title: The {Ni10Nb32} aggregate: a perspective on isopolyniobates as ligands.
abstract: [H4Ni10(H2O)8Nb32O102]20-, representing the first high-nuclear nickel-cation-bridged polyoxoniobate, has been synthesized. It incorporates two [{Ni2O4}(H2O)2(Nb6O19)]12-and two [Ni3(H2O)2Nb10O34]12-subunits exhibiting a rhombus-like architecture. Furthermore, the solution behaviour was examined by electrospray ionization mass spectrometry and the magnetic properties in the low temperature range indicate the presence of ferromagnetic interactions.
authors.affiliation: Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan, China. jyniu@henu.edu.cn jpwang@henu.edu.cn.
authors.forename: Zhijie
authors.initials: Z
authors.lastname: Liang
authors.affiliation: Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan, China. jyniu@henu.edu.cn jpwang@henu.edu.cn.
authors.forename: Dongdi
authors.initials: D
authors.lastname: Zhang
authors.affiliation: Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan, China. jyniu@henu.edu.cn jpwang@henu.edu.cn.
authors.forename: Haiying
authors.initials: H
authors.lastname: Wang
authors.affiliation: Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan, China. jyniu@henu.edu.cn jpwang@henu.edu.cn.
authors.forename: Pengtao
authors.initials: P
authors.lastname: Ma
authors.affiliation: Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan, China. jyniu@henu.edu.cn jpwang@henu.edu.cn.
authors.forename: Zongfei
authors.initials: Z
authors.lastname: Yang
authors.affiliation: Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan, China. jyniu@henu.edu.cn jpwang@henu.edu.cn.
authors.forename: Jingyang
authors.initials: J
authors.lastname: Niu
authors.affiliation: Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan, China. jyniu@henu.edu.cn jpwang@henu.edu.cn.
authors.forename: Jingping
authors.initials: J
authors.lastname: Wang