title: Microencapsulation of advanced solvents for carbon capture.
abstract: Purpose-designed, water-lean solvents have been developed to improve the energy efficiency of CO2capture from power plants, including CO2-binding organic liquids (CO2BOLs) and ionic liquids (ILs). Many of these solvents are highly viscous or change phases, posing challenges for conventional process equipment. Such problems can be overcome by encapsulation. Micro-Encapsulated CO2Sorbents (MECS) consist of a CO2-absorbing solvent or slurry encased in spherical, CO2-permeable polymer shells. The resulting capsules have diameters in the range of 100-600 μm, greatly increasing the surface area and CO2absorption rate of the encapsulated solvent. Encapsulating these new solvents requires careful selection of shell materials and fabrication techniques. We find several common classes of polymers are not compatible with MECS production, but we develop two custom formulations, a silicone and an acrylate, that show promise for encapsulating water-lean solvents. We make the first demonstration of an encapsulated IL for CO2capture. The rate of CO2absorption is enhanced by a factor of 3.5 compared to a liquid film, a value that can be improved by further development of shell materials and fabrication techniques.
authors: Lawrence Livermore National Laboratory, Livermore, CA, USA. stolaroff1@llnl.gov.
authors: Joshuah K
authors: JK
authors: Stolaroff
authors: Lawrence Livermore National Laboratory, Livermore, CA, USA. stolaroff1@llnl.gov.
authors: Congwang
authors: C
authors: Ye
authors: Lawrence Livermore National Laboratory, Livermore, CA, USA. stolaroff1@llnl.gov.
authors: James S
authors: JS
authors: Oakdale
authors: Lawrence Livermore National Laboratory, Livermore, CA, USA. stolaroff1@llnl.gov.
authors: Sarah E
authors: SE
authors: Baker
authors: Lawrence Livermore National Laboratory, Livermore, CA, USA. stolaroff1@llnl.gov.
authors: William L
authors: WL
authors: Smith
authors: Lawrence Livermore National Laboratory, Livermore, CA, USA. stolaroff1@llnl.gov.
authors: Du T
authors: DT
authors: Nguyen
authors: Lawrence Livermore National Laboratory, Livermore, CA, USA. stolaroff1@llnl.gov.
authors: Christopher M
authors: CM
authors: Spadaccini
authors: Lawrence Livermore National Laboratory, Livermore, CA, USA. stolaroff1@llnl.gov.
authors: Roger D
authors: RD
authors: Aines