title: Polyethyleneimine High-Energy Hydrophilic Surface Interfacial Treatment toward Efficient and Stable Perovskite Solar Cells.
abstract: The interfacial contact is critical for the performance of perovskite solar cells (PSCs), leading to dense perovskite thin films and efficient charge transport. In this contribution, an effective interfacial treatment solution using polyethyleneimine (PEI) was developed to improve the performance and stability of PSCs. Inserting PEI between the s-VOxand perovskite layers can produce a high-energy hydrophilic surface to facilitate the formation of a high-quality perovskite layer by the solution method. Accordingly, the surface coverage of perovskite film on the s-VOxlayer increased from 80% to 95%, and the PCE of the device improved from 12.06% (with an average of 10.16%) to 14.4% (with an average value of 12.8%) under an irradiance of 100 mW cm-2AM 1.5G sunlight. More importantly, the stability of PSCs was further improved after adding another PEI layer between the electron transport layer and LiF/Al layer, less than 10% decay in efficiency during a 10-days observation. Since all layers of the PSCs were fabricated at low temperature (<150 °C), these PEI-treated PSCs based on the amorphous VOxlayer have the potential to contribute significantly toward the development of efficient and stable solar cells on flexible substrates.
authors.affiliation: State Centre for International Cooperation on Designer Low-Carbon and Environmental Material (SCICDLCEM), School of Materials Science and Engineering, Zhengzhou University , Zhengzhou 450001, P. R. China.
authors.forename: Pengwei
authors.initials: P
authors.lastname: Li
authors.affiliation: State Centre for International Cooperation on Designer Low-Carbon and Environmental Material (SCICDLCEM), School of Materials Science and Engineering, Zhengzhou University , Zhengzhou 450001, P. R. China.
authors.forename: Chao
authors.initials: C
authors.lastname: Liang
authors.affiliation: State Centre for International Cooperation on Designer Low-Carbon and Environmental Material (SCICDLCEM), School of Materials Science and Engineering, Zhengzhou University , Zhengzhou 450001, P. R. China.
authors.forename: Yiqiang
authors.initials: Y
authors.lastname: Zhang
authors.affiliation: Key Laboratory of Green Printing Institute of Chemistry, Chinese Academy of Sciences (ICCAS), Beijing Engineering Research Centre of Nanomaterials for Green Printing Technology, Beijing National Laboratory for Molecular Sciences (BNLMS) , Beijing 10090, P. R. China.
authors.forename: Fengyu
authors.initials: F
authors.lastname: Li
authors.affiliation: Key Laboratory of Green Printing Institute of Chemistry, Chinese Academy of Sciences (ICCAS), Beijing Engineering Research Centre of Nanomaterials for Green Printing Technology, Beijing National Laboratory for Molecular Sciences (BNLMS) , Beijing 10090, P. R. China.
authors.forename: Yanlin
authors.initials: Y
authors.lastname: Song
authors.affiliation: State Centre for International Cooperation on Designer Low-Carbon and Environmental Material (SCICDLCEM), School of Materials Science and Engineering, Zhengzhou University , Zhengzhou 450001, P. R. China.
authors.forename: Guosheng
authors.initials: G
authors.lastname: Shao
keywords: amorphous VOx; hydrophilic surface; interfacial treatment; perovskite solar cells; polyethyleneimine