title: Rh-Mediated Enantioselective Synthesis, Crystal Structures, and Photophysical/Chiroptical Properties of Phenanthrenol-Based [9]Helicene-like Molecules.
abstract: The enantioselective synthesis of phenanthrenol-based [9]helicene-like molecules has been achieved via the rhodium-mediated intramolecular [2 + 2 + 2] cycloadditions of 3-phenanthrenol-linked triynes. Crystal structures and photophysical/chiroptical properties of these [9]helicene-like molecules were compared with the corresponding [7]helicene-like molecules.
authors.forename: Ryota
authors.initials: R
authors.lastname: Yamano
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology , Koganei, Tokyo 184-8588, Japan.
authors.forename: Jun
authors.initials: J
authors.lastname: Hara
authors.forename: Koichi
authors.initials: K
authors.lastname: Murayama
authors.forename: Haruki
authors.initials: H
authors.lastname: Sugiyama
authors.forename: Kota
authors.initials: K
authors.lastname: Teraoka
authors.forename: Hidehiro
authors.initials: H
authors.lastname: Uekusa
authors.forename: Susumu
authors.initials: S
authors.lastname: Kawauchi
authors.forename: Yu
authors.initials: Y
authors.lastname: Shibata
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology , Koganei, Tokyo 184-8588, Japan.
authors.forename: Ken
authors.identifier: 0000-0003-0534-7559
authors.initials: K
authors.lastname: Tanaka