Preparation of poly(glycidylmethacrylate-divinylbenzene) weak acid cation exchange stationary phases with succinic anhydride, phthalic anhydride, and maleic anhydride for ion chromatography.
In this work, poly(glycidylmethacrylate-divinylbenzene) microspheres were prepared and applied for the preparation of weak acid cation exchange stationary phases. Succinic anhydride, phthalic anhydride, and maleic anhydride were selected as carboxylation reagents to prepare three weak acid cation exchangers by direct chemical derivatization reaction without solvent or catalyst. The diameters and dispersity of the microspheres were characterized by scanning electron microscopy; the amount of accessible epoxy groups and mechanical stability were also measured. The weak acid cation exchangers were characterized by Fourier transform infrared spectroscopy; the content of carboxyl groups was measured by traditional acid base titration method. The chromatographic properties were characterized and compared by separating alkali, alkaline earth metal ions and ammonium and polar amines. The separation properties enhanced in the order of succinic anhydride, phthalic anhydride, and maleic anhydride modified poly(glycidylmethacrylate-divinylbenzene) cation exchangers.
Department of Chemistry, Xixi Campus, Zhejiang University, Hangzhou, China.
Junwei
J
Liu
Institute of Forensic Science and Technology of Nanjing Public Security Bureau, Nanjing, China.
Yong
Y
Wang
Zhejiang Institute of Geology and Mineral Resources, Hangzhou, China.
Shuchao
S
Wu
Department of Chemistry, Xixi Campus, Zhejiang University, Hangzhou, China.
Peimin
P
Zhang
Department of Chemistry, Xixi Campus, Zhejiang University, Hangzhou, China.
Yan
Y
Zhu
Carboxylic acid anhydride; Cation exchange stationary phases; Polymeric stationary phases