title: Asymmetric total synthesis of hedyosumin E aglycon, 7,10-epoxyhedyosminolide and ent-zedolactone A.
abstract: The asymmetric total syntheses of hedyosumin E aglycon, 7,10-epoxyhedyosminolide and ent-zedolactone A were realized, with the first two being achieved for the first time.
authors: CAS Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, 345 Lingling Road, Shanghai 200032, China. bfsun@sioc.ac.cn.
authors: Xuan
authors: X
authors: Wang
authors: Wang-Bin
authors: WB
authors: Sun
authors: Jian-Ping
authors: JP
authors: Zou
authors: Guo-Qiang
authors: GQ
authors: Lin
authors: Bing-Feng
authors: BF
authors: Sun
mesh_terms: D015107:4-Butyrolactone / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry; D002384:Catalysis; D018360:Crystallography, X-Ray; D061565:Cycloaddition Reaction; D008958:Models, Molecular; D045789:Sesquiterpenes, Guaiane / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: C507783:7,10-epoxy-hedyosminolide; D045789:Sesquiterpenes, Guaiane; C000626191:hedyosumin E; C416072:zedolactone A; D015107:4-Butyrolactone