title: Redox-Neutral Rh(III)-Catalyzed Olefination of Carboxamides with Trifluoromethyl Allylic Carbonate.
abstract: The rhodium(III)-catalyzed olefination of various carboxamides with α-CF3-substituted allylic carbonate is described. This reaction provides direct access to linear CF3-allyl frameworks with complete trans-selectivity. In particular, a rhodium catalyst provided Heck-type γ-CF3-allylation products via the β-O-elimination of rhodacycle intermediate and subsequent olefin migration process.
authors: Jihye
authors: J
authors: Park
authors: Sangil
authors: S
authors: Han
authors: Mijin
authors: M
authors: Jeon
authors: Neeraj Kumar
authors: NK
authors: Mishra
authors: Seok-Yong
authors: SY
authors: Lee
authors: Biocenter, Gyeonggi Institute of Science & Technology Promotion, Suwon 443-270, Republic of Korea.
authors: Jong Suk
authors: JS
authors: Lee
authors: Jong Hwan
authors: JH
authors: Kwak
authors: Sung Hee
authors: SH
authors: Um
authors: In Su
authors: IS
authors: Kim