title: Synthesis, characterization, and reactivity of a side-on manganese(iii)-peroxo complex bearing a pentadentate aminopyridine ligand.
abstract: A manganese(ii) complex has been prepared with a proline-derived pentadentate ligand (Pro3Py), and it can be converted to a peroxomanganese(iii) complex in the presence of H2O2 and triethylamine. The resulting peroxomanganese(iii) complex was well characterised by UV-vis, EPR and ESI-MS techniques, and the geometric structure was discussed based on DFT calculations.
authors.affiliation: State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China. wsun@licp.cas.cn wangyong@licp.cas.cn and University of Chinese Academy of Sciences, Beijing 100039, China.
authors.forename: Junyi
authors.initials: J
authors.lastname: Du
authors.affiliation: State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China. wsun@licp.cas.cn wangyong@licp.cas.cn.
authors.forename: Daqian
authors.initials: D
authors.lastname: Xu
authors.affiliation: Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China. chunxizhang@iccas.ac.cn.
authors.forename: Chunxi
authors.initials: C
authors.lastname: Zhang
authors.affiliation: State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China. wsun@licp.cas.cn wangyong@licp.cas.cn.
authors.forename: Chungu
authors.initials: C
authors.lastname: Xia
authors.affiliation: State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China. wsun@licp.cas.cn wangyong@licp.cas.cn.
authors.forename: Yong
authors.initials: Y
authors.lastname: Wang
authors.affiliation: State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China. wsun@licp.cas.cn wangyong@licp.cas.cn.
authors.forename: Wei
authors.initials: W
authors.lastname: Sun