title: First three-dimensional actinide polyrotaxane framework mediated by windmill-like six-connected oligomeric uranyl: dual roles of the pseudorotaxane precursor.
abstract: The first 3D actinide polyrotaxane framework (named IHEP-URCP-2) has been obtained based on windmill-like six-connected high-nuclear oligomeric uranyl nodes under hydrothermal conditions. Notably, the in situ formed pseudorotaxane ligand simultaneously plays dual roles of both a bulky pseudorotaxane linker and a supramolecular guest.
authors.affiliation: Laboratory of Nuclear Energy Chemistry and Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China. shiwq@ihep.ac.cn.
authors.forename: Lei
authors.initials: L
authors.lastname: Mei
authors.forename: Zhen-Ni
authors.initials: ZN
authors.lastname: Xie
authors.forename: Kong-Qiu
authors.initials: KQ
authors.lastname: Hu
authors.forename: Lin
authors.initials: L
authors.lastname: Wang
authors.forename: Li-Yong
authors.initials: LY
authors.lastname: Yuan
authors.forename: Zi-Jie
authors.initials: ZJ
authors.lastname: Li
authors.forename: Zhi-Fang
authors.initials: ZF
authors.lastname: Chai
authors.forename: Wei-Qun
authors.initials: WQ
authors.lastname: Shi