title: Chemical and plasma surface modification of lignocellulose coconut waste for the preparation of advanced biobased composite materials.
abstract: In this study, surface-modified grinded coconut waste (CW) particles were used as bio-fillers to prepare polymeric composite materials with enhanced properties. Epoxy resin modified with acrylated and epoxidized soybean oil (AESO) was used as the polymer matrix. Two different strategies, namely chemical treatment and plasma enhanced chemical vapor deposition (PECVD) were utilized to modify the surface of CW particles for using them as compatible bio-fillers in composite preparation. Chemical modification involved the treatment of CW particles in a highly alkali NaOH solution, while PECVD modification involved coating of a thin film of hydrophobic poly(hexafluorobutyl acrylate) (PHFBA) around individual CW particle surfaces. Untreated and surface-modified CW particles were used in 10-50wt% for preparation of epoxy composites. FTIR analysis was performed to study the effect of modification on the structures of particles and as-prepared composites. The composite morphologies were investigated by XRD and SE. TGA test was conducted to study the thermal behavior of the composites. Also, the effects of CW particle surface modification on the mechanical and water sorption properties of epoxy resin composites were investigated in detail. It was observed that PECVD-treated CW particles had much more positive effects on the thermal, mechanical, wettability and flammability properties of composites.
authors.affiliation: Department of Chemical Engineering, Faculty of Engineering, Selcuk University, 42075 Konya, Turkey. Electronic address: suheyla@selcuk.edu.tr.
authors.forename: Suheyla
authors.initials: S
authors.lastname: Kocaman
authors.affiliation: Department of Chemical Engineering, Faculty of Engineering, Selcuk University, 42075 Konya, Turkey. Electronic address: karamanm@selcuk.edu.tr.
authors.forename: Mustafa
authors.initials: M
authors.lastname: Karaman
authors.affiliation: Department of Chemical Engineering, Faculty of Engineering, Selcuk University, 42075 Konya, Turkey. Electronic address: mehmetgursoy@selcuk.edu.tr.
authors.forename: Mehmet
authors.initials: M
authors.lastname: Gursoy
authors.affiliation: Department of Chemical Engineering, Faculty of Engineering, Selcuk University, 42075 Konya, Turkey. Electronic address: ahmetli@selcuk.edu.tr.
authors.forename: Gulnare
authors.initials: G
authors.lastname: Ahmetli
mesh_terms: D003059:Cocos / Q000737:chemistry; D057927:Hydrophobic and Hydrophilic Interactions; D008031:Lignin / Q000737:chemistry*; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry; D013499:Surface Properties; D017155:Wettability
chemical_list: D011108:Polymers; C036909:lignocellulose; D008031:Lignin
keywords: Biocomposite; Chemical treatment; Coconut waste; PECVD