Surface characterization and chemical analysis of bamboo substrates pretreated by alkali hydrogen peroxide.
The surface characterization and chemical analysis of bamboo substrates by alkali hydrogen peroxide pretreatment (AHPP) were investigated in this study. The results tended to manifest that AHPP prior to enzymatic and chemical treatment was potential for improving accessibility and reactivity of bamboo substrates. The inorganic components, organic solvent extractives and acid-soluble lignin were effectively removed by AHPP. X-ray photoelectron spectroscopy (XPS) analysis indicated that the surface of bamboo chips had less lignin but more carbohydrate after pre-treatment. Fiber surfaces became etched and collapsed, and more pores and debris on the substrate surface were observed with Scanning Electron Microscopy (SEM). Brenauer-Emmett-Teller (BET) results showed that both of pore volume and surface area were increased after AHPP. Although XRD analysis showed that AHPP led to relatively higher crystallinity, pre-extraction could overall enhance the accessibility of enzymes and chemicals into the bamboo structure.
College of Light Industry and Food Engineering, Guangxi University, Nanning 530004, PR China; Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control, Nanning 530004, PR China.
Xueping
X
Song
College of Light Industry and Food Engineering, Guangxi University, Nanning 530004, PR China; Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control, Nanning 530004, PR China.
Yan
Y
Jiang
College of Light Industry and Food Engineering, Guangxi University, Nanning 530004, PR China; Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control, Nanning 530004, PR China.
Xianjian
X
Rong
College of Light Industry and Food Engineering, Guangxi University, Nanning 530004, PR China; Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control, Nanning 530004, PR China.
Wei
W
Wei
College of Light Industry and Food Engineering, Guangxi University, Nanning 530004, PR China; Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control, Nanning 530004, PR China.
Shuangfei
S
Wang
College of Light Industry and Food Engineering, Guangxi University, Nanning 530004, PR China; Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control, Nanning 530004, PR China. Electronic address: nieshuangxi061@163.com.
Shuangxi
S
Nie
D000468:Alkalies / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry*; D008031:Lignin / Q000737:chemistry; D031787:Sasa / Q000737:chemistry*; D013499:Surface Properties
D000468:Alkalies; D008031:Lignin; D006861:Hydrogen Peroxide
AHPP; BET; Bamboo; Surface characterization; XDR; XPS