New optical paper sensor for in situ measurement of hydrogen sulphide in waters and atmospheres.
A novel and low-cost colorimetric sensor for the determination of hydrogen sulphide in environmental samples has been developed. This sensor is based on the immobilization of the reagent N,N-Dimethyl-p-phenylenediamine and FeCl3 in paper support, in which the H2S is adsorbed in order to give rise to the formation of methylene blue as reaction product. The sensor has been applied to determine H2S in water and air samples. Two different sampling systems for H2S caption from the air have been assayed: active and passive sampling. The analytical properties of the different systems have been obtained and compared. The analytical signals, corresponding to the methylene blue, have been obtained measuring the absorbance by conventional reflectance diffuse or using different algorithms for quantifying color intensity. The results obtained with both measurement procedures were comparable, with a detection limit of 1.11 and 1.12mLm(-3) for air samples (active and passive), and 0.5mgL(-1) for water samples. The developed sensor provides good accuracy and precision (RSD<12%) and simplifies significantly the analytical measurements because it avoids the need of preparing derivatization reagents, sample handling and allows in situ measurements. The reaction product obtained is highly stable in this support and no provide any blank signal. Under the optimal conditions, the proposed method exhibit excellent visual sensitivity for the naked eye procedure, making the detection of H2S possible.
Department of Analytical Chemistry, Faculty of Chemistry, University of Valencia, Doctor Moliner 50, Burjassot, Valencia, Spain.
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Pla-Tolós
Department of Analytical Chemistry, Faculty of Chemistry, University of Valencia, Doctor Moliner 50, Burjassot, Valencia, Spain.
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Moliner-Martínez
Department of Analytical Chemistry, Faculty of Chemistry, University of Valencia, Doctor Moliner 50, Burjassot, Valencia, Spain.
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Verdú-Andrés
Department of Analytical Chemistry, Faculty of Chemistry, University of Valencia, Doctor Moliner 50, Burjassot, Valencia, Spain.
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Casanova-Chafer
Department of Analytical Chemistry, Faculty of Chemistry, University of Valencia, Doctor Moliner 50, Burjassot, Valencia, Spain.
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Molins-Legua
Department of Analytical Chemistry, Faculty of Chemistry, University of Valencia, Doctor Moliner 50, Burjassot, Valencia, Spain.
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Campíns-Falcó
Air sampling; Colorimetric paper sensor; Hydrogen sulphide; Methylene blue; Smartphone based colorimetric readout; Water analysis