title: Single molecular tuning of the charge balance in blue-emitting iridium dendrimers for efficient nondoped solution-processed phosphorescent OLEDs.
abstract: The single molecular tuning of charge balance has been demonstrated here by integrating a p-type dendron, an n-type dendron and a blue emissive Ir core into one dendritic platform. Compared with the commonly used physical blending, not only can the charge balance be well tailored, but also the intrinsic phase separation can be successfully eliminated in such developed single molecular systems (B-TCz2TPO1 and B-TCz1TPO2). As a consequence, their corresponding nondoped solution-processed PhOLEDs achieve more than doubled external quantum efficiencies accompanied by a negligible efficiency roll-off.
authors.affiliation: State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China. junqiaod@ciac.ac.cn lixiang@ciac.ac.cn and University of the Chinese Academy of Sciences, Beijing 100049, P. R. China.
authors.forename: Yang
authors.initials: Y
authors.lastname: Wang
authors.affiliation: College of Chemistry and Environmental Science, Hebei University, Baoding 071002, P. R. China.
authors.forename: Yaoming
authors.initials: Y
authors.lastname: Lu
authors.affiliation: College of Chemistry and Environmental Science, Hebei University, Baoding 071002, P. R. China.
authors.forename: Baoxiang
authors.initials: B
authors.lastname: Gao
authors.affiliation: State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China. junqiaod@ciac.ac.cn lixiang@ciac.ac.cn.
authors.forename: Shumeng
authors.initials: S
authors.lastname: Wang
authors.affiliation: State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China. junqiaod@ciac.ac.cn lixiang@ciac.ac.cn.
authors.forename: Junqiao
authors.initials: J
authors.lastname: Ding
authors.affiliation: State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China. junqiaod@ciac.ac.cn lixiang@ciac.ac.cn.
authors.forename: Lixiang
authors.initials: L
authors.lastname: Wang
authors.affiliation: State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China. junqiaod@ciac.ac.cn lixiang@ciac.ac.cn.
authors.forename: Xiabin
authors.initials: X
authors.lastname: Jing
authors.affiliation: State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China. junqiaod@ciac.ac.cn lixiang@ciac.ac.cn.
authors.forename: Fosong
authors.initials: F
authors.lastname: Wang