title: Controlling O coverage and stability by alloying Au and Ag.
abstract: One of the most critical factors in oxidation catalysis is controlling the state of oxygen on the surface. Au and Ag are both effective selective oxidation catalysts for various reactions, and their interactions with oxygen are critical for determining their catalytic performance. Here, we show that the state of oxygen on a catalytic surface can be controlled by alloying Au and Ag. Using temperature programmed desorption, density functional theory (DFT), and Monte Carlo simulations, we examine how alloying Au into an Ag(110) surface affects O2dissociation, O coverage, and O stability. DFT calculations indicate that Au resides in the second layer, in agreement with previous experimental findings. The minimum ensemble size for O2dissociation is 2 Ag atoms in adjacent rows of the second layer. Surprisingly, adsorbed O2and the dissociation transition state interact directly with metal atoms in the adjacent trough, such that Au in this position inhibits O2dissociation by direct repulsion with oxygen electronic states. Using Monte Carlo simulations based on DFT energetics, we create models of the surface that agree closely with our experimental results. Both show that the O2uptake decreases nearly linearly as the Au concentration increases, and no O2uptake occurs for Au concentrations above 50%. For Au concentrations greater than 18%, increasing the Au concentration also decreases the stability of the adsorbed O. Based on these results, the O coverage and O stability can be tuned, in some cases independently. We also study how the reactivity of the surface is affected by these factors using CO2oxidation as a simple test reaction.
authors.affiliation: Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA and School of Engineering and Applied Sciences, Harvard University, Cambridge, MA, USA.
authors.forename: Matthew M
authors.identifier: http://orcid.org/0000-0002-4157-1745
authors.initials: MM
authors.lastname: Montemore
authors.affiliation: School of Engineering and Applied Sciences, Harvard University, Cambridge, MA, USA.
authors.forename: Ekin D
authors.initials: ED
authors.lastname: Cubuk
authors.affiliation: Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA.
authors.forename: J Eric
authors.initials: JE
authors.lastname: Klobas
authors.affiliation: Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA.
authors.forename: Martin
authors.initials: M
authors.lastname: Schmid
authors.affiliation: School of Engineering and Applied Sciences, Harvard University, Cambridge, MA, USA.
authors.forename: Robert J
authors.initials: RJ
authors.lastname: Madix
authors.affiliation: Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA and School of Engineering and Applied Sciences, Harvard University, Cambridge, MA, USA.
authors.forename: Cynthia M
authors.initials: CM
authors.lastname: Friend
authors.affiliation: School of Engineering and Applied Sciences, Harvard University, Cambridge, MA, USA and Department of Physics, Harvard University, Cambridge, MA, USA. kaxiras@physics.harvard.edu.
authors.forename: Efthimios
authors.initials: E
authors.lastname: Kaxiras