Grinding size-dependent mechanoresponsive luminescent Cd(ii) coordination polymer.
In this work, we report a new mechanoresponsive luminescent Cd(ii) coordination polymer that exhibits a sensitivity to mechanical stimulation. The luminescence colour changed gradually from weak yellowish-green to bright cyan in response to different grinding sizes, thereby showing interesting mechanochromic properties, namely a grinding-enhanced luminescence and good crystalline maintenance ability.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. zfk@fjirsm.ac.cn and University of Chinese Academy of Sciences, Beijing 100039, P. R. China.
Yong
Y
Yan
Fujian University of Technology, Fuzhou, Fujian 35002, P. R. China.
Jun
J
Chen
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. zfk@fjirsm.ac.cn and University of Chinese Academy of Sciences, Beijing 100039, P. R. China.
Ning-Ning
NN
Zhang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. zfk@fjirsm.ac.cn.
Ming-Sheng
MS
Wang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. zfk@fjirsm.ac.cn and University of Chinese Academy of Sciences, Beijing 100039, P. R. China.
Cai
C
Sun
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. zfk@fjirsm.ac.cn and University of Chinese Academy of Sciences, Beijing 100039, P. R. China.
Xiu-Shuang
XS
Xing
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. zfk@fjirsm.ac.cn and University of Chinese Academy of Sciences, Beijing 100039, P. R. China.
Rong
R
Li
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. zfk@fjirsm.ac.cn and University of Chinese Academy of Sciences, Beijing 100039, P. R. China.
Jian-Gang
JG
Xu
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. zfk@fjirsm.ac.cn.
Fa-Kun
FK
Zheng
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. zfk@fjirsm.ac.cn.
Guo-Cong
GC
Guo