title: Achieving the Trade-Off between Selectivity and Activity in Semihydrogenation of Alkynes by Fabrication of (Asymmetrical Pd@Ag Core)@(CeO2Shell) Nanocatalysts via Autoredox Reaction.
abstract: (Asymmetrical Pd@Ag core)@(CeO2shell) nanostructures are successfully fabricated via a clean and facile modified autoredox reaction by the preaddition of Pd seeds in the growth solution. In a subsequent catalytic test, it is found that the as-obtained bimetallic core@shell nanoparticles exhibit excellent catalytic performance in semihydrogenation of alkynes. The trade-off between selectivity and activity is well realized.
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, P. R. China.
authors.forename: Shuyan
authors.initials: S
authors.lastname: Song
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, P. R. China.
authors.forename: Kai
authors.initials: K
authors.lastname: Li
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, P. R. China.
authors.forename: Jing
authors.initials: J
authors.lastname: Pan
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, P. R. China.|Changchun Institute of Applied Chemistry, Graduate University of Chinese Academy of Sciences, Beijing, 100039, P. R. China.
authors.forename: Fan
authors.initials: F
authors.lastname: Wang
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, P. R. China.|Changchun Institute of Applied Chemistry, Graduate University of Chinese Academy of Sciences, Beijing, 100039, P. R. China.
authors.forename: Junqi
authors.initials: J
authors.lastname: Li
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, P. R. China.
authors.forename: Jing
authors.initials: J
authors.lastname: Feng
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, P. R. China.
authors.forename: Shuang
authors.initials: S
authors.lastname: Yao
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, P. R. China.
authors.forename: Xin
authors.initials: X
authors.lastname: Ge
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, P. R. China.
authors.forename: Xiao
authors.initials: X
authors.lastname: Wang
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, P. R. China.
authors.forename: Hongjie
authors.initials: H
authors.lastname: Zhang
keywords: CeO2; autoredox; bimetallic; core@shell; nanocatalysts; noble metals