title: Capacity Fade Analysis of Sulfur Cathodes in Lithium-Sulfur Batteries.
abstract: Rechargeable lithium-sulfur (Li-S) batteries are receiving ever-increasing attention due to their high theoretical energy density and inexpensive raw sulfur materials. However, their rapid capacity fade has been one of the key barriers for their further improvement. It is well accepted that the major degradation mechanisms of S-cathodes include low electrical conductivity of S and sulfides, precipitation of nonconductive Li2S2and Li2S, and poly-shuttle effects. To determine these degradation factors, a comprehensive study of sulfur cathodes with different amounts of electrolytes is presented here. A survey of the fundamentals of Li-S chemistry with respect to capacity fade is first conducted; then, the parameters obtained through electrochemical performance and characterization are used to determine the key causes of capacity fade in Li-S batteries. It is confirmed that the formation and accumulation of nonconductive Li2S2/Li2S films on sulfur cathode surfaces are the major parameters contributing to the rapid capacity fade of Li-S batteries.
authors.affiliation: Biomaterials Bioengineering and Nanotechnology Laboratory Department of Orthopaedics West Virginia University Morgantown WV 26506 USA; Department of Mechanical and Aerospace Engineering West Virginia University Morgantown WV 26506 USA.
authors.forename: Jianhua
authors.initials: J
authors.lastname: Yan
authors.affiliation: Department of Mechanical and Aerospace Engineering West Virginia University Morgantown WV 26506 USA.
authors.forename: Xingbo
authors.initials: X
authors.lastname: Liu
authors.affiliation: Biomaterials Bioengineering and Nanotechnology Laboratory Department of Orthopaedics West Virginia University Morgantown WV 26506 USA.
authors.forename: Bingyun
authors.initials: B
authors.lastname: Li
keywords: Li–S batteries; electrolytes; fundamentals; poly‐shuttle