title: Synthesis of CdS hollow spheres coupled with g-C3N4 as efficient visible-light-driven photocatalysts.
abstract: CdS hollow spheres (CdS HS) coupled with graphitic carbon nitride (g-C3N4) photocatalysts are synthesized and characterized by x-ray diffraction (XRD), transmission electron microscopy (TEM), ultraviolet-visible diffuse reflection spectroscopy (DRS), x-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR), and photoluminescence spectroscopy (PL). The effect of CdS content on CdS HS/g-C3N4 activity is investigated by  the degradation of Rhodamine B (RhB). The sample of 20 wt% CdS content shows the best photocatalytic performance under visible-light irradiation, with the corresponding RhB degradation rate reaching 97.3%. The excellent photoactivity of CdS HS/g-C3N4 is attributed to the synergistic effect of g-C3N4 and CdS HS. A possible photocatalytic mechanism of the CdS HS/g-C3N4 composite is proposed and corroborated by PL.
authors.affiliation: Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission & Ministry of Education, South-Central University for Nationalities, Wuhan 430074, People's Republic of China. School of Food and Biochemical Engineering, Guangxi Science & Technology Normal University, Laibin 546199, People's Republic of China.
authors.forename: Chunyan
authors.initials: C
authors.lastname: Zhang
authors.forename: Yongfeng
authors.initials: Y
authors.lastname: Lu
authors.forename: Qingqing
authors.initials: Q
authors.lastname: Jiang
authors.forename: Juncheng
authors.initials: J
authors.lastname: Hu