title: The Aryne [2,3] Stevens Rearrangement.
abstract: Arynes are employed in the transition-metal-free and mild [2,3] Stevens rearrangement of tertiary allylic amines for the synthesis of functionalized homoallylic amines in moderate to good yield with a broad substrate scope. The key nitrogen ylide intermediate was generated by the N-arylation of allyl amines using arynes. Moreover, the reaction of chiral allyl amines with arynes resulted in the enantiospecific synthesis of homoallylic amines. In addition, preliminary studies on the [1,2] Stevens rearrangement is also presented.
authors.affiliation: Academy of Scientific and Innovative Research (AcSIR) , New Delhi 110020, India.
authors.forename: Tony
authors.initials: T
authors.lastname: Roy
authors.affiliation: Academy of Scientific and Innovative Research (AcSIR) , New Delhi 110020, India.
authors.forename: Manikandan
authors.initials: M
authors.lastname: Thangaraj
authors.affiliation: Academy of Scientific and Innovative Research (AcSIR) , New Delhi 110020, India.
authors.forename: Trinadh
authors.initials: T
authors.lastname: Kaicharla
authors.forename: Rupa V
authors.initials: RV
authors.lastname: Kamath
authors.forename: Rajesh G
authors.initials: RG
authors.lastname: Gonnade
authors.affiliation: Academy of Scientific and Innovative Research (AcSIR) , New Delhi 110020, India.
authors.forename: Akkattu T
authors.initials: AT
authors.lastname: Biju