title: In Situ Generation of NiO Nanoparticles in a Magnetic Metal-Organic Framework Exhibiting Three-Dimensional Magnetic Ordering.
abstract: NiO nanoparticles were in situ formed in a new metal-organic framework (MOF), [Ni3(pyip)2(HCOO)2(H2O)2]n[1; H2pyip = 5-(pyridine-4-yl)isophthalic acid], which was characterized by Fourier transform infrared spectroscopy, elemental analysis, thermogravimetric analysis, transmission electron microscopy, and powder and single-crystal X-ray diffraction. The MOF 1 shows a 3,6-connected three-dimensional rtl topology network with a topological symbol of (4.62)2(42.610.83). Magnetic property studies showed that the combination of NiO nanoparticles within the magnetic MOF leads to the occurrence of long-range magnetic ordering below a critical temperature of 18 K.
authors.affiliation: Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (MOE), ‡State Key Laboratory of Elemento-Organic Chemistry, and §Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University , Tianjin300071, China.
authors.forename: Xixi
authors.initials: X
authors.lastname: Meng
authors.affiliation: Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (MOE), ‡State Key Laboratory of Elemento-Organic Chemistry, and §Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University , Tianjin300071, China.
authors.forename: Xuejing
authors.initials: X
authors.lastname: Zhang
authors.affiliation: Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (MOE), ‡State Key Laboratory of Elemento-Organic Chemistry, and §Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University , Tianjin300071, China.
authors.forename: Yanmin
authors.initials: Y
authors.lastname: Bing
authors.affiliation: Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (MOE), ‡State Key Laboratory of Elemento-Organic Chemistry, and §Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University , Tianjin300071, China.
authors.forename: Na
authors.initials: N
authors.lastname: Xu
authors.affiliation: Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (MOE), ‡State Key Laboratory of Elemento-Organic Chemistry, and §Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University , Tianjin300071, China.
authors.forename: Wei
authors.initials: W
authors.lastname: Shi
authors.affiliation: Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (MOE), ‡State Key Laboratory of Elemento-Organic Chemistry, and §Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University , Tianjin300071, China.
authors.forename: Peng
authors.identifier: http://orcid.org/0000-0001-6130-1227
authors.initials: P
authors.lastname: Cheng