title: Iminophenyl Oxazolinylphenylamine for Enantioselective Cobalt-Catalyzed Hydrosilylation of Aryl Ketones.
abstract: A new family of chiral iminophenyl oxazolinylphenylamines (IPOPA) was designed and synthesized through three steps from commercially available starting materials. An efficient cobalt-catalyzed asymmetric hydrosilylation of simple ketones with a low catalyst loading of CoCl2 and IPOPA was developed to afford chiral alcohols in good yields with high enantioselectivities.
authors: Department of Chemistry, Zhejiang University , Hangzhou 310058, China.
authors: Xu
authors: X
authors: Chen
authors: Department of Chemistry, Zhejiang University , Hangzhou 310058, China.
authors: Zhan
authors: Z
authors: Lu