title: Recent progress of arsenic adsorption on TiO2in the presence of coexisting ions: A review.
abstract: Arsenic (As)-contaminated wastewater and groundwater pose a pressing environmental issue and worldwide concern. Adsorption of As using TiO2materials, in combination with filtration, introduces a promising technology for the treatment of As-contaminated water. This review presents an overview on the recent progress of the application of TiO2for removal of As from wastewater and groundwater. The main focus is on the following three pressing issues that limit the field applications of TiO2for As removal: coexisting ions, simulation of breakthrough curves, and regeneration and reuse of spent TiO2materials. We first examined how the coexisting ions in water, especially high concentrations of cations in industrial wastewater, affect the efficacy of As removal using the TiO2materials. We then discussed As breakthrough curves and the effect of compounded ions on the breakthrough curves. We successfully simulated the breakthrough curves by PHREEQC after integrating the CD-MUSIC model. We further discussed challenges facing the regeneration and reuse of TiO2media for practical applications. We offer our perspectives on remaining issues and future research needs.
authors.affiliation: State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China; University of Chinese Academy of Sciences, Beijing 100049, China. Electronic address: jilin2008yanli@163.com.
authors.forename: Li
authors.initials: L
authors.lastname: Yan
authors.affiliation: State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China; University of Chinese Academy of Sciences, Beijing 100049, China.
authors.forename: Shan
authors.initials: S
authors.lastname: Hu
authors.affiliation: State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China; University of Chinese Academy of Sciences, Beijing 100049, China. Electronic address: cyjing@rcees.ac.cn.
authors.forename: Chuanyong
authors.initials: C
authors.lastname: Jing
mesh_terms: D000327:Adsorption; D001151:Arsenic / Q000032:analysis / Q000737:chemistry*; D005374:Filtration / Q000295:instrumentation / Q000379:methods; D060587:Groundwater / Q000737:chemistry; D007700:Kinetics; D008956:Models, Chemical; D014025:Titanium / Q000737:chemistry; D014865:Waste Disposal, Fluid / Q000379:methods; D062065:Wastewater / Q000032:analysis; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000737:chemistry*; D018508:Water Purification / Q000379:methods*
chemical_list: D001151:Arsenic; D014025:Titanium; D062065:Wastewater; D014874:Water Pollutants, Chemical
keywords: Arsenic; CD-MUSIC; Coexisting ions; PHREEQC; Regeneration; TiO(2) adsorbent