title: Effect of industrial dust on precipitation chemistry in the Czech Republic (Central Europe) from 1850 to 2013.
abstract: Using statistical relationships between the composition of precipitation at eight long-term monitoring stations and emission rates of sulphur (S) and nitrogen (N) compounds, as well as industrial dust in the Czech Republic and Slovakia (Central Europe), we modelled historic pH and concentrations of sulphate (SO4(2-)), nitrate (NO3(-)), ammonium (NH4(+)), chloride (Cl(-)), base cations (BC), and bicarbonate (HCO3(-)) in bulk precipitation from 1850 to 2013. Our model suggests that concentrations of SO4(2-), NO3(-), and HCO3(-) were similar (11-16 μeq l(-1)) in 1850. Cations were dominated by NH4(+) and BC (24-27 μeq l(-1)) and precipitation pH was >5.6. The carbonate buffering system was depleted around 1920 and precipitation further acidified at an exponential rate until the 1980s, when concentrations of SO4(2-), NO3(-), Cl(-), NH4(+) and BC reached maxima of 126, 55, 16, 76, and 57 μeq l(-1), respectively, and pH decreased to 4.2. Dust emissions from industrial sources were an important source of BC. Without their contribution, pH would have decreased to 4.0 in the 1980s, and the carbonate buffering system would have been depleted already in the 1870s. Since the late 1980s, concentrations of strong acid anions and BC have decreased by 46-81% (i.e. more than in Europe on average) due to a 53-93% reduction in regional emissions of S and N compounds and dust from industrial and agricultural sources. The present composition of precipitation is similar to the late 19th century, except for NO3(-) concentrations, which are similar to those during 1926-1950. Precipitation pH now exceeds 5.0, the carbonate buffering system has been re-established, and HCO3(-) has again become (after almost a century) a significant component of precipitation chemistry.
authors.affiliation: Biology Centre CAS, Institute of Hydrobiology, Na Sádkách 7, 37005 České Budějovice, Czech Republic; Faculty of Science, University of South Bohemia, Branišovská 1760, 37005 České Budějovice, Czech Republic. Electronic address: jkopacek@hbu.cas.cz.
authors.forename: Jiří
authors.initials: J
authors.lastname: Kopáček
authors.affiliation: Biology Centre CAS, Institute of Hydrobiology, Na Sádkách 7, 37005 České Budějovice, Czech Republic.
authors.forename: Josef
authors.initials: J
authors.lastname: Hejzlar
authors.affiliation: Czech Geological Survey, Klárov 3, 11821 Prague 1, Czech Republic.
authors.forename: Pavel
authors.initials: P
authors.lastname: Krám
authors.affiliation: Czech Geological Survey, Klárov 3, 11821 Prague 1, Czech Republic.
authors.forename: Filip
authors.initials: F
authors.lastname: Oulehle
authors.affiliation: Coordination Centre for Effects, RIVM, P.O. Box 1, NL-3720 BA Bilthoven, The Netherlands.
authors.forename: Maximilian
authors.initials: M
authors.lastname: Posch
mesh_terms: D018153:Czech Republic; D004391:Dust; D004784:Environmental Monitoring; D007221:Industry; D012621:Seasons
chemical_list: D004391:Dust
keywords: Ammonium; Base cations; Chloride; Czech Republic; Nitrate; Sulphate; pH