title: Regio- and Stereoselective Dehydrogenative Silylation and Hydrosilylation of Vinylarenes Catalyzed by Ruthenium Alkylidenes.
abstract: Development of regio- and stereoselective dehydrogenative silylation and hydrosilylation of vinylarenes with alkoxysilanes, catalyzed by ruthenium alkylidenes, is described. Varying L- and X-type ligands on ruthenium alkylidenes permits selective access to either (E)-vinylsilanes or β-alkylsilanes with high regio- and stereocontrol. cis,cis-1,5-Cyclooctadiene was identified as the most effective sacrificial hydrogen acceptor for the dehydrogenative silylation of vinylarenes, which allows use of a nearly equimolar ratio of alkenes and silanes.
authors.affiliation: Department of Chemistry and Biochemistry, University of Texas at Arlington , Arlington, Texas 76019, United States.
authors.forename: Apparao
authors.initials: A
authors.lastname: Bokka
authors.affiliation: Department of Chemistry and Biochemistry, University of Texas at Arlington , Arlington, Texas 76019, United States.
authors.forename: Junha
authors.initials: J
authors.lastname: Jeon