Energetic aminated-azole assemblies from intramolecular and intermolecular N-HO and N-HN hydrogen bonds.
Compounds with adjacent C-NO2, C-NH2 and N-NH2 groups were designed and synthesized via amination. Their structures were characterized by infrared, and multinuclear NMR spectroscopy, elemental analysis, and X-ray single crystal diffraction. The effect of intramolecular and intermolecular N-HO and N-HN hydrogen bonds is discussed. Detonation properties were calculated by EXPLO 5 software based on calculated HOFs and experimental densities.
Department of Chemistry, University of Idaho, Moscow, ID 83844-2343, USA. jshreeve@uidaho.edu.
Chunlin
C
He
Department of Chemistry, University of Idaho, Moscow, ID 83844-2343, USA. jshreeve@uidaho.edu.
Ping
P
Yin
Department of Chemistry, University of Minnesota Minneapolis, MN 55455, USA.
Lauren A
LA
Mitchell
Naval Research Laboratory 4555 Overlook Avenue, Washington, D.C., USA.
Damon A
DA
Parrish
Department of Chemistry, University of Idaho, Moscow, ID 83844-2343, USA. jshreeve@uidaho.edu.
Jean'ne M
JM
Shreeve