title: Pyrene-fused Acenes and Azaacenes: Synthesis and Applications.
abstract: In this account, the synthesis and applications of pyrene-fused acenes, as well as pyrene-fused azaacenes, have been carefully reviewed. Moreover, the synthetic methods involving two key synthons (different lengths of dienes and ynes) have been included. Furthermore, the "clean reaction" strategy has been introduced for the preparation of pyrene-fused acenes with a single terminal-pyrene unit from tetracene to octacene, as well as for the synthesis of pyrene-fused octatwistacenes and nonatwistacenes with double terminal-pyrene units. Similarly, the synthons and the synthetic methods for pyrene-fused azaacenes have also been summarized. The applications of pyrene-fused acenes and pyrene-fused azaacenes have been included.
authors.affiliation: School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, 693 Xiongchu Avenue, Wuhan, Hubei, 430073, P. R. China.|School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639738.
authors.forename: Junbo
authors.initials: J
authors.lastname: Li
authors.affiliation: School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, 693 Xiongchu Avenue, Wuhan, Hubei, 430073, P. R. China.
authors.forename: Shao
authors.initials: S
authors.lastname: Chen
authors.affiliation: School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639738.
authors.forename: Zilong
authors.initials: Z
authors.lastname: Wang
authors.affiliation: School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639738.|Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, SPMS-04-01, 21 Nanyang Link, Singapore, 637371.
authors.forename: Qichun
authors.initials: Q
authors.lastname: Zhang
keywords: azaacenes; clean reaction; polycycles; pyrene; synthetic methods