title: Enantiospecific total syntheses of meroterpenoids (-)-F1839-I and (-)-corallidictyals B and D.
abstract: Enantiospecific total syntheses of spiromeroterpenoid natural products (-)-F1839-I and (-)-corallidictyals B and D were achieved using the environmentally benign and highly atom economical Lewis acid catalysed Friedel-Crafts reaction and a highly regio- and stereoselective spirocyclic C-O bond formation reaction.
authors.affiliation: Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur - 208016, India. ddethe@iitk.ac.in.
authors.forename: Dattatraya H
authors.initials: DH
authors.lastname: Dethe
authors.affiliation: Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur - 208016, India. ddethe@iitk.ac.in.
authors.forename: Balu D
authors.initials: BD
authors.lastname: Dherange
authors.affiliation: Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur - 208016, India. ddethe@iitk.ac.in.
authors.forename: Saghir
authors.initials: S
authors.lastname: Ali
authors.affiliation: Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur - 208016, India. ddethe@iitk.ac.in.
authors.forename: Mahesh M
authors.initials: MM
authors.lastname: Parsutkar
mesh_terms: D001688:Biological Products / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D055772:Green Chemistry Technology; D058116:Lewis Acids / Q000737:chemistry; D008958:Models, Molecular; D012717:Sesquiterpenes / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism; D013729:Terpenes / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D001688:Biological Products; D058116:Lewis Acids; D012717:Sesquiterpenes; D013729:Terpenes; C586604:corallidictyal D; C091979:corallidictyal A