title: Experimental and Theoretical Studies of the Spectroscopic Properties of Chalcone Derivatives.
abstract: Newly synthesized, differently substituted chalcones (1,3-diaryl-2-propen-1-ones) have been studied using steady-state and time-resolved techniques combined with quantum-chemical modelling. To explore spectroscopic structure - property relationships the substituent (acceptor moiety) was chosen according to systematic variation in the Hammett parameter. It was shown that photophysical properties of the studied donor-acceptor (D-A) molecules can be predicted in terms of a simple model from the properties of individual chromophores (composite-model of decoupled moieties: donor (D) and acceptor (A)). The results of spectroscopic measurements also indicate that for investigated D-A fluorophores in medium-polar solvent, the initially populated, locally excited (LE) state (where the fundamental role plays donor moiety (D*-A)) reacts further to produce intramolecular charge transfer (ICT) state. Additionally, the experimental absorption (Mge) and fluorescence (Meg) transition dipole moments were calculated on the basis of spectroscopic data and compared with results of our quantum-chemical calculations. The absorption transition dipole moment was found to vary linearly with the Hammett substituent coefficient (σ).
authors.affiliation: Faculty of Chemical Technology and Engineering, UTP University of Science and Technology, ul. Seminaryjna 3, 85-326, Bydgoszcz, Poland.
authors.forename: Marek
authors.initials: M
authors.lastname: Pietrzak
authors.affiliation: Institute of Experimental Physics, University of Gdańsk, ul. Wita Stwosza 57, 80-952, Gdańsk, Poland. fizmj@univ.gda.pl.
authors.forename: Marek
authors.identifier: http://orcid.org/0000-0002-0607-986X
authors.initials: M
authors.lastname: Józefowicz
authors.affiliation: Faculty of Chemical Technology and Engineering, UTP University of Science and Technology, ul. Seminaryjna 3, 85-326, Bydgoszcz, Poland.
authors.forename: Agnieszka
authors.initials: A
authors.lastname: Bajorek
authors.affiliation: Institute of Experimental Physics, University of Gdańsk, ul. Wita Stwosza 57, 80-952, Gdańsk, Poland.
authors.forename: Janina R
authors.initials: JR
authors.lastname: Heldt
keywords: Chalcones, Azachalcones; Donor–acceptor system; Intramolecular charge transfer