Magnetic cobalt ferrite composite as an efficient catalyst for photocatalytic oxidation of carbamazepine.
A magnetic spinel cobalt ferrite nanoparticle composite (CFO) was prepared via an ultrasonication-assisted co-precipitation method. The morphological structure and surface composition of CFO before and after reaction were investigated by using X-ray diffraction, scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray, and Fourier transform infrared spectroscopy, indicating the consumption of iron oxide during photodegradation. X-ray photoelectron spectroscopy and vibrating sample magnetometry confirm the preparation of the ferrite nanoparticle composite and its magnetic properties. The prepared CFO was then used for the photocatalytic degradation of carbamazepine (CBZ) as an example of pharmaceuticals and personal care products (PPCPs) from aqueous solution. The effects of the nanocomposite dosage, contact time, and solution pH on the photodegradation process were investigated. More than 96% of the CBZ was degraded within 100 min at 0.2 g·L-1CFO in the presence of UV light. The reactive species for CBZ degradation in the CFO/UV system was identified as hydroxyl radicals by the methanol scavenging method. Combined with the detection of leached iron ions during the process, the CBZ degradation mechanism can be presumed to be heterogeneous and homogeneous photocatalytic degradation in the CFO/UV system. Furthermore, iminostilbene and acridine were detected as intermediate products by GC-MS.
State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai, 200092, China.
Yongzhen
Y
He
Department of Hydraulic Engineering, Tongji University, Shanghai, 200092, China. daichaomeng@tongji.edu.cn.
Chaomeng
C
Dai
State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai, 200092, China. zhouxuefei@tongji.edu.cn.
Xuefei
X
Zhou
D002220:Carbamazepine / Q000737:chemistry*; D002384:Catalysis; D003035:Cobalt / Q000737:chemistry*; D005290:Ferric Compounds / Q000737:chemistry*; D008280:Magnetics; D008855:Microscopy, Electron, Scanning; D046529:Microscopy, Electron, Transmission; D053761:Nanocomposites / Q000737:chemistry* / Q000648:ultrastructure; D010084:Oxidation-Reduction; D056951:Photoelectron Spectroscopy; D010782:Photolysis; D017550:Spectroscopy, Fourier Transform Infrared; D014961:X-Ray Diffraction
D005290:Ferric Compounds; C569492:cobalt ferrite; D002220:Carbamazepine; D003035:Cobalt
Carbamazepine; Cobalt ferrite; Photocatalytic degradation; Ultraviolet