title: Synthesis and Electrochemical Lithium Storage Behavior of Carbon Nanotubes Filled with Iron Sulfide Nanoparticles.
abstract: Carbon nanotubes (CNTs) filled with iron sulfide nanoparticles (NPs) are prepared by inserting sulfur and ferrocene into the hollow core of CNTs followed by heat treatment. It is found that pyrrhotite-11T iron sulfide (Fe-S) NPs with an average size of ≈15 nm are encapsulated in the tubular cavity of the CNTs (Fe-S@CNTs), and each particle is a single crystal. When used as the anode material of lithium-ion batteries, the Fe-S@CNT material exhibits excellent electrochemical lithium storage performance in terms of high reversible capacity, good cyclic stability, and desirable rate capability. In situ transmission electron microscopy studies show that the CNTs not only play an essential role in accommodating the volume expansion of the Fe-S NPs but also provide a fast transport path for Li ions. The results demonstrate that CNTs act as a unique nanocontainer and reactor that permit the loading and formation of electrochemically active materials with desirable electrochemical lithium storage performance. CNTs with their superior structural stability and Li-ion transfer kinetics are responsible for the improved rate capability and cycling performance of Fe-S NPs in CNTs.
authors.affiliation: Shenyang National Laboratory for Materials Science Institute of Metal Research Chinese Academy of Sciences Shenyang 110016 P. R. China; School of Metallurgy and Environment Central South University Changsha 410083 P. R. China.
authors.forename: Wan-Jing
authors.initials: WJ
authors.lastname: Yu
authors.affiliation: Shenyang National Laboratory for Materials Science Institute of Metal Research Chinese Academy of Sciences Shenyang 110016 P. R. China.
authors.forename: Chang
authors.initials: C
authors.lastname: Liu
authors.affiliation: Shenyang National Laboratory for Materials Science Institute of Metal Research Chinese Academy of Sciences Shenyang 110016 P. R. China.
authors.forename: Lili
authors.initials: L
authors.lastname: Zhang
authors.affiliation: Shenyang National Laboratory for Materials Science Institute of Metal Research Chinese Academy of Sciences Shenyang 110016 P. R. China.
authors.forename: Peng-Xiang
authors.initials: PX
authors.lastname: Hou
authors.affiliation: Shenyang National Laboratory for Materials Science Institute of Metal Research Chinese Academy of Sciences Shenyang 110016 P. R. China.
authors.forename: Feng
authors.initials: F
authors.lastname: Li
authors.affiliation: School of Metallurgy and Environment Central South University Changsha 410083 P. R. China.
authors.forename: Bao
authors.initials: B
authors.lastname: Zhang
authors.affiliation: Shenyang National Laboratory for Materials Science Institute of Metal Research Chinese Academy of Sciences Shenyang 110016 P. R. China.
authors.forename: Hui-Ming
authors.initials: HM
authors.lastname: Cheng
keywords: carbon nanotubes; confinement effect; in situ TEM; iron sulfide nanoparticles; lithium‐ion batteries