title: A path for synthesis of boron-nitride nanostructures in volume of arc plasma.
abstract: We find a possible channel for direct nanosynthesis of boron-nitride (BN) nanostructures, including growth of BN nanotubes from a mixture of BN diatomic molecules by quantum-classical molecular dynamics simulations. No catalyst or boron nanoparticle is needed for this synthesis, however the conditions for the synthesis of each of the nanostructures, such as temperature and flux of the BN feedstock are identified and are compatible with the conditions in an electric arc at high pressure. We also find that BN nanostructures can be synthetized by feeding a boron nanoparticle by BN diatomic molecules, however if hydrogen rich molecules like NH3or HBNH are used as a feedstock, two-dimensional nanoflake stable structures are formed.
authors.affiliation: Institute for Advanced Computational Science and Department of Materials Science and Engineering, State University of New York at Stony Brook, Stony Brook, NY 11794-5250, United States.
authors.forename: Longtao
authors.initials: L
authors.lastname: Han
authors.forename: Predrag
authors.initials: P
authors.lastname: Krstić