title: Ullmann coupling reaction of aryl chlorides on Au(111) using dosed Cu as a catalyst and the programmed growth of 2D covalent organic frameworks.
abstract: The efficiency of Ullmann reaction of aryl chlorides on an Au(111) surface has been substantially increased by using dosed Cu as a catalyst. The different reactivity of aryl bromides and aryl chlorides has been exploited to design a programmed, on-surface synthesis to form 2D covalent organic frameworks.
authors.affiliation: Shanghai Key Laboratory of Functional Materials Chemistry, Key Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Meilong Road 130, Shanghai 200237, China. liupn@ecust.edu.cn.
authors.forename: Ke Ji
authors.initials: KJ
authors.lastname: Shi
authors.affiliation: Shanghai Key Laboratory of Functional Materials Chemistry, Key Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Meilong Road 130, Shanghai 200237, China. liupn@ecust.edu.cn.
authors.forename: Xin
authors.initials: X
authors.lastname: Zhang
authors.affiliation: Shanghai Key Laboratory of Functional Materials Chemistry, Key Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Meilong Road 130, Shanghai 200237, China. liupn@ecust.edu.cn.
authors.forename: Chen Hui
authors.initials: CH
authors.lastname: Shu
authors.affiliation: Shanghai Key Laboratory of Functional Materials Chemistry, Key Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Meilong Road 130, Shanghai 200237, China. liupn@ecust.edu.cn.
authors.forename: Deng Yuan
authors.initials: DY
authors.lastname: Li
authors.affiliation: Shanghai Key Laboratory of Functional Materials Chemistry, Key Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Meilong Road 130, Shanghai 200237, China. liupn@ecust.edu.cn.
authors.forename: Xin Yan
authors.initials: XY
authors.lastname: Wu
authors.affiliation: Shanghai Key Laboratory of Functional Materials Chemistry, Key Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Meilong Road 130, Shanghai 200237, China. liupn@ecust.edu.cn.
authors.forename: Pei Nian
authors.initials: PN
authors.lastname: Liu