title: Superhydrophobic silica wool-a facile route to separating oil and hydrophobic solvents from water.
abstract: Silica microfiber wool was systematically functionalized in order to provide an extremely water repellent and oleophilic material. This was carried out using a two-step functionalization that was shown to be a highly effective method for generating an intense water repulsion and attraction for oil. A demonstration of the silica wools application is shown through the highly efficient separation of oils and hydrophobic solvents from water. Water is confined to the extremities of the material, while oil is absorbed into the voids within the wool. The effect of surface functionalization is monitored though observing the interaction of the material with both oils and water, in addition to scanning electron microscope images, x-ray photoelectron spectroscopy and energy dispersive x-ray analysis. The material can be readily utilized in many applications, including the cleaning of oil spills and filtering during industrial processes, as well as further water purification tasks-while not suffering the losses of efficiency observed in current leading polymeric materials.
authors.affiliation: Materials Chemistry Research Centre, Department of Chemistry, University College London, 20 Gordon Street, London WC1H OAJ, UK.
authors.forename: Colin R
authors.initials: CR
authors.lastname: Crick
authors.affiliation: Materials Chemistry Research Centre, Department of Chemistry, University College London, 20 Gordon Street, London WC1H OAJ, UK.
authors.forename: Davinder S
authors.initials: DS
authors.lastname: Bhachu
authors.affiliation: Materials Chemistry Research Centre, Department of Chemistry, University College London, 20 Gordon Street, London WC1H OAJ, UK.
authors.forename: Ivan P
authors.initials: IP
authors.lastname: Parkin
keywords: oil spill; oleophilic; separation; superhydrophobic; water