Formation, Characterization, and Reactivity of a Nonheme Oxoiron(IV) Complex Derived from the Chiral Pentadentate Ligand asN4Py.
The chiral pentadentate low-spin (S = 1) oxoiron(IV) complex [FeIV(O)(asN4Py)]2+(2) was synthesized and spectroscopically characterized. Its formation kinetics, reactivity, and (enantio)selectivity in an oxygen-atom-transfer reaction was investigated in detail and compared to a similar pentadentate ligand-containing system.
Department of Chemistry, University of Pannonia , 8201 Veszprém, Hungary.
Dóra
D
Lakk-Bogáth
Department of Chemistry, University of Pannonia , 8201 Veszprém, Hungary.
Róbert
R
Csonka
Department of Chemistry, University of Pannonia , 8201 Veszprém, Hungary.
Gábor
G
Speier
Aix Marseille Université, CNRS, Centrale Marseille, iSm2 UMR 7313 , 13397 Marseille, France.
Marius
M
Réglier
Aix Marseille Université, CNRS, Centrale Marseille, iSm2 UMR 7313 , 13397 Marseille, France.
A Jalila
AJ
Simaan
Aix Marseille Université, CNRS, Centrale Marseille, Spectropole FR1739 , 13397 Marseille, France.
Jean-Valère
JV
Naubron
Aix Marseille Université, CNRS, Centrale Marseille, Spectropole FR1739 , 13397 Marseille, France.
Michel
M
Giorgi
Research Centre for Energy, Hungarian Academy of Sciences , H-1525 Budapest, Hungary.
Károly
K
Lázár
Department of Chemistry, University of Pannonia , 8201 Veszprém, Hungary.
József
J
Kaizer