title: Synthesis, crystal structure and magnetic properties of a cyanide-bridged heterometallic {CoIIMnIII} chain.
abstract: The assembly reaction between the low-spin [CoII(dmphen)(CN)3]-metalloligand and the [MnIII(salen)(H2O)]+complex cation yielded the one-dimensional compound {[MnIII(salen)(μ-NC)2CoII(dmphen)(CN)]·2H2O}n(1), which behaves as a ferrimagnetic chain, the intrachain magnetic coupling being J = -1.71(1) cm-1.
authors.affiliation: Department of Inorganic Chemistry, Physical Chemistry and Electrochemistry, Faculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest, 1-7 Gh. Polizu Street, 01106, Bucharest, Romania. alexandru.gabriela@gmail.com.
authors.forename: Maria-Gabriela
authors.initials: MG
authors.lastname: Alexandru
authors.affiliation: Coordination and Supramolecular Chemistry Laboratory, "Ilie Murgulescu" Institute of Physical Chemistry, Romanian Academy, Splaiul Independentei 202, Bucharest-060021, Romania.
authors.forename: Diana
authors.initials: D
authors.lastname: Visinescu
authors.affiliation: "Petru Poni" Institute of Macromolecular Chemistry of the Romanian Academy, Aleea Grigore Ghica Vodă 41-A, RO-700487 Iasi, Romania.
authors.forename: Sergiu
authors.initials: S
authors.lastname: Shova
authors.affiliation: Departament de Química Inorgànica/Instituto de Ciencia Molecular, Facultat de Química de la Universitat de València, C/Catedrático José Beltrán 2, 46980 Paterna, València, Spain. miguel.julve@uv.es.
authors.forename: Francesc
authors.initials: F
authors.lastname: Lloret
authors.affiliation: Departament de Química Inorgànica/Instituto de Ciencia Molecular, Facultat de Química de la Universitat de València, C/Catedrático José Beltrán 2, 46980 Paterna, València, Spain. miguel.julve@uv.es.
authors.forename: Miguel
authors.initials: M
authors.lastname: Julve