title: Template-Engaged Synthesis of 1D Hierarchical Chainlike LiCoO2 Cathode Materials with Enhanced High-Voltage Lithium Storage Capabilities.
abstract: A novel 1D hierarchical chainlike LiCoO2 organized by flake-shaped primary particles is synthesized via a facile template-engaged strategy by using CoC2O4·2H2O as a self-sacrificial template obtained from a simple coprecipitation method. The resultant LiCoO2 has a well-built hierarchical structure, consisting of secondary micrometer-sized chains and sub-micrometer-sized primary flakes, while these primary LiCoO2 flakes have specifically exposed fast-Li(+)-diffused active {010} facets. Owing to this unique hierarchical structure, the chainlike LiCoO2 serves as a stable cathode material for lithium-ion batteries (LIBs) operated at a high cutoff voltage up to 4.5 V, enabling highly reversible capacity, remarkable rate performance, and long-term cycle life. Specifically, the chainlike LiCoO2 can deliver a reversible discharge capacity as high as 168, 156, 150, and 120 mAh g(-1) under the current density of 0.1, 0.5, 1, and 5 C, respectively, while about 85% retention of the initial capacity can be retained after 200 cycles under 1 C at room temperature. Moreover, the chainlike LiCoO2 also shows an excellent cycling stability at a wide operating temperature range, showing the capacity retention of ∼73% after 200 cycles at 55 °C and of ∼68% after 50 cycles at -10 °C, respectively. The work described here suggests the great potential of the hierarchical chainlike LiCoO2 as high-voltage cathode materials aimed toward developing advanced LIBs with high energy density and power density.
authors: Department of Advanced Energy Materials, College of Materials Science and Engineering, Sichuan University , Chengdu, 610064, P. R. China.|College of Chemistry and Chemical Engineering, Luoyang Normal University , Luoyang, 471934, P. R. China.
authors: Naiteng
authors: N
authors: Wu
authors: Department of Advanced Energy Materials, College of Materials Science and Engineering, Sichuan University , Chengdu, 610064, P. R. China.
authors: Yun
authors: Y
authors: Zhang
authors: Department of Advanced Energy Materials, College of Materials Science and Engineering, Sichuan University , Chengdu, 610064, P. R. China.
authors: Yunhong
authors: Y
authors: Wei
authors: Department of Advanced Energy Materials, College of Materials Science and Engineering, Sichuan University , Chengdu, 610064, P. R. China.
authors: Heng
authors: H
authors: Liu
authors: Department of Advanced Energy Materials, College of Materials Science and Engineering, Sichuan University , Chengdu, 610064, P. R. China.
authors: Hao
authors: H
authors: Wu
keywords: LiCoO2; cathode material; chainlike morphology; hierarchical structure; lithium-ion batteries