title: A new separation and preconcentration method for selenium in some foods using modified silica gel with 2,6-diamino-4-phenil-1,3,5-triazine.
abstract: A novel and simple solid phase extraction method was improved and recommended for selenium. Silica gel was modified with 2,6-diamino-4-phenil-1,3,5-triazine and characterized by FTIR, SEM and elemental analysis and used adsorbent for column solid phase extraction of selenium ions. The experimental parameters (pH, flow rates, amounts of the modified silica gel, concentration and type of eluent, volume of sample, etc.) on the recoveries of selenium were optimized. Standard reference materials were analyzed for validation of method. The present method was successfully applied to the detection of total selenium in water and microwave digested some food samples with quantitative recoveries (> 95%). The relative standard deviations were<8%. Matrix influences were not observed. The adsorption capacity of modified silica gel was 5.90mgg-1. The LOD was 0.015μgL-1. Enrichment factor was obtained as 50 for the introduced method.
authors.affiliation: Gaziosmanpaşa University, Faculty of Science and Arts, Chemistry Department, 60250 Tokat, Turkey. Electronic address: durali.mendil@gop.edu.tr.
authors.forename: Durali
authors.initials: D
authors.lastname: Mendil
authors.affiliation: Gaziosmanpaşa University, Faculty of Science and Arts, Chemistry Department, 60250 Tokat, Turkey.
authors.forename: Zafer
authors.initials: Z
authors.lastname: Demirci
authors.affiliation: Gaziosmanpaşa University, Faculty of Science and Arts, Chemistry Department, 60250 Tokat, Turkey.
authors.forename: Ozgur Dogan
authors.initials: OD
authors.lastname: Uluozlu
authors.affiliation: Gaziosmanpaşa University, Faculty of Science and Arts, Chemistry Department, 60250 Tokat, Turkey.
authors.forename: Mustafa
authors.initials: M
authors.lastname: Tuzen
authors.affiliation: Erciyes University, Faculty of Science, Department of Chemistry, 38039 Kayseri, Turkey.
authors.forename: Mustafa
authors.initials: M
authors.lastname: Soylak
mesh_terms: D012643:Selenium / Q000737:chemistry*; D058428:Silica Gel / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry; D052616:Solid Phase Extraction / Q000379:methods*; D013054:Spectrophotometry, Atomic / Q000379:methods*
chemical_list: D058428:Silica Gel; D012822:Silicon Dioxide; D012643:Selenium
keywords: Graphite furnace atomic absorption spectrometry; Modified silica gel; Selenium; Solid phase extraction