title: A three-coordinate Fe(ii) center within a [3Fe-(μ3-S)] cluster that provides an accessible coordination site.
abstract: A μ3-sulfide bridged triiron cluster(ii,ii,iii) supported by a cyclophane ligand undergoes metal-based reduction to yield an all-ferrous species. The latter complex incorporates a three-coordinate iron center that provides an accessible coordination site to a solvent molecule.
authors.affiliation: University of Florida, Department of Chemistry, Center for Catalysis, Gainesville, FL 32611-7200, USA. murray@chem.ufl.edu.
authors.forename: Yousoon
authors.initials: Y
authors.lastname: Lee
authors.forename: Khalil A
authors.initials: KA
authors.lastname: Abboud
authors.forename: Ricardo
authors.initials: R
authors.lastname: García-Serres
authors.forename: Leslie J
authors.initials: LJ
authors.lastname: Murray