Bis(dipyrrinato)zinc(II) Complexes: Emission in the Solid State.
This Communication reports the first observation of solid-state photoluminescence in bis(dipyrrinato)zinc(II) complexes with various substituents. The report discusses the effect of their substituents on their crystal structures and spectroscopic properties. Their meso-aryl groups are revealed to play important roles in the spectroscopic properties in the solid state.
Department of Chemistry, Graduate School of Science, The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Mizuho
M
Tsuchiya
Department of Chemistry, Graduate School of Science, The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.|JST-PRESTO , 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan.
Ryota
R
Sakamoto
Department of Chemistry, Graduate School of Science, The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Masaki
M
Shimada
Department of Chemistry, Graduate School of Science, The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Yoshinori
Y
Yamanoi
Department of Chemistry, Graduate School of Science, The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Yohei
Y
Hattori
Japan Synchrotron Radiation Research Institute (JASRI) , 1-1-1 Koto, Sayo-cho, Sayo-gun, Hyogo 679-5198, Japan.
Kunihisa
K
Sugimoto
Division of Physics, Faculty of Pure and Applied Sciences, Tsukuba Research Center for Interdisciplinary Materials Science, and Center for Integrated Research in Fundamental Science and Engineering, University of Tsukuba , 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8571, Japan.
Eiji
E
Nishibori
Department of Chemistry, Graduate School of Science, The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Hiroshi
H
Nishihara