title: Cobalt Ferrite Bearing Nitrogen-Doped Reduced Graphene Oxide Layers Spatially Separated with Microporous Carbon as Efficient Oxygen Reduction Electrocatalyst.
abstract: The present work discloses how high-quality dispersion of fine particles of cobalt ferrite (CF) could be attained on nitrogen-doped reduced graphene oxide (CF/N-rGO) and how this material in association with a microporous carbon phase could deliver significantly enhanced activity toward electrochemical oxygen reduction reaction (ORR). Our study indicates that the microporous carbon phase plays a critical role in spatially separating the layers of CF/N-rGO and in creating a favorable atmosphere to ensure the seamless distribution of the reactants to the active sites located on CF/N-rGO. In terms of the ORR current density, the heat-treated hybrid catalyst at 150 °C (CF/N-rGO-150) is found to be clearly outperforming (7.4 ± 0.5 mA/cm(2)) the state-of-the-art 20 wt % Pt-supported carbon catalyst (PtC) (5.4 ± 0.5 mA/cm(2)). The mass activity and stability of CF-N-rGO-150 are distinctly superior to PtC even after 5000 electrochemical cycles. As a realistic system level exploration of the catalyst, testing of a primary zinc-air battery could be demonstrated using CF/N-rGO-150 as the cathode catalyst. The battery is giving a galvanostatic discharge time of 15 h at a discharge current density of 20 mA/cm(2) and a specific capacity of ∼630 mAh g(-1) in 6 M KOH by using a Zn foil as the anode. Distinctly, the battery performance of this system is found to be superior to that of PtC in less concentrated KOH solution as the electrolyte.
authors.affiliation: Physical and Materials Chemistry Division, CSIR-National Chemical Laboratory , Dr. Homi Bhabha Road, Pune 41108, India.|Academy of Scientific and Innovative Research , Anusandhan Bhawan, 2 Rafi Marg, New Delhi 110001, India.
authors.forename: Varchaswal
authors.initials: V
authors.lastname: Kashyap
authors.affiliation: Physical and Materials Chemistry Division, CSIR-National Chemical Laboratory , Dr. Homi Bhabha Road, Pune 41108, India.|Academy of Scientific and Innovative Research , Anusandhan Bhawan, 2 Rafi Marg, New Delhi 110001, India.
authors.forename: Santosh K
authors.initials: SK
authors.lastname: Singh
authors.affiliation: Physical and Materials Chemistry Division, CSIR-National Chemical Laboratory , Dr. Homi Bhabha Road, Pune 41108, India.|Academy of Scientific and Innovative Research , Anusandhan Bhawan, 2 Rafi Marg, New Delhi 110001, India.
authors.forename: Sreekumar
authors.initials: S
authors.lastname: Kurungot
keywords: Zn−air battery; cobalt ferrite; microporous carbon; nanoparticle; oxygen reduction reaction; solvothermal method