title: A N-heterocyclic tetracarbene Pd(ii) moiety containing a Pd(ii)-Pb(ii) bimetallic MOF for three-component cyclotrimerization via benzyne.
abstract: A novel Pd(ii)-Pb(ii) bimetallic metal-organic framework Pd(ii)-Pb(ii)-MOF (B) which contains an N-heterocyclic tetracarbene Pd(ii) moiety was synthesized based on a chelating N-heterocyclic dicarbene Pd(ii)-NHDC ligand (A) under solvothermal conditions. It can be a highly active heterogeneous catalyst for three-component cyclotrimerization via benzyne species.
authors.affiliation: College of Chemistry, Chemical Engineering and Materials Science, Key Laboratory of Molecular and Nano Probes, Engineering Research Center of Pesticide and Medicine Intermediate Clean Production, Ministry of Education, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Wenhua East Road, Jinan 250014, People's Republic of China. yubindong@sdnu.edu.cn.
authors.forename: Ying
authors.initials: Y
authors.lastname: Dong
authors.affiliation: College of Chemistry, Chemical Engineering and Materials Science, Key Laboratory of Molecular and Nano Probes, Engineering Research Center of Pesticide and Medicine Intermediate Clean Production, Ministry of Education, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Wenhua East Road, Jinan 250014, People's Republic of China. yubindong@sdnu.edu.cn.
authors.forename: Yue
authors.initials: Y
authors.lastname: Li
authors.affiliation: College of Chemistry, Chemical Engineering and Materials Science, Key Laboratory of Molecular and Nano Probes, Engineering Research Center of Pesticide and Medicine Intermediate Clean Production, Ministry of Education, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Wenhua East Road, Jinan 250014, People's Republic of China. yubindong@sdnu.edu.cn.
authors.forename: Yong-Liang
authors.initials: YL
authors.lastname: Wei
authors.affiliation: College of Chemistry, Chemical Engineering and Materials Science, Key Laboratory of Molecular and Nano Probes, Engineering Research Center of Pesticide and Medicine Intermediate Clean Production, Ministry of Education, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Wenhua East Road, Jinan 250014, People's Republic of China. yubindong@sdnu.edu.cn.
authors.forename: Jian-Cheng
authors.initials: JC
authors.lastname: Wang
authors.affiliation: College of Chemistry, Chemical Engineering and Materials Science, Key Laboratory of Molecular and Nano Probes, Engineering Research Center of Pesticide and Medicine Intermediate Clean Production, Ministry of Education, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Wenhua East Road, Jinan 250014, People's Republic of China. yubindong@sdnu.edu.cn.
authors.forename: Jian-Ping
authors.initials: JP
authors.lastname: Ma
authors.affiliation: College of Chemistry, Chemical Engineering and Materials Science, Key Laboratory of Molecular and Nano Probes, Engineering Research Center of Pesticide and Medicine Intermediate Clean Production, Ministry of Education, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Wenhua East Road, Jinan 250014, People's Republic of China. yubindong@sdnu.edu.cn.
authors.forename: Jun
authors.initials: J
authors.lastname: Ji
authors.affiliation: College of Chemistry, Chemical Engineering and Materials Science, Key Laboratory of Molecular and Nano Probes, Engineering Research Center of Pesticide and Medicine Intermediate Clean Production, Ministry of Education, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Wenhua East Road, Jinan 250014, People's Republic of China. yubindong@sdnu.edu.cn.
authors.forename: Bing-Jian
authors.initials: BJ
authors.lastname: Yao
authors.affiliation: College of Chemistry, Chemical Engineering and Materials Science, Key Laboratory of Molecular and Nano Probes, Engineering Research Center of Pesticide and Medicine Intermediate Clean Production, Ministry of Education, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Wenhua East Road, Jinan 250014, People's Republic of China. yubindong@sdnu.edu.cn.
authors.forename: Yu-Bin
authors.initials: YB
authors.lastname: Dong