title: A closer look on the coordination of soft nitrogen-donor ligands to Cm(iii): SO3-Ph-BTBP.
abstract: We present a combined theoretical and experimental study on the recently developed hydrophilic SO3-Ph-BTBP ligand. Vibronic side band spectroscopy and time-resolved laser fluorescence spectroscopy (TRLFS) were employed to prove the theoretical prediction of the ligand's coordination mode.
authors.affiliation: Institut für Nukleare Entsorgung (INE), Karlsruher Institut für Technologie, D-76131 Karlsruhe, Germany. Michael.Trumm@kit.edu.
authors.forename: M
authors.initials: M
authors.lastname: Trumm
authors.affiliation: Institut für Nukleare Entsorgung (INE), Karlsruher Institut für Technologie, D-76131 Karlsruhe, Germany. Michael.Trumm@kit.edu and Ruprecht Karls Universität Heidelberg, Physikalisch-Chemisches Institut, Im Neuenheimer Feld 253, D-69120 Heidelberg, Germany. Christoph.Wagner@kit.edu.
authors.forename: C
authors.initials: C
authors.lastname: Wagner
authors.affiliation: Institut für Nukleare Entsorgung (INE), Karlsruher Institut für Technologie, D-76131 Karlsruhe, Germany. Michael.Trumm@kit.edu.
authors.forename: B
authors.initials: B
authors.lastname: Schimmelpfennig
authors.affiliation: Institut für Nukleare Entsorgung (INE), Karlsruher Institut für Technologie, D-76131 Karlsruhe, Germany. Michael.Trumm@kit.edu.
authors.forename: A
authors.initials: A
authors.lastname: Geist
authors.affiliation: Institut für Nukleare Entsorgung (INE), Karlsruher Institut für Technologie, D-76131 Karlsruhe, Germany. Michael.Trumm@kit.edu and Ruprecht Karls Universität Heidelberg, Physikalisch-Chemisches Institut, Im Neuenheimer Feld 253, D-69120 Heidelberg, Germany. Christoph.Wagner@kit.edu.
authors.forename: P J
authors.initials: PJ
authors.lastname: Panak