title: Effect of anaerobic digestion on sequential pyrolysis kinetics of organic solid wastes using thermogravimetric analysis and distributed activation energy model.
abstract: Thermogravimetric analysis, Gaussian-fit-peak model (GFPM), and distributed activation energy model (DAEM) were firstly used to explore the effect of anaerobic digestion on sequential pyrolysis kinetic of four organic solid wastes (OSW). Results showed that the OSW weight loss mainly occurred in the second pyrolysis stage relating to organic matter decomposition. Compared with raw substrate, the weight loss of corresponding digestate was lower in the range of 180-550°C, but was higher in 550-900°C. GFPM analysis revealed that organic components volatized at peak temperatures of 188-263, 373-401 and 420-462°C had a faster degradation rate than those at 274-327°C during anaerobic digestion. DAEM analysis showed that anaerobic digestion had discrepant effects on activation energy for four OSW pyrolysis, possibly because of their different organic composition. It requires further investigation for the special organic matter, i.e., protein-like and carbohydrate-like groups, to confirm the assumption.
authors.affiliation: School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, PR China; State Key Laboratory of Pollution Control and Resources Reuse, National Engineering Research Center for Urban Pollution Control, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, PR China.
authors.forename: Xiaowei
authors.initials: X
authors.lastname: Li
authors.affiliation: School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, PR China.
authors.forename: Qingqing
authors.initials: Q
authors.lastname: Mei
authors.affiliation: State Key Laboratory of Pollution Control and Resources Reuse, National Engineering Research Center for Urban Pollution Control, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, PR China. Electronic address: daixiaohu@tongji.edu.cn.
authors.forename: Xiaohu
authors.initials: X
authors.lastname: Dai
authors.affiliation: School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, PR China.
authors.forename: Guoji
authors.initials: G
authors.lastname: Ding
mesh_terms: D007700:Kinetics; D008962:Models, Theoretical; D016011:Normal Distribution; D012037:Refuse Disposal; D062611:Solid Waste / Q000032:analysis*; D013696:Temperature; D013818:Thermogravimetry / Q000379:methods*
chemical_list: D062611:Solid Waste
keywords: Anaerobic digestion; Distributed activation energy model; Organic solid wastes; Pyrolysis; Thermogravimetric analysis