title: A Simple Approach to Fabricate an Efficient Inverted Polymer Solar Cell with a Novel Small Molecular Electrolyte as the Cathode Buffer Layer.
abstract: A novel small-molecule electrolyte, 1,1'-bis(4-hydroxypropyl)-[4,4'-bipyridine]-1,1'-diium bromide (V-OH), containing a mixture of PTB7:PC71BM has been designed and synthesized as a cathode buffer layer for inverted polymer solar cells (iPSCs). The molecular structure of this new compound comprises a viologen skeleton with hydroxyl group terminals. While the viologen unit is responsible for generating a favorable interface dipole, the two terminal hydroxyl groups of V-OH may generate a synergy effect in the magnitude of the interface dipole. Consequently, the devices containing the V-OH interlayer exhibited a power conversion efficiency (PCE) of 9.13% (short circuit current = 17.13 mA/cm2, open circuit voltage = 0.75 V, fill factor = 71.1%). The PCE of the devices with V-OH exhibited better long-term stability compared to that of the devices without V-OH. Thus, we found that it is possible to enhance the efficiency of PSCs by a simple approach without the need for complicated methods of device fabrication.
authors.affiliation: Department of Polymer Engineering, Pukyong National University , Busan 48547, Korea.
authors.forename: Youn Hwan
authors.initials: YH
authors.lastname: Kim
authors.affiliation: Department of Polymer Engineering, Pukyong National University , Busan 48547, Korea.
authors.forename: Nadhila
authors.initials: N
authors.lastname: Sylvianti
authors.affiliation: Department of Polymer Engineering, Pukyong National University , Busan 48547, Korea.
authors.forename: Mutia Anissa
authors.initials: MA
authors.lastname: Marsya
authors.affiliation: Department of Chemistry, Pukyong National University , Busan 48513, Korea.
authors.forename: Juyun
authors.initials: J
authors.lastname: Park
authors.affiliation: Department of Chemistry, Pukyong National University , Busan 48513, Korea.
authors.forename: Yong-Cheol
authors.initials: YC
authors.lastname: Kang
authors.affiliation: Department of Materials Chemistry and Engineering, Konkuk University , Seoul 05029, Korea.
authors.forename: Doo Kyung
authors.initials: DK
authors.lastname: Moon
authors.affiliation: Department of Polymer Engineering, Pukyong National University , Busan 48547, Korea.
authors.forename: Joo Hyun
authors.initials: JH
authors.lastname: Kim
keywords: cathode buffer layer; electrolyte; inverted polymer solar cell; viologen; work function