title: Application of chitosan/poly(vinyl alcohol)/CuO (CS/PVA/CuO) beads as an adsorbent material for the removal of Pb(II) from aqueous environment.
abstract: The utilization of CS/PVA/CuO as a novel adsorbent for the removal of Pb(II) from aqueous solution has been examined in a batch adsorption process with several experimental conditions including initial solution pH, dose, contact time, initial metal ion concentration, and temperature. The new and novel material was characterized by structural (XRD), spectral (FTIR), morphological with elemental (SEM with EDS), and size of the nanoparticles (TEM) analyses. The pseudo-first-order, pseudo-second-order and intraparticle diffusion kinetics equations were used to analyze the kinetic data of the adsorption process and the data was fitted well with the pseudo-second-order kinetic model with R2values (close to the unity). Equilibrium isotherms for the adsorption of Pb(II) were analyzed by the Langmuir, Freundlich, and D-R isotherm models. The best interpretation for the equilibrium data was given by Langmuir isotherm, and the maximum adsorption capacity was 116.84mg/g at pH 5, and adsorbent dose of 100mg at 323K. Different thermodynamic parameters namely, Gibbs free energy change (-8.436, -9.167 and -9.723kJ/mol for 303, 313 and 323K respectively), enthalpy change (11.61, 11.52 and 11.62kJ/mol), and entropy change (0.0661J/mol k), were also evaluated from the temperature dependence, and the results suggest that the adsorption reaction is spontaneous and endothermic in nature.
authors.affiliation: School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, PR China.
authors.forename: Xu
authors.initials: X
authors.lastname: Jiao
authors.affiliation: School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, PR China. Electronic address: guthayuvaraja@tju.edu.cn.
authors.forename: Yuvaraja
authors.initials: Y
authors.lastname: Gutha
authors.affiliation: School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, PR China.
authors.forename: Weijiang
authors.initials: W
authors.lastname: Zhang
mesh_terms: D000327:Adsorption; D002413:Cations, Divalent; D048271:Chitosan / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D006801:Humans; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D007854:Lead / Q000302:isolation & purification*; D011142:Polyvinyl Alcohol / Q000737:chemistry*; D013696:Temperature; D013816:Thermodynamics; D062065:Wastewater / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods
chemical_list: D002413:Cations, Divalent; D048271:Chitosan; D003300:Copper; D007854:Lead; D011142:Polyvinyl Alcohol; D062065:Wastewater; D014874:Water Pollutants, Chemical; C030973:cupric oxide
keywords: Adsorption; Chitosan; CuO nanorods; PVA; Pb(II)