title: Nucleophilic Additions to Coordinated 1,10-Phenanthroline: Intramolecular, Intermolecular, Reversible, and Irreversible.
abstract: KN(SiMe3)2reacts with [Re(CO)3(phen)(PMe3)]OTf via reversible addition to the phen ligand and irreversible deprotonation of the PMe3ligand followed by intramolecular attack to phen by the deprotonated phosphane, whereas MeLi irreversibly adds to phen. The addition of MeLi has been shown to be intermolecular, unlike previously known nucleophilic additions to pyridines.
authors.affiliation: Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, Julián Clavería 8, 33006, Oviedo, Spain.
authors.forename: Rebeca
authors.initials: R
authors.lastname: Arévalo
authors.affiliation: Departamento de Química Física y Analítica, Universidad de Oviedo, Julián Clavería 8, 33006, Oviedo, Spain.
authors.forename: M Isabel
authors.initials: MI
authors.lastname: Menéndez
authors.affiliation: Departamento de Química Física y Analítica, Universidad de Oviedo, Julián Clavería 8, 33006, Oviedo, Spain.
authors.forename: Ramón
authors.initials: R
authors.lastname: López
authors.affiliation: Unidad de Resonancia Magnética Nuclear, Servicios Científico-Técnicos de la Universidad de Oviedo, Fernando Bongera s/n, 33006, Oviedo, Spain.
authors.forename: Isabel
authors.initials: I
authors.lastname: Merino
authors.affiliation: Centro de Investigación en Nanomateriales y Nanotecnología (CINN), CSIC-Universidad de Oviedo-Principado de Asturias, Avda. de la Vega 4-6, 33940, El Entrego, Spain.
authors.forename: Lucía
authors.initials: L
authors.lastname: Riera
authors.affiliation: Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, Julián Clavería 8, 33006, Oviedo, Spain.|Centro de Investigación en Nanomateriales y Nanotecnología (CINN), CSIC-Universidad de Oviedo-Principado de Asturias, Avda. de la Vega 4-6, 33940, El Entrego, Spain.
authors.forename: Julio
authors.initials: J
authors.lastname: Pérez
keywords: N ligands; nucleophilic addition; phenanthroline complexes; pyridine dearomatization; rhenium carbonyls