title: Construction of High-Nuclearity Manganese-Cluster-Organic Frameworks by Using a Tripodal Alcohol Ligand.
abstract: Two novel cluster-organic frameworks based on the 12-nuclearity manganese-cluster secondary building unit (SBU), [MnIII4MnII8(L)4(Ac)8(MeO)2(μ5-O)2(H2O)4](Ac)2·16H2O (1) and [MnIII4MnII8(L)4(Ac)8(MeO)2(μ5-O)2(H2O)4](Ac)2·12H2O (2), where Ac = CH3COO-and MeO = CH3O, have been constructed from solvothermal reactions of the 3-nuclearity manganese cluster [Mn3(μ3-O)(Ac)6(py)3](ClO4) (Mn3, where py = pyridine) with a tripodal alcohol ligand containing a 4-pyridyl group. 1 and 2 represent the first examples of metal-organic frameworks containing 12-nuclearity manganese-cluster SBUs. In addition, 1 exhibits an integration of the porosity and magnetic properties from both the framework and cluster in a porous material.
authors.affiliation: State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University , Fuzhou, Fujian 350108, China.
authors.forename: Xiang
authors.initials: X
authors.lastname: Ma
authors.affiliation: Fuqing Branch of Fujian Normal University , Fuqing, Fujian 350300, China.
authors.forename: Dan
authors.initials: D
authors.lastname: Zhao
authors.affiliation: State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University , Fuzhou, Fujian 350108, China.
authors.forename: Li-Fen
authors.initials: LF
authors.lastname: Lin
authors.affiliation: State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University , Fuzhou, Fujian 350108, China.
authors.forename: Shao-Jie
authors.initials: SJ
authors.lastname: Qin
authors.affiliation: State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University , Fuzhou, Fujian 350108, China.
authors.forename: Wen-Xu
authors.initials: WX
authors.lastname: Zheng
authors.affiliation: State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University , Fuzhou, Fujian 350108, China.
authors.forename: Yan-Jie
authors.initials: YJ
authors.lastname: Qi
authors.affiliation: State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University , Fuzhou, Fujian 350108, China.
authors.forename: Xin-Xiong
authors.initials: XX
authors.lastname: Li
authors.affiliation: State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University , Fuzhou, Fujian 350108, China.
authors.forename: Shou-Tian
authors.initials: ST
authors.lastname: Zheng