title: Supramolecular assembly of cobaloxime on nanoring-coated carbon nanotubes: addressing the stability of the pyridine-cobalt linkage under hydrogen evolution turnover conditions.
abstract: A carbon nanotube-cobaloxime nanohybrid was prepared through supramolecular assembly of tailored polymerizable amphiphiles, leading to the coordination of cobalt on pyridine-coated nanotubes. This material was used as a catalyst for hydrogen evolution in fully aqueous media. This study provides a definitive asset regarding the stability of the pyridine-cobalt axial bond under H2evolution turnover conditions.
authors.affiliation: Service de Chimie Bioorganique et de Marquage (SCBM), CEA, Université Paris-Saclay, 91191 Gif-sur-Yvette, France. eric.doris@cea.fr and Laboratoire de Chimie et Biologie des Métaux, Université Grenoble Alpes, CNRS, CEA, 17 rue des Martyrs, F-38000 Grenoble, France. vincent.artero@cea.fr.
authors.forename: Simon
authors.initials: S
authors.lastname: Donck
authors.affiliation: Laboratoire de Chimie et Biologie des Métaux, Université Grenoble Alpes, CNRS, CEA, 17 rue des Martyrs, F-38000 Grenoble, France. vincent.artero@cea.fr.
authors.forename: Jennifer
authors.initials: J
authors.lastname: Fize
authors.affiliation: Service de Chimie Bioorganique et de Marquage (SCBM), CEA, Université Paris-Saclay, 91191 Gif-sur-Yvette, France. eric.doris@cea.fr.
authors.forename: Edmond
authors.initials: E
authors.lastname: Gravel
authors.affiliation: Service de Chimie Bioorganique et de Marquage (SCBM), CEA, Université Paris-Saclay, 91191 Gif-sur-Yvette, France. eric.doris@cea.fr.
authors.forename: Eric
authors.initials: E
authors.lastname: Doris
authors.affiliation: Laboratoire de Chimie et Biologie des Métaux, Université Grenoble Alpes, CNRS, CEA, 17 rue des Martyrs, F-38000 Grenoble, France. vincent.artero@cea.fr.
authors.forename: Vincent
authors.initials: V
authors.lastname: Artero