title: A concept for the removal of microplastics from the marine environment with innovative host-guest relationships.
abstract: Environmental pollution caused by inert anthropogenic stressors such as microplastics in aquatic media is constantly increasing. Through the proliferating use of plastic products in daily life, more and more plastic particles enter waters as primary microplastics. Even though large scale plastic items such as plastic bottles and bags represent the highest percentage of plastic waste, their degeneration also generates microparticles and nanoparticles (secondary microplastics). Modern sewage treatment plants require innovative ideas in order to deal with this man-made problem. State-of-the-art technology offers approaches to minimise the amount of microplastics in aquatic systems. These technologies, however, are either insufficient or very costly, as well as time-consuming in both cases. The conceptual idea presented here is to apply innovative inorganic-organic hybrid silica gels which provide a cost-effective and straightforward approach. Currently, the synthesis of preorganised bioinspired compounds is advancing in order to produce functionalised hybrid silica gels in a further step. These gels have the ability to remove stressors such as microplastics from waste water. By means of the sol-gel process, bioinspired silane compounds are currently being permuted to macromolecules and examined with respect to their properties as fixation and filter material in order to remove the hydrophobic anthropogenic stressors sustainably. Here, the reproduction of biological systems plays a significant role. In particular in material sciences, this approach is becoming increasingly important. Among other concepts, new biomimetic molecules form the basis for the investigation of innovative host-guest relationships for anthropogenic stressors in the environment and their implementation in technical processes.
authors.affiliation: Institute for Environmental Sciences Landau, University of Koblenz - Landau, Fortstr 7, 76829, Landau in der Pfalz, Germany.
authors.forename: Adrian Frank
authors.initials: AF
authors.lastname: Herbort
authors.affiliation: Institute for Environmental Sciences Landau, University of Koblenz - Landau, Fortstr 7, 76829, Landau in der Pfalz, Germany. schuhen@uni-landau.de.
authors.forename: Katrin
authors.initials: K
authors.lastname: Schuhen
mesh_terms: D040761:Biomimetic Materials; D004784:Environmental Monitoring; D004787:Environmental Pollution; D010969:Plastics / Q000302:isolation & purification*; D012623:Seawater; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*
chemical_list: D010969:Plastics; D014874:Water Pollutants, Chemical
keywords: Green chemistry; Hybrid silica gel; Microbeads; Microplastics; Self-organised organosilanes; Sol-gel process; Sustainable development; Water pollution