title: Peracetic Acid Depolymerization of Biorefinery Lignin for Production of Selective Monomeric Phenolic Compounds.
abstract: Lignin is the largest source of renewable material with an aromatic skeleton. However, due to the recalcitrant and heterogeneous nature of the lignin polymer, it has been a challenge to effectively depolymerize lignin and produce high-value chemicals with high selectivity. In this study, a highly efficient lignin-to-monomeric phenolic compounds (MPC) conversion method based on peracetic acid (PAA) treatment was reported. PAA treatment of two biorefinery lignin samples, diluted acid pretreated corn stover lignin (DACSL) and steam exploded spruce lignin (SESPL), led to complete solubilization and production of selective hydroxylated monomeric phenolic compounds (MPC-H) and monomeric phenolic acid compounds (MPC-A) including 4-hydroxy-2-methoxyphenol, p-hydroxybenzoic acid, vanillic acid, syringic acid, and 3,4-dihydroxybenzoic acid. The maximized MPC yields obtained were 18 and 22 % based on the initial weight of the lignin in SESPL and DACSL, respectively. However, we found that the addition of niobium pentoxide catalyst to PAA treatment of lignin can significantly improve the MPC yields up to 47 %. The key reaction steps and main mechanisms involved in this new lignin-to-MPC valorization pathway were investigated and elucidated.
authors.affiliation: Voiland School of Chemical Engineering and Bioengineering, Bioproducts, Science & Engineering Laboratory, Washington State University, 2710 Crimson Way, Richland, WA, 99354, USA.
authors.forename: Ruoshui
authors.initials: R
authors.lastname: Ma
authors.affiliation: Voiland School of Chemical Engineering and Bioengineering, Bioproducts, Science & Engineering Laboratory, Washington State University, 2710 Crimson Way, Richland, WA, 99354, USA.
authors.forename: Mond
authors.initials: M
authors.lastname: Guo
authors.affiliation: Voiland School of Chemical Engineering and Bioengineering, Bioproducts, Science & Engineering Laboratory, Washington State University, 2710 Crimson Way, Richland, WA, 99354, USA.
authors.forename: Kuan-Ting
authors.initials: KT
authors.lastname: Lin
authors.affiliation: Food and Environmental Laboratory, Washington State, University-TriCities, 2710 Crimson Way, Richland, WA, 99354, USA.
authors.forename: Vincent R
authors.initials: VR
authors.lastname: Hebert
authors.affiliation: Wood Materials and Engineering Laboratory, Washington State University, Pullman, WA, 99164, USA.
authors.forename: Jinwen
authors.initials: J
authors.lastname: Zhang
authors.affiliation: Wood Materials and Engineering Laboratory, Washington State University, Pullman, WA, 99164, USA.
authors.forename: Michael P
authors.initials: MP
authors.lastname: Wolcott
authors.affiliation: Voiland School of Chemical Engineering and Bioengineering, Bioproducts, Science & Engineering Laboratory, Washington State University, 2710 Crimson Way, Richland, WA, 99354, USA.
authors.forename: Melissa
authors.initials: M
authors.lastname: Quintero
authors.affiliation: Chemical and Biological Process Development Group, Pacific Northwest National Laboratory, Richland, WA, 99354, USA.
authors.forename: Karthikeyan K
authors.initials: KK
authors.lastname: Ramasamy
authors.affiliation: National Bioenergy Center, National Renewable Energy Lab, 1617 Cole Blvd, Golden, CO, 80127, USA.
authors.forename: Xiaowen
authors.initials: X
authors.lastname: Chen
authors.affiliation: Voiland School of Chemical Engineering and Bioengineering, Bioproducts, Science & Engineering Laboratory, Washington State University, 2710 Crimson Way, Richland, WA, 99354, USA. x.zhang@wsu.edu.
authors.forename: Xiao
authors.initials: X
authors.lastname: Zhang
mesh_terms: D018533:Biomass; D002384:Catalysis; D062385:Hydroxybenzoates / Q000737:chemistry*; D008031:Lignin / Q000737:chemistry*; D010463:Peracetic Acid / Q000737:chemistry*; D058105:Polymerization
chemical_list: D062385:Hydroxybenzoates; D008031:Lignin; C017616:phenolic acid; D010463:Peracetic Acid
keywords: C−C bond; biomass; depolymerization; lignin; oxidation