title: A cheap protocol for colour measure and for diagnostic in planning a cultural heritage restoration. Case study: main façade of Palazzo Governi (Cagliari, Sardinia, Italy).
abstract: Due to the bad state of conservation, "Palazzo Governi", a seventeenth-century building located in the old town district of "Stampace" in Cagliari (Sardinia, Italy), was subjected to restoration. Thus, according to the Italian Law n. 1089, the main façade colour must be reproduced, and therefore, its identification was required. The available samples looked fairly degraded, in particular as an easy plaster to crumble; so, some other analyses able to identify the degradation cause were performed. Two different approaches were adopted to attain the first goal, the visual colour assessment by a sensory panel (subjective) and the instrumental measurement by colorimetry (objective). Ion chromatography and inductively coupled plasma-optical emission spectroscopy analyses, as well as conductivity and pH measurements, were performed to evaluate the presence of water-soluble salts inside the plaster, as possible cause of degradation; the binder/aggregate ratio was also evaluated. A full mineralogical and petrographic characterisation of the materials constituting the samples, as well as the identification of their stratigraphy and some other morphologic and structural features suitable to highlight eventual forms of degradation, were performed by optical microscopy. Scanning electron microscopy coupled to X-ray microanalysis was been also used in order to confirm and/or to integrate data obtained by optical microscopy. The samples have been compared with two samples coming from two other buildings, also located in Sardinia, that looked in good conservation state. The results evidenced that the causes of degradation come from a high salt (especially sulphate) content and a scarce presence of binder in the plaster that can be imputed to a wrong initial composition and/ or to a leaching by acidic rain.
authors.affiliation: Chemistry Department, "Sapienza" University of Rome, Rome, Italy. mariapia.sammartino@uniroma1.it.
authors.forename: M P
authors.initials: MP
authors.lastname: Sammartino
authors.affiliation: Chemistry Department, "Sapienza" University of Rome, Rome, Italy.
authors.forename: C
authors.initials: C
authors.lastname: Genova
authors.affiliation: Earth Science Department, "Sapienza" University of Rome, Rome, Italy.
authors.forename: S
authors.initials: S
authors.lastname: Ronca
authors.affiliation: Architect Responsible for The Design and Supervision, Ittiri, SS, Italy.
authors.forename: G
authors.initials: G
authors.lastname: Cau
authors.affiliation: Chemistry Department, "Sapienza" University of Rome, Rome, Italy.
authors.forename: G
authors.initials: G
authors.lastname: Visco
mesh_terms: D003116:Color; D004577:Electron Probe Microanalysis; D007558:Italy; D008855:Microscopy, Electron, Scanning
keywords: Colorimetry; Diagnostics; OM and SEM/EDS; Plaster; Sensor panel; Water-soluble salts