title: A mononuclear nonheme cobalt(iii)-hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions.
abstract: A mononuclear nonheme cobalt(iii)-hydroperoxide complex bearing a tetramethylated cyclam ligand, [(12-TMC)Co(III)(OOH)](2+), was synthesized and characterized spectroscopically and computationally; the cobalt(iii)-hydroperoxide complex exhibited an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions.
authors.affiliation: Department of Chemistry and Nano Science, Ewha Womans University, Seoul 03760, Korea. wwnam@ewha.ac.kr.
authors.forename: Woon-Young
authors.initials: WY
authors.lastname: Tcho
authors.forename: Bin
authors.initials: B
authors.lastname: Wang
authors.forename: Yong-Min
authors.initials: YM
authors.lastname: Lee
authors.forename: Kyung-Bin
authors.initials: KB
authors.lastname: Cho
authors.forename: Jason
authors.initials: J
authors.lastname: Shearer
authors.forename: Wonwoo
authors.initials: W
authors.lastname: Nam