Rh(III)-Catalyzed C-C/C-N Coupling of Imidates with α-Diazo Imidamide: Synthesis of Isoquinoline-Fused Indoles.
Imidate esters and diazo compounds have been established as bifunctional substrates for the construction of biologically active fused heterocycles via rhodium-catalyzed C-H activation and C-C/C-N coupling. This reaction occurs under mild conditions with high efficiency, step economy, and low catalyst loading.
Dalian Institute of Chemical Physics, Chinese Academy of Sciences , Dalian 116023, China.
He
H
Wang
Dalian Institute of Chemical Physics, Chinese Academy of Sciences , Dalian 116023, China.
Lei
L
Li
Dalian Institute of Chemical Physics, Chinese Academy of Sciences , Dalian 116023, China.
Songjie
S
Yu
Dalian Institute of Chemical Physics, Chinese Academy of Sciences , Dalian 116023, China.
Yunyun
Y
Li
Dalian Institute of Chemical Physics, Chinese Academy of Sciences , Dalian 116023, China.
Xingwei
X
Li