title: Self-Assembly Behavior of Ultrahighly Charged Amphiphilic Polyelectrolyte on Solid Surfaces.
abstract: The adsorption process of a geminized amphiphilic polyelectrolyte, comprising double elementary charges and double hydrophobic tails in each repeat unit (denoted as PAGC8), was investigated and characterized by means of quartz crystal microbalance with dissipation (QCM-D), ellipsometry, and atomic force microscopy (AFM). By comparison, the self-assembly behaviors of a traditional polyelectrolyte without hydrophobic chains (denoted as PASC1) and an amphiphilic polyelectrolyte with a single hydrophilic headgroup and hydrophobic tail in each repeat unit (denoted as PASC8) at the solid/liquid interface were also investigated in parallel. A two-regime buildup was found in both amphiphilic systems of PASC8and PAGC8, where the first regime was dependent on electrostatic interactions between polyelectrolytes and oppositely charged substrates, and the rearrangements of the preadsorbed chains and their aggregation behaviors on surface dominated the second regime. Furthermore, it was found that the adsorbed amount and conformation changed as a function of the charge density and bulk concentrations of the polyelectrolytes. The comparison of the adsorbed mass obtained from QCM-D and ellipsometry allowed calculating the coupling water content which reached high values and indicated a flexible aggregate conformation in the presence of PAGC8, resulting in controlling the suspension stability even at an extremely low concentration. In order to provide an insight into the mechanism of the suspension stability of colloidal dispersions, we gave a further explanation with respect to the interactions between surfaces in the presence of the geminized polyelectrolyte.
authors.affiliation: Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences , Beijing 100190, P. R. China.
authors.forename: Hui
authors.initials: H
authors.lastname: Yang
authors.affiliation: College of Civil Engineering, Shenzhen University , Shenzhen 518060, P. R. China.
authors.forename: Huabo
authors.initials: H
authors.lastname: Duan
authors.affiliation: College of Chemistry and Chemical Engineering, Guangzhou University , Guangzhou 510006, P. R. China.
authors.forename: Xu
authors.initials: X
authors.lastname: Wu
authors.affiliation: Biolin Scientific AB, Shanghai Representative Office, Shanghai 200120, P. R. China.
authors.forename: Min
authors.initials: M
authors.lastname: Wang
authors.affiliation: Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences , Beijing 100190, P. R. China.
authors.forename: Ting
authors.initials: T
authors.lastname: Chen
authors.affiliation: Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences , Beijing 100190, P. R. China.
authors.forename: Fanghui
authors.initials: F
authors.lastname: Liu
authors.affiliation: Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences , Beijing 100190, P. R. China.
authors.forename: Shizhe
authors.initials: S
authors.lastname: Huang
authors.affiliation: Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences , Beijing 100190, P. R. China.
authors.forename: Wei
authors.initials: W
authors.lastname: Zhang
authors.affiliation: Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences , Beijing 100190, P. R. China.
authors.forename: Gang
authors.initials: G
authors.lastname: Chen
authors.affiliation: Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences , Beijing 100190, P. R. China.|College of Civil Engineering, Shenzhen University , Shenzhen 518060, P. R. China.
authors.forename: Danfeng
authors.initials: D
authors.lastname: Yu
authors.affiliation: Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences , Beijing 100190, P. R. China.
authors.forename: Jinben
authors.initials: J
authors.lastname: Wang