title: Unraveling the synthesis of homoleptic [Ag(N,N-diaryl-NHC)2]Y (Y = BF4, PF6) complexes by ball-milling.
abstract: A user-friendly and general mechanochemical method was developed to access rarely described NHC (N-heterocyclic carbene) silver(i) complexes featuring N,N-diarylimidazol(idin)ene ligands and non-coordinating tetrafluoroborate or hexafluorophosphate counter anions. Comparison with syntheses in solution clearly demonstrated the superiority of the ball-milling conditions.
authors: Institut des Biomolécules Max Mousseron (IBMM), UMR 5247, Université de Montpellier, CNRS, ENSCM, Université de Montpellier, Campus Triolet, Place Eugène Bataillon, 34095 Montpellier cedex 5, France. xavier.bantreil@umontpellier.fr thomas-xavier.metro@umontpellier.fr frederic.lamaty@umontpellier.fr.
authors: Audrey
authors: A
authors: Beillard
authors: Xavier
authors: X
authors: Bantreil
authors: Thomas-Xavier
authors: TX
authors: Métro
authors: Jean
authors: J
authors: Martinez
authors: Frédéric
authors: F
authors: Lamaty