title: High oxidation state bromocarbyne complexes.
abstract: Bromination of the carbyne complexes [W([triple bond, length as m-dash]CR)Br(CO)2(dcpe)] (R = Ph, SiPh3; dcpe = 1,2-bis(dicyclohexylphosphino)ethane) provides high oxidation state derivatives [W([triple bond, length as m-dash]CPh)Br3(dcpe)] and [W([triple bond, length as m-dash]CBr)Br3(dcpe)], the latter via an unprecedented bromodesilylation process.
authors.affiliation: Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory ACT 2601, Australia. a.hill@anu.edu.au.
authors.forename: Anthony F
authors.identifier: http://orcid.org/0000-0003-2167-0604
authors.initials: AF
authors.lastname: Hill
authors.affiliation: Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory ACT 2601, Australia. a.hill@anu.edu.au.
authors.forename: Richard Y
authors.identifier: http://orcid.org/0000-0001-7891-9621
authors.initials: RY
authors.lastname: Kong