title: Geographical discrimination of extra-virgin olive oils from the Italian coasts by combining stable isotope data and carotenoid content within a multivariate analysis.
abstract: We have determined the isotopic composition and the carotenoid contents of 38 extra-virgin olive oils (EVOOs) from seven regions along the Italian coasts, by means of isotope ratio mass spectrometry (IRMS) and resonant Raman spectroscopy (RRS), respectively. The application of linear discriminant analysis to our overall results demonstrated the combination of isotope and carotenoid data is a promising method to discriminate EVOOs from production sites that are impacted by similar geographical and climatic parameters. In particular, this dual approach allowed correct classification of 82% EVOO samples, while separate IRMS and RRS investigations were able to discriminate only samples from Sicily and Latium, respectively.
authors.affiliation: Istituto di Biologia Agroambientale e Forestale, Consiglio Nazionale delle Ricerche, 05010 Porano (TR), Italy. Electronic address: silvia.portarena@ibaf.cnr.it.
authors.forename: S
authors.initials: S
authors.lastname: Portarena
authors.affiliation: Istituto di Biologia Agroambientale e Forestale, Consiglio Nazionale delle Ricerche, 05010 Porano (TR), Italy.
authors.forename: C
authors.initials: C
authors.lastname: Baldacchini
authors.affiliation: Istituto di Biologia Agroambientale e Forestale, Consiglio Nazionale delle Ricerche, 05010 Porano (TR), Italy; Dipartimento di Scienze del Sistema Terra e Tecnologie per l'Ambiente, Consiglio Nazionale delle Ricerche, 00185 Roma, Italy.
authors.forename: E
authors.initials: E
authors.lastname: Brugnoli
mesh_terms: D002247:Carbon Isotopes / Q000032:analysis*; D002338:Carotenoids / Q000032:analysis*; D007558:Italy; D015999:Multivariate Analysis; D000069463:Olive Oil / Q000737:chemistry*; D010938:Plant Oils / Q000737:chemistry*; D013059:Spectrum Analysis, Raman / Q000379:methods*
chemical_list: D002247:Carbon Isotopes; D000069463:Olive Oil; D010938:Plant Oils; D002338:Carotenoids
keywords: Carotenoid content; Chemometrics; Geographical origin; Isotope ratio mass spectrometry; Olive oil; Raman spectroscopy