Thermoelectric properties of in-situ plasma spray synthesized sub-stoichiometry TiO2-x.
The thermoelectric properties of sub-stoichiometric TiO2-xdeposits produced by cascaded-plasma spray process are investigated from room-temperature to 750 K. Sub-stoichiometric TiO2-xdeposits are formed through in-situ reaction of the TiO1.9within the high temperature plasma flame and manipulated through introduction of varying amounts of hydrogen in the plasma. Although the TiO2-xparticles experience reduction within plasma, it can also re-oxidize through interaction with the surrounding ambient atmosphere, resulting in a complex interplay between process conditions and stoichiometry. The deposits predominantly contain rutile phase with presence of Magneli phases especially under significantly reducing plasma conditions. The resultant deposits show sensitivity to thermoelectric properties and under certain optimal conditions repeatedly show Seebeck coefficients reaching values of -230 μV K-1at temperatures of 750 K while providing an electrical conductivity of 5.48 × 103S m-1, relatively low thermal conductivity in the range of 1.5 to 2 W m-1K-1resulting in power factor of 2.9 μW cm-1K-2. The resultant maximum thermoelectric figure of merit value reached 0.132 under these optimal conditions. The results point to a potential pathway for a large-scale fabrication of low-cost oxide based thermoelectric with potential applicability at moderate to high temperatures.
Center for Thermal Spray Research, Stony Brook University, Stony Brook, NY11794-2275, USA.
Hwasoo
H
Lee
Center for Thermal Spray Research, Stony Brook University, Stony Brook, NY11794-2275, USA.
Su Jung
SJ
Han
Center for Thermal Spray Research, Stony Brook University, Stony Brook, NY11794-2275, USA.
Ramachandran
R
Chidambaram Seshadri
Center for Thermal Spray Research, Stony Brook University, Stony Brook, NY11794-2275, USA.
Sanjay
S
Sampath