Twisted and tubular silica structures by anionic surfactant fibers encapsulation.
Organic molecules imprinting can be used for introducing specific properties and functionalities such as chirality to mesoporous materials. Particularly organic self-assemblies can work as a scaffold for templating inorganic materials such as silica. During recent years chiral imprinting of anionic surfactant for fabrication of twisted rod-like silica structures assisted by co-structuring directing agent were thoroughly investigated. The organic self-assemblies of anionic surfactants can also be used for introducing other shapes in rod-like silica structures. Here we report the formation of amphiphilic N-miristoyl-l-alanine self-assemblies in aqueous solution upon stirring and at presence of l-arginine. These anionic surfactant self-assemblies form fibers that grow by increasing the stirring duration. The fibers were studied using transmission electron microscopy, infra-red spectroscopy and vibrational circular dichroism. Addition of silica precursor 1,2-bis(triethoxysilyl)ethylene and co-structuring directing agent N-trimethoxysilylpropyl-N,N,N-trimethylammonium chloride at different stages of fibers' growth leads to formation of different silica structures. By controlling stirring duration, we obtained twisted tubular silica structures as a result of fibers encapsulation. We decorated these structures with gold nanoparticles by different methods and measured their optical activity.
Department of Physical Chemistry, University of Geneva, 30 Quai Ernest-Ansermet, 1211 Geneva, Switzerland.
Mahshid
M
Chekini
Department of Quantum Matter Physics, Laboratory of Crystallography, University of Geneva, 24 Quai Ernest-Ansermet, 1211 Geneva, Switzerland.
Laure
L
Guénée
Paul Scherrer Institut, CH-5232 Villigen PSI, Switzerland.
Valentina
V
Marchionni
Department of Physical Chemistry, University of Geneva, 30 Quai Ernest-Ansermet, 1211 Geneva, Switzerland.
Manish
M
Sharma
Department of Physical Chemistry, University of Geneva, 30 Quai Ernest-Ansermet, 1211 Geneva, Switzerland. Electronic address: Thomas.Buergi@unige.ch.
Thomas
T
Bürgi
Chiral anionic surfactant; Chiral mesoporous silica; Encapsulation; Organic fiber; Self-assembly; l-Arginine