title: Crystal structure of fac-aquatricarbonyl[(S)-valin-ato-κ(2) N,O]-rhenium(I).
abstract: In the mol-ecule of the title compound, [Re(C5H10NO2)(CO)3(H2O)], the Re(I) atom adopts a distorted octa-hedral coordination sphere defined by one aqua and three carbonyl ligands as well as one amino N and one carboxyl-ate O atom of the chelating valinate anion. The carbonyl ligands are arranged in a fac-configuration around the Re(I) ion. In the crystal, an intricate hydrogen-bonding system under participation of two O-H, two N-H and one C-H donor groups and the carboxyl-ate and carbonyl O atoms as acceptor groups contribute to the formation of a three-dimensional supra-molecular network.
authors.affiliation: Department of Inorganic Chemistry, Ukrainian State University of Chemical Technology, Gagarin Ave. 8, Dnipropetrovsk 49005, Ukraine.
authors.forename: Kseniia O
authors.initials: KO
authors.lastname: Piletska
authors.affiliation: Inorganic Chemistry Department, National Taras Shevchenko University of Kyiv, Volodymyrska Street 64/13, Kyiv 01601, Ukraine.
authors.forename: Kostiantyn V
authors.initials: KV
authors.lastname: Domasevitch
authors.affiliation: Department of Inorganic Chemistry, Ukrainian State University of Chemical Technology, Gagarin Ave. 8, Dnipropetrovsk 49005, Ukraine.
authors.forename: Alexander V
authors.initials: AV
authors.lastname: Shtemenko
keywords: crystal structure; rhenium carbonyl complex; valine