title: Balancing C=C Functionalization and C=O Reduction in Cu-H Catalysis.
abstract: Coppercabana: The copper(I) hydride catalyzed functionalization of unactivated alkenes has been shown to be compatible with conventional carbonyl reduction. Through the combination of both pathways or complete suppression of C=O reduction in favor of C=C functionalization, methods for the stereoselective synthesis of a variety of chiral molecules have been developed.
authors.affiliation: Institut für Chemie, Technische Universität Berlin, Strasse des 17. Juni 115, 10623, Berlin, Germany.
authors.forename: Jens
authors.initials: J
authors.lastname: Mohr
authors.affiliation: Institut für Chemie, Technische Universität Berlin, Strasse des 17. Juni 115, 10623, Berlin, Germany. martin.oestreich@tu-berlin.de.
authors.forename: Martin
authors.identifier: 0000-0002-1487-9218
authors.initials: M
authors.lastname: Oestreich
keywords: asymmetric catalysis; copper catalysis; copper hydride; hydrosilanes; reduction