title: Spectrophotometric determination of gold(III) in forensic and pharmaceutical samples and results complemented with ICP AES and EDXRF analysis.
abstract: Spectrophotometric method with three systems were developed here for the determination of gold(III) using o-dianisidine, aniline sulphate and catechol. Gold(III),in the system 1 it oxidizes o-dianisidine, in the system 2 it oxidizes catechol followed by its coupling with o-dianisidine, in the system 3 it oxidizes catechol followed by its coupling with aniline sulphate forming dye products with respective λmax446nm, 540nm, and 505nm. All the three systems were optimized and analytical parameters were calculated. The molar absorptivity values were 9.27×104, 1.97×104and 1.62×104respectively for the systems 1, 2 and 3 with the corresponding Sandell sensitivity values (μgcm-2), 0.0021, 0.0096 and 0.011. The optimized systems were used for the determination of gold present in some forensic jewellery and pharmaceutical samples and the results obtained were compared with the results of all samples determined by Inductively Coupled Plasma - Atomic Emission Spectrometric method and a few of them were also complemented by Energy Dispersive X-Ray Fluorescent spectral analysis.
authors.affiliation: Forensic Science Laboratory, Madivala, Bangalore 560068, India.
authors.forename: Vani
authors.initials: V
authors.lastname: Nagaraja
authors.affiliation: Forensic Science Laboratory, Madivala, Bangalore 560068, India.
authors.forename: M Kiran
authors.initials: MK
authors.lastname: Kumar
authors.affiliation: Department of Chemistry, University of Mysore, Manasagangothri, Mysore 570006, India. Electronic address: gnagendrappa@yahoo.co.in.
authors.forename: Nagendrappa
authors.initials: N
authors.lastname: Giddappa
mesh_terms: D000814:Aniline Compounds / Q000737:chemistry; D002138:Calibration; D002396:Catechols / Q000737:chemistry; D003116:Color; D004396:Coloring Agents / Q000737:chemistry; D003962:Dianisidine / Q000737:chemistry; D044707:Forensic Sciences / Q000379:methods; D006046:Gold / Q000032:analysis* / Q000737:chemistry; D055498:Jewelry / Q000032:analysis*; D057230:Limit of Detection; D008515:Medicine, Ayurvedic / Q000379:methods; D010084:Oxidation-Reduction; D013052:Spectrometry, X-Ray Emission / Q000379:methods; D013054:Spectrophotometry, Atomic / Q000379:methods; D013056:Spectrophotometry, Ultraviolet / Q000379:methods*; D013607:Tablets / Q000032:analysis* / Q000737:chemistry
chemical_list: D000814:Aniline Compounds; D002396:Catechols; D004396:Coloring Agents; D013607:Tablets; D006046:Gold; C034221:catechol; D003962:Dianisidine; C023650:aniline
keywords: Aniline sulphate; Catechol; EDXRF; Gold(III); ICP-AES; Jewellery; Oxidation; Pharmaceuticals; Spectrophotometry; Systems1–3; o-dianisidine