Direct synthesis of non-breathing MIL-53(Al)(ht) from a terephthalate-based ionic liquid as linker precursor.
An organic imidazolium salt of terephthalic acid has been utilized as a linker precursor for the synthesis of an aluminum-based metal organic framework (MOF) with MIL-53(ht) structure. This material shows the predicted porosity in terms of nitrogen and hydrogen sorption without exhibiting the breathing effect typical for MIL-53(Al) materials.
Erlangen Catalysis Resource Center, Friedrich-Alexander Universität Erlangen-Nürnberg, Egerlandstr. 3, 91058 Erlangen, Germany. Martin.Hartmann@fau.de.
Marcus
M
Fischer
Institute of Chemical Reaction Engineering, Friedrich-Alexander Universität Erlangen-Nürnberg, Egerlandstr. 3, 91058 Erlangen, Germany. Peter.Schulz@fau.de.
Johannes
J
Schwegler
Erlangen Catalysis Resource Center, Friedrich-Alexander Universität Erlangen-Nürnberg, Egerlandstr. 3, 91058 Erlangen, Germany. Martin.Hartmann@fau.de.
Carolin
C
Paula
Institute of Chemical Reaction Engineering, Friedrich-Alexander Universität Erlangen-Nürnberg, Egerlandstr. 3, 91058 Erlangen, Germany. Peter.Schulz@fau.de.
Peter S
PS
Schulz
Erlangen Catalysis Resource Center, Friedrich-Alexander Universität Erlangen-Nürnberg, Egerlandstr. 3, 91058 Erlangen, Germany. Martin.Hartmann@fau.de.
Martin
M
Hartmann