title: Orthogonal dual-click diyne for CuAAC and/or SPAAC couplings.
abstract: Carbamate-tethered propargyl and benzocyclononyne moieties within a single molecular unit undergo cycloaddition with azides under complementary CuAAC and/or SPAAC coupling conditions. The carbamate linker can be cleaved by analogy to the -CBz protecting group for click capture-and-release applications.
authors.affiliation: Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida 32306-4390, USA. gdudley@chem.fsu.edu.
authors.forename: Ron R
authors.initials: RR
authors.lastname: Ramsubhag
authors.forename: Gregory B
authors.initials: GB
authors.lastname: Dudley