title: Decarbonylative Silylation of Esters by Combined Nickel and Copper Catalysis for the Synthesis of Arylsilanes and Heteroarylsilanes.
abstract: An efficient nickel/copper-catalyzed decarbonylative silylation reaction of carboxylic acid esters with silylboranes is described. This reaction provides access to structurally diverse silanes with high efficiency and excellent functional-group tolerance starting from readily available esters.
authors: Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074, Aachen, Germany.
authors: Lin
authors: L
authors: Guo
authors: Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074, Aachen, Germany.
authors: Adisak
authors: A
authors: Chatupheeraphat
authors: Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074, Aachen, Germany. Magnus.Rueping@rwth-aachen.de.|King Abdullah University of Science and Technology (KAUST), KAUST Catalysis Center (KCC), Thuwal, 23955-6900, Saudi Arabia. Magnus.Rueping@rwth-aachen.de.
authors: Magnus
authors: M
authors: Rueping
keywords: copper; decarbonylative cross-couplings; esters; nickel; silylation