title: Rhodium-Catalyzed Hydrogen-Releasing ortho-Alkenylation of 7-Azaindoles.
abstract: An efficient rhodium-catalyzed dehydrogenative Heck-type reaction between N-aryl-substituted 7-azaindoles and various alkenes through a H2-releasing process without the need of any oxidizing agent was developed. The novel methodology broadens the scope of metal-catalyzed hydrogen-releasing reactions to include rhodium catalysis.
authors: Key laboratory of Drug Targeting and Drug Delivery System of the Ministry of Education, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China.
authors: Wei-Huan
authors: WH
authors: Li
authors: Key laboratory of Drug Targeting and Drug Delivery System of the Ministry of Education, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China.
authors: Lin
authors: L
authors: Wu
authors: Key laboratory of Drug Targeting and Drug Delivery System of the Ministry of Education, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China.|Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, 610041, P. R. China.
authors: Shuai-Shuai
authors: SS
authors: Li
authors: Key laboratory of Drug Targeting and Drug Delivery System of the Ministry of Education, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China.
authors: Chen-Fei
authors: CF
authors: Liu
authors: Key laboratory of Drug Targeting and Drug Delivery System of the Ministry of Education, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China.
authors: Guo-Tai
authors: GT
authors: Zhang
authors: Key laboratory of Drug Targeting and Drug Delivery System of the Ministry of Education, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China.
authors: Lin
authors: L
authors: Dong
keywords: 7-azaindoles; hydrogen-releasing; olefin; ortho-alkenylation; rhodium