title: Conformational Preferences and the Phase Stability of Fullerene Hexa-adducts.
abstract: Molecular conformation and the assembly structure determine the spatial arrangements of the constituent units and the functions of a molecule. Although, fullerene hexa-adducts (FHAs) have been known as functional materials with great versatility, their conformational preferences and phase stability remain a complicate issue. By choosing bithiophene (T2 ) and dodecyl bithiophene (C12 T2 ) as the peripheral units of FHA, and using microscopic, scattering and diffraction characterizations, our study reveals how the intramolecular interaction and environmental stimulus affects the conformational preferences and phase stability of FHAs.
authors.affiliation: Department of Applied Chemistry, National Chiao Tung University, 1001 Ta Hsueh Rd., Hsinchu, 30010, Taiwan.
authors.forename: San-Lien
authors.initials: SL
authors.lastname: Wu
authors.affiliation: Department of Applied Chemistry, National Chiao Tung University, 1001 Ta Hsueh Rd., Hsinchu, 30010, Taiwan.
authors.forename: Chen-Yang
authors.initials: CY
authors.lastname: Hong
authors.affiliation: Department of Applied Chemistry, National Chiao Tung University, 1001 Ta Hsueh Rd., Hsinchu, 30010, Taiwan.
authors.forename: Kuan-Yi
authors.initials: KY
authors.lastname: Wu
authors.affiliation: Department of Applied Chemistry, National Chiao Tung University, 1001 Ta Hsueh Rd., Hsinchu, 30010, Taiwan.
authors.forename: Shih-Ting
authors.initials: ST
authors.lastname: Lan
authors.affiliation: Department of Applied Chemistry, National Chiao Tung University, 1001 Ta Hsueh Rd., Hsinchu, 30010, Taiwan.
authors.forename: Chou-Ting
authors.initials: CT
authors.lastname: Hsieh
authors.affiliation: Department of Chemical Engineering and Frontier Research Center on Fundamental and Applied Sciences of Matters, National Tsing Hua University, Hsin-Chu, 30013, Taiwan.
authors.forename: Hsin-Lung
authors.initials: HL
authors.lastname: Chen
authors.affiliation: Department of Applied Chemistry, National Chiao Tung University, 1001 Ta Hsueh Rd., Hsinchu, 30010, Taiwan. kclwang@nctu.edu.tw.
authors.forename: Chien-Lung
authors.initials: CL
authors.lastname: Wang
keywords: conformation; conjugated molecule; fullerene; phase stability; self-organization