Adsorptive Removal of Nitrate from Aqueous Solution Using Nitrogen Doped Activated Carbon.
Activated carbon (AC) has been widely applied for adsorptive removal of organic contaminants from aqueous phase, but not for ionic pollutants. In this study, nitrogen doped AC was prepared to increase the adsorption capacity of nitrate from water. AC was oxidized with (NH4)2S2O8solution to maximize oxygen content for the first step, and then NH3gas treatment was carried out at 950°C to aim at forming quaternary nitrogen (N-Q) species on AC surface (Ox-9.5AG). Influence of solution pH was examined so as to elucidate the relationship between surface charge and adsorption amounts of nitrate. The results showed that Ox-9.5AG exhibited about twice higher adsorption capacity than non-treatment AC at any initial nitrate concentration and any equilibrium solution pH (pHe) investigated. The more decrease in pHevalue, the more adsorption amount of negatively charged nitrate ion, because the surface charge of AC and Ox-9.5AG could become more positive in acidic solution. The oxidation and consecutive ammonia treatments lead to increase in nitrogen content from 0.35 to 6.4% and decrease in the pH of the point of zero charge (pHpzc) from 7.1 to 4.0 implying that positively charged N-Q of a Lewis acid was created on the surface of Ox-9.5AG. Based on a Langmuir data analysis, maximum adsorption capacity attained 0.5-0.6 mmol/g of nitrate and adsorption affinity was 3.5-4.0 L/mmol at pHe2.5 for Ox-9.5AG.
Safety and Health Organization, Chiba University.
Motoi
M
Machida
Tatsuru
T
Goto
Yoshimasa
Y
Amano
Tatsuya
T
Iida
D000327:Adsorption; D002244:Carbon / Q000737:chemistry*; D009566:Nitrates / Q000737:chemistry* / Q000302:isolation & purification*; D009584:Nitrogen / Q000737:chemistry*; D012996:Solutions; D013499:Surface Properties; D014867:Water / Q000737:chemistry
D009566:Nitrates; D012996:Solutions; D014867:Water; D002244:Carbon; D009584:Nitrogen