title: Electrosynthesis Using a Recyclable Mediator-Electrolyte System Based on Ionically Tagged Phenyl Iodide and 1,1,1,3,3,3-Hexafluoroisopropanol.
abstract: A new type of redox mediator for electrosynthesis based on the iodine(I)/iodine(III) redox couple is reported. It is demonstrated that the use of 1,1,1,3,3,3-hexafluoroisopropanol as solvent plays a crucial role for both the selective anodic generation of the active iodine(III) species and the subsequent chemical transformation. Furthermore, the supporting electrolyte is merged with the mediator by tethering the redox-active iodophenyl moiety to an alkylammonium group, allowing for straightforward recovery and reuse of both components.
authors: Institute of Chemistry, Rostock University , Albert-Einstein-Str. 3a, 18059 Rostock, Germany.
authors: Timo
authors: T
authors: Broese
authors: Institute of Chemistry, Rostock University , Albert-Einstein-Str. 3a, 18059 Rostock, Germany.
authors: Robert
authors: R
authors: Francke