title: Regioselective preparation of a bis-pyrazolinofullerene by a macrocyclization reaction.
abstract: A single isomer of a pyrazolinofullerene bis-adduct was prepared by tether-directed remote functionalization. Specifically, a macrocyclization reaction between C60and a bis-hydrazone reagent has been carried out to generate a regioisomerically pure fullerene bis-adduct which presents a lower LUMO than pristine C60.
authors.affiliation: Universidad de Castilla la Mancha, Instituto de Nanociencia, Nanotecnología y Materiales Moleculares (INAMOL), 45071-Toledo, Spain. Fernando.Langa@uclm.es.
authors.forename: Virginia
authors.initials: V
authors.lastname: Cuesta
authors.affiliation: Laboratoire de Chimie des Matériaux Moléculaires, Ecole Européenne de Chimie, Polymères et Matériaux, Université de Strasbourg et CNRS (UMR 7509), 25 rue Becquerel, 67087-Strasbourg, France.
authors.forename: Maxence
authors.initials: M
authors.lastname: Urbani
authors.affiliation: Universidad de Castilla la Mancha, Instituto de Nanociencia, Nanotecnología y Materiales Moleculares (INAMOL), 45071-Toledo, Spain. Fernando.Langa@uclm.es.
authors.forename: Pilar
authors.initials: P
authors.lastname: de la Cruz
authors.affiliation: Universidad de Castilla la Mancha, Instituto de Nanociencia, Nanotecnología y Materiales Moleculares (INAMOL), 45071-Toledo, Spain. Fernando.Langa@uclm.es.
authors.forename: Lorena
authors.initials: L
authors.lastname: Welte
authors.affiliation: Laboratoire de Chimie des Matériaux Moléculaires, Ecole Européenne de Chimie, Polymères et Matériaux, Université de Strasbourg et CNRS (UMR 7509), 25 rue Becquerel, 67087-Strasbourg, France.
authors.forename: Jean-François
authors.initials: JF
authors.lastname: Nierengarten
authors.affiliation: Universidad de Castilla la Mancha, Instituto de Nanociencia, Nanotecnología y Materiales Moleculares (INAMOL), 45071-Toledo, Spain. Fernando.Langa@uclm.es.
authors.forename: Fernando
authors.initials: F
authors.lastname: Langa