title: Synthesis of Trisubstituted Vinyl Sulfides via Oxidative Thiolation Initiated Cascade Reaction of Alkynoates with Thiols.
abstract: A thiolation initiated cascade reaction of aryl alkynoates has been developed with thiol as a coupling partner. This radical process has been demonstrated to proceed through S-H bond cleavage, thiolation of alkynoate, aryl migration, and decarboxylation. This reaction tolerates a wide scope of substrates resulting in good chemical yields, which provides an easy and practical strategy for preparation of trisubstituted vinyl sulfides.
authors.affiliation: School of Chemistry and Chemical Engineering, State Key laboratory of Coordination Chemistry, Nanjing University , Nanjing 210093, China.
authors.forename: Shengyang
authors.initials: S
authors.lastname: Ni
authors.affiliation: School of Chemistry and Chemical Engineering, State Key laboratory of Coordination Chemistry, Nanjing University , Nanjing 210093, China.
authors.forename: Lijun
authors.initials: L
authors.lastname: Zhang
authors.affiliation: School of Chemistry and Chemical Engineering, State Key laboratory of Coordination Chemistry, Nanjing University , Nanjing 210093, China.
authors.forename: Wenzhong
authors.initials: W
authors.lastname: Zhang
authors.affiliation: School of Chemistry and Chemical Engineering, State Key laboratory of Coordination Chemistry, Nanjing University , Nanjing 210093, China.
authors.forename: Haibo
authors.initials: H
authors.lastname: Mei
authors.affiliation: School of Chemistry and Chemical Engineering, State Key laboratory of Coordination Chemistry, Nanjing University , Nanjing 210093, China.|MaAnShan High-Tech Research Institute of Nanjing University , MaAnShan 238200, China.
authors.forename: Jianlin
authors.initials: J
authors.lastname: Han
authors.affiliation: School of Chemistry and Chemical Engineering, State Key laboratory of Coordination Chemistry, Nanjing University , Nanjing 210093, China.|MaAnShan High-Tech Research Institute of Nanjing University , MaAnShan 238200, China.
authors.forename: Yi
authors.initials: Y
authors.lastname: Pan