Controlled formation of ordered coordination polymeric networks using silsesquioxane building blocks.
In this report, we synthesized ordered coordination polymers using polyhedral oligomeric silsesquioxanes (POSS) as a building block. A POSS with eight carboxylic terminals was coordinated with copper ions at various temperatures, forming polymeric networks. This novel coordination polymer has a long-range ordered structure.
National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan. s-kataoka@aist.go.jp endo-akira@aist.go.jp.
Subhabrata
S
Banerjee
National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan. s-kataoka@aist.go.jp endo-akira@aist.go.jp.
Sho
http://orcid.org/0000-0003-3954-7292
S
Kataoka
National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan. s-kataoka@aist.go.jp endo-akira@aist.go.jp.
Toshikazu
T
Takahashi
National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan. s-kataoka@aist.go.jp endo-akira@aist.go.jp.
Yoshihiro
Y
Kamimura
National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan. s-kataoka@aist.go.jp endo-akira@aist.go.jp.
Kunio
K
Suzuki
National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan. s-kataoka@aist.go.jp endo-akira@aist.go.jp.
Kazuhiko
K
Sato
National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan. s-kataoka@aist.go.jp endo-akira@aist.go.jp.
Akira
A
Endo