Conversion of Dinitrogen to Nitriles at a Multinuclear Titanium Framework.
Activation and functionalization of N2 : A mixed diimide/dinitride tetranuclear titanium complex formed by activation of dinitrogen served as a unique platform for the synthesis of nitriles. Functional groups such as aromatic C-X (X=Cl, Br, I) bonds, nitro groups, and ammonia-sensitive aldehyde and chloromethyl moieties were compatible with the synthetic method.
Advanced Catalysis Research Group, RIKEN, Center for Sustainable Resource Science, 2-1 Hirosawa, Wako, Saitama, 351-0198, Japan.
Murali Mohan
MM
Guru
Advanced Catalysis Research Group, RIKEN, Center for Sustainable Resource Science, 2-1 Hirosawa, Wako, Saitama, 351-0198, Japan.|Organometallic Chemistry Laboratory, RIKEN, 2-1 Hirosawa, Wako, Saitama, 351-0198, Japan.
Takanori
T
Shima
Advanced Catalysis Research Group, RIKEN, Center for Sustainable Resource Science, 2-1 Hirosawa, Wako, Saitama, 351-0198, Japan. houz@riken.jp.|Organometallic Chemistry Laboratory, RIKEN, 2-1 Hirosawa, Wako, Saitama, 351-0198, Japan. houz@riken.jp.
Zhaomin
0000-0003-2841-5120
Z
Hou
dinitrogen activation; hydrides; nitriles; organometallics; titanium