title: Thermal and near-infrared light induced spin crossover in a mononuclear iron(ii) complex with a tetrathiafulvalene-fused dipyridophenazine ligand.
abstract: A mononuclear Fe(ii) complex involving a tetrathiafulvalene-based ligand exhibits thermal spin-crossover (around 143 K) with pronounced hysteresis behaviour (48 K). The chromophoric and π-extended ligand allows Near-Infrared (NIR) sensitization for the light-induced excited spin-state trapping (LIESST) with T(LIESST) = 90 K.
authors.affiliation: Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS - Université de Rennes 1, 35042, Rennes Cedex, France. fabrice.pointillart@univ-rennes1.fr.
authors.forename: F
authors.initials: F
authors.lastname: Pointillart
authors.forename: X
authors.initials: X
authors.lastname: Liu
authors.forename: M
authors.initials: M
authors.lastname: Kepenekian
authors.forename: B
authors.initials: B
authors.lastname: Le Guennic
authors.forename: S
authors.initials: S
authors.lastname: Golhen
authors.forename: V
authors.initials: V
authors.lastname: Dorcet
authors.forename: T
authors.initials: T
authors.lastname: Roisnel
authors.forename: O
authors.initials: O
authors.lastname: Cador
authors.forename: Z
authors.initials: Z
authors.lastname: You
authors.forename: J
authors.initials: J
authors.lastname: Hauser
authors.forename: S
authors.initials: S
authors.lastname: Decurtins
authors.forename: L
authors.initials: L
authors.lastname: Ouahab
authors.forename: S-X
authors.initials: SX
authors.lastname: Liu