Simultaneous introduction of various palladium active sites into MOF via one-pot synthesis: Pd@[Cu3-xPdx(BTC)2]n.
Simultaneous incorporation of palladium within Pd-Pd and/or Pd-Cu paddlewheels as framework-nodes and Pd nanoparticle (NP) dispersion into MOF have been achieved for the first time via one-pot synthesis. In particular, the framework substitution of Cu(2+) by Pd(2+) as well as the pore loading with PdNPs have been confirmed and characterized by XPS. The obtained solids featuring such multiple Pd-sites show enhanced catalytic activity in the aqueous-phase hydrogenation of p-nitrophenol (PNP) with NaBH4 to p-aminophenol (PAP).
Inorganic Chemistry II-Organometallics and Materials Chemistry, Ruhr-University Bochum, Universitätsstraße 150, 44801 Bochum, Germany.
Wenhua
W
Zhang
Zhihao
Z
Chen
Majd
M
Al-Naji
Penghu
P
Guo
Stefan
S
Cwik
Olesia
O
Halbherr
Yuemin
Y
Wang
Martin
M
Muhler
Nicole
N
Wilde
Roger
R
Gläser
Roland A
RA
Fischer