title: Cp*Rh(III)-Catalyzed Low Temperature C-H Allylation of N-Aryl-trichloro Acetimidamide.
abstract: The readily synthesized trichloro acetimidamide was found to be an excellent directing group for the directed C-H-allylation reactions. Depending on the allylating agent used, selectively either mono- or diallylated products were readily synthesized. Moreover, the trichloro acetimidamide directing group was found to be highly efficient even at lower temperature for the C-H-allylation reaction. Due to mildness of the reaction conditions, double bond isomerization or cyclization to indole side product was not observed.
authors.affiliation: Department of Chemistry, Indian Institute of Technology Kharagpur , Kharagpur 721302, India.
authors.forename: Suvankar
authors.initials: S
authors.lastname: Debbarma
authors.affiliation: Department of Chemistry, Indian Institute of Technology Kharagpur , Kharagpur 721302, India.
authors.forename: Sourav Sekhar
authors.initials: SS
authors.lastname: Bera
authors.affiliation: Department of Chemistry, Indian Institute of Technology Kharagpur , Kharagpur 721302, India.
authors.forename: Modhu Sudan
authors.initials: MS
authors.lastname: Maji