title: Transient Cataluminescence on Flowerlike MgO for Discrimination and Detection of Volatile Organic Compounds.
abstract: Methodologies for simple and rapid identification of gas compounds are needed in the fields of environmental and security. Here, a new and simple method for the discrimination of gas compounds was designed through an interesting transient cataluminescence (TRCTL) phenomenon on the highly efficient MgO materials. The flowerlike MgO with high CTL activity was controllably synthesized via a facile and time-saving aqueous precipitation route and characterized by scanning electron microscopy, powder X-ray diffractometry, high-resolution transmission electron microscopy, and N2 adsorption measurements, etc. With flowerlike MgO working as the sensing material, the newly developed CTL gas sensor exhibited highly active, ultrafast, and characteristic responses toward many analytes; the TRCTL curves thus were obtained and 10 VOCs have been successfully identified. Parallel experimental results show that the controllable synthesis of flowerlike MgO can greatly enhance the discrimination capacities for VOCs. Further, the TRCTL of CHCl3 and C2H5OC2H5 were taken as typical examples to illustrate the possible sensing mechanism, which could contribute to explaining processes of catalytic oxidations. We expect this novel TRCTL concept will be of practical importance for applications including gas detection, gas discrimination, and research of chemical kinetics processes.
authors.affiliation: Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University , Chengdu, Sichuan 610064, China.
authors.forename: Honglin
authors.initials: H
authors.lastname: Xu
authors.affiliation: Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University , Chengdu, Sichuan 610064, China.
authors.forename: Qiuyan
authors.initials: Q
authors.lastname: Li
authors.affiliation: Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University , Chengdu, Sichuan 610064, China.
authors.forename: Lichun
authors.initials: L
authors.lastname: Zhang
authors.affiliation: Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University , Chengdu, Sichuan 610064, China.
authors.forename: Binrong
authors.initials: B
authors.lastname: Zeng
authors.affiliation: Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University , Chengdu, Sichuan 610064, China.
authors.forename: Dongyan
authors.initials: D
authors.lastname: Deng
authors.affiliation: Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University , Chengdu, Sichuan 610064, China.
authors.forename: Yi
authors.initials: Y
authors.lastname: Lv