Classical/Non-classical Polyoxometalate Hybrids.
Two polyanions [SeI V2PdII4WVI14O56H]11-and [SeI V4PdII4WVI28O108H12]12-are the first hybrid polyoxometalates in which classical (Group 5/6 metal based) and non-classical (late transition-metal based) polyoxometalate units are joined. Requiring no supporting groups, this co-condensation of polyoxotungstate and isopolyoxopalladate constituents also provides a logical link between POM-PdIIcoordination complexes and the young subclass of polyoxopalladates. Solid-state, solution, and gas-phase studies suggest interesting specific reactivities for these hybrids and point to several potential derivatives and functionalization strategies.
Jülich-Aachen Research Alliance (JARA-FIT) and Peter Grünberg Institute 6, Forschungszentrum Jülich, 52425, Jülich, Germany. n.izarova@fz-juelich.de.
Natalya V
http://orcid.org/0000-0001-5631-1930
NV
Izarova
Central Institute for Engineering, Electronics and Analytics 3, Forschungszentrum Jülich, 52425, Jülich, Germany.
Beatrix
B
Santiago-Schübel
Central Institute for Engineering, Electronics and Analytics 3, Forschungszentrum Jülich, 52425, Jülich, Germany.
Sabine
S
Willbold
Jülich-Aachen Research Alliance (JARA-FIT) and Peter Grünberg Institute 6, Forschungszentrum Jülich, 52425, Jülich, Germany.|Institute of Inorganic Chemistry, RWTH Aachen University, 52074, Aachen, Germany.
Volkmar
V
Heß
Jülich-Aachen Research Alliance (JARA-FIT) and Peter Grünberg Institute 6, Forschungszentrum Jülich, 52425, Jülich, Germany. paul.koegerler@ac.rwth-aachen.de.|Institute of Inorganic Chemistry, RWTH Aachen University, 52074, Aachen, Germany. paul.koegerler@ac.rwth-aachen.de.
Paul
http://orcid.org/0000-0001-7831-3953
P
Kögerler
77Se NMR; ESI mass spectrometry; palladium; polyoxometalates; tungsten