title: Intramolecular Hgπ interactions of d-character with non-bridging atoms in mercury-aryl complexes.
abstract: Mercury 5d-orbitals are involved in intramolecular π-interactions with carbon and sulfur nearest and next-nearest neighbors in mercury-aryl complexes. This unexpected character of the electron cloud of mercury was revealed by high energy-resolution XANES spectroscopy readily interpreted in terms of a final-state local (l,m)-projected density of states (DOS).
authors.affiliation: ISTerre, Université Grenoble Alpes, CNRS, CS 40700, 38058 Grenoble, France. anthony.lannes@gmail.com alain.manceau@univ-grenoble-alpes.fr.
authors.forename: A
authors.initials: A
authors.lastname: Lannes
authors.forename: A
authors.initials: A
authors.lastname: Manceau
authors.forename: M
authors.initials: M
authors.lastname: Rovezzi
authors.forename: P
authors.initials: P
authors.lastname: Glatzel
authors.forename: Y
authors.initials: Y
authors.lastname: Joly
authors.forename: I
authors.initials: I
authors.lastname: Gautier-Luneau