title: Photoredox Catalysis in Nickel-Catalyzed Cross-Coupling.
abstract: The traditional transition metal-catalyzed cross-coupling reaction, although well suited for C(sp2)-C(sp2) cross-coupling, has proven less amenable toward coupling of C(sp3)-hybridized centers, particularly using functional group tolerant reagents and reaction conditions. The development of photoredox/Ni dual catalytic methods for cross-coupling has opened new vistas for the construction of carbon-carbon bonds at C(sp3)-hybridized centers. In this chapter, a general outline of the features of such processes is detailed.
authors: Instituto de Química-Universidade Federal do Rio Grande do Norte, Natal, RN, Brazil.
authors: Livia N
authors: LN
authors: Cavalcanti
authors: Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, PA, 19104-6323, USA. gmolandr@sas.upenn.edu.
authors: Gary A
authors: GA
authors: Molander
keywords: Alkylsilicates; Alkyltrifluoroborates; Cross-coupling; Photoredox catalysis