title: Microwave assisted conversion of microcrystalline cellulose into value added chemicals using dilute acid catalyst.
abstract: One of the grand challenges of this century is to transition fuels and chemicals production derived from fossil feedstocks to renewable feedstocks such as cellulosic biomass. Here we describe fast microwave conversion of microcrystalline cellulose (MCC) in water, with dilute acid catalyst to produce valuable platform chemicals. Single 10min microwave assisted treatment was able to convert >60% of MCC, with >50mol% yield of desirable products such as glucose, HMF, furfural and levulinic acid. Recycling of residual MCC with make-up fresh MCC resulted in an overall conversion of >93% after 5 cycles while maintaining >60% conversion in each cycle. Addition of isopropanol (70%v/v) as a co-solvent increased the yields of HMF and levulinic acid. This work shows for the first time proof of concept for complete conversion of recalcitrant microcrystalline cellulose in mild conditions of low temperature, dilute acid and short residence time using energy efficient microwave technology.
authors.affiliation: Department of Chemical Engineering, Monash University, Clayton VIC 3800, Australia. Electronic address: teck.ching@monash.edu.
authors.forename: Teck Wei
authors.initials: TW
authors.lastname: Ching
authors.affiliation: Department of Chemical Engineering, Monash University, Clayton VIC 3800, Australia. Electronic address: victoria.haritos@monash.edu.
authors.forename: Victoria
authors.initials: V
authors.lastname: Haritos
authors.affiliation: Department of Chemical Engineering, Monash University, Clayton VIC 3800, Australia. Electronic address: akshat.tanksale@monash.edu.
authors.forename: Akshat
authors.initials: A
authors.lastname: Tanksale
keywords: 5-hydroxymethylfurfural; Glucose; Isopropanol; Levulinic acid; Microcrystalline cellulose; Microwave; Sulfuric acid