title: In-Situ Fabrication of Graphene Oxide Hybrid Ni-Based Metal-Organic Framework (Ni-MOFs@GO) with Ultrahigh Capacitance as Electrochemical Pseudocapacitor Materials.
abstract: This paper reports a series of novel Ni-based metal-organic framework (Ni-MOFs) prepared by a facile solvothermal process. The synthetic conditions have great effects on the Ni-MOFs morphologies, porous textures, and their electrochemical performance. Improved capacitance performance was successfully realized by the in-situ hybrid of Ni-MOFs with graphene oxide (GO) nanosheets (Ni-MOFs@GO). The pseudocapacitance of ca. 1457.7 F/g for Ni-MOFs obtained at 180 °C with HCl as the modulator was elevated to ca. 2192.4 F/g at a current density of 1 A/g for the Ni-MOFs@GO with GO contents of 3 wt %. Additionally, the capacitance retention was also promoted from ca. 83.5% to 85.1% of its original capacitance at 10 A/g even after 3000 cycles accordingly. These outstanding electrochemical properties of Ni-based MOF materials may be related to their inherent characteristics, such as the unique flower-like architecture and fascinating synergetic effect between the Ni-MOFs and the GO nanosheets.
authors.affiliation: Department of Materials Physics, School of Physics and Optoelectronic Engineering, Nanjing University of Information Science & Technology , 219 Ningliu Road, Nanjing, Jiangsu 210044, China.
authors.forename: Yingjie
authors.initials: Y
authors.lastname: Zhou
authors.affiliation: Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), National Jiangsu Synergistic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University (Nanjing Tech) , 30 South Puzhu Road, Nanjing, Jiangsu 211816, China.
authors.forename: Zemin
authors.initials: Z
authors.lastname: Mao
authors.affiliation: Department of Materials Physics, School of Physics and Optoelectronic Engineering, Nanjing University of Information Science & Technology , 219 Ningliu Road, Nanjing, Jiangsu 210044, China.
authors.forename: Wei
authors.initials: W
authors.lastname: Wang
authors.affiliation: Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), National Jiangsu Synergistic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University (Nanjing Tech) , 30 South Puzhu Road, Nanjing, Jiangsu 211816, China.
authors.forename: Zhengkai
authors.initials: Z
authors.lastname: Yang
authors.affiliation: Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), National Jiangsu Synergistic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University (Nanjing Tech) , 30 South Puzhu Road, Nanjing, Jiangsu 211816, China.
authors.forename: Xiang
authors.initials: X
authors.lastname: Liu
keywords: graphite oxide; metal−organic framework (MOFs); nanocomposites; nickel; pseudocapacitor