title: Fischer-Tropsch synthesis over MOF-supported cobalt catalysts (Co@MIL-53(Al)).
abstract: Novel nanohybrid materials were prepared by immobilizing Co nanoparticles on a microporous framework MIL-53(Al) as a porous host matrix. The synthesized cobalt-containing materials were characterized by XRD, STEM, and oxygen titration. The catalytic performance of Co@MIL-53(Al) nanohybrids was examined in Fischer-Tropsch synthesis (FTS) for the first time. A higher selectivity to C5+ hydrocarbons and lower selectivity to methane for Co@MIL-53(Al) as compared to conventional Co/Al2O3 were observed.
authors.affiliation: N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky prospect 47, Moscow 119991, Russia. sharf@ioc.ac.ru.
authors.forename: V I
authors.initials: VI
authors.lastname: Isaeva
authors.affiliation: N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky prospect 47, Moscow 119991, Russia. sharf@ioc.ac.ru.
authors.forename: O L
authors.initials: OL
authors.lastname: Eliseev
authors.affiliation: N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky prospect 47, Moscow 119991, Russia. sharf@ioc.ac.ru.
authors.forename: R V
authors.initials: RV
authors.lastname: Kazantsev
authors.affiliation: Chemistry Department, M.V. Lomonosov Moscow State University, Leninskie Gory 1, bldg. 3, Moscow 119992, Russia and A. N. Frumkin Institute of Physical Chemistry and Electrochemistry RAS, 31 Leninsky prospect, Moscow 119071, Russia.
authors.forename: V V
authors.initials: VV
authors.lastname: Chernyshev
authors.affiliation: N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky prospect 47, Moscow 119991, Russia. sharf@ioc.ac.ru.
authors.forename: P E
authors.initials: PE
authors.lastname: Davydov
authors.affiliation: Samara State Technical University, Molodogvardeiskaya ul. 244, Samara 443100, Russia.
authors.forename: B R
authors.initials: BR
authors.lastname: Saifutdinov
authors.affiliation: N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky prospect 47, Moscow 119991, Russia. sharf@ioc.ac.ru.
authors.forename: A L
authors.initials: AL
authors.lastname: Lapidus
authors.affiliation: N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky prospect 47, Moscow 119991, Russia. sharf@ioc.ac.ru and Chemistry Department, M.V. Lomonosov Moscow State University, Leninskie Gory 1, bldg. 3, Moscow 119992, Russia.
authors.forename: L M
authors.initials: LM
authors.lastname: Kustov