title: β-Phase Morphology in Ordered Poly(9,9-dioctylfluorene) Nanopillars by Template Wetting Method.
abstract: An efficient method based in template wetting is applied for fabrication of ordered Poly(9,9-dioctylfluorene) (PFO) nanopillars with β-phase morphology. In this process, nanoporous alumina obtained by anodization process is used as template. PFO nanostructures are prepared under ambient conditions via infiltration of the polymeric solution into the pores of the alumina with an average pore diameter of 225 nm and a pore depth of 500 nm. The geometric features of the resulting structures are characterized with environmental scanning electron microscopy (ESEM), luminescence fluorimeter (PL) and micro μ-X-ray diffractometer (μ-XRD). The characterization demonstrates the β-phase of the PFO in the nanopillars fabricated. Furthermore, the PFO nanopillars are characterized by Raman spectroscopy to study the polymer conformation. These ordered nanostructures can be used in optoelectronic applications such as polymer light-emitting diodes, sensors and organic solar cells.
authors: Departament d'Enginyeria Electrónica, Eléctrica i Automática, Universitat Rovira i Virgili, Avda. Països Catalans 26, 43007, Tarragona, Spain.
authors: R
authors: R
authors: Palacios
authors: Departament d'Enginyeria Electrónica, Eléctrica i Automática, Universitat Rovira i Virgili, Avda. Països Catalans 26, 43007, Tarragona, Spain.
authors: P
authors: P
authors: Formentin
authors: Institute of Chemical Research of Catalonia (ICIQ), Avda. Països Catalans 16, 43007, Tarragona, Spain.
authors: E
authors: E
authors: Martinez-Ferrero
authors: Departament d'Enginyeria Electrónica, Eléctrica i Automática, Universitat Rovira i Virgili, Avda. Països Catalans 26, 43007, Tarragona, Spain.
authors: J
authors: J
authors: Pallarès
authors: Departament d'Enginyeria Electrónica, Eléctrica i Automática, Universitat Rovira i Virgili, Avda. Països Catalans 26, 43007, Tarragona, Spain. lluis.marsal@urv.cat.
authors: L F
authors: LF
authors: Marsal
keywords: Luminescence; Nanopillars; Nanoporous alumina; PFO; Raman spectroscopy; Template wetting