title: Highly efficient hydrolysis of ammonia borane by anion (-OH, F-, Cl-)-tuned interactions between reactant molecules and CoP nanoparticles.
abstract: The CoP nanoparticle catalyst had excellent catalytic activity and a short catalytic induction period in the presence of anions, and high sustainability in ammonia borane hydrolysis, with an initial turnover frequency of 72.2 mol(H2)mol(CoP)-1min-1at ambient temperature. This value is unprecedented for noble-metal-free catalytic systems.
authors.affiliation: Key Laboratory of Photochemical Conversion and Optoelectronic Materials and HKU-CAS Joint Laboratory on New Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China. fuwf@mail.ipc.ac.cn.
authors.forename: Zi-Cheng
authors.initials: ZC
authors.lastname: Fu
authors.affiliation: Key Laboratory of Photochemical Conversion and Optoelectronic Materials and HKU-CAS Joint Laboratory on New Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China. fuwf@mail.ipc.ac.cn.
authors.forename: Yong
authors.initials: Y
authors.lastname: Xu
authors.affiliation: Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hung Hom, Hong Kong, P. R. China.
authors.forename: Sharon Lai-Fung
authors.initials: SL
authors.lastname: Chan
authors.affiliation: College of Chemistry and Engineering, Yunnan Normal University, Kunming 650092, P. R. China.
authors.forename: Wei-Wei
authors.initials: WW
authors.lastname: Wang
authors.affiliation: Key Laboratory of Photochemical Conversion and Optoelectronic Materials and HKU-CAS Joint Laboratory on New Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China. fuwf@mail.ipc.ac.cn.
authors.forename: Fang
authors.initials: F
authors.lastname: Li
authors.affiliation: Key Laboratory of Photochemical Conversion and Optoelectronic Materials and HKU-CAS Joint Laboratory on New Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China. fuwf@mail.ipc.ac.cn.
authors.forename: Fei
authors.initials: F
authors.lastname: Liang
authors.affiliation: Key Laboratory of Photochemical Conversion and Optoelectronic Materials and HKU-CAS Joint Laboratory on New Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China. fuwf@mail.ipc.ac.cn.
authors.forename: Yong
authors.initials: Y
authors.lastname: Chen
authors.affiliation: Key Laboratory of Photochemical Conversion and Optoelectronic Materials and HKU-CAS Joint Laboratory on New Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China. fuwf@mail.ipc.ac.cn.
authors.forename: Zhe-Shuai
authors.initials: ZS
authors.lastname: Lin
authors.affiliation: Key Laboratory of Photochemical Conversion and Optoelectronic Materials and HKU-CAS Joint Laboratory on New Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China. fuwf@mail.ipc.ac.cn and College of Chemistry and Engineering, Yunnan Normal University, Kunming 650092, P. R. China.
authors.forename: Wen-Fu
authors.initials: WF
authors.lastname: Fu
authors.affiliation: Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China.
authors.forename: Chi-Ming
authors.initials: CM
authors.lastname: Che