title: Oxidative degradation of emerging micropollutant acesulfame in aqueous matrices by UVA-induced H2O2/Fe2+and S2O82-/Fe2+processes.
abstract: In the present study, UVA/H2O2/Fe2+and UVA/S2O82-/Fe2+processes were applied to degrade the artificial sweetener, acesulfame (ACE) in ultrapure water (UW), groundwater (GW), and secondary effluent (WW). The degradation time and mineralization of 75 μM of ACE determined the efficacy of the procedures. The results indicated that the UVA-induced H2O2/Fe2+and S2O82-/Fe2+systems are a promising alternative for the removal of ACE from different aqueous matrices as both studied processes completely degraded the target compound at an ACE/oxidant/Fe2+molar ratio of 1/10/1 and pH 3. In the case of UVA-induced systems application without pH adjustment, the ACE decomposition was achieved only in ultrapure water. The maximum mineralization of ACE in ultrapure water by the UVA/H2O2/Fe2+system (molar ratio of 1/10/1) at pH 3 resulted in residual TOC of 18.3%. The oxidative effectiveness of the UVA/S2O82-/Fe2+system was proved to be mainly formed by the hydroxyl radicals. The obtained results indicate that UVA light can be successfully used for the oxidation of the studied artificial sweetener in various aqueous matrices with carefully adjusted process conditions.
authors.affiliation: Tallinn University of Technology, Department of Chemical Engineering, Ehitajate tee 5, 19086 Tallinn, Estonia. Electronic address: eneliis.kattel@ttu.ee.
authors.forename: Eneliis
authors.initials: E
authors.lastname: Kattel
authors.affiliation: Tallinn University of Technology, Department of Chemical Engineering, Ehitajate tee 5, 19086 Tallinn, Estonia.
authors.forename: Marina
authors.initials: M
authors.lastname: Trapido
authors.affiliation: Tallinn University of Technology, Department of Chemical Engineering, Ehitajate tee 5, 19086 Tallinn, Estonia.
authors.forename: Niina
authors.initials: N
authors.lastname: Dulova
mesh_terms: D006861:Hydrogen Peroxide / Q000737:chemistry*; D017665:Hydroxyl Radical / Q000737:chemistry; D007501:Iron / Q000737:chemistry*; D010084:Oxidation-Reduction; D013431:Sulfates / Q000737:chemistry*; D013843:Thiazines / Q000737:chemistry / Q000528:radiation effects; D014466:Ultraviolet Rays; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000528:radiation effects; D018508:Water Purification / Q000379:methods
chemical_list: D013431:Sulfates; D013843:Thiazines; D014874:Water Pollutants, Chemical; D017665:Hydroxyl Radical; D006861:Hydrogen Peroxide; D007501:Iron; C006362:acetosulfame
keywords: Activated persulfate; Artificial sweetener; Photo-Fenton process; UVA-irradiation; Water treatment