title: Synthesis and characterization of pristine closo-[Ge10](2.).
abstract: The first [Ge10](2-) Zintl anion, which is neither filled nor connected to another metal atom is presented in terms of X-ray structure, Raman-spectrum and ESI-MS. Pure [Ge10](2-), adapting a D4d symmetric closo-structure, were crystallized from a Rb4Ge9/ethylendiamine solution, containing 7-amino-1-trimethylsilyl-5-aza-hepta-3-en-1-yne. The role of the latter on the formation of [Rb(222-crypt)]2[Ge10](en)1.5 is discussed.
authors.affiliation: Technische Universität München, Department Chemie, Lichtenbergstrasse 4, 85747 Garching, Germany. Thomas.faessler@lrz.tum.de.
authors.forename: Manuel M
authors.initials: MM
authors.lastname: Bentlohner
authors.affiliation: Technische Universität München, Department Chemie, Lichtenbergstrasse 4, 85747 Garching, Germany. Thomas.faessler@lrz.tum.de.
authors.forename: Christina
authors.initials: C
authors.lastname: Fischer
authors.affiliation: Technische Universität München, Department Chemie, Lichtenbergstrasse 4, 85747 Garching, Germany. Thomas.faessler@lrz.tum.de.
authors.forename: Thomas F
authors.initials: TF
authors.lastname: Fässler