Absolute cross sections for electronic excitation of condensed tetrahydrofuran (THF) by 11-16 eV electrons.
Absolute cross section (CS) data on the interaction of low energy electrons with DNA and its molecular constituents are required as input parameters in Monte-Carlo type simulations, for several radiobiological applications. Previously [V. Lemelin et al., J. Chem. Phys. 144, 074701 (2016)], we measured absolute vibrational CSs for low-energy electron scattering from condensed tetrahydrofuran, a convenient surrogate for the deoxyribose. Here we report absolute electronic CSs for energy losses of between 6 and 11.5 eV, by electrons with energies between 11 and 16 eV. The variation of these CSs with incident electron energy shows no evidence of transient anion states, consistent with theoretical and other experimental results, indicating that initial electron capture leading to DNA strand breaks occurs primarily on DNA bases or the phosphate group.
Groupe en Sciences des Radiations, Département de Médecine Nucléaire et Radiobiologie, Faculté de Médecine et Sciences des Radiations, Université de Sherbrooke, Sherbrooke, Québec J1H 5N4, Canada.
V
V
Lemelin
Groupe en Sciences des Radiations, Département de Médecine Nucléaire et Radiobiologie, Faculté de Médecine et Sciences des Radiations, Université de Sherbrooke, Sherbrooke, Québec J1H 5N4, Canada.
A D
AD
Bass
Groupe en Sciences des Radiations, Département de Médecine Nucléaire et Radiobiologie, Faculté de Médecine et Sciences des Radiations, Université de Sherbrooke, Sherbrooke, Québec J1H 5N4, Canada.
P
P
Cloutier
Groupe en Sciences des Radiations, Département de Médecine Nucléaire et Radiobiologie, Faculté de Médecine et Sciences des Radiations, Université de Sherbrooke, Sherbrooke, Québec J1H 5N4, Canada.
L
L
Sanche
D004583:Electrons; D005663:Furans / Q000737:chemistry*
D005663:Furans; C018674:tetrahydrofuran