title: A Novel Fluorescent Probe for the Highly Selective and Sensitive Detection of Palladium in Aqueous Medium.
abstract: Based on the Pd0-catalyzed Tsuji-Trost allylic oxidative insertion reaction, we developed a fluorescent probe PdL1 for sensing Pd0. As expected, probe PdL1 exhibited high selectivity and excellent sensitivity in both absorbance and fluorescence detection of Pd0in CH3CH2OH/PBS (10 mM, pH = 7.4, 6:4, v/v) solution. The detection limit was calculated to be as low as 15 nM, which can meet the selective requirements for practical application.
authors: Department of Fundamental Courses, Henan University of Animal Husbandry and Economy, Zhengzhou, 450046, China. mazhiwei1986@126.com.
authors: Zhiwei
authors: Z
authors: Ma
authors: Integarated Chinese and Western Medicine Postdoctoral Research Station, Medical College, Jinan University, Guangzhou, 510632, China.
authors: Xiao
authors: X
authors: Wang
authors: Henan Furen Phamaceutical Technology Development Limited Company, Zhengzhou, 450002, China.
authors: Yanling
authors: Y
authors: Sun
authors: Department of Fundamental Courses, Henan University of Animal Husbandry and Economy, Zhengzhou, 450046, China.
authors: Juntao
authors: J
authors: Liu
authors: Department of Fundamental Courses, Henan University of Animal Husbandry and Economy, Zhengzhou, 450046, China.
authors: Yan
authors: Y
authors: Tong
authors: Department of Fundamental Courses, Henan University of Animal Husbandry and Economy, Zhengzhou, 450046, China.
authors: Zhijing
authors: Z
authors: Liu
keywords: Fluorescence; NBD; Pd0; Tsuji-Trost reaction