Vibrational dynamics (IR, Raman, NRVS) and a DFT study of a new antitumor tetranuclearstannoxane cluster, Sn(iv)-oxo-{di-o-vanillin} dimethyl dichloride.
The vibrational dynamics of a newly synthesized tetrastannoxane was characterized with a combination of experimental (Raman, IR and tin-based nuclear resonance vibrational spectroscopy) and computational (DFT/B3LYP) methods, with an emphasis on the vibrations of the tin sites. The cytotoxic activity revealed a significant regression selectively against the human pancreatic cell lines.
Department of Chemistry, Aligarh Muslim University, Aligarh 202002, India. farukh_arjmand@yahoo.co.in.
F
F
Arjmand
S
S
Sharma
M
M
Usman
B M
BM
Leu
M Y
MY
Hu
L
L
Toupet
D
D
Gosztola
S
S
Tabassum
D001547:Benzaldehydes / Q000737:chemistry*; D045744:Cell Line, Tumor; D006801:Humans; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D010190:Pancreatic Neoplasms / Q000737:chemistry* / Q000378:metabolism*; D011789:Quantum Theory; D013055:Spectrophotometry, Infrared; D014001:Tin / Q000737:chemistry*; D014732:Vibration
D001547:Benzaldehydes; D009942:Organometallic Compounds; D014001:Tin; C100058:vanillin