Design and synthesis of squaramide-based MOFs as efficient MOF-supported hydrogen-bonding organocatalysts.
Herein, we utilize a new, squaramide-based ligand, combined with a postsynthetic exchange (PSE) synthetic approach to prepare a series of Cu(ii)-squaramide MOFs that are active catalysts for the Friedel-Crafts reaction.
Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093, USA. scohen@ucsd.edu and Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (MOE), Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin 300071, P. R. China.
Xiaoping
X
Zhang
Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093, USA. scohen@ucsd.edu.
Zhenjie
Z
Zhang
Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093, USA. scohen@ucsd.edu.
Jake
J
Boissonnault
Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093, USA. scohen@ucsd.edu.
Seth M
SM
Cohen