title: Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex.
abstract: A cyanide-bridged [Co3Fe2] cluster with trigonal bipyramidal geometry shows solvent-driven reversible on/off switching of its thermally induced electron-transfer-coupled spin transition (ETCST) behaviour.
authors.affiliation: Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8571, Japan. oshio@chem.tsukuba.ac.jp.
authors.forename: Rong-Jia
authors.identifier: http://orcid.org/0000-0001-7898-567X
authors.initials: RJ
authors.lastname: Wei
authors.affiliation: Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8571, Japan. oshio@chem.tsukuba.ac.jp.
authors.forename: Ryohei
authors.initials: R
authors.lastname: Nakahara
authors.affiliation: Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8571, Japan. oshio@chem.tsukuba.ac.jp.
authors.forename: Jamie M
authors.identifier: http://orcid.org/0000-0003-0138-933X
authors.initials: JM
authors.lastname: Cameron
authors.affiliation: Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8571, Japan. oshio@chem.tsukuba.ac.jp and School of Chemistry, The University of Nottingham, University Park, Nottingham, NG7 2RD, UK.
authors.forename: Graham N
authors.initials: GN
authors.lastname: Newton
authors.affiliation: Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8571, Japan. oshio@chem.tsukuba.ac.jp.
authors.forename: Takuya
authors.initials: T
authors.lastname: Shiga
authors.affiliation: Photon Factory and Condensed Matter Research Center, Institute of Materials Structure Science, High Energy Accelerator Research Organization (KEK), Tsukuba 305-0801, Japan.
authors.forename: Hajime
authors.initials: H
authors.lastname: Sagayama
authors.affiliation: Photon Factory and Condensed Matter Research Center, Institute of Materials Structure Science, High Energy Accelerator Research Organization (KEK), Tsukuba 305-0801, Japan.
authors.forename: Reiji
authors.initials: R
authors.lastname: Kumai
authors.affiliation: Photon Factory and Condensed Matter Research Center, Institute of Materials Structure Science, High Energy Accelerator Research Organization (KEK), Tsukuba 305-0801, Japan.
authors.forename: Youichi
authors.initials: Y
authors.lastname: Murakami
authors.affiliation: Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8571, Japan. oshio@chem.tsukuba.ac.jp.
authors.forename: Hiroki
authors.identifier: http://orcid.org/0000-0002-4682-4705
authors.initials: H
authors.lastname: Oshio