title: Electrochemically active porous organic polymers based on corannulene.
abstract: For the first time, porous organic polymers (POPs) based on the smallest buckybowl, corannulene (BB-POPs) have been synthesized. Three POPs were synthesised via Sonogashira co-polymerization of 1,2,5,6-tetrabromocorannulene and alkyne linkers. BB-POP-3 exhibits the highest surface area (SABET= 560 m2g-1) and CO2adsorption of 11.7 wt%, while they retain the redox properties of corannulene.
authors.affiliation: Department of Chemistry and Biochemistry, The University of Texas, Dallas, 800 W. Campbell Rd. Richardson, Texas, 75080, USA. ronald.smaldone@utdallas.edu.
authors.forename: Arosha A K
authors.initials: AA
authors.lastname: Karunathilake
authors.affiliation: Department of Chemistry and Biochemistry, The University of Texas, Dallas, 800 W. Campbell Rd. Richardson, Texas, 75080, USA. ronald.smaldone@utdallas.edu.
authors.forename: Christina M
authors.initials: CM
authors.lastname: Thompson
authors.affiliation: Department of Chemistry and Biochemistry, The University of Texas, Dallas, 800 W. Campbell Rd. Richardson, Texas, 75080, USA. ronald.smaldone@utdallas.edu.
authors.forename: Sahila
authors.initials: S
authors.lastname: Perananthan
authors.affiliation: Department of Chemistry and Biochemistry, The University of Texas, Dallas, 800 W. Campbell Rd. Richardson, Texas, 75080, USA. ronald.smaldone@utdallas.edu.
authors.forename: John P
authors.initials: JP
authors.lastname: Ferraris
authors.affiliation: Department of Chemistry and Biochemistry, The University of Texas, Dallas, 800 W. Campbell Rd. Richardson, Texas, 75080, USA. ronald.smaldone@utdallas.edu.
authors.forename: Ronald A
authors.initials: RA
authors.lastname: Smaldone