title: Room temperature synthesis of ultra-small, near-unity single-sized lead halide perovskite quantum dots with wide color emission tunability, high color purity and high brightness.
abstract: Phosphor with extremely narrow emission line widths, high brightness, and wide color emission tunability in visible regions is required for display and lighting applications, yet none has been reported in the literature so far. In the present study, single-sized lead halide perovskite (APbX 3; A = CH3NH3 and Cs; X = Cl, Br, and I) nanocrystalline (NC) phosphors were achieved for the first time in a one-pot reaction at room temperature (25 °C). The size-dependent samples, which included four families of CsPbBr3 NCs and exhibited sharp excitonic absorption peaks and pure band gap emission, were directly obtained by simply varying the concentration of ligands. The continuity of the optical spectrum can be successively tuned over the entire UV-visible spectral region (360-610 nm) by preparing CsPbCl3, CsPbI3, and CsPb(Y/Br)3 (Y = Cl and I) NCs with the use of CsPbBr3 NCs as templates by anion exchange while maintaining the size of NCs and high quantum yields of up to 80%. Notably, an emission line width of 10-24 nm, which is completely consistent with that of their single particles, indicates the formation of single-sized NCs. The versatility of the synthetic strategy was validated by extending it to the synthesis of single-sized CH3NH3PbX 3 NCs by simply replacing the cesium precursor by the CH3NH3 X precursor.
authors.affiliation: Chemistry, College of Chemistry, Jilin University, Changchun 130012, People's Republic of China.
authors.forename: Lucheng
authors.initials: L
authors.lastname: Peng
authors.forename: Jing
authors.initials: J
authors.lastname: Geng
authors.forename: Lisha
authors.initials: L
authors.lastname: Ai
authors.forename: Ying
authors.initials: Y
authors.lastname: Zhang
authors.forename: Renguo
authors.initials: R
authors.lastname: Xie
authors.forename: Wensheng
authors.initials: W
authors.lastname: Yang