title: Ruthenium(II) Biscarboxylate-Catalyzed Borylations of C(sp2)-H and C(sp3)-H Bonds.
abstract: Versatile borylations of C(sp2)-H and C(sp3)-H were achieved with ruthenium(II) biscarboxylate complexes. The robust nature of the ruthenium(II) catalyst enabled C(sp3)-H borylation on pyrrolidines, piperidines, and azepanes with ample scope and excellent positional selectivity control.
authors: Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstrasse 2, 37077, Göttingen, Germany.
authors: Suman De
authors: S
authors: Sarkar
authors: Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstrasse 2, 37077, Göttingen, Germany.
authors: N Y Phani
authors: NY
authors: Kumar
authors: Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstrasse 2, 37077, Göttingen, Germany.
authors: Lutz
authors: 0000-0001-7034-8772
authors: L
authors: Ackermann
keywords: C−H activation; alkanes; boron; mechanism; ruthenium