title: Unexpected Reactivity of Trifluoromethyl Diazomethane (CF3CHN2): Electrophilicity of the Terminal N-Atom.
abstract: After more than 70 years since its discovery, CF3CHN2 was found to possess a novel reactivity mode: N-terminal electrophile. With C-nucleophiles it gives hydrazones that are easily transformed into valuable CF3-heterocycles.
authors.affiliation: Enamine Ltd., Chervonotkatska 78, Kyiv 02094, Ukraine.|Department of Chemistry, National Taras Shevchenko University of Kyiv , Volodymyrska 64, Kyiv 01033, Ukraine.
authors.forename: Anton V
authors.initials: AV
authors.lastname: Arkhipov
authors.affiliation: Enamine Ltd., Chervonotkatska 78, Kyiv 02094, Ukraine.|Department of Chemistry, National Taras Shevchenko University of Kyiv , Volodymyrska 64, Kyiv 01033, Ukraine.
authors.forename: Viatcheslav V
authors.initials: VV
authors.lastname: Arkhipov
authors.affiliation: Laboratoire de Chimie Organique, Institute of Chemistry, Biology and Innovation (CBI), UMR 8231, ESPCI ParisTech/CNRS/PSL Research University , 10 rue Vauquelin, Paris 75231 Cedex 05, France.
authors.forename: Janine
authors.initials: J
authors.lastname: Cossy
authors.affiliation: Department of Chemistry, National Taras Shevchenko University of Kyiv , Volodymyrska 64, Kyiv 01033, Ukraine.
authors.forename: Volodymir O
authors.initials: VO
authors.lastname: Kovtunenko
authors.affiliation: Enamine Ltd., Chervonotkatska 78, Kyiv 02094, Ukraine.|Department of Chemistry, National Taras Shevchenko University of Kyiv , Volodymyrska 64, Kyiv 01033, Ukraine.|Laboratoire de Chimie Organique, Institute of Chemistry, Biology and Innovation (CBI), UMR 8231, ESPCI ParisTech/CNRS/PSL Research University , 10 rue Vauquelin, Paris 75231 Cedex 05, France.
authors.forename: Pavel K
authors.initials: PK
authors.lastname: Mykhailiuk