title: Visualization of anisotropic-isotropic phase transformation dynamics in battery electrode particles.
abstract: Anisotropy, or alternatively, isotropy of phase transformations extensively exist in a number of solid-state materials, with performance depending on the three-dimensional transformation features. Fundamental insights into internal chemical phase evolution allow manipulating materials with desired functionalities, and can be developed via real-time multi-dimensional imaging methods. Here, we report a five-dimensional imaging method to track phase transformation as a function of charging time in individual lithium iron phosphate battery cathode particles during delithiation. The electrochemically driven phase transformation is initially anisotropic with a preferred boundary migration direction, but becomes isotropic as delithiation proceeds further. We also observe the expected two-phase coexistence throughout the entire charging process. We expect this five-dimensional imaging method to be broadly applicable to problems in energy, materials, environmental and life sciences.
authors: Photon Science, National Synchrotron Light Source II, Brookhaven National Laboratory, Upton, New York 11973, USA.
authors: Jiajun
authors: J
authors: Wang
authors: Photon Science, National Synchrotron Light Source II, Brookhaven National Laboratory, Upton, New York 11973, USA.
authors: Yu-Chen
authors: YC
authors: Karen Chen-Wiegart
authors: Photon Science, National Synchrotron Light Source II, Brookhaven National Laboratory, Upton, New York 11973, USA.
authors: Christopher
authors: C
authors: Eng
authors: Photon Science, National Synchrotron Light Source II, Brookhaven National Laboratory, Upton, New York 11973, USA.
authors: Qun
authors: Q
authors: Shen
authors: Photon Science, National Synchrotron Light Source II, Brookhaven National Laboratory, Upton, New York 11973, USA.
authors: Jun
authors: J
authors: Wang