title: A drastic change in the superhydrophilic crystal porosities of metallosupramolecular structures via a slight change in pH.
abstract: A unique pH-controlled synthesis of two metallosupramolecular structures from CoAu complex anions and ZnIIcations is reported. A dense coordination polymer (porosity ∼13%) was formed at a pH of 5.0, whereas a porous ionic framework (porosity ∼61%) that selectively adsorbs CO2and H2O was created when the pH was adjusted to 5.5.
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. konno@chem.sci.osaka-u.ac.jp.
authors.forename: Sireenart
authors.initials: S
authors.lastname: Surinwong
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. konno@chem.sci.osaka-u.ac.jp.
authors.forename: Nobuto
authors.identifier: http://orcid.org/0000-0003-2457-0967
authors.initials: N
authors.lastname: Yoshinari
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. konno@chem.sci.osaka-u.ac.jp.
authors.forename: Tatsuhiro
authors.initials: T
authors.lastname: Kojima
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. konno@chem.sci.osaka-u.ac.jp.
authors.forename: Takumi
authors.initials: T
authors.lastname: Konno