title: MoS2 Nanosheets Functionalized Composite Mixed Matrix Membrane for Enhanced CO2 Capture via Surface Drop-Coating Method.
abstract: Molybdenum disulfide (MoS2) is a graphene-like two-dimensional inorganic material, which has been used for the first time as an inorganic nanofiller to prepare a composite mixed matrix membrane to separate CO2 and N2. Polysulfone (PSf) was used as a support substrate and poly(dimethylsiloxane) (PDMS) was used as the gutter layer. The selective layer was prepared by mixing a CO2-philic copolymer Pebax 1657 with MoS2 nanosheets to enhance CO2 permeance. In addition, a simple drop-coating and evaporation method was developed to prepare the selective layer. Both permeability and selectivity of the MoS2-Pebax membrane have exceeded the pristine Pebax membrane. The permeability and selectivity reached to the maximum values of 64 Barrer and 93, respectively, at 0.15 wt % MoS2 nanosheets loadings. This result has been on the Robeson's upper bound line. The membrane also showed higher stability. The separation mechanism of the membrane is based on the well-known solution-diffusion mechanism. In addition, the stronger adsorption energy of MoS2 nanosheets to CO2 than N2 also provides the enhancement of gas selectivity.
authors.affiliation: School of Chemical Engineering and Energy, Zhengzhou University , Zhengzhou 450001, P. R. China.
authors.forename: Yijia
authors.initials: Y
authors.lastname: Shen
authors.affiliation: School of Civil Engineering and Communication, North China University of Water Resources and Electric Power , Zhengzhou 450045, P. R. China.
authors.forename: Huixian
authors.initials: H
authors.lastname: Wang
authors.affiliation: School of Chemical Engineering and Energy, Zhengzhou University , Zhengzhou 450001, P. R. China.
authors.forename: Xiang
authors.initials: X
authors.lastname: Zhang
authors.affiliation: School of Chemical Engineering and Energy, Zhengzhou University , Zhengzhou 450001, P. R. China.
authors.forename: Yatao
authors.initials: Y
authors.lastname: Zhang
keywords: CO2 capture; MoS2 nanosheets; composite mixed matrix membrane; drop-coating method; solution-diffusion mechanism