title: Replacement of Calcite (CaCO3) by Cerussite (PbCO3).
abstract: The mobility of toxic elements, such as lead (Pb) can be attenuated by adsorption, incorporation, and precipitation on carbonate minerals in subsurface environments. Here, we report a study of the bulk transformation of single-crystal calcite (CaCO3) into polycrystalline cerussite (PbCO3) through reaction with acidic Pb-bearing solutions. This reaction began with the growth of a cerussite shell on top of calcite surfaces followed by the replacement of the remaining calcite core. The external shape of the original calcite was preserved by a balance between calcite dissolution and cerussite growth controlled by adjusting the Pb2+concentration and pH. The relation between the rounded calcite core and the surrounding lath-shaped cerussite aggregates was imaged by transmission X-ray microscopy, which revealed preferentially elongated cerussite crystals parallel to the surface and edge directions of calcite. The replacement reaction involved concurrent development of ∼100 nm wide pores parallel to calcite c-glide or (12̅0) planes, which may have provided permeability for chemical exchange during the reaction. X-ray reflectivity measurements showed no clear epitaxial relation of cerussite to the calcite (104) surface. These results demonstrate Pb sequestration through mineral replacement reactions and the critical role of nanoporosity (3% by volume) on the solid phase transformation through a dissolution-recrystallization mechanism.
authors: Ke
authors: K
authors: Yuan
authors: Sang Soo
authors: SS
authors: Lee
authors: Vincent
authors: V
authors: De Andrade
authors: Department of Geological Sciences, University of Delaware , Newark, Delaware 19716, United States.
authors: Neil C
authors: NC
authors: Sturchio
authors: Paul
authors: P
authors: Fenter
mesh_terms: D000327:Adsorption; D002119:Calcium Carbonate / Q000737:chemistry*; D008903:Minerals; D012996:Solutions
chemical_list: D008903:Minerals; D012996:Solutions; D002119:Calcium Carbonate