title: Synthesis, Structure, and Antibacterial Activity of a Thallium(III)-Containing Polyoxometalate, [Tl2{B-β-SiW8O30(OH)}2]12.
abstract: We have synthesized and structurally characterized the first discrete thallium-containing polyoxometalate, [Tl2{B-β-SiW8O30(OH)}2]12-(1). Polyanion 1 was characterized in the solid-state and shown to be solution-stable by203/205Tl NMR, electrospray ionization mass spectrometry, and electrochemical studies. The antibacterial activity of 1 was also investigated.
authors.affiliation: Department of Life Sciences and Chemistry, Jacobs University , P.O. Box 750561, 28725 Bremen, Germany.
authors.forename: Wassim W
authors.initials: WW
authors.lastname: Ayass
authors.affiliation: Department of Inorganic and Analytical Chemistry, University of Debrecen , Egyetem tér 1, 4032 Debrecen, Hungary.
authors.forename: Tamás
authors.initials: T
authors.lastname: Fodor
authors.affiliation: Department of Life Sciences and Chemistry, Jacobs University , P.O. Box 750561, 28725 Bremen, Germany.
authors.forename: Zhengguo
authors.initials: Z
authors.lastname: Lin
authors.affiliation: Department of Life Sciences and Chemistry, Jacobs University , P.O. Box 750561, 28725 Bremen, Germany.
authors.forename: Rachelle M
authors.initials: RM
authors.lastname: Smith
authors.affiliation: Department of Life Sciences and Chemistry, Jacobs University , P.O. Box 750561, 28725 Bremen, Germany.
authors.forename: Xiaolin
authors.initials: X
authors.lastname: Xing
authors.affiliation: Department of Life Sciences and Chemistry, Jacobs University , P.O. Box 750561, 28725 Bremen, Germany.
authors.forename: Khaled
authors.initials: K
authors.lastname: Abdallah
authors.affiliation: Department of Inorganic and Analytical Chemistry, University of Debrecen , Egyetem tér 1, 4032 Debrecen, Hungary.
authors.forename: Imre
authors.initials: I
authors.lastname: Tóth
authors.affiliation: Department of Inorganic and Analytical Chemistry, University of Debrecen , Egyetem tér 1, 4032 Debrecen, Hungary.
authors.forename: László
authors.initials: L
authors.lastname: Zékány
authors.affiliation: Departament de Química Física i Inorgànica, Universitat Rovira i Virgili , Marcel·lí Domingo 1, 43007 Tarragona, Spain.
authors.forename: Magda
authors.initials: M
authors.lastname: Pascual-Borràs
authors.affiliation: Departament de Química Física i Inorgànica, Universitat Rovira i Virgili , Marcel·lí Domingo 1, 43007 Tarragona, Spain.
authors.forename: Antonio
authors.initials: A
authors.lastname: Rodríguez-Fortea
authors.affiliation: Departament de Química Física i Inorgànica, Universitat Rovira i Virgili , Marcel·lí Domingo 1, 43007 Tarragona, Spain.
authors.forename: Josep M
authors.initials: JM
authors.lastname: Poblet
authors.affiliation: Key Laboratory of Cluster Science, Ministry of Education of China; Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry, Beijing Institute of Technology , 100081 Beijing, P. R. China.
authors.forename: Linyuan
authors.initials: L
authors.lastname: Fan
authors.affiliation: Key Laboratory of Cluster Science, Ministry of Education of China; Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry, Beijing Institute of Technology , 100081 Beijing, P. R. China.
authors.forename: Jie
authors.initials: J
authors.lastname: Cao
authors.affiliation: Laboratoire de Chimie-Physique, UMR 8000 CNRS, Université Paris-Sud , F-91405 Orsay, France.
authors.forename: Bineta
authors.initials: B
authors.lastname: Keita
authors.affiliation: Department of Life Sciences and Chemistry, Jacobs University , P.O. Box 750561, 28725 Bremen, Germany.
authors.forename: Matthias S
authors.initials: MS
authors.lastname: Ullrich
authors.affiliation: Department of Life Sciences and Chemistry, Jacobs University , P.O. Box 750561, 28725 Bremen, Germany.
authors.forename: Ulrich
authors.initials: U
authors.lastname: Kortz