title: Chiral Hypervalent, Pentacoordinated Phosphoranes.
abstract: This review presents synthetic procedures applied to the preparation of chiral (mainly optically active) pentacoordinated, hypervalent mono and bicyclic phosphoranes. The mechanisms of their stereoisomerization and their selected interconversions are also presented.
authors.affiliation: Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 Lodz, Poland. dkrasowska@gmail.com.
authors.forename: Dorota
authors.initials: D
authors.lastname: Krasowska
authors.affiliation: Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 Lodz, Poland. jacekchrzanowski1@gmail.com.
authors.forename: Jacek
authors.initials: J
authors.lastname: Chrzanowski
authors.affiliation: Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 Lodz, Poland. piokiel@cbmm.lodz.pl.
authors.forename: Piotr
authors.initials: P
authors.lastname: Kiełbasiński
authors.affiliation: Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 Lodz, Poland. drabow@gmail.com.|Department of Chemistry, Environment Protection and Biotechnology, Jan Dlugosz University in Czestochowa, Armii Krajowej Ave. 13/15, 42-200 Czestochowa, Poland. drabow@gmail.com.
authors.forename: Józef
authors.initials: J
authors.lastname: Drabowicz
mesh_terms: D000838:Anions / Q000737:chemistry; D060326:Chemistry Techniques, Synthetic; D061565:Cycloaddition Reaction; D006868:Hydrolysis; D010753:Phosphoranes / Q000138:chemical synthesis / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000838:Anions; D010753:Phosphoranes
keywords: Berry pseudorotation; chirality; hypervalency; phosphoranes; turnstile rotation