title: [Mn(III)Mn(IV)2Mo14O56](17-): A Mixed-Valence Meso-Polyoxometalate Anion Encapsulated by a 64-Nuclearity Silver Cluster.
abstract: A 64-nuclearity silver cluster encapsulating a unique POM anion [Mn(III)Mn(IV)2Mo14O56](17-) has been synthesized. The formation of the templating core performs a reassembly process for increasing nuclearities from {MnMo9} to {Mn3Mo14}. It represents a rare inorganic meso anion containing mixed-valent Mn that is built up by d-{Mn(IV)Mo7} and l-{Mn(IV)Mo7} units connecting together through a {Mn(III)} fragment.
authors.affiliation: Department of Chemistry, College of Chemistry and Chemical Engineering , Xiamen, 361005, People's Republic of China.
authors.forename: Jian-Yu
authors.initials: JY
authors.lastname: Wang
authors.affiliation: Department of Chemistry, College of Chemistry and Chemical Engineering , Xiamen, 361005, People's Republic of China.
authors.forename: Kuan-Guan
authors.initials: KG
authors.lastname: Liu
authors.affiliation: Department of Chemistry, College of Chemistry and Chemical Engineering , Xiamen, 361005, People's Republic of China.
authors.forename: Zong-Jie
authors.initials: ZJ
authors.lastname: Guan
authors.affiliation: Department of Chemistry, College of Chemistry and Chemical Engineering , Xiamen, 361005, People's Republic of China.
authors.forename: Zi-Ang
authors.initials: ZA
authors.lastname: Nan
authors.affiliation: Department of Chemistry, College of Chemistry and Chemical Engineering , Xiamen, 361005, People's Republic of China.
authors.forename: Yu-Mei
authors.initials: YM
authors.lastname: Lin
authors.affiliation: Department of Chemistry, College of Chemistry and Chemical Engineering , Xiamen, 361005, People's Republic of China.|Department of Chemistry, Tsinghua University , Bejing, 100084, People's Republic of China.
authors.forename: Quan-Ming
authors.initials: QM
authors.lastname: Wang