title: Azide Tripodal Dendrons from Behera's Amine and Their Clicked Dendrimers.
abstract: Diazo transfer reactions on Behera's amine and its next-generation analogue formed G0 and G1 azide dendrons bearing three and nine tert-butyl-protected esters, respectively. The utility of the new dendrons was demonstrated by copper-catalyzed azide-alkyne cycloaddition, with 1,3,5-triethynylbenzene, forming two novel dendrimers in a convergent manner. Acid-mediated dendrimer deprotection was successful, and the resulting carboxy-terminated dendrimers were analyzed by NMR and DOSY experiments.
authors.affiliation: Department of Chemistry and Biochemistry, San Diego State University , 5500 Campanile Drive, San Diego, California 92182-1030, United States.
authors.forename: Farhana
authors.initials: F
authors.lastname: Barmare
authors.affiliation: Department of Chemistry and Biochemistry, San Diego State University , 5500 Campanile Drive, San Diego, California 92182-1030, United States.
authors.forename: Marie-Caline Z
authors.initials: MC
authors.lastname: Abadjian
authors.affiliation: University of Pittsburgh Hillman Cancer Institute , 5117 Centre Avenue, Pittsburgh, Pennsylvania 15213, United States.
authors.forename: Erik C
authors.initials: EC
authors.lastname: Wiener
authors.affiliation: Department of Chemistry and Biochemistry, San Diego State University , 5500 Campanile Drive, San Diego, California 92182-1030, United States.
authors.forename: Douglas B
authors.initials: DB
authors.lastname: Grotjahn
mesh_terms: D000480:Alkynes / Q000737:chemistry; D000588:Amines / Q000737:chemistry*; D001386:Azides / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry; D050091:Dendrimers / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D011108:Polymers / Q000737:chemistry; D012997:Solvents / Q000737:chemistry
chemical_list: D000480:Alkynes; D000588:Amines; D001386:Azides; D050091:Dendrimers; D011108:Polymers; D012997:Solvents; D003300:Copper