Rational design of a flu-type heterometallic cluster-based Zr-MOF.
Following the HSAB principle, the cooperative assembly of tetrahedral [Cu4I4(Ina)4]4-metalloligands and 8-connecting [Zr6(μ3-OH)8(OH)8]8+building units leads to the first heterometallic cluster-based Zr-MOF (1). The results provide a successful strategy for rational design of heterometallic cluster-based Zr-MOFs.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, Fujian, China. ydq@fjirsm.ac.cn.
Yan-Xi
YX
Tan
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, Fujian, China. ydq@fjirsm.ac.cn and University of the Chinese Academy of Sciences, Beijing 100049, China.
Xue
X
Yang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, Fujian, China. ydq@fjirsm.ac.cn and University of the Chinese Academy of Sciences, Beijing 100049, China.
Bei-Bei
BB
Li
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, Fujian, China. ydq@fjirsm.ac.cn.
Daqiang
http://orcid.org/0000-0003-4627-072X
D
Yuan