title: A stable lithiated silicon-chalcogen battery via synergetic chemical coupling between silicon and selenium.
abstract: Li-ion batteries dominate portable energy storage due to their exceptional power and energy characteristics. Yet, various consumer devices and electric vehicles demand higher specific energy and power with longer cycle life. Here we report a full-cell battery that contains a lithiated Si/graphene anode paired with a selenium disulfide (SeS2) cathode with high capacity and long-term stability. Selenium, which dissolves from the SeS2cathode, was found to become a component of the anode solid electrolyte interphase (SEI), leading to a significant increase of the SEI conductivity and stability. Moreover, the replacement of lithium metal anode impedes unwanted side reactions between the dissolved intermediate products from the SeS2cathode and lithium metal and eliminates lithium dendrite formation. As a result, the capacity retention of the lithiated silicon/graphene-SeS2full cell is 81% after 1,500 cycles at 268 mA gSeS2-1. The achieved cathode capacity is 403 mAh gSeS2-1(1,209 mAh cmSeS2-3).
authors.affiliation: Center for Innovative Fuel Cell and Battery Technologies, School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive, NW, Atlanta, Georgia 30332, USA.|School of Materials Science and Engineering, Gwangju Institute of Science Technology (GIST), 123 Cheomdangwagi-ro, Buk-gu, Gwangju 61005, South Korea.
authors.forename: KwangSup
authors.initials: K
authors.lastname: Eom
authors.affiliation: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA.
authors.forename: Jung Tae
authors.initials: JT
authors.lastname: Lee
authors.affiliation: Department of Inorganic Chemistry, Dresden University of Technology, Bergstrasse 66, 01069 Dresden, Germany.
authors.forename: Martin
authors.initials: M
authors.lastname: Oschatz
authors.affiliation: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA.
authors.forename: Feixiang
authors.initials: F
authors.lastname: Wu
authors.affiliation: Department of Inorganic Chemistry, Dresden University of Technology, Bergstrasse 66, 01069 Dresden, Germany.
authors.forename: Stefan
authors.initials: S
authors.lastname: Kaskel
authors.affiliation: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA.
authors.forename: Gleb
authors.initials: G
authors.lastname: Yushin
authors.affiliation: Center for Innovative Fuel Cell and Battery Technologies, School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive, NW, Atlanta, Georgia 30332, USA.
authors.forename: Thomas F
authors.initials: TF
authors.lastname: Fuller