title: Selective and Efficient Reduction of Carbon Dioxide to Carbon Monoxide on Oxide-Derived Nanostructured Silver Electrocatalysts.
abstract: In this work, the selective electrocatalytic reduction of carbon dioxide to carbon monoxide on oxide-derived silver electrocatalysts is presented. By a simple synthesis technique, the overall high faradaic efficiency for CO production on the oxide-derived Ag was shifted by more than 400 mV towards a lower overpotential compared to that of untreated Ag. Notably, the Ag resulting from Ag oxide is capable of electrochemically reducing CO2 to CO with approximately 80 % catalytic selectivity at a moderate overpotential of 0.49 V, which is much higher than that (ca. 4 %) of untreated Ag under identical conditions. Electrokinetic studies show that the improved catalytic activity is ascribed to the enhanced stabilization of COOH(.) intermediate. Furthermore, highly nanostructured Ag is likely able to create a high local pH near the catalyst surface, which may also facilitate the catalytic activity for the reduction of CO2 with suppressed H2 evolution.
authors.affiliation: Materials for Energy Conversion and Storage (MECS), Department of Chemical Engineering, Delft University of Technology, P.O. Box 5045, 2600, GA, Delft, The Netherlands.|State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao, 266580, Shandong, P.R. China.
authors.forename: Ming
authors.identifier: 0000-0003-3561-5710
authors.initials: M
authors.lastname: Ma
authors.affiliation: Materials for Energy Conversion and Storage (MECS), Department of Chemical Engineering, Delft University of Technology, P.O. Box 5045, 2600, GA, Delft, The Netherlands.
authors.forename: Bartek J
authors.initials: BJ
authors.lastname: Trześniewski
authors.affiliation: Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, 5600, MB, Eindhoven, The Netherlands.
authors.forename: Jie
authors.initials: J
authors.lastname: Xie
authors.affiliation: Materials for Energy Conversion and Storage (MECS), Department of Chemical Engineering, Delft University of Technology, P.O. Box 5045, 2600, GA, Delft, The Netherlands. W.Smith@tudelft.nl.
authors.forename: Wilson A
authors.initials: WA
authors.lastname: Smith
keywords: carbon dioxide; conversion of carbon dioxide; electrocatalysis; heterogeneous catalysis; surface chemistry