title: Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands.
abstract: The first helicene-NHC-iridium complexes have been prepared in enantiopure forms. Their stereochemical, electronic, and chiroptical features were characterized experimentally and via first-principles calculations, highlighting the helical and iridium-centered chirality.
authors.affiliation: Institut des Sciences Chimiques de Rennes, UMR 6226, Institut de Physique de Rennes, UMR 6251, Campus de Beaulieu, CNRS-Université de Rennes 1, 35042 Rennes Cedex, France. jeanne.crassous@univ-rennes1.fr.
authors.forename: Nora
authors.initials: N
authors.lastname: Hellou
authors.forename: Claire
authors.initials: C
authors.lastname: Jahier-Diallo
authors.forename: Olivier
authors.initials: O
authors.lastname: Baslé
authors.forename: Monika
authors.initials: M
authors.lastname: Srebro-Hooper
authors.forename: Loïc
authors.initials: L
authors.lastname: Toupet
authors.forename: Thierry
authors.initials: T
authors.lastname: Roisnel
authors.forename: Elsa
authors.initials: E
authors.lastname: Caytan
authors.forename: Christian
authors.initials: C
authors.lastname: Roussel
authors.forename: Nicolas
authors.initials: N
authors.lastname: Vanthuyne
authors.forename: Jochen
authors.initials: J
authors.lastname: Autschbach
authors.forename: Marc
authors.initials: M
authors.lastname: Mauduit
authors.forename: Jeanne
authors.initials: J
authors.lastname: Crassous