Development of Heteroatom-introducing Methodologies Based on Ate Complex Formation: Perfluoroalkylation, Borylation, Aromatic Hydroxylation, and Amination Reactions.
We have developed regio- and chemoselective heteroelement-introducing reactions based on ate complex formation. This review is focused on novelly designed reactive species for efficient access to perfluoroalkylated aliphatic and aromatic compounds as well as Csp2-borylated compounds.
Graduate School of Pharmaceutical Sciences, The University of Tokyo.
Keiichi
K
Hirano
D000478:Alkylation; D000586:Amination; D002621:Chemistry / Q000379:methods*; D056831:Coordination Complexes / Q000737:chemistry*; D015195:Drug Design; D006900:Hydroxylation
D056831:Coordination Complexes