title: Preparation and characterization of hierarchical porous carbons derived from solid leather waste for supercapacitor applications.
abstract: Utilization of crust leather waste (CLW) as precursors for the preparation of hierarchical porous carbons (HPC) were investigated. HPCs were prepared from CLW by pre-carbonization followed by chemical activation using KOH at relatively high temperatures. Textural properties of HPC's showed an extent of micro-and mesoporosity with maximum BET surface area of 716m(2)/g. Inducements of graphitic planes in leather waste derived carbons were observed from X-ray diffraction and HR-TEM analysis. Microstructure, thermal behavior and surface functional groups were identified using FT-Raman, thermo gravimetric analysis and FT-IR techniques. HPCs were evaluated for electrochemical properties by cyclic voltammetry (CV), galvanostatic charge/discharge (GCD) and electrochemical impedance spectroscopy (EIS) by three electrode system. CLC9 sample showed a maximum capacitance of 1960F/g in 1M KCl electrolyte. Results achieved from rectangular curves of CV, GCD symmetric curves and Nyquist plots show that the leather waste carbon is suitable to fabricate supercapacitors as it possess high specific capacitance and electrochemical cycle stability. The present study proposes an effective method for solid waste management in leather industry by the way of converting toxic leather waste to new graphitic porous carbonaceous materials as a potential candidate for energy storage devices.
authors.affiliation: Materials Division, School of Advanced Sciences, Vellore Institute of Technology (VIT) University, Chennai Campus, Chennai 600 127, India.
authors.forename: Niketha
authors.initials: N
authors.lastname: Konikkara
authors.affiliation: Materials Division, School of Advanced Sciences, Vellore Institute of Technology (VIT) University, Chennai Campus, Chennai 600 127, India. Electronic address: jklsac14@yahoo.co.in.
authors.forename: L John
authors.initials: LJ
authors.lastname: Kennedy
authors.affiliation: Catalysis and Nanomaterials Research Laboratory, Department of Chemistry, Loyola College (Autonomous) Chennai 600 034, India.
authors.forename: J Judith
authors.initials: JJ
authors.lastname: Vijaya
keywords: Electrochemical behavior; Leather waste; Porous carbon; Supercapacitors