title: Innovative plasticized alginate obtained by thermo-mechanical mixing: Effect of different biobased polyols systems.
abstract: Plasticized alginate films with different biobased polyols (glycerol and sorbitol) and their mixtures were successfully prepared by thermo-mechanical mixing instead of the usual casting-evaporation procedure. The microstructure and properties of the different plasticized alginate formulations were investigated by SEM, FTIR, XRD, DMTA and uniaxial tensile tests. SEM and XRD results showed that native alginate particles were largely destructured with the plasticizers (polyols and water), under a thermo-mechanical input. With increasing amount of plasticizers, the samples showed enhanced homogeneity while their thermal and mechanical properties decreased. Compared to sorbitol, glycerol resulted in alginate films with a higher flexibility due to its better plasticization efficiency resulting from its smaller size and higher hydrophilic character. Glycerol and sorbitol mixtures seemed to be an optimum to obtain the best properties. This work showed that thermo-mechanical mixing is a promising method to produce, at large scale, plasticized alginate-based films with improved properties.
authors.affiliation: BioTeam/ICPEES-ECPM, UMR CNRS 7515, Université de Strasbourg, 25 rue Becquerel, 67087 Strasbourg, Cedex 2, France.
authors.forename: Chengcheng
authors.initials: C
authors.lastname: Gao
authors.affiliation: BioTeam/ICPEES-ECPM, UMR CNRS 7515, Université de Strasbourg, 25 rue Becquerel, 67087 Strasbourg, Cedex 2, France.
authors.forename: Eric
authors.initials: E
authors.lastname: Pollet
authors.affiliation: BioTeam/ICPEES-ECPM, UMR CNRS 7515, Université de Strasbourg, 25 rue Becquerel, 67087 Strasbourg, Cedex 2, France. Electronic address: luc.averous@unistra.fr.
authors.forename: Luc
authors.initials: L
authors.lastname: Avérous
mesh_terms: D000464:Alginates / Q000737:chemistry*; D020723:Glucuronic Acid / Q000737:chemistry; D005990:Glycerol / Q000737:chemistry*; D006603:Hexuronic Acids / Q000737:chemistry; D010968:Plasticizers / Q000737:chemistry*; D011108:Polymers; D013012:Sorbitol / Q000737:chemistry*; D014867:Water
chemical_list: D000464:Alginates; D006603:Hexuronic Acids; D010968:Plasticizers; D011108:Polymers; D014867:Water; D013012:Sorbitol; D020723:Glucuronic Acid; D005990:Glycerol
keywords: Alginate; Glycerol; Plasticization; Sorbitol; Thermo-mechanical mixing