title: Synthetic Methodology for the Fabrication of Porous Porphyrin Materials with Metal-Organic-Polymer Aerogels.
abstract: A promising fabrication strategy used for designing porous porphyrin materials and a group of rigid carboxyl porphyrins based metal-organic-polymer aerogels (MOPAs) has been proposed recently. These newly synthesized MOPAs were exemplarily characterized by FT-IR, UV-vis-DRS, EDS, PXRD, TGA, SEM, TEM, and gas sorption measurements. A gelation study has shown that solvents, molar ratio, temperature, and peripheral carboxyl number in porphyrins all affect gel generation. The MOPA series exhibit eminent thermal stability, high removal efficiency in dye adsorption, versatile morphologies, and permanent tunable porosity; also the BET surface areas fall within the range 249-779 m(2) g(-1). All of the mentioned properties are significantly superior to some other porous materials, which enable these compounds to be potential candidates for dye uptake, gas storage, and separation.
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry & Materials Science, Northwest University , Xi'an, Shaanxi 710069, China.
authors.forename: Xin
authors.initials: X
authors.lastname: Zhao
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry & Materials Science, Northwest University , Xi'an, Shaanxi 710069, China.|Xi'an Tieyi Binhe School , Xi'an, Shaanxi 710038, China.
authors.forename: Lin
authors.initials: L
authors.lastname: Yuan
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry & Materials Science, Northwest University , Xi'an, Shaanxi 710069, China.
authors.forename: Zeng-Qi
authors.initials: ZQ
authors.lastname: Zhang
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry & Materials Science, Northwest University , Xi'an, Shaanxi 710069, China.
authors.forename: Yong-Song
authors.initials: YS
authors.lastname: Wang
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry & Materials Science, Northwest University , Xi'an, Shaanxi 710069, China.
authors.forename: Qiong
authors.initials: Q
authors.lastname: Yu
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry & Materials Science, Northwest University , Xi'an, Shaanxi 710069, China.
authors.forename: Jun
authors.initials: J
authors.lastname: Li