Synergistic effect of nanocavities in anatase TiO2 nanobelts for photocatalytic degradation of methyl orange dye in aqueous solution.
Nanocavities are empty voids exposed on the surface of one dimensional TiO2 nanostructured material. Often, they exhibited beneficial optical and electrical properties that leads to efficient photocatalytic reactions. This study reports formation of nanocavities on anatase TiO2 nanobelts (TNB) through dehydroxylation of surface hydroxyl groups during calcination process (350-600°C). The morphological and crystal structure analysis of TNB-500, -550 and -600 displayed the nanobelts shape with high density of nano-size cavities and increase in average diameter with calcination temperature. The SAED patterns confirm the anatase TiO2 phase. The enhanced light absorption properties of biphasic anatase/TiO2-B and anatase TiO2 than H2Ti3O7 are attributed to transformation of crystal structure upon calcination process. The catalytic activity was evaluated for degradation of methyl orange dye in aqueous solution under solar light irradiation. The reaction variables such as calcination temperature, amount of catalyst and pH of the methyl orange dye solution were studied and discussed in detail. Under optimal experimental conditions TNB-550 photocatalyst displayed highest degradation performance about 8 folds higher than H2Ti3O7. The high performance is explained as due to synergistic properties of one dimensional anatase TiO2 with high density of nanocavities leading to one dimensional transfer of electrons and high absorption co-efficient in UV-A spectrum are suitable for efficient red-ox reactions.
Nano Catalysis and Solar Fuels Research Laboratory, Department of Materials Science & Nanotechnology, Yogi Vemana University, Vemanapuram, Kadapa 516003, Andhra Pradesh, India.
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Praveen Kumar
Nano Catalysis and Solar Fuels Research Laboratory, Department of Materials Science & Nanotechnology, Yogi Vemana University, Vemanapuram, Kadapa 516003, Andhra Pradesh, India.
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Lakshmana Reddy
Nano Catalysis and Solar Fuels Research Laboratory, Department of Materials Science & Nanotechnology, Yogi Vemana University, Vemanapuram, Kadapa 516003, Andhra Pradesh, India.
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Karthikeyan
Nano Catalysis and Solar Fuels Research Laboratory, Department of Materials Science & Nanotechnology, Yogi Vemana University, Vemanapuram, Kadapa 516003, Andhra Pradesh, India.
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Chinnaiah
Nano Catalysis and Solar Fuels Research Laboratory, Department of Materials Science & Nanotechnology, Yogi Vemana University, Vemanapuram, Kadapa 516003, Andhra Pradesh, India.
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Bramhaiah
Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology (CSIR-IICT), Hyderabad 500007, Telangana, India.
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Durga Kumari
Nano Catalysis and Solar Fuels Research Laboratory, Department of Materials Science & Nanotechnology, Yogi Vemana University, Vemanapuram, Kadapa 516003, Andhra Pradesh, India. Electronic address: shankar@yogivemanauniversity.ac.in.
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Shankar
Dye degradation; Nanocavities; Photocatalytic; Solar light; TiO(2) nanobelts