title: Catalytic oxidation of 1,2-DCBz over V2O5/TiO2-CNTs: effect of CNT diameter and surface functional groups.
abstract: A series of V2O5/TiO2-carbon nanotube (CNT) catalysts were prepared and tested to decompose gaseous 1,2-dichlorobenzene (1,2-DCBz). Several physicochemical methods, including nitrogen adsorption, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and H2temperature-programmed reduction (TPR) were employed to characterise their physicochemical properties. To better understand the effect of CNT properties on the reactivity of V2O5/TiO2-CNT catalysts, the 1,2-DCBz residue remaining in the off-gas and on the catalyst surface were both collected and analysed. The results indicate that the outer diameter and the surface functional groups (hydroxide radical and carboxyl) of CNTs significantly influence upon the catalytic activity of CNT-containing V2O5/TiO2catalysts: the CNT outer diameter mainly affects the aggregation of CNTs and the π-π interaction between the benzene ring and CNTs, while the introduction of -OH and -COOH groups by acid treatment can further enlarge specific surface area (SSA) and contribute to a higher average oxidation state of vanadium (Vaos) and supplemental surface chemisorbed oxygen (Oads). In addition, the enhanced mobility of lattice oxygen (Olatt)also improves the oxidation ability of the catalysts.
authors.affiliation: State Key Laboratory of Clean Energy Utilization, Institute for Thermal Power Engineering, Zhejiang University, Hangzhou, 310027, China.
authors.forename: Cuicui
authors.initials: C
authors.lastname: Du
authors.affiliation: School of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai, 200093, China. wangql1987@usst.edu.cn.
authors.forename: Qiulin
authors.initials: Q
authors.lastname: Wang
authors.affiliation: State Key Laboratory of Clean Energy Utilization, Institute for Thermal Power Engineering, Zhejiang University, Hangzhou, 310027, China.
authors.forename: Yaqi
authors.initials: Y
authors.lastname: Peng
authors.affiliation: State Key Laboratory of Clean Energy Utilization, Institute for Thermal Power Engineering, Zhejiang University, Hangzhou, 310027, China. lushy@zju.edu.cn.
authors.forename: Shengyong
authors.initials: S
authors.lastname: Lu
authors.affiliation: State Key Laboratory of Clean Energy Utilization, Institute for Thermal Power Engineering, Zhejiang University, Hangzhou, 310027, China.
authors.forename: Longjie
authors.initials: L
authors.lastname: Ji
authors.affiliation: State Key Laboratory of Clean Energy Utilization, Institute for Thermal Power Engineering, Zhejiang University, Hangzhou, 310027, China.
authors.forename: Mingjiang
authors.initials: M
authors.lastname: Ni
mesh_terms: D000327:Adsorption; D002384:Catalysis; D002396:Catechols; D002722:Chlorobenzenes; D046529:Microscopy, Electron, Transmission; D037742:Nanotubes, Carbon; D010084:Oxidation-Reduction; D056951:Photoelectron Spectroscopy; D014025:Titanium / Q000737:chemistry; D017968:Vanadium Compounds; D014961:X-Ray Diffraction
chemical_list: D002396:Catechols; D002722:Chlorobenzenes; D037742:Nanotubes, Carbon; D017968:Vanadium Compounds; C009495:titanium dioxide; C055404:3,4-dichlorocatechol; C004726:2-dichlorobenzene; C066075:vanadium pentoxide; D014025:Titanium
keywords: 1,2-dichlorobenzene; CNT diameter; CNT functional group; Carbon nanotubes; Catalytic oxidation; PCDD/Fs