Tuning of the electronic and photophysical properties of ladder-type quaterphenyl by selective methylene-bridge fluorination.
The photophysics (spectral positions, band shapes, fluorescence quantum yields and lifetimes) of a series of fluorinated ladder type quaterphenyls L4P and L4P-Fn (n = 2, 4, 6) depend strongly on the degree and position of fluorine, despite the fact that substitution is not performed in the rings but only in methylene-bridges. This is driven by subtle differences in the molecular orbitals (MOs) participating in the electronic transitions, and in the vibronic pattern of the S0 and S1 electronic states as revealed by (TD)DFT calculations. Solid state spectra for n = 0, 2, 4 are similar to those of solution due to small intermolecular interactions as revealed by combined X-ray and (TD)DFT analysis.
Institute for Advanced Studies, IMDEA Nanoscience, C/Faraday 9, Campus Cantoblanco, 28049, Madrid, Spain. milian@uv.es johannes.gierschner@imdea.org.
Benedikt
B
Dänekamp
Björn
B
Kobin
Santanu
S
Bhattacharyya
Stefan
S
Hecht
Begoña
B
Milián-Medina
Johannes
J
Gierschner