title: [BEDT-TTF][Fe(C2O4)Cl2]: an organic-inorganic hybrid semiconductive antiferromagnet.
abstract: A radical cation salt composed of an organic donor, BEDT-TTF1.0+, and a one-dimensional inorganic anion, [Fe(C2O4)Cl2-]n, was obtained by electrocrystallization, and was identified as a semiconductor with values of σ300K= 3.0 × 10-5S cm-1. Spin-canted antiferromagnetic long-range ordering was observed at 5.5 K from ZFCM/FCM/RM measurement and confirmed using AC measurement.
authors.affiliation: Organic Solid Laboratory, CMS & BNLMS, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China. zhangbin@iccasa.c.cn.
authors.forename: B
authors.initials: B
authors.lastname: Zhang
authors.affiliation: Institute of Condensed Matter and Material Physics, School of Physics, Peking University, Beijing, 100871, P. R. China.
authors.forename: Y
authors.initials: Y
authors.lastname: Zhang
authors.affiliation: BNLMS, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, P. R. China.
authors.forename: Z
authors.initials: Z
authors.lastname: Wang
authors.affiliation: Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China.
authors.forename: D
authors.initials: D
authors.lastname: Yang
authors.affiliation: BSRF, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100047, P. R. China.
authors.forename: Z
authors.initials: Z
authors.lastname: Gao
authors.affiliation: National Center for Nanoscience and Technology, Beijing, 100190, P. R. China.
authors.forename: D
authors.initials: D
authors.lastname: Wang
authors.affiliation: National Center for Nanoscience and Technology, Beijing, 100190, P. R. China.
authors.forename: Y
authors.initials: Y
authors.lastname: Guo
authors.affiliation: Organic Solid Laboratory, CMS & BNLMS, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China. zhangbin@iccasa.c.cn.
authors.forename: D
authors.initials: D
authors.lastname: Zhu
authors.affiliation: Department of Organic and Polymeric Materials, Tokyo Institute of Technology, O-Okayama 2-12-1, Meguro-Ku, Tokyo 152-8552, Japan.
authors.forename: T
authors.initials: T
authors.lastname: Mori