title: Hydrogen Uptake by an Inclined Polycatenated Dynamic Metal-Organic Framework Based Material.
abstract: A 2D + 2D → 3D inclined polycatenated dynamic metal-organic framework of {[Cu(4-bpe)(2-ntp)(H2O)2]·2H2O}n[1, where 2-ntp2-= 2-nitroterephthalate and 4-bpe = 1,2-bis-(4-pyridyl)ethane] has been synthesized and characterized. The variable-temperature powder X-ray diffraction study indicates the dynamic nature of the inclined polycatenated framework, and the dehydrated framework with exposed metal centers exhibits excellent type I H2adsorption of 1.94 wt % at 77 K and 1 bar of pressure.
authors.affiliation: Department of Chemistry, Jadavpur University , Jadavpur, Kolkata 700 032, India.
authors.forename: Dilip Kumar
authors.initials: DK
authors.lastname: Maity
authors.affiliation: Department of Chemistry, Jadavpur University , Jadavpur, Kolkata 700 032, India.
authors.forename: Arijit
authors.initials: A
authors.lastname: Halder
authors.affiliation: Department of Chemistry, Jadavpur University , Jadavpur, Kolkata 700 032, India.
authors.forename: Goutam
authors.initials: G
authors.lastname: Pahari
authors.affiliation: Department of Chemistry, Jadavpur University , Jadavpur, Kolkata 700 032, India.
authors.forename: Fazle
authors.initials: F
authors.lastname: Haque
authors.affiliation: Department of Chemistry, Jadavpur University , Jadavpur, Kolkata 700 032, India.
authors.forename: Debajyoti
authors.identifier: http://orcid.org/0000-0001-8820-8209
authors.initials: D
authors.lastname: Ghoshal