Hierarchically Flower-like N-Doped Porous Carbon Materials Derived from an Explosive 3-Fold Interpenetrating Diamondoid Copper Metal-Organic Framework for a Supercapacitor.
A peculiar copper metal-organic framework (Cu-MOF) was synthesized by a self-assembly method, which presents a 3-fold interpenetrating diamondoid net based on the square-planar Cu(II) node. Although it exhibits a high degree of interpenetration, the Cu-MOF still exhibits a one-dimensional channel, which provides a template for constructing porous materials through the "precursor" strategy. Furthermore, the explosive ClO4(-) ion, which resided in the channel, could induce the quick decomposition of organic ingredients and release a huge amount of gas, which is beneficial for the porosity of postsynthetic materials. Significantly, we first utilize this explosive MOF to prepare a series of Cu@C composites through the calcination-thermolysis method at different temperatures, which contain copper particles exhibiting various shapes and combinations with the carbon substrate. Considering the hole-forming effect of copper particles, Cu@C composites were etched by HCl to afford a sequence of hierarchically flower-like N-doped porous carbon materials (NPCs), which retain the original morphology of the Cu-MOF. Interestingly, NPC-900, originating from the calcination of the Cu-MOF at 900 °C, exhibits a more regular flower-like morphology, the largest specific surface area, abundant porosities, and multiple nitrogen functionalities. The remarkable specific capacitances are 138 F g(-1) at 5 mV s(-1) and 149 F g(-1) at 0.5 A g(-1) for the NPC-900 electrode in a 6 M potassium hydroxide aqueous solution. Moreover, the retention of capacitance remains 86.8% (125 F g(-1)) at 1 A g(-1) over 2000 cycles, which displays good chemical stability. These findings suggest that NPC-900 can be applied as a suitable electrode for a supercapacitor.
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Material Sciences, Northwest University , Xi'an 710069, P. R. China.|Shannxi Key Laboratory of Phytochemistry , Baoji 721016, P. R. China.
Zuo-Xi
ZX
Li
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Material Sciences, Northwest University , Xi'an 710069, P. R. China.
Kang-Yu
KY
Zou
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Material Sciences, Northwest University , Xi'an 710069, P. R. China.
Xue
X
Zhang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Material Sciences, Northwest University , Xi'an 710069, P. R. China.
Tong
T
Han
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Material Sciences, Northwest University , Xi'an 710069, P. R. China.
Ying
Y
Yang