title: Anderson-like alkoxo-polyoxovanadate clusters serving as unprecedented second building units to construct metal-organic polyhedra.
abstract: Unprecedented Anderson-like alkoxo-polyoxovanadate [V6O6(OCH3)9(μ6-SO4)(COO)3](2-) polyanions can serve as 3-connected second building units (SBUs) that assemble with dicarboxylate or tricarboxylate ligands to form a new family of metal organic tetrahedrons of V4E6 and V4F4 type (V = vertex, E = edge, and F = face). To our knowledge, this alkoxo-polyoxovanadate-based SBU is the first ever reported.
authors.affiliation: Institute of Functional Material Chemistry, Local United Engineering Lab for Power Battery, Northeast Normal University, Changchun, 130024 Jilin, People's Republic of China. wangxl824@nenu.edu.cn zmsu@nenu.edu.cn.
authors.forename: Yu-Teng
authors.initials: YT
authors.lastname: Zhang
authors.forename: Xin-Long
authors.initials: XL
authors.lastname: Wang
authors.forename: Shuang-Bao
authors.initials: SB
authors.lastname: Li
authors.forename: Ya-Ru
authors.initials: YR
authors.lastname: Gong
authors.forename: Bai-Qiao
authors.initials: BQ
authors.lastname: Song
authors.forename: Kui-Zhan
authors.initials: KZ
authors.lastname: Shao
authors.forename: Zhong-Min
authors.initials: ZM
authors.lastname: Su