title: Hetero-bimetallic paddlewheel clusters in coordination polymers formed by a water-induced single-crystal-to-single-crystal transformation.
abstract: Herein we report a water-induced single-crystal to single-crystal transformation that involves the formation of hetero-bimetallic paddlewheel clusters in coordination polymers. Through this transformation, which involves the cleavage and formation of different coordination bonds, two different Cu(ii)-Zn(ii) and Cu(ii)-Ni(ii) paddlewheel units exhibiting a 1 : 1 metal ratio were created.
authors: Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, Spain. inhar.imaz@icn2.cat daniel.maspoch@icn2.cat.
authors: Jorge
authors: J
authors: Albalad
authors: Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, Spain. inhar.imaz@icn2.cat daniel.maspoch@icn2.cat.
authors: Javier
authors: J
authors: Aríñez-Soriano
authors: Institut de Ciència de Materials de Barcelona (ICMAB-SCIC), Bellaterra, Spain and CIBER-BBN, Barcelona, Spain.
authors: José
authors: J
authors: Vidal-Gancedo
authors: Institut de Ciència de Materials de Barcelona (ICMAB-SCIC), Bellaterra, Spain and CIBER-BBN, Barcelona, Spain.
authors: Vega
authors: V
authors: Lloveras
authors: ALBA Synchrotron, 08290 Cerdanyola del Vallès, Barcelona, Catalonia, Spain.
authors: Jordi
authors: J
authors: Juanhuix
authors: Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, Spain. inhar.imaz@icn2.cat daniel.maspoch@icn2.cat.
authors: Inhar
authors: I
authors: Imaz
authors: Institut de Ciència de Materials de Barcelona (ICMAB-SCIC), Bellaterra, Spain and ICREA, Pg. Lluís Companys 23, 08010 Barcelona, Spain.
authors: Núria
authors: N
authors: Aliaga-Alcalde
authors: Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, Spain. inhar.imaz@icn2.cat daniel.maspoch@icn2.cat and ICREA, Pg. Lluís Companys 23, 08010 Barcelona, Spain.
authors: Daniel
authors: D
authors: Maspoch