Efficient and recyclable copper-based MOF-catalyzed N-arylation of N-containing heterocycles with aryliodides.
Copper-based MOF-199 was used as an efficient heterogeneous catalyst to catalyze cross-coupling reactions between N-containing heterocycles and aryliodides with high yields. The catalyst can be easily separated from the reaction mixture, and can be reused at least 5 times without significantly decreasing the activity. The XRD results showed that the crystallinity and structure of MOF-199 can be maintained well during the coupling reaction.
School of Chemistry and Chemical Engineering/The Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, Shihezi 832003, China. cesxjw@foxmail.com.
Zihao
Z
Li
Guangdong Bioengineering Institute, Guangdong Academy of Science, Guangzhou 510316, China.
Fei
F
Meng
School of Chemistry and Chemical Engineering/The Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, Shihezi 832003, China. cesxjw@foxmail.com.
Jie
J
Zhang
School of Chemistry and Chemical Engineering/The Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, Shihezi 832003, China. cesxjw@foxmail.com.
Jianwei
J
Xie
School of Chemistry and Chemical Engineering/The Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, Shihezi 832003, China. cesxjw@foxmail.com.
Bin
B
Dai