title: Studies the effects of ultrasonic irradiation and dielectric constants of solvents on formation of lead(II) supramolecular polymer; new precursors for synthesis of lead(II) oxide nanoparticles.
abstract: In order to evaluation the effects of ultrasonic irradiations and dielectric constants of solvents on formation [Pb2(5-Clq-8-ol)2(OAc)2]n(1), [H5-Clq-8-ol=5-chloroquinolin-8-ol and OAc-=acetate],we designed some experiments and synthesized six samples of 1 under different conditions. Microrods of a lead(II) supramolecular polymer, were synthesized under these conditions. These microstructures were characterized by IR spectroscopy, X-ray powder diffraction (XRD) and Scanning Electron Microscopy (SEM). The results indicated that compound 1 with the best crystallinity can be obtained in the presence of MeCN and H2O (as the bulk sample) and in the presence of MeCN and EtOH (by sonochemical process). The least agglomeration of microrods was observed in H2O which is due to high dielectric constant of it. By considering all of the factors consist of crystallinity and agglomeration of the products and their corresponding histograms, it seems that MeCN is the best solvent for synthesis of 1. The samples which were synthesized in the presence of MeCN, had been used as new precursors for fabricating lead(II) oxide nanoparticles via thermal decomposition in oleic acid (OA).
authors.affiliation: School of Chemistry, College of Science, University of Tehran, P.O. Box 14155-6455, Tehran, Islamic Republic of Iran.
authors.forename: Yasamin
authors.initials: Y
authors.lastname: Noori
authors.affiliation: School of Chemistry, College of Science, University of Tehran, P.O. Box 14155-6455, Tehran, Islamic Republic of Iran. Electronic address: akhbari.k@khayam.ut.ac.ir.
authors.forename: Kamran
authors.initials: K
authors.lastname: Akhbari
authors.affiliation: Department of Materials Science and Technology, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla, Thailand.
authors.forename: Anukorn
authors.initials: A
authors.lastname: Phuruangrat
authors.affiliation: Departement of Chemistry, Biology and Biotechnologies, University of Perugia, Perugia, Italy.
authors.forename: Ferdinando
authors.initials: F
authors.lastname: Costantino
keywords: Dielectric constants; Lead(II); Nanoparticles; Solvent effect; Sonochemical; Supramolecular polymer