title: Stereoselective synthesis of vinylsilanes via copper-catalyzed silylation of alkenes with silanes.
abstract: An efficient and stereoselective synthesis of vinylsilanes via copper-catalyzed direct silylation of alkenes with silanes was developed. This study offers a new and expedient strategy for the synthesis of synthetically useful alkenyl organosilicon compounds in satisfactory yields and may provide a low-cost and environmentally benign alternative to currently employed precious metal systems for alkene silylation. Moreover, the transformation is proposed to proceed via a radical process and exhibits a broad substrate scope and good functional group tolerance.
authors: Chemical Engineering College, Nanjing University of Science and Technology, 200 Xiao Ling Wei, Nanjing, Jiangsu 210094, People's Republic of China. c.cai@njust.edu.cn.
authors: Jian
authors: J
authors: Gu
authors: Chemical Engineering College, Nanjing University of Science and Technology, 200 Xiao Ling Wei, Nanjing, Jiangsu 210094, People's Republic of China. c.cai@njust.edu.cn.
authors: Chun
authors: C
authors: Cai