title: Encapsulating Palladium Nanoparticles Inside Mesoporous MFI Zeolite Nanocrystals for Shape-Selective Catalysis.
abstract: Pd nanoparticles were successfully encapsulated inside mesoporous silicalite-1 nanocrystals (Pd@mnc-S1) by a one-pot method. The as-synthesized Pd@mnc-S1 with excellent stability functioned as an active and reusable heterogeneous catalyst. The unique porosity and nanostructure of silicalite-1 crystals endowed the Pd@mnc-S1 material general shape-selectivity for various catalytic reactions, including selective hydrogenation, oxidation, and carbon-carbon coupling reactions.
authors.affiliation: School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, P. R. China.
authors.forename: Tian-Lu
authors.initials: TL
authors.lastname: Cui
authors.affiliation: School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, P. R. China.
authors.forename: Wen-Yu
authors.initials: WY
authors.lastname: Ke
authors.affiliation: School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, P. R. China.
authors.forename: Wen-Bei
authors.initials: WB
authors.lastname: Zhang
authors.affiliation: School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, P. R. China.
authors.forename: Hong-Hui
authors.initials: HH
authors.lastname: Wang
authors.affiliation: School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, P. R. China. xinhaoli@sjtu.edu.cn.
authors.forename: Xin-Hao
authors.initials: XH
authors.lastname: Li
authors.affiliation: School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, P. R. China. chemcj@sjtu.edu.cn.
authors.forename: Jie-Sheng
authors.initials: JS
authors.lastname: Chen
keywords: mesoporous materials; nanocrystals; palladium; shape-selective catalysis; zeolites