title: Hypervalent Iodine(III)-Induced Domino Oxidative Cyclization for the Synthesis of Cyclopenta[b]furans.
abstract: A new strategy for cyclopenta[b]furan synthesis mediated by hypervalent iodine(III) has been described. The approach employs diacetoxyiodobenzene-induced initial dehydrogenation to a putative trienone intermediate and triggered sequential cycloisomerization to form the cyclo-penta[b]furan targets.
authors.affiliation: Department of Chemistry, National Changhua University of Education, Changhua 50007, Taiwan. mhlin@cc.ncue.edu.tw.
authors.forename: Mei-Huey
authors.initials: MH
authors.lastname: Lin
authors.affiliation: Department of Chemistry, National Changhua University of Education, Changhua 50007, Taiwan. stu01250008@gmail.com.
authors.forename: Yu-Chun
authors.initials: YC
authors.lastname: Chen
authors.affiliation: Department of Chemistry, National Changhua University of Education, Changhua 50007, Taiwan. shihhao9239@yahoo.com.tw.
authors.forename: Shih-Hao
authors.initials: SH
authors.lastname: Chiu
authors.affiliation: Department of Chemistry, National Changhua University of Education, Changhua 50007, Taiwan. evons44@gmail.com.
authors.forename: Yun-Fan
authors.initials: YF
authors.lastname: Chen
authors.affiliation: Department of Chemistry, National Changhua University of Education, Changhua 50007, Taiwan. th_chuang@hotmail.com.
authors.forename: Tsung-Hsun
authors.initials: TH
authors.lastname: Chuang
mesh_terms: D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000138:chemical synthesis*; D002384:Catalysis; D003500:Cyclization; D005663:Furans / Q000138:chemical synthesis*; D007455:Iodine / Q000737:chemistry*; D007462:Iodobenzenes / Q000737:chemistry*; D007536:Isomerism; D015394:Molecular Structure; D010084:Oxidation-Reduction
chemical_list: D019086:Bridged Bicyclo Compounds, Heterocyclic; D005663:Furans; D007462:Iodobenzenes; D007455:Iodine
keywords: cycloisomerization; cyclopenta[b]furan; diacetoxyiodobenzene; domino oxidative cyclization; hypervalent iodine(III)