title: Probing the Influence of Dielectric Environment on Excitons in Monolayer WSe2: Insight from High Magnetic Fields.
abstract: Excitons in atomically thin semiconductors necessarily lie close to a surface, and therefore their properties are expected to be strongly influenced by the surrounding dielectric environment. However, systematic studies exploring this role are challenging, in part because the most readily accessible exciton parameter-the exciton's optical transition energy-is largely unaffected by the surrounding medium. Here we show that the role of the dielectric environment is revealed through its systematic influence on the size of the exciton, which can be directly measured via the diamagnetic shift of the exciton transition in high magnetic fields. Using exfoliated WSe2monolayers affixed to single-mode optical fibers, we tune the surrounding dielectric environment by encapsulating the flakes with different materials and perform polarized low-temperature magneto-absorption studies to 65 T. The systematic increase of the exciton's size with dielectric screening, and concurrent reduction in binding energy (also inferred from these measurements), is quantitatively compared with leading theoretical models. These results demonstrate how exciton properties can be tuned in future 2D optoelectronic devices.
authors.affiliation: National High Magnetic Field Laboratory , Los Alamos, New Mexico 87545, United States.
authors.forename: Andreas V
authors.initials: AV
authors.lastname: Stier
authors.affiliation: Department of Physics, University of Washington , Seattle, Washington 98195, United States.
authors.forename: Nathan P
authors.initials: NP
authors.lastname: Wilson
authors.affiliation: Department of Materials Science, University of Washington , Seattle, Washington 98195, United States.
authors.forename: Genevieve
authors.initials: G
authors.lastname: Clark
authors.affiliation: Department of Physics, University of Washington , Seattle, Washington 98195, United States.|Department of Materials Science, University of Washington , Seattle, Washington 98195, United States.
authors.forename: Xiaodong
authors.initials: X
authors.lastname: Xu
authors.affiliation: National High Magnetic Field Laboratory , Los Alamos, New Mexico 87545, United States.
authors.forename: Scott A
authors.initials: SA
authors.lastname: Crooker
keywords: 2D semiconductor; dichalcogenide; dielectric screening; exciton; monolayer WSe2