title: A decacobalt(ii) cluster with triple-sandwich structure obtained by partial reductive hydrolysis of a pentacobalt(ii/iii) Weakley-type polyoxometalate.
abstract: Partial reductive hydrolysis of a penta-CoII/IIIcluster [Co(H2O)2(CoIIIW9O34)(PW9O34)]12-(1) leads to the formation of [Co2{Co3(H2O)(Co(OH)2W7O26)(PW9O34)}2]22-(2). This polyoxometalate is made up of two capping [PW9O34]9-units and two bridging [W7O26]10-units that assemble to encapsulate a novel deca-CoIIcluster core comprising octahedral and tetrahedral CoIIions.
authors: Instituto de Ciencia Molecular (ICMol), Universitat de València, c/Catedrático José Beltrán, 2, 46980 Paterna, Spain. carlos.gimenez@uv.es eugenio.coronado@uv.es.
authors: Yan
authors: http://orcid.org/0000-0002-2849-5602
authors: Y
authors: Duan
authors: Instituto de Ciencia Molecular (ICMol), Universitat de València, c/Catedrático José Beltrán, 2, 46980 Paterna, Spain. carlos.gimenez@uv.es eugenio.coronado@uv.es.
authors: Juan M
authors: JM
authors: Clemente-Juan
authors: Instituto de Catálisis y Petroleoquímica, (CSIC), c/Marie Curie, 2, Cantoblanco, 28049 Madrid, Spain.
authors: José L G
authors: JL
authors: Fierro
authors: Instituto de Ciencia Molecular (ICMol), Universitat de València, c/Catedrático José Beltrán, 2, 46980 Paterna, Spain. carlos.gimenez@uv.es eugenio.coronado@uv.es.
authors: Carlos
authors: http://orcid.org/0000-0002-3174-0912
authors: C
authors: Giménez-Saiz
authors: Instituto de Ciencia Molecular (ICMol), Universitat de València, c/Catedrático José Beltrán, 2, 46980 Paterna, Spain. carlos.gimenez@uv.es eugenio.coronado@uv.es.
authors: Eugenio
authors: E
authors: Coronado