title: Room-Temperature Characterization of a Mixed-Valent μ-Hydroxodicopper(II,III) Complex.
abstract: Bis(μ-hydroxo)dicopper(II,II) bearing a naphthyridine-based ligand has been synthesized and characterized in the solid state and solution. Cyclic voltammetry at room temperature displays a reversible redox system that corresponds to the monoelectronic oxidation of the complex. Spectroscopic and time-resolved spectroelectrochemical data coupled to theoretical results support the formation of a charge-localized mixed-valent Cu(II,III)2 species.
authors: DCM (UMR CNRS 5250), Université Grenoble-Alpes , CS 40700, 38058 Grenoble, France.
authors: James A
authors: JA
authors: Isaac
authors: CEMCA (UMR CNRS 6521), Université de Bretagne Occidentale , 6 avenue Le Gorgeu, 29238 Brest, France.
authors: Federica
authors: F
authors: Gennarini
authors: CEMCA (UMR CNRS 6521), Université de Bretagne Occidentale , 6 avenue Le Gorgeu, 29238 Brest, France.
authors: Isidoro
authors: I
authors: López
authors: DCM (UMR CNRS 5250), Université Grenoble-Alpes , CS 40700, 38058 Grenoble, France.|Institut de Chimie, CLAC, UMR 7177 CNRS, Université de Strasbourg , 67008 Strasbourg, France.
authors: Aurore
authors: A
authors: Thibon-Pourret
authors: DCM (UMR CNRS 5250), Université Grenoble-Alpes , CS 40700, 38058 Grenoble, France.
authors: Rolf
authors: R
authors: David
authors: DCM (UMR CNRS 5250), Université Grenoble-Alpes , CS 40700, 38058 Grenoble, France.
authors: Gisèle
authors: G
authors: Gellon
authors: DCM (UMR CNRS 5250), Université Grenoble-Alpes , CS 40700, 38058 Grenoble, France.
authors: Béatrice
authors: B
authors: Gennaro
authors: DCM (UMR CNRS 5250), Université Grenoble-Alpes , CS 40700, 38058 Grenoble, France.
authors: Christian
authors: C
authors: Philouze
authors: Institut für Anorganische Chemie, Georg-August Universität Göttingen , Tammannstraße 4, 37077 Göttingen, Germany.
authors: Franc
authors: F
authors: Meyer
authors: Institut für Anorganische Chemie, Georg-August Universität Göttingen , Tammannstraße 4, 37077 Göttingen, Germany.
authors: Serhiy
authors: S
authors: Demeshko
authors: CEMCA (UMR CNRS 6521), Université de Bretagne Occidentale , 6 avenue Le Gorgeu, 29238 Brest, France.
authors: Yves
authors: Y
authors: Le Mest
authors: Aix-Marseille, CNRS, Centrale Marseille, ISM2 UMR 7313, 13397 Marseille, France.
authors: Marius
authors: M
authors: Réglier
authors: DCM (UMR CNRS 5250), Université Grenoble-Alpes , CS 40700, 38058 Grenoble, France.
authors: Hélène
authors: H
authors: Jamet
authors: CEMCA (UMR CNRS 6521), Université de Bretagne Occidentale , 6 avenue Le Gorgeu, 29238 Brest, France.
authors: Nicolas
authors: N
authors: Le Poul
authors: DCM (UMR CNRS 5250), Université Grenoble-Alpes , CS 40700, 38058 Grenoble, France.
authors: Catherine
authors: C
authors: Belle