title: Development of a suitcase time-of-flight mass spectrometer for in situ fault diagnosis of SF6 -insulated switchgear by detection of decomposition products.
abstract: Sulfur hexafluoride (SF6 ) gas-insulated switchgear (GIS) is an essential piece of electrical equipment in a substation, and the concentration of the SF6 decomposition products are directly relevant to the security and reliability of the substation. The detection of SF6 decomposition products can be used to diagnosis the condition of the GIS.
  
  
  
  The decomposition products of SO2 , SO2 F2 , and SOF2 were selected as indicators for the diagnosis. A suitcase time-of-flight mass spectrometer (TOFMS) was designed to perform online GIS failure analysis. An RF VUV lamp was used as the photoelectron ion source; the sampling inlet, ion einzel lens, and vacuum system were well designed to improve the performance.
  
  
  
  The limit of detection (LOD) of SO2 and SO2 F2 within 200 s was 1 ppm, and the sensitivity was estimated to be at least 10-fold more sensitive than the previous design. The high linearity of SO2 , SO2 F2 in the range of 5-100 ppm has excellent linear correlation coefficient R(2) at 0.9951 and 0.9889, respectively.
  
  
  
  The suitcase TOFMS using orthogonal acceleration and reflecting mass analyzer was developed. It has the size of 663 × 496 × 338 mm and a weight of 34 kg including the battery and consumes only 70 W. The suitcase TOFMS was applied to analyze real decomposition products of SF6 inside a GIS and succeeded in finding out the hidden dangers. The suitcase TOFMS has wide application prospects for establishing an early-warning for the failure of the GIS. Copyright © 2016 John Wiley & Sons, Ltd.
authors.affiliation: Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China.
authors.forename: Keyong
authors.initials: K
authors.lastname: Hou
authors.affiliation: Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China.
authors.forename: Jinxu
authors.initials: J
authors.lastname: Li
authors.affiliation: Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China.
authors.forename: Tuanshuai
authors.initials: T
authors.lastname: Qu
authors.affiliation: Electric Power Research Institute, Guangxi Power Grid Corporation, Nanning, 530023, China.
authors.forename: Bin
authors.initials: B
authors.lastname: Tang
authors.affiliation: Electric Power Research Institute, Guangxi Power Grid Corporation, Nanning, 530023, China.
authors.forename: Liping
authors.initials: L
authors.lastname: Zhu
authors.affiliation: Electric Power Research Institute, Guangxi Power Grid Corporation, Nanning, 530023, China.
authors.forename: Yunguang
authors.initials: Y
authors.lastname: Huang
authors.affiliation: Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China.
authors.forename: Haiyang
authors.initials: H
authors.lastname: Li