title: Influence of Binders and Solvents on Stability of Ru/RuOxNanoparticles on ITO Nanocrystals as Li-O2Battery Cathodes.
abstract: Fundamental research on Li-O2batteries remains critical, and the nature of the reactions and stability are paramount for realising the promise of the Li-O2system. We report that indium tin oxide (ITO) nanocrystals with supported 1-2 nm oxygen evolution reaction (OER) catalyst Ru/RuOxnanoparticles (NPs) demonstrate efficient OER processes, reduce the recharge overpotential of the cell significantly and maintain catalytic activity to promote a consistent cycling discharge potential in Li-O2cells even when the ITO support nanocrystals deteriorate from the very first cycle. The Ru/RuOxnanoparticles lower the charge overpotential compared with those for ITO and carbon-only cathodes and have the greatest effect in DMSO electrolytes with a solution-processable F-free carboxymethyl cellulose (CMC) binder (<3.5 V) instead of polyvinylidene fluoride (PVDF). The Ru/RuOx/ITO nanocrystalline materials in DMSO provide efficient Li2O2decomposition from within the cathode during cycling. We demonstrate that the ITO is actually unstable from the first cycle and is modified by chemical etching, but the Ru/RuOxNPs remain effective OER catalysts for Li2O2during cycling. The CMC binders avoid PVDF-based side-reactions and improve the cyclability. The deterioration of the ITO nanocrystals is mitigated significantly in cathodes with a CMC binder, and the cells show good cycle life. In mixed DMSO-EMITFSI [EMITFSI=1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide] ionic liquid electrolytes, the Ru/RuOx/ITO materials in Li-O2cells cycle very well and maintain a consistently very low charge overpotential of 0.5-0.8 V.
authors.affiliation: Department of Applied Science and Technology (DISAT), Politecnico di Torino, C.so Duca degli Abruzzi 24, 10129, Torino, Italy.
authors.forename: Svetoslava
authors.identifier: 0000-0002-3562-8370
authors.initials: S
authors.lastname: Vankova
authors.affiliation: Department of Applied Science and Technology (DISAT), Politecnico di Torino, C.so Duca degli Abruzzi 24, 10129, Torino, Italy.
authors.forename: Carlotta
authors.identifier: 0000-0003-4772-771X
authors.initials: C
authors.lastname: Francia
authors.affiliation: Department of Applied Science and Technology (DISAT), Politecnico di Torino, C.so Duca degli Abruzzi 24, 10129, Torino, Italy.
authors.forename: Julia
authors.identifier: 0000-0003-4369-317X
authors.initials: J
authors.lastname: Amici
authors.affiliation: Department of Applied Science and Technology (DISAT), Politecnico di Torino, C.so Duca degli Abruzzi 24, 10129, Torino, Italy.
authors.forename: Juqin
authors.initials: J
authors.lastname: Zeng
authors.affiliation: Department of Applied Science and Technology (DISAT), Politecnico di Torino, C.so Duca degli Abruzzi 24, 10129, Torino, Italy.
authors.forename: Silvia
authors.identifier: 0000-0002-3579-9778
authors.initials: S
authors.lastname: Bodoardo
authors.affiliation: Department of Applied Science and Technology (DISAT), Politecnico di Torino, C.so Duca degli Abruzzi 24, 10129, Torino, Italy.
authors.forename: Nerino
authors.initials: N
authors.lastname: Penazzi
authors.affiliation: Department of Chemistry, University College Cork, Cork, T12 YN60, Ireland.
authors.forename: Gillian
authors.initials: G
authors.lastname: Collins
authors.affiliation: Department of Chemistry, University College Cork, Cork, T12 YN60, Ireland.
authors.forename: Hugh
authors.initials: H
authors.lastname: Geaney
authors.affiliation: Department of Chemistry, University College Cork, Cork, T12 YN60, Ireland.|Micro-Nano Systems Centre, Tyndall National Institute, Lee Maltings, Cork, T12 R5CP, Ireland.
authors.forename: Colm
authors.identifier: 0000-0001-7429-015X
authors.initials: C
authors.lastname: O'Dwyer
mesh_terms: D002384:Catalysis; D011211:Electric Power Supplies; D004563:Electrochemistry; D004566:Electrodes; D008094:Lithium / Q000737:chemistry*; D053768:Metal Nanoparticles / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D017975:Ruthenium Compounds / Q000737:chemistry; D012997:Solvents / Q000737:chemistry*; D017971:Tin Compounds / Q000737:chemistry*
chemical_list: D017975:Ruthenium Compounds; D012997:Solvents; D017971:Tin Compounds; C109984:indium tin oxide; D012428:Ruthenium; C027646:ruthenium tetraoxide; D008094:Lithium; D010100:Oxygen
keywords: batteries; lithium; nanoparticles; oxygen evolution reaction; ruthenium