title: Rhodium-catalyzed C-H functionalization with N-acylsaccharins.
abstract: A rhodium-catalyzed C-H functionalization with activated amides by decarbonylation has been developed. Notably, this is the first C-H arylation employing N-acylsaccharins as coupling partners to give biaryls in good to excellent yields. The highlight of the work is the high tolerance of functional groups such as formyl, ester, and vinyl and the use of a removable directing group.
authors.affiliation: College of Chemistry and Environment, South China Normal University, Guangzhou 510006, People's Republic of China. zhuoz@scnu.edu.cn.
authors.forename: Hongxiang
authors.initials: H
authors.lastname: Wu
authors.affiliation: College of Chemistry and Environment, South China Normal University, Guangzhou 510006, People's Republic of China. zhuoz@scnu.edu.cn.
authors.forename: Tingting
authors.initials: T
authors.lastname: Liu
authors.affiliation: College of Chemistry and Environment, South China Normal University, Guangzhou 510006, People's Republic of China. zhuoz@scnu.edu.cn.
authors.forename: Ming
authors.initials: M
authors.lastname: Cui
authors.affiliation: College of Chemistry and Environment, South China Normal University, Guangzhou 510006, People's Republic of China. zhuoz@scnu.edu.cn.
authors.forename: Yue
authors.initials: Y
authors.lastname: Li
authors.affiliation: College of Chemistry and Environment, South China Normal University, Guangzhou 510006, People's Republic of China. zhuoz@scnu.edu.cn.
authors.forename: Junsheng
authors.initials: J
authors.lastname: Jian
authors.affiliation: College of Chemistry and Environment, South China Normal University, Guangzhou 510006, People's Republic of China. zhuoz@scnu.edu.cn.
authors.forename: Hui
authors.initials: H
authors.lastname: Wang
authors.affiliation: College of Chemistry and Environment, South China Normal University, Guangzhou 510006, People's Republic of China. zhuoz@scnu.edu.cn and Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry Chinese Academy of Sciences, China.
authors.forename: Zhuo
authors.identifier: http://orcid.org/0000-0003-4875-2909
authors.initials: Z
authors.lastname: Zeng
mesh_terms: D000577:Amides / Q000737:chemistry*; D002384:Catalysis; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D012238:Rhodium / Q000737:chemistry*; D012439:Saccharin / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D000577:Amides; D012238:Rhodium; D012439:Saccharin