title: Triple-decker sandwich complexes with a bent cyclo-P5middle-deck.
abstract: New types of triple-decker complexes with an organo-substituted P5middle-deck were synthesized by the reaction of [Cp*Fe(η4-P5R)]-(1a: R = CH2SiMe3; 1b: R = NMe2) with halogeno-bridged transition metal dimers [Cp'''MX]2(M = Cr, Fe, Co, Ni; X = Cl, Br). By oxidation of [(Cp*Fe)(Cp'''Co)(μ,η4:3-P5CH2SiMe3)] 2a with [Cp2Fe][PF6], the cationic complex [(Cp*Fe)(Cp'''Co)(μ,η5:4-P5CH2SiMe3)]+was isolated. The electronic structure of the synthesized complexes was elucidated by DFT calculations.
authors.affiliation: Institut für Anorganische Chemie, Universität Regensburg, 93051 Regensburg, Germany. Manfred.scheer@ur.de.
authors.forename: Eric
authors.initials: E
authors.lastname: Mädl
authors.affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Division of RAS, Acad. Lavrentyev str. 3, 630090 Novosibirsk, Russia and Novosibirsk State University, Pirogava str. 2, 630090 Novosibirsk, Russia.
authors.forename: Eugenia
authors.initials: E
authors.lastname: Peresypkina
authors.affiliation: St. Petersburg State University, University pr. 26, 198504 Old Peterhoff, St. Petersburg, Russia.
authors.forename: Alexey Y
authors.identifier: http://orcid.org/0000-0002-1932-6647
authors.initials: AY
authors.lastname: Timoshkin
authors.affiliation: Institut für Anorganische Chemie, Universität Regensburg, 93051 Regensburg, Germany. Manfred.scheer@ur.de.
authors.forename: Manfred
authors.identifier: http://orcid.org/0000-0003-2182-5020
authors.initials: M
authors.lastname: Scheer