title: Isolation of a Moderately Stable but Sensitive Zwitterionic Diazonium Tetrazolyl-1,2,3-triazolate.
abstract: An unexpected formation of a diazonium compound was observed by nitration of an amino substituted triazolyl tetrazole with mixed acid. The crystal structure determination revealed a zwitterionic diazonium tetrazolyl-1,2,3-triazolate, whose constitution was supported by NMR and vibrational spectroscopic analysis. The thermal stability and sensitivity toward impact and friction were determined. In contrast, diazotriazoles are rather unstable and are mainly handled in solution and/or low temperatures, which is not the case for this diazonium tetrazolyl-1,2,3-triazolate, being stable at ambient temperature.
authors.affiliation: Department of Chemistry, Ludwig Maximilian University Munich , Butenandtstr. 5-13 (D), 81377 Munich, Germany.
authors.forename: Thomas M
authors.initials: TM
authors.lastname: Klapötke
authors.affiliation: Department of Chemistry, Ludwig Maximilian University Munich , Butenandtstr. 5-13 (D), 81377 Munich, Germany.
authors.forename: Burkhard
authors.initials: B
authors.lastname: Krumm
authors.affiliation: Department of Chemistry, Ludwig Maximilian University Munich , Butenandtstr. 5-13 (D), 81377 Munich, Germany.
authors.forename: Carolin
authors.initials: C
authors.lastname: Pflüger