title: Boosted Supercapacitive Energy with High Rate Capability of aCarbon Framework with Hierarchical Pore Structure in an Ionic Liquid.
abstract: The specific energy of a supercapacitor (SC) with an ionic liquid (IL)-based electrolyte is larger than that using an aqueous electrolyte owing to the wide operating voltage window provided by the IL. However, the wide-scale application of high-energy SCs using ILs is limited owing to a serious reduction of the energy with increasing power. The introduction of macropores to the porous material can mitigate the reduction in the gravimetric capacitance at high rates, but this lowers the volumetric capacitance. Synthetic polymers can be used to obtain macroporous frameworks with high apparent densities, but the preservation of the frameworks during activation is challenging. To simultaneously achieve high gravimetric capacitance, volumetric capacitance, and rate capability, a systematic strategy was used to synthesize a densely knitted carbon framework with a hierarchical pore structure by using a polymer. The energy of the SC using the hierarchically porous carbon was 160 Wh kg-1and 85 Wh L-1on an active material base at a power of 100 W kg-1in an IL electrolyte, and 60 % of the energy was still retained at a power larger than 5000 W kg-1. To illustrate, a full-packaged SC with the material could store/release energy comparable to a Ni-metal hydride battery (gravimetrically) and one order of magnitude higher than a commercial carbon-based SC (volumetrically), within one minute.
authors.affiliation: Department of Chemical Engineering, Norwegian University of Science and Technology, Sem Saelands vei 4, 7491, Trondheim, Norway.
authors.forename: Xuehang
authors.initials: X
authors.lastname: Wang
authors.affiliation: Department of Chemical Engineering, Norwegian University of Science and Technology, Sem Saelands vei 4, 7491, Trondheim, Norway.
authors.forename: Haitao
authors.initials: H
authors.lastname: Zhou
authors.affiliation: Department of Chemical Engineering, Norwegian University of Science and Technology, Sem Saelands vei 4, 7491, Trondheim, Norway.
authors.forename: Fengliu
authors.initials: F
authors.lastname: Lou
authors.affiliation: Department of Chemical Engineering, Norwegian University of Science and Technology, Sem Saelands vei 4, 7491, Trondheim, Norway.
authors.forename: Yahao
authors.initials: Y
authors.lastname: Li
authors.affiliation: Department of Chemical Engineering, Norwegian University of Science and Technology, Sem Saelands vei 4, 7491, Trondheim, Norway.
authors.forename: Marthe E M
authors.initials: ME
authors.lastname: Buan
authors.affiliation: Department of Chemical Engineering, Norwegian University of Science and Technology, Sem Saelands vei 4, 7491, Trondheim, Norway.
authors.forename: Xuezhi
authors.initials: X
authors.lastname: Duan
authors.affiliation: SINTEF Materials and Chemistry, Strindveien 4, 7034, Trondheim, Norway.
authors.forename: John C
authors.initials: JC
authors.lastname: Walmsley
authors.affiliation: SINTEF Materials and Chemistry, Strindveien 4, 7034, Trondheim, Norway.
authors.forename: Edel
authors.initials: E
authors.lastname: Sheridan
authors.affiliation: Department of Chemical Engineering, Norwegian University of Science and Technology, Sem Saelands vei 4, 7491, Trondheim, Norway.
authors.forename: De
authors.lastname: Chen
mesh_terms: D025802:Electric Capacitance; D011211:Electric Power Supplies; D004573:Electrolytes / Q000737:chemistry; D052578:Ionic Liquids / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry; D016062:Porosity
chemical_list: D004573:Electrolytes; D052578:Ionic Liquids; D011108:Polymers
keywords: carbon; energy storage; hierarchical structure; macroporous framework; supercapacitors