title: Investigation of holdup and axial dispersion of liquid phase in a catalytic exchange column using radiotracer technique.
abstract: Holdup and axial dispersion of liquid phase in a catalytic exchange column were investigated by measuring residence time distributions (RTD) using a radiotracer technique. RTD experiments were independently carried out with two different types of packings i.e. hydrophobic water-repellent supported platinum catalyst and a mixture (50% (v/v)) of hydrophobic catalyst and a hydrophillic wettable packing were used in the column. Mean residence times and hold-ups of the liquid phase were estimated at different operating conditions. Axial dispersion model (ADM) and axial dispersion with exchange model (ADEM) were used to simulate the measured RTD data. Both the models were found equally suitable to describe the measured data. The degree of axial mixing was estimated in terms of Peclet number (Pe) and Bodenstein number (Bo). Based on the obtained parameters of the ADM, correlations for total liquid hold-up (HT) and axial mixing in terms of Bo were proposed for design and scale up of the full-scale catalytic exchange column.
authors.affiliation: Heavy Water Division, Bhabha Atomic Research Centre, Mumbai 400085, India.
authors.forename: Rajesh
authors.initials: R
authors.lastname: Kumar
authors.affiliation: Isotopes Production and Applications Division, Bhabha Atomic Research Centre, Mumbai 400085, India. Electronic address: hjpant@barc.gov.in.
authors.forename: H J
authors.initials: HJ
authors.lastname: Pant
authors.affiliation: Isotopes Production and Applications Division, Bhabha Atomic Research Centre, Mumbai 400085, India.
authors.forename: Sunil
authors.initials: S
authors.lastname: Goswami
authors.affiliation: Isotopes Production and Applications Division, Bhabha Atomic Research Centre, Mumbai 400085, India.
authors.forename: V K
authors.initials: VK
authors.lastname: Sharma
authors.affiliation: Isotopes Production and Applications Division, Bhabha Atomic Research Centre, Mumbai 400085, India.
authors.forename: A
authors.initials: A
authors.lastname: Dash
authors.affiliation: Heavy Water Division, Bhabha Atomic Research Centre, Mumbai 400085, India.
authors.forename: S
authors.initials: S
authors.lastname: Mishra
authors.affiliation: Heavy Water Division, Bhabha Atomic Research Centre, Mumbai 400085, India.
authors.forename: K
authors.initials: K
authors.lastname: Bhanja
authors.affiliation: Heavy Water Division, Bhabha Atomic Research Centre, Mumbai 400085, India.
authors.forename: Sadhana
authors.initials: S
authors.lastname: Mohan
authors.affiliation: Department of Chemical Engineering, Indian Institute of Technology, Bombay, Mumbai 400076, India.
authors.forename: S M
authors.initials: SM
authors.lastname: Mahajani
keywords: Axial dispersion model; Axial dispersion with exchange model; Bodenstein number; Bromine-82; Catalytic exchange column; Holdup; Hydrophilic; Hydrophobic; Mean residence time; Peclet number; Radiotracer; Residence time distribution; Trickle bed contactor