title: Gelation of Luminescent Supramolecular Cages and Transformation to Crystals with Trace-Doped-Enhancement Luminescence.
abstract: Supramolecular gels with hierarchical order and complexity have been assembled. The gels contain well-defined Ag4L2luminescent supramolecular cages as cores, which are cross-linked via Ag-P coordination bonding. The resulting gels are highly luminescent and exhibit rich stimuli-responsive behaviors toward mechanical and chemical (nitroexplosive and anions) stimuli. The gels could be transformed to highly luminescent crystal materials upon addition of halogen anions, in which only traces of lumiphor are accommodated in a host crystal matrix.
authors: Sun Yat-Sen University, Lehn Institute of Functional Materials, MOE Laboratory of Bioinorganic and Synthetic Chemistry, MOE Key Laboratory of Polymeric Composite and Functional Materials , Guangzhou 510275, China.
authors: Juan
authors: J
authors: Feng
authors: Sun Yat-Sen University, Lehn Institute of Functional Materials, MOE Laboratory of Bioinorganic and Synthetic Chemistry, MOE Key Laboratory of Polymeric Composite and Functional Materials , Guangzhou 510275, China.
authors: Lihua
authors: L
authors: Zeng
authors: Sun Yat-Sen University, Lehn Institute of Functional Materials, MOE Laboratory of Bioinorganic and Synthetic Chemistry, MOE Key Laboratory of Polymeric Composite and Functional Materials , Guangzhou 510275, China.
authors: Kunyu
authors: K
authors: Chen
authors: Sun Yat-Sen University, Lehn Institute of Functional Materials, MOE Laboratory of Bioinorganic and Synthetic Chemistry, MOE Key Laboratory of Polymeric Composite and Functional Materials , Guangzhou 510275, China.
authors: Haobin
authors: H
authors: Fang
authors: Sun Yat-Sen University, Lehn Institute of Functional Materials, MOE Laboratory of Bioinorganic and Synthetic Chemistry, MOE Key Laboratory of Polymeric Composite and Functional Materials , Guangzhou 510275, China.
authors: Jianyong
authors: J
authors: Zhang
authors: Sun Yat-Sen University, Lehn Institute of Functional Materials, MOE Laboratory of Bioinorganic and Synthetic Chemistry, MOE Key Laboratory of Polymeric Composite and Functional Materials , Guangzhou 510275, China.
authors: Zhenguo
authors: Z
authors: Chi
authors: Sun Yat-Sen University, Lehn Institute of Functional Materials, MOE Laboratory of Bioinorganic and Synthetic Chemistry, MOE Key Laboratory of Polymeric Composite and Functional Materials , Guangzhou 510275, China.
authors: Cheng-Yong
authors: CY
authors: Su