Raman scattering and anomalous Stokes-anti-Stokes ratio in MoTe2 atomic layers.
Stokes and anti-Stokes Raman scattering are performed on atomic layers of hexagonal molybdenum ditelluride (MoTe2), a prototypical transition metal dichalcogenide (TMDC) semiconductor. The data reveal all six types of zone center optical phonons, along with their corresponding Davydov splittings, which have been challenging to see in other TMDCs. We discover that the anti-Stokes Raman intensity of the low energy layer-breathing mode becomes more intense than the Stokes peak under certain experimental conditions, and find the effect to be tunable by excitation frequency and number of atomic layers. These observations are interpreted as a result of resonance effects arising from the C excitons in the vicinity of the Brillouin zone center in the photon-electron-phonon interaction process.
Department of Physics, University of Massachusetts, Amherst, Massachusetts 01003, USA.
Thomas
T
Goldstein
Department of Physics, University of Massachusetts, Amherst, Massachusetts 01003, USA.
Shao-Yu
SY
Chen
Department of Physics, University of Massachusetts, Amherst, Massachusetts 01003, USA.
Jiayue
J
Tong
Department of Physics, Carnegie Mellon University, Pittsburgh, PA 15213, USA.
Di
D
Xiao
Department of Mechanical &Industrial Engineering, University of Massachusetts, Amherst, Massachusetts 01003, USA.
Ashwin
A
Ramasubramaniam
Department of Physics, University of Massachusetts, Amherst, Massachusetts 01003, USA.
Jun
J
Yan