title: Palladium-Catalyzed Decarboxylative Synthesis of Arylamines.
abstract: A novel approach has been developed for the synthesis of arylamines via the palladium-catalyzed intramolecular decarboxylative coupling (IDC) of aroyloxycarbamates, obtained in situ by reacting aryl carboxylic acids with hydroxycarbamates. The reaction offers facile access to structurally diverse arylamines with the site-specific formation of the C(sp2)-N bond under mild conditions.
authors.affiliation: Key Laboratory of Cluster Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic, School of Chemistry, Beijing Institute of Technology , Beijing 100081, People's Republic of China.
authors.forename: Qipu
authors.initials: Q
authors.lastname: Dai
authors.affiliation: Key Laboratory of Cluster Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic, School of Chemistry, Beijing Institute of Technology , Beijing 100081, People's Republic of China.
authors.forename: Peihe
authors.initials: P
authors.lastname: Li
authors.affiliation: Key Laboratory of Cluster Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic, School of Chemistry, Beijing Institute of Technology , Beijing 100081, People's Republic of China.
authors.forename: Nuannuan
authors.initials: N
authors.lastname: Ma
authors.affiliation: Key Laboratory of Cluster Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic, School of Chemistry, Beijing Institute of Technology , Beijing 100081, People's Republic of China.
authors.forename: Changwen
authors.initials: C
authors.lastname: Hu