title: Identification of two mechanisms for current production in a biharmonic flashing electron ratchet.
abstract: Ratchets rectify the motion of randomly moving particles, which are driven by isotropic sources of energy such as thermal and chemical energy, without applying a net, time-averaged force between source and drain. This paper describes the behavior of a damped electron, modeled by a quantum Lindblad master equation, within a flashing ratchet (a one-dimensional potential that oscillates between a flat surface and a periodic asymmetric surface). By examining the complete space of all biharmonic potential shapes and a large range of oscillation frequencies, two modes of ratchet operation, differentiated by their oscillation frequencies (relative to the rate of electron relaxation), are identified. Slow-oscillating, strong friction ratchets operate by a classical, overdamped mechanism. In fast-oscillating, weak friction ratchets, current is primarily produced when the frequency of the oscillating potential is resonant with the beating of the electron wave function in the potential well. The shape of the ratchet potential determines the direction of the current (and, in some cases, straightforwardly accounts for current reversals), but the maximum achievable current at any shape is controlled by the degree of friction applied to the electron.
authors.affiliation: Department of Chemistry, Northwestern University, 2145 Sheridan Rd., Evanston, Illinois 60208-3113, USA.|Center for Bio-Inspired Energy Science, Northwestern University, 303 E. Superior Street, 11th floor, Chicago, Illinois 60611-3015, USA.
authors.forename: Bryan
authors.initials: B
authors.lastname: Lau
authors.affiliation: Center for Bio-Inspired Energy Science, Northwestern University, 303 E. Superior Street, 11th floor, Chicago, Illinois 60611-3015, USA.
authors.forename: Ofer
authors.initials: O
authors.lastname: Kedem
authors.affiliation: Department of Chemistry, Northwestern University, 2145 Sheridan Rd., Evanston, Illinois 60208-3113, USA.|Center for Bio-Inspired Energy Science, Northwestern University, 303 E. Superior Street, 11th floor, Chicago, Illinois 60611-3015, USA.
authors.forename: Mark A
authors.initials: MA
authors.lastname: Ratner
authors.affiliation: Department of Chemistry, Northwestern University, 2145 Sheridan Rd., Evanston, Illinois 60208-3113, USA.|Center for Bio-Inspired Energy Science, Northwestern University, 303 E. Superior Street, 11th floor, Chicago, Illinois 60611-3015, USA.
authors.forename: Emily A
authors.initials: EA
authors.lastname: Weiss