title: The Hiyama Cross-Coupling Reaction: New Discoveries.
abstract: In this account recent developments in the Hiyama cross-coupling reaction from 2010 up today are presented. The most important methodology involves formation of biaryl systems by using aryl bromides or iodides and aryl trialkoxy silanes: other variants are far less studied. The most useful procedures are collected paying special attention to the synthetic application of this methodology in synthetic organic chemistry.
authors.affiliation: University of Alicante, Alicante, Spain.
authors.forename: Francisco
authors.initials: F
authors.lastname: Foubelo
authors.affiliation: University of Alicante, Alicante, Spain.
authors.forename: Carmen
authors.initials: C
authors.lastname: Nájera
authors.affiliation: University of Alicante, Alicante, Spain.
authors.forename: Miguel
authors.initials: M
authors.lastname: Yus
keywords: Hiyama reaction; biaryls; cross-coupling; palladium catalysts; silicon compounds