title: Anti-Markovnikov rearrangement in sulfur mediated allylic C-H amination of olefins.
abstract: Cationic rearrangement reactions usually follow Markovnikov's rule to give more substituted carbocations as stable intermediates. During our study on sulfur mediated allylic C-H amination of olefins, very rare cases of anti-Markovnikov rearrangement from secondary carbocations toward primary carbocations or primary triflates were observed.
authors.affiliation: State Key Laboratory of Chemical Resource Engineering, Department of Organic Chemistry, Faculty of Science, Beijing University of Chemical Technology, Beijing 100029, China. dhg@mail.buct.edu.cn jxxu@mail.buct.edu.cn lipf@mail.buct.edu.cn.
authors.forename: Zhong
authors.initials: Z
authors.lastname: Zhang
authors.affiliation: State Key Laboratory of Chemical Resource Engineering, Department of Organic Chemistry, Faculty of Science, Beijing University of Chemical Technology, Beijing 100029, China. dhg@mail.buct.edu.cn jxxu@mail.buct.edu.cn lipf@mail.buct.edu.cn.
authors.forename: Hongguang
authors.initials: H
authors.lastname: Du
authors.affiliation: State Key Laboratory of Chemical Resource Engineering, Department of Organic Chemistry, Faculty of Science, Beijing University of Chemical Technology, Beijing 100029, China. dhg@mail.buct.edu.cn jxxu@mail.buct.edu.cn lipf@mail.buct.edu.cn.
authors.forename: Jiaxi
authors.initials: J
authors.lastname: Xu
authors.affiliation: State Key Laboratory of Chemical Resource Engineering, Department of Organic Chemistry, Faculty of Science, Beijing University of Chemical Technology, Beijing 100029, China. dhg@mail.buct.edu.cn jxxu@mail.buct.edu.cn lipf@mail.buct.edu.cn.
authors.forename: Pingfan
authors.initials: P
authors.lastname: Li