title: Effects of Ru(ii/iii) redox on the Co(ii) coordination number and magnetic properties of 1D cyanide-bridged Co-Ru compounds.
abstract: A new 1D cyanide-bridged Co-Ru compound, {[trans-RuIII(dmap)4(CN)2Co(dipic)(MeOH)](PF6)}n(1a) (dmap = 4-dimethylaminopyridine, dipic = pyridine-2,6-dicarboxylate), and its reduced state, [trans-RuII(dmap)4(CN)2Co(dipic)]n(1b) have been synthesized. Upon the Ru center reduction from iii to ii, the MeOH solvent molecule bound to Co(ii) in 1a is expelled. 1a displays ferrimagnetic properties but 1b is only a paramagnetic compound.
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China. tsheng@fjirsm.ac.cn and School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China.
authors.forename: Xiaoquan
authors.initials: X
authors.lastname: Zhu
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China. tsheng@fjirsm.ac.cn and School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China.
authors.forename: Shaodong
authors.initials: S
authors.lastname: Su
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China. tsheng@fjirsm.ac.cn and School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China.
authors.forename: Wenhai
authors.initials: W
authors.lastname: Cao
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China. tsheng@fjirsm.ac.cn.
authors.forename: Shengmin
authors.initials: S
authors.lastname: Hu
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China. tsheng@fjirsm.ac.cn.
authors.forename: Yuehong
authors.initials: Y
authors.lastname: Wen
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China. tsheng@fjirsm.ac.cn.
authors.forename: Xintao
authors.initials: X
authors.lastname: Wu
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China. tsheng@fjirsm.ac.cn.
authors.forename: Tianlu
authors.identifier: http://orcid.org/0000-0003-0415-3955
authors.initials: T
authors.lastname: Sheng