title: A Highly Stable Nonhysteretic {Cu2(tebpz) MOF+water} Molecular Spring.
abstract: A molecular spring formed by a hydrophobic metal-organic framework Cu2(tebpz) (tebpz=3,3',5,5'-tetraethyl-4,4'-bipyrazolate) and water is presented. This nanoporous heterogeneous lyophobic system (HLS) has exceptional properties compared to numerous reported systems of such type in terms of stability, efficiency, and operating pressure. Mechanical and thermal energetic characteristics as well as stability of the system are discussed and compared in detail with those of other previously reported HLS.
authors.affiliation: Institut de Chimie de Clermont-Ferrand, Universite Clermont Auvergne, SIGMA Clermont, BP 10448, 63000, Clermont-Ferrand, France.|UMR 6296, CNRS, 63177, Aubiere, France.|Laboratory of Thermomolecular Energetics, National Technical, University of Ukraine "Kyiv Polytechnic Institute", Pr. Peremogy 37, 03056, Kyiv, Ukraine.|CIC Energigune, Albert Einstein 48, 01510, Miñano, Álava, Spain.
authors.forename: Yaroslav
authors.initials: Y
authors.lastname: Grosu
authors.affiliation: Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Guangdong, 515063, China.
authors.forename: Mian
authors.initials: M
authors.lastname: Li
authors.affiliation: Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Guangdong, 515063, China.
authors.forename: Yun-Lei
authors.initials: YL
authors.lastname: Peng
authors.affiliation: Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Guangdong, 515063, China.
authors.forename: Dong
authors.initials: D
authors.lastname: Luo
authors.affiliation: Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Guangdong, 515063, China.
authors.forename: Dan
authors.initials: D
authors.lastname: Li
authors.affiliation: CIC Energigune, Albert Einstein 48, 01510, Miñano, Álava, Spain.
authors.forename: Abdessamad
authors.initials: A
authors.lastname: Faik
authors.affiliation: Institut de Chimie de Clermont-Ferrand, Universite Clermont Auvergne, SIGMA Clermont, BP 10448, 63000, Clermont-Ferrand, France.|UMR 6296, CNRS, 63177, Aubiere, France.
authors.forename: Jean-Marie
authors.initials: JM
authors.lastname: Nedelec
authors.affiliation: Institut de Chimie de Clermont-Ferrand, Universite Clermont Auvergne, SIGMA Clermont, BP 10448, 63000, Clermont-Ferrand, France.|UMR 6296, CNRS, 63177, Aubiere, France.
authors.forename: Jean-Pierre
authors.initials: JP
authors.lastname: Grolier
keywords: energy conversion; heterogeneous lyophobic systems; interfaces; metal-organic frameworks; molecular devices