title: Transfer Hydro-dehalogenation of Organic Halides Catalyzed by Ruthenium(II) Complex.
abstract: A simple and efficient Ru(II)-catalyzed transfer hydro-dehalogenation of organic halides using 2-propanol solvent as the hydride source was reported. This methodology is applicable for hydro-dehalogenation of a variety of aromatic halides and α-haloesters and amides without additional ligand, and quantitative yields were achieved in many cases. The potential synthetic application of this method was demonstrated by efficient gram-scale transformation with catalyst loading as low as 0.5 mol %.
authors.affiliation: College of Chemistry and Materials Engineering, Wenzhou University , Wenzhou 325035, China.
authors.forename: Tingjie
authors.initials: T
authors.lastname: You
authors.affiliation: College of Chemistry and Materials Engineering, Wenzhou University , Wenzhou 325035, China.
authors.forename: Zhenrong
authors.initials: Z
authors.lastname: Wang
authors.affiliation: College of Chemistry and Materials Engineering, Wenzhou University , Wenzhou 325035, China.
authors.forename: Jiajia
authors.initials: J
authors.lastname: Chen
authors.affiliation: College of Chemistry and Materials Engineering, Wenzhou University , Wenzhou 325035, China.
authors.forename: Yuanzhi
authors.identifier: 0000-0002-7125-269X
authors.initials: Y
authors.lastname: Xia