Regeneration of commercial selective catalyst reduction catalysts deactivated by Pb and other inorganic elements.
The regeneration of commercial SCR (Selective Catalyst Reduction) catalysts deactivated by Pb and other elements was studied. The deactivated catalyst samples were prepared by chemical impregnation with mixed solution containing K2SO4, Na2SO4, CaSO4, Pb(NO3)2 and NH4H2PO4. A novel method combining Ethylenediaminetetraacetic acid disodium salt (EDTA-2Na) and H2SO4 solution (viz. catalysts treated by dilute EDTA-2Na and H2SO4 solution in sequence) was used to recover the activity of deactivated samples, and the effect was compared with single H2SO4, oxalic acid, acetic acid, EDTA or HNO3 solutions. The surface structure, acidity and reducibility of samples were characterized by N2 adsorption-desorption, inductively coupled plasma optical emission spectrometer (ICP-OES), scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray fluorescence (XRF), H2-temperature programmed section (H2-TPR), NH3-temperature programmed desorption (NH3-TPD) and in situ DRIFTS. Impurities caused a decrease of specific surface area and surface reducibility, as well as Brønsted acid sites, and therefore led to severe deactivation of the SCR catalyst. The use of an acid solution alone possibly eliminated the impurities on the deactivated catalyst to some extent, and also increased the specific surface area and Brønsted acid sites and promoted the surface reducibility, thus recovered the activity partially. The combination of EDTA-2Na and H2SO4 could remove most of the impurities and improve the activity significantly. The removal of Pb should be an important factor for regeneration. Due to a high removal rate for Pb and other impurities, the combination of EDTA-2Na and H2SO4 solutions provided the best efficiency.
Center for Excellence in Urban Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China; University of Chinese Academy of Sciences, Beijing 100049, China.
Yanke
Y
Yu
Center for Excellence in Urban Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China; University of Chinese Academy of Sciences, Beijing 100049, China.
Jinxiu
J
Wang
Center for Excellence in Urban Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China; University of Chinese Academy of Sciences, Beijing 100049, China. Electronic address: jschen@iue.ac.cn.
Jinsheng
J
Chen
Huadian Zouxian Power Co. Ltd, Shandong 273522, China.
Xinjiang
X
He
Huadian Zouxian Power Co. Ltd, Shandong 273522, China.
Yujing
Y
Wang
Huadian Zouxian Power Co. Ltd, Shandong 273522, China.
Kai
K
Song
CSIRO Materials Science & Engineering, Private Bag 33, Clayton, VIC, 3168, Australia. Electronic address: zongli.xie@csiro.au.
Zongli
Z
Xie
D000327:Adsorption; D007287:Inorganic Chemicals / Q000737:chemistry*; D007854:Lead / Q000737:chemistry*; D008956:Models, Chemical; D010084:Oxidation-Reduction; D013696:Temperature
D007287:Inorganic Chemicals; D007854:Lead
Brønsted acid sites; Pb; Reducibility; Regeneration; SCR catalysts