Pyridine-antipyrine appended indole derivative for selective recognition of Fe3+: Concentration dependent coloration.
Combination of pyridine, antipyrine and indole in a single molecule (L2) allows selective recognition of Fe3+colorimetrically in CH3CN. The structure of L2 is confirmed from single crystal X-ray diffraction analysis. The probe displays two different visible bands at 541nm and 715nm in the presence of Fe3+, associated with two different colors, viz. green and pink-violet allowing determination of unknown Fe3+concentration. Interestingly, removal of 2-picolyl group from indole N-center of L2 generates L3 that behaves similarly at low Fe3+concentration (>0 to 1.1mM) but differently at higher Fe3+concentration (>1.1mM), indicating involvement of pyridyl-N donor towards Fe3+, and hence different coordination environment around Fe3+at higher concentration.
Department of Chemistry, The University of Burdwan, Burdwan 713104, West Bengal, India.
Sabyasachi
S
Ta
Department of Chemistry, The University of Burdwan, Burdwan 713104, West Bengal, India.
Sandip
S
Nandi
Department of Chemistry, The University of Burdwan, Burdwan 713104, West Bengal, India.
Milan
M
Ghosh
Department of Chemistry, The University of Burdwan, Burdwan 713104, West Bengal, India.
Somenath
S
Banerjee
Department of Chemistry, The University of Burdwan, Burdwan 713104, West Bengal, India. Electronic address: ddas100in@yahoo.com.
Debasis
D
Das
Absorption; Antipyrine; Colorimetric; Fe(3+); Indole; NIR; Pyridine