title: A Cyanide-Bridged Magnetically Switchable Cage with Encapsulated Water Molecules.
abstract: A cage complex, H2O@[Co5Fe4], was found to encapsulate two water molecules during its self-assembly. The complex exhibited remarkable multifunctionality, combining magnetic switching from the thermal electron-transfer-coupled spin transition of the cage host and dipolar reorientational motion of the confined water, as evidenced by permittivity measurements, density functional theory calculations, and solid-state2H NMR spectra.
authors.affiliation: Graduate School of Pure and Applied Sciences, University of Tsukuba , Tsukuba 305-8571, Japan.
authors.forename: Rong-Jia
authors.initials: RJ
authors.lastname: Wei
authors.affiliation: Graduate School of Pure and Applied Sciences, University of Tsukuba , Tsukuba 305-8571, Japan.
authors.forename: Takuya
authors.initials: T
authors.lastname: Shiga
authors.affiliation: School of Chemistry, The University of Nottingham , University Park, Nottingham NG7 2RD, U.K.
authors.forename: Graham N
authors.initials: GN
authors.lastname: Newton
authors.affiliation: School of Chemistry, The University of Nottingham , University Park, Nottingham NG7 2RD, U.K.
authors.forename: David
authors.initials: D
authors.lastname: Robinson
authors.affiliation: Department of Chemistry, Faculty of Science, Hokkaido University , Kita 10, Nishi 8, Sapporo 060-0810, Japan.
authors.forename: Sadamu
authors.initials: S
authors.lastname: Takeda
authors.affiliation: Graduate School of Pure and Applied Sciences, University of Tsukuba , Tsukuba 305-8571, Japan.
authors.forename: Hiroki
authors.initials: H
authors.lastname: Oshio