Potential of polyaniline modified clay nanocomposite as a selective decontamination adsorbent for Pb(II) ions from contaminated waters; kinetics and thermodynamic study.
BACKGROUND
Nowadays significant attention is to nanocomposite compounds in water cleaning. In this article the synthesis and characterization of conductive polyaniline/clay (PANI/clay) as a hybrid nanocomposite with extended chain conformation and its application for water purification are presented.


METHODS
Clay samples were obtained from the central plain of Abhar region, Abhar, Zanjan Province, Iran. Clay was dried and sieved before used as adsorbent. The conductive polyaniline was inflicted into the layers of clay to fabricate a hybrid material. The structural properties of the fabricated nanocomposite are studied by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscope (SEM). The elimination process of Pb(II) and Cd(II) ions from synthetics aqueous phase on the surface of PANI/clay as adsorbent were evaluated in batch experiments. Flame atomic absorption instrument spectrophotometer was used for determination of the studied ions concentration. Consequence change of the pH and initial metal amount in aqueous solution, the procedure time and the used adsorbent dose as the effective parameters on the removal efficiency was investigated.


RESULTS
Surface characterization was exhibited that the clay layers were flaked in the hybrid nanocomposite. The results show that what happen when a nanocomposite polyaniline chain is inserted between the clay layers. The adsorption of ions confirmed a pH dependency procedure and a maximum removal value was seen at pH 5.0. The adsorption isotherm and the kinetics of the adsorption processes were described by Temkin model and pseudo-second-order equation. Time of procedure, pH and initial ion amount have a severe effect on adsorption efficiency of PANI/clay.


CONCLUSIONS
By using suggested synthesise method, nano-composite as the adsorbent simply will be prepared. The prepared PANI/clay showed excellent adsorption capability for decontamination of Pb ions from contaminated water. Both of suggested synthesise and removal methods are affordable techniques.
Department of Chemistry, Faculty of Science, University of Zanjan, 45371-38791 Zanjan, Iran.
Somayeh
S
Piri
Department of Environmental Science, Faculty of Science, University of Zanjan, 45371-38791 Zanjan, Iran.
Zahra Alikhani
ZA
Zanjani
Department of Chemistry, Faculty of Science, University of Zanjan, 45371-38791 Zanjan, Iran.
Farideh
F
Piri
Department of Environmental Science, Faculty of Science, University of Zanjan, 45371-38791 Zanjan, Iran.
Abbasali
A
Zamani
Department of Chemistry, Faculty of Science, University of Zanjan, 45371-38791 Zanjan, Iran.
Mohamadreza
M
Yaftian
Iranian Research Organization for Science and Technology, Tehran, Iran.
Mehdi
M
Davari
Clay; Heavy metals; Nanocomposite; Nanolayers; Natural adsorbent; Polyaniline; Water treatment