title: Aminotroponiminates as tunable, redox-active ligands: reversible single electron transfer and reductive dimerisation.
abstract: Aminotroponiminates (atis) are shown to be redox-active ligands. Under strongly reducing conditions, the result of electron transfer can be controlled by the choice of the metal bound to the ati ligand. Either reversible electron transfer or a reductively induced dimerisation is observed. The latter reaction is (regio- and diastereo-) selective and chemically reversible.
authors.affiliation: Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany. crispin.lichtenberg@uni-wuerzburg.de.
authors.forename: C
authors.initials: C
authors.lastname: Lichtenberg
authors.forename: I
authors.initials: I
authors.lastname: Krummenacher