title: Hybrid Supramolecular and Colloidal Hydrogels that Bridge Multiple Length Scales.
abstract: Hybrid nanocomposites were constructed based on colloidal nanofibrillar hydrogels with interpenetrating supramolecular hydrogels, displaying enhanced rheological yield strain and a synergistic improvement in storage modulus. The supramolecular hydrogel consists of naphthyl-functionalized hydroxyethyl cellulose and a cationic polystyrene derivative decorated with methylviologen moieties, physically cross-linked with cucurbit[8]uril macrocyclic hosts. Fast exchange kinetics within the supramolecular system are enabled by reversible cross-linking through the binding of the naphthyl and viologen guests. The colloidal hydrogel consists of nanofibrillated cellulose that combines a mechanically strong nanofiber skeleton with a lateral fibrillar diameter of a few nanometers. The two networks interact through hydroxyethyl cellulose adsorption to the nanofibrillated cellulose surfaces. This work shows methods to bridge the length scales of molecular and colloidal hybrid hydrogels, resulting in synergy between reinforcement and dynamics.
authors.affiliation: Melville Laboratory for Polymer Synthesis, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB21EW (UK).
authors.forename: Emma-Rose
authors.initials: ER
authors.lastname: Janeček
authors.affiliation: Molecular Materials, Department of Applied Physics, Aalto University (previously Helsinki University of Technology), P.O. Box 15100, FIN-00076, Espoo (Finland).
authors.forename: Jason R
authors.initials: JR
authors.lastname: McKee
authors.affiliation: Melville Laboratory for Polymer Synthesis, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB21EW (UK).
authors.forename: Cindy S Y
authors.initials: CS
authors.lastname: Tan
authors.affiliation: Molecular Materials, Department of Applied Physics, Aalto University (previously Helsinki University of Technology), P.O. Box 15100, FIN-00076, Espoo (Finland).
authors.forename: Antti
authors.initials: A
authors.lastname: Nykänen
authors.affiliation: Molecular Materials, Department of Applied Physics, Aalto University (previously Helsinki University of Technology), P.O. Box 15100, FIN-00076, Espoo (Finland).
authors.forename: Marjo
authors.initials: M
authors.lastname: Kettunen
authors.affiliation: Department of Forest Products Technology, School of Chemical Technology, Aalto University, P.O. Box 16300, FIN-00076 Aalto (Finland).
authors.forename: Janne
authors.initials: J
authors.lastname: Laine
authors.affiliation: Molecular Materials, Department of Applied Physics, Aalto University (previously Helsinki University of Technology), P.O. Box 15100, FIN-00076, Espoo (Finland).
authors.forename: Olli
authors.initials: O
authors.lastname: Ikkala
authors.affiliation: Melville Laboratory for Polymer Synthesis, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB21EW (UK).
authors.forename: Oren A
authors.initials: OA
authors.lastname: Scherman
keywords: Hydrogele; Nanoverbundstoffe; Nanozellulose; Supramolekulare Chemie