title: Pulse electrosynthesis of novel wormlike gadolinium oxide nanostructure and its nanocomposite with conjugated electroactive polymer as a hybrid and high efficient electrode material for energy storage device.
abstract: An effective approach for increasing the life cycle of pure p-type conductive polymers is combining conventional conductive polymers and nanomaterials to fabricate hybrid electrodes. In this paper, Gadolinium oxide (Gd2O3) has first been synthesized using pulse electrochemical approach. Hybrid POAP/Gd2O3films have then been fabricated by POAP electropolymerization in the presence of Gd2O3nanoparticles as active electrodes for electrochemical supercapacitors. Surface and electrochemical analyses have been used for characterization of Gd2O3and POAP/Gd2O3composite films. Different electrochemical methods including galvanostatic charge discharge experiments, cyclic voltammetry and electrochemical impedance spectroscopy have been applied to study the system performance. Specific capacitance, specific energy and specific power of the composite film are calculated 300F·g-1, 41.66Wh·kg-1and 833.22W·kg-1respectively. This work introduces new nanocomposite materials for electrochemical redox capacitors with such advantages as the ease of synthesis, high active surface area and stability in an aqueous electrolyte.
authors: Department of Chemistry, Payame Noor University, Iran.
authors: Hamid Mohammad
authors: HM
authors: Shiri
authors: Department of Chemistry, Faculty of Science, University of Qom, Qom, Iran; Faculty of Chemistry, K. N. Toosi University of Technology, Tehran, Iran. Electronic address: ehsani46847@yahoo.com.
authors: Ali
authors: A
authors: Ehsani
keywords: Capacitor; Impedance; Metal oxide; Nanocomposite