title: Enantioselective synthesis of quaternary α-aminophosphonates by Pd-catalyzed arylation of cyclic α-ketiminophosphonates with arylboronic acids.
abstract: A highly enantioselective addition of arylboronic acids to cyclic α-ketiminophosphonates is reported using a chiral palladium phosphinooxazoline catalyst, providing an efficient and facile route to quaternary α-aminophosphonates in high yields and up to 99.9% enantioselectivity.
authors.affiliation: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China. ygzhou@dicp.ac.cn.
authors.forename: Zhong
authors.initials: Z
authors.lastname: Yan
authors.forename: Bo
authors.initials: B
authors.lastname: Wu
authors.forename: Xiang
authors.initials: X
authors.lastname: Gao
authors.forename: Yong-Gui
authors.initials: YG
authors.lastname: Zhou