title: Manganese Phosphate Self-assembled Nanoparticle Surface and Its application for Superoxide Anion Detection.
abstract: Quantitative analysis of superoxide anion (O2(·-)) has increasing importance considering its potential damages to organism. Herein, a novel Mn-superoxide dismutase (MnSOD) mimics, silica-manganous phosphate (SiO2-Mn3(PO4)2) nanoparticles, were designed and synthesized by surface self-assembly processes that occur on the surface of silica-phytic acid (SiO2-PA) nanoparticles. The composite nanoparticles were characterized by fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), scanning electronic microscopy (SEM), electron diffraction pattern, energy dispersive spectroscopy (EDS) and elemental mapping. Then the electrochemical measurements of O2(·-) based on the incorporation of SiO2-Mn3(PO4)2 onto the surface of electrodes were performed, and some satisfactory results were obtained. This is the first report that manganous phosphate (Mn3(PO4)2) nanoparticles with shape-controlled, but not multilayer sheets, were utilized for O2(·-) detection. The surface self-assembly technology we proposed will offer the ideal material to construct more types biosensor and catalytic system for its nanosized effect.
authors.affiliation: National and Local Joint Engineering Research Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Biofunctional Materials, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing, 210023, China.
authors.forename: Xiaohui
authors.initials: X
authors.lastname: Shen
authors.affiliation: National and Local Joint Engineering Research Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Biofunctional Materials, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing, 210023, China.
authors.forename: Qi
authors.initials: Q
authors.lastname: Wang
authors.affiliation: National and Local Joint Engineering Research Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Biofunctional Materials, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing, 210023, China.
authors.forename: Yuhong
authors.initials: Y
authors.lastname: Liu
authors.affiliation: National and Local Joint Engineering Research Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Biofunctional Materials, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing, 210023, China.
authors.forename: Wenxiao
authors.initials: W
authors.lastname: Xue
authors.affiliation: National and Local Joint Engineering Research Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Biofunctional Materials, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing, 210023, China.
authors.forename: Lie
authors.initials: L
authors.lastname: Ma
authors.affiliation: National and Local Joint Engineering Research Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Biofunctional Materials, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing, 210023, China.
authors.forename: Shuaihui
authors.initials: S
authors.lastname: Feng
authors.affiliation: National and Local Joint Engineering Research Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Biofunctional Materials, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing, 210023, China.
authors.forename: Mimi
authors.initials: M
authors.lastname: Wan
authors.affiliation: National and Local Joint Engineering Research Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Biofunctional Materials, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing, 210023, China.
authors.forename: Fenghe
authors.initials: F
authors.lastname: Wang
authors.affiliation: National and Local Joint Engineering Research Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Biofunctional Materials, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing, 210023, China.
authors.forename: Chun
authors.initials: C
authors.lastname: Mao