title: Tuning of the Electronic Levels of Oligothiophene-Naphthalimide Assemblies by Chemical Modification.
abstract: Inversion of the connections of amidine linkers combined with controlled oligothiophene chain catenation in oligothiophene-naphthalimide assemblies provides an efficient method to tune the HOMO and LUMO values in this type of assemblies. This modification also suppresses the intramolecular charge transfer (ICT) band normally found in this type of derivatives, also delocalizing the frontier molecular orbitals over the whole conjugated skeleton. The resultant assemblies were used in the fabrication of field-effect transistors, which showed well-balanced ambipolar transport.
authors.affiliation: Department of Organic Chemistry, Faculty of Chemistry, Complutense University of Madrid, Madrid, 28040, Spain.
authors.forename: Alejandro
authors.initials: A
authors.lastname: de la Peña
authors.affiliation: Departament of Physical Chemistry, University of Malaga, Malaga, 29071, Spain.
authors.forename: Iratxe
authors.initials: I
authors.lastname: Arrechea-Marcos
authors.affiliation: Department of Organic Chemistry, Faculty of Chemistry, Complutense University of Madrid, Madrid, 28040, Spain.
authors.forename: María J
authors.initials: MJ
authors.lastname: Mancheño
authors.affiliation: Departament of Physical Chemistry, University of Malaga, Malaga, 29071, Spain.
authors.forename: M Carmen
authors.initials: MC
authors.lastname: Ruiz Delgado
authors.affiliation: Departament of Physical Chemistry, University of Malaga, Malaga, 29071, Spain. teodomiro@uma.es.
authors.forename: J Teodomiro
authors.initials: JT
authors.lastname: López Navarrete
authors.affiliation: Department of Organic Chemistry, Faculty of Chemistry, Complutense University of Madrid, Madrid, 28040, Spain. segura@ucm.es.
authors.forename: José L
authors.initials: JL
authors.lastname: Segura
authors.affiliation: Departament of Physical Chemistry, University of Malaga, Malaga, 29071, Spain. rocioponce@uma.es.
authors.forename: Rocío
authors.identifier: http://orcid.org/0000-0002-3836-3494
authors.initials: R
authors.lastname: Ponce Ortiz
keywords: charge transfer; field-effect transistors; heterocycles; organic semiconductors; spectroscopy