A highly stable amino-coordinated MOF for unprecedented block off N2adsorption and extraordinary CO2/N2separation.
A highly stable amino-coordinated metal-organic framework ZJU-198 has been synthesized and structurally characterized, exhibiting high CO2uptake of 105.8 cm3cm-3while blocking off N2adsorption at 1.0 bar and 298 K, attributed to the unique pore window sizes.
State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, China. gdqian@zju.edu.cn.
Ling
L
Zhang
State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, China. gdqian@zju.edu.cn.
Ke
K
Jiang
College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China.
Mengdie
M
Jiang
State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, China. gdqian@zju.edu.cn.
Dan
D
Yue
State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, China. gdqian@zju.edu.cn.
Yating
Y
Wan
College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China.
Huabin
H
Xing
State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, China. gdqian@zju.edu.cn.
Yu
Y
Yang
State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, China. gdqian@zju.edu.cn.
Yuanjing
Y
Cui
State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, China. gdqian@zju.edu.cn and Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698, USA. banglin.chen@utsa.edu.
Banglin
B
Chen
State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, China. gdqian@zju.edu.cn.
Guodong
G
Qian