title: A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol.
abstract: For the first time, structurally defined manganese pincer complexes catalyze the dehydrogenation of aqueous methanol to hydrogen and carbon dioxide, which is a transformation of interest with regard to the implementation of a hydrogen and methanol economy. Excellent long-term stability was demonstrated for the Mn-PNPiPr catalyst, as a turnover of more than 20 000 was reached. In addition to methanol, other important hydrogen carriers were also successfully dehydrogenated.
authors.affiliation: Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Straße 29a, 18059, Rostock, Germany.
authors.forename: María
authors.initials: M
authors.lastname: Andérez-Fernández
authors.affiliation: Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Straße 29a, 18059, Rostock, Germany.
authors.forename: Lydia K
authors.initials: LK
authors.lastname: Vogt
authors.affiliation: Institut für Chemie, Universität Rostock, Dr. Lorenz-Weg 1, 18059, Rostock, Germany.
authors.forename: Steffen
authors.initials: S
authors.lastname: Fischer
authors.affiliation: Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Straße 29a, 18059, Rostock, Germany.
authors.forename: Wei
authors.initials: W
authors.lastname: Zhou
authors.affiliation: Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Straße 29a, 18059, Rostock, Germany.
authors.forename: Haijun
authors.initials: H
authors.lastname: Jiao
authors.affiliation: Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Straße 29a, 18059, Rostock, Germany.
authors.forename: Marcel
authors.initials: M
authors.lastname: Garbe
authors.affiliation: Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Straße 29a, 18059, Rostock, Germany.
authors.forename: Saravanakumar
authors.initials: S
authors.lastname: Elangovan
authors.affiliation: Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Straße 29a, 18059, Rostock, Germany.
authors.forename: Kathrin
authors.initials: K
authors.lastname: Junge
authors.affiliation: Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Straße 29a, 18059, Rostock, Germany.
authors.forename: Henrik
authors.initials: H
authors.lastname: Junge
authors.affiliation: Institut für Chemie, Universität Rostock, Dr. Lorenz-Weg 1, 18059, Rostock, Germany.
authors.forename: Ralf
authors.initials: R
authors.lastname: Ludwig
authors.affiliation: Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Straße 29a, 18059, Rostock, Germany.
authors.forename: Matthias
authors.identifier: 0000-0001-5709-0965
authors.initials: M
authors.lastname: Beller
keywords: dehydrogenation; homogeneous catalysis; ligand design; manganese; methanol