title: Atomic Linkage Flexibility Tuned Isotropic Negative, Zero, and Positive Thermal Expansion in MZrF6(M = Ca, Mn, Fe, Co, Ni, and Zn).
abstract: The controllable isotropic thermal expansion with a broad coefficient of thermal expansion (CTE) window is intriguing but remains challenge. Herein we report a cubic MZrF6series (M = Ca, Mn, Fe, Co, Ni and Zn), which exhibit controllable thermal expansion over a wide temperature range and with a broader CTE window (-6.69 to +18.23 × 10-6/K). In particular, an isotropic zero thermal expansion (ZTE) is achieved in ZnZrF6, which is one of the rarely documented high-temperature isotropic ZTE compounds. By utilizing temperature-dependent high-energy synchrotron X-ray total scattering diffraction, it is found that the flexibility of metal···F atomic linkages in MZrF6plays a critical role in distinct thermal expansions. The flexible metal···F atomic linkages induce negative thermal expansion (NTE) for CaZrF6, whereas the stiff ones bring positive thermal expansion (PTE) for NiZrF6. Thermal expansion could be transformed from striking negative, to zero, and finally to considerable positive though tuning the flexibility of metal···F atomic linkages by substitution with a series of cations on M sites of MZrF6. The present study not only extends the scope of NTE families and rare high-temperature isotropic ZTE compounds but also proposes a new method to design systematically controllable isotropic thermal expansion frameworks from the perspective of atomic linkage flexibility.
authors: Department of Physical Chemistry, University of Science and Technology Beijing , Beijing 100083, China.
authors: Lei
authors: L
authors: Hu
authors: Department of Physical Chemistry, University of Science and Technology Beijing , Beijing 100083, China.
authors: Jun
authors: J
authors: Chen
authors: Department of Physical Chemistry, University of Science and Technology Beijing , Beijing 100083, China.
authors: Jiale
authors: J
authors: Xu
authors: Department of Physical Chemistry, University of Science and Technology Beijing , Beijing 100083, China.
authors: Na
authors: N
authors: Wang
authors: Department of Physical Chemistry, University of Science and Technology Beijing , Beijing 100083, China.
authors: Fei
authors: F
authors: Han
authors: X-ray Science Division, Argonne National Laboratory , Argonne, Illinois 60439, United States.
authors: Yang
authors: Y
authors: Ren
authors: Department of Physical Chemistry, University of Science and Technology Beijing , Beijing 100083, China.
authors: Zhao
authors: Z
authors: Pan
authors: Department of Physical Chemistry, University of Science and Technology Beijing , Beijing 100083, China.
authors: Yangchun
authors: Y
authors: Rong
authors: Key Laboratory of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences , Beijing 100190, China.
authors: Rongjin
authors: R
authors: Huang
authors: Department of Physical Chemistry, University of Science and Technology Beijing , Beijing 100083, China.
authors: Jinxia
authors: J
authors: Deng
authors: Key Laboratory of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences , Beijing 100190, China.
authors: Laifeng
authors: L
authors: Li
authors: Department of Physical Chemistry, University of Science and Technology Beijing , Beijing 100083, China.
authors: Xianran
authors: X
authors: Xing