title: Chemical kinetic model uncertainty minimization through laminar flame speed measurements.
abstract: Laminar flame speed measurements were carried for mixture of air with eight C3-4hydrocarbons (propene, propane, 1,3-butadiene, 1-butene, 2-butene,iso-butene,n-butane, andiso-butane) at the room temperature and ambient pressure. Along with C1-2hydrocarbon data reported in a recent study, the entire dataset was used to demonstrate how laminar flame speed data can be utilized to explore and minimize the uncertainties in a reaction model for foundation fuels. The USC Mech II kinetic model was chosen as a case study. The method of uncertainty minimization using polynomial chaos expansions (MUM-PCE) (D.A. Sheen and H. Wang, Combust. Flame 2011, 158, 2358-2374) was employed to constrain the model uncertainty for laminar flame speed predictions. Results demonstrate that a reaction model constrained only by the laminar flame speed values of methane/air flames notably reduces the uncertainty in the predictions of the laminar flame speeds of C3and C4alkanes, because the key chemical pathways of all of these flames are similar to each other. The uncertainty in model predictions for flames of unsaturated C3-4hydrocarbons remain significant without considering fuel specific laminar flames speeds in the constraining target data set, because the secondary rate controlling reaction steps are different from those in the saturated alkanes. It is shown that the constraints provided by the laminar flame speeds of the foundation fuels could reduce notably the uncertainties in the predictions of laminar flame speeds of C4alcohol/air mixtures. Furthermore, it is demonstrated that an accurate prediction of the laminar flame speed of a particular C4alcohol/air mixture is better achieved through measurements for key molecular intermediates formed during the pyrolysis and oxidation of the parent fuel.
authors.affiliation: Department of Aerospace and Mechanical Engineering, University of Southern California, Los Angeles, CA 90089-1453, USA.
authors.forename: Okjoo
authors.initials: O
authors.lastname: Park
authors.affiliation: Exponent, Los Angeles, CA 90066, USA.
authors.forename: Peter S
authors.initials: PS
authors.lastname: Veloo
authors.affiliation: Chemical Sciences Division, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA.
authors.forename: David A
authors.initials: DA
authors.lastname: Sheen
authors.affiliation: Department of Mechanical Engineering, Stanford University, Stanford, CA 94305-3032, USA.
authors.forename: Yujie
authors.initials: Y
authors.lastname: Tao
authors.affiliation: Department of Aerospace and Mechanical Engineering, University of Southern California, Los Angeles, CA 90089-1453, USA.
authors.forename: Fokion N
authors.initials: FN
authors.lastname: Egolfopoulos
authors.affiliation: Department of Mechanical Engineering, Stanford University, Stanford, CA 94305-3032, USA.
authors.forename: Hai
authors.initials: H
authors.lastname: Wang
keywords: Laminar flame speeds; alkanes; alkenes; chemical model development; kinetics; uncertainty quantification