title: Enhanced ZT of InxCo4Sb12-InSb Nanocomposites Fabricated by Hydrothermal Synthesis Combined with Solid-Vapor Reaction: A Signature of Phonon-Glass and Electron-Crystal Materials.
abstract: A rapid route of synthesizing pristine Co4Sb12at relatively low temperature was previously developed. However, filling the voids using the same procedure is not successful. We develop a new route to fabricate In-filled cobalt skutterudites with InSb nanoinclusions InxCo4Sb12-(InSb)yvia solid-vapor reaction between hydrothermally synthesized Co4Sb12powder and the indium chunk. The nanocomposites are characterized using powder X-ray diffraction, field-emission scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, and inductively coupled plasma mass spectrometry (ICP-MS). With the success of partial filling of In into the voids and InSb nanoinclusions, the power factor of the InxCo4Sb12-(InSb)ynanocomposites is significantly enhanced, and the thermal conductivity is lowered as compared with the pristine Co4Sb12. As a result, ZT with its highest value of 1.0 is attained for the hierarchical structured In0.04Co4Sb12-(InSb)0.05nanocomposite at 575 K. The attained ZT value is among the highest ever reported value at T ≤ 575 K for In-filled cobalt skutterudites.
authors.affiliation: Department of Physics, National Changhua University of Education , Changhua 500, Taiwan.
authors.forename: Ahmad
authors.initials: A
authors.lastname: Gharleghi
authors.affiliation: Department of Physics, National Changhua University of Education , Changhua 500, Taiwan.
authors.forename: Peng-Chun
authors.initials: PC
authors.lastname: Hung
authors.affiliation: Department of Physics, National Changhua University of Education , Changhua 500, Taiwan.
authors.forename: Fei-Hung
authors.initials: FH
authors.lastname: Lin
authors.affiliation: Department of Physics, National Changhua University of Education , Changhua 500, Taiwan.
authors.forename: Chia-Jyi
authors.identifier: http://orcid.org/0000-0001-5770-7611
authors.initials: CJ
authors.lastname: Liu
keywords: filled skutterudite; hydrothermal synthesis; nanocomposites; phonon-glass and electron-crystal thermoelectric material; solid−vapor reaction