title: Pattern-Directed Ordering of Spin-Dewetted Liquid Crystal Micro- or Nanodroplets as Pixelated Light Reflectors and Locomotives.
abstract: Chemical pattern directed spin-dewetting of a macroscopic droplet composed of a dilute organic solution of liquid crystal (LC) formed an ordered array of micro- and nanoscale LC droplets. Controlled evaporation of the spin-dewetted droplets through vacuum drying could further miniaturize the size to the level of ∼90 nm. The size, periodicity, and spacing of these mesoscale droplets could be tuned with the variations in the initial loading of LC in the organic solution, the strength of the centripetal force on the droplet, and the duration of the evaporation. A simple theoretical model was developed to predict the spacing between the spin-dewetted droplets. The patterned LC droplets showed a reversible phase transition from nematic to isotropic and vice versa with the periodic exposure of a solvent vapor and its removal. A similar phase transition behavior was also observed with the periodic increase or reduction of temperature, suggesting their usefulness as vapor or temperature sensors. Interestingly, when the spin-dewetted droplets were confined between a pair of electrodes and an external electric field was applied, the droplets situated at the hydrophobic patches showed light-reflecting properties under the polarization microscopy highlighting their importance in the development of micro- or nanoscale LC displays. The digitized LC droplets, which were stationary otherwise, showed dielectrophoretic locomotion under the guidance of the external electric field beyond a threshold intensity of the field. Remarkably, the motion of these droplets could be restricted to the hydrophilic zones, which were confined between the hydrophobic patches of the chemically patterned surface. The findings could significantly contribute in the development of futuristic vapor or temperature sensors, light reflectors, and self-propellers using the micro- or nanoscale digitized LC droplets.
authors.affiliation: Department of Chemical Engineering, Indian Institute of Technology Guwahati , Guwahati, Assam 781039, India.
authors.forename: Bolleddu
authors.initials: B
authors.lastname: Ravi
authors.affiliation: Department of Chemical Engineering, Indian Institute of Technology Guwahati , Guwahati, Assam 781039, India.
authors.forename: Snigdha
authors.initials: S
authors.lastname: Chakraborty
authors.affiliation: Centre for Nanotechnology, Indian Institute of Technology Guwahati , Guwahati, Assam 781039, India.
authors.forename: Mitradip
authors.initials: M
authors.lastname: Bhattacharjee
authors.affiliation: Department of Chemical Engineering, Indian Institute of Technology Guwahati , Guwahati, Assam 781039, India.
authors.forename: Shirsendu
authors.initials: S
authors.lastname: Mitra
authors.affiliation: Department of Chemical Engineering, Indian Institute of Technology Kanpur , Kanpur, Uttar Pradesh 208016, India.
authors.forename: Abir
authors.initials: A
authors.lastname: Ghosh
authors.affiliation: Department of Chemical Engineering, Indian Institute of Technology Guwahati , Guwahati, Assam 781039, India.|Centre for Nanotechnology, Indian Institute of Technology Guwahati , Guwahati, Assam 781039, India.
authors.forename: Partho Sarathi
authors.initials: PS
authors.lastname: Gooh Pattader
authors.affiliation: Department of Chemical Engineering, Indian Institute of Technology Guwahati , Guwahati, Assam 781039, India.|Centre for Nanotechnology, Indian Institute of Technology Guwahati , Guwahati, Assam 781039, India.
authors.forename: Dipankar
authors.identifier: http://orcid.org/0000-0002-9703-5300
authors.initials: D
authors.lastname: Bandyopadhyay
keywords: electric field; liquid crystal; locomotion; nanodroplet; spin-dewetting