title: Fluorimetric detection of Sn(2+) ion in aqueous medium using Salicylaldehyde based nanoparticles and application to natural samples analysis.
abstract: The fluorescent 2-[(E)-(2-phenylhydrazinylidene)methyl]phenol nanoparticles (PHPNPs) were prepared by a simple reprecipitation method. The prepared PHPNPs examined by Dynamic Light Scattering show narrower particle size distribution having an average particle size of 93.3nm. The Scanning Electron Microphotograph shows distinct spherical shaped morphology of nanoparticles. The blue shift in UV-absorption and fluorescence spectra of PHPNPs with respect to corresponding spectra of PHP in acetone solution indicates H- aggregates and Aggregation Induced Enhanced Emission (AIEE) for nanoparticles. The nanoparticles show selective tendency towards the recognition of Sn(2+) ions by enhancing the fluorescence intensity preference to Cu(2+), Fe(3+), Fe(2+), Ni(2+), NH4(+), Ca(2+), Pb(2+), Hg(2+) and Zn(2+) ions, which actually seem to quench the fluorescence of nanoparticles. The studies on Langmuir adsorption plot, fluorescence lifetime of PHPNPs, DLS-Zeta sizer, UV-visible and fluorescence titration with and without Sn(2+) helped to propose a suitable mechanism of fluorescence enhancement of nanoparticles by Sn(2+) and their binding ability during complexation. The fluorescence enhancement effect of PHPNPs induced by Sn(2+) is further used to develop an analytical method for detection of Sn(2+) from aqueous medium in environmental samples.
authors.affiliation: Dr. Babasaheb Ambedkar Technological University, Lonere, Dist: Raigad, Maharashtra, India.
authors.forename: Kishor S
authors.initials: KS
authors.lastname: Patil
authors.affiliation: Fluorescence Spectroscopy Research Laboratory, Department of Chemistry, Shivaji University, Kolhapur- 416004, Maharashtra, India.
authors.forename: Prasad G
authors.initials: PG
authors.lastname: Mahajan
authors.affiliation: Fluorescence Spectroscopy Research Laboratory, Department of Chemistry, Shivaji University, Kolhapur- 416004, Maharashtra, India. Electronic address: srp_fsl@rediffmail.com.
authors.forename: Shivajirao R
authors.initials: SR
authors.lastname: Patil
keywords: 2-[(E)-(2-phenylhydrazinylidene)methyl]phenol nanoparticles (PHPNPs); Excited state complex; Fluorescence enhancement; Schiff base; Sn(2+) detection