title: Wire-Active Microrheology to Differentiate Viscoelastic Liquids from Soft Solids.
abstract: Viscoelastic liquids are characterized by a finite static viscosity and a yield stress of zero, whereas soft solids have an infinite viscosity and a non-zero yield stress. The rheological nature of viscoelastic materials has long been a challenge and is still a matter of debate. Here, we provide for the first time the constitutive equations of linear viscoelasticity for magnetic wires in yield-stress materials, together with experimental measurements by using magnetic rotational spectroscopy (MRS). In MRS, the wires were subjected to a rotational magnetic field as a function of frequency and the motion of the wire was monitored by using time-lapse microscopy. The studied soft solids were aqueous dispersions of gel-forming polysaccharide (gellan gum) at concentrations above the gelification point. It was found that soft solids exhibited a clear and distinctive signature compared with viscous and viscoelastic liquids. In particular, the average wire rotation velocity equaled zero over a broad frequency range. We also showed that the MRS technique is quantitative. The equilibrium elastic modulus was retrieved from the wire oscillation amplitudes, and agrees with polymer-dynamics theory.
authors.affiliation: Matière et Systèmes Complexes, UMR 7057 CNRS, Université Denis Diderot Paris-VII, Bâtiment Condorcet, 10 rue Alice Domon et Léonie Duquet, 75205, Paris, France.
authors.forename: Frédéric
authors.initials: F
authors.lastname: Loosli
authors.affiliation: Matière et Systèmes Complexes, UMR 7057 CNRS, Université Denis Diderot Paris-VII, Bâtiment Condorcet, 10 rue Alice Domon et Léonie Duquet, 75205, Paris, France.
authors.forename: Matthieu
authors.initials: M
authors.lastname: Najm
authors.affiliation: Matière et Systèmes Complexes, UMR 7057 CNRS, Université Denis Diderot Paris-VII, Bâtiment Condorcet, 10 rue Alice Domon et Léonie Duquet, 75205, Paris, France.
authors.forename: Raymond
authors.initials: R
authors.lastname: Chan
authors.affiliation: Matière et Systèmes Complexes, UMR 7057 CNRS, Université Denis Diderot Paris-VII, Bâtiment Condorcet, 10 rue Alice Domon et Léonie Duquet, 75205, Paris, France.
authors.forename: Evdokia
authors.initials: E
authors.lastname: Oikonomou
authors.affiliation: Matière et Systèmes Complexes, UMR 7057 CNRS, Université Denis Diderot Paris-VII, Bâtiment Condorcet, 10 rue Alice Domon et Léonie Duquet, 75205, Paris, France.
authors.forename: Arnaud
authors.initials: A
authors.lastname: Grados
authors.affiliation: Matière et Systèmes Complexes, UMR 7057 CNRS, Université Denis Diderot Paris-VII, Bâtiment Condorcet, 10 rue Alice Domon et Léonie Duquet, 75205, Paris, France.
authors.forename: Mathieu
authors.initials: M
authors.lastname: Receveur
authors.affiliation: Matière et Systèmes Complexes, UMR 7057 CNRS, Université Denis Diderot Paris-VII, Bâtiment Condorcet, 10 rue Alice Domon et Léonie Duquet, 75205, Paris, France.
authors.forename: Jean-François
authors.initials: JF
authors.lastname: Berret
keywords: gels; magnetic properties; microrheology; rotational spectroscopy; viscoelastic solids