title: Mixed-Metal Zeolitic Imidazolate Frameworks and their Selective Capture of Wet Carbon Dioxide over Methane.
abstract: A presynthesized, square planar copper imidazole complex, [Cu(imidazole)4](NO3)2, was utilized as a precursor in the synthesis of a new series of zeolitic imidazolate frameworks, termed ZIF-202, -203, and -204. The structures of all three members were solved by single-crystal X-ray diffraction analysis, which revealed ZIF-203 and -204 having successfully integrated square planar units within the backbones of their respective frameworks. As a result of this unit, the structures of both ZIF-203 and -204 were found to adopt unprecedented three-dimensional nets, namely, ntn and thl, respectively. One member of this series, ZIF-204, was demonstrated to be highly porous, exhibit exceptional stability in water, and selectively capture CO2 over CH4 under both dry and wet conditions without any loss in performance over three cycles. Remarkably, the regeneration of ZIF-204 was performed under the mild conditions of flowing a pure N2 gas through the material at ambient temperature.
authors.affiliation: Faculty of Chemistry, University of Science, Vietnam National University-Ho Chi Minh City , Ho Chi Minh City 721337, Vietnam.|Department of Chemistry, School of Education, Can Tho University , Can Tho City 721337, Vietnam.
authors.forename: Nhung T T
authors.initials: NT
authors.lastname: Nguyen
authors.affiliation: Faculty of Chemistry, University of Science, Vietnam National University-Ho Chi Minh City , Ho Chi Minh City 721337, Vietnam.
authors.forename: Tien N H
authors.initials: TN
authors.lastname: Lo
authors.affiliation: Department of Chemistry, Soongsil University , 369 Sangdo-Ro, Dongjak-Gu, Seoul 156-743, Republic of Korea.
authors.forename: Jaheon
authors.initials: J
authors.lastname: Kim
authors.affiliation: Faculty of Chemistry, University of Science, Vietnam National University-Ho Chi Minh City , Ho Chi Minh City 721337, Vietnam.
authors.forename: Huong T D
authors.initials: HT
authors.lastname: Nguyen
authors.affiliation: Faculty of Chemistry, University of Science, Vietnam National University-Ho Chi Minh City , Ho Chi Minh City 721337, Vietnam.|Department of Chemistry, School of Education, Can Tho University , Can Tho City 721337, Vietnam.
authors.forename: Toan B
authors.initials: TB
authors.lastname: Le
authors.affiliation: Department of Chemistry, University of California-Berkeley; Materials Sciences Division, Lawrence Berkeley National Laboratory; and Berkeley Global Science Institute , Berkeley, California 94720, United States.|Center of Research Excellence in Nanotechnology, King Fahd University of Petroleum and Minerals , Dhahran 34464, Saudi Arabia.
authors.forename: Kyle E
authors.initials: KE
authors.lastname: Cordova
authors.affiliation: Department of Chemistry, University of California-Berkeley; Materials Sciences Division, Lawrence Berkeley National Laboratory; and Berkeley Global Science Institute , Berkeley, California 94720, United States.|Center of Research Excellence in Nanotechnology, King Fahd University of Petroleum and Minerals , Dhahran 34464, Saudi Arabia.
authors.forename: Hiroyasu
authors.initials: H
authors.lastname: Furukawa