title: Simultaneous determination of arsenic and mercury species in rice by ion-pairing reversed phase chromatography with inductively coupled plasma mass spectrometry.
abstract: An analytical method using reversed phase chromatography-inductively coupled plasma mass spectrometry for arsenic and mercury speciation analysis was described. The effect of ion-pairing reagent on simultaneous separation of four arsenic (arsenite, arsenate, monomethlyarsonate and dimethylarsinate) and three mercury species (inorganic mercury (Hg(II)), methylmecury and ethylmercury) was investigated. Parameters including concentrations and pH of the mobile phase were optimized. The separation and re-equilibration time was attained within 20min. Meanwhile, a sequential extraction method for arsenic and mercury in rice was tested. Subsequently, 1% HNO3 microwave-assisted extraction was chosen. Calibration curves based on peak area measurements were linear with correlation coefficient greater than 0.9958 for each species in the range studied. The detection limits of the species were in the range of 0.84-2.41μg/L for arsenic and 0.01-0.04μg/L for mercury, respectively. The proposed method was then successfully applied for the simultaneous determination of arsenic and mercury species in rice flour standard material and two kinds of rice from local markets.
authors.affiliation: College of Food Science and Engineering, Nanjing University of Finance and Economics/The Jiangsu Province Center of Cooperative Innovation for Modern Grain Circulation and Security, Nanjing 210023, People's Republic of China. Electronic address: fangyong10@njue.edu.cn.
authors.forename: Yong
authors.initials: Y
authors.lastname: Fang
authors.affiliation: College of Food Science and Engineering, Nanjing University of Finance and Economics/The Jiangsu Province Center of Cooperative Innovation for Modern Grain Circulation and Security, Nanjing 210023, People's Republic of China.
authors.forename: Yushi
authors.initials: Y
authors.lastname: Pan
authors.affiliation: College of Food Science and Engineering, Nanjing University of Finance and Economics/The Jiangsu Province Center of Cooperative Innovation for Modern Grain Circulation and Security, Nanjing 210023, People's Republic of China.
authors.forename: Peng
authors.initials: P
authors.lastname: Li
authors.affiliation: College of Food Science and Engineering, Nanjing University of Finance and Economics/The Jiangsu Province Center of Cooperative Innovation for Modern Grain Circulation and Security, Nanjing 210023, People's Republic of China.
authors.forename: Mei
authors.initials: M
authors.lastname: Xue
authors.affiliation: College of Food Science and Engineering, Nanjing University of Finance and Economics/The Jiangsu Province Center of Cooperative Innovation for Modern Grain Circulation and Security, Nanjing 210023, People's Republic of China.
authors.forename: Fei
authors.initials: F
authors.lastname: Pei
authors.affiliation: College of Food Science and Engineering, Nanjing University of Finance and Economics/The Jiangsu Province Center of Cooperative Innovation for Modern Grain Circulation and Security, Nanjing 210023, People's Republic of China.
authors.forename: Wenjian
authors.initials: W
authors.lastname: Yang
authors.affiliation: College of Food Science and Engineering, Nanjing University of Finance and Economics/The Jiangsu Province Center of Cooperative Innovation for Modern Grain Circulation and Security, Nanjing 210023, People's Republic of China.
authors.forename: Ning
authors.initials: N
authors.lastname: Ma
authors.affiliation: College of Food Science and Engineering, Nanjing University of Finance and Economics/The Jiangsu Province Center of Cooperative Innovation for Modern Grain Circulation and Security, Nanjing 210023, People's Republic of China; College of Food Science and Technology, Nanjing Agricultural University, Nanjing 210095, People's Republic of China.
authors.forename: Qiuhui
authors.initials: Q
authors.lastname: Hu
mesh_terms: D001151:Arsenic / Q000032:analysis / Q000737:chemistry*; D002851:Chromatography, High Pressure Liquid / Q000379:methods*; D056148:Chromatography, Reverse-Phase / Q000379:methods*; D013058:Mass Spectrometry / Q000379:methods*; D008628:Mercury / Q000032:analysis / Q000737:chemistry*; D012275:Oryza / Q000737:chemistry*
chemical_list: D008628:Mercury; D001151:Arsenic
keywords: Arsenic; HPLC; ICP-MS; Mercury; Speciation