title: Soluble Metal-Nanoparticle-Decorated Porous Coordination Polymers for the Homogenization of Heterogeneous Catalysis.
abstract: Ultrasmall metal nanoparticles (MNPs) were decorated on soluble porous coordination polymers (PCPs) with high metal loadings. The solubility of the composite and the size of the MNPs can be controlled by varying the ratio of the precursors to the supports. The soluble PCPs can serve as a platform to homogenize heterogeneous MNPs catalysts, which exhibited excellent activity and recyclability in C-H activation and Suzuki reactions. This strategy combines the advantages of homogeneous and heterogeneous catalysis and may bring new inspiration to catalysis.
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , 155 Yangqiao Road West, 331800 Fuzhou, China.
authors.forename: Yuan-Biao
authors.initials: YB
authors.lastname: Huang
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , 155 Yangqiao Road West, 331800 Fuzhou, China.
authors.forename: Qiang
authors.initials: Q
authors.lastname: Wang
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , 155 Yangqiao Road West, 331800 Fuzhou, China.
authors.forename: Jun
authors.initials: J
authors.lastname: Liang
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , 155 Yangqiao Road West, 331800 Fuzhou, China.
authors.forename: Xusheng
authors.initials: X
authors.lastname: Wang
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , 155 Yangqiao Road West, 331800 Fuzhou, China.
authors.forename: Rong
authors.initials: R
authors.lastname: Cao