title: A redox active switch for lanthanide luminescence in phenolate complexes.
abstract: The reversible oxidation of coordinated phenolates into phenoxyl radicals results in a dramatic quenching (>95%) of the luminescence of the f metal ion.
authors.affiliation: Département de Chimie Moléculaire, Chimie Inorganique Redox (CIRE), UMR CNRS 5250, Université Grenoble-Alpes, B. P. 53, 38041 Grenoble Cedex 9, France. fabrice.thomas@univ-grenoble-alpes.fr and Laboratoire de Reconnaissance Ionique et Chimie de Coordination SCIB, UMR-E3 CEA-UJF, INAC, CEA-Grenoble, 17 rue des Martyrs, 38054 Grenoble Cedex 09, France.
authors.forename: J K
authors.initials: JK
authors.lastname: Molloy
authors.affiliation: Département de Chimie Moléculaire, Chimie Inorganique Redox (CIRE), UMR CNRS 5250, Université Grenoble-Alpes, B. P. 53, 38041 Grenoble Cedex 9, France. fabrice.thomas@univ-grenoble-alpes.fr.
authors.forename: O
authors.initials: O
authors.lastname: Jarjayes
authors.affiliation: Département de Chimie Moléculaire, Chimie Inorganique Redox (CIRE), UMR CNRS 5250, Université Grenoble-Alpes, B. P. 53, 38041 Grenoble Cedex 9, France. fabrice.thomas@univ-grenoble-alpes.fr.
authors.forename: C
authors.initials: C
authors.lastname: Philouze
authors.affiliation: Laboratoire de Reconnaissance Ionique et Chimie de Coordination SCIB, UMR-E3 CEA-UJF, INAC, CEA-Grenoble, 17 rue des Martyrs, 38054 Grenoble Cedex 09, France.
authors.forename: L
authors.initials: L
authors.lastname: Fedele
authors.affiliation: Laboratoire de Reconnaissance Ionique et Chimie de Coordination SCIB, UMR-E3 CEA-UJF, INAC, CEA-Grenoble, 17 rue des Martyrs, 38054 Grenoble Cedex 09, France.
authors.forename: D
authors.identifier: http://orcid.org/0000-0003-0038-4916
authors.initials: D
authors.lastname: Imbert
authors.affiliation: Département de Chimie Moléculaire, Chimie Inorganique Redox (CIRE), UMR CNRS 5250, Université Grenoble-Alpes, B. P. 53, 38041 Grenoble Cedex 9, France. fabrice.thomas@univ-grenoble-alpes.fr.
authors.forename: F
authors.initials: F
authors.lastname: Thomas
mesh_terms: D028581:Lanthanoid Series Elements / Q000737:chemistry*; D049449:Luminescence; D010084:Oxidation-Reduction; D010636:Phenols / Q000737:chemistry*
chemical_list: D028581:Lanthanoid Series Elements; D010636:Phenols; C042329:phenoxy radical