title: Formation of Large Ag Clusters with Shells of Methane, Ethylene, and Acetylene in He Droplets.
abstract: Helium droplets were used to assemble composite metal-molecular clusters. Produced clusters have several hundreds of silver atoms in the core, immersed in a shell consisting of methane, ethylene, or acetylene molecules. The structure of the clusters was studied via infrared spectra of the C-H stretches of the hydrocarbon molecules. The spectra of the clusters containing methane and acetylene show two distinct features due to molecules on the interface with silver core and those in the volume of the neat molecular part of the clusters. The relative intensities of the peaks are in good agreement with the estimates based on the number of the captured particles. Experiments also suggest that selection rules for infrared transitions for molecules adsorbed on metal surfaces are also valid for silver clusters as small as 300 atoms.
authors: Department of Chemistry, University of Southern California , Los Angeles, California 90089, United States.
authors: Evgeny
authors: E
authors: Loginov
authors: Department of Chemistry, University of Southern California , Los Angeles, California 90089, United States.
authors: Luis F
authors: LF
authors: Gomez
authors: Department of Chemistry, University of Southern California , Los Angeles, California 90089, United States.
authors: Boris G
authors: BG
authors: Sartakov
authors: Department of Chemistry, University of Southern California , Los Angeles, California 90089, United States.
authors: Andrey F
authors: AF
authors: Vilesov