title: Controlling film topography to form highly hydrophobic waterborne coatings.
abstract: Coatings have a tremendous impact on economy as they reduce corrosion that has an estimated cost of 3% of the world's GDP. Hydrophobic coatings are particularly efficient for this purpose and the challenge is to produce cost effective and environmentally friendly, highly hydrophobic, cohesive and non-porous coatings applicable to large and irregular surfaces. This work shows that this goal can be achieved by forming wrinkles on the surface of waterborne coatings through fine-tuning of the film forming conditions. The proof of concept was demonstrated by using waterborne dispersions of copolymers of 1H,1H,2H,2H-perfluorodecyl acrylate and 2-ethylhexyl acrylate, and using the temperature and hardness of the copolymer as control variables during film formation. This allowed the formation of transparent films with a wrinkled surface that had a contact angle of 133°, which represents an increase of 20° with respect to the film cast under standard conditions.
authors.affiliation: POLYMAT and Kimika Aplikatua Saila, Kimika Zientzien Fakultatea, University of the Basque Country UPV/EHU, Joxe Mari Korta Zentroa, Tolosa Hiribidea 72, Donostia-San Sebastian, 20018, Spain. jm.asua@ehu.es.
authors.forename: Ana B
authors.initials: AB
authors.lastname: López
authors.affiliation: POLYMAT and Kimika Aplikatua Saila, Kimika Zientzien Fakultatea, University of the Basque Country UPV/EHU, Joxe Mari Korta Zentroa, Tolosa Hiribidea 72, Donostia-San Sebastian, 20018, Spain. jm.asua@ehu.es.
authors.forename: José C
authors.initials: JC
authors.lastname: de la Cal
authors.affiliation: POLYMAT and Kimika Aplikatua Saila, Kimika Zientzien Fakultatea, University of the Basque Country UPV/EHU, Joxe Mari Korta Zentroa, Tolosa Hiribidea 72, Donostia-San Sebastian, 20018, Spain. jm.asua@ehu.es.
authors.forename: José M
authors.initials: JM
authors.lastname: Asua