title: Levels of Contamination by Perfluoroalkyl Substances in Honey from Selected European Countries.
abstract: Perfluoroalkyl substances (PFASs) are man-made chemicals manufactured for numerous applications. The aim of this study was to assess the levels of 10 PFASs in selected types of honey samples from selected eastern, northern and southern European countries. A total of 26 samples of honey were analyzed. PFCAs (perfluoroalkyl carboxylic acids) were detected in almost all (92 %) analyzed samples in the range of 0.124-0.798 ng g(-1) ww (wet weight). The average concentrations of particular PFCAs (ng g(-1) ww) in honey samples increased in the following order: perfluorononanoic acid (0.164) < perfluorooctanoic acid (0.189) < perfluoroheptanoic acid (0.271) < perfluorodecanoic acid (0.278). Amongst perfluoroalkane sulfonates, only perfluorohexane sulfonate (PFHxS) was identified in four of 26 analyzed samples, and its concentrations ranged from 0.080 to 0.191 ng g(-1) ww. Italian eucalyptus honey contained the highest total content of PFASs (0.878 ng g(-1) ww). Samples originating from an industrial region of Poland showed 20 % higher concentrations of PFCAs compared to those from non-industrial regions.
authors.affiliation: Malopolska Centre of Food Monitoring, Faculty of Food Technology, University of Agriculture in Krakow, 122, Balicka str., 30-149, Krakow, Poland. m.surma@ur.krakow.pl.
authors.forename: Magdalena
authors.initials: M
authors.lastname: Surma
authors.affiliation: Department of Chemistry and Biodynamics of Food, Division of Food Science, Institute of Animal Reproduction and Food Research of the Polish Academy of Sciences, 10, Tuwima str., 10-748, Olsztyn, Poland.
authors.forename: Henryk
authors.initials: H
authors.lastname: Zieliński
authors.affiliation: Department of Chemistry and Biodynamics of Food, Division of Food Science, Institute of Animal Reproduction and Food Research of the Polish Academy of Sciences, 10, Tuwima str., 10-748, Olsztyn, Poland.
authors.forename: Mariusz
authors.initials: M
authors.lastname: Piskuła
mesh_terms: D005060:Europe; D006722:Honey / Q000032:analysis*; D006845:Hydrocarbons, Fluorinated / Q000032:analysis*
chemical_list: D006845:Hydrocarbons, Fluorinated
keywords: Honey; PFASs; PFCAs; PFSAs; d-SPE; micro-HPLC–MS/MS