title: Influence of Polar Organic Solvents in an Ionic Liquid Containing Lithium Bis(fluorosulfonyl)amide: Effect on the Cation-Anion Interaction, Lithium Ion Battery Performance, and Solid Electrolyte Interphase.
abstract: Ionic liquid-organic solvent mixtures have recently been investigated as potential battery electrolytes. However, contradictory results with these mixtures have been shown for battery performance. In this manuscript, we studied the influence of the addition of polar organic solvents into the ionic liquid electrolyte 1 M lithium bis(fluorosulfonyl)amide (LiFSI)-1-butyl-1-methylpyrrolidinium bis(fluorosulfonyl)amide ([Py1,4]FSI) and tested it for lithium ion battery applications. From infrared and Raman spectroscopy, clear changes in the lithium solvation and cation-anion interactions in the ionic liquid were observed on addition of organic solvents. From the lithiation/delithiation studies on electrodeposited Ge, the storage capacity for the ionic liquid-highly polar organic solvent (acetonitrile) mixture was found to be the highest at low C-rates (0.425 C) compared to using an ionic liquid alone and ionic liquid-less polar solvent (dimethyl carbonate) mixtures. Furthermore, XPS and AFM were used to evaluate the solid electrolyte interphase (SEI) and to correlate its stability with Li storage capacity.
authors.affiliation: Institute of Electrochemistry, Clausthal University of Technology , Arnold-Sommerfeld-Strasse 6, 38678 Clausthal-Zellerfeld, Germany.
authors.forename: Abhishek
authors.initials: A
authors.lastname: Lahiri
authors.affiliation: Institute of Electrochemistry, Clausthal University of Technology , Arnold-Sommerfeld-Strasse 6, 38678 Clausthal-Zellerfeld, Germany.
authors.forename: Guozhu
authors.initials: G
authors.lastname: Li
authors.affiliation: Institute of Electrochemistry, Clausthal University of Technology , Arnold-Sommerfeld-Strasse 6, 38678 Clausthal-Zellerfeld, Germany.
authors.forename: Mark
authors.initials: M
authors.lastname: Olschewski
authors.affiliation: Institute of Electrochemistry, Clausthal University of Technology , Arnold-Sommerfeld-Strasse 6, 38678 Clausthal-Zellerfeld, Germany.
authors.forename: Frank
authors.initials: F
authors.lastname: Endres
keywords: X-ray photoelectron spectroscopy; atomic force microscopy; battery electrolytes; intermolecular interactions; ionic liquids; lithium-ion battery; solid−electrolyte interphase