Peroxide-assisted microwave activation of pyrolysis char for adsorption of dyes from wastewater.
In this study, mesoporous activated biochar with high surface area and controlled pore size was prepared from char obtained as a by-product of pyrolysis of Prosopis juliflora biomass. The activation was carried out by a simple process that involved H2O2 treatment followed by microwave pyrolysis. H2O2 impregnation time and microwave power were optimized to obtain biochar with high specific surface area and high adsorption capacity for commercial dyes such as Remazol Brilliant Blue and Methylene Blue. Adsorption parameters such as initial pH of the dye solution and adsorbent dosage were also optimized. Pore size distribution, surface morphology and elemental composition of activated biochar were thoroughly characterized. H2O2 impregnation time of 24h and microwave power of 600W produced nanostructured biochar with narrow and deep pores of 357m(2)g(-1) specific surface area. Langmuir and Langmuir-Freundlich isotherms described the adsorption equilibrium, while pseudo second order model described the kinetics of adsorption.
Department of Chemical Engineering, Indian Institute of Technology Madras, Chennai 600036, India; National Center for Combustion Research and Development, Indian Institute of Technology Madras, Chennai 600036, India.
Vaishakh
V
Nair
Department of Chemical Engineering, Indian Institute of Technology Madras, Chennai 600036, India; National Center for Combustion Research and Development, Indian Institute of Technology Madras, Chennai 600036, India. Electronic address: vinu@iitm.ac.in.
R
R
Vinu
D000327:Adsorption; D000880:Anthraquinones / Q000737:chemistry / Q000302:isolation & purification; D018533:Biomass; D002606:Charcoal / Q000737:chemistry*; D004396:Coloring Agents / Q000737:chemistry / Q000302:isolation & purification*; D006861:Hydrogen Peroxide / Q000737:chemistry; D007700:Kinetics; D008751:Methylene Blue / Q000737:chemistry / Q000302:isolation & purification; D008855:Microscopy, Electron, Scanning; D008872:Microwaves; D029862:Prosopis / Q000737:chemistry; D012996:Solutions / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D062065:Wastewater / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods
D000880:Anthraquinones; D002606:Charcoal; D004396:Coloring Agents; D006861:Hydrogen Peroxide; D008751:Methylene Blue; D012996:Solutions; D062065:Wastewater; D014874:Water Pollutants, Chemical; C540010:biochar; C024758:Remazol Brilliant Blue R
Activation; Adsorption; Biochar; Dyes; Hydrogen peroxide; Kinetics; Microwave