Peroxodisulfate-mediated selenoamination of alkenes yielding amidoselenide-containing sulfamides and azoles.
A new protocol for C-Se and C-N bond formation by the direct difunctionalization of alkenes is reported. The protocol is operationally simple, has a wide substrate scope, and uses readily available amino sources. This reaction represents a significant addition to the limited number of intermolecular selenide difunctionalization reactions of alkenes and would find practical application in the synthesis of nitrogen- and selenium-containing molecules.
College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, P. R. China. sunk468@nenu.edu.cn liulin@aynu.edu.cn and Henan Province Key Laboratory of New Opto-Electronic Functional Materials, Anyang 455000, P. R. China.
Kai
K
Sun
College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, P. R. China. sunk468@nenu.edu.cn liulin@aynu.edu.cn.
Xin
X
Wang
College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, P. R. China. sunk468@nenu.edu.cn liulin@aynu.edu.cn.
Yunhe
Y
Lv
College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, P. R. China. sunk468@nenu.edu.cn liulin@aynu.edu.cn.
Gang
G
Li
College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, P. R. China. sunk468@nenu.edu.cn liulin@aynu.edu.cn.
Hezhen
H
Jiao
College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, P. R. China. sunk468@nenu.edu.cn liulin@aynu.edu.cn.
Changwei
C
Dai
College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, P. R. China. sunk468@nenu.edu.cn liulin@aynu.edu.cn.
Yangyang
Y
Li
College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, P. R. China. sunk468@nenu.edu.cn liulin@aynu.edu.cn.
Chong
C
Zhang
College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, P. R. China. sunk468@nenu.edu.cn liulin@aynu.edu.cn and Henan Province Key Laboratory of New Opto-Electronic Functional Materials, Anyang 455000, P. R. China.
Lin
L
Liu