title: Metallogrid Single-Molecule Magnet: Solvent-Induced Nuclearity Transformation and Magnetic Hysteresis at 16 K.
abstract: Structural assembly and reversible transformation between a metallogrid Dy4 SMM (2) and its fragment Dy2 (1) were established in the different solvent media. The zero-field magnetization relaxation was slowed for dysprosium metallogrid (2) with relaxation barrier of Ueff = 61.3 K when compared to Dy2 (1). Both magnetic dilution and application of a moderate magnetic field suppress ground-state quantum tunneling of magnetization and result in an enhanced Ueff of 119.9 and 96.7 K for 2, respectively. Interestingly, the lanthanide metallogrid complex (2) exhibits magnetic hysteresis loop even up to 16 K at a given field sweep rate of 500 Oe/s.
authors.affiliation: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Collaborative Innovation Center of Advanced Catalysis & Green Manufacturing, School of Petrochemical Engineering, Changzhou University , Changzhou, Jiangsu 213164, China.
authors.forename: Wei
authors.initials: W
authors.lastname: Huang
authors.affiliation: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Collaborative Innovation Center of Advanced Catalysis & Green Manufacturing, School of Petrochemical Engineering, Changzhou University , Changzhou, Jiangsu 213164, China.
authors.forename: Fu-Xing
authors.initials: FX
authors.lastname: Shen
authors.affiliation: Institute for Materials Chemistry and Engineering, Kyushu University , 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan.
authors.forename: Shu-Qi
authors.initials: SQ
authors.lastname: Wu
authors.affiliation: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Collaborative Innovation Center of Advanced Catalysis & Green Manufacturing, School of Petrochemical Engineering, Changzhou University , Changzhou, Jiangsu 213164, China.
authors.forename: Li
authors.initials: L
authors.lastname: Liu
authors.affiliation: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Collaborative Innovation Center of Advanced Catalysis & Green Manufacturing, School of Petrochemical Engineering, Changzhou University , Changzhou, Jiangsu 213164, China.
authors.forename: Dayu
authors.initials: D
authors.lastname: Wu
authors.affiliation: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Collaborative Innovation Center of Advanced Catalysis & Green Manufacturing, School of Petrochemical Engineering, Changzhou University , Changzhou, Jiangsu 213164, China.
authors.forename: Zhe
authors.initials: Z
authors.lastname: Zheng
authors.affiliation: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Collaborative Innovation Center of Advanced Catalysis & Green Manufacturing, School of Petrochemical Engineering, Changzhou University , Changzhou, Jiangsu 213164, China.
authors.forename: Jun
authors.initials: J
authors.lastname: Xu
authors.affiliation: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Collaborative Innovation Center of Advanced Catalysis & Green Manufacturing, School of Petrochemical Engineering, Changzhou University , Changzhou, Jiangsu 213164, China.
authors.forename: Ming
authors.initials: M
authors.lastname: Zhang
authors.affiliation: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Collaborative Innovation Center of Advanced Catalysis & Green Manufacturing, School of Petrochemical Engineering, Changzhou University , Changzhou, Jiangsu 213164, China.
authors.forename: Xing-Cai
authors.initials: XC
authors.lastname: Huang
authors.affiliation: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Collaborative Innovation Center of Advanced Catalysis & Green Manufacturing, School of Petrochemical Engineering, Changzhou University , Changzhou, Jiangsu 213164, China.
authors.forename: Jun
authors.initials: J
authors.lastname: Jiang
authors.affiliation: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Collaborative Innovation Center of Advanced Catalysis & Green Manufacturing, School of Petrochemical Engineering, Changzhou University , Changzhou, Jiangsu 213164, China.
authors.forename: Feifei
authors.initials: F
authors.lastname: Pan
authors.affiliation: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Collaborative Innovation Center of Advanced Catalysis & Green Manufacturing, School of Petrochemical Engineering, Changzhou University , Changzhou, Jiangsu 213164, China.
authors.forename: Yao
authors.initials: Y
authors.lastname: Li
authors.affiliation: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Collaborative Innovation Center of Advanced Catalysis & Green Manufacturing, School of Petrochemical Engineering, Changzhou University , Changzhou, Jiangsu 213164, China.
authors.forename: Kun
authors.initials: K
authors.lastname: Zhu
authors.affiliation: Institute for Materials Chemistry and Engineering, Kyushu University , 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan.
authors.forename: Osamu
authors.initials: O
authors.lastname: Sato