Synthesis, characterization and application of a new chelating resin for solid phase extraction, preconcentration and determination of trace metals in some dairy samples by flame atomic absorption spectrometry.
In this study, a simple and rapid solid phase extraction/preconcentration procedure was developed for determination of Cd(II), Co(II), Cr(III), Cu(II), Fe(III), Mn(II), Pb(II), and Zn(II) trace metals by flame atomic absorption spectrometry (FAAS). A new chelating resin, poly(N-cyclohexylacrylamide-co-divinylbenzene-co-2-acrylamido-2-methyl-1-propanesulfonic acid) (NCA-co-DVB-co-AMPS) (hereafter CDAP) was synthesized and characterized. The influences of the analytical parameters such as pH of the sample solution, type and concentration of eluent, flow rates of the sample and eluent, volume of the sample and eluent, amount of chelating resin, and interference of ions were examined. The limit of detection (LOD) of analytes were found (3s) to be in the range of 0.65-1.90μgL(-1). Preconcentration factor (PF) of 200 and the relative standard deviation (RSD) of ⩽2% were achieved (n=11). The developed method was applied for determination of analytes in some dairy samples and certified reference materials.
Cumhuriyet University, Department of Food Technology, Gemerek Vocational School, TR-58840 Sivas, Turkey. Electronic address: teslimadasbasi@hotmail.com.
Teslima
T
Daşbaşı
Erciyes University, Department of Chemistry, Faculty of Science, TR-38039 Kayseri, Turkey.
Şerife
Ş
Saçmacı
Uşak University, Department of Material Science and Nanotechnology, Faculty of Engineering, TR-64200 Uşak, Turkey.
Nevin
N
Çankaya
Uşak University, Department of Material Science and Nanotechnology, Faculty of Engineering, TR-64200 Uşak, Turkey.
Cengiz
C
Soykan
D002614:Chelating Agents / Q000737:chemistry; D003611:Dairy Products / Q000032:analysis*; D012117:Resins, Synthetic / Q000737:chemistry*; D052616:Solid Phase Extraction / Q000379:methods*; D013054:Spectrophotometry, Atomic / Q000379:methods*; D014131:Trace Elements / Q000737:chemistry*
D002614:Chelating Agents; D012117:Resins, Synthetic; D014131:Trace Elements
Chelating resin; Dairy samples; FAAS; Solid phase extraction; Trace metals