title: Novel and efficient transformation of enamides into α-acyloxy ketones via an acyl intramolecular migration process.
abstract: Hydrogen peroxide and anhydride mediated transformation of enamides to afford substituted α-acyloxy ketones is described. This transition-metal-free cascade reaction has a broad substrate scope and high efficiency. The acyl intramolecular migration procedure successfully achieved this acyloxylation process under mild conditions and increased the atom efficiency.
authors.affiliation: State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, Department of Chemistry, Lanzhou University, Lanzhou, 730000, China. hgs@lzu.edu.cn.
authors.forename: Xiaoqiang
authors.identifier: http://orcid.org/0000-0001-7499-6662
authors.initials: X
authors.lastname: Zhou
authors.affiliation: State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, Department of Chemistry, Lanzhou University, Lanzhou, 730000, China. hgs@lzu.edu.cn.
authors.forename: Haojie
authors.initials: H
authors.lastname: Ma
authors.affiliation: State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, Department of Chemistry, Lanzhou University, Lanzhou, 730000, China. hgs@lzu.edu.cn.
authors.forename: Jinhui
authors.initials: J
authors.lastname: Cao
authors.affiliation: State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, Department of Chemistry, Lanzhou University, Lanzhou, 730000, China. hgs@lzu.edu.cn.
authors.forename: Xingxing
authors.initials: X
authors.lastname: Liu
authors.affiliation: State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, Department of Chemistry, Lanzhou University, Lanzhou, 730000, China. hgs@lzu.edu.cn.
authors.forename: Guosheng
authors.initials: G
authors.lastname: Huang