Direct Conversion from Terminal Borylene into Terminal Phosphinidene.
The first terminal manganese phosphinidene complex was quantitatively synthesized from a terminal alkylborylene complex. Its structure and bonding, as well as the reaction mechanism, were investigated through a combination of experimental and computational studies.
Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074, Würzburg, Germany. h.braunschweig@uni-wuerzburg.de.|Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074, Würzburg, Germany. h.braunschweig@uni-wuerzburg.de.
Holger
H
Braunschweig
Department of Chemistry, Division of Natural and Exact Sciences, University of Guanajuato, campus Gto., Noria Alta s/n, 36050, Guanajuato, Mexico.
J Oscar C
JO
Jimenez-Halla
Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.|Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
Krzysztof
K
Radacki
Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
Rong
R
Shang
boranes; borylene complexes; iminophosphines; manganese complexes; phosphinidene complexes