title: Evidence of double layer/capacitive charging in carbon nanomaterial-based solid contact polymeric ion-selective electrodes.
abstract: This paper presents the first direct spectroscopic evidence for double layer or capacitive charging of carbon nanomaterial-based solid contacts in all-solid-state polymeric ion-selective electrodes (ISEs). Here, we used synchrotron radiation-X-ray photoelectron spectroscopy (SR-XPS) and SR valence band (VB) spectroscopy in the elucidation of the charging mechanism of the SCs.
authors.affiliation: Department of Inorganic and Analytical Chemistry, University of Geneva, Quai Ernest-Ansermet 30, CH-1211 Geneva, Switzerland. gaston.crespo@unige.ch.
authors.forename: Maria
authors.initials: M
authors.lastname: Cuartero
authors.forename: Josiah
authors.initials: J
authors.lastname: Bishop
authors.forename: Raymart
authors.initials: R
authors.lastname: Walker
authors.forename: Robert G
authors.initials: RG
authors.lastname: Acres
authors.forename: Eric
authors.initials: E
authors.lastname: Bakker
authors.forename: Roland
authors.initials: R
authors.lastname: De Marco
authors.forename: Gaston A
authors.initials: GA
authors.lastname: Crespo