title: Guest-tuned spin crossover in flexible supramolecular assemblies templated by a halide (Cl-, Br-or I-).
abstract: Ligand 1,3-bis(3-(pyridin-2-yl)-1H-pyrazol-5-yl)benzene, L, forms mononuclear spin crossover complexes [FeL3]2+with pendant arms that cause them to dimerize through numerous intermolecular interactions forming supramolecular (X@[FeL3]2)3+cations. They have the flexibility to encapsulate Cl-, Br-or I-, which allow tuning the magnetic properties, in the solid state and in solution.
authors.affiliation: Departament de Química Inorgànica and IN2UB, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain. guillem.aromi.qi.ub.es.
authors.forename: M D
authors.initials: MD
authors.lastname: Darawsheh
authors.affiliation: Departament de Química Inorgànica and IN2UB, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain. guillem.aromi.qi.ub.es.
authors.forename: L A
authors.initials: LA
authors.lastname: Barrios
authors.affiliation: Instituto de Ciencia de Materiales de Aragón (ICMA), CSIC and Universidad de Zaragoza, Plaza San Francisco s/n, 50009, Zaragoza, Spain.
authors.forename: O
authors.identifier: 0000-0003-2095-5843
authors.initials: O
authors.lastname: Roubeau
authors.affiliation: Advanced Light Source, Berkeley Laboratory, 1 Cyclotron Road, Berkeley, California 94720, USA.
authors.forename: S J
authors.initials: SJ
authors.lastname: Teat
authors.affiliation: Departament de Química Inorgànica and IN2UB, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain. guillem.aromi.qi.ub.es.
authors.forename: G
authors.identifier: 0000-0002-0997-9484
authors.initials: G
authors.lastname: Aromí