title: One-pot conversion reactions of glycosyl boranophosphates into glycosyl phosphate derivatives via acyl phosphite intermediates.
abstract: A one-pot synthesis of glycosyl phosphates and their P-modified analogs from glycosyl boranophosphates under mild basic conditions has been conducted.31P NMR monitoring of the reaction mixture revealed that the key intermediates of these reactions were acyl phosphites, which could not be formed from the corresponding H-phosphonate diesters.
authors.affiliation: Department of Medical Genome Sciences, Graduate School of Frontier Sciences, The University of Tokyo, Bioscience Building 702, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8562, Japan.
authors.forename: Kazuki
authors.initials: K
authors.lastname: Sato
authors.affiliation: Department of Medicinal and Life Science, Faculty of Pharmaceutical Sciences, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510, Japan. twada@rs.tus.ac.jp.
authors.forename: Takeshi
authors.initials: T
authors.lastname: Wada
mesh_terms: D001880:Boranes / Q000737:chemistry*; D006031:Glycosylation; D010710:Phosphates / Q000737:chemistry*; D017905:Phosphites / Q000737:chemistry*
chemical_list: D001880:Boranes; D010710:Phosphates; D017905:Phosphites; C510710:boranophosphate