Collisions of FeO+with H2and He in a Cryogenic Ion Trap.
The nominal temperature range of cryogenic radio-frequency ion traps has recently been extended down to T=2.3 K. Whereas in situ He tagging of mass-selected ions embedded in dense helium buffer gas is becoming common for recording IR spectra through photofragmentation of small and large ions, much less activity is devoted to the field of cold chemistry, which in this contribution means the two orders of magnitude extending from 300 to below 3 K. The importance of this temperature range for understanding the dynamics of bi- and termolecular reactions is illustrated with new results for the time-honored reaction of FeO+with H2obtained with the cryogenic ion trap ISORI in Prague. The rate coefficient for forming Fe++H2O increases steeply with decreasing temperature. In addition more product channels open up, such as the stabilized reaction-intermediate complexes H2FeO+and Hen-FeO+formed by ternary association with He. For the FeOH++H channel only a minor signal is observed. The rate coefficients provide deep insight into lifetimes, bottlenecks, and barriers impeding almost completely the exothermic, but spin-forbidden, reaction at room temperature. For some of the He-tagged ions, IR predissociation spectra are recorded. A breakthrough is obtaining the first spectrum of [(H2)FeO]+, synthesized and tagged in situ with He. These results pave the way to study the structures of reaction intermediates stabilized in the gas phase by means of collisions with helium.
Department of Organic Chemistry, Faculty of Science, Charles University in Prague, 12843, Prague 2, Czech Republic.|Department of Physics, University of Technology, 09107, Chemnitz, Germany.
Dieter
http://orcid.org/0000-0002-3550-305X
D
Gerlich
Department of Organic Chemistry, Faculty of Science, Charles University in Prague, 12843, Prague 2, Czech Republic.
Juraj
J
Jašík
Department of Organic Chemistry, Faculty of Science, Charles University in Prague, 12843, Prague 2, Czech Republic.
Erik
E
Andris
Department of Organic Chemistry, Faculty of Science, Charles University in Prague, 12843, Prague 2, Czech Republic.
Rafael
R
Navrátil
Department of Organic Chemistry, Faculty of Science, Charles University in Prague, 12843, Prague 2, Czech Republic.
Jana
J
Roithová
IR spectroscopy; cold chemistry; ion traps; ion-molecule reactions; reaction intermediates