title: {Tc(NO)(Cp)(PPh3)}(+) - a novel technetium(i) core.
abstract: Reactions between [Tc(I)(NO)X2(PPh3)2(CH3CN)] complexes (X = Cl, Br) and KCp form the pseudotetrahedral organotechnetium compounds [Tc(I)(NO)(Cp)(PPh3)X]. The halide ligands can readily be replaced by other halides or organometallic ligands giving access to a novel family of technetium(i) compounds with the robust {Tc(NO)(Cp)(PPh3)}(+) core.
authors.affiliation: Freie Universität Berlin, Institute of Chemistry and Biochemistry, Fabeckstr. 34/36, D-14195 Berlin, Germany. Ulrich.Abram@fu-berlin.de.
authors.forename: J
authors.initials: J
authors.lastname: Ackermann
authors.affiliation: Freie Universität Berlin, Institute of Chemistry and Biochemistry, Fabeckstr. 34/36, D-14195 Berlin, Germany. Ulrich.Abram@fu-berlin.de.
authors.forename: A
authors.initials: A
authors.lastname: Hagenbach
authors.affiliation: Freie Universität Berlin, Institute of Chemistry and Biochemistry, Fabeckstr. 34/36, D-14195 Berlin, Germany. Ulrich.Abram@fu-berlin.de.
authors.forename: U
authors.initials: U
authors.lastname: Abram