title: Real-time analysis of Pd2(dba)3activation by phosphine ligands.
abstract: A combination of UV-Vis spectroscopy and electrospray ionization mass spectrometry is used for real-time monitoring of Pd2(dba)3activation with sulfonated versions of PPh3and Buchwald-type ligands. This provides insight into the effect of ligand and preparation conditions on activation and allows for establishment of rational activation protocols.
authors.affiliation: Department of Chemistry, University of Victoria, P.O. Box 3065, Victoria, BC V8W3V6, Canada. mcindoe@uvic.ca.
authors.forename: Eric
authors.initials: E
authors.lastname: Janusson
authors.affiliation: Department of Chemistry, University of Victoria, P.O. Box 3065, Victoria, BC V8W3V6, Canada. mcindoe@uvic.ca.
authors.forename: Harmen S
authors.identifier: http://orcid.org/0000-0002-5754-5998
authors.initials: HS
authors.lastname: Zijlstra
authors.affiliation: Department of Chemistry, University of Victoria, P.O. Box 3065, Victoria, BC V8W3V6, Canada. mcindoe@uvic.ca.
authors.forename: Peter P T
authors.initials: PP
authors.lastname: Nguyen
authors.affiliation: Department of Chemistry, University of Victoria, P.O. Box 3065, Victoria, BC V8W3V6, Canada. mcindoe@uvic.ca.
authors.forename: Landon
authors.initials: L
authors.lastname: MacGillivray
authors.affiliation: Department of Chemistry, University of Victoria, P.O. Box 3065, Victoria, BC V8W3V6, Canada. mcindoe@uvic.ca.
authors.forename: Julio
authors.initials: J
authors.lastname: Martelino
authors.affiliation: Department of Chemistry, University of Victoria, P.O. Box 3065, Victoria, BC V8W3V6, Canada. mcindoe@uvic.ca.
authors.forename: J Scott
authors.identifier: http://orcid.org/0000-0001-7073-5246
authors.initials: JS
authors.lastname: McIndoe