title: Reversible formylborane/SO2coupling at a frustrated Lewis pair framework.
abstract: Carbon monoxide is reduced by HB(C6F5)2at the Mes2PCH2CH2B(C6F5)2P/B FLP template to give the respective FLP stabilized (η2-formyl)borane product 2. This adds sulfur dioxide by insertion of a SO bond into the three-membered ring to give the P/B FLP coordinated SO2adduct 9.
authors.affiliation: Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, 48149 Münster, Germany. erker@uni-muenster.de.
authors.forename: Ke-Yin
authors.initials: KY
authors.lastname: Ye
authors.affiliation: Mulliken Center for Theoretical Chemistry, Institut für Physikalische und Theoretische Chemie, Universität Bonn, Beringstraße 4, 53115 Bonn, Germany.
authors.forename: Markus
authors.identifier: 0000-0001-6711-5804
authors.initials: M
authors.lastname: Bursch
authors.affiliation: Mulliken Center for Theoretical Chemistry, Institut für Physikalische und Theoretische Chemie, Universität Bonn, Beringstraße 4, 53115 Bonn, Germany.
authors.forename: Zheng-Wang
authors.initials: ZW
authors.lastname: Qu
authors.affiliation: Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, 48149 Münster, Germany. erker@uni-muenster.de.
authors.forename: Constantin G
authors.initials: CG
authors.lastname: Daniliuc
authors.affiliation: Mulliken Center for Theoretical Chemistry, Institut für Physikalische und Theoretische Chemie, Universität Bonn, Beringstraße 4, 53115 Bonn, Germany.
authors.forename: Stefan
authors.initials: S
authors.lastname: Grimme
authors.affiliation: Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, 48149 Münster, Germany. erker@uni-muenster.de.
authors.forename: Gerald
authors.identifier: 0000-0002-5196-2491
authors.initials: G
authors.lastname: Kehr
authors.affiliation: Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, 48149 Münster, Germany. erker@uni-muenster.de.
authors.forename: Gerhard
authors.identifier: 0000-0003-2488-3699
authors.initials: G
authors.lastname: Erker