title: Transition-Metal-Catalyzed Electrophilic Amination: Application of O-Benzoylhydroxylamines in the Construction of the C-N Bond.
abstract: Transition-metal-catalyzed electrophilic amination has been developed into a powerful tool for C-N bond construction. So far, O-benzoylhydroxylamines are the most widely used electrophilic aminating reagents. Herein, we summarize the recent advances of O-benzoylhydroxylamines involved in electrophilic amination catalyzed by transition metals. Several pioneering studies and some of the relevant mechanisms are discussed in this review.
authors.affiliation: School of Chemical Engineering, Shandong University of Technology, 266 West Xincun Road, Zibo, 255049, P. R. China.
authors.forename: Xu
authors.initials: X
authors.lastname: Dong
authors.affiliation: School of Chemical Engineering, Shandong University of Technology, 266 West Xincun Road, Zibo, 255049, P. R. China.
authors.forename: Qing
authors.initials: Q
authors.lastname: Liu
authors.affiliation: School of Chemical Engineering, Shandong University of Technology, 266 West Xincun Road, Zibo, 255049, P. R. China.|Engineering Research Center of Textile Chemicals, Dyeing and Finishing of Shandong University of Technology, Zibo, 255049, P. R. China.
authors.forename: Yunhui
authors.initials: Y
authors.lastname: Dong
authors.affiliation: School of Chemical Engineering, Shandong University of Technology, 266 West Xincun Road, Zibo, 255049, P. R. China.|College of Materials Science and Engineering, Hunan University, Changsha, Hunan, 410082, China.|Engineering Research Center of Textile Chemicals, Dyeing and Finishing of Shandong University of Technology, Zibo, 255049, P. R. China.
authors.forename: Hui
authors.identifier: http://orcid.org/0000-0001-8916-6055
authors.initials: H
authors.lastname: Liu
keywords: O-benzoylhydroxylamines; cross-coupling; electrophilic amination; tertiary amines; transition-metal catalysis