title: From discrete molecule, to polymer, to MOF: mapping the coordination chemistry of Cd(II) using (113)Cd solid-state NMR.
abstract: Studies of three related Cd(II) systems (a discrete [Cd(II)2] unit, a one-dimensional [Cd(II)2]n coordination polymer and a Cd(II)-based MOF) all derived from the ligand 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine, reveal an exceptionally rare example of (113)Cd-(113)Cd J coupling in the polymer that is detectable by solid-state NMR ((2)JCd-Cd = ∼65 Hz).
authors: Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie, Ottawa, ON, Canada K1N 6N5. m.murugesu@uottawa.ca David.Bryce@uottawa.ca.
authors: Jamie M
authors: JM
authors: Frost
authors: Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie, Ottawa, ON, Canada K1N 6N5. m.murugesu@uottawa.ca David.Bryce@uottawa.ca.
authors: Libor
authors: L
authors: Kobera
authors: Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie, Ottawa, ON, Canada K1N 6N5. m.murugesu@uottawa.ca David.Bryce@uottawa.ca.
authors: Amélie
authors: A
authors: Pialat
authors: Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie, Ottawa, ON, Canada K1N 6N5. m.murugesu@uottawa.ca David.Bryce@uottawa.ca.
authors: Yixin
authors: Y
authors: Zhang
authors: Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie, Ottawa, ON, Canada K1N 6N5. m.murugesu@uottawa.ca David.Bryce@uottawa.ca.
authors: Scott A
authors: SA
authors: Southern
authors: Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie, Ottawa, ON, Canada K1N 6N5. m.murugesu@uottawa.ca David.Bryce@uottawa.ca.
authors: Bulat
authors: B
authors: Gabidullin
authors: Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie, Ottawa, ON, Canada K1N 6N5. m.murugesu@uottawa.ca David.Bryce@uottawa.ca.
authors: David L
authors: DL
authors: Bryce
authors: Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie, Ottawa, ON, Canada K1N 6N5. m.murugesu@uottawa.ca David.Bryce@uottawa.ca.
authors: Muralee
authors: M
authors: Murugesu