title: Pseudocontact shifts from mobile spin labels.
abstract: This paper presents a detailed analysis of the pseudocontact shift (PCS) field induced by a mobile spin label that is viewed as a probability density distribution with an associated effective magnetic susceptibility anisotropy. It is demonstrated that non-spherically symmetric density can lead to significant deviations from the commonly used point dipole approximation for the PCS. Analytical and numerical solutions are presented for the general partial differential equation that describes the non-point case. It is also demonstrated that it is possible, with some reasonable approximations, to reconstruct paramagnetic centre probability distributions from the experimental PCS data.
authors.affiliation: School of Chemistry, University of Southampton, Highfield Campus, Southampton, SO17 1BJ, UK. e.suturina@soton.ac.uk.
authors.forename: Elizaveta A
authors.initials: EA
authors.lastname: Suturina
authors.affiliation: School of Chemistry, University of Southampton, Highfield Campus, Southampton, SO17 1BJ, UK. e.suturina@soton.ac.uk.
authors.forename: Ilya
authors.initials: I
authors.lastname: Kuprov