title: Water-based synthesis and characterisation of a new Zr-MOF with a unique inorganic building unit.
abstract: A new, microporous Zr-MOF was obtained using 2,5-pyrazinedicarboxylic acid (H2PzDC). The linker leads to the formation of a new 1D inorganic building unit composed of μ-OH bridged {Zr6O4(OH4)} clusters which are arranged in a hexagonal array and connected by the PzDC2-ions. The structure was determined from powder X-ray diffraction data.
authors.affiliation: Institut für Anorganische Chemie, Christian-Albrechts-Universität, Max-Eyth-Straße 2, D 24118 Kiel, Germany. stock@ac.uni-kiel.de.
authors.forename: S
authors.initials: S
authors.lastname: Waitschat
authors.affiliation: Institut für Anorganische Chemie, Christian-Albrechts-Universität, Max-Eyth-Straße 2, D 24118 Kiel, Germany. stock@ac.uni-kiel.de.
authors.forename: H
authors.initials: H
authors.lastname: Reinsch
authors.affiliation: Institut für Anorganische Chemie, Christian-Albrechts-Universität, Max-Eyth-Straße 2, D 24118 Kiel, Germany. stock@ac.uni-kiel.de.
authors.forename: N
authors.identifier: http://orcid.org/0000-0002-0339-7352
authors.initials: N
authors.lastname: Stock