title: Evaluation of flow injection analysis method with spectrophotometric detection for the determination of atrazine in soil extracts.
abstract: A method for determining atrazine in soil extracts was evaluated by flow injection analysis with spectrophotometric detection. The method is based on the reaction of atrazine with pyridine in an acid medium followed by the reaction with NaOH and sulfanilic acid. Several analytical conditions were previously studied and optimized. Under the best conditions of analysis, the limits of detection and quantification were 0.15 and 0.45 mg L(-1), respectively, for a linear response between 0.50 and 2.50 mg L(-1), and a sampling throughput of 21 determinations per hour. Using the standard addition method, the maximum relative standard deviation of 17% and recovery values between 80 and 100% were observed for three extracts from soil samples with different composition. The proposed method is simple, low-cost and easy to use, and can be employed for studies involving atrazine in soil samples or for screening of atrazine in soils.
authors.affiliation: a Department of Chemistry , Federal University of Paraná , Curitiba , PR , Brazil.
authors.forename: Elisandra C
authors.initials: EC
authors.lastname: Martins
authors.affiliation: b Department of Soil Science , Federal University of Paraná , Curitiba , PR , Brazil.
authors.forename: Vander De F
authors.initials: Vde F
authors.lastname: Melo
authors.affiliation: a Department of Chemistry , Federal University of Paraná , Curitiba , PR , Brazil.
authors.forename: Gilberto
authors.initials: G
authors.lastname: Abate
mesh_terms: D001280:Atrazine / Q000032:analysis*; D004784:Environmental Monitoring / Q000379:methods*; D017022:Flow Injection Analysis; D006540:Herbicides / Q000032:analysis*; D012987:Soil / Q000737:chemistry*; D012989:Soil Pollutants / Q000032:analysis*; D013053:Spectrophotometry / Q000379:methods
chemical_list: D006540:Herbicides; D012987:Soil; D012989:Soil Pollutants; D001280:Atrazine
keywords: Atrazine; FIA; soil; spectrophotometry