title: Quantum Dynamics of the17O +32O2Collision Process.
abstract: We report full quantum integral and differential cross sections and rate constants for the17O +32O2reactive process. This constitutes the first quantum scattering study of the17O16O16O system. We emphasize the comparison with the18O +32O2collision in close connection to the mass-independent fractionation (hereafter referred to as MIF) puzzle for ozone in atmospheric chemistry. We find similar general trends in the cross sections and rate constants for both rare isotopes, but we note some singular behaviors peculiar to the use of17O isotope, particularly at the lowest collision energies.
authors.affiliation: Laboratoire Interdisciplinaire Carnot de Bourgogne, UMR CNRS 6303, Université de Bourgogne Franche-Comté , 21078 Dijon, France.|UFR Sciences et Techniques, Université de Franche-Comté , 25030 Besancon, France.
authors.forename: Grégoire
authors.initials: G
authors.lastname: Guillon
authors.affiliation: Laboratoire Interdisciplinaire Carnot de Bourgogne, UMR CNRS 6303, Université de Bourgogne Franche-Comté , 21078 Dijon, France.|UFR Sciences et Techniques, Université de Franche-Comté , 25030 Besancon, France.
authors.forename: Pascal
authors.initials: P
authors.lastname: Honvault