title: Cationic [(Iminophosphine)Nickel(Allyl)]+Complexes as the First Example of Nickel Catalysts for Direct Hydroamination of Allenes.
abstract: The first example of nickel-catalyzed hydroamination of allenes is reported. The new cationic [(3-iminophosphine)nickel(allyl)]+catalysts have been fully characterized and act regioselectively in the catalytic hydroamination of allenes with secondary amines at room temperature.
authors.affiliation: Department of Chemistry and Biochemistry, School of Green Chemistry and Engineering, College of Natural Sciences and Mathematics, The University of Toledo, 2801 W. Bancroft St. MS 602, Toledo, Ohio, 43606-3390, USA.
authors.forename: Hosein
authors.initials: H
authors.lastname: Tafazolian
authors.affiliation: Department of Chemistry and Biochemistry, School of Green Chemistry and Engineering, College of Natural Sciences and Mathematics, The University of Toledo, 2801 W. Bancroft St. MS 602, Toledo, Ohio, 43606-3390, USA.
authors.forename: Joseph A R
authors.identifier: http://orcid.org/0000-0003-3019-0055
authors.initials: JA
authors.lastname: Schmidt
keywords: N,P ligands; allyl ligands; catalysis; homogeneous catalysis; organometallic chemistry