title: Synthesis of Highly Functionalized Triarylbismuthines by Functional Group Manipulation and Use in Palladium- and Copper-Catalyzed Arylation Reactions.
abstract: Organobismuthines are an attractive class of organometallic reagents that can be accessed from inexpensive and nontoxic bismuth salts. Triarylbismuthines are particularly interesting due to their air and moisture stability and high functional group tolerance. We report herein a detailed study on the preparation of highly functionalized triarylbismuth reagents by triple functional group manipulation and their use in palladium- and copper-catalyzed C-, N-, and O-arylation reactions.
authors.affiliation: Université du Québec à Montréal , Département de Chimie, C.P. 8888, Succursale Centre-Ville, Montréal, Québec, Canada , H3C 3P8.
authors.forename: Martin
authors.initials: M
authors.lastname: Hébert
authors.affiliation: Université du Québec à Montréal , Département de Chimie, C.P. 8888, Succursale Centre-Ville, Montréal, Québec, Canada , H3C 3P8.
authors.forename: Pauline
authors.initials: P
authors.lastname: Petiot
authors.affiliation: Université du Québec à Montréal , Département de Chimie, C.P. 8888, Succursale Centre-Ville, Montréal, Québec, Canada , H3C 3P8.
authors.forename: Emeline
authors.initials: E
authors.lastname: Benoit
authors.affiliation: Université du Québec à Montréal , Département de Chimie, C.P. 8888, Succursale Centre-Ville, Montréal, Québec, Canada , H3C 3P8.
authors.forename: Julien
authors.initials: J
authors.lastname: Dansereau
authors.affiliation: Université du Québec à Montréal , Département de Chimie, C.P. 8888, Succursale Centre-Ville, Montréal, Québec, Canada , H3C 3P8.
authors.forename: Tabinda
authors.initials: T
authors.lastname: Ahmad
authors.affiliation: Université du Québec à Montréal , Département de Chimie, C.P. 8888, Succursale Centre-Ville, Montréal, Québec, Canada , H3C 3P8.
authors.forename: Adrien
authors.initials: A
authors.lastname: Le Roch
authors.affiliation: Concordia University , Department of Chemistry and Biochemistry, 7141 Sherbrooke Street West, Montréal, Québec, Canada , H4B 1R6.
authors.forename: Xavier
authors.initials: X
authors.lastname: Ottenwaelder
authors.affiliation: Université du Québec à Montréal , Département de Chimie, C.P. 8888, Succursale Centre-Ville, Montréal, Québec, Canada , H3C 3P8.
authors.forename: Alexandre
authors.initials: A
authors.lastname: Gagnon