title: Hierarchically-Porous Carbon Derived from a Large-Scale Iron-based Organometallic Complex for Versatile Energy Storage.
abstract: Inspired by the preparation of the hierarchically-porous carbon (HPC) derived from metal organic frameworks (MOFs) for energy storage, in this work, a simple iron-based metal- organic complex (MOC), which was simpler and cheaper compared with the MOF, was selected to achieve versatile energy storage. The intertwined 1 D nanospindles and enriched-oxygen doping of the HPC was obtained after one-step carbonization of the MOC. When employed in lithium-ion batteries, the HPC exhibited reversible capacity of 778 mA h g(-1) after 60 cycles at 50 mA g(-1) . Moreover, the HPC maintained a capacity of 188 mA h g(-1) after 400 cycles at 100 mA g(-1) as the anode material in a sodium-ion battery. In addition, the HPC served as the cathode matrix for evaluation of a lithium-sulfur battery. The general preparation process of the HPC is commercial, which is responsible for the large-scale production for its practical application.
authors.affiliation: Faculty of Chemistry, National & Local United Engineering Laboratory for Power Batteries, Northeast Normal University, Changchun, 130024, China.
authors.forename: Chao-Ying
authors.initials: CY
authors.lastname: Fan
authors.affiliation: Faculty of Chemistry, National & Local United Engineering Laboratory for Power Batteries, Northeast Normal University, Changchun, 130024, China.
authors.forename: Huan-Huan
authors.initials: HH
authors.lastname: Li
authors.affiliation: Faculty of Chemistry, National & Local United Engineering Laboratory for Power Batteries, Northeast Normal University, Changchun, 130024, China.
authors.forename: Hai-Feng
authors.initials: HF
authors.lastname: Wang
authors.affiliation: Faculty of Chemistry, National & Local United Engineering Laboratory for Power Batteries, Northeast Normal University, Changchun, 130024, China. sunhz335@nenu.edu.cn.
authors.forename: Hai-Zhu
authors.initials: HZ
authors.lastname: Sun
authors.affiliation: Faculty of Chemistry, National & Local United Engineering Laboratory for Power Batteries, Northeast Normal University, Changchun, 130024, China. xinglong@nenu.edu.cn.
authors.forename: Xing-Long
authors.initials: XL
authors.lastname: Wu
authors.affiliation: Faculty of Chemistry, National & Local United Engineering Laboratory for Power Batteries, Northeast Normal University, Changchun, 130024, China. jpzhang@nenu.edu.cn.
authors.forename: Jing-Ping
authors.initials: JP
authors.lastname: Zhang
mesh_terms: D002244:Carbon / Q000737:chemistry*; D011211:Electric Power Supplies; D007501:Iron / Q000737:chemistry*; D008094:Lithium / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D016062:Porosity; D013455:Sulfur / Q000737:chemistry; D013696:Temperature
chemical_list: D009942:Organometallic Compounds; D013455:Sulfur; D002244:Carbon; D008094:Lithium; D007501:Iron
keywords: energy storage; hierarchical porosity; large-scale production; nanospindles; organometallic complex