Thienyl Difluoroboron β-Diketonates in Solution and Polylactide Media.
Difluoroboron β-diketonates have impressive optical properties in both solution and the solid state. In particular, both fluorescence and room-temperature phosphorescence are present when the dyes are confined to a rigid matrix, such as poly(lactic acid) (PLA). To expand current knowledge and color range capabilities of this unique type of multi-emitting chromophore, a series of thienyl-substituted BF2bdk complexes have been synthesized. The photophysical properties were investigated in methylene chloride solution and in the solid state as dye/PLA blends. By varying donor ability, i.e. methyl, phenyl, methoxyl, and thienyl substituents, and by changing the dye loading in the PLA media (0.1-10% dye loading) red-shifted emission was achieved, important for biological imaging applications. In dilute CH2Cl2solution, complexes exhibited absorptions ranging from 350 - 420 nm, solid-state fluorescence in PLA ranging from 390 - 500 nm, and oxygen sensitive phosphorescence ranging from 540 - 585 nm in PLA blends. Promising candidates as dye/PLA blends serve as models for dyepolymer conjugates for application as biological oxygen nanoprobes.
Department of Chemistry, University of Virginia, McCormick Road, Charlottesville, VA 22904.
Milena
M
Kolpaczynska
Department of Chemistry, University of Virginia, McCormick Road, Charlottesville, VA 22904.
Christopher A
CA
DeRosa
Department of Chemistry, University of Virginia, McCormick Road, Charlottesville, VA 22904.
William A
WA
Morris
Department of Chemistry, University of Virginia, McCormick Road, Charlottesville, VA 22904.
Cassandra L
CL
Fraser
difluoroboron β–diketonate complexes; dye/PLA blends; fluorescence; room temperature phosphorescence; thiophene