title: The Diphosphorus Complex [Cp2Mo2(CO)4(η2-P2)] as a Building Block for the Synthesis of Mixed-Hybrid Coordination Polymers.
abstract: The three-component reaction of the tetrahedral diphosphorus complex [Cp2Mo2(CO)4(η2-P2)] (1), with Ag[BF4] (2) in the presence of 2,2'-bipyrimidine (3) leads to the formation of the two novel two-dimensional networks4and5. Compound4is a new two-dimensional organometallic-organic hybrid polymer, while derivative5represents a unique two-dimensional organometallic-inorganic-organic hybrid polymer. These results show the possibility of synthesizing a new class of coordination polymers, which could not be obtained from two-component reactions with organic molecules in addition of metal ions.
authors.affiliation: Institut für Anorganische Chemie der Universität Regensburg 93040 Regensburg Germany.
authors.forename: Mehdi Elsayed
authors.initials: ME
authors.lastname: Moussa
authors.affiliation: Institut für Anorganische Chemie der Universität Regensburg 93040 Regensburg Germany.
authors.forename: Bianca
authors.initials: B
authors.lastname: Attenberger
authors.affiliation: Institut für Anorganische Chemie der Universität Regensburg 93040 Regensburg Germany.
authors.forename: Martin
authors.initials: M
authors.lastname: Fleischmann
authors.affiliation: Institut für Anorganische Chemie der Universität Regensburg 93040 Regensburg Germany.
authors.forename: Andrea
authors.initials: A
authors.lastname: Schreiner
authors.affiliation: Institut für Anorganische Chemie der Universität Regensburg 93040 Regensburg Germany.
authors.forename: Manfred
authors.identifier: 0000-0003-2182-5020
authors.initials: M
authors.lastname: Scheer
keywords: 2,2′‐Bipyrimidine; Hybrid polymers; Molybdenum; Phosphorus; Self‐assembly