title: Performance Characteristics of Bio-Inspired Metal Nanostructures as Surface-Enhanced Raman Scattered (SERS) Substrates.
abstract: The fabrication of high-performance plasmonic nanomaterials for bio-sensing and trace chemical detection is a field of intense theoretical and experimental research. The use of metal-silicon nanopillar arrays as analytical sensors has been reported with reasonable results in recent years. The use of bio-inspired nanocomposite structures that follow the Fibonacci numerical architecture offers the opportunity to develop nanostructures with theoretically higher and more reproducible plasmonic fields over extended areas. The work presented here describes the nanofabrication process for a series of 40 µm × 40 µm bio-inspired arrays classified as asymmetric fractals (sunflower seeds and romanesco broccoli), bilaterally symmetric (acacia leaves and honeycombs), and radially symmetric (such as orchids and lily flowers) using electron beam lithography. In addition, analytical capabilities were evaluated using surface-enhanced Raman scattering (SERS). The substrate characterization and SERS performance of the developed substrates as the strategies to assess the design performance are presented and discussed.
authors: Department of Chemistry, University of Puerto Rico, Puerto Rico.
authors: Hector I
authors: HI
authors: Areizaga-Martinez
authors: Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, USA.
authors: Ivan
authors: I
authors: Kravchenko
authors: Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, USA.
authors: Nickolay V
authors: NV
authors: Lavrik
authors: Department of Chemistry, University of Tennessee, USA.
authors: Michael J
authors: MJ
authors: Sepaniak
authors: Department of Chemistry, University of Puerto Rico, Puerto Rico.
authors: Samuel P
authors: SP
authors: Hernández-Rivera
authors: Department of Chemistry, University of Puerto Rico, Puerto Rico marco.dejesus@upr.edu.
authors: Marco A
authors: MA
authors: De Jesús
keywords: Bio-inspired nanostructures; Fibonacci sequence; lithography; surface-enhanced spectroscopy