title: A highly porous rht-type acylamide-functionalized metal-organic framework exhibiting large CO2uptake capabilities.
abstract: A new, highly porous acylamide-functionalized MOF with a (3,24)-connected rht-type network (HNUST-5) has been synthesized and structurally determined using powder X-ray diffraction. HNUST-5 exhibits a high BET surface area of 3643 m2g-1, and a large CO2uptake capability (38.9 mmol g-1under 36 bar) with an excellent selectivity of CO2/CH4(7.3) and CO2/N2(32.5) at 273 K.
authors.affiliation: Key Laboratory of Theoretical Organic Chemistry and Function Molecule of Ministry of Education, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201, China. zbaishu@163.com hnust_chem@163.com and State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210023, China.
authors.forename: Baishu
authors.initials: B
authors.lastname: Zheng
authors.affiliation: Key Laboratory of Theoretical Organic Chemistry and Function Molecule of Ministry of Education, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201, China. zbaishu@163.com hnust_chem@163.com.
authors.forename: Hang
authors.initials: H
authors.lastname: Wang
authors.affiliation: Key Laboratory of Theoretical Organic Chemistry and Function Molecule of Ministry of Education, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201, China. zbaishu@163.com hnust_chem@163.com.
authors.forename: Zhaoxu
authors.initials: Z
authors.lastname: Wang
authors.affiliation: ST-ERATO, Itami Molecular Nanocarbon Project, Chikusa, Nagoya, 464-8602, Japan.
authors.forename: Noriaki
authors.initials: N
authors.lastname: Ozaki
authors.affiliation: State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210023, China.
authors.forename: Cheng
authors.initials: C
authors.lastname: Hang
authors.affiliation: Key Laboratory of Theoretical Organic Chemistry and Function Molecule of Ministry of Education, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201, China. zbaishu@163.com hnust_chem@163.com.
authors.forename: Xin
authors.initials: X
authors.lastname: Luo
authors.affiliation: Key Laboratory of Theoretical Organic Chemistry and Function Molecule of Ministry of Education, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201, China. zbaishu@163.com hnust_chem@163.com.
authors.forename: Lu
authors.initials: L
authors.lastname: Huang
authors.affiliation: Key Laboratory of Theoretical Organic Chemistry and Function Molecule of Ministry of Education, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201, China. zbaishu@163.com hnust_chem@163.com.
authors.forename: Wenjiang
authors.initials: W
authors.lastname: Zeng
authors.affiliation: Key Laboratory of Theoretical Organic Chemistry and Function Molecule of Ministry of Education, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201, China. zbaishu@163.com hnust_chem@163.com.
authors.forename: Ming
authors.initials: M
authors.lastname: Yang
authors.affiliation: State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210023, China and State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing, 210009, China. duanjingui@njtech.edu.cn.
authors.forename: Jingui
authors.initials: J
authors.lastname: Duan