title: Differences between graphene and graphene oxide in gelatin based systems for transient biodegradable energy storage applications.
abstract: A comparison between graphene flakes and graphene oxide as filler in gelatin based systems for low-cost transient biodegradable energy storage applications has been carried out. The two bio-composites have been prepared and characterized by rheological measurements, cyclic voltammetry measurements, chronopotentiometry measurements and impedance spectroscopy. Differences in dielectric and mechanical properties have been correlated to the different structural organizations determinate by the hydrophobic/hydrophilic character of the used filler. In particular, the addition of the graphene oxide to the gelatin causes an increase in the elastic modulus with a parallel increase in the mechanical stability with time as compared to the composites obtained by adding graphene. Conversely, the surface capacitance is slightly increased by the graphene oxide addition compared to the pure gelatin sample. On the other hand, the introduction of the graphene flakes into the gelatin leads to a marked increase of the dielectric properties of the resulting bio-composite.
authors.affiliation: Department of Industrial Engineering, University of Salerno, Via G. Paolo II 132, 84084 Fisciano (SA), Italy. Institute for Polymers, Composites and Biomaterials (IPCB-CNR), Piazzale Enrico Fermi 1, 80055 Portici (NA), Italy.
authors.forename: G
authors.initials: G
authors.lastname: Landi
authors.forename: A
authors.initials: A
authors.lastname: Sorrentino
authors.forename: S
authors.initials: S
authors.lastname: Iannace
authors.forename: H C
authors.initials: HC
authors.lastname: Neitzert