title: Zeolite CAN and AFI-Type Zeolitic Imidazolate Frameworks with Large 12-Membered Ring Pore Openings Synthesized Using Bulky Amides as Structure-Directing Agents.
abstract: Using bulky amides as the structure-directing agents (SDAs) is an alternative synthetic strategy for the exploration of crystalline large pore (≥12-membered ring) zeolitic imidazolate frameworks (ZIFs). Specifically, by using the bulky amides, dibutylformamide (DBF) and dipropylformamide (DPF) as solvent and imidazole (Im) as a ligand, two ZIFs mimicking the CAN and AlPO-5 (AFI) zeotypes with 12-membered ring (MR) pore openings were synthesized, and denoted as CAN-[Zn(Im)2] and AFI-[Zn(Im)2], respectively. These two materials are the first known examples of Zn(Im)2polymorphs with 12-MR pores and AFI-[Zn(Im)2] has the largest pore apertures reported to date for ZIF materials. The concept that the bulky amides used were not simply acting as the solvent, but were in fact acting as SDAs or templates during the synthesis of the large pore ZIFs, was suggested by the closeness of the geometrical fit between the guest DBF and the can cages (composite building units) of the CAN-[Zn(Im)2].
authors.affiliation: College of Chemistry and Chemical Engineering, Taiyuan University of Technology , Taiyuan 030024, China.
authors.forename: Qi
authors.initials: Q
authors.lastname: Shi
authors.affiliation: MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University , Guangzhou 510275, China.
authors.forename: Wei-Jian
authors.initials: WJ
authors.lastname: Xu
authors.affiliation: MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University , Guangzhou 510275, China.
authors.forename: Rui-Kang
authors.initials: RK
authors.lastname: Huang
authors.affiliation: MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University , Guangzhou 510275, China.
authors.forename: Wei-Xiong
authors.initials: WX
authors.lastname: Zhang
authors.affiliation: MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University , Guangzhou 510275, China.
authors.forename: Yang
authors.initials: Y
authors.lastname: Li
authors.affiliation: Analytical Instrumentation Center, Institute of Coal Chemistry, Chinese Academy of Sciences , Taiyuan 030001, China.
authors.forename: Pengfei
authors.initials: P
authors.lastname: Wang
authors.affiliation: School of Science, Shenyang University of Technology , Shenyang 110870, China.
authors.forename: Fa-Nian
authors.initials: FN
authors.lastname: Shi
authors.affiliation: College of Chemistry and Chemical Engineering, Taiyuan University of Technology , Taiyuan 030024, China.
authors.forename: Libo
authors.initials: L
authors.lastname: Li
authors.affiliation: College of Chemistry and Chemical Engineering, Taiyuan University of Technology , Taiyuan 030024, China.
authors.forename: Jinping
authors.initials: J
authors.lastname: Li
authors.affiliation: College of Chemistry and Chemical Engineering, Taiyuan University of Technology , Taiyuan 030024, China.
authors.forename: Jinxiang
authors.identifier: 0000-0001-5623-3514
authors.initials: J
authors.lastname: Dong