title: Multifaceted magnetization dynamics in the mononuclear complex [ReIVCl4(CN)2]2.
abstract: The mononuclear complex (Bu4N)2[ReIVCl4(CN)2]·2DMA (DMA = N,N-dimethylacetamide) displays intricate magnetization dynamics, implying Orbach, direct, and Raman-type relaxation processes. The Orbach relaxation process is characterized by an energy barrier of 39 K (27 cm-1) that is discussed based on high-field electron paramagnetic resonance (EPR), inelastic neutron scattering and frequency-domain THz EPR investigations.
authors.affiliation: Department of Chemistry, University of California Berkeley, California 94720, USA. jrlong@berkeley.edu.
authors.forename: Xiaowen
authors.initials: X
authors.lastname: Feng
authors.affiliation: MOE Key Lab of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, P. R. China and CNRS, CRPP, UPR 8641, F-33600 Pessac, France. clerac@crpp-bordeaux.cnrs.fr and Univ. Bordeaux, CRPP, UPR 8641, F-33600 Pessac, France.
authors.forename: Jun-Liang
authors.identifier: http://orcid.org/0000-0002-5811-6300
authors.initials: JL
authors.lastname: Liu
authors.affiliation: CNRS, CRPP, UPR 8641, F-33600 Pessac, France. clerac@crpp-bordeaux.cnrs.fr and Univ. Bordeaux, CRPP, UPR 8641, F-33600 Pessac, France and CNRS, ICMCB, UPR 9048, F-33600 Pessac, France.
authors.forename: Kasper S
authors.initials: KS
authors.lastname: Pedersen
authors.affiliation: Berlin Joint EPR Laboratory, Institut für Nanospektroskopie, Helmholtz-Zentrum für Materialien und Energie, 12489 Berlin, Germany.
authors.forename: Joscha
authors.initials: J
authors.lastname: Nehrkorn
authors.affiliation: Berlin Joint EPR Laboratory, Institut für Nanospektroskopie, Helmholtz-Zentrum für Materialien und Energie, 12489 Berlin, Germany.
authors.forename: Alexander
authors.initials: A
authors.lastname: Schnegg
authors.affiliation: Helmholtz-Zentrum für Materialien und Energie, Inst. f. Methoden und Instrumente der Forschung mit Synchrotronstrahlung, 12489 Berlin, Germany.
authors.forename: Karsten
authors.initials: K
authors.lastname: Holldack
authors.affiliation: Department of Chemistry, University of Copenhagen, DK-2100 Copenhagen, Denmark.
authors.forename: Jesper
authors.initials: J
authors.lastname: Bendix
authors.affiliation: Institut Laue-Langevin, 38042 Grenoble Cedex 9, France and Institute of Chemistry, Academia Sinica, Nankang, 11529 Taipei, Taiwan, ROC.
authors.forename: Marc
authors.initials: M
authors.lastname: Sigrist
authors.affiliation: Institut Laue-Langevin, 38042 Grenoble Cedex 9, France.
authors.forename: Hannu
authors.initials: H
authors.lastname: Mutka
authors.affiliation: CNRS, CRPP, UPR 8641, F-33600 Pessac, France. clerac@crpp-bordeaux.cnrs.fr and Univ. Bordeaux, CRPP, UPR 8641, F-33600 Pessac, France.
authors.forename: Dumitru
authors.initials: D
authors.lastname: Samohvalov
authors.affiliation: CNRS, CRPP, UPR 8641, F-33600 Pessac, France. clerac@crpp-bordeaux.cnrs.fr and Univ. Bordeaux, CRPP, UPR 8641, F-33600 Pessac, France.
authors.forename: David
authors.initials: D
authors.lastname: Aguilà
authors.affiliation: MOE Key Lab of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, P. R. China.
authors.forename: Ming-Liang
authors.identifier: http://orcid.org/0000-0003-4725-0798
authors.initials: ML
authors.lastname: Tong
authors.affiliation: Department of Chemistry, University of California Berkeley, California 94720, USA. jrlong@berkeley.edu and Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA and Department of Chemical and Biomolecular Engineering, University of California Berkeley, Berkeley, California 94720, USA.
authors.forename: Jeffrey R
authors.initials: JR
authors.lastname: Long
authors.affiliation: CNRS, CRPP, UPR 8641, F-33600 Pessac, France. clerac@crpp-bordeaux.cnrs.fr and Univ. Bordeaux, CRPP, UPR 8641, F-33600 Pessac, France.
authors.forename: Rodolphe
authors.initials: R
authors.lastname: Clérac