Facile Synthesis of Monodispersed Polysulfide Spheres for Building Structural Colors with High Color Visibility and Broad Viewing Angle.
The synthesis and assembly of monodispersed colloidal spheres are currently the subject of extensive investigation to fabricate artificial structural color materials. However, artificial structural colors from general colloidal crystals still suffer from the low color visibility and strong viewing angle dependence which seriously hinder their practical application in paints, colorimetric sensors, and color displays. Herein, monodispersed polysulfide (PSF) spheres with intrinsic high refractive index (as high as 1.858) and light-absorbing characteristics are designed, synthesized through a facile polycondensation and crosslinking process between sodium disulfide and 1,2,3-trichloropropane. Owing to their high monodispersity, sufficient surface charge, and good dispersion stability, the PSF spheres can be assembled into large-scale and high-quality 3D photonic crystals. More importantly, high structural color visibility and broad viewing angle are easily achieved because the unique features of PSF can remarkably enhance the relative reflectivity and eliminate the disturbance of scattering and background light. The results of this study provide a simple and efficient strategy to create structural colors with high color visibility, which is very important for their practical application.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, P. R. China.
Feihu
F
Li
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, P. R. China.
Bingtao
B
Tang
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, P. R. China.
Suli
S
Wu
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, P. R. China.
Shufen
S
Zhang
colloidal assembly; color visibility; high refractive index; monodispersed spheres; structural colors