title: Spin-crossover between high-spin (S = 5/2) and low-spin (S = 1/2) states in six-coordinate iron(iii) porphyrin complexes having two pyridine-N oxide derivatives.
abstract: In contrast to the general tendency that six coordinate iron(iii) porphyrin complexes with neutral oxygen ligands adopt a high-spin state in a wide range of temperature, some complexes with substituted pyridine N-oxides have exhibited spin-crossover from high-spin to low-spin states with decreasing temperature both in solution and in the solid state.
authors.affiliation: Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University, 1060 Nishikawatsu, Matsue 690-8504, Japan. ikeue@riko.shimane-u.ac.jp.
authors.forename: Yuki
authors.initials: Y
authors.lastname: Ide
authors.affiliation: Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University, 1060 Nishikawatsu, Matsue 690-8504, Japan. ikeue@riko.shimane-u.ac.jp.
authors.forename: Nami
authors.initials: N
authors.lastname: Murai
authors.affiliation: Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University, 1060 Nishikawatsu, Matsue 690-8504, Japan. ikeue@riko.shimane-u.ac.jp.
authors.forename: Hiroki
authors.initials: H
authors.lastname: Ishimae
authors.affiliation: Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University, 1060 Nishikawatsu, Matsue 690-8504, Japan. ikeue@riko.shimane-u.ac.jp.
authors.forename: Masaaki
authors.initials: M
authors.lastname: Suzuki
authors.affiliation: Advanced Research Support Center, Ehime University, 2-5, Bunkyo-cho, Matsuyama, 790-8577, Japan.
authors.forename: Shigeki
authors.initials: S
authors.lastname: Mori
authors.affiliation: Department of Chemistry, Faculty of Science, Toho University, Funabashi 274-8510, Japan.
authors.forename: Masashi
authors.initials: M
authors.lastname: Takahashi
authors.affiliation: Department of Chemistry, Faculty of Science, Toho University, Funabashi 274-8510, Japan.
authors.forename: Mikio
authors.initials: M
authors.lastname: Nakamura
authors.affiliation: Shimane Institute for Industrial Technology, 1 Hokuryo, Matsue, Shimane 690-0816, Japan.
authors.forename: Katsumi
authors.initials: K
authors.lastname: Yoshino
authors.affiliation: Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University, 1060 Nishikawatsu, Matsue 690-8504, Japan. ikeue@riko.shimane-u.ac.jp.
authors.forename: Takahisa
authors.initials: T
authors.lastname: Ikeue