title: Regio- and Stereoselective Oxysulfonylation of Allenes.
abstract: A highly regio- and stereoselective oxysulfonylation of allenes was developed that provided direct access to 2-sulfonyl allylic alcohols in good yields. By means of dioxygen activation, selective difunctionlization of allenes could be successfully achieved under mild metal-free conditions. Preliminary mechanistic investigation disclosed that this transformation probably goes through a radical process.
authors.affiliation: College of Chemistry and Molecular Sciences, the Institute for Advanced Studies (IAS), Wuhan University , Wuhan, Hubei 430072, P. R. China.
authors.forename: Zhiyuan
authors.initials: Z
authors.lastname: Huang
authors.affiliation: College of Chemistry and Molecular Sciences, the Institute for Advanced Studies (IAS), Wuhan University , Wuhan, Hubei 430072, P. R. China.
authors.forename: Qingquan
authors.initials: Q
authors.lastname: Lu
authors.affiliation: College of Chemistry and Molecular Sciences, the Institute for Advanced Studies (IAS), Wuhan University , Wuhan, Hubei 430072, P. R. China.
authors.forename: Yichang
authors.initials: Y
authors.lastname: Liu
authors.affiliation: College of Chemistry and Molecular Sciences, the Institute for Advanced Studies (IAS), Wuhan University , Wuhan, Hubei 430072, P. R. China.
authors.forename: Dong
authors.initials: D
authors.lastname: Liu
authors.affiliation: College of Chemistry and Molecular Sciences, the Institute for Advanced Studies (IAS), Wuhan University , Wuhan, Hubei 430072, P. R. China.
authors.forename: Jian
authors.initials: J
authors.lastname: Zhang
authors.affiliation: College of Chemistry and Molecular Sciences, the Institute for Advanced Studies (IAS), Wuhan University , Wuhan, Hubei 430072, P. R. China.|State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics , Lanzhou 730000, P. R. China.
authors.forename: Aiwen
authors.initials: A
authors.lastname: Lei