A Kinetic Self-Sorting Approach to Heterocircuit [3]Rotaxanes.
In this proof-of-concept study, an active-template coupling is used to demonstrate a novel kinetic self-sorting process. This process iteratively increases the yield of the target heterocircuit [3]rotaxane product at the expense of other threaded species.
School of Biological and Chemical Sciences, Queen Mary University of London, UK.
Edward A
EA
Neal
School of Chemistry, University of Southampton, Highfield, Southampton, SO17 1BJ, UK. s.goldup@soton.ac.uk.
Stephen M
0000-0003-3781-0464
SM
Goldup
CuAAC; active templates; cycloaddition; rotaxanes; self-sorting