title: Effective bromo and chloro peroxidation catalysed by tungsten(vi) amino triphenolate complexes.
abstract: Amino triphenolate tungsten(vi) complexes have been prepared and they proved to be efficient catalysts in haloperoxidation reactions using hydrogen peroxide as a terminal oxidant and inorganic sources of halides. In particular, interesting results have been obtained in the challenging chloroperoxidation reactivity (catalyst loading down to 0.05% with TONs up to 900). A comparison among three different metal complexes bearing the same ligand (vanadium(v), molybdenum(vi) and tungsten(vi)) showed much better performances of the last complex both on bromo and chloro peroxidations.
authors.affiliation: Dipartimento di Scienze Chimiche, Università di Padova and CIRCC, Padova Unit, via Marzolo 1, 35131 Padova, Italy. giulia.licini@unipd.it.
authors.forename: Elena
authors.initials: E
authors.lastname: Badetti
authors.forename: Francesco
authors.initials: F
authors.lastname: Romano
authors.forename: Luciano
authors.initials: L
authors.lastname: Marchiò
authors.forename: Sara
authors.initials: S
authors.lastname: Taşkesenlioğlu
authors.forename: Arif
authors.initials: A
authors.lastname: Daştan
authors.forename: Cristiano
authors.initials: C
authors.lastname: Zonta
authors.forename: Giulia
authors.initials: G
authors.lastname: Licini