title: Surfactant-Mediated Crystallization-Driven Self-Assembly of Crystalline/Ionic Complexed Block Copolymers in Aqueous Solution.
abstract: A series of crystalline/ionic complexed block copolymers (BCPs) with various compositions have been prepared by sequential reactions. The BCPs with different hydrophilic fractions can self-assemble into various morphologies, such as spindlelike, rodlike, and spherical micelles with different crystallinity of the core. Bis(2-ethylhexyl) sulfosuccinate sodium salt (AOT) is added as a surfactant to induce the morphological transition of BCPs in aqueous media. The introduced AOT can be tightly bound to the cationic units, and a water-insoluble unit in the corona forms, leading to a reduced tethering density. Consequently, morphological variety changing from rods to platelets to fibril to dendrite-like micelles can be observed.
authors.affiliation: College of Materials and Textiles, Zhejiang Sci-Tech University , Hangzhou 310018, P. R. China.|Key Laboratory of Advanced Textile Materials and Manufacturing Technology (ATMT), Ministry of Education , Hangzhou 310018, P. R. China.|National Engineering Laboratory for Textile Fiber Materials and Processing Technology (Zhejiang), Hangzhou 310018, P. R. China.
authors.forename: Zaizai
authors.identifier: 0000-0001-7115-0442
authors.initials: Z
authors.lastname: Tong
authors.affiliation: College of Materials and Textiles, Zhejiang Sci-Tech University , Hangzhou 310018, P. R. China.
authors.forename: Runke
authors.initials: R
authors.lastname: Zhang
authors.affiliation: College of Materials and Textiles, Zhejiang Sci-Tech University , Hangzhou 310018, P. R. China.|Key Laboratory of Advanced Textile Materials and Manufacturing Technology (ATMT), Ministry of Education , Hangzhou 310018, P. R. China.|National Engineering Laboratory for Textile Fiber Materials and Processing Technology (Zhejiang), Hangzhou 310018, P. R. China.
authors.forename: Pianpian
authors.initials: P
authors.lastname: Ma
authors.affiliation: College of Materials and Textiles, Zhejiang Sci-Tech University , Hangzhou 310018, P. R. China.
authors.forename: Haian
authors.initials: H
authors.lastname: Xu
authors.affiliation: College of Materials and Textiles, Zhejiang Sci-Tech University , Hangzhou 310018, P. R. China.
authors.forename: Hua
authors.initials: H
authors.lastname: Chen
authors.affiliation: College of Materials and Textiles, Zhejiang Sci-Tech University , Hangzhou 310018, P. R. China.
authors.forename: Yanming
authors.initials: Y
authors.lastname: Li
authors.affiliation: College of Materials and Textiles, Zhejiang Sci-Tech University , Hangzhou 310018, P. R. China.
authors.forename: Weijiang
authors.initials: W
authors.lastname: Yu
authors.affiliation: College of Materials and Textiles, Zhejiang Sci-Tech University , Hangzhou 310018, P. R. China.
authors.forename: Wangqian
authors.initials: W
authors.lastname: Zhuo
authors.affiliation: College of Materials and Textiles, Zhejiang Sci-Tech University , Hangzhou 310018, P. R. China.|Key Laboratory of Advanced Textile Materials and Manufacturing Technology (ATMT), Ministry of Education , Hangzhou 310018, P. R. China.|National Engineering Laboratory for Textile Fiber Materials and Processing Technology (Zhejiang), Hangzhou 310018, P. R. China.
authors.forename: Guohua
authors.initials: G
authors.lastname: Jiang