Palladium/Lewis Acid Co-catalyzed Divergent Asymmetric Ring-Opening Reactions of Azabenzonorbornadienes with Alcohols.
By fine tuning the combinations of chiral palladium catalysts and Lewis acids, both the additional and reductive asymmetric ring-opening reactions of azabenzonorbornadienes with alcohols were accomplished with good chemoselectivity, regioselectivity, and enantioselectivity. It was proven that the reductive ring-opening products were generated through a transfer-hydrogenation process with alcohols as hydrogen source.
YMU-HKBU Joint Laboratory of Traditional Natural Medicine, Yunnan Minzu University , 650500 Kunming, China.
Fan
F
Yang
YMU-HKBU Joint Laboratory of Traditional Natural Medicine, Yunnan Minzu University , 650500 Kunming, China.
Jingchao
J
Chen
YMU-HKBU Joint Laboratory of Traditional Natural Medicine, Yunnan Minzu University , 650500 Kunming, China.
Jianbin
J
Xu
YMU-HKBU Joint Laboratory of Traditional Natural Medicine, Yunnan Minzu University , 650500 Kunming, China.
Fujie
F
Ma
YMU-HKBU Joint Laboratory of Traditional Natural Medicine, Yunnan Minzu University , 650500 Kunming, China.
Yongyun
Y
Zhou
YMU-HKBU Joint Laboratory of Traditional Natural Medicine, Yunnan Minzu University , 650500 Kunming, China.
Madhuri Vikas
MV
Shinde
YMU-HKBU Joint Laboratory of Traditional Natural Medicine, Yunnan Minzu University , 650500 Kunming, China.
Baomin
B
Fan