title: Decolorization of Methylene Blue by Persulfate Activated with FeO Magnetic Particles.
abstract: In this study, the degradation of methylene blue (MB) was conducted to evaluate the feasibility of using persulfate oxidation activated with iron oxide (FeO) magnetic particles. The results demonstrated that the decolorization rate of MB increased with increasing FeO concentration, exhibiting maximum efficiency at pH0 3.0. The kinetics of MB was studied in the binary FeO catalyst and persulfate oxidation system. The surface properties of FeO before and after reaction was analyzed using cyclic voltammogram (CV), three-dimensional excitation-emission fluorescence matrix (EEFM) spectroscopy, zeta potential, particle size distribution measurements, X-ray diffraction (XRD) and environmental scanning electron microscopy-energy dispersive X-ray spectrometry (ESEM-EDS). The CV data indicated that a reversible redox reaction holds the key to explaining the significant activity of the catalyst. EEFM was used to evaluate the catalyst yield of FeO by fluorescence intensity plots with excitation/emission at 220/300 nm and 260/300 nm. The XRD and ESEM-EDS results confirmed the presence of FeO in the catalyst.
authors.affiliation: Department of Marine Environmental Engineering, National Kaohsiung Marine University, 142 Haijhuan Road, Nanzih District, Kaohsiung City 81157, Taiwan.
authors.forename: Chang-Mao
authors.initials: CM
authors.lastname: Hung
authors.forename: Chiu-Wen
authors.initials: CW
authors.lastname: Chen
authors.forename: Yi-Yuan
authors.initials: YY
authors.lastname: Liu
authors.forename: Cheng-Di
authors.initials: CD
authors.lastname: Dong
mesh_terms: D002384:Catalysis; D003116:Color; D005290:Ferric Compounds / Q000737:chemistry; D008280:Magnetics; D008751:Methylene Blue / Q000737:chemistry*; D017670:Sodium Compounds / Q000737:chemistry*; D013052:Spectrometry, X-Ray Emission; D013431:Sulfates / Q000737:chemistry*; D013499:Surface Properties; D014961:X-Ray Diffraction
chemical_list: D005290:Ferric Compounds; D017670:Sodium Compounds; D013431:Sulfates; C000499:ferric oxide; C024625:sodium persulfate; D008751:Methylene Blue