title: Pd@[nBu₄][Br] as a Simple Catalytic System for N-Alkylation Reactions with Alcohols.
abstract: Palladium nanoparticles, simply and briefly generated in commercial and cheap onium salts using supercritical carbon dioxide, have been found to be an effective catalytic system for additive free N-alkylation reaction using alcohols via cascade oxidation/condensation/reduction steps.
authors: CNRS, Université de Bordeaux, ISM, UMR 5255, ISM, 351 cours de la libération, 33405 Talence Cedex, France. mathieu.pucheault@u-bordeaux.fr.
authors: Bastien
authors: B
authors: Cacciuttolo
authors: CNRS, Université de Bordeaux, ICMCB, UPR 9048, ICMCB-CNRS, 87 avenue du Dr Albert Schweitzer, 33608 Pessac Cedex, France. aymonier@icmcb-bordeaux.cnrs.fr.
authors: Oana
authors: O
authors: Pascu
authors: CNRS, Université de Bordeaux, ICMCB, UPR 9048, ICMCB-CNRS, 87 avenue du Dr Albert Schweitzer, 33608 Pessac Cedex, France. aymonier@icmcb-bordeaux.cnrs.fr.
authors: Cyril
authors: C
authors: Aymonier
authors: CNRS, Université de Bordeaux, ISM, UMR 5255, ISM, 351 cours de la libération, 33405 Talence Cedex, France. mathieu.pucheault@u-bordeaux.fr.
authors: Mathieu
authors: M
authors: Pucheault
mesh_terms: D000438:Alcohols / Q000737:chemistry*; D000478:Alkylation; D000588:Amines / Q000737:chemistry; D002245:Carbon Dioxide / Q000737:chemistry; D002384:Catalysis; D053758:Nanoparticles / Q000737:chemistry / Q000648:ultrastructure; D009861:Onium Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry*
chemical_list: D000438:Alcohols; D000588:Amines; D009861:Onium Compounds; D002245:Carbon Dioxide; D010165:Palladium
keywords: N-alkylation; nanoparticle; onium salt