title: Cobalt-catalyzed chelation assisted C-H allylation of aromatic amides with unactivated olefins.
abstract: The cobalt-catalyzed chelation assisted ortho C-H allylation of aromatic amides with unactivated aliphatic alkenes is reported. The reaction proceeds in air under mild reaction conditions, providing allylated products in good to excellent yields with high E-selectivities. This operationally simple method shows a high functional group tolerance.
authors.affiliation: Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan. chatani@chem.eng.osaka-u.ac.jp.
authors.forename: Takuma
authors.initials: T
authors.lastname: Yamaguchi
authors.affiliation: Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan. chatani@chem.eng.osaka-u.ac.jp.
authors.forename: Yadagiri
authors.initials: Y
authors.lastname: Kommagalla
authors.affiliation: Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan. chatani@chem.eng.osaka-u.ac.jp.
authors.forename: Yoshinori
authors.initials: Y
authors.lastname: Aihara
authors.affiliation: Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan. chatani@chem.eng.osaka-u.ac.jp.
authors.forename: Naoto
authors.initials: N
authors.lastname: Chatani