title: Suitable Morphology Makes CoSn(OH)6 Nanostructure a Superior Electrochemical Pseudocapacitor.
abstract: Morphology of a material with different facet, edge, kink, etc., generally influences the rate of a catalytic reaction.1,2 Herein, we account for the importance of altered morphology of a nanomaterial for a supercapacitor device and employed CoSn(OH)6 as an electrode material. Suitable fabrication of a stable aqueous asymmetric supercapacitor (AAS) using metal hydroxide as positive electrode can be beneficial if the high energy density is derived without sacrificing the power density. Here we have synthesized an uncommon hierarchical mesoporous nanostructured (HNS) CoSn(OH)6 to fabricate a pseudocapacitor. In this endeavor, NH3 is found to be a well-suited hydrolyzing agent for the synthesis.3 Serendipitously, HNS was transformed into favored cubic nanostructure (CNS) in NaOH solution. In solution, NaOH acts as a structure directing as well as an etching agent. Both the samples (HNS & CNS) were used as pseudocapacitor electrodes in KOH electrolyte independently, which is reported for the first time. The HNS exhibits very high specific capacitance value (2545 F/g at 2.5 A/g specific current) with better cyclic durability over CNS sample (851 F/g at 2.5 A/g specific current). To examine the real cell application, we used HNS sample as the positive electrode material with the activated carbon (AC) as the negative electrode material for the development of an aqueous asymmetric supercapacitor (AAS). The as-fabricated AAS exhibited very high specific capacitance value of 713 F/g at a specific current of 1.5 A/g and retained 92% specific capacitance value even after 10 000 charge-discharge cycles. A maximum energy density of 63.5 Wh kg(-1) and a maximum power density of 5277 W kg(-1) were ascertained from the as-fabricated AAS, HNS CoSn(OH)6//AC.
authors.affiliation: Department of Chemistry and §Department of Civil Engineering, Indian Institute of Technology , Kharagpur 721302, India.
authors.forename: Ramkrishna
authors.initials: R
authors.lastname: Sahoo
authors.affiliation: Department of Chemistry and §Department of Civil Engineering, Indian Institute of Technology , Kharagpur 721302, India.
authors.forename: Anup Kumar
authors.initials: AK
authors.lastname: Sasmal
authors.affiliation: Department of Chemistry and §Department of Civil Engineering, Indian Institute of Technology , Kharagpur 721302, India.
authors.forename: Chaiti
authors.initials: C
authors.lastname: Ray
authors.affiliation: Department of Chemistry and §Department of Civil Engineering, Indian Institute of Technology , Kharagpur 721302, India.
authors.forename: Soumen
authors.initials: S
authors.lastname: Dutta
authors.affiliation: Department of Chemistry and §Department of Civil Engineering, Indian Institute of Technology , Kharagpur 721302, India.
authors.forename: Anjali
authors.initials: A
authors.lastname: Pal
authors.affiliation: Department of Chemistry and §Department of Civil Engineering, Indian Institute of Technology , Kharagpur 721302, India.
authors.forename: Tarasankar
authors.initials: T
authors.lastname: Pal
keywords: ammonia; aqueous asymmetric supercapacitor (AAS); etching; hierarchical (HNS) and cubic (CNS) CoSn(OH)6 nanostructures; pseudocapacitor; sodium hydroxide