title: {[Ir3(cod)3(μ3-S)2](μ3-S)SnCl}2- a ternary Ir-Sn-S cluster with the iridium atoms in three different chemical environments.
abstract: Reactions of Sn-S clusters with [IrCl(cod)]2afforded an Ir-Sn-S cluster with unprecedented topology, {[Ir3(cod)3(μ3-S)2](μ3-S)SnCl}2, in which two [Ir3S2] units and a central [Sn2S2] unit are connected via Ir-S and Ir-Sn bonds. Each of the crystallographically independent Ir atoms exhibits a specific chemical environment. Quantum chemical studies shed light on the electronic structure of the multinary cluster and the Ir-Sn bonds.
authors.affiliation: Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Philipps-Universität Marburg, Hans-Meerwein-Straße 4, D-35043 Marburg, Germany. dehnen@chemie.uni-marburg.de.
authors.forename: Eliza
authors.initials: E
authors.lastname: Leusmann
authors.affiliation: Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Philipps-Universität Marburg, Hans-Meerwein-Straße 4, D-35043 Marburg, Germany. dehnen@chemie.uni-marburg.de.
authors.forename: Eugenie
authors.initials: E
authors.lastname: Geringer
authors.affiliation: Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Philipps-Universität Marburg, Hans-Meerwein-Straße 4, D-35043 Marburg, Germany. dehnen@chemie.uni-marburg.de.
authors.forename: Bastian
authors.initials: B
authors.lastname: Weinert
authors.affiliation: Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Philipps-Universität Marburg, Hans-Meerwein-Straße 4, D-35043 Marburg, Germany. dehnen@chemie.uni-marburg.de.
authors.forename: Stefanie
authors.initials: S
authors.lastname: Dehnen