title: Hot-Press-Assisted Adhesions between Polyimide Films and Titanium Plates Utilizing Coating Layers of Silane Coupling Agents.
abstract: The development of low material-consuming adhesion techniques for different kinds of materials such as polymers and metals is important for the realization of sustainable societies. This study demonstrates that coating layers, expected to be formed as self-assembled monolayers, of silane coupling agents can act as adhesion layers at the polymer film-metal plate interfaces. Polyimide films were alkaline hydrolyzed to generate carboxy groups on their surfaces, whereas titanium plate surfaces were treated with the aminosilanes to form their coating layers thereon. These modified surfaces were placed in contact with each other and then hot pressed, which resulted in adhesion between them. An examination of the adhesion strength using lap shear tests and surface characterization of the prepared surfaces using X-ray photoelectron spectroscopy and other techniques indicated the formation of ionic bonds and/or amide bonds between the carboxy groups of the PI film surfaces and the amino groups immobilized on the titanium plate surfaces. The activation of the carboxy groups using N-hydroxysuccinimide resulted in adhesion obtaining a water-resistant property, which supported the increase in amide bond formation. On the basis of the results, the adhesion mechanism and the possible breaking points upon the breaking of adhesions are proposed.
authors.affiliation: Department of Industrial Chemistry, Faculty of Engineering and ‡Graduate School of Chemical Sciences and Technology, Tokyo University of Science , 12-1 Ichigayafunagawara-machi, Shinjuku-ku, Tokyo 162-0826, Japan.
authors.forename: Mineo
authors.initials: M
authors.lastname: Hashizume
authors.affiliation: Department of Industrial Chemistry, Faculty of Engineering and ‡Graduate School of Chemical Sciences and Technology, Tokyo University of Science , 12-1 Ichigayafunagawara-machi, Shinjuku-ku, Tokyo 162-0826, Japan.
authors.forename: Soichiro
authors.initials: S
authors.lastname: Fukagawa
authors.affiliation: Department of Industrial Chemistry, Faculty of Engineering and ‡Graduate School of Chemical Sciences and Technology, Tokyo University of Science , 12-1 Ichigayafunagawara-machi, Shinjuku-ku, Tokyo 162-0826, Japan.
authors.forename: Shoko
authors.initials: S
authors.lastname: Mishima
authors.affiliation: Department of Industrial Chemistry, Faculty of Engineering and ‡Graduate School of Chemical Sciences and Technology, Tokyo University of Science , 12-1 Ichigayafunagawara-machi, Shinjuku-ku, Tokyo 162-0826, Japan.
authors.forename: Takumi
authors.initials: T
authors.lastname: Osuga
authors.affiliation: Department of Industrial Chemistry, Faculty of Engineering and ‡Graduate School of Chemical Sciences and Technology, Tokyo University of Science , 12-1 Ichigayafunagawara-machi, Shinjuku-ku, Tokyo 162-0826, Japan.
authors.forename: Kazutoshi
authors.initials: K
authors.lastname: Iijima