title: Synthesis of Androprostamine A and Resormycin.
abstract: Syntheses of androprostamine A (1), and resormycin (3), anti-prostate cancer peptidyl natural products produced by microorganisms, were completed. The characteristic enamide structures of these compounds were installed using the Horner-Wadsworth-Emmons reaction from the corresponding phosphonates in reasonable Z-selectivity.
authors.affiliation: Institute of Microbial Chemistry (BIKAKEN), Tokyo.
authors.forename: Hikaru
authors.initials: H
authors.lastname: Abe
authors.forename: Yohko
authors.initials: Y
authors.lastname: Yamazaki
authors.forename: Chiharu
authors.initials: C
authors.lastname: Sakashita
authors.forename: Isao
authors.initials: I
authors.lastname: Momose
authors.forename: Takumi
authors.initials: T
authors.lastname: Watanabe
authors.forename: Masakatsu
authors.initials: M
authors.lastname: Shibasaki
mesh_terms: D002934:Cinnamates / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009842:Oligopeptides / Q000138:chemical synthesis* / Q000737:chemistry; D011422:Propionates / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D002934:Cinnamates; D009842:Oligopeptides; D011422:Propionates; C000599108:androprostamine A; C111138:resormycin