title: An Effective Pd-Catalyzed Regioselective Hydroformylation of Olefins with Formic Acid.
abstract: An effective palladium-catalyzed regioselective hydroformylation of olefins with formic acid is described. The ligand plays a crucial role in directing the reaction pathway. Linear aldehydes can be obtained in up to 93% yield with >20:1 regioselectivity using 1,3-bis(diphenylphosphino)propane (dppp) as the ligand. The reaction process is operationally simple and requires no syngas.
authors: State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Chemistry for Life Sciences, Center for Multimolecular Organic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University , Nanjing 210093, China.
authors: Wenlong
authors: W
authors: Ren
authors: State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Chemistry for Life Sciences, Center for Multimolecular Organic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University , Nanjing 210093, China.
authors: Wenju
authors: W
authors: Chang
authors: State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Chemistry for Life Sciences, Center for Multimolecular Organic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University , Nanjing 210093, China.
authors: Jie
authors: J
authors: Dai
authors: State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Chemistry for Life Sciences, Center for Multimolecular Organic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University , Nanjing 210093, China.
authors: Yuan
authors: Y
authors: Shi
authors: State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Chemistry for Life Sciences, Center for Multimolecular Organic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University , Nanjing 210093, China.
authors: Jingfu
authors: J
authors: Li
authors: State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Chemistry for Life Sciences, Center for Multimolecular Organic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University , Nanjing 210093, China.|Department of Chemistry, Colorado State University , Fort Collins, Colorado 80523, United States.
authors: Yian
authors: Y
authors: Shi