title: Lead ion induced chemodosimeter approach of a tripodal hydroxyl-quinoline based phospho-ester through P-O bond cleavage.
abstract: Lead ion induced P-O bond breaking with instant colour change was observed in a tripodal hydroxyl-quinoline based phosphor-ester (). A new penta-coordinated lead chelate complex [Pb4HQ6(ClO4)2] was found. The hydrolysis reaction followed by P-O bond cleavage with 'Pb-O' and 'Pb-N' bond formation proved the chemodosimeter approach.
authors.affiliation: Department of Applied Chemistry, Indian School of Mines, Dhanbad, Jharkhand 826004, India. dey.s.ac@ismdhanbad.ac.in hpnayek@yahoo.com.
authors.forename: Dibyendu
authors.initials: D
authors.lastname: Sain
authors.affiliation: Department of Applied Chemistry, Indian School of Mines, Dhanbad, Jharkhand 826004, India. dey.s.ac@ismdhanbad.ac.in hpnayek@yahoo.com.
authors.forename: Chanda
authors.initials: C
authors.lastname: Kumari
authors.affiliation: Department of Applied Chemistry, Indian School of Mines, Dhanbad, Jharkhand 826004, India. dey.s.ac@ismdhanbad.ac.in hpnayek@yahoo.com.
authors.forename: Ashish
authors.initials: A
authors.lastname: Kumar
authors.affiliation: Department of Applied Chemistry, Indian School of Mines, Dhanbad, Jharkhand 826004, India. dey.s.ac@ismdhanbad.ac.in hpnayek@yahoo.com.
authors.forename: Hari Pada
authors.initials: HP
authors.lastname: Nayek
authors.affiliation: Department of Applied Chemistry, Indian School of Mines, Dhanbad, Jharkhand 826004, India. dey.s.ac@ismdhanbad.ac.in hpnayek@yahoo.com.
authors.forename: Swapan
authors.initials: S
authors.lastname: Dey