title: Molecular engineering for efficient and selective iron porphyrin catalysts for electrochemical reduction of CO2to CO.
abstract: Iron porphyrins Fe-pE, Fe-mE, and Fe-oE were synthesized and their electrochemical behavior for CO2reduction to CO has been investigated. The controlled potential electrolysis of Fe-mE gave exclusive 65% Faradaic efficiency (FE) whereas Fe-oE achieved quasi-quantitative 98% FE (2% H2) for CO production.
authors.affiliation: Department of Chemistry, KTH Royal Institute of Technology, 10044 Stockholm, Sweden. leleduan@kth.se lichengs@kth.se.
authors.forename: Ram B
authors.initials: RB
authors.lastname: Ambre
authors.affiliation: Department of Chemistry, KTH Royal Institute of Technology, 10044 Stockholm, Sweden. leleduan@kth.se lichengs@kth.se.
authors.forename: Quentin
authors.initials: Q
authors.lastname: Daniel
authors.affiliation: Division of Theoretical Chemistry & Biology, School of Biotechnology, KTH Royal Institute of Technology, 10691 Stockholm, Sweden.
authors.forename: Ting
authors.initials: T
authors.lastname: Fan
authors.affiliation: Department of Chemistry, KTH Royal Institute of Technology, 10044 Stockholm, Sweden. leleduan@kth.se lichengs@kth.se.
authors.forename: Hong
authors.initials: H
authors.lastname: Chen
authors.affiliation: Department of Chemistry, KTH Royal Institute of Technology, 10044 Stockholm, Sweden. leleduan@kth.se lichengs@kth.se.
authors.forename: Biaobiao
authors.identifier: http://orcid.org/0000-0002-4093-1251
authors.initials: B
authors.lastname: Zhang
authors.affiliation: Department of Chemistry, KTH Royal Institute of Technology, 10044 Stockholm, Sweden. leleduan@kth.se lichengs@kth.se.
authors.forename: Lei
authors.initials: L
authors.lastname: Wang
authors.affiliation: Division of Theoretical Chemistry & Biology, School of Biotechnology, KTH Royal Institute of Technology, 10691 Stockholm, Sweden.
authors.forename: Mårten S G
authors.initials: MS
authors.lastname: Ahlquist
authors.affiliation: Department of Chemistry, KTH Royal Institute of Technology, 10044 Stockholm, Sweden. leleduan@kth.se lichengs@kth.se.
authors.forename: Lele
authors.initials: L
authors.lastname: Duan
authors.affiliation: Department of Chemistry, KTH Royal Institute of Technology, 10044 Stockholm, Sweden. leleduan@kth.se lichengs@kth.se and State Key Laboratory of Fine Chemicals, DUT-KTH Joint Education and Research Center on Molecular Devices, Dalian University of Technology (DUT), Dalian 116012, P. R. China.
authors.forename: Licheng
authors.initials: L
authors.lastname: Sun