title: DBN hexafluorophosphate salts as convenient sulfonylating and phosphonylating agents.
abstract: Air-stable N-sulfonyl and N-phosphonyl DBN hexafluorophosphate salts have been synthesised under mild conditions as sulfonylating and phosphonylating agents. These salts are highly efficient in the sulfonylation and phosphonylation of a range of N- and O-nucleophiles to generate sulfonamides, sulfonate esters, phosphoramidates and phosphonate esters in good yields.
authors.affiliation: Centre for Sustainable Chemical Technologies, University of Bath, Claverton Down, Bath, BA2 7AY, UK. C.Jones@bath.ac.uk.
authors.forename: Caroline S
authors.initials: CS
authors.lastname: Jones
authors.affiliation: Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK.
authors.forename: Steven D
authors.initials: SD
authors.lastname: Bull
authors.affiliation: Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK.
authors.forename: Jonathan M J
authors.initials: JM
authors.lastname: Williams