title: New 3 D Tubular Porous Structure of an Organic-Zincophosphite Framework with Interesting Gas Adsorption and Luminescence Properties.
abstract: A new 3D tubular zinc phosphite, Zn2(C22H22N8)0.5(HPO3)2⋅H2O (1), incorporating a tetradentate organic ligand was synthesized under hydro(solvo)thermal conditions and structurally characterized by single-crystal X-ray diffraction. Compound 1 is the first example of inorganic zincophosphite chains being interlinked through 1,2,4,5-tetrakis(imidazol-1-ylmethyl)benzene to form a tubular porous framework with unusual organic-inorganic hybrid channels. The thermal and chemical stabilities, high capacity for CO2adsorption compared to that for N2adsorption, and interesting optical properties of LED devices fabricated using this compound were also studied.
authors.affiliation: Institute of Bioscience and Biotechnology, National Taiwan Ocean University, Keelung, 202, Taiwan), Fax: (+886) 2-24622320. twcmwang@gmail.com.
authors.forename: Chih-Min
authors.initials: CM
authors.lastname: Wang
authors.affiliation: Institute of Chemistry, Academia Sinica, Nankang, Taipei, 115, Taiwan.
authors.forename: Li-Wei
authors.initials: LW
authors.lastname: Lee
authors.affiliation: Institute of Bioscience and Biotechnology, National Taiwan Ocean University, Keelung, 202, Taiwan), Fax: (+886) 2-24622320.
authors.forename: Tsung-Yuan
authors.initials: TY
authors.lastname: Chang
authors.affiliation: Institute of Bioscience and Biotechnology, National Taiwan Ocean University, Keelung, 202, Taiwan), Fax: (+886) 2-24622320.
authors.forename: Bing-Lun
authors.initials: BL
authors.lastname: Fan
authors.affiliation: Institute of Bioscience and Biotechnology, National Taiwan Ocean University, Keelung, 202, Taiwan), Fax: (+886) 2-24622320.
authors.forename: Chih-Ling
authors.initials: CL
authors.lastname: Wang
authors.affiliation: Institute of Bioscience and Biotechnology, National Taiwan Ocean University, Keelung, 202, Taiwan), Fax: (+886) 2-24622320.
authors.forename: Hsiu-Mei
authors.initials: HM
authors.lastname: Lin
authors.affiliation: Institute of Chemistry, Academia Sinica, Nankang, Taipei, 115, Taiwan.
authors.forename: Kuang-Lieh
authors.initials: KL
authors.lastname: Lu
keywords: luminescence; organic-inorganic hybrid composites; phosphites; tetradentate ligand; zinc