title: Monitoring and distribution patterns of pesticide residues in soil from cotton/wheat fields of Pakistan.
abstract: The excessive use of hazardous pesticides for massive cotton and wheat production has deteriorated the quality of Okara district's soil. Thus, in order to sustain the production of good-quality food, it is essential to determine the residue levels of pesticides in the agricultural soil and define their possible sources. Thus, the present study focused on the determination of selected pesticides in the soil samples obtained from cotton/wheat fields by using the modified multi-residue pesticide analysis method based on GCMS and HPLC-UV. Most of soil samples were found to be highly contaminated with imidacloprid, chlorpyrifos, and α-cypermethrin residues. Selected pesticides were significantly correlated with each other at p < 0.05 except imidacloprid, which was negatively correlated with triazophos, MCPA methyl ester, selected pyrethroid pesticides, and their metabolite. Soil pH and phosphate levels were significantly positively correlated while sulfate content was negatively correlated with most of selected pesticides. The varimax normalized factor analysis divides the selected pesticides to the two major factors that explained 87.19% of the total variance which evidenced that pesticide in the same cluster shared a common source in the soil. A significant negative correlation of chlorpyrifos in the second factor pointed towards a source different from other pesticides. Factor and cluster analysis indicated that sulfate levels of soil positively affected the persistence/ mobility of imidacloprid.
authors.affiliation: Department of Chemistry, Lahore College for Women University, Lahore, Pakistan. naziarafiqchem@gmail.com.
authors.forename: Nazia
authors.initials: N
authors.lastname: Rafique
authors.affiliation: Department of Chemistry, Lahore College for Women University, Lahore, Pakistan.
authors.forename: Saadia R
authors.initials: SR
authors.lastname: Tariq
authors.affiliation: Department of Chemistry, Forman Christian College-A Chartered University, Lahore, Pakistan.
authors.forename: Dildar
authors.initials: D
authors.lastname: Ahmed
mesh_terms: D000383:Agriculture; D004784:Environmental Monitoring; D003368:Gossypium / Q000254:growth & development; D010154:Pakistan; D010573:Pesticide Residues / Q000032:analysis*; D012989:Soil Pollutants / Q000032:analysis*; D014908:Triticum / Q000254:growth & development
chemical_list: D010573:Pesticide Residues; D012989:Soil Pollutants
keywords: Cluster analysis; Cotton/wheat field’s soil; Factor analysis; GCMS; Pesticide residues