title: Classification of the Electronic Properties of Chelating Ligands in cis-[LL'Rh(CO)2] Complexes.
abstract: By analogy to the Tolman electronic parameter, a ligand electronic parameter, referred to as L2EP, is introduced here for estimating the donating ability of chelating ligands, featuring two coordinating extremities. It is based on the average of the computed infrared stretching frequencies of CO in a series of isostructural rhodium(I)-dicarbonyl complexes, that is linearly correlated to the number x of N-heterocyclic carbene coordinating ends (x = 0, 1, or 2). The L2EP values allow the design of an unified scale for the classification of the electron donation of chelating ligands, based on an ortho-phenylene bridge substituted by two coordinating extremities, which may have a different donating character. Strengths and limitations of the L2EP scale are illustrated for a large diversity of bidentate chelating ligands with coordinating ends ranging from extremely electron-rich phosphonium yldiides to extremely electron-poor amidiniophosphonites.
authors.affiliation: CNRS, LCC (Laboratoire de Chimie de Coordination), 205, route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France.|Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France.
authors.forename: Yves
authors.initials: Y
authors.lastname: Canac
authors.affiliation: CNRS, LCC (Laboratoire de Chimie de Coordination), 205, route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France.|Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France.
authors.forename: Christine
authors.identifier: http://orcid.org/0000-0002-0008-9506
authors.initials: C
authors.lastname: Lepetit