title: Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium-Catalyzed Arylation.
abstract: The synthesis of a newC3v-symmetric crushed fullerene C60H24(5) has been accomplished in three steps from truxene through sixfold palladium-catalyzed intramolecular arylation of asyn-trialkylated truxene precursor. Laser irradiation of5induces cyclodehydrogenation processes that result in the formation of C60, as detected by LDI-MS.
authors: Institute of Chemical Research of Catalonia (ICIQ) Barcelona Institute of Science and Technology Av. Països Catalans 16 43007 Tarragona Spain.
authors: Ruth
authors: R
authors: Dorel
authors: Institute of Chemical Research of Catalonia (ICIQ) Barcelona Institute of Science and Technology Av. Països Catalans 16 43007 Tarragona Spain.
authors: Paula
authors: P
authors: de Mendoza
authors: Institute of Chemical Research of Catalonia (ICIQ) Barcelona Institute of Science and Technology Av. Països Catalans 16 43007 Tarragona Spain.
authors: Pilar
authors: P
authors: Calleja
authors: Institute of Chemical Research of Catalonia (ICIQ) Barcelona Institute of Science and Technology Av. Països Catalans 16 43007 Tarragona Spain.
authors: Sergio
authors: S
authors: Pascual
authors: Institute of Chemical Research of Catalonia (ICIQ) Barcelona Institute of Science and Technology Av. Països Catalans 16 43007 Tarragona Spain.
authors: Esther
authors: E
authors: González-Cantalapiedra
authors: Institute of Chemical Research of Catalonia (ICIQ) Barcelona Institute of Science and Technology Av. Països Catalans 16 43007 Tarragona Spain.
authors: Noemí
authors: N
authors: Cabello
authors: Institute of Chemical Research of Catalonia (ICIQ) Barcelona Institute of Science and Technology Av. Països Catalans 16 43007 Tarragona Spain; Departament de Química Orgànica i Analítica Universitat Rovira i Virgili C/ Marcel·lí Domingo s/n 43007 Tarragona Spain.
authors: Antonio M
authors: 0000-0001-6808-3007
authors: AM
authors: Echavarren
keywords: Arylation; Fullerenes; Mass spectrometry; Palladium; Truxene