title: Palladium-catalysed hydroamidocarbonylation of 1,3-dienes.
abstract: Herein, we report our recent result on the development of the selective catalytic method towards the synthesis of β,γ-unsaturated imides via Pd-catalysed hydroamidocarbonylation of conjugated dienes. Note that this reaction proceeds under acid additive free conditions. Various dienes, including those of high industrial value (e.g. isoprene, 1,3-butadiene), are shown to be compatible with our established method (28 examples, 40-99% yield), which leads to the corresponding β,γ-unsaturated imides in a highly efficient and atom-economic fashion.
authors.affiliation: Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany. matthias.beller@catalysis.de.
authors.forename: Haoquan
authors.initials: H
authors.lastname: Li
authors.forename: Xianjie
authors.initials: X
authors.lastname: Fang
authors.forename: Ralf
authors.initials: R
authors.lastname: Jackstell
authors.forename: Helfried
authors.initials: H
authors.lastname: Neumann
authors.forename: Matthias
authors.initials: M
authors.lastname: Beller