title: Remote Photoregulated Ring Gliding in a [2]Rotaxane via a Molecular Effector.
abstract: A molecular barbiturate messenger, which is reversibly released/captured by a photoswitchable artificial molecular receptor, is shown to act as an effector to control ring gliding on a distant hydrogen-bonding [2]rotaxane. Thus, light-driven chemical communication governing the operation of a remote molecular machine is demonstrated using an information-rich neutral molecule.
authors.affiliation: Institut des Sciences Moléculaires, CNRS UMR 5255, Université de Bordeaux , 33405 Talence, France.
authors.forename: Arnaud
authors.initials: A
authors.lastname: Tron
authors.affiliation: Institut des Sciences Moléculaires, CNRS UMR 5255, Université de Bordeaux , 33405 Talence, France.
authors.forename: Isabelle
authors.identifier: 0000-0002-2694-3133
authors.initials: I
authors.lastname: Pianet
authors.affiliation: Departamento de Química Orgánica, Facultad de Química, Universidad de Murcia , E-30100 Murcia, Spain.
authors.forename: Alberto
authors.initials: A
authors.lastname: Martinez-Cuezva
authors.affiliation: School of Chemistry, University of Birmingham , Edgbaston, Birmingham B15 2TT, United Kingdom.
authors.forename: James H R
authors.initials: JH
authors.lastname: Tucker
authors.affiliation: Institut des Sciences Moléculaires, CNRS UMR 5255, Université de Bordeaux , 33405 Talence, France.
authors.forename: Luca
authors.initials: L
authors.lastname: Pisciottani
authors.affiliation: Departamento de Química Orgánica, Facultad de Química, Universidad de Murcia , E-30100 Murcia, Spain.
authors.forename: Mateo
authors.initials: M
authors.lastname: Alajarin
authors.affiliation: Departamento de Química Orgánica, Facultad de Química, Universidad de Murcia , E-30100 Murcia, Spain.
authors.forename: Jose
authors.initials: J
authors.lastname: Berna
authors.affiliation: Institut des Sciences Moléculaires, CNRS UMR 5255, Université de Bordeaux , 33405 Talence, France.
authors.forename: Nathan D
authors.identifier: 0000-0003-0285-1741
authors.initials: ND
authors.lastname: McClenaghan