title: In situ decoration of graphene sheets with gold nanoparticles synthetized by pulsed laser ablation in liquids.
abstract: The demand for nanocomposites of graphene and carbonaceous materials decorated with metallic nanoparticles is increasing on account of their applications in science and technology. Traditionally, the production of graphene-metal assemblies is achieved by the non-environmentally friendly reduction of metallic salts in carbonaceous suspensions. However, precursor residues during nanoparticle growth may reduce their surface activity and promote cross-chemical undesired effects. In this work we present a laser-based alternative to synthesize ligand-free gold nanoparticles that are anchored onto the graphene surface in a single reaction step. Laser radiation is used to generate highly pure nanoparticles from a gold disk surrounded by a graphene oxide suspension. The produced gold nanoparticles are directly immobilized onto the graphene surface. Moreover, the presence of graphene oxide influences the size of the nanoparticles and its interaction with the laser, causes only a slight reduction of the material. This work constitutes a green alternative synthesis of graphene-metal assemblies and a practical methodology that may inspire future developments.
authors.affiliation: GROC·UJI, Institute of New Imaging Technologies, Universitat Jaume I, Avda. Sos Baynat s/n, 12071, Castellón, Spain.
authors.forename: Rafael
authors.initials: R
authors.lastname: Torres-Mendieta
authors.affiliation: INAM, Institute of Advanced Materials, Universitat Jaume I, Avda. Sos Baynat s/n, 12071, Castellón, Spain.
authors.forename: David
authors.initials: D
authors.lastname: Ventura-Espinosa
authors.affiliation: INAM, Institute of Advanced Materials, Universitat Jaume I, Avda. Sos Baynat s/n, 12071, Castellón, Spain.
authors.forename: Sara
authors.initials: S
authors.lastname: Sabater
authors.affiliation: GROC·UJI, Institute of New Imaging Technologies, Universitat Jaume I, Avda. Sos Baynat s/n, 12071, Castellón, Spain.
authors.forename: Jesus
authors.initials: J
authors.lastname: Lancis
authors.affiliation: GROC·UJI, Institute of New Imaging Technologies, Universitat Jaume I, Avda. Sos Baynat s/n, 12071, Castellón, Spain.
authors.forename: Gladys
authors.initials: G
authors.lastname: Mínguez-Vega
authors.affiliation: INAM, Institute of Advanced Materials, Universitat Jaume I, Avda. Sos Baynat s/n, 12071, Castellón, Spain.
authors.forename: Jose A
authors.initials: JA
authors.lastname: Mata