title: A Well-Defined {[(PhCH₂O)₂P(CH₃)₂CHNCH(CH₃)₂]₂PdCl₂} Complex Catalyzed Hiyama Coupling of Aryl Bromides with Arylsilanes.
abstract: A palladium (II) complex {[(PhCH₂O)₂P(CH₃)₂CHNCH(CH₃)₂]₂PdCl₂} catalyzed Hiyama cross-coupling reaction between aryl bromides and arylsilanes has been developed. The substituted biaryls were produced in moderate to high yields, regardless of electron-withdrawing or electron-donating.
authors.affiliation: Institute of Coordination Catalysis, College of Chemistry and Bio-Engineering, Yichun University, Yichun 336000, China. guomengping65@163.com.|Engineering Center of Jiangxi University for Lithium Energy, Yichun University, Yichun 336000, China. guomengping65@163.com.
authors.forename: Mengping
authors.initials: M
authors.lastname: Guo
authors.affiliation: Institute of Coordination Catalysis, College of Chemistry and Bio-Engineering, Yichun University, Yichun 336000, China. fuleiqing2009@163.com.|Engineering Center of Jiangxi University for Lithium Energy, Yichun University, Yichun 336000, China. fuleiqing2009@163.com.
authors.forename: Leiqing
authors.initials: L
authors.lastname: Fu
authors.affiliation: Institute of Coordination Catalysis, College of Chemistry and Bio-Engineering, Yichun University, Yichun 336000, China. lijiamin@163.com.
authors.forename: Jiamin
authors.initials: J
authors.lastname: Li
authors.affiliation: Institute of Coordination Catalysis, College of Chemistry and Bio-Engineering, Yichun University, Yichun 336000, China. zhoulanjiang@163.com.
authors.forename: Lanjiang
authors.initials: L
authors.lastname: Zhou
authors.affiliation: Institute of Coordination Catalysis, College of Chemistry and Bio-Engineering, Yichun University, Yichun 336000, China. kangyanping@163.com.
authors.forename: Yanping
authors.initials: Y
authors.lastname: Kang
mesh_terms: D002384:Catalysis; D006842:Hydrocarbons, Brominated / Q000737:chemistry*; D009944:Organoplatinum Compounds / Q000737:chemistry*; D011084:Polycyclic Aromatic Hydrocarbons / Q000138:chemical synthesis* / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*
chemical_list: D006842:Hydrocarbons, Brominated; D009944:Organoplatinum Compounds; D011084:Polycyclic Aromatic Hydrocarbons; D012821:Silanes
keywords: Hiyama cross-coupling reaction; palladium (II) complex; synthetic method; unsymmetrical biaryls