title: Pushing TCto 27.5 K in a heavy atom radical ferromagnet.
abstract: In the solid state the iodo-substituted bisdiselenazolyl radical 1c orders as a ferromagnet with TC= 10.5 K. With the application of pressure TCrises rapidly, reaching a value of 27.5 K at 2.4 GPa. The accompanying structural and magnetic changes have been examined by high resolution powder X-ray diffraction and by DFT calculations of magnetic exchange interactions.
authors.affiliation: Department of Chemistry, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada. oakley@uwaterloo.ca.
authors.forename: Kristina
authors.initials: K
authors.lastname: Lekin
authors.affiliation: Graduate School of Engineering, Kyushu Institute of Technology, Kitakyushu 804-8550, Japan.
authors.forename: Kazuma
authors.initials: K
authors.lastname: Ogata
authors.affiliation: Department of Chemistry, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada. oakley@uwaterloo.ca.
authors.forename: Adrian
authors.initials: A
authors.lastname: Maclean
authors.affiliation: Department of Chemistry, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada. oakley@uwaterloo.ca.
authors.forename: Aaron
authors.initials: A
authors.lastname: Mailman
authors.affiliation: Department of Chemistry, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada. oakley@uwaterloo.ca.
authors.forename: Stephen M
authors.initials: SM
authors.lastname: Winter
authors.affiliation: Department of Chemistry, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada. oakley@uwaterloo.ca.
authors.forename: Abdeljalil
authors.initials: A
authors.lastname: Assoud
authors.affiliation: Graduate School of Engineering, Kyushu Institute of Technology, Kitakyushu 804-8550, Japan.
authors.forename: Masaki
authors.initials: M
authors.lastname: Mito
authors.affiliation: Department of Physics, University of Saskatchewan, Saskatoon, Saskatchewan S7N 5E2, Canada.
authors.forename: John S
authors.initials: JS
authors.lastname: Tse
authors.affiliation: Laboratoire de Physique des Solides Denses, Department of Physics, University of Ottawa, Ottawa, Ontario K1N 6N5, Canada.
authors.forename: Serge
authors.initials: S
authors.lastname: Desgreniers
authors.affiliation: Materials Science Division, Japan Synchrotron Radiation Research Institute, SPring-8, Sayo, Hyogo 679-5198, Japan.
authors.forename: Naohisa
authors.initials: N
authors.lastname: Hirao
authors.affiliation: Brockhouse Institute for Materials Research, McMaster University, Hamilton, Ontario L8S 4M1, Canada.
authors.forename: Paul A
authors.initials: PA
authors.lastname: Dube
authors.affiliation: Department of Chemistry, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada. oakley@uwaterloo.ca.
authors.forename: Richard T
authors.initials: RT
authors.lastname: Oakley