title: N,B-Bidentate Boryl Ligand-Supported Iridium Catalyst for Efficient Functional-Group-Directed C-H Borylation.
abstract: Convenient silylborane precursors for introducing N,B-bidentate boryl ligands onto transition metals were designed, prepared, and employed in ready formation of irdium(III) complexes via Si-B oxidative addition. A practical, efficient catalytic ortho-borylation reaction of arenes with a broad range of directing groups was developed using an in situ generated catalyst from the silylborane preligand 3c and [IrCl(COD)]2.
authors.affiliation: Frontier Institute of Science and Technology, Xi'an Jiaotong University , Xi'an, 710054, China.
authors.forename: Guanghui
authors.initials: G
authors.lastname: Wang
authors.affiliation: Frontier Institute of Science and Technology, Xi'an Jiaotong University , Xi'an, 710054, China.
authors.forename: Li
authors.initials: L
authors.lastname: Liu
authors.affiliation: Frontier Institute of Science and Technology, Xi'an Jiaotong University , Xi'an, 710054, China.
authors.forename: Hong
authors.initials: H
authors.lastname: Wang
authors.affiliation: Frontier Institute of Science and Technology, Xi'an Jiaotong University , Xi'an, 710054, China.
authors.forename: You-Song
authors.initials: YS
authors.lastname: Ding
authors.affiliation: Frontier Institute of Science and Technology, Xi'an Jiaotong University , Xi'an, 710054, China.
authors.forename: Jing
authors.initials: J
authors.lastname: Zhou
authors.affiliation: Department of Medicinal Chemistry, School of Pharmacy, Xi'an Jiaotong University , Xi'an, 710061, China.
authors.forename: Shuai
authors.initials: S
authors.lastname: Mao
authors.affiliation: Frontier Institute of Science and Technology, Xi'an Jiaotong University , Xi'an, 710054, China.|State Key Laboratory of Elemento-Organic Chemistry, Nankai University , Tianjin, 300071, China.
authors.forename: Pengfei
authors.identifier: 0000-0002-4736-2477
authors.initials: P
authors.lastname: Li