title: Catalytic Enantioselective Arylboration of Alkenylarenes.
abstract: A method for the catalytic enantioselective arylboration of alkenylarenes is disclosed. The reaction leads to the formation of 1,1-diarylalkanes that also incorporate an additional pinacol boronic ester which can be easily transformed to a variety of groups. The products are formed with excellent diastereoselectivities and enantioselectivities.
authors.affiliation: Department of Chemistry, Indiana University, 800 E. Kirkwood Ave., Bloomington, IN, 47401, USA.
authors.forename: Kaitlyn M
authors.initials: KM
authors.lastname: Logan
authors.affiliation: Department of Chemistry, Indiana University, 800 E. Kirkwood Ave., Bloomington, IN, 47401, USA.
authors.forename: M Kevin
authors.initials: MK
authors.lastname: Brown
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D001896:Boron Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000475:Alkenes; D001896:Boron Compounds; D009942:Organometallic Compounds; D010165:Palladium; D003300:Copper
keywords: alkenes; copper; cross-coupling; enantioselective catalysis; palladium