title: Quantitative analysis of hydrogen sites and occupancy in deep mantle hydrous wadsleyite using single crystal neutron diffraction.
abstract: Evidence from seismological and mineralogical studies increasingly indicates that water from the oceans has been transported to the deep earth to form water-bearing dense mantle minerals. Wadsleyite [(Mg, Fe2+)2SiO4] has been identified as one of the most important host minerals incorporating this type of water, which is capable of storing the entire mass of the oceans as a hidden reservoir. To understand the effects of such water on the physical properties and chemical evolution of Earth's interior, it is essential to determine where in the crystal structure the hydration occurs and which chemical bonds are altered and weakened after hydration. Here, we conduct a neutron time-of-flight single-crystal Laue diffraction study on hydrous wadsleyite. Single crystals were grown under pressure to a size suitable for the experiment and with physical qualities representative of wet, deep mantle conditions. The results of this neutron single crystal diffraction study unambiguously demonstrate the method of hydrogen incorporation into the wadsleyite, which is qualitatively different from that of its denser polymorph, ringwoodite, in the wet mantle. The difference is a vital clue towards understanding why these dense mantle minerals show distinctly different softening behaviours after hydration.
authors.affiliation: Institute for Planetary Materials, Okayama University, Misasa, Tottori 682-0193, Japan.
authors.forename: Narangoo
authors.initials: N
authors.lastname: Purevjav
authors.affiliation: Institute for Planetary Materials, Okayama University, Misasa, Tottori 682-0193, Japan.
authors.forename: Takuo
authors.initials: T
authors.lastname: Okuchi
authors.affiliation: Institute for Planetary Materials, Okayama University, Misasa, Tottori 682-0193, Japan.|Kochi Institute for Core Sample Research, Japan Agency for Marine-Earth Science and Technology, Nankoku, Kochi 783-8502, Japan.
authors.forename: Naotaka
authors.initials: N
authors.lastname: Tomioka
authors.affiliation: Chemical and Engineering Materials Division, Neutron Sciences Directorate, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA.
authors.forename: Xiaoping
authors.initials: X
authors.lastname: Wang
authors.affiliation: Chemical and Engineering Materials Division, Neutron Sciences Directorate, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA.
authors.forename: Christina
authors.initials: C
authors.lastname: Hoffmann