Highly durable organic electrode for sodium-ion batteries via a stabilized α-C radical intermediate.
It is a challenge to prepare organic electrodes for sodium-ion batteries with long cycle life and high capacity. The highly reactive radical intermediates generated during the sodiation/desodiation process could be a critical issue because of undesired side reactions. Here we present durable electrodes with a stabilized α-C radical intermediate. Through the resonance effect as well as steric effects, the excessive reactivity of the unpaired electron is successfully suppressed, thus developing an electrode with stable cycling for over 2,000 cycles with 96.8% capacity retention. In addition, the α-radical demonstrates reversible transformation between three states: C=C; α-C·radical; and α-C-anion. Such transformation provides additional Na+storage equal to more than 0.83 Na+insertion per α-C radical for the electrodes. The strategy of intermediate radical stabilization could be enlightening in the design of organic electrodes with enhanced cycling life and energy storage capability.
Department of Materials Science and Engineering, South University of Science and Technology of China, Shenzhen 518055, China.
Shaofei
S
Wu
Department of Materials Science and Engineering, South University of Science and Technology of China, Shenzhen 518055, China.
Wenxi
W
Wang
Department of Materials Science and Engineering, South University of Science and Technology of China, Shenzhen 518055, China.
Minchan
M
Li
Department of Materials Science and Engineering, South University of Science and Technology of China, Shenzhen 518055, China.
Lujie
L
Cao
Department of Materials Science and Engineering, South University of Science and Technology of China, Shenzhen 518055, China.
Fucong
F
Lyu
Department of Materials Science and Engineering, South University of Science and Technology of China, Shenzhen 518055, China.
Mingyang
M
Yang
Department of Materials Science and Engineering, South University of Science and Technology of China, Shenzhen 518055, China.
Zhenyu
Z
Wang
Department of Materials Science and Engineering, South University of Science and Technology of China, Shenzhen 518055, China.
Yang
Y
Shi
Department of Materials Science and Engineering, South University of Science and Technology of China, Shenzhen 518055, China.
Bo
B
Nan
Department of Materials Science and Engineering, South University of Science and Technology of China, Shenzhen 518055, China.
Sicen
S
Yu
Department of Materials Science and Engineering, South University of Science and Technology of China, Shenzhen 518055, China.
Zhifang
Z
Sun
Department of Materials Science and Engineering, South University of Science and Technology of China, Shenzhen 518055, China.
Yao
Y
Liu
Department of Materials Science and Engineering, South University of Science and Technology of China, Shenzhen 518055, China.
Zhouguang
0000-0003-3769-9356
Z
Lu