title: Electronic spectrum of 9-methylanthracenium radical cation.
abstract: The predissociation spectrum of the cold, argon-tagged, 9-methylanthracenium radical cation is reported from 8000 cm(-1) to 44 500 cm(-1). The reported spectrum contains bands corresponding to at least eight electronic transitions ranging from the near infrared to the ultraviolet. These electronic transitions are assigned through comparison with ab initio energies and intensities. The infrared D1←D0 transitions exhibit significant vibronic activity, which is assigned through comparison with TD-B3LYP excited state frequencies and intensities, as well as modelled vibronic interactions. Dissociation of 9-methylanthracenium is also observed at high visible-photon energies, resulting in the loss of either CH2 or CH3. The relevance of these spectra, and the spectra of other polycyclic aromatic hydrocarbon radical cations, to the largely unassigned diffuse interstellar bands, is discussed.
authors.affiliation: School of Chemistry, UNSW Sydney, New South Wales 2052, Australia.
authors.forename: Gerard D
authors.initials: GD
authors.lastname: O'Connor
authors.affiliation: School of Chemistry, The University of Melbourne, Victoria 3010, Australia.
authors.forename: Julian A
authors.initials: JA
authors.lastname: Sanelli
authors.affiliation: School of Chemistry, The University of Melbourne, Victoria 3010, Australia.
authors.forename: Vik
authors.initials: V
authors.lastname: Dryza
authors.affiliation: School of Chemistry, The University of Melbourne, Victoria 3010, Australia.
authors.forename: Evan J
authors.initials: EJ
authors.lastname: Bieske
authors.affiliation: School of Chemistry, UNSW Sydney, New South Wales 2052, Australia.
authors.forename: Timothy W
authors.initials: TW
authors.lastname: Schmidt