title: Direct Measurement of the Fluid Phase Diagram.
abstract: The thermodynamic phase of a fluid (liquid, vapor or supercritical) is fundamental to all chemical processes, and the critical point is particularly important for supercritical chemical extraction. Conventional phase measurement methods require hours to obtain a single datum on the pressure and temperature diagram. Here, we present the direct measurement of the full pressure-temperature phase diagram, with 10 000 microwells. Orthogonal, linear, pressure and temperature gradients are obtained with 100 parallel microchannels (spanning the pressure range), each with 100 microwells (spanning the temperature range). The phase-mapping approach is demonstrated with both a pure substance (CO2) and a mixture (95% CO2 + 5% N2). Liquid, vapor, and supercritical regions are clearly differentiated, and the critical pressure is measured at 1.2% error with respect to the NIST standard. This approach provides over 100-fold improvement in measurement speed over conventional methods.
authors.affiliation: Department of Mechanical and Industrial Engineering, University of Toronto , 5 King's College Road, Toronto, M5S3G8, Ontario, Canada.
authors.forename: Bo
authors.initials: B
authors.lastname: Bao
authors.affiliation: Department of Mechanical and Industrial Engineering, University of Toronto , 5 King's College Road, Toronto, M5S3G8, Ontario, Canada.
authors.forename: Jason
authors.initials: J
authors.lastname: Riordon
authors.affiliation: Department of Mechanical and Industrial Engineering, University of Toronto , 5 King's College Road, Toronto, M5S3G8, Ontario, Canada.
authors.forename: Yi
authors.initials: Y
authors.lastname: Xu
authors.affiliation: Department of Mechanical and Industrial Engineering, University of Toronto , 5 King's College Road, Toronto, M5S3G8, Ontario, Canada.
authors.forename: Huawei
authors.initials: H
authors.lastname: Li
authors.affiliation: Department of Mechanical and Industrial Engineering, University of Toronto , 5 King's College Road, Toronto, M5S3G8, Ontario, Canada.
authors.forename: David
authors.initials: D
authors.lastname: Sinton