title: Cu-Catalyzed hydrophosphorylative ring opening of propargyl epoxides: highly selective access to 4-phosphoryl 2,3-allenols.
abstract: A novel CuI-catalyzed cross-coupling of propargyl epoxides with P(O)H compounds is disclosed. The reaction proceeded efficiently under mild conditions to give 4-phosphoryl 2,3-allenols in good to high yields with excellent selectivity. The utility of the products was demonstrated and a plausible mechanism was also proposed.
authors.affiliation: State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing Tech University, Nanjing 210009, China. shenrw@njtech.edu.cn.
authors.forename: Ruwei
authors.initials: R
authors.lastname: Shen
authors.affiliation: State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing Tech University, Nanjing 210009, China. shenrw@njtech.edu.cn.
authors.forename: Jianlin
authors.initials: J
authors.lastname: Yang
authors.affiliation: State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing Tech University, Nanjing 210009, China. shenrw@njtech.edu.cn.
authors.forename: Haipeng
authors.initials: H
authors.lastname: Zhao
authors.affiliation: State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing Tech University, Nanjing 210009, China. shenrw@njtech.edu.cn.
authors.forename: Yu
authors.initials: Y
authors.lastname: Feng
authors.affiliation: State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing Tech University, Nanjing 210009, China. shenrw@njtech.edu.cn.
authors.forename: Lixiong
authors.initials: L
authors.lastname: Zhang
authors.affiliation: National Institute of Advanced Industrial Science & Technology (AIST), Tsukuba, Ibaraki 305-8565, Japan. libiao-han@aist.go.jp.
authors.forename: Li-Biao
authors.initials: LB
authors.lastname: Han