title: Tailor-made Covalent Organic-Inorganic Polyoxometalate Hybrids: Versatile Platforms for the Elaboration of Functional Molecular Architectures.
abstract: Post-functionalization of organically modified polyoxometalates (POMs) is a powerful synthetic tool to devise functional building blocks for the rational elaboration of POM-based molecular materials. In this personal account we focus on iodoaryl-terminated POM platforms, describe reliable routes to the synthesis of covalent organic-inorganic POM-based hybrids and their integration into advanced molecular architectures or multi-scale assemblies as well as their immobilization onto surfaces. Valorisation of the remarkable redox properties of POMs in the fields of artificial synthesis and molecular electronic is especially considered.
authors.affiliation: Institut Parisien de Chimie Moléculaire UMR CNRS 8232, Sorbonne Universités, UPMC-Paris06, 4 Place Jussieu, F-75005, Paris, France.
authors.forename: Guillaume
authors.initials: G
authors.lastname: Izzet
authors.affiliation: Institut Parisien de Chimie Moléculaire UMR CNRS 8232, Sorbonne Universités, UPMC-Paris06, 4 Place Jussieu, F-75005, Paris, France.
authors.forename: Florence
authors.initials: F
authors.lastname: Volatron
authors.affiliation: Institut Parisien de Chimie Moléculaire UMR CNRS 8232, Sorbonne Universités, UPMC-Paris06, 4 Place Jussieu, F-75005, Paris, France.
authors.forename: Anna
authors.initials: A
authors.lastname: Proust
keywords: artificial photosynthesis; modified electrodes; organic-inorganic hybrids; palladium cross-coupling; polyoxometalates