title: Organic photoredox catalysis for the oxidation of silicates: applications in radical synthesis and dual catalysis.
abstract: Metal free photooxidation of alkyl bis(catecholato)silicates with the organic dye 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyano-benzene (4CzIPN) allows the smooth formation of alkyl radicals. The latter can be efficiently engaged either with radical acceptors to provide homolytic addition products or in photoredox/nickel dual catalysis reactions to obtain cross-coupling products.
authors.affiliation: Institut Parisien de Chimie Moléculaire, UMR CNRS 8232, Sorbonne Universités UPMC Univ Paris 06. 4 Place Jussieu, CC 229, F-75252 Paris Cedex 05, France.
authors.forename: Christophe
authors.initials: C
authors.lastname: Lévêque
authors.affiliation: Institut Parisien de Chimie Moléculaire, UMR CNRS 8232, Sorbonne Universités UPMC Univ Paris 06. 4 Place Jussieu, CC 229, F-75252 Paris Cedex 05, France.
authors.forename: Ludwig
authors.initials: L
authors.lastname: Chenneberg
authors.affiliation: Institut Parisien de Chimie Moléculaire, UMR CNRS 8232, Sorbonne Universités UPMC Univ Paris 06. 4 Place Jussieu, CC 229, F-75252 Paris Cedex 05, France.
authors.forename: Vincent
authors.initials: V
authors.lastname: Corcé
authors.affiliation: Institut Parisien de Chimie Moléculaire, UMR CNRS 8232, Sorbonne Universités UPMC Univ Paris 06. 4 Place Jussieu, CC 229, F-75252 Paris Cedex 05, France.
authors.forename: Cyril
authors.initials: C
authors.lastname: Ollivier
authors.affiliation: Institut Parisien de Chimie Moléculaire, UMR CNRS 8232, Sorbonne Universités UPMC Univ Paris 06. 4 Place Jussieu, CC 229, F-75252 Paris Cedex 05, France.
authors.forename: Louis
authors.initials: L
authors.lastname: Fensterbank