title: Efficient preparation of carbamates by Rh-catalysed oxidative carbonylation: unveiling the role of the oxidant.
abstract: The synthesis of a wide variety of carbamates from amines, alcohols and carbon monoxide has been achieved by means of a Rh-catalysed oxidative carbonylation reaction that uses Oxone as a stoichiometric oxidant. In-depth studies on the reaction mechanism shed light on the intimate role of Oxone in the catalytic cycle.
authors.affiliation: Departamento Química Inorgánica - ISQCH, Universidad de Zaragoza - CSIC, 50009 Zaragoza, Spain. miglesia@unizar.es oro@unizar.es.
authors.forename: Amaia
authors.identifier: 0000-0003-2888-1877
authors.initials: A
authors.lastname: Iturmendi
authors.affiliation: Departamento Química Inorgánica - ISQCH, Universidad de Zaragoza - CSIC, 50009 Zaragoza, Spain. miglesia@unizar.es oro@unizar.es.
authors.forename: Manuel
authors.identifier: 0000-0003-3144-5320
authors.initials: M
authors.lastname: Iglesias
authors.affiliation: Departamento Química Física - Instituto de Biocomputación y Física de Sistemas Complejos (BIFI), Universidad de Zaragoza, 50009 Zaragoza, Spain.
authors.forename: Julen
authors.identifier: 0000-0001-6089-6126
authors.initials: J
authors.lastname: Munárriz
authors.affiliation: Departamento Química Física - Instituto de Biocomputación y Física de Sistemas Complejos (BIFI), Universidad de Zaragoza, 50009 Zaragoza, Spain.
authors.forename: Victor
authors.identifier: 0000-0001-5823-7965
authors.initials: V
authors.lastname: Polo
authors.affiliation: Departamento Química Inorgánica - ISQCH, Universidad de Zaragoza - CSIC, 50009 Zaragoza, Spain. miglesia@unizar.es oro@unizar.es.
authors.forename: Jesús J
authors.identifier: 0000-0002-3327-0918
authors.initials: JJ
authors.lastname: Pérez-Torrente
authors.affiliation: Departamento Química Inorgánica - ISQCH, Universidad de Zaragoza - CSIC, 50009 Zaragoza, Spain. miglesia@unizar.es oro@unizar.es and King Fahd University of Petroleum & Minerals (KFUPM), Dhahran 31261, Saudi Arabia.
authors.forename: Luis A
authors.identifier: 0000-0001-7154-7239
authors.initials: LA
authors.lastname: Oro