title: Benzyltrifluoromethyl (or Fluoroalkyl) Selenide: Reagent for Electrophilic Trifluoromethyl (or Fluoroalkyl) Selenolation.
abstract: Trifluoromethylseleno substituent (CF3Se) is an emerging group, but its direct introduction onto organic molecules is still quite limited and mainly restricted to nucleophilic methods. Herein, we describe a new approach to easily and safely perform electrophilic trifluoromethylselenolation starting from a simple and easily accessible reagent, namely, benzyltrifluoromethyl selenide. This strategy can be generalized to various fluoroalkylselanyl groups, even functionalized ones.
authors: Institute of Chemistry and Biochemistry (ICBMS-UMR CNRS 5246), Université Lyon 1 , CNRS, 43 Bd du 11 novembre 1918, F-69622 Villeurbanne, France.
authors: Quentin
authors: Q
authors: Glenadel
authors: Institute of Chemistry and Biochemistry (ICBMS-UMR CNRS 5246), Université Lyon 1 , CNRS, 43 Bd du 11 novembre 1918, F-69622 Villeurbanne, France.
authors: Ermal
authors: E
authors: Ismalaj
authors: Institute of Chemistry and Biochemistry (ICBMS-UMR CNRS 5246), Université Lyon 1 , CNRS, 43 Bd du 11 novembre 1918, F-69622 Villeurbanne, France.
authors: Thierry
authors: T
authors: Billard