title: Spatial aromatic fences of metal-organic frameworks for manipulating the electron spin of a fulleropyrrolidine nitroxide radical.
abstract: The electron spin properties of a fulleropyrrolidine nitroxide radical incarcerated in the pores of MOF-177 and MIL-53 respectively were investigated for the first time. It was found that the spatial confinement effect and intramolecular interactions in these two solid-state spin systems lead to dramatically distinctive spin dynamics.
authors.affiliation: State Key Laboratory of Solid Lubrication & Laboratory of Clean Energy Chemistry and Materials, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, China. fengyq@licp.cas.cn hgli@licp.cas.cn.
authors.forename: Jiamei
authors.initials: J
authors.lastname: Cao
authors.forename: Yongqiang
authors.initials: Y
authors.lastname: Feng
authors.forename: Shengju
authors.initials: S
authors.lastname: Zhou
authors.forename: Xiaofeng
authors.initials: X
authors.lastname: Sun
authors.forename: Taishan
authors.initials: T
authors.lastname: Wang
authors.forename: Chunru
authors.initials: C
authors.lastname: Wang
authors.forename: Hongguang
authors.initials: H
authors.lastname: Li