title: Determination of Elemental Ratio in an Atomic Column by Electron Energy Loss Spectroscopy.
abstract: Atomic-resolution quantification of the elemental ratio of Fe to Mn at the octahedral and tetrahedral sites in brownmillerite Ca2Fe1.07Mn0.93O5 was determined using electron energy-loss spectroscopy combined with aberration-corrected scanning transmission electron microscopy. The combined techniques revealed that oversampling of the spectral imaging data yielded a spatially resolved area that very nearly reflects atomic resolution (∼1.2 Å radius). The average experimental ratios of Fe to Mn within this region were 17.5:82.5 for the octahedral sites and 81.6:18.4 for the tetrahedral sites. The elemental ratio in an octahedral atomic column was successfully extracted by estimating the mixing of signals from nearest neighbor columns. The results indicated that the ratio of Fe to Mn was 13:87 at the octahedral site, which is in good agreement with the results of neutron diffraction analysis. In addition, the uncertainty of experimental results obtained by using an average 1.2 Å radius was less than 10% at octahedral sites, depending on the sample thickness. In contrast, the experimental error due to dechanneling of incident electrons was larger at the tetrahedral sites. This experimental procedure has wide application for determining the spatially resolved composition ratio of elements in perovskite-like compounds.
authors.affiliation: Institute for Chemical Research, Kyoto University , Uji, Kyoto 611-0011, Japan.
authors.forename: Mitsutaka
authors.initials: M
authors.lastname: Haruta
authors.affiliation: Institute for Chemical Research, Kyoto University , Uji, Kyoto 611-0011, Japan.
authors.forename: Yoshiteru
authors.initials: Y
authors.lastname: Hosaka
authors.affiliation: Institute for Chemical Research, Kyoto University , Uji, Kyoto 611-0011, Japan.
authors.forename: Noriya
authors.initials: N
authors.lastname: Ichikawa
authors.affiliation: Institute for Chemical Research, Kyoto University , Uji, Kyoto 611-0011, Japan.
authors.forename: Takashi
authors.initials: T
authors.lastname: Saito
authors.affiliation: Institute for Chemical Research, Kyoto University , Uji, Kyoto 611-0011, Japan.
authors.forename: Yuichi
authors.initials: Y
authors.lastname: Shimakawa
authors.affiliation: Institute for Chemical Research, Kyoto University , Uji, Kyoto 611-0011, Japan.
authors.forename: Hiroki
authors.initials: H
authors.lastname: Kurata
keywords: EELS; STEM; nanoscale characterization