title: Cobalt-Catalyzed Carbozincation of Ynamides.
abstract: An original cobalt-catalyzed ynamide carbozincation leading mainly to diverse 3-aryl enamides with mild reaction conditions and good functional-group tolerance has been developed. This reaction displays an excellent regio- and total stereoselectivity and opens the way to appealing synthetic applications. Moreover, this approach allows the selective synthesis of biologically relevant 3,5-disubstituted oxazolone frameworks.
authors.affiliation: Institute of Organic and Analytical Chemistry, ICOA UMR 7311 CNRS, Université d'Orléans , rue de Chartres, 45100 Orléans, France.
authors.forename: Romain
authors.initials: R
authors.lastname: Sallio
authors.affiliation: LCM, CNRS, Ecole polytechnique, Université Paris Saclay , 91128 Palaiseau Cedex, France.
authors.forename: Martin
authors.initials: M
authors.lastname: Corpet
authors.affiliation: Institute of Organic and Analytical Chemistry, ICOA UMR 7311 CNRS, Université d'Orléans , rue de Chartres, 45100 Orléans, France.
authors.forename: Loic
authors.initials: L
authors.lastname: Habert
authors.affiliation: Normandie Univ, UNIROUEN, INSA Rouen, CNRS , COBRA (UMR 6014), 76000 Rouen, France.
authors.forename: Muriel
authors.initials: M
authors.lastname: Durandetti
authors.affiliation: LCM, CNRS, Ecole polytechnique, Université Paris Saclay , 91128 Palaiseau Cedex, France.
authors.forename: Corinne
authors.initials: C
authors.lastname: Gosmini
authors.affiliation: Institute of Organic and Analytical Chemistry, ICOA UMR 7311 CNRS, Université d'Orléans , rue de Chartres, 45100 Orléans, France.
authors.forename: Isabelle
authors.initials: I
authors.lastname: Gillaizeau