title: Multi-stimuli Responsive Supramolecular Structures Based on Azobenzene Surfactant-Encapsulated Polyoxometalate.
abstract: Multi-stimuli responsive materials have attracted intense attention as extensive application prospect in many fields, yet achievement of multi-stimuli responsiveness remains a challenge. Herein, we report a tri-stimuli responsive supramolecular structure fabricated by a cationic surfactant, 4-ethyl-4'-(trimethylaminohexyloxy) azobenzene bromide (ETAB), and anionic Eu-containing polyoxometalates (Eu-POM), based on an ionic self-assembly (ISA) strategy. Following different responsive mechanisms, the resultant ETAB/Eu-POM supramolecular materials are responsive to UV light, pH, and Cu(2+), respectively. The response to UV irradiation is based on the configuration change of azobenzene molecules. The response to H(+) can be attributed to the formation of a hydrogen bond W-O···H···O-H among Eu-POM, H(+), and H2O, which blocks the energy transfer pathway from O → W, while the coordination interaction between Cu(2+) and Oc (bridged oxygen of two octahedra sharing an edge in the Eu-POM molecule) causes the response to Cu(2+). The multi-stimuli responsive characteristics for the ETAB/Eu-POM supramolecular structures maybe provide a potential application in ultraviolet detection, optical storage devices, and chemical substance sensors, etc.
authors.affiliation: Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education , Jinan 250100, P.R. China.
authors.forename: Yongxian
authors.initials: Y
authors.lastname: Guo
authors.affiliation: Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education , Jinan 250100, P.R. China.
authors.forename: Yanjun
authors.initials: Y
authors.lastname: Gong
authors.affiliation: China Ionic Liquid Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences , Dalian 116023, P.R. China.
authors.forename: Yan'an
authors.initials: Y
authors.lastname: Gao
authors.affiliation: Petroleum Engineering Technology Research Institute of Shengli Oilfield, Sinopec , Dongying 257000, P.R. China.
authors.forename: Jianhong
authors.initials: J
authors.lastname: Xiao
authors.affiliation: Petroleum Engineering Technology Research Institute of Shengli Oilfield, Sinopec , Dongying 257000, P.R. China.
authors.forename: Tao
authors.initials: T
authors.lastname: Wang
authors.affiliation: Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education , Jinan 250100, P.R. China.
authors.forename: Li
authors.initials: L
authors.lastname: Yu