title: Assessing the fugitive emission of CH4via migration along fault zones - Comparing potential shale gas basins to non-shale basins in the UK.
abstract: This study considered whether faults bounding hydrocarbon-bearing basins could be conduits for methane release to the atmosphere. Five basin bounding faults in the UK were considered: two which bounded potential shale gas basins; two faults that bounded coal basins; and one that bounded a basin with no known hydrocarbon deposits. In each basin, two mobile methane surveys were conducted, one along the surface expression of the basin bounding fault and one along a line of similar length but not intersecting the fault. All survey data was corrected for wind direction, the ambient CH4concentration and the distance to the possible source. The survey design allowed for Analysis of Variance and this showed that there was a significant difference between the fault and control survey lines though a significant flux from the fault was not found in all basins and there was no apparent link to the presence, or absence, of hydrocarbons. As such, shale basins did not have a significantly different CH4flux to non-shale hydrocarbon basins and non-hydrocarbon basins. These results could have implications for CH4emissions from faults both in the UK and globally. Including all the corrected fault data, we estimate faults have an emissions factor of 11.5±6.3tCH4/km/yr, while the most conservative estimate of the flux from faults is 0.7±0.3tCH4/km/yr. The use of isotopes meant that at least one site of thermogenic flux from a fault could be identified. However, the total length of faults that penetrate through-basins and go from the surface to hydrocarbon reservoirs at depth in the UK is not known; as such, the emissions factor could not be multiplied by an activity level to estimate a total UK CH4flux.
authors.affiliation: Department of Earth Sciences, Durham University, Science Labs, Durham DH1 3LE, UK. Electronic address: i.m.boothroyd@durham.ac.uk.
authors.forename: I M
authors.initials: IM
authors.lastname: Boothroyd
authors.affiliation: School of Civil Engineering and Geosciences, Newcastle University, Newcastle NE1 7RU, UK.
authors.forename: S
authors.initials: S
authors.lastname: Almond
authors.affiliation: Department of Earth Sciences, Durham University, Science Labs, Durham DH1 3LE, UK.
authors.forename: F
authors.initials: F
authors.lastname: Worrall
authors.affiliation: School of Civil Engineering and Geosciences, Newcastle University, Newcastle NE1 7RU, UK.
authors.forename: R J
authors.initials: RJ
authors.lastname: Davies
keywords: Greenhouse gases; Hydrocarbons; Mobile survey