title: Deuterium substitution effects on the structural and magnetic phase transitions of a hydrogen-bonded coordination polymer, bis(glycolato)copper(ii).
abstract: Bis(glycolato)copper(ii) [Cu(HOCH2CO2)2] shows a structural phase transition around 220 K under cooling and 270 K under heating, and ferromagnetic ordering at 1.1 K. Deuterium substitution of the hydroxyl groups in it induced a large shift in the structural transition temperature while no shift in the ferromagnetic transition temperature took place.
authors.affiliation: Department of Chemistry, Tokyo Metropolitan University, 1-1 Minami-osawa, Hachioji, 192-0397, Japan.
authors.forename: Shota
authors.initials: S
authors.lastname: Yoneyama
authors.forename: Takeshi
authors.initials: T
authors.lastname: Kodama
authors.forename: Koichi
authors.initials: K
authors.lastname: Kikuchi
authors.forename: Takumi
authors.initials: T
authors.lastname: Fujisawa
authors.forename: Akira
authors.initials: A
authors.lastname: Yamaguchi
authors.forename: Akihiko
authors.initials: A
authors.lastname: Sumiyama
authors.forename: Yoshiaki
authors.initials: Y
authors.lastname: Shuku
authors.forename: Shinobu
authors.initials: S
authors.lastname: Aoyagi
authors.forename: Wataru
authors.initials: W
authors.lastname: Fujita