title: Carboxylate-Enhanced Rhodium(III)-Catalyzed Aryl C-H Alkylation with Conjugated Alkenes under Mild Conditions.
abstract: Rhodium(III)-catalyzed C-H bond functionalization for the synthesis of β-aryl aldehydes and ketones from (hetero)aryl oximes, pyri(mi)dine, as well as pyrazoles and α,β-unsaturated carbonyl compounds has been developed under exceedingly mild reaction conditions. Thus, the versatile rhodium(III) catalysis features high step- and atom-economy, oxidant-free reaction conditions, and broad substrate scope.
authors.affiliation: School of Pharmaceutical Sciences, Jiangnan University , Lihu Road 1800, 214122 Wuxi, P.R. China.
authors.forename: Zhao
authors.initials: Z
authors.lastname: Zhang
authors.affiliation: School of Pharmaceutical Sciences, Jiangnan University , Lihu Road 1800, 214122 Wuxi, P.R. China.
authors.forename: Mengyao
authors.initials: M
authors.lastname: Tang
authors.affiliation: School of Pharmaceutical Sciences, Jiangnan University , Lihu Road 1800, 214122 Wuxi, P.R. China.
authors.forename: Shengnan
authors.initials: S
authors.lastname: Han
authors.affiliation: Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen , Tammannstrasse 2, 37077 Göttingen, Germany.
authors.forename: Lutz
authors.initials: L
authors.lastname: Ackermann
authors.affiliation: School of Pharmaceutical Sciences, Jiangnan University , Lihu Road 1800, 214122 Wuxi, P.R. China.
authors.forename: Jie
authors.identifier: 0000-0002-6912-3346
authors.initials: J
authors.lastname: Li