title: Monodentate coordination of the normally chelating chiral diamine (R,R)-TMCDA.
abstract: After isolating an unusual binuclear, but monosolvated NaHMDS complex [{(R,R)-TMCDA}·(NaHMDS)2]∞which polymerises via intermolecular electrostatic NaMeHMDSinteractions, further (R,R)-TMCDA was added to produce the discrete binuclear amide [{κ2-(R,R)-TMCDA}·(NaHMDS)2{κ1-(R,R)-TMCDA}], whose salient feature is the unique monodentate coordination of one of the chiral diamine ligands.
authors.affiliation: WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow, G1 1XL, UK. charlie.ohara@strath.ac.uk.
authors.forename: Ana I
authors.initials: AI
authors.lastname: Ojeda-Amador
authors.affiliation: WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow, G1 1XL, UK. charlie.ohara@strath.ac.uk.
authors.forename: Antonio J
authors.initials: AJ
authors.lastname: Martínez-Martínez
authors.affiliation: WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow, G1 1XL, UK. charlie.ohara@strath.ac.uk.
authors.forename: Alan R
authors.initials: AR
authors.lastname: Kennedy
authors.affiliation: WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow, G1 1XL, UK. charlie.ohara@strath.ac.uk.
authors.forename: David R
authors.initials: DR
authors.lastname: Armstrong
authors.affiliation: WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow, G1 1XL, UK. charlie.ohara@strath.ac.uk.
authors.forename: Charles T
authors.identifier: 0000-0002-1691-1568
authors.initials: CT
authors.lastname: O'Hara