title: MoS2 Nanosheets Vertically Grown on Graphene Sheets for Lithium-Ion Battery Anodes.
abstract: A designed nanostructure with MoS2 nanosheets (NSs) perpendicularly grown on graphene sheets (MoS2/G) is achieved by a facile and scalable hydrothermal method, which involves adsorption of Mo7O24(6-) on a graphene oxide (GO) surface, due to the electrostatic attraction, followed by in situ growth of MoS2. These results give an explicit proof that the presence of oxygen-containing groups and pH of the solution are crucial factors enabling formation of a lamellar structure with MoS2 NSs uniformly decorated on graphene sheets. The direct coupling of edge Mo of MoS2 with the oxygen from functional groups on GO (C-O-Mo bond) is proposed. The interfacial interaction of the C-O-Mo bonds can enhance electron transport rate and structural stability of the MoS2/G electrode, which is beneficial for the improvement of rate performance and long cycle life. The graphene sheets improve the electrical conductivity of the composite and, at the same time, act not only as a substrate to disperse active MoS2 NSs homogeneously but also as a buffer to accommodate the volume changes during cycling. As an anode material for lithium-ion batteries, the manufactured MoS2/G electrode manifests a stable cycling performance (1077 mAh g(-1) at 100 mA g(-1) after 150 cycles), excellent rate capability, and a long cycle life (907 mAh g(-1) at 1000 mA g(-1) after 400 cycles).
authors.forename: Yongqiang
authors.initials: Y
authors.lastname: Teng
authors.forename: Hailei
authors.initials: H
authors.lastname: Zhao
authors.forename: Zijia
authors.initials: Z
authors.lastname: Zhang
authors.forename: Zhaolin
authors.initials: Z
authors.lastname: Li
authors.forename: Qing
authors.initials: Q
authors.lastname: Xia
authors.forename: Yang
authors.initials: Y
authors.lastname: Zhang
authors.forename: Lina
authors.initials: L
authors.lastname: Zhao
authors.forename: Xuefei
authors.initials: X
authors.lastname: Du
authors.forename: Zhihong
authors.initials: Z
authors.lastname: Du
authors.forename: Pengpeng
authors.initials: P
authors.lastname: Lv
authors.affiliation: Faculty of Energy and Fuels, Department of Hydrogen Energy, AGH University of Science and Technology , al. A. Mickiewicza 30, 30-059 Krakow, Poland.
authors.forename: Konrad
authors.initials: K
authors.lastname: Świerczek
keywords: C−O−Mo bond; Li-ion batteries; long cycle life; molybdenum disulfide; oxygen-containing groups on GO