title: A pseudo-icosahedral cage {Gd12} based on aminomethylphosphonate.
abstract: Reaction of (aminomethyl)phosphonic acid (ampH2) with a mixture of gadolinium and cobalt pivalates under solvothermal conditions, led to a pseudo-icosahedral cage {Gd12}, which shows a large magnetocaloric effect (MCE).
authors.affiliation: Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275, P. R. China. tongml@mail.sysu.edu.cn and School of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK. richard.winpenny@manchester.ac.uk.
authors.forename: Ze-Min
authors.initials: ZM
authors.lastname: Zhang
authors.affiliation: School of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK. richard.winpenny@manchester.ac.uk and Departent of Chemistry, College of Education, Salahaddin University-Erbil, Kurdistan Region, Iraq.
authors.forename: Karzan H
authors.initials: KH
authors.lastname: Zangana
authors.affiliation: School of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK. richard.winpenny@manchester.ac.uk.
authors.forename: Andreas K
authors.initials: AK
authors.lastname: Kostopoulos
authors.affiliation: Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275, P. R. China. tongml@mail.sysu.edu.cn.
authors.forename: Ming-Liang
authors.initials: ML
authors.lastname: Tong
authors.affiliation: School of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK. richard.winpenny@manchester.ac.uk.
authors.forename: Richard E P
authors.initials: RE
authors.lastname: Winpenny