title: Seeded preparation of ultrathin FeS2 nanosheets from Fe3O4 nanoparticles.
abstract: FeS2 nanomaterials with two-dimensional features hold great promise for electrochemical and photovoltaic applications. However, the preparation of ultrathin FeS2 nanosheets is still challenging because of the lack of a tailor-made approach. In this work, FeS2 nanosheets with a thickness of 2.1 nm are prepared through a Fe3O4-seeded approach. Uniform Fe3O4 nanoparticles are foremost synthesized via the standard method in organic media. The injection of a S solution leads to the replacement of O in Fe3O4 through anion-exchange, which generates (110) facet-enriched FeS2 nuclei. The subsequent (110) facet-mediated oriented attachment and fusion of FeS2 nuclei produce ultrathin FeS2 nanosheets. As catalysts in the hydrogen evolution reaction, FeS2 nanosheets exhibit good electrochemical activity.
authors.affiliation: Key Laboratory of Automobile Materials, Ministry of Education, College of Materials Science and Engineering, Jilin University, Changchun 130012, P. R. China and State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P. R. China. hao_zhang@jlu.edu.cn.
authors.forename: Tingting
authors.initials: T
authors.lastname: Li
authors.affiliation: State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P. R. China. hao_zhang@jlu.edu.cn.
authors.forename: Huiwen
authors.initials: H
authors.lastname: Liu
authors.affiliation: State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P. R. China. hao_zhang@jlu.edu.cn.
authors.forename: Zhennan
authors.initials: Z
authors.lastname: Wu
authors.affiliation: State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P. R. China. hao_zhang@jlu.edu.cn.
authors.forename: Yi
authors.initials: Y
authors.lastname: Liu
authors.affiliation: Key Laboratory of Automobile Materials, Ministry of Education, College of Materials Science and Engineering, Jilin University, Changchun 130012, P. R. China.
authors.forename: Zuoxing
authors.initials: Z
authors.lastname: Guo
authors.affiliation: State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P. R. China. hao_zhang@jlu.edu.cn.
authors.forename: Hao
authors.initials: H
authors.lastname: Zhang