title: Bipyridyltriazolium Chlorobismuthate with Thermo-/Photochromic and Photoluminescent Switching Behaviors Based on ET and CT†.
abstract: Matched with 3,5-bis(pyridine-2-yl)-1,2,4-triazole (2-bpt), a new electron donor-acceptor-based chlorobismuthate(III) hybrid, [2-bpt]2[Bi2Cl10(H2O)]·5H2O was prepared solvothermally and characterized. The title compound (hydrated form) and its dehydrated form exhibit photo- and thermo-induced intermolecular electron transfer (ET), which correspond to dual ET photo/thermochromism for hydrated form, charge transfer thermochromism during dehydration, and simultaneously photoluminescent responses, respectively.
authors: School of Chemistry & Material Science, Shanxi Normal University , Linfen 041004, P. R. China.
authors: Guoping
authors: G
authors: Li
authors: School of Chemistry & Material Science, Shanxi Normal University , Linfen 041004, P. R. China.
authors: Pengfei
authors: P
authors: Hao
authors: School of Chemistry & Material Science, Shanxi Normal University , Linfen 041004, P. R. China.
authors: Junju
authors: J
authors: Shen
authors: School of Chemistry & Material Science, Shanxi Normal University , Linfen 041004, P. R. China.
authors: Tanlai
authors: T
authors: Yu
authors: School of Chemistry & Material Science, Shanxi Normal University , Linfen 041004, P. R. China.
authors: Huihui
authors: H
authors: Li
authors: School of Chemistry & Material Science, Shanxi Normal University , Linfen 041004, P. R. China.
authors: Yunlong
authors: Y
authors: Fu