Advances in Organic and Organic-Inorganic Hybrid Polymeric Supports for Catalytic Applications.
In this review, the most recent advances (2014-2016) on the synthesis of new polymer-supported catalysts are reported, focusing the attention on the synthetic strategies developed for their preparation. The polymer-supported catalysts examined will be organic-based polymers and organic-inorganic hybrids and will include, among others, polystyrenes, poly-ionic liquids, chiral ionic polymers, dendrimers, carbon nanotubes, as well as silica and halloysite-based catalysts. Selected examples will show the synthesis and application in the field of organocatalysis and metal-based catalysis both for non-asymmetric and asymmetric transformations.
Dipartimento Scienze e Tecnologie Biologiche, Chimiche e Farmaceutiche (STEBICEF) Università di Palermo, Viale delle Scienze, Ed. 17, 90128 Palermo, Italy. annamariapia.salvo@unipa.it.
Anna Maria Pia
AM
Salvo
Dipartimento Scienze e Tecnologie Biologiche, Chimiche e Farmaceutiche (STEBICEF) Università di Palermo, Viale delle Scienze, Ed. 17, 90128 Palermo, Italy. francesco.giacalone@unipa.it.
Francesco
F
Giacalone
Dipartimento Scienze e Tecnologie Biologiche, Chimiche e Farmaceutiche (STEBICEF) Università di Palermo, Viale delle Scienze, Ed. 17, 90128 Palermo, Italy. michelangelo.gruttadauria@unipa.it.
Michelangelo
M
Gruttadauria
asymmetric catalysis; heterogeneous catalysis; metal catalyst; organic-inorganic hybrid; organocatalysis; polystyrene
Nano Lett. 2015 Feb 11;15(2):823-8
25625306
Org Biomol Chem. 2016 Apr 14;14(14):3521-5
26974873
ChemSusChem. 2015 Jan;8(1):123-30
25421122
Dalton Trans. 2016 Feb 7;45(5):2116-23
26486695
Chempluschem. 2016 Jan;81(1):86-92
31968742
ACS Appl Mater Interfaces. 2014 Apr 23;6(8):5947-54
24694114
Chemistry. 2013 Dec 16;19(51):17483-93
24265270
Chem Sci. 2015 Feb 1;6(2):1510-1515
29560239
Science. 2005 Sep 23;309(5743):2040-2
16179475
Org Biomol Chem. 2008 Mar 7;6(5):912-5
18292884
Chemistry. 2014 Jun 2;20(23):7122-7
24737394
Chempluschem. 2014 Mar;79(3):421-426
31986604
ACS Nano. 2016 Apr 26;10(4):4627-36
26974262
ChemSusChem. 2013 Jul;6(7):1186-90
23757327
Chem Soc Rev. 2014;43(20):7171-87
25000475
Phys Chem Chem Phys. 2011 Sep 7;13(33):14831-8
21792445
J Am Chem Soc. 2011 Nov 16;133(45):18082-5
22029262
Chem Commun (Camb). 2011 Mar 14;47(10):2838-40
21253627
ChemSusChem. 2014 Dec;7(12):3534-40
25336345
Chem Commun (Camb). 2013 Jan 11;49(3):231-3
23085774
ChemSusChem. 2011 Dec 16;4(12):1830-7
22110020
Bioconjug Chem. 1996 Nov-Dec;7(6):703-14
8950489
Org Lett. 2013 Nov 15;15(22):5798-801
24175676
Org Biomol Chem. 2015 Sep 21;13(35):9314-22
26240011
Chemistry. 2016 Jun 6;22(24):8368-75
27116117