title: Palladium-Catalyzed Direct Cross-Coupling of Carboranyllithium with (Hetero)Aryl Halides.
abstract: A palladium-catalyzed direct C-arylation reaction of readily available cage carboranyllithium reagents with aryl halides has been developed for the first time. This method is applicable to a wide range of aryl halide substrates including aryl iodides, aryl bromides, and heteroaromatic halides.
authors: State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, P. R. China.
authors: Ju-You
authors: JY
authors: Lu
authors: State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, P. R. China.
authors: Hong
authors: H
authors: Wan
authors: State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, P. R. China.
authors: Jianwei
authors: J
authors: Zhang
authors: State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, P. R. China.
authors: Zhixuan
authors: Z
authors: Wang
authors: State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, P. R. China.
authors: Yang
authors: Y
authors: Li
authors: State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, P. R. China.
authors: Yongmei
authors: Y
authors: Du
authors: State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, P. R. China.
authors: Chunying
authors: C
authors: Li
authors: Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education), School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an, 710119, P. R. China.
authors: Zhao-Tie
authors: ZT
authors: Liu
authors: Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education), School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an, 710119, P. R. China.
authors: Zhong-Wen
authors: ZW
authors: Liu
authors: State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, P. R. China.
authors: Jian
authors: J
authors: Lu
keywords: C(cage)−C(sp2) formation; carboranyllithium; cross-coupling; direct C-arylation; palladium