title: Facile Preparation and Lithium Storage Properties of TiO2 @Graphene Composite Electrodes with Low Carbon Content.
abstract: Over the past decade, TiO2 /graphene composites as electrodes for lithium ion batteries have attracted a great deal of attention for reasons of safety and environmental friendliness. However, most of the TiO2 /graphene electrodes have large graphene content (9-40 %), which is bound to increase the cost of the battery. Logically, reducing the amount of graphene is a necessary part to achieve a green battery. The synthesis of TiO2 nanosheets under solvothermal conditions without additives is now demonstrated. Through mechanical mixing TiO2 nanosheets with different amount of reduced graphene (rGO), a series of TiO2 @graphene composites was prepared with low graphene content (rGO content 1, 2, 3, and 5 wt %). When these composites were evaluated as anodes for lithium ion batteries, it was found that TiO2 +3 wt % rGO manifested excellent cycling stability and a high specific capacity (243.7 mAh g(-1) at 1 C; 1 C=167.5 mA g(-1) ), and demonstrated superior high-rate discharge/charge capability at 20 C.
authors.affiliation: School of Materials Science and Engineering, Tianjin University of Technology, Tianjin, 300384, P. R. China.|Tianjin Key Lab for Photoelectric Materials & Devices, Tianjin, 300384, P. R. China.
authors.forename: Sheng-Qi
authors.initials: SQ
authors.lastname: Guo
authors.affiliation: Tianjin Key Laboratory of Environmental Remediation and Pollution Control, Nankai University, Tianjin, 300071, P. R. China.
authors.forename: Meng-Meng
authors.initials: MM
authors.lastname: Zhen
authors.affiliation: Tianjin Key Laboratory of Environmental Remediation and Pollution Control, Nankai University, Tianjin, 300071, P. R. China. liul@nankai.edu.cn.
authors.forename: Lu
authors.initials: L
authors.lastname: Liu
authors.affiliation: School of Materials Science and Engineering, Tianjin University of Technology, Tianjin, 300384, P. R. China. zhyuan@tjut.edu.cn.|Tianjin Key Lab for Photoelectric Materials & Devices, Tianjin, 300384, P. R. China. zhyuan@tjut.edu.cn.
authors.forename: Zhi-Hao
authors.initials: ZH
authors.lastname: Yuan
keywords: anodes; graphene; lithium ion batteries; mechanical mixing; titanium dioxide