title: Study on the Application of the (S)-2-tert-Butyl-2-methyl-1,3-benzodioxole-4-carboxylic acid-based On-line HPLC-Exciton CD Analysis to Acyclic 1,3-Diols.
abstract: The application of the on-line HPLC-exciton CD analysis with (S)-TBMB-carboxylic acid that simultaneously determined the enantiomeric composition and absolute configuration of vicinal diols, diamines and amino alcohols to 1,3-diols was studied. All optical isomers of di-O-(S)-TBMB-carbonyl-1,3-butanediols and 2,4-pentanediols were separated and their absolute configurations were determined without reference samples on line by HPLC.
authors.affiliation: a Department of Applied Biological Chemistry, Faculty of Agriculture, Tohoku University.
authors.forename: S
authors.initials: S
authors.lastname: Sato
authors.affiliation: a Department of Applied Biological Chemistry, Faculty of Agriculture, Tohoku University.
authors.forename: K
authors.initials: K
authors.lastname: Shimizu
authors.affiliation: a Department of Applied Biological Chemistry, Faculty of Agriculture, Tohoku University.
authors.forename: J H
authors.initials: JH
authors.lastname: Kim
authors.affiliation: a Department of Applied Biological Chemistry, Faculty of Agriculture, Tohoku University.
authors.forename: E
authors.initials: E
authors.lastname: Ami
authors.affiliation: a Department of Applied Biological Chemistry, Faculty of Agriculture, Tohoku University.
authors.forename: K
authors.initials: K
authors.lastname: Akasaka
authors.affiliation: a Department of Applied Biological Chemistry, Faculty of Agriculture, Tohoku University.
authors.forename: H
authors.initials: H
authors.lastname: Ohrui
keywords: (S)-TBMB-carboxylic acid; 1,3-diols; exciton CD monitoring; fluorometry; on-line HPLC-exciton CD analysis