title: Topology-dependent emissive properties of zirconium-based porphyrin MOFs.
abstract: Highly ordered chromophoric linkers positioned within the metal-organic frameworks (MOFs) have the potential to mimic natural light-harvesting complexes. Herein we report topological control over the photophysical properties of MOFs via modular interchromophoric electronic coupling to manifest different steady-state singlet emission spectra and their corresponding fluorescence lifetimes.
authors.affiliation: Department of Chemistry and Biochemistry, Southern Illinois University, 1245 Lincoln Drive, Carbondale, Illinois 62901, USA. pderia@siu.edu.
authors.forename: Pravas
authors.identifier: http://orcid.org/0000-0001-7998-4492
authors.initials: P
authors.lastname: Deria
authors.affiliation: Department of Chemistry and Biochemistry, Southern Illinois University, 1245 Lincoln Drive, Carbondale, Illinois 62901, USA. pderia@siu.edu.
authors.forename: Jierui
authors.initials: J
authors.lastname: Yu
authors.affiliation: Department of Chemistry and Biochemistry, Southern Illinois University, 1245 Lincoln Drive, Carbondale, Illinois 62901, USA. pderia@siu.edu.
authors.forename: Rajesh P
authors.initials: RP
authors.lastname: Balaraman
authors.affiliation: Department of Chemistry and Biochemistry, Southern Illinois University, 1245 Lincoln Drive, Carbondale, Illinois 62901, USA. pderia@siu.edu.
authors.forename: Jamil
authors.initials: J
authors.lastname: Mashni
authors.affiliation: Department of Chemistry and Biochemistry, Southern Illinois University, 1245 Lincoln Drive, Carbondale, Illinois 62901, USA. pderia@siu.edu.
authors.forename: Sandra N
authors.initials: SN
authors.lastname: White