title: Dual responsive Pickering emulsions stabilized by constructed core crosslinked polymer nanoparticles via reversible covalent bonds.
abstract: In this study, pH- and glucose-responsive Pickering emulsions stabilized by core crosslinked polymer nanoparticles, which were constructed via reversible covalent bonds, were presented for the first time. Firstly, well-defined PDMA-b-PAPBA (poly(N,N-dimethylacrylamide)-b-poly(3-acrylamidophenylboronic acid)) diblock copolymers were synthesized via sequential reversible addition-fragmentation chain transfer (RAFT) polymerization reactions. By means of complexation of PBA units of PDMA-b-PAPBA with PVA in basic water, core crosslinked polymer nanoparticles (CCPNs) with a core-shell structure were formed. The PAPBA/PVA crosslinked network and PDMA acted as the core and shell, respectively. Because of the reversible B-O chemical bonds in the core, the as-produced CCPNs showed structural transitions in response to the external stimuli involving pH and glucose. Investigation of the interfacial activities revealed that CCPNs exhibited high emulsifying performances, and oil in water (o/w) Pickering emulsions could be formed at a low particle content. The formed Pickering emulsions showed high stability at room temperature without any disturbances, whereas de-emulsification was observed upon improving the pH or adding glucose at a given pH. This is the first report on a responsive Pickering emulsion whose stability can be manipulated by glucose, and this type of fabricated manipulative Pickering emulsions are expected to provide useful guidance in the fields of oil recovery, interfacial reactions, etc.
authors.affiliation: College of Chemistry, Xiangtan University, Xiangtan, Hunan Province 411105, China. gydx.1027@163.com.
authors.forename: Huazhang
authors.initials: H
authors.lastname: Guo
authors.affiliation: College of Chemistry, Xiangtan University, Xiangtan, Hunan Province 411105, China. gydx.1027@163.com.
authors.forename: Duanguang
authors.initials: D
authors.lastname: Yang
authors.affiliation: College of Chemistry, Xiangtan University, Xiangtan, Hunan Province 411105, China. gydx.1027@163.com.
authors.forename: Mei
authors.initials: M
authors.lastname: Yang
authors.affiliation: College of Chemistry, Xiangtan University, Xiangtan, Hunan Province 411105, China. gydx.1027@163.com and Key Laboratory of Polymeric Materials & Application Technology of Hunan Province, Key Laboratory of Advanced Functional Polymeric Materials of College of Hunan Province, Xiangtan, Hunan Province 411105, China.
authors.forename: Yong
authors.initials: Y
authors.lastname: Gao
authors.affiliation: College of Chemistry, Xiangtan University, Xiangtan, Hunan Province 411105, China. gydx.1027@163.com.
authors.forename: Yijiang
authors.initials: Y
authors.lastname: Liu
authors.affiliation: College of Chemistry, Xiangtan University, Xiangtan, Hunan Province 411105, China. gydx.1027@163.com and Key Laboratory of Polymeric Materials & Application Technology of Hunan Province, Key Laboratory of Advanced Functional Polymeric Materials of College of Hunan Province, Xiangtan, Hunan Province 411105, China.
authors.forename: Huaming
authors.initials: H
authors.lastname: Li