title: Enhanced electrochemical capacitance of polyimidazole coated covellite CuS dispersed CNT composite materials for application in supercapacitors.
abstract: Great attention has been paid to the design and synthesis of distinct core/shell heterostructures for high-performance supercapacitors. We have prepared unique heterostructures consisting of polyimidazole-coated copper sulphide over a carbon nanotube network (CuS@CNT) on nickel foam, which was accomplished through a facile and cost-effective solvothermal method combined with a dip coating process. Hexagonal covellite CuS nanoparticles were dispersed on CNTs using a solvothermal method where dimethylformamide and distilled water were used as solvents. The synthesized CuS and CuS@CNT supercapacitor electrode materials were thoroughly characterized. The polymer supported electrode (PIM/CuS@CNT) shows a high areal capacitance of 1.51 F cm(-2) at a current density of 1.2 A g(-1), which is higher than the CuS@CNT electrode and many other previously reported CuS electrode materials. After 1000 cycles at a high current density of 1.2 A g(-1), the retention rate is 92%, indicating good long-term cycling stability. These results indicate that the PIM/CuS@CNT electrode is promising for high-performance supercapacitor applications.
authors.affiliation: School of Electrical Engineering, Pusan National University, Gumjeong-Ku, Jangjeong-Dong, Busan 46241, South Korea. heeje@pusan.ac.kr.
authors.forename: Seenu
authors.initials: S
authors.lastname: Ravi
authors.affiliation: School of Electrical Engineering, Pusan National University, Gumjeong-Ku, Jangjeong-Dong, Busan 46241, South Korea. heeje@pusan.ac.kr.
authors.forename: Chandu V V M
authors.initials: CV
authors.lastname: Gopi
authors.affiliation: School of Electrical Engineering, Pusan National University, Gumjeong-Ku, Jangjeong-Dong, Busan 46241, South Korea. heeje@pusan.ac.kr.
authors.forename: Hee Je
authors.initials: HJ
authors.lastname: Kim