title: Guest-induced SC-SC transformation within the first K/Cd heterodimetallic triazole complex: a luminescent sensor for high-explosives and cyano molecules.
abstract: The first K/Cd heterodimetallic complex {[Cd1.5(TTPE)1.5Cl3K(H2O)3]·3H2O}n(1b) based on triazole has been generated from {[Cd(TTPE)(HCOO)](NO3)·3DMAC·H2O}n(1) during the ion- and solvent-exchange experiment in an irreversible SC-SC transformation. Based on its luminescence properties, we have, for the first time, demonstrated that 1b is a heterodimetallic sensor for detection of high-explosives and cyano molecules.
authors.affiliation: Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 300387, China. wangying790601@163.com and Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China.
authors.forename: Ying
authors.initials: Y
authors.lastname: Wang
authors.affiliation: Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 300387, China. wangying790601@163.com.
authors.forename: Wei
authors.initials: W
authors.lastname: Jia
authors.affiliation: Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 300387, China. wangying790601@163.com.
authors.forename: Ran
authors.initials: R
authors.lastname: Chen
authors.affiliation: Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 300387, China. wangying790601@163.com.
authors.forename: Xiao-Jun
authors.initials: XJ
authors.lastname: Zhao
authors.affiliation: Tianjin Key Laboratory of Water Resources and Environment, Tianjin Normal University, Tianjin 300387, China.
authors.forename: Zhong-Liang
authors.initials: ZL
authors.lastname: Wang
mesh_terms: D002104:Cadmium / Q000737:chemistry*; D053834:Explosive Agents / Q000032:analysis* / Q000737:chemistry; D049408:Luminescent Agents / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D009570:Nitriles / Q000032:analysis* / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D011188:Potassium / Q000737:chemistry*; D014227:Triazines / Q000032:analysis / Q000737:chemistry; D014230:Triazoles / Q000737:chemistry*
chemical_list: D053834:Explosive Agents; D049408:Luminescent Agents; D009570:Nitriles; D009942:Organometallic Compounds; D014227:Triazines; D014230:Triazoles; D002104:Cadmium; D011188:Potassium; C009160:cyclonite