Crystal Structure of High-Temperature Phase β-NaSrBO3 and Photoluminescence of β-NaSrBO3:Ce(3.).
α-NaSrBO3 is an excellent phosphor host for phosphor-converted white light-emitting diode (w-LED) application with very interesting properties. However, it undergoes a phase transformation to β-NaSrBO3 at the LED working temperature. In this study, the high-temperature phase β-NaSrBO3 was stabilized to room temperature by introducing Na(+) and Ce(3+) via a high-temperature solid-state reaction method. The crystal structure of β-NaSrBO3 was determined from the powder X-ray diffraction data. It crystallizes in space group P21/c with the following lattice parameters: a = 6.06214(8) Å, b = 5.41005(7) Å, c = 9.1468(1) Å, β = 102.116(1)°, and V = 293.301(7) Å(3). Na and Sr sites are found to be mixed occupied by each other, and the isolated [BO3](3-) anionic groups are distributed in parallel. Ce(3+)-activated β-NaSrBO3:Ce(3+) blue-emitting phosphors were synthesized. The temperature-dependent photoluminescence spectra indicate that the thermal stability of β-NaSrBO3:Ce(3+) is better than that of α-NaSrBO3:Ce(3+) at the same temperature. A near-ultraviolet pumped warm w-LED with a β-NaSrBO3:0.05Ce(3+) phosphor as the blue component was fabricated. The w-LED lamp after illumination at 250 mA gives chromaticity coordinates, a color rendering index, and a correlated color temperature of (0.3821, 0.3430), 92.8, and 3654 K, respectively.
The MOE key laboratory of weak-Light Nonlinear Photonics, School of Physics, Nankai University , Tianjin 300071, China.
Huan
H
Yi
The MOE key laboratory of weak-Light Nonlinear Photonics, School of Physics, Nankai University , Tianjin 300071, China.
Li
L
Wu
The MOE key laboratory of weak-Light Nonlinear Photonics, School of Physics, Nankai University , Tianjin 300071, China.
Liwei
L
Wu
Research and Development Center for Semiconductor Lighting, Institute of Semiconductors, Chinese Academy of Sciences , Beijing 100083, China.
Lixia
L
Zhao
School of Materials Sciences and Engineering, University of Science and Technology Beijing , Beijing 100083, China.
Zhiguo
Z
Xia
College of Electronic Information and Optical Engineering and Tianjin Key Laboratory of Photo-electronic Thin Film Devices and Technology, Nankai University , Tianjin 300071, China.
Yi
Y
Zhang
The MOE key laboratory of weak-Light Nonlinear Photonics, School of Physics, Nankai University , Tianjin 300071, China.
Yongfa
Y
Kong
The MOE key laboratory of weak-Light Nonlinear Photonics, School of Physics, Nankai University , Tianjin 300071, China.
Jingjun
J
Xu