title: Dioxygen-induced oxidative activation of a P-H bond: radical oxyphosphorylation of alkenes and alkynes toward β-oxy phosphonates.
abstract: The dioxygen-induced radical oxyphosphorylation of alkenes and alkynes is presented, wherein a P-H bond was activated by molecular oxygen. Various β-oxy phosphonates could be facilely synthesized without the assistance of any transition metals or extra organic initiators. Mechanistic studies showed that HP(O)Ph2acts as a reductant to accelerate oxyphosphorylation.
authors.affiliation: College of Chemistry and Molecular Sciences, The Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, Hubei, P. R. China. aiwenlei@whu.edu.cn.
authors.forename: Pan
authors.initials: P
authors.lastname: Peng
authors.affiliation: College of Chemistry and Molecular Sciences, The Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, Hubei, P. R. China. aiwenlei@whu.edu.cn.
authors.forename: Qingquan
authors.initials: Q
authors.lastname: Lu
authors.affiliation: College of Chemistry and Molecular Sciences, The Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, Hubei, P. R. China. aiwenlei@whu.edu.cn.
authors.forename: Long
authors.initials: L
authors.lastname: Peng
authors.affiliation: College of Chemistry and Molecular Sciences, The Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, Hubei, P. R. China. aiwenlei@whu.edu.cn.
authors.forename: Chao
authors.initials: C
authors.lastname: Liu
authors.affiliation: College of Chemistry and Molecular Sciences, The Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, Hubei, P. R. China. aiwenlei@whu.edu.cn.
authors.forename: Guangyu
authors.initials: G
authors.lastname: Wang
authors.affiliation: College of Chemistry and Molecular Sciences, The Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, Hubei, P. R. China. aiwenlei@whu.edu.cn and National Research Center for Carbohydrate Synthesis, Jiangxi Normal University, Nanchang, 330022, P. R. China.
authors.forename: Aiwen
authors.initials: A
authors.lastname: Lei