title: A fast electrochromic polymer based on TEMPO substituted polytriphenylamine.
abstract: A novel strategy to obtain rapid electrochromic switching response by introducing 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) moiety into polytriphenylamine backbone has been developed. The electrochromic properties of the integrated polymer film are investigated and a possible mechanism is proposed with TEMPO as a counterion-reservoir group to rapidly balance the charges during electrochromic switching, which leads to significantly improved electrochromism performance.
authors.affiliation: State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineer, Zhejiang University of Technology, Hangzhou 310014, China.|Department of Chemistry, Tongji University, Shanghai 200092, China.
authors.forename: Lvlv
authors.initials: L
authors.lastname: Ji
authors.affiliation: State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineer, Zhejiang University of Technology, Hangzhou 310014, China.
authors.forename: Yuyu
authors.initials: Y
authors.lastname: Dai
authors.affiliation: State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineer, Zhejiang University of Technology, Hangzhou 310014, China.
authors.forename: Shuanma
authors.initials: S
authors.lastname: Yan
authors.affiliation: State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineer, Zhejiang University of Technology, Hangzhou 310014, China.
authors.forename: Xiaojing
authors.initials: X
authors.lastname: Lv
authors.affiliation: College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China.
authors.forename: Chang
authors.initials: C
authors.lastname: Su
authors.affiliation: College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China.
authors.forename: Lihuan
authors.initials: L
authors.lastname: Xu
authors.affiliation: State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineer, Zhejiang University of Technology, Hangzhou 310014, China.|Department of Chemistry, Tsinghua University, Beijing 100084, China.
authors.forename: Yaokang
authors.initials: Y
authors.lastname: Lv
authors.affiliation: State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineer, Zhejiang University of Technology, Hangzhou 310014, China.
authors.forename: Mi
authors.initials: M
authors.lastname: Ouyang
authors.affiliation: Department of Chemistry, Tongji University, Shanghai 200092, China.
authors.forename: Zuofeng
authors.initials: Z
authors.lastname: Chen
authors.affiliation: State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineer, Zhejiang University of Technology, Hangzhou 310014, China.
authors.forename: Cheng
authors.initials: C
authors.lastname: Zhang