title: Raman spectral characteristics of magmatic-contact metamorphic coals from Huainan Coalfield, China.
abstract: Normal burial metamorphism of coal superimposed by magmatic-contact metamorphism makes the characteristics of the Raman spectrum of coal changed. Nine coal samples were chosen at a coal transect perpendicular to the intrusive dike, at the No. 3 coal seam, Zhuji Coal Mine, Huainan Coalfield, China, with different distances from dike-coal boundary (DCB). Geochemical (proximate and ultimate) analysis and mean random vitrinite reflectance (R0, %) indicate that there is a significant relationship between the values of volatile matter and R0in metamorphosed coals. Raman spectra show that the graphite band (G band) becomes the major band but the disordered band (D band) disappears progressively, with the increase of metamorphic temperature in coals, showing that the structural organization in high-rank contact-metamorphosed coals is close to that of well-crystallized graphite. Evident relationships are observed between the calculated Raman spectral parameters and the peak metamorphic temperature, suggesting some spectral parameters have the potentials to be used as geothermometers for contact-metamorphic coals.
authors.affiliation: CAS Key Laboratory of Crust-Mantle Materials and Environment, School of Earth and Space Sciences, University of Science and Technology of China, Hefei, Anhui 230026, China; Exploration Research Institute, Anhui Provincial Bureau of Coal Geology, Hefei, Anhui 230088, China.
authors.forename: Shancheng
authors.initials: S
authors.lastname: Chen
authors.affiliation: CAS Key Laboratory of Crust-Mantle Materials and Environment, School of Earth and Space Sciences, University of Science and Technology of China, Hefei, Anhui 230026, China; State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, The Chinese Academy of Sciences, Xi'an, Shaanxi 710075, China; Exploration Research Institute, Anhui Provincial Bureau of Coal Geology, Hefei, Anhui 230088, China.
authors.forename: Dun
authors.initials: D
authors.lastname: Wu
authors.affiliation: CAS Key Laboratory of Crust-Mantle Materials and Environment, School of Earth and Space Sciences, University of Science and Technology of China, Hefei, Anhui 230026, China; State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, The Chinese Academy of Sciences, Xi'an, Shaanxi 710075, China. Electronic address: lgj@ustc.edu.cn.
authors.forename: Guijian
authors.initials: G
authors.lastname: Liu
authors.affiliation: CAS Key Laboratory of Crust-Mantle Materials and Environment, School of Earth and Space Sciences, University of Science and Technology of China, Hefei, Anhui 230026, China.
authors.forename: Ruoyu
authors.initials: R
authors.lastname: Sun
keywords: Huainan Coalfield; Magmatic-contact metamorphosed coal; Raman spectroscopy; Vitrinite reflectance