title: Interface Play between Perovskite and Hole Selective Layer on the Performance and Stability of Perovskite Solar Cells.
abstract: Perovskite solar cells with variety of hole selective contacts such as 2,2',7,7'-tetrakis(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (Spiro-OMeTAD), poly(3-hexylthiophene-2,5-diyl), poly[bis(4-phenyl)(2,5,6-trimentlyphenyl)amine], 5,10,15-trihexyl-3,8,13-tris(4-methoxyphenyl)-10,15-dihydro-5H-diindolo[3,2-a:3',2'-c]carbazole (HMPDI), and 2',7'-bis(bis(4-methoxyphenyl)amino)spiro[cyclopenta[2,1-b:3,4-b']dithiophene-4,9'-fluorene] were employed to elucidate its role at the interface of perovskite and metallic cathode. Microscopy images revealed Spiro-OMeTAD and HMPDI produce smoother and intimate contact between perovskite/hole transporting materials (HTM) interfaces among others evaluated here. This morphological feature appears to be connected with three fundamental facts: (1) hole injection to the HTM is much more efficient as evidenced by photoluminescence measurements, (2) recombination losses are less important as evidenced by intensity-modulated photovoltage spectroscopy and impedance spectroscopy measurements, and (3) fabricated solar cells are much more robust against degradation by moisture. Devices with higher open-circuit photovoltages are characterized by higher values of the recombination resistance extracted from the impedance data. The variation in device hysteresis behavior can be ascribed mainly due to the molecular interaction and the core of HTM employed. In all cases, this fact is related with a larger value of the low-frequency capacitance, which indicates that the HTM can induce specific slow processes of ion accumulation at the interface. Notably, these processes tend to slowly relax in time, as hysteresis is substantially reduced for aged devices.
authors.affiliation: Abengoa Research, Abengoa, Campus Palmas Altas , C/Energı́a Solar no 1, 41014 Sevilla, Spain.
authors.forename: Manuel
authors.initials: M
authors.lastname: Salado
authors.affiliation: Department of Physical, Chemical and Natural Systems, Universidad Pablo de Olavide , Sevilla 41013, Spain.
authors.forename: Jesus
authors.initials: J
authors.lastname: Idigoras
authors.affiliation: Abengoa Research, Abengoa, Campus Palmas Altas , C/Energı́a Solar no 1, 41014 Sevilla, Spain.
authors.forename: Laura
authors.initials: L
authors.lastname: Calio
authors.affiliation: Abengoa Research, Abengoa, Campus Palmas Altas , C/Energı́a Solar no 1, 41014 Sevilla, Spain.
authors.forename: Samrana
authors.initials: S
authors.lastname: Kazim
authors.affiliation: Group for Molecular Engineering of Functional Materials, Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne , CH-1951 Sion, Switzerland.
authors.forename: Mohammad Khaja
authors.identifier: http://orcid.org/0000-0001-5955-4786
authors.initials: MK
authors.lastname: Nazeeruddin
authors.affiliation: Department of Physical, Chemical and Natural Systems, Universidad Pablo de Olavide , Sevilla 41013, Spain.
authors.forename: Juan A
authors.initials: JA
authors.lastname: Anta
authors.affiliation: Abengoa Research, Abengoa, Campus Palmas Altas , C/Energı́a Solar no 1, 41014 Sevilla, Spain.
authors.forename: Shahzada
authors.identifier: http://orcid.org/0000-0002-1218-2556
authors.initials: S
authors.lastname: Ahmad
keywords: electrochemical impedance spectroscopy; hole transport materials; interface; perovskite solar cells; small perturbation techniques