title: Remote C-H Functionalization by a Palladium-Catalyzed Transannular Approach.
abstract: Now within reach: In the remote C-H arylation of alicyclic amines the key step is the transannular coordination of the palladium catalyst (see picture, DG=directing group). This strategy is convenient for the late-stage functionalization of complex bioactive molecules in order to probe structure-activity relationships.
authors.affiliation: Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur-, 741246, West Bengal, India. suman.sarkar@iiserkol.ac.in.
authors.forename: Suman
authors.identifier: 0000-0002-6342-4711
authors.initials: S
authors.lastname: De Sarkar
keywords: C−H activation; alicyclic amines; arylation; palladium