A recyclable ionic liquid-oxomolybdenum(vi) catalytic system for the oxidative desulfurization of model and real diesel fuel.
The oxidative desulfurization of model and real diesel has been studied using the complex [MoO2Cl2(4,4'-di-tert-butyl-2,2'-bipyridine)] as (pre)catalyst, aq. H2O2 as oxidant, and an ionic liquid as extraction solvent. Under moderate conditions (50 °C) and short reaction times (<3 h), dibenzothiophene, 4-methyldibenzothiophene and 4,6-dimethyldibenzothiophene could be completely removed from the model diesel. The (pre)catalyst 1 was transformed in situ to the active catalyst [MoO(O2)2(di-tBu-bipy)]. By sequentially performing extractive desulfurization and ECODS steps, 76% sulfur removal was achieved for a real diesel (Sinitial = 2300 ppm). For both the model and real diesels, the catalyst/IL phase could be easily recycled and reused with no loss of desulfurization efficiency.
REQUIMTE/LAQV & Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal. igoncalves@ua.pt sbalula@fc.up.pt.
Diana
D
Julião
Ana C
AC
Gomes
Martyn
M
Pillinger
Rita
R
Valença
Jorge C
JC
Ribeiro
Isabel S
IS
Gonçalves
Salete S
SS
Balula