title: Stepwise Internal Energy Change of Protonated Methanol Clusters By Using the Inert Gas Tagging.
abstract: Structural isomer population of a hydrogen-bonded cluster generally depends on temperature. Therefore, determination of an isomer population profile in a wide temperature range is important to understand the nature of hydrogen bond networks of the cluster. To explore an isomer population profile, stepwise changes of internal vibrational energy of a protonated hydrogen-bonded cluster are performed by inert gas tagging. We observe infrared spectra of the protonated methanol pentamer with various tag species. The bare protonated methanol pentamer practically has only two possible isomer types. With the tagging, the relative population of the two isomer types changes according to the binding energy with the tag species. The observed relative population follows its theoretically predicted temperature dependence.
authors.affiliation: Department of Chemistry, Graduate School of Science, Tohoku University , Sendai 980-8578, Japan.
authors.forename: Takuto
authors.initials: T
authors.lastname: Shimamori
authors.affiliation: Institute of Atomic and Molecular Sciences, Academia Sinica , Taipei 10617, Taiwan.
authors.forename: Jer-Lai
authors.initials: JL
authors.lastname: Kuo
authors.affiliation: Department of Chemistry, Graduate School of Science, Tohoku University , Sendai 980-8578, Japan.
authors.forename: Asuka
authors.initials: A
authors.lastname: Fujii