Synthesis of different types of alkoxy fullerene derivatives from chlorofullerene C60Cl6.
We report novel synthetic routes for facile preparation of highly functionalized fullerene derivatives C60(OR)5X (X = H, Cl, Br), C60(OR)4O and C60(OR)2from chlorofullerene C60Cl6. The first water-soluble fullerene compound bearing residues of 3-oxypropanoic acid demonstrated a potent anti-HIV activity.
IPCP RAS, Semenov Prospect 1, Chernogolovka, 142432, Russia. troshin2003@inbox.ru.
Ekaterina A
EA
Khakina
IPCP RAS, Semenov Prospect 1, Chernogolovka, 142432, Russia. troshin2003@inbox.ru and HCC RAS, Miusskaya pl. 9, Moscow, 125047, Russia.
Ol'ga A
OA
Kraevaya
IPCP RAS, Semenov Prospect 1, Chernogolovka, 142432, Russia. troshin2003@inbox.ru and HCC RAS, Miusskaya pl. 9, Moscow, 125047, Russia.
Maria L
ML
Popova
INEOS RAS, Vavylova St. 28, B-334, Moscow, 119991, Russia.
Alexander S
AS
Peregudov
Department of Chemistry, Moscow State University, Leninskie gory, Moscow, 119991, Russia.
Sergey I
SI
Troyanov
IPCP RAS, Semenov Prospect 1, Chernogolovka, 142432, Russia. troshin2003@inbox.ru.
Alexander V
AV
Chernyak
IPCP RAS, Semenov Prospect 1, Chernogolovka, 142432, Russia. troshin2003@inbox.ru.
Vyacheslav M
VM
Martynenko
IPCP RAS, Semenov Prospect 1, Chernogolovka, 142432, Russia. troshin2003@inbox.ru.
Alexander V
AV
Kulikov
Rega Institute for Medical Research, KU Leuven, Minderbroedersstraat 10, B-3000, Leuven, Belgium.
Dominique
D
Schols
IPCP RAS, Semenov Prospect 1, Chernogolovka, 142432, Russia. troshin2003@inbox.ru and Skolkovo Institute of Science and Technology, Nobel St. 3, Moscow, 143026, Russian Federation.
Pavel A
PA
Troshin