title: Fluorescence detection of pesticides using quantum dot materials - A review.
abstract: High pesticide use, especially in agriculture, can lead to environmental pollution and potentially adverse health effects. As result, pesticide residues end up in different media, including water and food products, which may serve as direct routes for human exposure. There is thus a continuous drive to develop analytical methods for screening and quantification of these compounds in the different environmental media in which they may occur. Development of quantum dot (QD) based sensors for monitoring pesticides has gained momentum in recent years. QD materials have excellent and unique optical properties and have high fluorescence quantum yields compared to other fluorophores. They have thus been used in numerous studies for the development of probes for organic pollutants. In this paper we specifically review their application as fluorescence probes for pesticide detection in different media including water and in fruits and vegetables. The low detection limits reported demonstrate the potential use of these methods as alternatives to expensive and time-consuming conventional techniques. We also highlight potential limitations that these probes may present when it comes to routine application. Finally we discuss possible future improvements to enhance the selectivity and robustness of these sensors. We note that there is still a need for researchers to develop standardized QD based sensors which could lead to their commercialization and routine application.
authors.affiliation: Department of Chemistry, Faculty of Natural and Agricultural Sciences, University of Pretoria, Lynnwood Road, Pretoria 0002, South Africa.
authors.forename: S A
authors.initials: SA
authors.lastname: Nsibande
authors.affiliation: Department of Chemistry, Faculty of Natural and Agricultural Sciences, University of Pretoria, Lynnwood Road, Pretoria 0002, South Africa. Electronic address: patricia.forbes@up.ac.za.
authors.forename: P B C
authors.initials: PB
authors.lastname: Forbes
mesh_terms: D031541:Fluorescence Resonance Energy Transfer / Q000379:methods*; D010575:Pesticides / Q000032:analysis*; D045663:Quantum Dots
chemical_list: D010575:Pesticides
keywords: Fluorescence; Pesticides; Probes; Quantum dots; Sensors