Grape-Like Fe3O4 Agglomerates Grown on Graphene Nanosheets for Ultrafast and Stable Lithium Storage.
An in situ simple and effective synthesis method is effectively exploited to construct MOF-derived grape-like architecture anchoring on nitrogen-doped graphene, in which ultrafine Fe3O4 nanoparticles are uniformly dispersed (Fe3O4@C/NG). In this hybrid hierarchical structure, new synergistic features are accessed. The graphene oxide plane with functional groups is expected to alleviate the aggregation problem in the MOFs' growth. Moreover, the morphology and size of iron-based MOFs and carbon content are conveniently controlled by controlling the solution concentration of precursor. Through making use of in situ carbonization of the organic ligands in MOFs, Fe3O4 subunits are effectively protected by 3D interconnected conductive carbon at microscale. Consequently, when applied as anode materials, even as high as 10 A g(-1) after 1000 cycles, Fe3O4@C/NG still maintains as high as 458 mA h g(-1).
College of Chemistry and Molecular Engineering, Peking University , Beijing 100871, P. R. China.
Liya
L
Qi
College of Chemistry and Molecular Engineering, Peking University , Beijing 100871, P. R. China.
Yuelong
Y
Xin
Beijing Engineering Research Center of Power Lithium-ion Battery, Beijing 102200, P. R. China.
Zicheng
Z
Zuo
College of Chemistry and Molecular Engineering, Peking University , Beijing 100871, P. R. China.
Chengkai
C
Yang
College of Chemistry and Molecular Engineering, Peking University , Beijing 100871, P. R. China.
Kai
K
Wu
Beijing Engineering Research Center of Power Lithium-ion Battery, Beijing 102200, P. R. China.
Bin
B
Wu
College of Chemistry and Molecular Engineering, Peking University , Beijing 100871, P. R. China.
Henghui
H
Zhou
anode; hybrid nanomaterials; metal organic frameworks; metal oxides; microstructures