title: Characterization of PdH-C interactions in bis-dimethyldithiocarbamate palladium(ii) and its deuterated analog by luminescence spectroscopy at variable pressure.
abstract: We present the variable-pressure d-d luminescence spectra of crystalline bis-dimethyldithiocarbamate palladium(ii) and its deuterated analog. The energies and shifts of the band maxima provide evidence for intermolecular PdH-C interactions, with quantitative differences observed for the deuterated complex. Shifts show distinct interactions in three pressure ranges between 1 bar and 85 kbar.
authors.affiliation: Département de chimie, Université de Montréal, Montréal, Québec H3C 3J7, Canada. christian.reber@umontreal.ca.
authors.forename: Stéphanie
authors.initials: S
authors.lastname: Poirier
authors.affiliation: Département de chimie, Université de Montréal, Montréal, Québec H3C 3J7, Canada. christian.reber@umontreal.ca.
authors.forename: Elodie
authors.initials: E
authors.lastname: Tailleur
authors.affiliation: Département de chimie, Université de Montréal, Montréal, Québec H3C 3J7, Canada. christian.reber@umontreal.ca.
authors.forename: Hudson
authors.initials: H
authors.lastname: Lynn
authors.affiliation: Département de chimie, Université de Montréal, Montréal, Québec H3C 3J7, Canada. christian.reber@umontreal.ca.
authors.forename: Christian
authors.initials: C
authors.lastname: Reber