title: 1,2-Disubstituted Alkenes as Migratory Insertion Participants in Zn(II)-Promoted Metalloamination/Cyclization of N,N-Dimethylhydrazinoalkenes.
abstract: Diethylzinc-mediated metalloamination/cyclization of unsaturated N,N-dimethylhydrazines has been extended to the use of 1,2-disubstituted alkenes as N-Zn migratory insertion acceptors. Representative 2-arylethenes and vinylcyclopropanes readily serve as reaction participants in metalloamination/cyclization-allylation cascades.
authors.affiliation: Department of Chemistry and Biochemistry, Montana State University , Bozeman, Montana 59717, United States.
authors.forename: Bryce
authors.initials: B
authors.lastname: Sunsdahl
authors.affiliation: Department of Chemistry and Biochemistry, Montana State University , Bozeman, Montana 59717, United States.
authors.forename: Ky
authors.initials: K
authors.lastname: Mickelsen
authors.affiliation: Department of Chemistry and Biochemistry, Montana State University , Bozeman, Montana 59717, United States.
authors.forename: Sean
authors.initials: S
authors.lastname: Zabawa
authors.affiliation: Department of Chemistry and Biochemistry, Montana State University , Bozeman, Montana 59717, United States.
authors.forename: Bryon K
authors.initials: BK
authors.lastname: Anderson
authors.affiliation: Department of Chemistry and Biochemistry, Montana State University , Bozeman, Montana 59717, United States.
authors.forename: Tom
authors.initials: T
authors.lastname: Livinghouse