title: ICL-Based OF-CEAS: A Sensitive Tool for Analytical Chemistry.
abstract: Optical-feedback cavity-enhanced absorption spectroscopy (OF-CEAS) using mid-infrared interband cascade lasers (ICLs) is a sensitive technique for trace gas sensing. The setup of a V-shaped optical cavity operating with a 3.29 μm cw ICL is detailed, and a quantitative characterization of the injection efficiency, locking stability, mode matching, and detection sensitivity is presented. The experimental data are supported by a model to show how optical feedback affects the laser frequency as it is scanned across several longitudinal modes of the optical cavity. The model predicts that feedback enhancement effects under strongly absorbing conditions can cause underestimations in the measured absorption, and these predictions are verified experimentally. The technique is then used in application to the detection of nitrous oxide as an exemplar of the utility of this technique for analytical gas phase spectroscopy. The analytical performance of the spectrometer, expressed as noise equivalent absorption coefficient, was estimated as 4.9 × 10-9cm-1Hz-1/2, which compares well with recently reported values.
authors.affiliation: Department of Chemistry, Physical and Theoretical Chemistry Laboratory, University of Oxford , Oxford, United Kingdom.
authors.forename: Katherine M
authors.initials: KM
authors.lastname: Manfred
authors.affiliation: Department of Chemistry, Physical and Theoretical Chemistry Laboratory, University of Oxford , Oxford, United Kingdom.
authors.forename: Katharine M
authors.initials: KM
authors.lastname: Hunter
authors.affiliation: Department of Chemistry, Physical and Theoretical Chemistry Laboratory, University of Oxford , Oxford, United Kingdom.
authors.forename: Luca
authors.identifier: 0000-0003-1545-8498
authors.initials: L
authors.lastname: Ciaffoni
authors.affiliation: Department of Chemistry, Physical and Theoretical Chemistry Laboratory, University of Oxford , Oxford, United Kingdom.
authors.forename: Grant A D
authors.initials: GA
authors.lastname: Ritchie