title: Laser Measurements of the H Atom + Ozone Rate Constant at Mesospheric Temperatures.
abstract: The exothermic H + O3 reaction produces OH(v) Meinel band emissions, used to derive mesospheric H concentrations and chemical heating rates. We remeasured its rate constant to reduce its uncertainty and extended the measurements to lower mesospheric temperatures using modern laser-induced fluorescence (LIF) techniques. H atoms were produced by pulsed ultraviolet laser trace photolysis of O3, followed by reaction of O((1)D) with added H2. A second, delayed, frequency-mixed dye laser measured the reaction decay rate with the remaining ozone using LIF. We monitored either the H atom decay by two photon excitation at 205 nm and detection of red fluorescence, or the OH (v = 9) product time evolution with excitation of the B(2)Σ(+)-X(2)Π (0,9) band at 237 nm and emission in the blue B(2)Σ(+)-A(2)Σ(+) (0,7) band. By cooling the enclosed low pressure flow cell we obtained measurements from 140 to 305 K at 20 to 200 Torr in Ar. Small kinetic modeling corrections were made for secondary regeneration of H atoms. The results are consistent with the current NASA JPL recommendation for this rate constant and establish its extrapolation down to the lower temperatures of the mesosphere.
authors.affiliation: SRI International , 333 Ravenswood Avenue, Menlo Park, California 94025, United States.
authors.forename: Yingdi
authors.initials: Y
authors.lastname: Liu
authors.affiliation: SRI International , 333 Ravenswood Avenue, Menlo Park, California 94025, United States.
authors.forename: Jian
authors.initials: J
authors.lastname: Peng
authors.affiliation: SRI International , 333 Ravenswood Avenue, Menlo Park, California 94025, United States.
authors.forename: Kelsey
authors.initials: K
authors.lastname: Reppert
authors.affiliation: SRI International , 333 Ravenswood Avenue, Menlo Park, California 94025, United States.
authors.forename: Sara
authors.initials: S
authors.lastname: Callahan
authors.affiliation: SRI International , 333 Ravenswood Avenue, Menlo Park, California 94025, United States.
authors.forename: Gregory P
authors.initials: GP
authors.lastname: Smith