title: Probing the molecular character of periodic mesoporous organosilicates via photoluminescence of Lewis acid-base adducts.
abstract: Photoluminescence decay was used as a structure-sensitive method to compare the distribution of emitting sites in periodic mesoporous organosilicates (PMOs) to their respective molecular analogs. The observed close similarity of PL decays confirms the molecular nature of PMOs and high homogeneity of emitting sites.
authors.affiliation: Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1-5, 8093 Zürich, Switzerland. ccoperet@ethz.ch.
authors.forename: Indre
authors.initials: I
authors.lastname: Thiel
authors.affiliation: Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1-5, 8093 Zürich, Switzerland. ccoperet@ethz.ch.
authors.forename: Alexey
authors.initials: A
authors.lastname: Fedorov
authors.affiliation: Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1-5, 8093 Zürich, Switzerland. ccoperet@ethz.ch.
authors.forename: Rene
authors.initials: R
authors.lastname: Verel
authors.affiliation: Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1-5, 8093 Zürich, Switzerland. ccoperet@ethz.ch.
authors.forename: Sergii
authors.initials: S
authors.lastname: Yakunin
authors.affiliation: Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1-5, 8093 Zürich, Switzerland. ccoperet@ethz.ch.
authors.forename: Maksym V
authors.initials: MV
authors.lastname: Kovalenko
authors.affiliation: Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1-5, 8093 Zürich, Switzerland. ccoperet@ethz.ch.
authors.forename: Christophe
authors.initials: C
authors.lastname: Copéret