title: Synthesis of a monomolecular anionic FLP complex.
abstract: Despite intense research in FLP chemistry, nothing is known about monomolecular anionic FLPs and/or complexes thereof. Herein, synthesis and reaction of the first anionic FLP complex is described using [(OC)5W{(Me3Si)2HCP(H)OLi(12-crown-4)}], Cy2BCl and subsequent deprotonation by KHMDS. The obtained anionic FLP complex reacts readily with CO2in a concerted manner.
authors: Institut for Inorganic Chemistry of the Rheinische Friedrich-Wilhelms-Universität Bonn, Gerhardt-Domagk-Strasse 1, 53121 Bonn, Germany. r.streubel@uni-bonn.de.
authors: A W
authors: AW
authors: Kyri
authors: Institut for Inorganic Chemistry of the Rheinische Friedrich-Wilhelms-Universität Bonn, Gerhardt-Domagk-Strasse 1, 53121 Bonn, Germany. r.streubel@uni-bonn.de.
authors: R
authors: R
authors: Kunzmann
authors: Institut for Inorganic Chemistry of the Rheinische Friedrich-Wilhelms-Universität Bonn, Gerhardt-Domagk-Strasse 1, 53121 Bonn, Germany. r.streubel@uni-bonn.de.
authors: G
authors: G
authors: Schnakenburg
authors: Mulliken Center of the Rheinische Friedrich-Wilhelms-Universität Bonn, Beringstr. 4, 53115 Bonn, Germany. grimme@thch.uni-bonn.de.
authors: Z-W
authors: ZW
authors: Qu
authors: Mulliken Center of the Rheinische Friedrich-Wilhelms-Universität Bonn, Beringstr. 4, 53115 Bonn, Germany. grimme@thch.uni-bonn.de.
authors: S
authors: S
authors: Grimme
authors: Institut for Inorganic Chemistry of the Rheinische Friedrich-Wilhelms-Universität Bonn, Gerhardt-Domagk-Strasse 1, 53121 Bonn, Germany. r.streubel@uni-bonn.de.
authors: R
authors: R
authors: Streubel