Comments on the article by A. J. Lecloux (J Nanopart Res (2015) 17:447) regarding the use of volume-specific surface area (VSSA) to classify nanomaterials.
In November 2015, an article by A. J. Lecloux was published in this journal (J Nanopart Res, 17:447, 2015). The article focused on the use of volume-specific surface area (VSSA) for the implementation of the European Commission's recommended definition of "nanomaterial". In that paper, VSSA values were calculated for polydisperse particulate materials using a particle number-based averaging method which do not agree with earlier results of VSSA simulations of polydisperse materials reported in 2014 by the Joint Research Centre (JRC) of the European Commission (EC). In this contribution, we explain the difference between traditional view of VSSA which was used by the JRC and the proposed model of Lecloux. Through the use of some simple examples for polydisperse materials, it is demonstrated that the latter produces values which neither correspond to the generally accepted definition of VSSA nor relate to the commonly used experimental methods for determining VSSA using gas adsorption. Lecloux's model therefore does not constitute a basis for practical implementation of the EC's definition of nanomaterial using gas adsorption techniques.
Directorate for Health, Consumers and Reference Materials, Joint Research Centre of the European Commission, Via E. Fermi 2749, 21027 Ispra, VA Italy.
Neil
0000-0002-0643-1739
N
Gibson
Directorate for Health, Consumers and Reference Materials, Joint Research Centre of the European Commission, Via E. Fermi 2749, 21027 Ispra, VA Italy.
Hubert
H
Rauscher
Directorate for Health, Consumers and Reference Materials, Joint Research Centre of the European Commission, Retieseweg 111, 2440 Geel, Belgium.
Gert
G
Roebben
Modelling; Nanomaterial; Nanomaterial definition; Nanoparticles; Specific surface area