High hydroxide conductivity in a chemically stable crystalline metal-organic framework containing a water-hydroxide supramolecular chain.
A chemically stable cationic MOF encapsulating an in situ formed water-hydroxide supramolecular anionic chain is realized for high hydroxide (OH(-)) ion conductivity in the solid-state (Type A). High OH(-) ion conductivity and low activation energy of the MOF demonstrate the advantage of the in situ incorporation of OH(-) ions to achieve efficient OH(-) ion conduction in the solid-state.
Indian Institute of Science Education and Research (IISER) Pune, Dr. Homi Bhabha Road, Pune - 411008, India. sghosh@iiserpune.ac.in.
Sanjog S
SS
Nagarkar
Physical and Materials Chemistry Division, National Chemical Laboratory (NCL), Pune - 411008, India and Academy of Scientific and Innovative Research (AcSIR), Anusandhan Bhawan, New Delhi - 110001, India.
Bihag
B
Anothumakkool
Indian Institute of Science Education and Research (IISER) Pune, Dr. Homi Bhabha Road, Pune - 411008, India. sghosh@iiserpune.ac.in.
Aamod V
AV
Desai
Hefei National Laboratory for Physical Science at the Microscale, University of Technology of China, Hefei, Anhui - 230026, People's Republic of China.
Mandar M
MM
Shirolkar
Physical and Materials Chemistry Division, National Chemical Laboratory (NCL), Pune - 411008, India and Academy of Scientific and Innovative Research (AcSIR), Anusandhan Bhawan, New Delhi - 110001, India.
Sreekumar
S
Kurungot
Indian Institute of Science Education and Research (IISER) Pune, Dr. Homi Bhabha Road, Pune - 411008, India. sghosh@iiserpune.ac.in and Centre for Research in Energy & Sustainable Materials, IISER Pune, India.
Sujit K
SK
Ghosh