title: Dinuclear Ruthenium(III)-Ruthenium(IV) Complexes, Having a Doubly Oxido-Bridged and Acetato- or Nitrato-Capped Framework.
abstract: Dinuclear ruthenium complexes in a mixed-valence state of Ru(III)-Ru(IV), having a doubly oxido-bridged and acetato- or nitrato-capped framework, [{Ru(III,IV)(ebpma)}2(μ-O)2(μ-L)](PF6)2 [ebpma = ethylbis(2-pyridylmethyl)amine; L = CH3COO(-) (1), NO3(-) (2)], were synthesized. In aqueous solutions, the diruthenium complex 1 showed multiple redox processes accompanied by proton transfers depending on the pH. The protonated complex of 1, which is described as 1H+, was obtained.
authors.affiliation: Department of Materials and Life Sciences, Faculty of Science and Technology, Sophia University , 7-1 Kioi-cho, Chiyoda-ku, Tokyo 102-8554 Japan.
authors.forename: Tomoyo
authors.initials: T
authors.lastname: Suzuki
authors.affiliation: Department of Materials and Life Sciences, Faculty of Science and Technology, Sophia University , 7-1 Kioi-cho, Chiyoda-ku, Tokyo 102-8554 Japan.
authors.forename: Yutaka
authors.initials: Y
authors.lastname: Suzuki
authors.affiliation: Department of Chemistry, Faculty of Science, Kanagawa University , Hiratsuka, Kanagawa 259-1293, Japan.
authors.forename: Tatsuya
authors.initials: T
authors.lastname: Kawamoto
authors.affiliation: Graduate School of Science and Technology, Hirosaki University , Bunkyo-cho, Hirosaki 036-8561, Japan.
authors.forename: Ryo
authors.initials: R
authors.lastname: Miyamoto
authors.affiliation: Department of Materials and Life Sciences, Faculty of Science and Technology, Sophia University , 7-1 Kioi-cho, Chiyoda-ku, Tokyo 102-8554 Japan.
authors.forename: Shinkoh
authors.initials: S
authors.lastname: Nanbu
authors.affiliation: Department of Materials and Life Sciences, Faculty of Science and Technology, Sophia University , 7-1 Kioi-cho, Chiyoda-ku, Tokyo 102-8554 Japan.
authors.forename: Hirotaka
authors.initials: H
authors.lastname: Nagao