title: Free-Radical Carbocyanation of Cyclopropenes: Stereocontrolled Access to All-Carbon Quaternary Stereocenters in Acyclic Systems.
abstract: Free-radical carbocyanation of cyclopropenes offers straightforward access to tetrasubstituted cyclopropanes in satisfying yields with moderate diastereoselectivity. The incorporation of various functional groups on the cyclopropane ring allows a subsequent base-mediated ring-opening reaction leading to functionalized acyclic systems having an all-carbon quaternary stereocenter.
authors.affiliation: University of Bordeaux , Institute of Molecular Sciences, UMR-CNRS 5255, 351 cours de la libération, 33405 Talence, France.
authors.forename: Nitin S
authors.initials: NS
authors.lastname: Dange
authors.affiliation: University of Bordeaux , Institute of Molecular Sciences, UMR-CNRS 5255, 351 cours de la libération, 33405 Talence, France.
authors.forename: Frédéric
authors.initials: F
authors.lastname: Robert
authors.affiliation: University of Bordeaux , Institute of Molecular Sciences, UMR-CNRS 5255, 351 cours de la libération, 33405 Talence, France.
authors.forename: Yannick
authors.initials: Y
authors.lastname: Landais