title: Asymmetric Induction in Hydroacylation by Cooperative Iminium Ion-Transition-Metal Catalysis.
abstract: A new strategy for the rhodium-catalyzed enantioselective hydroacylation is described. This has been achieved through the merger of iminium ion catalysis and transition-metal catalysis such that asymmetric induction derives from a readily accessible, inexpensive chiral nonracemic secondary amine catalyst rather than a chiral nonracemic phosphine as is typical of conventional asymmetric hydroacylation methods.
authors: Department of Chemistry, University of Houston , Houston, Texas 77204-5003, United States.
authors: Ettore J
authors: EJ
authors: Rastelli
authors: Department of Chemistry, University of Houston , Houston, Texas 77204-5003, United States.
authors: Ngoc T
authors: NT
authors: Truong
authors: Department of Chemistry, University of Houston , Houston, Texas 77204-5003, United States.
authors: Don M
authors: DM
authors: Coltart