Adding value to gasification and co-pyrolysis chars as removal agents of Cr3.
The present work aims to assess the efficiency of chars, obtained from the gasification and co-pyrolysis of rice wastes, as adsorbents of Cr3+from aqueous solution. GC and PC chars, produced in the gasification and co-pyrolysis, respectively, of rice husk and polyethylene were studied. Cr3+removal assays were optimised for the initial pH value, adsorbent mass, contact time and Cr3+initial concentration. GC showed a better performance than PC with about 100% Cr3+removal, due to the pH increase that caused Cr precipitation. Under pH conditions in which the adsorption prevailed (pH<5.5), GC presented the highest uptake capacity (21.1mg Cr3+g-1char) for the following initial conditions: 50mg Cr3+L-1; pH 5; contact time: 24h;L/S ratio: 1000mLg-1. The pseudo-second order kinetic model showed the best adjustment to GC experimental data. Both the first and second order kinetic models fitted well to PC experimental data. The ion exchange was the dominant phenomenon on the Cr3+adsorption by GC sample. Also, this char significantly reduced the ecotoxicity of Cr3+solutions for the bacterium Vibrio fischeri. GC char proved to be an efficient material to remove Cr3+from aqueous solution, without the need for further activation.
LAQV-REQUIMTE, Departamento de Ciências e Tecnologia da Biomassa, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal.
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Godinho
LAQV-REQUIMTE, Departamento de Ciências e Tecnologia da Biomassa, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal.
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Dias
LAQV-REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal.
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Bernardo
LAQV-REQUIMTE, Departamento de Ciências e Tecnologia da Biomassa, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal. Electronic address: ncsn@fct.unl.pt.
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Lapa
LAQV-REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal.
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Fonseca
Unidade de Bioenergia, Laboratório Nacional de Energia e Geologia, Estrada do Paço do Lumiar, Ed. J, 1649-038 Lisboa, Portugal.
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Lopes
Unidade de Bioenergia, Laboratório Nacional de Energia e Geologia, Estrada do Paço do Lumiar, Ed. J, 1649-038 Lisboa, Portugal.
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Pinto
D000327:Adsorption; D018533:Biomass; D002606:Charcoal / Q000737:chemistry*; D002857:Chromium / Q000302:isolation & purification*; D012275:Oryza / Q000737:chemistry*; D020959:Polyethylene / Q000737:chemistry; D012037:Refuse Disposal / Q000379:methods*; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*
D014874:Water Pollutants, Chemical; C540010:biochar; D002857:Chromium; D002606:Charcoal; D020959:Polyethylene
Chars; Co-pyrolysis; Cr(3+) removal; Gasification; Rice wastes