Sorption isotherms, kinetic and optimization process of amino acid proline based polymer nanocomposite for the removal of selected textile dyes from industrial wastewater.
In this article, adsorption and kinetic studies were carried out on three textile dyes, namely Reactive Blue 222 (RB 222), Reactive Red 195 (RR 195) and Reactive Yellow 145 (RY 145). The dyes studied in a mixture were adsorbed under various conditions onto PRO-BEN, a bentonite modified with a new cationic proline polymer (l-proline-epichlorohydrin polymer). The proline polymer was characterized by1H NMR, Fourier transform infrared spectroscopy (FT-IR), dynamic light scattering (DLS) and TEM. The PRO-BEN composite was characterized by FT-IR, dynamic light scattering (DLS) (zeta potential), TEM imaging, SEM/EDX and X-ray photoelectron spectroscopy (characterize the binding energy). During adsorption studies, factors involving pH, temperature, the initial concentrations of the dyes and the quantity of PRO-BEN used during adsorption were established. The results revealed that the adsorption mechanism was categorized by the Langmuir type 1 isotherm. The adsorption data followed the pseudo-second order kinetic model. The intraparticle diffusion model indicated that adsorption did not only depend on the intraparticle diffusion of the dyes. The thermodynamic parameters verified that the adsorption process was spontaneous and exothermic. The Gibbs free energy values indicated that physisorption had occurred. Successful adsorption of dyes from an industrial effluent was achieved. Desorption studies concluded that PRO-BEN desorbed the dyes better than alumina. This can thereby be viewed as a recyclable remediation material. The PRO-BEN composite could be a cost efficient alternative towards the removal of organic dyes in wastewater treatment.
Department of Chemistry, Faculty of Applied Sciences, Durban University of Technology, Durban, South Africa.
Sharista
S
Raghunath
Department of Chemistry, Faculty of Applied Sciences, Durban University of Technology, Durban, South Africa. Electronic address: organicanand@gmail.com.
K
K
Anand
Department of Chemistry, Faculty of Applied Sciences, Durban University of Technology, Durban, South Africa. Electronic address: genganrm@dut.ac.za.
R M
RM
Gengan
Department of Civil and Chemical Engineering, University of South Africa (UNISA), South Africa.
Mithil Kumar
MK
Nayunigari
Department of Civil and Chemical Engineering, University of South Africa (UNISA), South Africa.
Arjun
A
Maity
D000327:Adsorption; D004396:Coloring Agents / Q000302:isolation & purification*; D007220:Industrial Waste; D007700:Kinetics; D008854:Microscopy, Electron / Q000379:methods; D053761:Nanocomposites / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D011392:Proline / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared; D013784:Textiles; D013816:Thermodynamics; D062065:Wastewater / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*
D004396:Coloring Agents; D007220:Industrial Waste; D011108:Polymers; D011392:Proline; D062065:Wastewater; D014874:Water Pollutants, Chemical
Adsorption kinetics; PRO-BEN; Proline polymer; Reactive dyes; XPS