title: Ionic Conductor of Li2SiO3as an Effective Dual-Functional Modifier To Optimize the Electrochemical Performance of Li4Ti5O12for High-Performance Li-Ion Batteries.
abstract: Ionic conductor of Li2SiO3(LSO) was used as an effective modifier to fabricate surface-modified Li4Ti5O12(LTO) via simply mixing followed by sintering at 750 °C in air. The electrochemical performance of LTO was enhanced by merely adjusting the mass ratio of LTO/LSO, and the LTO/LSO composite with 0.51 wt % LSO exhibited outstanding rate capabilities (achieving reversible capacities of 163.8, 157.6, 153.1, 147.0, and 137.9 mAh g-1at 100, 200, 400, 800, and 1600 mA g-1, respectively) and remarkable long-term cycling stability (120.2 mAh g-1after 2700 cycles with a capacity fading rate of only 0.0074% per cycle even at 500 mA g-1). Combining structural characterization with electrochemical analysis, the LSO coating coupled with the slight doping effect adjacent to the LTO surface contributes to the enhancement of both electronic and ionic conductivities of LTO.
authors.affiliation: Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), Shandong University , Jinan 250061, P. R. China.
authors.forename: Xue
authors.initials: X
authors.lastname: Bai
authors.affiliation: Department of Informatics, Bioengineering, Robotics, System Engineering (DIBRIS), University of Genova , via Balbi 5, Genova 16126, Italy.
authors.forename: Tao
authors.initials: T
authors.lastname: Li
authors.forename: Zhiya
authors.initials: Z
authors.lastname: Dang
authors.affiliation: Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), Shandong University , Jinan 250061, P. R. China.
authors.forename: Yong-Xin
authors.initials: YX
authors.lastname: Qi
authors.affiliation: Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), Shandong University , Jinan 250061, P. R. China.
authors.forename: Ning
authors.initials: N
authors.lastname: Lun
authors.affiliation: Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), Shandong University , Jinan 250061, P. R. China.
authors.forename: Yu-Jun
authors.identifier: http://orcid.org/0000-0002-8013-9437
authors.initials: YJ
authors.lastname: Bai
keywords: Li2SiO3; Li4Ti5O12; anode materials; ionic conductor; surface modification