title: Modeling of experimental data on trace elements and organic compounds content in industrial waste dumps.
abstract: The main objective of the study presented was to investigate the differences between 20 mine waste dumps located in the Silesian Region of Poland and Czech Republic, in terms of trace elements and polycyclic aromatic hydrocarbons contents. The Principal Component Analysis and Hierarchical Clustering Analysis were applied in exploration of the studied data. Since the data set was affected by outlying objects, the employment of a relevant analysis strategy was necessary. The final PCA model was constructed with the use of the Expectation-Maximization iterative approach preceded by a correct identification of outliers. The analysis of the experimental data indicated that three mine waste dumps located in Poland were characterized by the highest concentrations of dibenzo(g,h,i)anthracene and benzo(g,h,i)perylene, and six objects located in Czech Republic and three objects in Poland were distinguished by high concentrations of chrysene and indeno (1.2.3-cd) pyrene. Three of studied mine waste dumps, one located in Czech Republic and two in Poland, were characterized by low concentrations of Cr, Ni, V, naphthalene, acenaphthene, fluorene, phenanthrene, anthracene, fluoranthen, benzo(a)anthracene, chrysene, benzo (b) fluoranthene, benzo (k) fluoranthene, benzo(a)pyrene, dibenzo(g,h,i)anthracene, benzo(g,h,i)perylene and indeno (1.2.3-cd) pyrene in comparison with the remaining ones. The analysis contributes to the assessment and prognosis of ecological and health risks related to the emission of trace elements and organic compounds (PAHs) from the waste dumps examined. No previous research of similar scope and aims has been reported for the area concerned.
authors: Department of Energy Saving and Air Protection, Central Mining Institute, Pl. Gwarków 1, 40-166 Katowice, Poland. Electronic address: smolin@gig.katowice.pl.
authors: Adam
authors: A
authors: Smoliński
authors: Department of Environmental Monitoring, Central Mining Institute, Pl. Gwarków 1, 40-166 Katowice, Poland.
authors: Leszek
authors: L
authors: Drobek
authors: Institute of Environmental Engineering, Faculty of Mining and Geology, Technical University of Ostrava, 17. Listopadu 15, 708 33 Ostrava-Poruba, Czech Republic.
authors: Václav
authors: V
authors: Dombek
authors: Department of Organic Chemistry, Institute of Chemistry, University of Silesia, 40-006 Katowice, Poland.
authors: Andrzej
authors: A
authors: Bąk
mesh_terms: D016000:Cluster Analysis; D018153:Czech Republic; D004784:Environmental Monitoring; D007220:Industrial Waste / Q000032:analysis*; D015233:Models, Statistical; D011044:Poland; D011084:Polycyclic Aromatic Hydrocarbons / Q000032:analysis*; D025341:Principal Component Analysis; D014131:Trace Elements / Q000032:analysis*; D064091:Waste Disposal Facilities
chemical_list: D007220:Industrial Waste; D011084:Polycyclic Aromatic Hydrocarbons; D014131:Trace Elements
keywords: EM; HCA; Mine waste dump; PAHs; PCA; Trace elements