title: Flexible Microsupercapacitors Using Silk and Cotton Substrates.
abstract: Flexible microsupercapacitors (MSCs) are needed to power ultrasmall wearable electronic devices. Silk cocoons comprise microfibers of silk, which is an attractive natural resource to fabricate MSCs. These fibers are insulators; hence, they must be converted to conducting surfaces. Polyphenols from green tea have been used as a protective layer that also acted as a reducing agent for silver ions. The reduction of silver ions resulted in the formation of silver nanoparticles that subsequently reduced gold ions to gold. The gold film imparts conductivity to the silk fiber without affecting the mechanical strength of the silk fiber. The mechanical strength of uncoated silk fiber and gold coated silk fiber were found to be 5.2 and 5 GPa, respectively. A pseudocapacitive polymer, poly(3,4-ethylenedioxythiophene), was used as the active material to fabricate MSCs. The MSCs showed an impressive gravimetric capacitance of 500 F/g and areal capacitance of 62 mF/cm2. The power and energy densities were calculated to be 2458 W/kg and 44 Wh/kg, respectively. The device was coiled on a cylinder, and the performance of the device was found to be same as that of the uncoiled device. To demonstrate that the approach is not specific to silk, we also coated gold on cotton fibers using the protocol used to coat gold on silk. Coiled and uncoiled supercapacitors were fabricated using PEDOT coated cotton fibers. The gravimetric capacitance was found to be 250 F/g with energy and power densities of 5.5 Wh/kg and 1118 W/kg, respectively. We have also demonstrated that the devices can be connected in parallel and series to improve the performance of the miniaturized devices.
authors.affiliation: Polymers and Advanced Materials Laboratory, CSIR-National Chemical Laboratory, CSIR-Network of Institutes for Solar Energy , Dr. Homi Bhabha Road, Pune 411008, Maharashtra, India.
authors.forename: Chayanika
authors.initials: C
authors.lastname: Das
authors.affiliation: Polymers and Advanced Materials Laboratory, CSIR-National Chemical Laboratory, CSIR-Network of Institutes for Solar Energy , Dr. Homi Bhabha Road, Pune 411008, Maharashtra, India.
authors.forename: Kothandam
authors.initials: K
authors.lastname: Krishnamoorthy
keywords: cotton fibers; gold coated cotton threads; microsupercapacitors; silk fibers