title: Both Inter- and Intramolecular Coupling of O-H Groups Determine the Vibrational Response of the Water/Air Interface.
abstract: Vibrational coupling is relevant not only for dissipation of excess energy after chemical reactions but also for elucidating molecular structure and dynamics. It is particularly important for O-H stretch vibrational spectra of water, for which it is known that in bulk both intra- and intermolecular coupling alter the intensity and line shape of the spectra. In contrast with bulk, the unified picture of the inter/intra-molecular coupling of O-H groups at the water-air interface has been lacking. Here, combining sum-frequency generation experiments and simulation for isotopically diluted water and alcohols, we unveil effects of inter- and intramolecular coupling on the vibrational spectra of interfacial water. Our results show that both inter- and intramolecular coupling contribute to the O-H stretch vibrational response of the neat H2O surface, with intramolecular coupling generating a double-peak feature, while the intermolecular coupling induces a significant red shift in the O-H stretch response.
authors: Max Planck Institute for Polymer Research , Ackermannweg 10, 55128 Mainz, Germany.
authors: Jan
authors: J
authors: Schaefer
authors: Max Planck Institute for Polymer Research , Ackermannweg 10, 55128 Mainz, Germany.
authors: Ellen H G
authors: EH
authors: Backus
authors: Max Planck Institute for Polymer Research , Ackermannweg 10, 55128 Mainz, Germany.
authors: Yuki
authors: Y
authors: Nagata
authors: Max Planck Institute for Polymer Research , Ackermannweg 10, 55128 Mainz, Germany.
authors: Mischa
authors: M
authors: Bonn