title: Homocoupling of Iodoarenes and Bromoalkanes Using Photoredox Gold Catalysis: A Light Enabled Au(III) Reductive Elimination.
abstract: The formation of homocoupled alkane byproducts have been identified in the reduction of bromoalkanes via photoredox gold catalysis with dimeric Au(I) complexes. This prompted further investigation into the mechanism of formation of these byproducts and the diversity of C-X bonds amenable to this transformation. Examples were found when considering bromoalkanes while a wide variety of iodoarenes underwent this process in good to excellent yields. The light enabled homocoupling of iodoarenes made possible by photoredox gold catalysis is reported.
authors: Centre for Catalysis, Research and Innovation, Department of Chemistry and Biomolecular Sciences, University of Ottawa , Ottawa, Ontario, Canada.
authors: Huy
authors: H
authors: Tran
authors: Centre for Catalysis, Research and Innovation, Department of Chemistry and Biomolecular Sciences, University of Ottawa , Ottawa, Ontario, Canada.
authors: Terry
authors: T
authors: McCallum
authors: Centre for Catalysis, Research and Innovation, Department of Chemistry and Biomolecular Sciences, University of Ottawa , Ottawa, Ontario, Canada.
authors: Mathieu
authors: M
authors: Morin
authors: Centre for Catalysis, Research and Innovation, Department of Chemistry and Biomolecular Sciences, University of Ottawa , Ottawa, Ontario, Canada.
authors: Louis
authors: L
authors: Barriault