title: Supramolecular 3d-4f single-molecule magnet architectures.
abstract: The nanosized self-assemblies {[{LnIII}{H2O⊂CrLn}]2(H2O)} (Ln = Dy, 1 and Tb, 2) based on new 3d-4f mixed-metal coordination topologies are formed via extensive intramolecular hydrogen bonding that is directed by enclosed water molecules. Compounds 1 and 2 show single-molecule magnet characteristics manifested by hysteresis loops up to 1.6 K (Ueff= 8.3 cm-1) and 1 K (Ueff= 3.4 cm-1), respectively.
authors.affiliation: Institut für Anorganische Chemie, RWTH Aachen University, 52074 Aachen, Germany. kirill.monakhov@ac.rwth-aachen.de paul.koegerler@ac.rwth-aachen.de.
authors.forename: Sebastian
authors.initials: S
authors.lastname: Schmitz
authors.affiliation: Institut für Anorganische Chemie, RWTH Aachen University, 52074 Aachen, Germany. kirill.monakhov@ac.rwth-aachen.de paul.koegerler@ac.rwth-aachen.de.
authors.forename: Jan
authors.initials: J
authors.lastname: van Leusen
authors.affiliation: Jülich-Aachen Research Alliance (JARA-FIT) and Peter Grünberg Institute 6, Forschungszentrum Jülich, 52425 Jülich, Germany.
authors.forename: Natalya V
authors.initials: NV
authors.lastname: Izarova
authors.affiliation: Institut Néel (CNRS/UJF UPR2940), 38042 Grenoble cedex 9, France.
authors.forename: Yanhua
authors.initials: Y
authors.lastname: Lan
authors.affiliation: Institut Néel (CNRS/UJF UPR2940), 38042 Grenoble cedex 9, France and Physikalisches Institut, Karlsruhe Institute of Technology (KIT), 76131 Karlsruhe, Germany and Institut für Nanotechnologie, Karlsruhe Institute of Technology (KIT), 76344 Eggenstein-Leopoldshafen, Germany.
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Wernsdorfer
authors.affiliation: Institut für Anorganische Chemie, RWTH Aachen University, 52074 Aachen, Germany. kirill.monakhov@ac.rwth-aachen.de paul.koegerler@ac.rwth-aachen.de and Jülich-Aachen Research Alliance (JARA-FIT) and Peter Grünberg Institute 6, Forschungszentrum Jülich, 52425 Jülich, Germany.
authors.forename: Paul
authors.identifier: http://orcid.org/0000-0001-7831-3953
authors.initials: P
authors.lastname: Kögerler
authors.affiliation: Institut für Anorganische Chemie, RWTH Aachen University, 52074 Aachen, Germany. kirill.monakhov@ac.rwth-aachen.de paul.koegerler@ac.rwth-aachen.de.
authors.forename: Kirill Yu
authors.initials: KY
authors.lastname: Monakhov