title: Tuning the structure of 1,3,5-benzene tricarboxamide self-assemblies through stereochemistry.
abstract: A heterochiral 1,3,5-benzene tricarboxamide (BTA) monomer, derived from valine dodecyl ester, forms long rods in cyclohexane whilst its homochiral analogue assembles into dimers only at the same concentration. This highly original assembly behaviour is related to the destabilization of the dimeric structure containing the two heterochiral monomers as corroborated by a combined experimental and computational study.
authors: Sorbonne Universités, UPMC Univ Paris 06, CNRS, Institut Parisien de Chimie Moléculaire, 4 Place Jussieu, F-75005 Paris, France. matthieu.raynal@upmc.fr.
authors: Xavier
authors: X
authors: Caumes
authors: Sorbonne Universités, UPMC Univ Paris 06, CNRS, Institut Parisien de Chimie Moléculaire, 4 Place Jussieu, F-75005 Paris, France. matthieu.raynal@upmc.fr.
authors: Arianna
authors: A
authors: Baldi
authors: Sorbonne Universités, UPMC Univ Paris 06, CNRS, Institut Parisien de Chimie Moléculaire, 4 Place Jussieu, F-75005 Paris, France. matthieu.raynal@upmc.fr.
authors: Geoffrey
authors: G
authors: Gontard
authors: Service de Chimie des Matériaux Nouveaux, Université de Mons/Materia Nova, Place du Parc, 20, B-7000 Mons, Belgium.
authors: Patrick
authors: P
authors: Brocorens
authors: Service de Chimie des Matériaux Nouveaux, Université de Mons/Materia Nova, Place du Parc, 20, B-7000 Mons, Belgium.
authors: Roberto
authors: R
authors: Lazzaroni
authors: Aix Marseille Univ, CNRS, Centrale Marseille, iSm2, Marseille, France.
authors: Nicolas
authors: N
authors: Vanthuyne
authors: Sorbonne Universités, UPMC Univ Paris 06, CNRS, Institut Parisien de Chimie Moléculaire, 4 Place Jussieu, F-75005 Paris, France. matthieu.raynal@upmc.fr.
authors: Claire
authors: C
authors: Troufflard
authors: Sorbonne Universités, UPMC Univ Paris 06, CNRS, Institut Parisien de Chimie Moléculaire, 4 Place Jussieu, F-75005 Paris, France. matthieu.raynal@upmc.fr.
authors: Matthieu
authors: http://orcid.org/0000-0001-6830-1668
authors: M
authors: Raynal
authors: Sorbonne Universités, UPMC Univ Paris 06, CNRS, Institut Parisien de Chimie Moléculaire, 4 Place Jussieu, F-75005 Paris, France. matthieu.raynal@upmc.fr.
authors: Laurent
authors: L
authors: Bouteiller