title: Thermal destruction of wastes containing polychlorinated naphthalenes in an industrial waste incinerator.
abstract: A series of verification tests were carried out in order to confirm that polychlorinated naphthalenes (PCNs) contained in synthetic rubber products (Neoprene FB products) and aerosol adhesives, which were accidentally imported into Japan, could be thermally destroyed using an industrial waste incinerator. In the verification tests, Neoprene FB products containing PCNs at a concentration of 2800 mg/kg were added to industrial wastes at a ratio of 600 mg Neoprene FB product/kg-waste, and then incinerated at an average temperature of 985 °C. Total PCN concentrations were 14 ng/m3N in stack gas, 5.7 ng/g in bottom ash, 0.98 ng/g in boiler dust, and 1.2 ng/g in fly ash. Destruction efficiency (DE) and destruction removal efficiency (DRE) of congener No. 38/40, which is considered an input marker congener, were 99.9974 and 99.9995 %, respectively. The following dioxin concentrations were found: 0.11 ng-TEQ/m3N for the stack gas, 0.096 ng-TEQ/g for the bottom ash, 0.010 ng-TEQ/g for the boiler dust, and 0.072 ng-TEQ/g for the fly ash. Since the PCN levels in the PCN destruction test were even at slightly lower concentrations than in the baseline test without PCN addition, the detected PCNs are to a large degree unintentionally produced PCNs and does not mainly stem from input material. Also, the dioxin levels did not change. From these results, we confirmed that PCNs contained in Neoprene FB products and aerosol adhesives could be destroyed to a high degree by high-temperature incineration. Therefore, all recalled Neoprene FB products and aerosol adhesives containing PCNs were successfully treated under the same conditions as the verification tests.
authors.affiliation: Center for Material Cycles and Waste Management Research, National Institute for Environmental Studies, 16-2 Onogawa, Tsukuba, Ibaraki, 305-8506, Japan. tyama@nies.go.jp.
authors.forename: Takashi
authors.initials: T
authors.lastname: Yamamoto
authors.affiliation: Center for Material Cycles and Waste Management Research, National Institute for Environmental Studies, 16-2 Onogawa, Tsukuba, Ibaraki, 305-8506, Japan.
authors.forename: Yukio
authors.initials: Y
authors.lastname: Noma
authors.affiliation: Environment Protection Center, Kyoto University, Yoshidahonmachi, Sakyo, Kyoto, 606-8501, Japan.
authors.forename: Shin-Ichi
authors.initials: SI
authors.lastname: Sakai
mesh_terms: D060729:Coal Ash / Q000737:chemistry; D006358:Hot Temperature; D006843:Hydrocarbons, Chlorinated / Q000737:chemistry*; D017745:Incineration; D007220:Industrial Waste / Q000032:analysis*; D007564:Japan; D009281:Naphthalenes / Q000737:chemistry*; D000072317:Polychlorinated Dibenzodioxins / Q000737:chemistry
chemical_list: D060729:Coal Ash; D006843:Hydrocarbons, Chlorinated; D007220:Industrial Waste; D009281:Naphthalenes; D000072317:Polychlorinated Dibenzodioxins
keywords: Aerosol adhesive; Destruction efficiency; High-temperature incineration; Input marker congener; Neoprene; Polychlorinated naphthalene; Synthetic rubber product