title: High-throughput synthesis and characterization of nanocrystalline porphyrinic zirconium metal-organic frameworks.
abstract: We describe and employ a high-throughput screening method to accelerate the synthesis and identification of pure-phase, nanocrystalline metal-organic frameworks (MOFs). We demonstrate the efficacy of this method through its application to a series of porphyrinic zirconium MOFs, resulting in the isolation of MOF-525, MOF-545, and PCN-223 on the nanoscale.
authors.affiliation: Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA. dharris@northwestern.edu chadnano@northwesern.edu.
authors.forename: M L
authors.initials: ML
authors.lastname: Kelty
authors.affiliation: Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA. dharris@northwestern.edu chadnano@northwesern.edu.
authors.forename: W
authors.initials: W
authors.lastname: Morris
authors.affiliation: Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA. dharris@northwestern.edu chadnano@northwesern.edu.
authors.forename: A T
authors.initials: AT
authors.lastname: Gallagher
authors.affiliation: Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA. dharris@northwestern.edu chadnano@northwesern.edu.
authors.forename: J S
authors.initials: JS
authors.lastname: Anderson
authors.affiliation: Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA. dharris@northwestern.edu chadnano@northwesern.edu and International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA.
authors.forename: K A
authors.initials: KA
authors.lastname: Brown
authors.affiliation: Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA. dharris@northwestern.edu chadnano@northwesern.edu and International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA and Department of Materials Science and Engineering, Northwestern University, 2220 Campus Drive, Evanston, IL 60208, USA.
authors.forename: C A
authors.initials: CA
authors.lastname: Mirkin
authors.affiliation: Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA. dharris@northwestern.edu chadnano@northwesern.edu.
authors.forename: T D
authors.initials: TD
authors.lastname: Harris