title: Triazine-Based Highly Stable AADD-Type Self-Complementary Quadruple Hydrogen-Bonded Systems Devoid of Prototropy.
abstract: A new class of 1,3,5-triazine-based quadruple hydrogen-bonded system featuring AADD-type self-complementary arrays has been developed and characterized. This system forms highly stable molecular duplex in non-polar solvent (Kdim>1.9×107m-1in CDCl3) without prototropy-related issues, raising its prospects for application in supramolecular polymer science.
authors.affiliation: Organic Chemistry Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune, 411008, India.
authors.forename: Sanjeev
authors.initials: S
authors.lastname: Kheria
authors.affiliation: Organic Chemistry Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune, 411008, India.
authors.forename: Suresh
authors.initials: S
authors.lastname: Rayavarapu
authors.affiliation: Central NMR Facility, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune, 411008, India.
authors.forename: Amol S
authors.initials: AS
authors.lastname: Kotmale
authors.affiliation: Centre for Materials Characterization, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune-, 411008, India.
authors.forename: Rajesh G
authors.initials: RG
authors.lastname: Gonnade
authors.affiliation: Organic Chemistry Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune, 411008, India.
authors.forename: Gangadhar J
authors.initials: GJ
authors.lastname: Sanjayan
keywords: dimerization; prototropy; quadruple hydrogen bonding; self-assembly; triazines