title: Multielemental speciation analysis by advanced hyphenated technique - HPLC/ICP-MS: A review.
abstract: Speciation analysis has become an invaluable tool in human health risk assessment, environmental monitoring or food quality control. Another step is to develop reliable multielemental speciation methodologies, to reduce costs, waste and time needed for the analysis. Separation and detection of species of several elements in a single analytical run can be accomplished by high performance liquid chromatography hyphenated to inductively coupled plasma mass spectrometry (HPLC/ICP-MS). Our review assembles articles concerning multielemental speciation determination of: As, Se, Cr, Sb, I, Br, Pb, Hg, V, Mo, Te, Tl, Cd and W in environmental, biological, food and clinical samples analyzed with HPLC/ICP-MS. It addresses the procedures in terms of following issues: sample collection and pretreatment, selection of optimal conditions for elements species separation by HPLC and determination using ICP-MS as well as metrological approach. The presented work is the first review article concerning multielemental speciation analysis by advanced hyphenated technique HPLC/ICP-MS.
authors: Department of Trace Element Analysis by Spectroscopy Method, Faculty of Chemistry, Adam Mickiewicz University in Poznań, 89b Umultowska Street, 61-614 Poznań, Poland.
authors: Monika
authors: M
authors: Marcinkowska
authors: Department of Trace Element Analysis by Spectroscopy Method, Faculty of Chemistry, Adam Mickiewicz University in Poznań, 89b Umultowska Street, 61-614 Poznań, Poland. Electronic address: danutaba@amu.edu.pl.
authors: Danuta
authors: D
authors: Barałkiewicz
mesh_terms: D000818:Animals; D001151:Arsenic / Q000032:analysis*; D002851:Chromatography, High Pressure Liquid / Q000379:methods; D004785:Environmental Pollutants / Q000032:analysis; D006219:Halogens / Q000032:analysis*; D006801:Humans; D013058:Mass Spectrometry / Q000379:methods; D008670:Metals / Q000032:analysis*; D012643:Selenium / Q000032:analysis*
chemical_list: D004785:Environmental Pollutants; D006219:Halogens; D008670:Metals; D012643:Selenium; D001151:Arsenic
keywords: Analytical procedures; Hyphenated technique high performance liquid chromatography inductively coupled plasma mass spectrometry; Multielemental speciation; Review; Trace elements analysis