title: Optical, phonon and efficient visible and infrared photocatalytic activity of Cu doped ZnS micro crystals.
abstract: We report, the enhanced photocatalytic behaviour of Cu doped ZnS micro crystals. ZnS and different concentrations of Cu doped ZnS microcrystals were prepared. X-ray diffraction confirms the crystalline and phase of the particles. Morphology and sizes were studied using Scanning Electron Microscopy (SEM). Recorded optical absorption spectra show a band for around 365nm for pure ZnS, but there is a broad band in the near infrared regime for the Cu-doped ZnS microcrystals which are attributed to the d-d transitions of Cu2+ions. Phonon properties of as-prepared samples were investigated using Raman spectroscopy. Present work we investigate the potential of ZnS and Cu doped ZnS as a photocatalyst. For this from the degradation of methylene blue dye in aqueous media the photocatalytic activity of pure and highest doped ZnS samples with the irradiation of white light and infrared, enhanced photocatalytic activity were observed. Mechanism of white light an IR light based photocatalytic activity is explained based on the electron-hole pair production.
authors: Department of Physics, National Institute of Technology, Tiruchirappalli 620 015, India.
authors: Neena
authors: N
authors: Prasad
authors: Department of Physics, National Institute of Technology, Tiruchirappalli 620 015, India. Electronic address: bkarthik@nitt.edu.
authors: Karthikeyan
authors: K
authors: Balasubramanian
keywords: Methylene blue; Optical absorption; Phonon vibration; Photocatalytic activity; Raman spectroscopy