Hexacoordinated nitrogen(V) stabilized by high pressure.
In all of its known connections nitrogen retains a valence shell electron count of eight therefore satisfying the golden rule of chemistry - the octet rule. Despite the diversity of nitrogen chemistry (with oxidation states ranging from + 5 to -3), and despite numerous efforts, compounds containing nitrogen with a higher electron count (hypervalent nitrogen) remain elusive and are yet to be synthesized. One possible route leading to nitrogen's hypervalency is the formation of a chemical moiety containing pentavalent nitrogen atoms coordinated by more than four substituents. Here, we present theoretical evidence that a salt containing hexacoordinated nitrogen(V), in the form of an NF6-anion, could be synthesized at a modest pressure of 40 GPa (=400 kbar) via spontaneous oxidation of NF3by F2. Our results indicate that the synthesis of a new class of compounds containing hypervalent nitrogen is within reach of current high-pressure experimental techniques.
Centre of New Technologies, University of Warsaw, Warsaw 02-097, Poland.|Faculty of Mathematics and Natural Sciences, Cardinal Stefan Wyszyński University in Warsaw, Warsaw 01-938, Poland.
Dominik
D
Kurzydłowski
Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw 01-224, Poland.
Patryk
P
Zaleski-Ejgierd