title: [Study on the Preparation of Ba3Si6O9N4 : Eu(2+) Phosphor and the Characterization of Their Luminescence Properties].
abstract: Ba3Si6O9N4 : Eu(2+) phosphors were synthesized by two-step synthesis processes based on high temperature solid phase using BaSiO3 as a precursor. The influence mechanism of the Eu(2+) doping concentration to the luminescence properties of Ba3Si6O9N4 : Eu(2+) phosphors were mainly investigated. This paper made a comparison between the luminescence properties of Ba3Si6ON4 : Eu(2+) phosphors prepared by two-step processes and solid- state reaction method. The results showed that the Ba3Si6O9N4 : Eu(3+) phosphors synthesized by two-step processes had higher purity and higher crystallinity. There exists concentration quenching in Ba3Si6O9N4 : Eu(2+) phosphors for both two-step processes and solid-state reaction when the doping concentration x is more than 9%. Both the concentration quenching mechanism of Ba3 Si 09 N4 : EuI+ phosphor prepared by solid-state reaction and two-step processes is electric dipole-dipole interaction. The emission peak of Ba3Si6O9N4 : Eu(2+) phosphors (peak 489 nm) prepared by two-step processes had a blue shift compared to the emission peak of Ba3Si6O9N4 : Eu2+ phosphors (peak 512nm) prepared by solid-state reaction. The emission peak of Ba3Si6O9N4 : Eu2+ phosphors prepared by two-step processes relatively close to the theoretical value (480 nm). The spectrum analysis result showed that the element component of Ba3Si6O3N4 : Eu2+ phosphors prepared by two-step processes was closer to the theoretical value, it means that the two-step processes can effectively reduce the lattice defects. The Ba3Si6O9N4 : Eu(2+) phosphors synthesized by two-step processes had better thermal stability, which demonstrates to be a highly promising phosphor for white-LED applications.
authors.forename: Hua-yan
authors.initials: HY
authors.lastname: Pan
authors.forename: Le
authors.initials: L
authors.lastname: Wang
authors.forename: Dong
authors.initials: D
authors.lastname: Luo
authors.forename: Yang-hui
authors.initials: YH
authors.lastname: Li
authors.forename: Hong
authors.initials: H
authors.lastname: Zhang
authors.forename: Ye
authors.initials: Y
authors.lastname: Shen