title: Size-Tunable Olive-Like Anatase TiO2Coated with Carbon as Superior Anode for Sodium-Ion Batteries.
abstract: Olive-shaped anatase TiO2with tunable sizes in nanoscale are designed employing polyvinyl alcohol (PVA) as structure directing agents to exert dramatic impacts on structure shaping and size manipulation. Notably, the introduced PVA simultaneously serves as carbon sources, bringing about a homogenous carbon layer with intimate coupling interfaces for boosted electronic conductivity. Constructed from tiny crystalline grains, the uniformly dispersed carbon-coated TiO2nano-olives (TOC) possess subtle loose structure internally for prompt Na+transportations. When utilized for sodium-ion storage, the size effects are increasingly significant at high charge-discharge rates, leading to the much superior rate performances of TOC with the smallest size. Bestowed by the improved Na+adsorption and diffusion kinetics together with the promoted electron transfer, it delivers a high specific capacity of 267 mAh g-1at 0.1 C (33.6 mA g-1) and sustains 110 mAh g-1at a rather high rate of 20 C. Even after cycled at 10 C over 1000 cycles, a considerable capacity of 125 mAh g-1with a retention of 94.6% is still obtained, highlighting its marvelous long-term cyclability and high-rate capabilities.
authors: College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China.
authors: Jun
authors: J
authors: Chen
authors: College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China.
authors: Yan
authors: Y
authors: Zhang
authors: College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China.
authors: Guoqiang
authors: G
authors: Zou
authors: College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China.
authors: Zhaodong
authors: Z
authors: Huang
authors: College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China.
authors: Simin
authors: S
authors: Li
authors: College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China.
authors: Hanxiao
authors: H
authors: Liao
authors: Zhengzhou Zhiqin Science and Technology Co., Ltd, Zhengzhou, 450000, China.
authors: Jufeng
authors: J
authors: Wang
authors: College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China.
authors: Hongshuai
authors: H
authors: Hou
authors: College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China. xji@csu.edu.cn.
authors: Xiaobo
authors: X
authors: Ji
keywords: carbon coatings; high-rate performances; olive-like TiO2; sodium-ion batteries; tunable sizes