An innovative application of stable isotopes (δ2H and δ18O) for tracing pollutant plumes in groundwater.
The identification of the sources of contaminants present in groundwater at industrial sites is primordial to address environmental and industrial issues. However, available tools are often inadequate or expensive. Here, we present the data of stable isotopes (δ18O and δ2H) of the water molecule at an industrial site where electrochemistry plant occurs impacting the groundwater quality. High ClO3and ClO4contents and2H enrichment have been measured in groundwater. Recharge of aquifer relates to infiltration of rainwater and by subsurface inflow. On-site, industrial products are generated by electrolysis. We show that the electrolysis process leads to a large2H enrichment (+425‰) in solutions. In the absence of hydrothermal water input containing H2S, we demonstrate that the relationship between δ18O and δ2H can be easily used in a way to trace the origin of the ClO3and ClO4in groundwater. Isotopes evidenced first a leakage from end-product storage tanks or during the production process itself. Then, an accumulation and release of ClO3and ClO4from soil is demonstrated. Our study successfully shows that stable isotopes are a powerful and low cost tool for tracing pollutant plumes in an industrial context using electrolysis process.
BRGM, Laboratories Division, F45060 Orléans, France.
Philippe
P
Negrel
BRGM, Water, Environment and Ecotechnologies Division, F45060 Orléans, France. Electronic address: p.ollivier@brgm.fr.
Patrick
P
Ollivier
BRGM, Laboratories Division, F45060 Orléans, France.
Christine
C
Flehoc
BRGM, Water, Environment and Ecotechnologies Division, F45060 Orléans, France.
Daniel
D
Hube
D004784:Environmental Monitoring; D060587:Groundwater / Q000032:analysis*; D006859:Hydrogen / Q000032:analysis*; D010103:Oxygen Isotopes / Q000032:analysis*; D012987:Soil; D014874:Water Pollutants, Chemical / Q000032:analysis*
D010103:Oxygen Isotopes; D012987:Soil; D014874:Water Pollutants, Chemical; D006859:Hydrogen
Chlorate; Contaminated sites; Electrolysis; Groundwater; Perchlorate; Stable isotopes