title: Ru-Catalyzed Dehydrogenative C-O Bond Formation with Anilines and Phenols.
abstract: The Ru catalyzed cross-dehydrogenative C-O bond formation between anilines and phenols is described and discussed. The exclusive C-O versus C-N bond-formation selectivity, moreover in the absence of chelating-assisting directing groups and while leaving the N-H position untouched, is a remarkable feature of this metal-catalyzed radical cross-dehydrogenative coupling.
authors.affiliation: FB Chemie, Technische Universität Kaiserslautern, Erwin-Schrödinger Str. 52, 67663, Kaiserslautern, Germany.
authors.forename: Christophe
authors.initials: C
authors.lastname: Heitz
authors.affiliation: FB Chemie, Technische Universität Kaiserslautern, Erwin-Schrödinger Str. 52, 67663, Kaiserslautern, Germany.
authors.forename: Alexander W
authors.initials: AW
authors.lastname: Jones
authors.affiliation: FB Chemie, Technische Universität Kaiserslautern, Erwin-Schrödinger Str. 52, 67663, Kaiserslautern, Germany.
authors.forename: Bünyamin S
authors.initials: BS
authors.lastname: Oezkaya
authors.affiliation: FB Chemie, Technische Universität Kaiserslautern, Erwin-Schrödinger Str. 52, 67663, Kaiserslautern, Germany.
authors.forename: Christina L
authors.initials: CL
authors.lastname: Bub
authors.affiliation: FB Chemie, Technische Universität Kaiserslautern, Erwin-Schrödinger Str. 52, 67663, Kaiserslautern, Germany.
authors.forename: Marie-Laure
authors.initials: ML
authors.lastname: Louillat-Habermeyer
authors.affiliation: FB Chemie, Technische Universität Kaiserslautern, Erwin-Schrödinger Str. 52, 67663, Kaiserslautern, Germany.
authors.forename: Victoria
authors.initials: V
authors.lastname: Wagner
authors.affiliation: FB Chemie, Technische Universität Kaiserslautern, Erwin-Schrödinger Str. 52, 67663, Kaiserslautern, Germany.
authors.forename: Frederic W
authors.initials: FW
authors.lastname: Patureau
keywords: C−H activation; C−O bond formation; aniline; cross-dehydrogenative couplings; ruthenium