title: Evaluation of calcium alginate beads for Ce, La and Nd preconcentration from groundwater prior to ICP OES analysis.
abstract: Analytical methods for the determination of rare earth elements (REE) in natural waters by plasma spectrochemical techniques often require sample preparation procedures for analytes preconcentration as well as for removing matrix constituents, that may interfere on the analytical measurements. In the present work, calcium alginate (CA) beads were used for the first time aiming at Ce, La and Nd preconcentration from groundwater samples for further determination by inductively coupled plasma optical emission spectrometry (ICP OES). Test samples were analyzed in batch mode by transferring a 40mL test portion (pH=5±0.2) into a 50mL polyethylene flask containing 125mg CA beads. After 15min contact, the analytes were quantitatively extracted from the loaded CA beads with 2.0mL of 1.0molL-1HCl solution for further determination by ICP OES, using Ce (II) 456.236, La (II) 379.478 and Nd (II) 430.358nm emission lines. The proposed approach is a reliable alternative for REE single-stage preconcentration from aqueous samples, as it provided accurate results based on the addition and recovery analysis of groundwater. The results obtained by the proposed method were also compared with those from reference method based on inductively coupled plasma mass spectrometry (ICP-MS) and no significant differences were observed after applying the Student's t-test at 95% confidence level.
authors: Departamento de Química Fundamental, Instituto de Química, Universidade de São Paulo, Av. Prof. Lineu Prestes, 748, 05513-970 São Paulo, SP, Brazil. Electronic address: ggac@iq.usp.br.
authors: Gabriel G
authors: GG
authors: Arantes de Carvalho
authors: Departamento de Química Fundamental, Instituto de Química, Universidade de São Paulo, Av. Prof. Lineu Prestes, 748, 05513-970 São Paulo, SP, Brazil.
authors: Stalin
authors: S
authors: Kondaveeti
authors: Departamento de Química Fundamental, Instituto de Química, Universidade de São Paulo, Av. Prof. Lineu Prestes, 748, 05513-970 São Paulo, SP, Brazil.
authors: Denise F S
authors: DFS
authors: Petri
authors: Departamento de Química Fundamental, Instituto de Química, Universidade de São Paulo, Av. Prof. Lineu Prestes, 748, 05513-970 São Paulo, SP, Brazil.
authors: Alexandre M
authors: AM
authors: Fioroto
authors: Departamento de Química Fundamental, Instituto de Química, Universidade de São Paulo, Av. Prof. Lineu Prestes, 748, 05513-970 São Paulo, SP, Brazil.
authors: Luiza G R
authors: LGR
authors: Albuquerque
authors: Departamento de Química Fundamental, Instituto de Química, Universidade de São Paulo, Av. Prof. Lineu Prestes, 748, 05513-970 São Paulo, SP, Brazil.
authors: Pedro V
authors: PV
authors: Oliveira
keywords: Alginate beads; Cerium; Groundwater; ICP OES; Lanthanum; Neodymium; Preconcentration