title: Nucleophilic Transfer Reactions of the [Si(C2F5)3]-Moiety.
abstract: The tris(pentafluoroethyl)silanide anion is accessible by the deprotonation of Si(C2F5)3H at low temperatures. Subsequent quenching of the resulting salt-like compounds with suitable electrophiles, such as transition-metal complexes or Group 14 element halides, leads to a plethora of novel tris(pentafluoroethyl)silane derivatives. This underlines the versatility of Li[Si(C2F5)3] as a powerful nucleophilic transfer reagent.
authors.affiliation: Universität Bielefeld, Fakultät für Chemie, Centrum für Molekulare Materialien, Universitätsstrasse 25, 33615, Bielefeld, Germany.
authors.forename: Nico
authors.initials: N
authors.lastname: Schwarze
authors.affiliation: Universität Bielefeld, Fakultät für Chemie, Centrum für Molekulare Materialien, Universitätsstrasse 25, 33615, Bielefeld, Germany.
authors.forename: Simon
authors.initials: S
authors.lastname: Steinhauer
authors.affiliation: Universität Bielefeld, Fakultät für Chemie, Centrum für Molekulare Materialien, Universitätsstrasse 25, 33615, Bielefeld, Germany.
authors.forename: Beate
authors.initials: B
authors.lastname: Neumann
authors.affiliation: Universität Bielefeld, Fakultät für Chemie, Centrum für Molekulare Materialien, Universitätsstrasse 25, 33615, Bielefeld, Germany.
authors.forename: Hans-Georg
authors.initials: HG
authors.lastname: Stammler
authors.affiliation: Universität Bielefeld, Fakultät für Chemie, Centrum für Molekulare Materialien, Universitätsstrasse 25, 33615, Bielefeld, Germany.
authors.forename: Berthold
authors.initials: B
authors.lastname: Hoge
keywords: fluorine; nucleophilic transfer reactions; perfluoroalkyl compounds; silanides; silicon