiliation: Key Laboratory of Explosion Science and Technology of China, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081, P. R. China.
authors.forename: Wenchao
authors.initials: W
authors.lastname: Tong
authors.affiliation: Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081, P. R. China.
authors.forename: Yuzhen
authors.initials: Y
authors.lastname: Han
authors.affiliation: Key Laboratory of Explosion Science and Technology of China, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081, P. R. China.
authors.forename: Li
authors.initials: L
authors.lastname: Yang
authors.affiliation: Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing, 100081, P. R. China.
authors.forename: Bo
authors.initials: B
authors.lastname: Wang
keywords: copper azide; electrostatic sensitivity; energetic materials; metal-organic frameworks; primary explosives