title: Pd-Supported on N-doped carbon: improved heterogeneous catalyst for base-free alkoxycarbonylation of aryl iodides.
abstract: Novel Pd-based heterogeneous catalysts were prepared through immobilization of Pd(OAc)2/phenanthroline on carbon and subsequent pyrolysis. The most active catalyst was characterized by TEM, XPS and XRD techniques and was successfully used for the base-free methoxycarbonylation of aryl iodides. Notably, no metal contamination (detection limit < 0.5 ppm) in the final products was observed.
authors.affiliation: Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany. Matthias.Beller@catalysis.de and Laboratory of Industrial and Synthetic Organic Chemistry (LISOC), Dipartimento di Chimica e Tecnologie Chimiche, Università della Calabria, Via P. Bucci, 12/C, 87036 Arcavacata di Rende (CS), Italy.
authors.forename: Ida
authors.initials: I
authors.lastname: Ziccarelli
authors.affiliation: Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany. Matthias.Beller@catalysis.de.
authors.forename: Helfried
authors.initials: H
authors.lastname: Neumann
authors.affiliation: Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany. Matthias.Beller@catalysis.de.
authors.forename: Carsten
authors.initials: C
authors.lastname: Kreyenschulte
authors.affiliation: Laboratory of Industrial and Synthetic Organic Chemistry (LISOC), Dipartimento di Chimica e Tecnologie Chimiche, Università della Calabria, Via P. Bucci, 12/C, 87036 Arcavacata di Rende (CS), Italy.
authors.forename: Bartolo
authors.identifier: http://orcid.org/0000-0003-4582-1489
authors.initials: B
authors.lastname: Gabriele
authors.affiliation: Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany. Matthias.Beller@catalysis.de.
authors.forename: Matthias
authors.initials: M
authors.lastname: Beller