title: Metal-Free Cascade Oxidative Decarbonylative Alkylation/Arylation of Alkynoates with Alphatic Aldehydes.
abstract: The oxidative difunctionalization of aryl alkynoates with alphatic aldehydes as a cheap and abundant alkyl radical source was developed, providing a variety of trisubstituted alkenes in moderate to good yields. In this reaction, radical decarbonylative alkylation of C-C triple bond, 1,4-aryl migration, and decarboxylation were involved under metal-free conditions.
authors.affiliation: School of Chemistry and Environmental Engineering, Jiangsu University of Technology , Changzhou 213001, P. R. China.|School of Petrochemical Engineering, Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, Changzhou University , Changzhou 213164, P. R. China.
authors.forename: Changduo
authors.initials: C
authors.lastname: Pan
authors.affiliation: School of Chemistry and Environmental Engineering, Jiangsu University of Technology , Changzhou 213001, P. R. China.
authors.forename: Yu
authors.initials: Y
authors.lastname: Chen
authors.affiliation: School of Chemistry and Environmental Engineering, Jiangsu University of Technology , Changzhou 213001, P. R. China.
authors.forename: Shuai
authors.initials: S
authors.lastname: Song
authors.affiliation: School of Chemistry and Environmental Engineering, Jiangsu University of Technology , Changzhou 213001, P. R. China.
authors.forename: Lei
authors.initials: L
authors.lastname: Li
authors.affiliation: School of Petrochemical Engineering, Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, Changzhou University , Changzhou 213164, P. R. China.
authors.forename: Jin-Tao
authors.initials: JT
authors.lastname: Yu