title: Synthesis of Dendrimers with a Bidentate Phosphine Core Ligand Having Carboxy Groups at the Peripheral Layer and Their Application to Aqueous Media Cross-Coupling Reactions.
abstract: We prepared a series of dendrimers with a bidentate phosphine core ligand having carboxy groups at the peripheral layer. By employing the corresponding water-soluble dendritic phosphine-palladium complex as a catalyst, the aqueous media Suzuki-Miyaura reaction and Tsuji-Trost reaction proceeded to provide the corresponding cross-coupling product.
authors.affiliation: National Institute of Advanced Industrial Science and Technology (AIST).
authors.forename: Ken-Ichi
authors.initials: K
authors.lastname: Fujita
authors.forename: Hatsuhiko
authors.initials: H
authors.lastname: Hattori
mesh_terms: D002384:Catalysis; D050091:Dendrimers / Q000138:chemical synthesis* / Q000737:chemistry; D008024:Ligands; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010165:Palladium / Q000737:chemistry; D010720:Phosphines / Q000737:chemistry*; D012995:Solubility; D014867:Water / Q000737:chemistry
chemical_list: D050091:Dendrimers; D008024:Ligands; D009942:Organometallic Compounds; D010720:Phosphines; D014867:Water; D010165:Palladium