title: Bimodal activated carbons derived from resorcinol-formaldehyde cryogels.
abstract: Resorcinol-formaldehyde cryogels prepared at different dilution ratios have been activated with phosphoric acid at 450 °C and compared with their carbonaceous counterparts obtained by pyrolysis at 900 °C. Whereas the latter were, as expected, highly mesoporous carbons, the former cryogels had very different pore textures. Highly diluted cryogels allowed preparation of microporous materials with high surface areas, but activation of initially dense cryogels led to almost non-porous carbons, with much lower surface areas than those obtained by pyrolysis. The optimal acid concentration for activation, corresponding to stoichiometry between molecules of acid and hydroxyl groups, was 2 M l-1, and the acid-cryogel contact time also had an optimal value. Such optimization allowed us to achieve surface areas and micropore volumes among the highest ever obtained by activation with H3PO4, close to 2200 m2g-1and 0.7 cm3g-1, respectively. Activation of diluted cryogels with a lower acid concentration of 1.2 M l-1led to authentic bimodal activated carbons, having a surface area as high as 1780 m2g-1and 0.6 cm3g-1of microporous volume easily accessible through a widely developed macroporosity.
authors.affiliation: Institut Jean Lamour-UMR CNRS 7198, CNRS-Nancy-Université-UPV-Metz, Département Chimie et Physique des Solides et des Surfaces. ENSTIB, 27 rue Philippe Séguin, BP 1041, 88051 Épinal cedex 9, France.
authors.forename: Andrzej
authors.initials: A
authors.lastname: Szczurek
authors.affiliation: Institut Jean Lamour-UMR CNRS 7198, CNRS-Nancy-Université-UPV-Metz, Département Chimie et Physique des Solides et des Surfaces. ENSTIB, 27 rue Philippe Séguin, BP 1041, 88051 Épinal cedex 9, France.
authors.forename: Gisele
authors.initials: G
authors.lastname: Amaral-Labat
authors.affiliation: Institut Jean Lamour-UMR CNRS 7198, CNRS-Nancy-Université-UPV-Metz, Département Chimie et Physique des Solides et des Surfaces. ENSTIB, 27 rue Philippe Séguin, BP 1041, 88051 Épinal cedex 9, France.
authors.forename: Vanessa
authors.initials: V
authors.lastname: Fierro
authors.affiliation: ENSTIB-LERMAB, Nancy-Université, 27 rue Philippe Séguin, BP1041, 88051 Epinal cedex 9, France.
authors.forename: Antonio
authors.initials: A
authors.lastname: Pizzi
authors.affiliation: Institut Jean Lamour-UMR CNRS 7198, CNRS-Nancy-Université-UPV-Metz, Département Chimie et Physique des Solides et des Surfaces. ENSTIB, 27 rue Philippe Séguin, BP 1041, 88051 Épinal cedex 9, France; Member of the Institut Universitaire de France.
authors.forename: Alain
authors.initials: A
authors.lastname: Celzard
keywords: activated carbons; bimodal porosity; carbon cryogels; resorcinol