title: Reaction of C60with Inactive Secondary Amines and Aldehydes and the Cu(OAc)2-Promoted Regioselective Intramolecular C-H Functionalization of the Generated Fulleropyrrolidines.
abstract: The thermal reaction of C60with aromatic aldehydes and inactive secondary amines for the stereoselective synthesis of trans-1,2,5-trisubstituted fulleropyrrolidines has been developed. Moreover, when an o-hydroxyl group was located at the phenyl ring of the generated fulleropyrrolidines, the Cu(OAc)2-promoted regioselective intramolecular C-O coupling reaction occurred to generate unique tricycle-fused fullerene derivatives.
authors: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University , Changzhou 213164, China.
authors: Hai-Tao
authors: HT
authors: Yang
authors: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University , Changzhou 213164, China.
authors: Yi-Chen
authors: YC
authors: Tan
authors: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University , Changzhou 213164, China.
authors: Jie
authors: J
authors: Ge
authors: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University , Changzhou 213164, China.
authors: He
authors: H
authors: Wu
authors: Key Laboratory of Novel Thin Film Solar Cells, Institute of Plasma Physics, Chinese Academy of Sciences , P.O. Box 1126, Hefei 230031, China.
authors: Jia-Xing
authors: JX
authors: Li
authors: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University , Changzhou 213164, China.
authors: Yang
authors: Y
authors: Yang
authors: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University , Changzhou 213164, China.
authors: Xiao-Qiang
authors: XQ
authors: Sun
authors: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University , Changzhou 213164, China.
authors: Chun-Bao
authors: CB
authors: Miao