title: Iodine-Rich Imidazolium Iodate and Periodate Salts: En Route to Single-Based Biocidal Agents.
abstract: Two classes of iodine-rich salts that consist of iodine-rich cations and iodate (IO3-) or periodate (IO4-) anions were synthesized. The synthesis of analogous I3O8-salts was more difficult because of poor solubility and hydrolytic instability. All iodine-rich salts were fully characterized by infrared,1H nuclear magnetic resonance, and13C nuclear magnetic resonance spectroscopy as well as elemental analyses. The molecular structures of compounds 15 and 24 were elucidated by X-ray single-crystal diffraction. Additionally, the heats of formation were calculated with Gaussian 03. The detonation properties and biocidal efficiency were calculated and evaluated using CHEETAH 7.
authors.affiliation: Department of Chemistry, University of Idaho , Moscow, Idaho 83844-2343, United States.
authors.forename: Chunlin
authors.initials: C
authors.lastname: He
authors.affiliation: Department of Physics, Naval Postgraduate School , Monterey, California 93943, United States.
authors.forename: Joseph P
authors.initials: JP
authors.lastname: Hooper
authors.affiliation: Department of Chemistry, University of Idaho , Moscow, Idaho 83844-2343, United States.
authors.forename: Jean'ne M
authors.identifier: http://orcid.org/0000-0001-8622-4897
authors.initials: JM
authors.lastname: Shreeve
mesh_terms: D000890:Anti-Infective Agents / Q000737:chemistry*; D018360:Crystallography, X-Ray; D007093:Imidazoles / Q000737:chemistry*; D007452:Iodates / Q000737:chemistry*; D007455:Iodine / Q000737:chemistry*; D015394:Molecular Structure; D010504:Periodic Acid / Q000737:chemistry*; D012492:Salts / Q000737:chemistry*; D013057:Spectrum Analysis
chemical_list: D000890:Anti-Infective Agents; D007093:Imidazoles; D007452:Iodates; D012492:Salts; D010504:Periodic Acid; D007455:Iodine