title: Complex surface structure of (110) terminated strontium titanate nanododecahedra.
abstract: The surface structure of (110) faceted strontium titanate nanoparticles synthesized via solvothermal method has been resolved using high-resolution electron microscopy (HREM). We demonstrate that the surface is a titania-rich structure containing tetrahedrally coordinated TiO4units similar to the family of (n × 1) reconstructions observed on (110) surfaces of bulk crystalline strontium titanate. When compared with prior results for (001) terminated strontium titanate single crystals made with traditional transmission electron microscopy (TEM) sample preparation techniques, the results demonstrate that many models for oxide nanoparticles need to be revisited. This work serves as a reminder that attention must be paid to the surface of nanoparticles. Even with a simple perovskite as the starting point the end result can be very complex. As more materials are synthesized on the nanoscale, this will become increasingly important to take into consideration.
authors.affiliation: Department of Materials Science and Engineering, Northwestern University, Evanston, IL 60208, USA.
authors.forename: Lawrence A
authors.identifier: http://orcid.org/0000-0001-7644-3762
authors.initials: LA
authors.lastname: Crosby
authors.affiliation: Department of Chemistry, Northwestern University, Evanston, IL 60208, USA.
authors.forename: Robert M
authors.initials: RM
authors.lastname: Kennedy
authors.affiliation: Department of Materials Science and Engineering, Northwestern University, Evanston, IL 60208, USA.
authors.forename: Bor-Rong
authors.initials: BR
authors.lastname: Chen
authors.affiliation: Center for Nanoscale Materials, Argonne National Laboratory, Lemont, IL 60439, USA.
authors.forename: Jianguo
authors.initials: J
authors.lastname: Wen
authors.affiliation: Department of Chemistry, Northwestern University, Evanston, IL 60208, USA.
authors.forename: Kenneth R
authors.initials: KR
authors.lastname: Poeppelmeier
authors.affiliation: Department of Materials Science and Engineering, Northwestern University, Evanston, IL 60208, USA.
authors.forename: Michael J
authors.initials: MJ
authors.lastname: Bedzyk
authors.affiliation: Department of Materials Science and Engineering, Northwestern University, Evanston, IL 60208, USA.
authors.forename: Laurence D
authors.initials: LD
authors.lastname: Marks