title: Gold/Lewis Acid Catalyzed Cycloisomerization/Diastereoselective [3 + 2] Cycloaddition Cascade: Synthesis of Diverse Nitrogen-Containing Spiro Heterocycles.
abstract: A novel early and late transition-metal relay catalysis has been developed by combining a gold-catalyzed cycloisomerization and a Yb(OTf)3-catalyzed diastereoselective [3 + 2] cycloaddition with aziridines in a selective C-C bond cleavage mode. Various biologically significant complex nitrogen-containing spiro heterocycles were rapidly constructed from readily available starting materials under mild conditions.
authors: Key Lab for Colloid and Interface Chemistry of Education Ministry, School of Chemistry and Chemical Engineering, Shandong University , Jinan 250100, China.
authors: Bin
authors: B
authors: Wang
authors: Key Lab for Colloid and Interface Chemistry of Education Ministry, School of Chemistry and Chemical Engineering, Shandong University , Jinan 250100, China.
authors: Man
authors: M
authors: Liang
authors: Key Lab for Colloid and Interface Chemistry of Education Ministry, School of Chemistry and Chemical Engineering, Shandong University , Jinan 250100, China.
authors: Jian
authors: J
authors: Tang
authors: Key Lab for Colloid and Interface Chemistry of Education Ministry, School of Chemistry and Chemical Engineering, Shandong University , Jinan 250100, China.
authors: Yuting
authors: Y
authors: Deng
authors: Key Lab for Colloid and Interface Chemistry of Education Ministry, School of Chemistry and Chemical Engineering, Shandong University , Jinan 250100, China.
authors: Jinhong
authors: J
authors: Zhao
authors: Key Lab for Colloid and Interface Chemistry of Education Ministry, School of Chemistry and Chemical Engineering, Shandong University , Jinan 250100, China.
authors: Hao
authors: H
authors: Sun
authors: Key Lab for Colloid and Interface Chemistry of Education Ministry, School of Chemistry and Chemical Engineering, Shandong University , Jinan 250100, China.
authors: Chen-Ho
authors: CH
authors: Tung
authors: Key Lab for Colloid and Interface Chemistry of Education Ministry, School of Chemistry and Chemical Engineering, Shandong University , Jinan 250100, China.
authors: Jiong
authors: J
authors: Jia
authors: Key Lab for Colloid and Interface Chemistry of Education Ministry, School of Chemistry and Chemical Engineering, Shandong University , Jinan 250100, China.|State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , Shanghai 200032, China.
authors: Zhenghu
authors: Z
authors: Xu