title: Ion-induced nucleation of pure biogenic particles.
abstract: Atmospheric aerosols and their effect on clouds are thought to be important for anthropogenic radiative forcing of the climate, yet remain poorly understood. Globally, around half of cloud condensation nuclei originate from nucleation of atmospheric vapours. It is thought that sulfuric acid is essential to initiate most particle formation in the atmosphere, and that ions have a relatively minor role. Some laboratory studies, however, have reported organic particle formation without the intentional addition of sulfuric acid, although contamination could not be excluded. Here we present evidence for the formation of aerosol particles from highly oxidized biogenic vapours in the absence of sulfuric acid in a large chamber under atmospheric conditions. The highly oxygenated molecules (HOMs) are produced by ozonolysis of α-pinene. We find that ions from Galactic cosmic rays increase the nucleation rate by one to two orders of magnitude compared with neutral nucleation. Our experimental findings are supported by quantum chemical calculations of the cluster binding energies of representative HOMs. Ion-induced nucleation of pure organic particles constitutes a potentially widespread source of aerosol particles in terrestrial environments with low sulfuric acid pollution.
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mesh_terms: D000336:Aerosols / Q000737:chemistry*; D000397:Air Pollution / Q000032:analysis; D001272:Atmosphere / Q000737:chemistry*; D000081008:Bicyclic Monoterpenes; D057231:Climate Change; D003359:Cosmic Radiation; D006802:Human Activities; D007477:Ions / Q000737:chemistry*; D039821:Monoterpenes / Q000737:chemistry; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D010126:Ozone / Q000737:chemistry; D010316:Particle Size; D052638:Particulate Matter / Q000737:chemistry*; D011789:Quantum Theory; D013464:Sulfuric Acids / Q000032:analysis; D014835:Volatilization
chemical_list: D000336:Aerosols; D000081008:Bicyclic Monoterpenes; D007477:Ions; D039821:Monoterpenes; D052638:Particulate Matter; D013464:Sulfuric Acids; D010126:Ozone; C005451:alpha-pinene; C033158:sulfuric acid; D010100:Oxygen