title: Functionalization of Unactivated C(sp3)-H Bonds Using Metal-Carbene Insertion Reactions.
abstract: Versatile C-H insertions: Novel protocols for metal-carbene insertions using diazo compounds have been recently developed. Application of the respective rhodium and palladium catalytic systems allows formation of new carbon-carbon bonds in very good yields and selectivities.
authors.affiliation: Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059, Rostock, Germany.
authors.forename: Miguel
authors.initials: M
authors.lastname: Peña-López
authors.affiliation: Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059, Rostock, Germany.
authors.forename: Matthias
authors.identifier: 0000-0001-5709-0965
authors.initials: M
authors.lastname: Beller
keywords: C−H functionalization; carbenes; diazo compounds; palladium; rhodium