title: The Suppression of Columnar π-Stacking in 3-Adamantyl-1-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl.
abstract: 3-Adamantyl-1-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl (4) crystallizes as chains of radicals where the spin bearing benzotriazinyl moieties are isolated from each other. Magnetic susceptibility studies in the 5-300 K temperature region indicate that radical 4 demonstrates typical paramagnetic behavior stemming from non-interacting S = ½ spins.
authors.affiliation: Department of Chemistry, University of Cyprus, P. O. Box 20537, Nicosia 1678, Cyprus. constantinides.christos@ucy.ac.cy.
authors.forename: Christos P
authors.initials: CP
authors.lastname: Constantinides
authors.affiliation: Department of Chemistry, University of Cyprus, P. O. Box 20537, Nicosia 1678, Cyprus. berezin.andrey@ucy.ac.cy.
authors.forename: Andrey A
authors.initials: AA
authors.lastname: Berezin
authors.affiliation: Department of Chemistry, University of Cyprus, P. O. Box 20537, Nicosia 1678, Cyprus. georgia_zissimou@hotmail.com.
authors.forename: Georgia A
authors.initials: GA
authors.lastname: Zissimou
authors.affiliation: Department of Chemistry, University of Cyprus, P. O. Box 20537, Nicosia 1678, Cyprus. manoli.maria@ucy.ac.cy.
authors.forename: Maria
authors.initials: M
authors.lastname: Manoli
authors.affiliation: Department of Chemical Research Support, Weizmann Institute of Science, Rehovot 76100, Israel. gregory.leitus@weizmann.ac.il.
authors.forename: Gregory M
authors.initials: GM
authors.lastname: Leitus
authors.affiliation: Department of Chemistry, University of Cyprus, P. O. Box 20537, Nicosia 1678, Cyprus. koutenti@ucy.ac.cy.
authors.forename: Panayiotis A
authors.initials: PA
authors.lastname: Koutentis
mesh_terms: D018360:Crystallography, X-Ray; D008958:Models, Molecular; D013113:Spin Labels; D014227:Triazines / Q000737:chemistry*
chemical_list: D013113:Spin Labels; D014227:Triazines
keywords: 1,2,4-benzotriazinyls; adamantyl; crystal packing; hydrazyls; organic radicals; paramagnet