title: Analytical method to estimate resin cement diffusion into dentin.
abstract: This study analyzed the diffusion of two resin luting agents (resin cements) into dentin, with the aim of presenting an analytical method for estimating the thickness of the diffusion zone. Class V cavities were prepared in the buccal and lingual surfaces of molars (n=9). Indirect composite inlays were luted into the cavities with either a self-adhesive or a self-etch resin cement. The teeth were sectioned bucco-lingually and the cement–dentin interface was analyzed by using micro-Raman spectroscopy (MRS) and scanning electron microscopy. Evolution of peak intensities of the Raman bands, collected from the functional groups corresponding to the resin monomer (C─O─C, 1113  cm(−1)) present in the cements, and the mineral content (P─O, 961  cm(−1)) in dentin were sigmoid shaped functions. A Boltzmann function (BF) was then fitted to the peaks encountered at 1113  cm(−1) to estimate the resin cement diffusion into dentin. The BF identified a resin cement–dentin diffusion zone of 1.8±0.4  μm for the self-adhesive cement and 2.5±0.3  μm for the self-etch cement. This analysis allowed the authors to estimate the diffusion of the resin cements into the dentin. Fitting the MRS data to the BF contributed to and is relevant for future studies of the adhesive interface.
authors.affiliation: State University of Maringá, Department of Dentistry, Av. Mandacaru 1550, 87080-0009, Maringá, Paraná, Brazil.
authors.forename: Larissa Cristina
authors.initials: LC
authors.lastname: de Oliveira Ferraz
authors.affiliation: State University of Maringá, Department of Dentistry, Av. Mandacaru 1550, 87080-0009, Maringá, Paraná, Brazil.
authors.forename: Adriana Lemos Mori
authors.initials: AL
authors.lastname: Ubaldini
authors.affiliation: State University of Maringá, Department of Dentistry, Av. Mandacaru 1550, 87080-0009, Maringá, Paraná, Brazil.
authors.forename: Bruna Medeiros Bertol
authors.initials: BM
authors.lastname: de Oliveira
authors.affiliation: State University of Maringá, Department of Physics, Av. Colombo 5790, 87020-900, Maringá, Paraná, Brazil.
authors.forename: Antonio Medina
authors.initials: AM
authors.lastname: Neto
authors.affiliation: State University of Maringá, Department of Physics, Av. Colombo 5790, 87020-900, Maringá, Paraná, Brazil.
authors.forename: Fracielle
authors.initials: F
authors.lastname: Sato
authors.affiliation: State University of Maringá, Department of Physics, Av. Colombo 5790, 87020-900, Maringá, Paraná, Brazil.
authors.forename: Mauro Luciano
authors.initials: ML
authors.lastname: Baesso
authors.affiliation: State University of Maringá, Department of Dentistry, Av. Mandacaru 1550, 87080-0009, Maringá, Paraná, Brazil.
authors.forename: Renata Corrêa
authors.initials: RC
authors.lastname: Pascotto
mesh_terms: D002623:Chemistry Techniques, Analytical / Q000379:methods*; D003188:Composite Resins / Q000737:chemistry; D003804:Dentin / Q000737:chemistry*; D017220:Dentin-Bonding Agents / Q000737:chemistry; D004058:Diffusion; D008422:Materials Testing / Q000379:methods*; D008855:Microscopy, Electron, Scanning; D008962:Models, Theoretical; D019279:Resin Cements / Q000737:chemistry*; D013059:Spectrum Analysis, Raman
chemical_list: D003188:Composite Resins; D017220:Dentin-Bonding Agents; D019279:Resin Cements