title: A Library of Fluorinated Electrophiles for Chemical Tagging and Materials Synthesis.
abstract: Various applications could benefit from new fluorinated molecules that offer chemical handles for quickly functionalizing reactive surfaces and molecules. Herein, we report the synthesis of a library of fluorinated molecules that contain nonafluoro-tert-butyl groups and electrophilic handles, mostly acrylates and acrylamides. Featuring a variety of hydrophobic and hydrophilic linkers, these molecules could find use in polymer chemistry, biomaterials, biomedical imaging, and protein tagging.
authors.affiliation: Department of Chemistry and Biochemistry, Canisius College , 2001 Main Street, Buffalo, New York 14208-1098, United States.
authors.forename: Jonathan J
authors.initials: JJ
authors.lastname: Kasper
authors.affiliation: Department of Chemistry and Biochemistry, Canisius College , 2001 Main Street, Buffalo, New York 14208-1098, United States.
authors.forename: Jamie E
authors.initials: JE
authors.lastname: Hitro
authors.affiliation: Department of Chemistry and Biochemistry, Canisius College , 2001 Main Street, Buffalo, New York 14208-1098, United States.
authors.forename: Sabrina R
authors.initials: SR
authors.lastname: Fitzgerald
authors.affiliation: Department of Chemistry and Biochemistry, Canisius College , 2001 Main Street, Buffalo, New York 14208-1098, United States.
authors.forename: Joseph M
authors.initials: JM
authors.lastname: Schnitter
authors.affiliation: Department of Chemistry and Biochemistry, Canisius College , 2001 Main Street, Buffalo, New York 14208-1098, United States.
authors.forename: James J
authors.initials: JJ
authors.lastname: Rutowski
authors.affiliation: Department of Chemistry and Biochemistry, Canisius College , 2001 Main Street, Buffalo, New York 14208-1098, United States.
authors.forename: John A
authors.initials: JA
authors.lastname: Heck
authors.affiliation: Department of Chemistry and Biochemistry, Canisius College , 2001 Main Street, Buffalo, New York 14208-1098, United States.
authors.forename: Jeremy L
authors.initials: JL
authors.lastname: Steinbacher