title: Chiral Sensing of Various Amino Acids Using Induced Circularly Polarized Luminescence from Europium(III) Complexes of Phenanthroline Dicarboxylic Acid Derivatives.
abstract: Circularly polarized luminescence (CPL) was observed from [Eu(dppda)2 ](-) (dppda=4,7-diphenyl-1,10-phenanthroline-2,9-dicarboxylic acid) and [Eu(pzpda)2 ](-) (pzpda=pyrazino[2,3-f][1,10]phenanthroline-7,10-dicarboxylic acid) in aqueous solutions containing various amino acids. The selectivity of these complexes towards amino acids enabled them to be used as chiral sensors and their behavior was compared with that of [Eu(pda)2 ](-) (pda=1,10-phenanthroline-2,9-dicarboxylic acid). As these Eu(III) complexes have achiral D2d structures under ordinary conditions, there were no CPL signals in the emission assigned to f-f transitions. However, when the solutions contained particular amino acids they exhibited detectable CPL signals with glum values of about 0.1 (glum =CPL/2 TL; TL=total luminescence). On examining 13 amino acids with these three Eu(III) complexes, it was found that whether an amino acid induced a detectable CPL depended on the Eu(III) complex ligands. For example, when ornithine was used as a chiral agent, only [Eu(dppda)2 ](-) exhibited intense CPL in aqueous solutions of 10(-2)  mol dm(-3) . Steep amino acid concentration dependence suggested that CPL in [Eu(dppda)2 ](-) and [Eu(pzpda)2 ](-) was induced by the association of four or more amino acid molecules, whereas CPL in [Eu(pda)2 ](-) was induced by association of two arginine molecules.
authors.affiliation: Graduated School of Science and Engineering, University of Toyama, Gofuku, 3190, Toyama, Japan.
authors.forename: Taka-Aki
authors.initials: TA
authors.lastname: Uchida
authors.affiliation: Graduated School of Science and Engineering, University of Toyama, Gofuku, 3190, Toyama, Japan.
authors.forename: Koichi
authors.initials: K
authors.lastname: Nozaki
authors.affiliation: Graduated School of Science and Engineering, University of Toyama, Gofuku, 3190, Toyama, Japan. miwamura@sci.u-toyama.ac.jp.
authors.forename: Munetaka
authors.identifier: http://orcid.org/0000-0002-4888-9086
authors.initials: M
authors.lastname: Iwamura
keywords: amino acids; chirality; lanthanides; luminescence; sensors