title: An ultrastable zirconium-phosphonate framework as bifunctional catalyst for highly active CO2chemical transformation.
abstract: A zirconium-phosphonate network, as a bifunctional catalyst for carbon dioxide (CO2)/epoxide coupling reaction, exhibits very high activity that is superior to most documented metal-organic framework (MOF)-based catalysts. Furthermore, it possesses extraordinary tolerance to extremely harsh conditions, such as aqua regia. This paper describes the use of metal phosphonate as a new MOF applied to CO2transformation.
authors.affiliation: College of Chemistry and Chemical Engineering, Inner Mongolia University for the Nationalities, Tongliao 02800, P. R. China and State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, China. szm@ciac.ac.cn.
authors.forename: Chao-Ying
authors.initials: CY
authors.lastname: Gao
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, China. szm@ciac.ac.cn and University of Science and Technology of China, Hefei, Anhui 230026, China.
authors.forename: Jing
authors.initials: J
authors.lastname: Ai
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, China. szm@ciac.ac.cn.
authors.forename: Hong-Rui
authors.initials: HR
authors.lastname: Tian
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, China. szm@ciac.ac.cn.
authors.forename: Dai
authors.initials: D
authors.lastname: Wu
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, China. szm@ciac.ac.cn.
authors.forename: Zhong-Ming
authors.identifier: http://orcid.org/0000-0003-2894-6327
authors.initials: ZM
authors.lastname: Sun