title: C-O/C-H Coupling of Polyfluoroarenes with Aryl Carbamates by Cooperative Ni/Cu Catalysis.
abstract: Cross-coupling of polyfluoroarenes with aryl carbamates through the cleavage of both sp(2) C-O and C-H bonds is reported. The reaction conditions are simple, and only transition-metal catalysts and ligands are essential. Mechanistic studies indicated that Ni catalyst played an important role in activating C-O bond, while the Cu one in activating C-H Bond. The developed system proved to be effective for cross-coupling of terminal alkynes with aryl carbamates.
authors.affiliation: Beijing National Laboratory for Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University , Beijing 100871, China.
authors.forename: Yang
authors.initials: Y
authors.lastname: Wang
authors.affiliation: Shenzhen Graduate School of Peking University , Shenzhen 518055, China.
authors.forename: Song-Bai
authors.initials: SB
authors.lastname: Wu
authors.affiliation: Beijing National Laboratory for Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University , Beijing 100871, China.
authors.forename: Wen-Juan
authors.initials: WJ
authors.lastname: Shi
authors.affiliation: Beijing National Laboratory for Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University , Beijing 100871, China.|State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences , Shanghai 200032, China.
authors.forename: Zhang-Jie
authors.initials: ZJ
authors.lastname: Shi