title: Pb2Bi2GaB3O11, a new congruent-melting galloborate containing two types of asymmetric cations with a moderate birefringence.
abstract: Pb2Bi2GaB3O11, a new congruent-melting galloborate, which simultaneously contains two types of lone-pair cations and a π-conjugated system in one crystal structure, has been discovered through spontaneous crystallization. Single-crystal X-ray structural analysis shows that Pb2Bi2GaB3O11crystallizes in the monoclinic space group of C2/c. The parameters of the unit cell are a = 17.318(5) Å, b = 8.868(3) Å, c = 6.779(2) Å, β = 90.238(4)° and Z = 6. The structure of Pb2Bi2GaB3O11features three kinds of tunnels, circled by cation polyhedra, in two of which isolated BO3groups reside. However, the open Bi4O4channel, as the third tunnel formed by the Bi-O polyhedra, is hollow. Pb2Bi2GaB3O11possesses an experimental band gap of 4.43 eV and an ultraviolet (UV) cut-off edge of about 280 nm, which is proven by its diffuse reflection spectrum. Theoretical calculations have also been executed to evaluate its band structure, partial density of state (PDOS) and birefringence. The results indicate that the title compound possesses a direct band gap with a theoretical value of 3.48 eV, and even indicate that the Pb2+and Bi3+ions are stereochemically active and cooperate with the BO3groups, which contributes to a moderate birefringence of about 0.07 at 589 nm for Pb2Bi2GaB3O11.
authors.affiliation: Key Laboratory of Functional Materials and Devices for Special Environments of CAS; Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics & Chemistry of CAS, 40-1 South Beijing Road, Urumqi 830011, China. slpan@ms.xjb.ac.cn yangyun@ms.xjb.ac.cn.
authors.forename: Lili
authors.initials: L
authors.lastname: Liu
authors.forename: Yun
authors.initials: Y
authors.lastname: Yang
authors.forename: Linping
authors.initials: L
authors.lastname: Li
authors.forename: Zhihua
authors.initials: Z
authors.lastname: Yang
authors.forename: Shilie
authors.initials: S
authors.lastname: Pan