title: Crystal structure ofcatena-poly[[(N,N-diethyl-3-mesitylsulfonyl-1H-1,2,4-triazole-1-carboxamide-κN1)silver(I)]-μ-nitrato-κ3O,O':O].
abstract: The reaction of silver nitrate and cafenstrole (N,N-diethyl-3-mesitylsulfonyl-1H-1,2,4-triazole-1-carboxamide), a triazole herbicide, leads to the title coordination polymer, [Ag(NO3)(C16H22N4O3S)]n, whose asymmetric unit comprises one cafenstrole ligand mol-ecule, one AgIatom and one nitrate ion. The AgIatom, with a distorted trigonal-pyramidal environment, is coordinated by one nitro-gen atom of a triazole ring, two oxygen atoms of a nitrate ion and one oxygen atom of a neighboring nitrate ion. The coordination bonds between silver and oxygen atoms give rise to a one-dimensional (1D) coordination polymer structure along [001]. The dihedral angle between the planes of the triazole and benzene rings is 87.13 (11)°. In the crystal, the coordination polymer is stabilized by C-H⋯O hydrogen bonds and C-H⋯π inter-actions, resulting in a three-dimensional architecture.
authors.affiliation: Department of Chemistry (BK21 plus) and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 52828, Republic of Korea.
authors.forename: Hyunjin
authors.initials: H
authors.lastname: Park
authors.affiliation: Department of Chemistry (BK21 plus) and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 52828, Republic of Korea.
authors.forename: Eunjin
authors.initials: E
authors.lastname: Kwon
authors.affiliation: Photodynamic Therapy Research Institute, School of Nanoscience and Engineering, Inje University, 197 Injero, Gimhae, Gyeongnam 50834, Republic of Korea.
authors.forename: Il
authors.initials: I
authors.lastname: Yoon
authors.affiliation: Department of Chemistry (BK21 plus) and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 52828, Republic of Korea.
authors.forename: Jineun
authors.initials: J
authors.lastname: Kim
keywords: cafenstrole; coordination polymer; crystal structure; herbicide; silver; triazole