Carbon footprint assessment of recycling technologies for rare earth elements: A case study of recycling yttrium and europium from phosphor.
Rare earth elements are key raw materials in high-technology industries. Mining activities and manufacturing processes of such industries have caused considerable environmental impacts, such as soil erosion, vegetation destruction, and various forms of pollution. Sustaining the long-term supply of rare earth elements is difficult because of the global shortage of rare earth resources. The diminishing supply of rare earth elements has attracted considerable concern because many industrialized countries regarded such elements as important strategic resources for economic growth. This study aims to explore the carbon footprints of yttrium and europium recovery techniques from phosphor. Two extraction recovery methods, namely, acid extraction and solvent extraction, were selected for the analysis and comparison of carbon footprints. The two following functional units were used: (1) the same phosphor amounts for specific Y and Eu recovery concentrations, and (2) the same phosphor amounts for extraction. For acid extraction method, two acidic solutions (H2SO4and HCl) were used at two different temperatures (60 and 90°C). For solvent extraction method, acid leaching was performed followed by ionic liquid extraction. Carbon footprints from acid and solvent extraction methods were estimated to be 10.1 and 10.6kgCO2eq, respectively. Comparison of the carbon emissions of the two extraction methods shows that the solvent extraction method has significantly higher extraction efficiency, even though acid extraction method has a lower carbon footprint. These results may be used to develop strategies for life cycle management of rare earth resources to realize sustainable usage.
Institute of Environmental Engineering and Management, National Taipei University of Technology, Taiwan, ROC. Electronic address: allenhu@mail.ntut.edu.tw.
Allen H
AH
Hu
Institute of Environmental Engineering and Management, National Taipei University of Technology, Taiwan, ROC.
Chien-Hung
CH
Kuo
Institute of Environmental Engineering and Management, National Taipei University of Technology, Taiwan, ROC.
Lance H
LH
Huang
Department of Molecular Science & Engineering, National Taipei University of Technology, Taiwan, ROC.
Chao-Chin
CC
Su
D058572:Carbon Footprint; D005591:Chemical Fractionation / Q000379:methods; D005063:Europium / Q000302:isolation & purification*; D059027:Recycling / Q000379:methods*; D012997:Solvents / Q000737:chemistry; D015019:Yttrium / Q000302:isolation & purification*
D012997:Solvents; D005063:Europium; D015019:Yttrium
Carbon footprint; Life cycle assessment; Phosphor; Rare earth recycling technologies