Benzylic C(sp(3))-H Functionalization for C-N and C-O Bond Formation via Visible Light Photoredox Catalysis.
A visible light mediated highly selective benzylic C-H bond functionalization for intermolecular C-N and C-O bond formation is reported. This cross-dehydrogenative coupling reaction demonstrates a straightforward protocol for incorporating the heteroaromatics to the benzylic position. Benzylic oxidation of various alkyl aryls to corresponding carbonyl compounds has also been reported.
Molecular Synthesis and Drug Discovery Laboratory, Centre of Biomedical Research, Sanjay Gandhi Postgraduate Institute of Medical Sciences , Lucknow 226014, India.
Ganesh
G
Pandey
Molecular Synthesis and Drug Discovery Laboratory, Centre of Biomedical Research, Sanjay Gandhi Postgraduate Institute of Medical Sciences , Lucknow 226014, India.
Ramkrishna
R
Laha
Molecular Synthesis and Drug Discovery Laboratory, Centre of Biomedical Research, Sanjay Gandhi Postgraduate Institute of Medical Sciences , Lucknow 226014, India.
Deepak
D
Singh