Cascade C-H Functionalization/Amidation Reaction for Synthesis of Azepinone Derivatives.
A cascade C-H functionalization/amidation reaction of aminobiaryls with diazomalonates has been developed under rhodium catalysis, affording new azepinone derivatives in moderate to excellent yields.
Department of Chemistry, Zhejiang University , Hangzhou 310028, P. R. China.
Peng
P
Bai
Department of Chemistry, Zhejiang University , Hangzhou 310028, P. R. China.
Xing-Fen
XF
Huang
Department of Chemistry, Zhejiang University , Hangzhou 310028, P. R. China.
Guo-Dong
GD
Xu
Department of Chemistry, Zhejiang University , Hangzhou 310028, P. R. China.|State Key Laboratory of Elemento-organic Chemistry, Nankai University , Tianjin 300071, P. R. China.
Zhi-Zhen
ZZ
Huang