title: Synthesis of Tertiary Enamides by Ag2CO3-Promoted Pd-Catalyzed Alkenylation of Acyclic Secondary Amides.
abstract: A Pd-catalyzed methodology for the preparation of tertiary enamides from acyclic secondary amides and bromo acrylates under mild reaction conditions has been developed using [Pd2(dba)3], XantPhos, and Ag2CO3as a base. The reaction occurs through a stereospecific metal-mediated oxidative-insertion mechanism.
authors.affiliation: Namur Research College and Department of Chemistry, University of Namur , Rue de Bruxelles 61, B-5000 Namur, Belgium.
authors.forename: Arnaud
authors.initials: A
authors.lastname: Delforge
authors.affiliation: Namur Research College and Department of Chemistry, University of Namur , Rue de Bruxelles 61, B-5000 Namur, Belgium.
authors.forename: Irene
authors.initials: I
authors.lastname: Georgiou
authors.affiliation: Namur Research College and Department of Chemistry, University of Namur , Rue de Bruxelles 61, B-5000 Namur, Belgium.
authors.forename: Adrian
authors.initials: A
authors.lastname: Kremer
authors.affiliation: Namur Research College and Department of Chemistry, University of Namur , Rue de Bruxelles 61, B-5000 Namur, Belgium.
authors.forename: Johan
authors.initials: J
authors.lastname: Wouters
authors.affiliation: Namur Research College and Department of Chemistry, University of Namur , Rue de Bruxelles 61, B-5000 Namur, Belgium.|School of Chemistry, Cardiff University , Park Place, Main Building, CF10 3AT Cardiff, U.K.
authors.forename: Davide
authors.initials: D
authors.lastname: Bonifazi