title: Nanostructuration of PEDOT in Porous Coordination Polymers for Tunable Porosity and Conductivity.
abstract: A series of conductive porous composites were obtained by the polymerization of 3,4-ethylenedioxythiophene (EDOT) in the cavities of MIL-101(Cr). By controlling the amount of EDOT loaded into the host framework, it was possible to modulate the conductivity as well as the porosity of the composite. This approach yields materials with a reasonable electronic conductivity (1.1 × 10(-3) S·cm(-1)) while maintaining high porosity (SBET = 803 m(2)/g). This serves as a promising strategy for obtaining highly nanotextured conductive polymers with very high accessibility for small gas molecules, which are beneficial to the fabrication of a chemiresistive sensor for the detection of NO2.
authors.affiliation: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University , Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.|CREST, Japan Science and Technology Agency (JST) , 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan.
authors.forename: Benjamin
authors.initials: B
authors.lastname: Le Ouay
authors.affiliation: Institute for Materials Chemistry and Engineering, Kyushu University , 6-1 Kasuga-Koen, Kasuga, Fukuoka 816-8580, Japan.
authors.forename: Mickael
authors.initials: M
authors.lastname: Boudot
authors.affiliation: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University , Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
authors.forename: Takashi
authors.initials: T
authors.lastname: Kitao
authors.affiliation: Institute for Materials Chemistry and Engineering, Kyushu University , 6-1 Kasuga-Koen, Kasuga, Fukuoka 816-8580, Japan.
authors.forename: Takeshi
authors.initials: T
authors.lastname: Yanagida
authors.affiliation: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University , Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.|Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University , Yoshida, Sakyo-ku, Kyoto 606-8501, Japan.
authors.forename: Susumu
authors.initials: S
authors.lastname: Kitagawa
authors.affiliation: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University , Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.|CREST, Japan Science and Technology Agency (JST) , 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan.
authors.forename: Takashi
authors.initials: T
authors.lastname: Uemura