title: Amidines for Versatile Cobalt(III)-Catalyzed Synthesis of Isoquinolines through C-H Functionalization with Diazo Compounds.
abstract: A cobalt(III)-catalyzed C-H/N-H bond functionalization for the synthesis of 1-aminoisoquinolines from aryl amidines and diazo compounds has been developed. The reaction proceeds under mild reaction conditions, obviates the need for oxidants, produces only N2 and H2O as the byproducts, and features a broad substrate scope.
authors.affiliation: School of Pharmaceutical Science, Jiangnan University , Lihu Road 1800, 214122 Wuxi, P. R. China.
authors.forename: Jie
authors.initials: J
authors.lastname: Li
authors.affiliation: School of Pharmaceutical Science, Jiangnan University , Lihu Road 1800, 214122 Wuxi, P. R. China.
authors.forename: Mengyao
authors.initials: M
authors.lastname: Tang
authors.affiliation: School of Pharmaceutical Science, Jiangnan University , Lihu Road 1800, 214122 Wuxi, P. R. China.
authors.forename: Lei
authors.initials: L
authors.lastname: Zang
authors.affiliation: School of Pharmaceutical Science, Jiangnan University , Lihu Road 1800, 214122 Wuxi, P. R. China.
authors.forename: Xiaolei
authors.initials: X
authors.lastname: Zhang
authors.affiliation: School of Pharmaceutical Science, Jiangnan University , Lihu Road 1800, 214122 Wuxi, P. R. China.
authors.forename: Zhao
authors.initials: Z
authors.lastname: Zhang
authors.affiliation: Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen , Tammannstrasse 2, 37077 Göttingen, Germany.
authors.forename: Lutz
authors.initials: L
authors.lastname: Ackermann