title: Facile synthesis of one-dimensional organometallic-organic hybrid polymers based on a diphosphorus complex and flexible bipyridyl linkers.
abstract: The selective synthesis of a series of new "ladderlike" one-dimensional organometallic-organic hybrid polymers is shown. The polymers are obtained from the reaction of the diphosphorus ligand complex [Cp2Mo2(CO)4(η(2)-P2)] with the copper salt [Cu(CH3CN)4]BF4 in the presence of flexible organic bipyridyl linkers in high selectivity. This unique behaviour is supported by DFT calculations.
authors.affiliation: Institute für Anorganische Chemie der Universitöt Regensburg, 93040 Regensburg, Germany. manfred.scheer@chemie.uni-r.de.
authors.forename: M
authors.initials: M
authors.lastname: Elsayed Moussa
authors.forename: B
authors.initials: B
authors.lastname: Attenberger
authors.forename: E V
authors.initials: EV
authors.lastname: Peresypkina
authors.forename: M
authors.initials: M
authors.lastname: Fleischmann
authors.forename: G
authors.initials: G
authors.lastname: Balázs
authors.forename: M
authors.initials: M
authors.lastname: Scheer