title: Thermo Sensitivity of Polysiloxane/Silica Nanocomposites Affected by the Structure of Polymer-Filler Interface.
abstract: In this work thermo sensitivity was investigated with the bound rubber theory and thermoelasticity theory of the polymer-filler interface interaction between Polymethylvinylsiloxane (PMVS) and nanofillers (fumed and precipitated silica with the primary particle size of 10 nanometres). Bound rubber (the transition phase between PMVS and silica) content was measured by sol-gel analysis and swelling experiments. Results showed that the amount of bound rubber increases steadily with the increases of filler content. But the increasing rate suddenly decreased at certain silica content (between 40 and 50 phr of precipitated silica and between 30 and 40 phr of fumed silica, respectively), which was constant with the thermoelaticity experiment results. The temperature coefficients in low strain uniaxial extension are found to present sudden changing at the same silica content. This observation shows that thermo sensitivity is closely connected with the structure of polymer-filler interface.
authors.forename: Qian
authors.initials: Q
authors.lastname: Zhang
authors.forename: Yufeng
authors.initials: Y
authors.lastname: Zhou
authors.forename: Fengmei
authors.initials: F
authors.lastname: Yu
authors.forename: Lixian
authors.initials: L
authors.lastname: Song
authors.forename: Sumin
authors.initials: S
authors.lastname: Sun
authors.forename: Zhongyuan
authors.initials: Z
authors.lastname: Lu
authors.forename: Ai
authors.initials: A
authors.lastname: Lu
mesh_terms: D018625:Microscopy, Atomic Force; D015394:Molecular Structure; D053761:Nanocomposites; D011108:Polymers / Q000737:chemistry*; D011145:Polyvinyls / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry*; D012833:Siloxanes / Q000737:chemistry*
chemical_list: D011108:Polymers; D011145:Polyvinyls; D012833:Siloxanes; C014766:polymethylvinylsiloxane; D012822:Silicon Dioxide