title: Metal- and base-free reductive coupling reaction of P(O)-H with aryl/alkyl sulfonyl chlorides: a novel protocol for the construction of P-S-C bonds.
abstract: Novel and efficient synthesis of S-aryl/alkyl phosphinothioates from P(O)-H and aryl/alkyl sulfonyl chlorides under metal- and base-free conditions is described. This reaction provides an alternative strategy for the construction of P-S-C bonds in moderate to excellent yields. Moreover, this method can be readily applied to gram-scale preparation.
authors.affiliation: School of Chemical and Environmental Engineering, Shanghai Institute of Technology, 100 Hai-Quan Road, Shanghai 201418, China. xhzhang@sit.edu.cn lilianglcx@sit.edu.cn.
authors.forename: Dungai
authors.initials: D
authors.lastname: Wang
authors.affiliation: School of Chemical and Environmental Engineering, Shanghai Institute of Technology, 100 Hai-Quan Road, Shanghai 201418, China. xhzhang@sit.edu.cn lilianglcx@sit.edu.cn.
authors.forename: Jinlong
authors.initials: J
authors.lastname: Zhao
authors.affiliation: School of Chemical and Environmental Engineering, Shanghai Institute of Technology, 100 Hai-Quan Road, Shanghai 201418, China. xhzhang@sit.edu.cn lilianglcx@sit.edu.cn.
authors.forename: Weigang
authors.initials: W
authors.lastname: Xu
authors.affiliation: School of Chemical and Environmental Engineering, Shanghai Institute of Technology, 100 Hai-Quan Road, Shanghai 201418, China. xhzhang@sit.edu.cn lilianglcx@sit.edu.cn.
authors.forename: Changwei
authors.initials: C
authors.lastname: Shao
authors.affiliation: School of Chemical and Environmental Engineering, Shanghai Institute of Technology, 100 Hai-Quan Road, Shanghai 201418, China. xhzhang@sit.edu.cn lilianglcx@sit.edu.cn.
authors.forename: Zheng
authors.initials: Z
authors.lastname: Shi
authors.affiliation: School of Chemical and Environmental Engineering, Shanghai Institute of Technology, 100 Hai-Quan Road, Shanghai 201418, China. xhzhang@sit.edu.cn lilianglcx@sit.edu.cn.
authors.forename: Liang
authors.initials: L
authors.lastname: Li
authors.affiliation: School of Chemical and Environmental Engineering, Shanghai Institute of Technology, 100 Hai-Quan Road, Shanghai 201418, China. xhzhang@sit.edu.cn lilianglcx@sit.edu.cn.
authors.forename: Xinghua
authors.initials: X
authors.lastname: Zhang