title: Biodiesel production from wet microalgae by using graphene oxide as solid acid catalyst.
abstract: In order to produce biodiesel from lipids in wet microalgae with graphene oxide (GO) as solid acid catalyst, the effects on lipids conversion efficiencies of catalyst dosage, transesterification temperature, reaction time, methanol dosage and chloroform dosage were investigated. Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and elemental analysis revealed that GO contained 0.997mmol SO3H groups per gram and high amounts of OH groups. Scanning electron microscopy showed that wet microalgae cells were adsorbed on hydrophilic GO surfaces covered with many OH groups. Lipids extracted by chloroform from microalgal cells were transformed into fatty acids methyl esters (FAMEs) through transesterification catalyzed by the acid centers (SO3H groups) in GO catalysts. The lipids conversion efficiency into FAMEs was 95.1% in microwave-assisted transesterification reactions of 5wt.% GO catalyst at 90°C for 40min.
authors.affiliation: State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China. Electronic address: juncheng@zju.edu.cn.
authors.forename: Jun
authors.initials: J
authors.lastname: Cheng
authors.affiliation: State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China.
authors.forename: Yi
authors.initials: Y
authors.lastname: Qiu
authors.affiliation: State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China.
authors.forename: Rui
authors.initials: R
authors.lastname: Huang
authors.affiliation: State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China.
authors.forename: Weijuan
authors.initials: W
authors.lastname: Yang
authors.affiliation: State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China.
authors.forename: Junhu
authors.initials: J
authors.lastname: Zhou
authors.affiliation: State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China.
authors.forename: Kefa
authors.initials: K
authors.lastname: Cen
mesh_terms: D056804:Biofuels / Q000382:microbiology*; D002384:Catalysis; D004951:Esterification; D006108:Graphite / Q000737:chemistry*; D008055:Lipids / Q000737:chemistry*; D058086:Microalgae / Q000737:chemistry*; D008872:Microwaves; D056951:Photoelectron Spectroscopy; D017550:Spectroscopy, Fourier Transform Infrared
chemical_list: D056804:Biofuels; D008055:Lipids; D006108:Graphite
keywords: Biodiesel; Graphene oxide; Solid acid catalyst; Wet microalgae