title: Graphene oxide/alginate beads as adsorbents: Influence of the load and the drying method on their physicochemical-mechanical properties and adsorptive performance.
abstract: Graphene oxide/alginate beads were prepared from lab-synthesized graphene oxide, varying its content within the beads (0.05, 0.125, and 0.25wt.%). Ethanol-drying and lyophilization were compared as drying methods to obtain suitable adsorbents which were later tested to the removal of a model organic molecule (methylene blue). The morphological and textural properties of all the beads were characterized by scanning electron microscopy and N2adsorption/desorption isotherms at -196°C, respectively. Limited porosity was obtained for all cases (SBET<60m2/g). Uniaxial compression tests were performed to assess the mechanical properties of the beads. Ethanol-dried ones exhibited higher Young's elasticity modulus (E=192kPa) than the lyophilized samples (twice at 0.25wt.% graphene oxide loading), which disclosed breakage points at lower deformation percentages. Adsorption experiments were conducted and dye adsorption isotherms were obtained for the beads with the best removal performance. The experimental data were better fitted by the Langmuir model. The highest maximum adsorption capacity (4.25mmol/g) was obtained for the lyophilized beads with the highest graphene oxide content. Mechanical properties were found to be affected also by the dye adsorption.
authors.affiliation: Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Industrias, Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía-PINMATE, Intendente Güiraldes 2620, Ciudad Universitaria, (C1428BGA) Buenos Aires, Argentina.
authors.forename: Emiliano
authors.initials: E
authors.lastname: Platero
authors.affiliation: Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Industrias, Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía-PINMATE, Intendente Güiraldes 2620, Ciudad Universitaria, (C1428BGA) Buenos Aires, Argentina; Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Godoy Cruz 2290, (C1425FQB) Buenos Aires, Argentina.
authors.forename: Maria Emilia
authors.initials: ME
authors.lastname: Fernandez
authors.affiliation: Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Industrias, Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía-PINMATE, Intendente Güiraldes 2620, Ciudad Universitaria, (C1428BGA) Buenos Aires, Argentina; Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Godoy Cruz 2290, (C1425FQB) Buenos Aires, Argentina.
authors.forename: Pablo Ricardo
authors.initials: PR
authors.lastname: Bonelli
authors.affiliation: Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Industrias, Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía-PINMATE, Intendente Güiraldes 2620, Ciudad Universitaria, (C1428BGA) Buenos Aires, Argentina; Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Godoy Cruz 2290, (C1425FQB) Buenos Aires, Argentina; Universidad de Buenos Aires, Facultad de Farmacia y Bioquímica, Departamento de Tecnología Farmacéutica, Cátedra de Farmacotecnia II, Junín 956, (C1113AAD) Buenos Aires, Argentina. Electronic address: analea@di.fcen.uba.ar.
authors.forename: Ana Lea
authors.initials: AL
authors.lastname: Cukierman
mesh_terms: D000327:Adsorption; D000464:Alginates / Q000737:chemistry*; D002627:Chemistry, Physical; D000431:Ethanol / Q000737:chemistry; D005612:Freeze Drying; D020723:Glucuronic Acid / Q000737:chemistry; D006108:Graphite / Q000737:chemistry*; D006603:Hexuronic Acids / Q000737:chemistry; D010087:Oxides / Q000737:chemistry*; D010316:Particle Size; D013499:Surface Properties
chemical_list: D000464:Alginates; D006603:Hexuronic Acids; D010087:Oxides; D000431:Ethanol; D006108:Graphite; D020723:Glucuronic Acid
keywords: Alginate beads; Basic dye removal; Graphene oxide; Mechanical properties