title: KGM-based magnetic carbon aerogels matrix for the uptake of methylene blue and methyl orange.
abstract: In this study, the preparation of magnetic Fe and Mn oxides (Mag-FMBO) loaded carbon aerogels (CA) based on konjac glucomannan (KGM) and their performance for dyes adsorption were investigated. The prepared magnetic carbon aerogels (Mag-CA) materials were characterized by various methods, including BET surface area analysis, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and vibrating sample magnetometer (VSM). What's more, the Mag-CA materials were used as adsorbents to remove dyes [anionic methyl orange (MO) and cationic methylene blue (MB)] from aqueous solutions. The results showed that Mag-CA had an excellent adsorption performance towards MO and MB. The adsorption equilibrium data of both MO and MB can be well described by Langmuir model. The maximum MO and MB uptake capacity of Mag-CA reached 7.42mgg-1and 9.37mgg-1according to Langmuir isotherm at 303K, respectively. Thermodynamic parameters such as ΔG, ΔH and ΔS were estimated to understand the adsorption mechanism of MO and MB. The adsorption processes of MO and MB could be well described by the pseudo-second-order model. Moreover, Mag-CA with dyes (MO or MB) were successfully regenerated by ethanol and then easily separated from aqueous solution by applying magnetic field.
authors: College of Food Science and Technology, Huazhong Agriculture University, Wuhan, 430070, China.
authors: Shuxin
authors: S
authors: Ye
authors: College of Food Science and Technology, Huazhong Agriculture University, Wuhan, 430070, China.
authors: Weiping
authors: W
authors: Jin
authors: College of Food Science and Technology, Huazhong Agriculture University, Wuhan, 430070, China.
authors: Qing
authors: Q
authors: Huang
authors: College of Food Science and Technology, Huazhong Agriculture University, Wuhan, 430070, China.
authors: Ying
authors: Y
authors: Hu
authors: College of Food Science and Technology, Huazhong Agriculture University, Wuhan, 430070, China; Key Laboratory of Environment Correlative Dietology (Huazhong Agricultural University), Ministry of Education, China.
authors: Yan
authors: Y
authors: Li
authors: College of Food Science and Technology, Huazhong Agriculture University, Wuhan, 430070, China; Hubei Collaborative Innovation Centre for Industrial Fermentation, Hubei University of Technology, Wuhan 430068, China; Key Laboratory of Environment Correlative Dietology (Huazhong Agricultural University), Ministry of Education, China. Electronic address: libinfood@mail.hzau.edu.cn.
authors: Bin
authors: B
authors: Li
mesh_terms: D000327:Adsorption; D001391:Azo Compounds / Q000302:isolation & purification*; D005290:Ferric Compounds / Q000737:chemistry; D005782:Gels; D006801:Humans; D007700:Kinetics; D060526:Magnetic Fields; D059346:Magnets; D017895:Manganese Compounds / Q000737:chemistry; D008351:Mannans / Q000737:chemistry*; D008751:Methylene Blue / Q000302:isolation & purification*; D037742:Nanotubes, Carbon / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry; D013816:Thermodynamics; D062065:Wastewater / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods*
chemical_list: D001391:Azo Compounds; D005290:Ferric Compounds; D005782:Gels; D017895:Manganese Compounds; D008351:Mannans; D008751:Methylene Blue; D037742:Nanotubes, Carbon; D010087:Oxides; D062065:Wastewater; D014874:Water Pollutants, Chemical; C000499:ferric oxide; C022901:(1-6)-alpha-glucomannan; C027424:manganese oxide; C100258:methyl orange
keywords: Dyes adsorption; KGM; Magnetic carbon aerogels