title: Intermetal oxygen atom transfer from an FeVO complex to a MnIIIcomplex: an experimental and theoretical approach.
abstract: Oxygen atom transfer (OAT) reaction between an FeVO complex and a MnIIIcomplex resulted in the eventual formation of their corresponding FeIIIand MnVO complexes. The reaction proceeded via an initial fast OAT reaction between the FeVO and MnIIIcomplexes, yielding a half equivalent of a MnVO complex and a μ-oxo bridged FeIVdimer. The dimer regenerated the FeVO species via equilibrium, which then reacted with the remaining MnIIIcomplex to produce another half equivalent of the MnVO complex.
authors.affiliation: Department of Chemistry and Nano Science, Ewha Womans University, Seoul 03760, Korea. wwnam@ewha.ac.kr.
authors.forename: Seungwoo
authors.initials: S
authors.lastname: Hong
authors.affiliation: Department of Chemistry and Nano Science, Ewha Womans University, Seoul 03760, Korea. wwnam@ewha.ac.kr.
authors.forename: Soo Jeong
authors.initials: SJ
authors.lastname: Jang
authors.affiliation: Department of Chemistry and Nano Science, Ewha Womans University, Seoul 03760, Korea. wwnam@ewha.ac.kr.
authors.forename: Kyung-Bin
authors.initials: KB
authors.lastname: Cho
authors.affiliation: Department of Chemistry and Nano Science, Ewha Womans University, Seoul 03760, Korea. wwnam@ewha.ac.kr.
authors.forename: Wonwoo
authors.initials: W
authors.lastname: Nam