An anionic zeolite-like metal-organic framework (AZMOF) with a Moravia network for organic dye absorption through cation-exchange.
An anionic zeolite-like metal-organic framework (AZMOF) with a twisted partially augmented the net, known as the "Moravia" net, [(CH3)2NH2]6[Sr13(O)3()8(OH)2(H2O)16]·xS (, where S represents non-coordinated solvent molecules, and is the abbreviation of benzo-(1,2;3,4;5,6)-tris-(thiophene-2'-carboxylic acid)), has been solvothermally synthesized and characterized, which possesses an anionic framework and nano-sized sodalite cage. Through cation-exchange, is capable of uptaking large organic cationic dyes including Rhodamine B (RB), Basic Red 2 (BR2), Crystal Violet (CV) and Methylene Blue (MB), amongst which the adsorption capability for RB (up to 545 mg g(-1)), and BR2 (up to 675 mg g(-1)) is the highest for reported absorbants to date.
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China. zhuhaibin@seu.edu.cn.
Yu
Y
Shen
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China. zhuhaibin@seu.edu.cn.
Cong-Cong
CC
Fan
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China. zhuhaibin@seu.edu.cn.
Yu-Zhen
YZ
Wei
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China. zhuhaibin@seu.edu.cn.
Jie
J
Du
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China. zhuhaibin@seu.edu.cn.
Hai-Bin
HB
Zhu
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, China. zhaoyue@nju.edu.cn.
Yue
Y
Zhao