title: Hydroxypropyl methylcellulose based aerogels: Synthesis, characterization and application as adsorbents for wastewater pollutants.
abstract: Hydroxypropyl methylcellulose (HPMC) E4M and J5MS samples with degrees of substitution of methyl groups (DS) 1.9 and 1.5, respectively, and molar substitutions of hydroxypropyl groups (MS) 0.25 and 0.75, respectively, were used to create aerogels in the presence of citric (cit), oxalic (oxa) or terephthalic (ter) acids, as crosslinkers. E4M-cit, J5MS-cit and J5MS-oxa aerogels presented outstanding stability in water, acid media, alcohols, acetone and hydrocarbons, density values of∼(0.020±0.002)g/cm3, compressive modulus ranging from (111±9)kPa to (133±11)kPa. On the other hand, E4M-oxa, E4M-ter and J5MS-ter aerogels were not adequate adsorbents because they collapsed in water. The adsorption behavior of 17α-ethinyl estradiol (EE) and methylene blue (MB) onto E4M-cit, J5MS-cit and J5MS-oxa aerogels were fitted to Freundlich model, indicating higher affinity of EE for J5MS-cit and J5MS-oxa and higher affinity of MB for E4M-cit aerogels. HPMC aeorogels could be successfully reused.
authors.affiliation: Department of Fundamental Chemistry, Institute of Chemistry, University of São Paulo, Av. Prof. Lineu Prestes, 748, 05508-000 São Paulo, SP, Brazil. Electronic address: bih.martins42@gmail.com.
authors.forename: Bianca F
authors.initials: BF
authors.lastname: Martins
authors.affiliation: Department of Fundamental Chemistry, Institute of Chemistry, University of São Paulo, Av. Prof. Lineu Prestes, 748, 05508-000 São Paulo, SP, Brazil. Electronic address: pv.toledo@hotmail.com.
authors.forename: Paulo V O
authors.initials: PV
authors.lastname: de Toledo
authors.affiliation: Department of Fundamental Chemistry, Institute of Chemistry, University of São Paulo, Av. Prof. Lineu Prestes, 748, 05508-000 São Paulo, SP, Brazil. Electronic address: dfsp@iq.usp.br.
authors.forename: Denise F S
authors.initials: DF
authors.lastname: Petri
keywords: 17 α-ethinyl estradiol; Adsorption; Aerogels; Hydroxypropyl methylcellulose; Methylene blue; Organic pollutants