title: Pd-Catalyzed Regioselective Arylboration of Vinylarenes.
abstract: A palladium-catalyzed 1,2-arylboration of vinylarenes with aryldiazonium tetrafluoroborates and bis(pinacolato)diboron has been disclosed. It is reported for the first time that styrene derivatives can be successfully employed as good substrates for 1,2-arylboration of alkenes. Mechanistic studies suggest that no Pd-H reinsertion occurred under our standard conditions, which is the key for the success of this transformation.
authors: Institute of Next Generation Matter Transformation, College of Chemical Engineering, Huaqiao University , 668 Jimei Boulevard, Xiamen, Fujian 361021, P. R. China.
authors: Kai
authors: K
authors: Yang
authors: Institute of Next Generation Matter Transformation, College of Chemical Engineering, Huaqiao University , 668 Jimei Boulevard, Xiamen, Fujian 361021, P. R. China.|National Laboratory for Molecular Sciences, Institute of Chemistry, CAS , Beijing 100190, P. R. China.
authors: Qiuling
authors: Q
authors: Song