title: Co-Catalyzed Hydroarylation of Unactivated Olefins.
abstract: A mild, general, scalable, and functional group tolerant intramolecular hydroarylation of unactivated olefins using a Co(salen) complex, a N-fluoropyridinium salt, and a disiloxane reagent was reported. This method, which was carried out at room temperature, afforded six-membered benzocyclic compounds from mono-, 1,1- or trans-1,2-di, and trisubstituted olefins.
authors.affiliation: Faculty of Pharmacy, Musashino University , 1-1-20, Shinmachi, Nishitokyo-shi, Tokyo 202-8585, Japan.
authors.forename: Hiroki
authors.initials: H
authors.lastname: Shigehisa
authors.affiliation: Faculty of Pharmacy, Musashino University , 1-1-20, Shinmachi, Nishitokyo-shi, Tokyo 202-8585, Japan.
authors.forename: Takuya
authors.initials: T
authors.lastname: Ano
authors.affiliation: Faculty of Pharmacy, Musashino University , 1-1-20, Shinmachi, Nishitokyo-shi, Tokyo 202-8585, Japan.
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Honma
authors.affiliation: Faculty of Pharmacy, Musashino University , 1-1-20, Shinmachi, Nishitokyo-shi, Tokyo 202-8585, Japan.
authors.forename: Kousuke
authors.initials: K
authors.lastname: Ebisawa
authors.affiliation: Faculty of Pharmacy, Musashino University , 1-1-20, Shinmachi, Nishitokyo-shi, Tokyo 202-8585, Japan.
authors.forename: Kou
authors.initials: K
authors.lastname: Hiroya