title: Autoxidative C(sp(2))-P Formation: Direct Phosphorylation of Heteroarenes under Oxygen, Metal-Free, and Solvent-Free Conditions.
abstract: We reveal here a direct autoxidative phosphorylation of heteroarenes induced by oxygen under metal-free and solvent-free conditions. This new methodology provides an economical, operationally simple, and environmentally friendly approach toward (Het)C(sp(2))-P formation with medium to excellent yields. Heteroarenes including thiazole and quinoxaline derivatives are applicable under standard conditions, which is testified via a radical mechanism.
authors.affiliation: Jiangsu Key Laboratory of Pesticide Science and Department of Chemistry, College of Sciences, Nanjing Agricultural University , Nanjing 210095, P. R. China.|College of Plant Protection, Nanjing Agricultural University , Nanjing 210095, P. R. China.
authors.forename: Kai
authors.initials: K
authors.lastname: Luo
authors.affiliation: Jiangsu Key Laboratory of Pesticide Science and Department of Chemistry, College of Sciences, Nanjing Agricultural University , Nanjing 210095, P. R. China.|College of Plant Protection, Nanjing Agricultural University , Nanjing 210095, P. R. China.
authors.forename: Yao-Zhong
authors.initials: YZ
authors.lastname: Chen
authors.affiliation: Jiangsu Key Laboratory of Pesticide Science and Department of Chemistry, College of Sciences, Nanjing Agricultural University , Nanjing 210095, P. R. China.
authors.forename: Li-Xian
authors.initials: LX
authors.lastname: Chen
authors.affiliation: Jiangsu Key Laboratory of Pesticide Science and Department of Chemistry, College of Sciences, Nanjing Agricultural University , Nanjing 210095, P. R. China.|Beijing National Laboratory for Molecular Sciences and Institute of Chemistry, Chinese Academy of Sciences , Beijing 100190, P. R. China.
authors.forename: Lei
authors.initials: L
authors.lastname: Wu