title: Nitrate decontamination through functionalized chitosan in brackish water.
abstract: N, N, N-Triethyl ammonium functionalized cross-linked chitosan beads (TEACCB) was prepared by alkylation of glutaraldehyde cross-linked chitosan beads to remove nitrate from brackish water. Physico-chemical characteristics of TEACCB were analyzed using FTIR, SEM, EDAX, TGA, DTA, BET surface area, swelling ratio and pHzpc. The maximum nitrate removal capacity of TEACCB was 2.26meq/g and is higher than other reported chitosan based adsorbents. Nitrate removal ratio in the presence and absence of common anions like chloride and sulphate demonstrated the selectively of TEACCB towards nitrate. The kinetic data of nitrate removal fitted well with the pseudo-second-order kinetic model. The thermodynamic parameters indicated that nitrate removal could be spontaneous and exothermic in nature. TEACCB was reused with 100% efficiency after regenerating with 0.05N HCl. Column study was carried out to remove nitrate from brackish water. These results are very significant to develop TEACCB based nitrate removal technology with great efficiency.
authors.affiliation: Department of Chemical Engineering, School of Bioengineering, SRM University, Kattankulathur-603 203, Kancheepuram District, Tamil Nadu, India.
authors.forename: Sowmya
authors.initials: S
authors.lastname: Appunni
authors.affiliation: Department of Chemical Engineering, School of Bioengineering, SRM University, Kattankulathur-603 203, Kancheepuram District, Tamil Nadu, India.
authors.forename: Mathur P
authors.initials: MP
authors.lastname: Rajesh
authors.affiliation: Department of Chemical Engineering, School of Bioengineering, SRM University, Kattankulathur-603 203, Kancheepuram District, Tamil Nadu, India. Electronic address: sivaprabha50@gmail.com.
authors.forename: Sivaraman
authors.initials: S
authors.lastname: Prabhakar
mesh_terms: D048271:Chitosan / Q000737:chemistry*; D003666:Decontamination / Q000379:methods*; D007700:Kinetics; D008956:Models, Chemical; D009566:Nitrates / Q000737:chemistry / Q000302:isolation & purification*; D000068357:Saline Waters; D013696:Temperature; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000378:metabolism
chemical_list: D009566:Nitrates; D014874:Water Pollutants, Chemical; D048271:Chitosan
keywords: Brackish water; Chitosan; Column study; Nitrate