title: Giant Piezoelectricity and High Curie Temperature in Nanostructured Alkali Niobate Lead-Free Piezoceramics through Phase Coexistence.
abstract: Because of growing environmental concerns, the development of lead-free piezoelectric materials with enhanced properties has become of great interest. Here, we report a giant piezoelectric coefficient (d33) of 550 pC/N and a high Curie temperature (TC) of 237 °C in (1-x-y)K1-wNawNb1-zSbzO3-xBiFeO3-yBi0.5Na0.5ZrO3(KNwNSz-xBF-yBNZ) ceramics by optimizing x, y, z, and w. Atomic-resolution polarization mapping by Z-contrast imaging reveals the intimate coexistence of rhombohedral (R) and tetragonal (T) phases inside nanodomains, that is, a structural origin for the R-T phase boundary in the present KNN system. Hence, the physical origin of high piezoelectric performance can be attributed to a nearly vanishing polarization anisotropy and thus low domain wall energy, facilitating easy polarization rotation between different states under an external field.
authors.affiliation: Department of Materials Science, Sichuan University , Chengdu 610064, People's Republic of China.|Sichuan Province Key Laboratory of Information Materials and Devices Application, Chengdu University of Information Technology , Chengdu 610225, People's Republic of China.
authors.forename: Bo
authors.initials: B
authors.lastname: Wu
authors.affiliation: Department of Materials Science and Engineering, National University of Singapore , Singapore 117575, Singapore.
authors.forename: Haijun
authors.initials: H
authors.lastname: Wu
authors.affiliation: Department of Materials Science, Sichuan University , Chengdu 610064, People's Republic of China.
authors.forename: Jiagang
authors.initials: J
authors.lastname: Wu
authors.affiliation: Department of Materials Science, Sichuan University , Chengdu 610064, People's Republic of China.
authors.forename: Dingquan
authors.initials: D
authors.lastname: Xiao
authors.affiliation: Department of Materials Science, Sichuan University , Chengdu 610064, People's Republic of China.
authors.forename: Jianguo
authors.initials: J
authors.lastname: Zhu
authors.affiliation: Department of Materials Science and Engineering, National University of Singapore , Singapore 117575, Singapore.
authors.forename: Stephen J
authors.initials: SJ
authors.lastname: Pennycook