title: A platinum(ii)-palladium(ii)-nickel(ii) heterotrimetallic coordination polymer showing a cooperative effect on catalytic hydrogen evolution.
abstract: Stepwise construction of a 1D heterotrimetallic coordination polymer containing all three group 10 metal ions via an ammineplatinum(ii) metalloligand with d-penicillamine is reported. This system showed a significant enhancement in heterogeneous catalytic activity for electrochemical hydrogen evolution by the stepwise introduction of PdIIand NiIIinto the PtIImetalloligand.
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. konno@chem.sci.osaka-u.ac.jp.
authors.forename: Naoto
authors.initials: N
authors.lastname: Kuwamura
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. konno@chem.sci.osaka-u.ac.jp.
authors.forename: Yoshinari
authors.initials: Y
authors.lastname: Kurioka
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. konno@chem.sci.osaka-u.ac.jp.
authors.forename: Takumi
authors.identifier: http://orcid.org/0000-0003-4612-5418
authors.initials: T
authors.lastname: Konno