title: Assembly of NHC-stabilized 2-hydrophosphasilenes from Si(iv) precursors: a Lewis acid-base complex.
abstract: NHC-stabilized 2-hydrophosphasilenes are obtained from 1,2-dihydro-2-chlorophosphasilanes as Si(iv) precursors by a NHC-assisted 1,2-elimination of HCl. The NHC-exchange of these compounds is demonstrated as a proof of donor acceptor bonding between NHC and the silicon centre of the "Si[double bond, length as m-dash]P" moiety. We have also explored the possibility of similar exchanges in NHC-stabilized Si2and P2compounds. Theoretical DFT calculations were performed to address the nature of Si-P bonding in the NHC-stabilized 2-hydrophosphasilenes.
authors.affiliation: Tata Institute of Fundamental Research, Centre for Interdisciplinary Sciences 21, Brundavan Colony, Narsingi, Hyderabad-500075, India. ajana@tifrh.res.in.
authors.forename: Debabrata
authors.initials: D
authors.lastname: Dhara
authors.affiliation: Tata Institute of Fundamental Research, Centre for Interdisciplinary Sciences 21, Brundavan Colony, Narsingi, Hyderabad-500075, India. ajana@tifrh.res.in.
authors.forename: Debdeep
authors.initials: D
authors.lastname: Mandal
authors.affiliation: Tata Institute of Fundamental Research, Centre for Interdisciplinary Sciences 21, Brundavan Colony, Narsingi, Hyderabad-500075, India. ajana@tifrh.res.in.
authors.forename: Avijit
authors.initials: A
authors.lastname: Maiti
authors.affiliation: Department of Medicinal and Aromatic Plants, University of Aksaray, Aksaray, Turkey. cemburakyildiz@aksaray.edu.tr.
authors.forename: Cem B
authors.initials: CB
authors.lastname: Yildiz
authors.affiliation: National Institute of Science Education and Research, Bhimpur-Padanpur, Jatni, Khurda, Bhubaneswar-752050, Odisha, India.
authors.forename: Pankaj
authors.initials: P
authors.lastname: Kalita
authors.affiliation: Institut für Biochemie, Ernst-Moritz-Arndt Universität Greifswald, Felix-Hausdorff-Straße 4, D-17487 Greifswald, Germany. carola.schulzke@uni-greifswald.de.
authors.forename: Nicolas
authors.initials: N
authors.lastname: Chrysochos
authors.affiliation: Institut für Biochemie, Ernst-Moritz-Arndt Universität Greifswald, Felix-Hausdorff-Straße 4, D-17487 Greifswald, Germany. carola.schulzke@uni-greifswald.de.
authors.forename: Carola
authors.initials: C
authors.lastname: Schulzke
authors.affiliation: National Institute of Science Education and Research, Bhimpur-Padanpur, Jatni, Khurda, Bhubaneswar-752050, Odisha, India and Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, India. vc@iitk.ac.in.
authors.forename: Vadapalli
authors.initials: V
authors.lastname: Chandrasekhar
authors.affiliation: Tata Institute of Fundamental Research, Centre for Interdisciplinary Sciences 21, Brundavan Colony, Narsingi, Hyderabad-500075, India. ajana@tifrh.res.in.
authors.forename: Anukul
authors.initials: A
authors.lastname: Jana