title: Efficient nickel-catalyzed phosphinylation of C-S bonds forming C-P bonds.
abstract: The first nickel-catalyzed phosphinylation of C-S bonds forming C-P bonds is developed. This transformation can proceed readily with the simple Ni(cod)2at a loading down to 0.1 mol% at the 10 mmol scale. A variety of aryl sulfur compounds, i.e. sulfides, sulfoxides and sulfones all couple with P(O)-H compounds to produce the corresponding organophosphorus compounds in high yields, which provides an efficient new method for the construction of C-P bonds.
authors.affiliation: State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China. chentieqiao@hnu.edu.cn sf_yin@hnu.edu.cn.
authors.forename: Jia
authors.initials: J
authors.lastname: Yang
authors.affiliation: State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China. chentieqiao@hnu.edu.cn sf_yin@hnu.edu.cn.
authors.forename: Jing
authors.initials: J
authors.lastname: Xiao
authors.affiliation: State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China. chentieqiao@hnu.edu.cn sf_yin@hnu.edu.cn.
authors.forename: Tieqiao
authors.initials: T
authors.lastname: Chen
authors.affiliation: State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China. chentieqiao@hnu.edu.cn sf_yin@hnu.edu.cn.
authors.forename: Shuang-Feng
authors.initials: SF
authors.lastname: Yin
authors.affiliation: National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8565, Japan. libiao-han@aist.go.jp.
authors.forename: Li-Biao
authors.initials: LB
authors.lastname: Han