title: Gold-catalyzed [3+2]-annulations of α-aryl diazonitriles with ynamides and allenamides to yield 1-amino-1H-indenes.
abstract: Gold-catalyzed [3+2]-annulations of α-aryl diazonitriles with ynamides and allenamides yield 1-amino-1H-indenes in two distinct pathways; the success of these annulations relies on the high electrophilicity of α-cyano arylgold carbenes to activate an ionic pathway.
authors.affiliation: Department of Chemistry, National Tsing-Hua University, 101, Sec. 2, Kuang-Fu Rd., Hsinchu, 30013, Taiwan, Republic of China. rsliu@mx.nthu.edu.tw.
authors.forename: RahulKumar Rajmani
authors.initials: RR
authors.lastname: Singh
authors.affiliation: Department of Chemistry, National Tsing-Hua University, 101, Sec. 2, Kuang-Fu Rd., Hsinchu, 30013, Taiwan, Republic of China. rsliu@mx.nthu.edu.tw.
authors.forename: Samir Kundlik
authors.initials: SK
authors.lastname: Pawar
authors.affiliation: Department of Chemistry, National Tsing-Hua University, 101, Sec. 2, Kuang-Fu Rd., Hsinchu, 30013, Taiwan, Republic of China. rsliu@mx.nthu.edu.tw.
authors.forename: Min-Jie
authors.initials: MJ
authors.lastname: Huang
authors.affiliation: Department of Chemistry, National Tsing-Hua University, 101, Sec. 2, Kuang-Fu Rd., Hsinchu, 30013, Taiwan, Republic of China. rsliu@mx.nthu.edu.tw.
authors.forename: Rai-Shung
authors.initials: RS
authors.lastname: Liu