Determination of nickel in hydrogenated fats and selected chocolate bars in Czech Republic.
Nickel is a metal that can be present in products containing hardened edible oils, possibly as leftover catalyst from the vegetable oil hardening process. Nickel may cause toxic effects including the promotion of cancer and contact allergy. In this work, nickel content was determined in hydrogenated vegetable fats and confectionery products, made with these fats, available on the Czech market using newly developed method combining microwave digestion and graphite furnace AAS. While concentrations of 0.086±0.014mg.kg(-1) or less were found in hydrogenated vegetable fats, the Ni content in confectionery products was significantly higher, varying between 0.742±0.066 and 3.141±0.217mg.kg(-1). Based on an average consumer basket, daily intake of nickel from vegetable fats is at least twice as low as intake from confectionery products. Based on results, the levels of nickel in neither vegetable fats nor confectionery products, do not represent a significant health risk.
Department of Hygiene, Faculty of Military Health, University of Defence, Trebesska 1575, Hradec Kralove CZ-500 01, Czech Republic. Electronic address: dohnalova.luc@gmail.com.
Lucie
L
Dohnalova
Department of Chemistry, Faculty of Science, University of Hradec Kralove, Rokitanskeho 62, Hradec Kralove CZ-500 03, Czech Republic. Electronic address: pavel.bucek@uhk.cz.
Pavel
P
Bucek
Department of Informatics, Faculty of Science, University of Hradec Kralove, Rokitanskeho 62, Hradec Kralove CZ-500 03, Czech Republic. Electronic address: petr.vobornik@uhk.cz.
Petr
P
Vobornik
Department of Chemistry, Faculty of Science, University of Hradec Kralove, Rokitanskeho 62, Hradec Kralove CZ-500 03, Czech Republic. Electronic address: vlastimil.dohnal@uhk.cz.
Vlastimil
V
Dohnal
D000069956:Chocolate / Q000032:analysis*; D018153:Czech Republic; D005223:Fats / Q000032:analysis / Q000737:chemistry; D005506:Food Contamination / Q000032:analysis*; D006801:Humans; D006865:Hydrogenation; D009532:Nickel / Q000032:analysis*; D010938:Plant Oils / Q000032:analysis*; D013054:Spectrophotometry, Atomic / Q000379:methods*
D005223:Fats; D010938:Plant Oils; D009532:Nickel
Atomic absorption spectrometry; Hydrogenated fats; Microwave mineralization; Nickel