title: Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins.
abstract: Cofactor-mimetic aerobic oxidation has conceptually merged with catalysis of syngas reactions to form a wide range of Markovnikov-selective olefin radical hydrofunctionalizations. We cover the development of the field and review contributions to reaction invention, mechanism, and application to complex molecule synthesis. We also provide a mechanistic framework for understanding this compendium of radical reactions.
authors.affiliation: Department of Chemistry, The Scripps Research Institute , La Jolla, California 92037, United States.
authors.forename: Steven W M
authors.initials: SW
authors.lastname: Crossley
authors.affiliation: Department of Chemistry, The Scripps Research Institute , La Jolla, California 92037, United States.
authors.forename: Carla
authors.initials: C
authors.lastname: Obradors
authors.affiliation: Department of Chemistry, The Scripps Research Institute , La Jolla, California 92037, United States.
authors.forename: Ruben M
authors.initials: RM
authors.lastname: Martinez
authors.affiliation: Department of Chemistry, The Scripps Research Institute , La Jolla, California 92037, United States.
authors.forename: Ryan A
authors.initials: RA
authors.lastname: Shenvi