title: Molecular Crystal Engineering: Tuning Organic Semiconductor from p-type to n-type by Adjusting Their Substitutional Symmetry.
abstract: Focusing on the bottleneck of molecularly engineered organic semiconductors, a breakthrough is made to tune the electronic properties of organic semiconductors from p-type to n-type by using fluorinated metal phthalocyanines as examples. The experimentally observed p-type to n-type transition characteristics of single-crystal field-effect devices result from a combination of extrinsic and intrinsic properties of materials with different fluoridation substitution.
authors.affiliation: Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, School of Science, Tianjin University and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China.|School of Materials Science and Engineering, Nanyang Technological University, 639798, Singapore.
authors.forename: Hui
authors.initials: H
authors.lastname: Jiang
authors.affiliation: School of Materials Science and Engineering, Nanyang Technological University, 639798, Singapore.
authors.forename: Peng
authors.initials: P
authors.lastname: Hu
authors.affiliation: Institute of High Performance Computing, Agency for Science, Technology and Research, 138632, Singapore.
authors.forename: Jun
authors.initials: J
authors.lastname: Ye
authors.affiliation: Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 639798, Singapore.
authors.forename: Yongxin
authors.initials: Y
authors.lastname: Li
authors.affiliation: School of Materials Science and Engineering, Nanyang Technological University, 639798, Singapore.
authors.forename: Henan
authors.initials: H
authors.lastname: Li
authors.affiliation: Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, School of Science, Tianjin University and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China.
authors.forename: Xiaotao
authors.initials: X
authors.lastname: Zhang
authors.affiliation: Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, School of Science, Tianjin University and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China.
authors.forename: Rongjin
authors.initials: R
authors.lastname: Li
authors.affiliation: Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
authors.forename: Huanli
authors.initials: H
authors.lastname: Dong
authors.affiliation: Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, School of Science, Tianjin University and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China.|Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
authors.forename: Wenping
authors.initials: W
authors.lastname: Hu
authors.affiliation: School of Materials Science and Engineering, Nanyang Technological University, 639798, Singapore.
authors.forename: Christian
authors.initials: C
authors.lastname: Kloc
keywords: metal phthalocyanines; mobility; organic field-effect transistor; organic single crystal