title: Facilitated fabrication of high strength silica aerogels using cellulose nanofibrils as scaffold.
abstract: Monolithic cellulose nanofibrils (CNF)-silica composite aerogels were successfully prepared by immersing CNF aerogels into a silica solution in a two-step sol-gel process (initial hydrolysis of tetraethyl orthosilicate (TEOS) followed by condensation of silica particles). Aerogels were characterized by SEM, BET surface area test, bulk density and silica content analysis, FTIR spectroscopy, and compression test. The form of SiO2 existing in the composite aerogel was the spherical individual particles coated on CNF fibrils. The pH value of condensation solution was found to have great influence on the properties of the composite aerogels. By varying the pH value of condensation atmosphere from 8 to 12, the bulk densities of composite aerogels were able to be linearly increased from 0.059gcm(-3) to 0.29gcm(-3)，and the silica content in the matrix sharply jumped from 3wt% to 79wt%. The porosities of the aerogels remained very high, between 85 and 96%, and the surface area of the composite aerogel reached up to 700.1m(2)g(-1). The compression properties of the composite aerogel improved greatly compared with those of the silica aerogel, about 8-30 times higher. Moreover, the compressive strength of the composite aerogel prepared in this work greatly exceeded the conventional insulation materials found in the recent commercial market, and without substantial increases in thermal conductivity. Hence, the findings of this research offer a promising application for composite aerogels and give a theoretical basis for developing new advanced materials.
authors.affiliation: College of Engineering, Nanjing Agricultural University, Nanjing, 210031, China; Center for Renewable Carbon, University of Tennessee, Knoxville, TN 37996, USA.
authors.forename: Jingjing
authors.initials: J
authors.lastname: Fu
authors.affiliation: Center for Renewable Carbon, University of Tennessee, Knoxville, TN 37996, USA; Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing, 100091, China. Electronic address: swang@utk.edu.
authors.forename: Siqun
authors.initials: S
authors.lastname: Wang
authors.affiliation: College of Engineering, Nanjing Agricultural University, Nanjing, 210031, China. Electronic address: chunxiahe@tom.com.
authors.forename: Chunxia
authors.initials: C
authors.lastname: He
authors.affiliation: Center for Renewable Carbon, University of Tennessee, Knoxville, TN 37996, USA; College of Chemical Engineering, Fujian Agriculture and Forestry University, Fuzhou, 350002, China.
authors.forename: Zexiang
authors.initials: Z
authors.lastname: Lu
authors.affiliation: Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing, 100091, China.
authors.forename: Jingda
authors.initials: J
authors.lastname: Huang
authors.affiliation: Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing, 100091, China.
authors.forename: Zhilin
authors.initials: Z
authors.lastname: Chen
mesh_terms: D002482:Cellulose / Q000737:chemistry*; D005782:Gels / Q000138:chemical synthesis*; D006863:Hydrogen-Ion Concentration; D000074266:Materials Science; D057139:Nanofibers / Q000737:chemistry*; D016062:Porosity; D012822:Silicon Dioxide / Q000737:chemistry*
chemical_list: D005782:Gels; D012822:Silicon Dioxide; D002482:Cellulose
keywords: Aerogels; Cellulose; Compression properties; Insulation; Silica