title: Ferromagnetic coupling mediated by Coπ non-covalent contacts in a pentacoordinate Co(ii) compound showing field-induced slow relaxation of magnetization.
abstract: [Co(II)(dpt)(NCS)2], where dpt = bis(3-aminopropyl)amine, was identified as a pentacoordinate Co(II) compound showing field-induced slow relaxation of magnetization. Furthermore, intermolecular ferromagnetic coupling mediated by Coπ non-covalent contacts, where π orbitals originate from the thiocyanato ligand, is reported for the first time.
authors.affiliation: Regional Centre of Advanced Technologies and Materials, Department of Inorganic Chemistry, Faculty of Science, Palacký University, 17. listopadu 12, CZ-771 46 Olomouc, Czech Republic. zdenek.travnicek@upol.cz.
authors.forename: I
authors.initials: I
authors.lastname: Nemec
authors.affiliation: Regional Centre of Advanced Technologies and Materials, Department of Inorganic Chemistry, Faculty of Science, Palacký University, 17. listopadu 12, CZ-771 46 Olomouc, Czech Republic. zdenek.travnicek@upol.cz.
authors.forename: R
authors.initials: R
authors.lastname: Herchel
authors.affiliation: Regional Centre of Advanced Technologies and Materials, Department of Inorganic Chemistry, Faculty of Science, Palacký University, 17. listopadu 12, CZ-771 46 Olomouc, Czech Republic. zdenek.travnicek@upol.cz.
authors.forename: Z
authors.initials: Z
authors.lastname: Trávníček