title: Comparative Study of the Catalytic Activities of Three Distinct Carbonaceous Materials through Photocatalytic Oxidation, CO Conversion, Dye Degradation, and Electrochemical Measurements.
abstract: In order to compare the catalytic activities of reduced graphene oxide (rGO), graphene oxide (GO), and graphene, we conducted oxidation of 2-aminothiophenol (2-ATP) and reduction of nitrobenzene (NB) in their presence by using high-resolution photoemission spectroscopy (HRPES). In addition, we determined conversion rates of CO to CO2in the presence of these catalysts by performing a residual gas analyzer (RGA) under a UHV condition, Orange II and methylene blue degradations UV-vis spectrophotometry, and electrochemistry (EC) measurements in an aqueous solution, as well as by obtaining cyclic voltammograms and determining the change of the condition of electrodes before and after the oxidation of 2-ATP. We found that we can successively fabricate GO (oxidation) and graphene (reduction) from rGO by controlling the oxidation or reduction procedure time and then clearly comparing the critical properties among them as we perform various oxidation and reduction activities.
authors.affiliation: Department of Chemistry, Sookmyung Women's University, Seoul 140-742, Republic of Korea.
authors.forename: Hangil
authors.initials: H
authors.lastname: Lee
authors.affiliation: Molecular-Level Interfaces Research Center, Department of Chemistry, KAIST, Daejeon 305-701, Republic of Korea.
authors.forename: Yeonwoo
authors.initials: Y
authors.lastname: Kim
authors.affiliation: Department of Chemistry, Sookmyung Women's University, Seoul 140-742, Republic of Korea.
authors.forename: Min Ji
authors.initials: MJ
authors.lastname: Kim
authors.affiliation: Beamline Research Division, Pohang Accelerator Laboratory (PAL), Pohang 790-784, Republic of Korea.
authors.forename: Ki-Jeong
authors.initials: KJ
authors.lastname: Kim
authors.affiliation: Department of Chemistry, Sookmyung Women's University, Seoul 140-742, Republic of Korea.
authors.forename: Byung-Kwon
authors.initials: BK
authors.lastname: Kim