title: Combination of Cp*RhIII-Catalyzed C-H Activation and a Wagner-Meerwein-Type Rearrangement.
abstract: A combination of Cp*RhIII-catalyzed C-H activation and Wagner-Meerwein-type rearrangement was successfully achieved for the first time. Thus, bridged polycyclic molecules that are not readily accessible by other means were accessed under mild conditions with high efficiency (as low as 0.5 mol % Rh catalyst) in the coupling of N-phenoxyacetamide with 7-azabenzonorbornadiene.
authors.affiliation: Westfälische Wilhelms-Universität Münster, Organisch-Chemisches Institut, Corrensstrasse 40, 48149, Münster, Germany.
authors.forename: Xiaoming
authors.identifier: 0000-0001-7981-3757
authors.initials: X
authors.lastname: Wang
authors.affiliation: Westfälische Wilhelms-Universität Münster, Organisch-Chemisches Institut, Corrensstrasse 40, 48149, Münster, Germany.
authors.forename: Andreas
authors.initials: A
authors.lastname: Lerchen
authors.affiliation: Westfälische Wilhelms-Universität Münster, Organisch-Chemisches Institut, Corrensstrasse 40, 48149, Münster, Germany.
authors.forename: Tobias
authors.identifier: 0000-0002-1937-0285
authors.initials: T
authors.lastname: Gensch
authors.affiliation: Westfälische Wilhelms-Universität Münster, Organisch-Chemisches Institut, Corrensstrasse 40, 48149, Münster, Germany.
authors.forename: Tobias
authors.initials: T
authors.lastname: Knecht
authors.affiliation: Westfälische Wilhelms-Universität Münster, Organisch-Chemisches Institut, Corrensstrasse 40, 48149, Münster, Germany.
authors.forename: Constantin G
authors.initials: CG
authors.lastname: Daniliuc
authors.affiliation: Westfälische Wilhelms-Universität Münster, Organisch-Chemisches Institut, Corrensstrasse 40, 48149, Münster, Germany.
authors.forename: Frank
authors.identifier: 0000-0002-0648-956X
authors.initials: F
authors.lastname: Glorius
keywords: C−H activation; RhIII catalysis; Wagner-Meerwein rearrangement; azabicyclic alkenes