title: Visible-light induced oxidant-free oxidative cross-coupling for constructing allylic sulfones from olefins and sulfinic acids.
abstract: An oxidant-free dehydrogenative sulfonylation of α-methyl-styrene derivatives was developed for the construction of allylic sulfones by using eosin Y as a photosensitizer in conjunction with a cobaloxime catalyst. The process features a low-cost metal catalyst and atom economy, which provides an appealing strategy for future synthetic chemistry.
authors.affiliation: College of Chemistry and Molecular Sciences, the Institute for Advanced Studies (IAS), Wuhan University, Wuhan, 430072, P. R. China. aiwenlei@whu.edu.cn.
authors.forename: Guoting
authors.initials: G
authors.lastname: Zhang
authors.affiliation: College of Chemistry and Molecular Sciences, the Institute for Advanced Studies (IAS), Wuhan University, Wuhan, 430072, P. R. China. aiwenlei@whu.edu.cn.
authors.forename: Lingling
authors.initials: L
authors.lastname: Zhang
authors.affiliation: College of Chemistry and Molecular Sciences, the Institute for Advanced Studies (IAS), Wuhan University, Wuhan, 430072, P. R. China. aiwenlei@whu.edu.cn.
authors.forename: Hong
authors.initials: H
authors.lastname: Yi
authors.affiliation: College of Chemistry and Molecular Sciences, the Institute for Advanced Studies (IAS), Wuhan University, Wuhan, 430072, P. R. China. aiwenlei@whu.edu.cn.
authors.forename: Yi
authors.initials: Y
authors.lastname: Luo
authors.affiliation: School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400030, P. R. China.
authors.forename: Xiaotian
authors.initials: X
authors.lastname: Qi
authors.affiliation: Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry & University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190, P. R. China. lzwu@mail.ipc.ac.cn.
authors.forename: Chen-Ho
authors.initials: CH
authors.lastname: Tung
authors.affiliation: Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry & University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190, P. R. China. lzwu@mail.ipc.ac.cn.
authors.forename: Li-Zhu
authors.initials: LZ
authors.lastname: Wu
authors.affiliation: College of Chemistry and Molecular Sciences, the Institute for Advanced Studies (IAS), Wuhan University, Wuhan, 430072, P. R. China. aiwenlei@whu.edu.cn and Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China.
authors.forename: Aiwen
authors.initials: A
authors.lastname: Lei