title: [Ag(OH2)2][Ag(SO4)2]: A Hydrate of a Silver(II) Salt.
abstract: When exposed to air at ambient conditions, AgSO4slowly reacts with moisture, yielding AgSO4⋅H2O. The crystal structure determination (powder data) shows that it may be described as [Ag(OH2)2][Ag(SO4)2], with some sulfate groups being shared between different Ag2+cations, resembling in that way its Cu2+analogue. [Ag(OH2)2][Ag(SO4)2], the first hydrate of a compound of Ag2+, was extensively characterized using many physicochemical methods.
authors.affiliation: Centre of New Technologies, University of Warsaw, Żwirki i Wigury 93, 02-089, Warsaw, Poland.|Faculty of Chemistry, University of Warsaw, Pasteur 1, 02-093, Warsaw, Poland.
authors.forename: Tomasz E
authors.initials: TE
authors.lastname: Gilewski
authors.affiliation: Centre of New Technologies, University of Warsaw, Żwirki i Wigury 93, 02-089, Warsaw, Poland.|Faculty of Chemistry, University of Warsaw, Pasteur 1, 02-093, Warsaw, Poland.
authors.forename: Jakub
authors.initials: J
authors.lastname: Gawraczyński
authors.affiliation: Centre of New Technologies, University of Warsaw, Żwirki i Wigury 93, 02-089, Warsaw, Poland.
authors.forename: Mariana
authors.initials: M
authors.lastname: Derzsi
authors.affiliation: University of Ljubljana, Faculty of Civil and Geodetic Engineering, Institute of Mathematics, Physics and Mechanics, Jadranska 19, 1000, Ljubljana, Slovenia.
authors.forename: Zvonko
authors.initials: Z
authors.lastname: Jagličić
authors.affiliation: Department of Inorganic Chemistry and Technology, Jožef Stefan Institute, Jamova 39, 1000, Ljubljana, Slovenia.
authors.forename: Zoran
authors.initials: Z
authors.lastname: Mazej
authors.affiliation: Faculty of Chemistry, University of Warsaw, Pasteur 1, 02-093, Warsaw, Poland.
authors.forename: Piotr
authors.initials: P
authors.lastname: Połczyński
authors.affiliation: Faculty of Chemistry, University of Warsaw, Pasteur 1, 02-093, Warsaw, Poland.
authors.forename: Rafal
authors.initials: R
authors.lastname: Jurczakowski
authors.affiliation: Centre of New Technologies, University of Warsaw, Żwirki i Wigury 93, 02-089, Warsaw, Poland.
authors.forename: Piotr J
authors.initials: PJ
authors.lastname: Leszczyński
authors.affiliation: Centre of New Technologies, University of Warsaw, Żwirki i Wigury 93, 02-089, Warsaw, Poland.
authors.forename: Wojciech
authors.identifier: http://orcid.org/0000-0001-7317-5547
authors.initials: W
authors.lastname: Grochala
keywords: hydrates; oxidizers; silver; sulfate