Synthesis by free radical polymerization and properties of BN-polystyrene and BN-poly(vinylbiphenyl).
Free radical polymerization of B-vinyl- and B-styryl-functionalized azaborinine monomers gives well-defined hybrid polymers that were fully characterized by multinuclear NMR and GPC analysis; their solubility, thermal characteristics, and photophysical properties are dramatically different from those of the all-carbon polystyrene analogues.
Department of Chemistry, Rutgers University Newark, Newark, NJ 07102, USA and State Key Laboratory of Heavy Oil Processing and Centre for Bioengineering and Biotechnology, China University of Petroleum (East China), 66 Changjiang West Road, Qingdao Economic Development Zone, Qingdao, Shandong 266580, People's Republic of China.
Wen-Ming
WM
Wan
Department of Chemistry, Boston College, Chestnut Hill, MA 02467, USA.
Andrew W
AW
Baggett
Department of Chemistry, Rutgers University Newark, Newark, NJ 07102, USA.
Fei
F
Cheng
Department of Chemistry, Rutgers University Newark, Newark, NJ 07102, USA.
Huina
H
Lin
Ashley N
AN
Lamm
Department of Chemistry, Boston College, Chestnut Hill, MA 02467, USA.
Shih-Yuan
SY
Liu
Department of Chemistry, Rutgers University Newark, Newark, NJ 07102, USA.
Frieder
0000-0001-8031-9254
F
Jäkle