title: Transfer-printing of active layers to achieve high quality interfaces in sequentially deposited multilayer inverted polymer solar cells fabricated in air.
abstract: Polymer solar cells (PSCs) are greatly influenced by both the vertical concentration gradient in the active layer and the quality of the various interfaces. To achieve vertical concentration gradients in inverted PSCs, a sequential deposition approach is necessary. However, a direct approach to sequential deposition by spin-coating results in partial dissolution of the underlying layers which decreases the control over the process and results in not well-defined interfaces. Here, we demonstrate that by using a transfer-printing process based on polydimethylsiloxane (PDMS) stamps we can obtain increased control over the thickness of the various layers while at the same time increasing the quality of the interfaces and the overall concentration gradient within the active layer of PSCs prepared in air. To optimize the process and understand the influence of various interlayers, our approach is based on surface free energy, spreading parameters and work of adhesion calculations. The key parameter presented here is the insertion of high quality hole transporting and electron transporting layers, respectively above and underneath the active layer of the inverted structure PSC which not only facilitates the transfer process but also induces the adequate vertical concentration gradient in the device to facilitate charge extraction. The resulting non-encapsulated devices (active layer prepared in air) demonstrate over 40% increase in power conversion efficiency with respect to the reference spin-coated inverted PSCs.
authors.affiliation: Department of Engineering Science, University of Electro-Communications , Chofu , Japan.
authors.forename: Varun
authors.initials: V
authors.lastname: Vohra
authors.affiliation: Department of Engineering Science, University of Electro-Communications , Chofu , Japan.
authors.forename: Takuya
authors.initials: T
authors.lastname: Anzai
authors.affiliation: Department of Engineering Science, University of Electro-Communications , Chofu , Japan.
authors.forename: Shusei
authors.initials: S
authors.lastname: Inaba
authors.affiliation: Istituto per lo Studio delle Macromolecole, CNR-ISMAC , Milano , Italy.
authors.forename: William
authors.initials: W
authors.lastname: Porzio
authors.affiliation: Istituto di Cristallografia-Sincrotrone Elettra , Basovizza , Italy.
authors.forename: Luisa
authors.initials: L
authors.lastname: Barba
keywords: 209 Solar cell / Photovoltaics; 50 Energy Materials; P3HT; PDMS; Polymer solar cell; organic electronics; transfer