title: Synthesis and structure of Zr(iv)- and Ce(iv)-based CAU-24 with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene.
abstract: Two new MOFs denoted as M-CAU-24 (M = Zr, Ce) based on 1,2,4,5-tetrakis(4-carboxyphenyl)benzene (H4TCPB) were obtained under mild reaction conditions within 15 min. The MOFs with composition [M6(μ3-O)4(μ3-OH)4(OH)4(H2O)4(TCPB)2] crystallise in the scu topology, a connectivity hitherto unreported for Zr-MOFs with tetracarboxylate linker molecules. Zr-CAU-24 exhibits UV/blue ligand-based luminescence.
authors.affiliation: Institut für Anorganische Chemie, Christian-Albrechts-Universität zu Kiel, Max-Eyth-Straße 2, 24118 Kiel, Germany. stock@ac.uni-kiel.de.
authors.forename: M
authors.initials: M
authors.lastname: Lammert
authors.forename: H
authors.initials: H
authors.lastname: Reinsch
authors.forename: C A
authors.initials: CA
authors.lastname: Murray
authors.forename: M T
authors.initials: MT
authors.lastname: Wharmby
authors.forename: H
authors.initials: H
authors.lastname: Terraschke
authors.forename: N
authors.initials: N
authors.lastname: Stock