title: Steric Switching from Photochemical to Thermal Reaction Pathways for Enhanced Efficiency in Metal-Mediated Nitrogen Fixation.
abstract: Programmed manipulation of the subtle interplay of nonbonded steric interactions within a supporting ligand environment has been used for the conversion of a photochemically driven chemical cycle for group 6 metal-mediated nitrogen fixation into a thermally promoted process with increased energy efficiency and atom economy for key transformations involving N≡N bond cleavage and N-atom functionalization of coordinated N2.
authors: Laboratory for Applied Catalyst Science and Technology, Department of Chemistry and Biochemistry, University of Maryland , College Park, Maryland 20742, United States.
authors: Leila M
authors: LM
authors: Duman
authors: Laboratory for Applied Catalyst Science and Technology, Department of Chemistry and Biochemistry, University of Maryland , College Park, Maryland 20742, United States.
authors: Wesley S
authors: WS
authors: Farrell
authors: Laboratory for Applied Catalyst Science and Technology, Department of Chemistry and Biochemistry, University of Maryland , College Park, Maryland 20742, United States.
authors: Peter Y
authors: PY
authors: Zavalij
authors: Laboratory for Applied Catalyst Science and Technology, Department of Chemistry and Biochemistry, University of Maryland , College Park, Maryland 20742, United States.
authors: Lawrence R
authors: LR
authors: Sita