title: In Situ Synthesis of Metal Nanoparticle Embedded Hybrid Soft Nanomaterials.
abstract: The allure of integrating the tunable properties of soft nanomaterials with the unique optical and electronic properties of metal nanoparticles has led to the development of organic-inorganic hybrid nanomaterials. A promising method for the synthesis of such organic-inorganic hybrid nanomaterials is afforded by the in situ generation of metal nanoparticles within a host organic template. Due to their tunable surface morphology and porosity, soft organic materials such as gels, liquid crystals, and polymers that are derived from various synthetic or natural compounds can act as templates for the synthesis of metal nanoparticles of different shapes and sizes. This method provides stabilization to the metal nanoparticles by the organic soft material and advantageously precludes the use of external reducing or capping agents in many instances. In this Account, we exemplify the green chemistry approach for synthesizing these materials, both in the choice of gelators as soft material frameworks and in the reduction mechanisms that generate the metal nanoparticles. Established herein is the core design principle centered on conceiving multifaceted amphiphilic soft materials that possess the ability to self-assemble and reduce metal ions into nanoparticles. Furthermore, these soft materials stabilize the in situ generated metal nanoparticles and retain their self-assembly ability to generate metal nanoparticle embedded homogeneous organic-inorganic hybrid materials. We discuss a remarkable example of vegetable-based drying oils as host templates for metal ions, resulting in the synthesis of novel hybrid nanomaterials. The synthesis of metal nanoparticles via polymers and self-assembled materials fabricated via cardanol (a bioorganic monomer derived from cashew nut shell liquid) are also explored in this Account. The organic-inorganic hybrid structures were characterized by several techniques such as UV-visible spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Utilization of silver nanoparticle-based hybrid nanomaterials as an antimicrobial material is another illustration of the advantage of hybrid nanomaterials. We envision that the results summarized in this Account will help the scientific community to design and develop diverse organic-inorganic hybrid materials using environmentally benign methods and that these materials will yield advanced properties that have multifaceted applications in various research fields.
authors.affiliation: Department of Chemistry and Center for Discovery and Innovation, The City College of New York , 85 St. Nicholas Terrace, New York, New York 10031, United States.
authors.forename: Kizhmuri P
authors.initials: KP
authors.lastname: Divya
authors.affiliation: Department of Chemistry and Center for Discovery and Innovation, The City College of New York , 85 St. Nicholas Terrace, New York, New York 10031, United States.|Ph.D. Program in Chemistry, The Graduate Center of The City University of New York , New York, New York 10016, United States.
authors.forename: Mikhail
authors.initials: M
authors.lastname: Miroshnikov
authors.affiliation: Institute for Stem Cell Biology and Regenerative Medicine (inStem) , Bellary Road, Bangalore 560065, India.
authors.forename: Debjit
authors.initials: D
authors.lastname: Dutta
authors.affiliation: Institute for Stem Cell Biology and Regenerative Medicine (inStem) , Bellary Road, Bangalore 560065, India.
authors.forename: Praveen Kumar
authors.initials: PK
authors.lastname: Vemula
authors.affiliation: Department of Materials Science and NanoEngineering, Rice University , Houston, Texas 77005, United States.
authors.forename: Pulickel M
authors.initials: PM
authors.lastname: Ajayan
authors.affiliation: Department of Chemistry and Center for Discovery and Innovation, The City College of New York , 85 St. Nicholas Terrace, New York, New York 10031, United States.|Ph.D. Program in Chemistry, The Graduate Center of The City University of New York , New York, New York 10016, United States.
authors.forename: George
authors.initials: G
authors.lastname: John