title: Adiabatic Electron-Transfer Reactions on Semiconducting Electrodes.
abstract: Theoretical treatments of electrochemical reactions at semiconductors are usually based on theories that presume a weak interaction between the reactant and the electrode. Herein a theory is developed that is valid for arbitrary interaction strengths, and its consequences are explored within a simple coupling scheme. This model can be used as a framework for the investigation of specific catalytic reactions including photoelectrocatalysis.
authors: Institute of Theoretical Chemistry, Ulm University, 89069, Ulm, Germany.
authors: Wolfgang
authors: W
authors: Schmickler
authors: Institute of Theoretical Chemistry, Ulm University, 89069, Ulm, Germany.|Instituto de Fisica Enrique Gaviola, IFEG-CONICET-FAMAF, Universidad Nacional de Córdoba, Córdoba, Argentina.
authors: Elizabeth
authors: E
authors: Santos
authors: Kazan National Research Technological University, 420015, Kazan, Russian Federation.
authors: Michael
authors: M
authors: Bronshtein
authors: Kazan National Research Technological University, 420015, Kazan, Russian Federation.
authors: Renat
authors: R
authors: Nazmutdinov
keywords: density functional theory; electrocatalysis; electrochemistry; electron transfer; semiconductors