title: Comparative Photocatalytic Degradation of Monoazo and Diazo Dyes Under Simulated Visible Light Using Fe3+/C/S doped-TiO2 Nanoparticles.
abstract: This research work delved into the photocatalytic degradation of monoazo dye (methyl orange) and diazo dye (congo red) in aqueous solution using Fe3+/C/S-doped TiO2 nanocomposites. The nanocomposites were synthesised through sol-gel method and characterized using XRD, FTIR, SEM, TEM, EDX, BET and UV-Vis. Photocatalytic degradation of the dyes was monitored under simulated visible light using pristine TiO2, C/S/doped-TiO2 and Fe3+/C/S doped-TiO2 with varying concentrations of Fe3+. The influence of catalyst doping, solution pH, and light intensity were also examined. Doping TiO2 with Fe3+/C/S caused reduction in its band gap value with the resultant improvement in its visible light activity. The photocatalytic efficiency of the catalysts is given as follows: TiO2 < C/S/TiO2 < Fe3+/C/S-TiO2 with Fe3+/C/S-TiO2 (0.3% Fe3+) as the best performing photocatalyst. The monoazo dye experienced higher degradation efficiency than the diazo dye. Degradation of the azo dyes was observed to decrease with increasing pH from 2 to 12. Increased visible light intensity enhanced the photodegradation efficiency of the dye. Dye decolourization was observed to be faster than its mineralization.
authors.forename: William Wilson
authors.initials: WW
authors.lastname: Anku
authors.forename: Samuel Osei-Bonsu
authors.initials: SO
authors.lastname: Oppong
authors.forename: Sudheesh Kumar
authors.initials: SK
authors.lastname: Shukla
authors.forename: Poomani Penny
authors.initials: PP
authors.lastname: Govender