title: Dual color emitting Eu doped strontium orthosilicate phosphors synthesized by bio-template assisted ultrasound for solid state lightning and display applications.
abstract: A novel Sr2SiO4:Eu (1-5mol %) superstructures (SS) were synthesized using bio-sacrificial A.V. gel assisted ultrasound method. Powder X-ray diffraction patterns confirmed the presence of both α and β phase formation. It was evident that the morphological growth was highly reliant on A.V. gel concentration, sonication time, pH and sonication power. The formation mechanisms for different hierarchical SS were proposed. From diffuse reflectance spectra, the energy band gap was estimated and found to be ∼4.70-5.11eV. The photoluminescence emission spectra for the excitation at 392nm, shows characteristic emission peaks at 593, 613, 654 and 702nm which were attributed to5D0→7F0,7F1,7F2and7F3transitions of Eu3+ions respectively. Conversely, when the samples were subjected to the heat treatment at 850°C for 3h under argon atmosphere, display an intense broad emission peak with two de-convoluted peaks at 490 and 550nm due to 4f65d1→4f1(8S7/2) transitions of Eu2+ions. The concentration quenching phenomenon was discussed which attributes to energy transfer, electron-phonon coupling and ion-ion interaction. The Judd-Ofelt intensity parameters and other radiative properties were estimated by using emission spectra. The CIE chromaticity coordinate values of Sr2SiO4:Eu2+and Eu3+nanophosphors were located in green and red regions respectively. The calculated CCT and CRI values specify that the present phosphor can be fairly useful for both green and red components of white LED's. Luminescence decay and quantum yield suggest the suitability of this phosphor as an efficient luminescent medium for light emitting diodes. Overall, the results elucidated a rapid, environmentally benign, cost-effective and convenient method for Sr2SiO4:Eu3+synthesis and for the possible applications such as solid state lighting and display devices.
authors: Department of Physics, Govt. First Grade College, Sira, Tumkur 572 103, India; Research and Development Center, Bharathiar University, Coimbatore 641 046, India.
authors: M
authors: M
authors: Venkataravanappa
authors: Prof. C.N.R. Rao Centre for Advanced Materials, Tumkur University, Tumkur 572 103, India. Electronic address: bhushanvlc@gmail.com.
authors: H
authors: H
authors: Nagabhushana
authors: Department of Physics, BMS Institute of Technology and Management, VTU-Affiliated, Bangalore 560 064, India.
authors: B
authors: B
authors: Daruka Prasad
authors: Department of Physics, Acharya Institute of Graduate Studies, Bangalore 560 107, India; Research and Development Center, Bharathiar University, Coimbatore 641 046, India.
authors: G P
authors: GP
authors: Darshan
authors: Prof. C.N.R. Rao Centre for Advanced Materials, Tumkur University, Tumkur 572 103, India.
authors: R B
authors: RB
authors: Basavaraj
authors: Department of Chemistry, University College of Science, Tumkur University Tumkur 572103, India.
authors: G R
authors: GR
authors: Vijayakumar
mesh_terms: D003116:Color; D005063:Europium / Q000737:chemistry*; D008030:Lightning; D049449:Luminescence; D010087:Oxides / Q000737:chemistry; D013324:Strontium / Q000737:chemistry*; D000069453:Ultrasonic Waves
chemical_list: D010087:Oxides; D005063:Europium; D013324:Strontium
keywords: Light emitting diodes; Nanophosphor; Photoluminescence; SS; Ultrasound