title: Sorption properties of an amorphous hydroxo titanate towards Pb(2+), Ni(2+), and Cu(2+) ions in aqueous solution.
abstract: Titanates may be selectively used as inorganic adsorbents for heavy metal ions owing to their stability and fast adsorption kinetics. Nevertheless, the synthesis of such materials usually requires extreme reaction conditions. In this work, a new titanium-based material was rapidly synthesized under mild laboratory conditions. The obtained amorphous hydroxo titanate was tested for heavy metal sorption through kinetic and equilibrium batch tests, which indicated that the new material had high adsorption rates and adsorption capacities towards Cu(2+), Ni(2+) and Pb(2) ions. Adsorption kinetics were pseudo-second order, and equilibrium data fitted the Langmuir isotherm model. The calculated maximum adsorption capacities of Cu(2+), Ni(2+) and Pb(2+) in deionized water were around 1 mmol g(-1), and they decreased for Cu(2+) and Ni(2+) in the presence of Na(+), Ca(2+) and Mg(2+) ions, whereas the alkali metal ions did not influence Pb(2+) uptake. The efficiency of adsorption and recovery of lead ions were evaluated through column dynamic tests, by feeding the column with groundwater and tap water spiked with Pb(2+). The high performance of the hydroxo titanate over several cycles of retention and elution suggested that the product is potentially useful for the solid phase extraction of lead at trace levels in natural water samples, with potential use in metal pre-concentration for analytical applications.
authors.affiliation: a National Research Council , Water Research Institute (CNR IRSA) , Bari , Italy.
authors.forename: Angela
authors.initials: A
authors.lastname: Volpe
authors.affiliation: a National Research Council , Water Research Institute (CNR IRSA) , Bari , Italy.
authors.forename: Michele
authors.initials: M
authors.lastname: Pagano
authors.affiliation: a National Research Council , Water Research Institute (CNR IRSA) , Bari , Italy.
authors.forename: Carlo
authors.initials: C
authors.lastname: Pastore
authors.affiliation: b National Research Council , Institute of Crystallography (CNR IC) , Bari , Italy.
authors.forename: Corrado
authors.initials: C
authors.lastname: Cuocci
authors.affiliation: c Department of Chemistry , University of Bari Aldo Moro , Bari , Italy.
authors.forename: Antonella
authors.initials: A
authors.lastname: Milella
mesh_terms: D000327:Adsorption; D003300:Copper / Q000737:chemistry / Q000302:isolation & purification*; D006863:Hydrogen-Ion Concentration; D007477:Ions / Q000737:chemistry / Q000302:isolation & purification; D007854:Lead / Q000737:chemistry / Q000302:isolation & purification*; D008962:Models, Theoretical; D009532:Nickel / Q000737:chemistry / Q000302:isolation & purification*; D010087:Oxides; D014025:Titanium / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000302:isolation & purification; D018508:Water Purification
chemical_list: D007477:Ions; D010087:Oxides; D014874:Water Pollutants, Chemical; C525208:peroxo-titanate; D007854:Lead; D003300:Copper; D009532:Nickel; D014025:Titanium
keywords: heavy metals; hydroxo titanate; peroxymonosulfate; preconcentration; sorption