Facile Way of Synthesis for Molybdenum Iodides.
Molybdenum iodides are prepared based on a new way of synthesis, namely, via reductive metathesis reaction of MoCl5with SiI4. MoI3was formed at 150 °C. Mo6I12and the new molybdenum iodides Mo6I16and Mo6I18with the well-known [Mo6I8]4+cluster core were obtained in the temperature range 550-600 °C. Compounds were structurally characterized by powder and single-crystal X-ray diffraction techniques.
Section for Solid State and Theoretical Inorganic Chemistry, Institute of Inorganic Chemistry, University of Tübingen , Auf der Morgenstelle 18, 72076 Tübingen, Germany.
Markus
M
Ströbele
Section for Solid State and Theoretical Inorganic Chemistry, Institute of Inorganic Chemistry, University of Tübingen , Auf der Morgenstelle 18, 72076 Tübingen, Germany.
Robert
R
Thalwitzer
Section for Solid State and Theoretical Inorganic Chemistry, Institute of Inorganic Chemistry, University of Tübingen , Auf der Morgenstelle 18, 72076 Tübingen, Germany.
H-Jürgen
HJ
Meyer