title: Rhodium(iii)-catalyzed ortho-alkenylation using a cyclic N-phosphoryl ketimine as the directing group.
abstract: A novel cyclic N-phosphoryl ketimine structure can efficiently react with olefins as useful directing groups to construct a myriad of phosphate scaffolds via rhodium(iii)-catalyzed ortho-alkenylation. This method provides a probability that the coupling products could be used as a building block to access more complex organic phosphorus compounds.
authors.affiliation: Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry, West China School of Pharmacy, Sichuan University, Chengdu 610041, China. dongl@scu.edu.cn.
authors.forename: Yu-Qin
authors.initials: YQ
authors.lastname: Zhu
authors.affiliation: Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry, West China School of Pharmacy, Sichuan University, Chengdu 610041, China. dongl@scu.edu.cn.
authors.forename: Liu
authors.initials: L
authors.lastname: Qin
authors.affiliation: Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry, West China School of Pharmacy, Sichuan University, Chengdu 610041, China. dongl@scu.edu.cn.
authors.forename: Qiang
authors.initials: Q
authors.lastname: Song
authors.affiliation: Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry, West China School of Pharmacy, Sichuan University, Chengdu 610041, China. dongl@scu.edu.cn.
authors.forename: Fu
authors.initials: F
authors.lastname: Su
authors.affiliation: Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences, Urumqi, 830011, China.
authors.forename: Yan-Jun
authors.initials: YJ
authors.lastname: Xu
authors.affiliation: Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry, West China School of Pharmacy, Sichuan University, Chengdu 610041, China. dongl@scu.edu.cn.
authors.forename: Lin
authors.initials: L
authors.lastname: Dong