title: Ultrasensitive determination of carbendazim in water and orange juice using a carbon paste electrode.
abstract: A carbon paste electrode was used for the electrochemical quantification of carbendazim in water and orange juice samples. Carbendazim oxidation on the electrode surface was found to be controlled by adsorption. The novel electrochemical procedure for carbendazim quantification employed differential pulse voltammetry using a carbon paste electrode under optimal conditions. Carbendazim oxidation currents were linear at concentrations of 2.84 to 45.44 µg L(-1), with a limit of detection of 0.96 µg L(-1). The proposed method was applied to carbendazim quantification in ultrapurified water, river water, and orange juice. Recovery rates in water and orange juice samples were in the 97%-101% range, indicating that the method can be employed to determine carbendazim in these matrices, with advantages including shorter analysis time and lower cost than routine methods such as chromatography or spectroscopy. The electrode showed good reproducibility, remarkable stability, and especially good surface renewability by simple mechanical polishing. The recovery rates observed were highly concordant with those obtained for high-performance liquid chromatography, having a relative standard deviation of less than 1.3%.
authors.affiliation: a Chemistry Program, Universidade Estadual de Mato Grosso do Sul , Dourados , MS , Brazil.
authors.forename: Gilberto J
authors.initials: GJ
authors.lastname: Arruda
authors.affiliation: b Institute of Chemistry, Universidade Federal de Mato Grosso do Sul , Campo Grande , MS , Brazil.
authors.forename: Fábio De
authors.initials: FD
authors.lastname: Lima
authors.affiliation: a Chemistry Program, Universidade Estadual de Mato Grosso do Sul , Dourados , MS , Brazil.
authors.forename: Claudia A L
authors.initials: CA
authors.lastname: Cardoso
mesh_terms: D001562:Benzimidazoles / Q000032:analysis*; D002219:Carbamates / Q000032:analysis*; D002244:Carbon / Q000032:analysis*; D032084:Citrus sinensis / Q000737:chemistry*; D017097:Electric Impedance; D004566:Electrodes; D015203:Reproducibility of Results; D014867:Water / Q000032:analysis*
chemical_list: D001562:Benzimidazoles; D002219:Carbamates; D014867:Water; D002244:Carbon; C006698:carbendazim
keywords: Carbendazim; carbon paste electrode; cyclic voltammetry; differential pulse voltammetry; orange juice; water