title: Organic Nitrate Contribution to New Particle Formation and Growth in Secondary Organic Aerosols from α-Pinene Ozonolysis.
abstract: The chemical kinetics of organic nitrate production during new particle formation and growth of secondary organic aerosols (SOA) were investigated using the short-lived radioactive tracer (13)N in flow-reactor studies of α-pinene oxidation with ozone. Direct and quantitative measurements of the nitrogen content indicate that organic nitrates accounted for ∼40% of SOA mass during initial particle formation, decreasing to ∼15% upon particle growth to the accumulation-mode size range (>100 nm). Experiments with OH scavengers and kinetic model results suggest that organic peroxy radicals formed by α-pinene reacting with secondary OH from ozonolysis are key intermediates in the organic nitrate formation process. The direct reaction of α-pinene with NO3 was found to be less important for particle-phase organic nitrate formation. The nitrogen content of SOA particles decreased slightly upon increase of relative humidity up to 80%. The experiments show a tight correlation between organic nitrate content and SOA particle-number concentrations, implying that the condensing organic nitrates are among the extremely low volatility organic compounds (ELVOC) that may play an important role in the nucleation and growth of atmospheric nanoparticles.
authors.affiliation: Multiphase Chemistry Department, Max Planck Institute for Chemistry , Mainz 55128, Germany.
authors.forename: Thomas
authors.initials: T
authors.lastname: Berkemeier
authors.affiliation: Laboratory of Environmental Chemistry, Paul Scherrer Institute , Villigen 5232, Switzerland.
authors.forename: Markus
authors.initials: M
authors.lastname: Ammann
authors.affiliation: Institute of Energy and Climate Research , IEK-8, Forschungszentrum Jülich, Jülich 52425, Germany.
authors.forename: Thomas F
authors.initials: TF
authors.lastname: Mentel
authors.affiliation: Multiphase Chemistry Department, Max Planck Institute for Chemistry , Mainz 55128, Germany.
authors.forename: Ulrich
authors.initials: U
authors.lastname: Pöschl
authors.affiliation: Multiphase Chemistry Department, Max Planck Institute for Chemistry , Mainz 55128, Germany.
authors.forename: Manabu
authors.initials: M
authors.lastname: Shiraiwa
mesh_terms: D000336:Aerosols; D000393:Air Pollutants / Q000737:chemistry*; D039821:Monoterpenes / Q000737:chemistry; D009566:Nitrates / Q000737:chemistry; D010126:Ozone / Q000737:chemistry; D010316:Particle Size; D055549:Volatile Organic Compounds / Q000737:chemistry
chemical_list: D000336:Aerosols; D000393:Air Pollutants; D039821:Monoterpenes; D009566:Nitrates; D055549:Volatile Organic Compounds; D010126:Ozone