title: Relay Rh(II)/Pd(0) Dual Catalysis: Selective Construction of Cyclic All-Quaternary Carbon Centers.
abstract: A novel relay Rh(II)/Pd(0) dual catalysis strategy that promotes the divergent reaction of α-diazo-carbonyl compounds with allylic carboxylates for the selective construction of cyclic all-quaternary carbon centers has been developed. This binary catalyst system rendered domino C-H insertion/allylic alkylation process under mild conditions. Remarkably, the domino catalytic reaction shows good selectivity and excellent tolerance to various functionalities and is operationally simple.
authors: Shaanxi Key Laboratory of Natural Products & Chemical Biology, College of Science, Northwest A&F University , Yangling 712100, PR China.
authors: Zi-Sheng
authors: ZS
authors: Chen
authors: Shaanxi Key Laboratory of Natural Products & Chemical Biology, College of Science, Northwest A&F University , Yangling 712100, PR China.
authors: Xiao-Yan
authors: XY
authors: Huang
authors: Shaanxi Key Laboratory of Natural Products & Chemical Biology, College of Science, Northwest A&F University , Yangling 712100, PR China.
authors: Jin-Ming
authors: JM
authors: Gao
authors: Shaanxi Key Laboratory of Natural Products & Chemical Biology, College of Science, Northwest A&F University , Yangling 712100, PR China.
authors: Kegong
authors: K
authors: Ji