Hexanuclear Platinum(II) Thiolate Macrocyclic Host: Charge-Transfer-Driven Inclusion of a Ag(I) Ion Guest.
The inclusion of a Ag(I) ion by a hexanuclear platinum(II) thiolate macrocycle in solution was demonstrated, and the inclusion structure was determined by X-ray crystallography. Unique host-guest intermetallic interactions driven by charge transfer were elucidated by optical absorption spectroscopy and theoretical calculations.
Graduate School of Environmental Science and ‡Faculty of Environmental Earth Science, Hokkaido University , North 10 West 5, Sapporo 060-0810, Japan.
Yukatsu
Y
Shichibu
Graduate School of Environmental Science and ‡Faculty of Environmental Earth Science, Hokkaido University , North 10 West 5, Sapporo 060-0810, Japan.
Keisuke
K
Yoshida
Graduate School of Environmental Science and ‡Faculty of Environmental Earth Science, Hokkaido University , North 10 West 5, Sapporo 060-0810, Japan.
Katsuaki
K
Konishi