title: Chemoselective Synthesis of Carbamates using CO2 as Carbon Source.
abstract: Synthesis of carbamates directly from amines using CO2 as the carbon source is a straightforward and sustainable approach. Herein, we describe a highly effective and chemoselective methodology for the synthesis of carbamates at room temperature and atmospheric pressure. This methodology can also be applied to protect the amino group in amino acids and peptides, and also to synthesize important pharmaceuticals.
authors.affiliation: Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstr. 2, 37077, Göttingen, Germany.
authors.forename: Daniel
authors.initials: D
authors.lastname: Riemer
authors.affiliation: Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstr. 2, 37077, Göttingen, Germany.
authors.forename: Pradipbhai
authors.initials: P
authors.lastname: Hirapara
authors.affiliation: Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstr. 2, 37077, Göttingen, Germany. shoubhik.das@chemie.uni-goettingen.de.
authors.forename: Shoubhik
authors.initials: S
authors.lastname: Das
mesh_terms: D000596:Amino Acids / Q000737:chemistry; D001274:Atmospheric Pressure; D002219:Carbamates / Q000138:chemical synthesis* / Q000737:chemistry; D002244:Carbon / Q000737:chemistry*; D002245:Carbon Dioxide / Q000737:chemistry*; D060326:Chemistry Techniques, Synthetic; D013696:Temperature
chemical_list: D000596:Amino Acids; D002219:Carbamates; D002245:Carbon Dioxide; D002244:Carbon
keywords: carbamates; carbon dioxide; chemoselective; peptides; protecting group