title: Conjugated microporous polymer networks with adjustable microstructures for high CO2uptake capacity and selectivity.
abstract: A series of phenylene-based conjugated microporous polymers (CMPs) of the A6+ Mx(x = 2, 3, 4, 6) type were synthesized. By tuning the monomer length and geometry, the BET surface area of CMPs can be tuned from 571 to 1115 m2g-1. Amongst the synthesized CMPs, A6CMP-1 exhibits the highest CO2adsorption capacity of 1218 mg g-1at 318 K and 60 bar pressure. In addition, A6CMP-4 shows a high selectivity ratio of 47 for CO2/N2.
authors.affiliation: Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Changchun, 130103, China. xuyh@jlnu.edu.cn.
authors.forename: Long
authors.initials: L
authors.lastname: Qin
authors.affiliation: Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Changchun, 130103, China. xuyh@jlnu.edu.cn.
authors.forename: Guang-Juan
authors.initials: GJ
authors.lastname: Xu
authors.affiliation: Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Changchun, 130103, China. xuyh@jlnu.edu.cn.
authors.forename: Chan
authors.initials: C
authors.lastname: Yao
authors.affiliation: Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Changchun, 130103, China. xuyh@jlnu.edu.cn.
authors.forename: Yan-Hong
authors.identifier: http://orcid.org/0000-0002-9663-6681
authors.initials: YH
authors.lastname: Xu