Efficacy of zero-valent copper (Cu(0)) nanoparticles and reducing agents for dechlorination of mono chloroaromatics.
The zero-valent copper (Cu(0)) nanoparticles were prepared by chemical reduction method. The morphology of nanoparticles was investigated by using X ray diffraction, scanning electron microscopy-energy dispersive X ray, UV-visible spectrophotometer and Brunauer-Emmett-Teller surface area analyser. The Cu(0) nanoparticles along with reducing agents, NaBH4/5% acidified alcohol were used for the dechlorination of chloroaromatics at room temperature. Chlorobenzene (Cl-B), chlorotoluene (Cl-T), chloropyridine (Cl-Py) and chlorobiphenyl (Cl-BPh) were selected as the contaminants. The effect of various operating parameters such as pH, concentration of the catalyst and reducing agent (NaBH4), and recycling of the catalyst on dechlorination were studied. Nearly complete dechlorination of all the chloroaromatics were achieved in the presence of Cu(0) nanoparticles (2.5 g L(-1)) and NaBH4 (1.0 g L(-1)) within 12 h. On the contrary, approximately 70% of dechlorination was observed in the presence of 5% acidified alcohol at similar experimental conditions. The dechlorination mechanism highlighted the importance of Cu(0) nanoparticles as a surface mediator. The kinetics of the dechlorination of chloroaromatics was investigated and compared with chloroaliphatics. The dechlorination rate differed from 0.23 h(-1) (Cl-B) to 0.15 h(-1) (Cl-BPh) in the presence of Cu(0) nanoparticles and NaBH4. The effectiveness of Cu(0) nanoparticles with NaBH4 (1 g L(-1)) and 5% acidified alcohol as electron donors were studied by oxidation-reduction potential and observed to be -1016 mV and -670 mV, respectively. Final products of the dechlorination were benzene, toluene, pyridine and biphenyl, as identified by gas chromatograph mass spectrometer and nuclear magnetic resonance spectroscopy.
Energy and Environment Laboratory, Department of Applied Chemistry, Defence Institute of Advanced Technology (DU), Ministry of Defence, Pune, 411 025, India.
Sandesh S
SS
Raut
Chemical Engineering and Process Development Division, CSIR-National Chemical Laboratory, Pune, 411 008, India.
Sanjay P
SP
Kamble
Energy and Environment Laboratory, Department of Applied Chemistry, Defence Institute of Advanced Technology (DU), Ministry of Defence, Pune, 411 025, India. Electronic address: ps_kulkarni@rediffmail.com.
Prashant S
PS
Kulkarni
D002384:Catalysis; D002722:Chlorobenzenes / Q000737:chemistry; D003300:Copper / Q000737:chemistry*; D054879:Halogenation; D007700:Kinetics; D053758:Nanoparticles / Q000737:chemistry*; D019163:Reducing Agents / Q000737:chemistry*; D014961:X-Ray Diffraction
D002722:Chlorobenzenes; D019163:Reducing Agents; D003300:Copper; C031294:chlorobenzene
Acidified alcohol; ChloroAromatics; Hydrodechlorination; NaBH(4); Wastewater treatment; Zero-valent copper (Cu(0)) nanoparticles