title: Stable bromoallene oxides.
abstract: The first stable bromoallene oxides were obtained by the DMDO epoxidation of 1-bromo-1,3-di-tert-alkylallenes, producing the first crystalline allene oxide of any kind. The epoxidations are regioselective for the bromine-bearing Δ1,2alkene, and also face selective producing single diastereomer E-olefin products.
authors.affiliation: Department of Chemistry, Imperial College London, London, SW7 2AZ, UK. c.braddock@imperial.ac.uk.
authors.forename: D
authors.identifier: http://orcid.org/0000-0002-4161-7256
authors.initials: D
authors.lastname: Christopher Braddock
authors.affiliation: Department of Chemistry, Imperial College London, London, SW7 2AZ, UK. c.braddock@imperial.ac.uk.
authors.forename: Areeb
authors.identifier: http://orcid.org/0000-0002-4509-5272
authors.initials: A
authors.lastname: Mahtey
authors.affiliation: Department of Chemistry, Imperial College London, London, SW7 2AZ, UK. c.braddock@imperial.ac.uk.
authors.forename: Henry S
authors.identifier: http://orcid.org/0000-0002-8635-8390
authors.initials: HS
authors.lastname: Rzepa
authors.affiliation: Department of Chemistry, Imperial College London, London, SW7 2AZ, UK. c.braddock@imperial.ac.uk.
authors.forename: Andrew J P
authors.initials: AJ
authors.lastname: White