title: Interactions of titania based nanoparticles with silica and green-tea: Photo-degradation and -luminescence.
abstract: An effective way to modify the photocatalytic activity of both anatase and rutile TiO2 nanoparticles by coating the surface with either an inorganic (SiO2/silica) or organic (green-tea) layer using a chemical approach is demonstrated. Tetraethyl orthosilicate (TEOS) was used to cover the surface of TiO2 with silica which facilitates the inhibition of photocatalytic activity, ensuring its application in sunscreens by blocking the reactive oxygen species (ROS). Green-tea extract, rich in epigallocatechin gallate (EGCG), was used to coat/stabilize nano-sized TiO2. The morphology of these coatings was revealed by transmission electron microscopy (TEM) and by energy dispersive spectroscopy (EDS) mapping. These studies showed good coverage for both types of coating, but with somewhat better uniformity of the coating layer on rutile TiO2 compared to anatase due to its more uniform particle geometry. The effectiveness of each coating was evaluated by photodegradation of an organic dye (methyl orange). These studies showed rutile_polyphenol exhibits the highest photocatalytic activity among rutile forms which validates its feasibility to be used in photodegradation.
authors.affiliation: Academy of Scientific and Innovative Research, CSIR - National Physical Laboratory, Dr. K. S. Krishnan Road, New Delhi 110012, India.
authors.forename: Rajni
authors.initials: R
authors.lastname: Verma
authors.affiliation: Academy of Scientific and Innovative Research, CSIR - National Physical Laboratory, Dr. K. S. Krishnan Road, New Delhi 110012, India.
authors.forename: Aditi
authors.initials: A
authors.lastname: Awasthi
authors.affiliation: Academy of Scientific and Innovative Research, CSIR - National Physical Laboratory, Dr. K. S. Krishnan Road, New Delhi 110012, India.
authors.forename: Punita
authors.initials: P
authors.lastname: Singh
authors.affiliation: Academy of Scientific and Innovative Research, CSIR - National Physical Laboratory, Dr. K. S. Krishnan Road, New Delhi 110012, India.
authors.forename: Ritu
authors.initials: R
authors.lastname: Srivastava
authors.affiliation: Electron Microscopy Center - Center for Nanoscale Materials, Argonne National Laboratory, Argonne, IL 60439-4838, USA.
authors.forename: Huaping
authors.initials: H
authors.lastname: Sheng
authors.affiliation: Electron Microscopy Center - Center for Nanoscale Materials, Argonne National Laboratory, Argonne, IL 60439-4838, USA.
authors.forename: Jianguo
authors.initials: J
authors.lastname: Wen
authors.affiliation: Electron Microscopy Center - Center for Nanoscale Materials, Argonne National Laboratory, Argonne, IL 60439-4838, USA.
authors.forename: Dean J
authors.initials: DJ
authors.lastname: Miller
authors.affiliation: Academy of Scientific and Innovative Research, CSIR - National Physical Laboratory, Dr. K. S. Krishnan Road, New Delhi 110012, India. Electronic address: aks@nplindia.org.
authors.forename: Avanish K
authors.initials: AK
authors.lastname: Srivastava
mesh_terms: D002384:Catalysis; D049449:Luminescence; D053758:Nanoparticles / Q000737:chemistry*; D010316:Particle Size; D055668:Photochemical Processes; D059808:Polyphenols / Q000737:chemistry; D012822:Silicon Dioxide / Q000737:chemistry*; D013499:Surface Properties; D013662:Tea / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*
chemical_list: D059808:Polyphenols; D013662:Tea; C009495:titanium dioxide; D012822:Silicon Dioxide; D014025:Titanium
keywords: Electron microscopy; Green-tea; Photocatalytic activity; Silica; TiO(2) nanoparticles