title: Cobalt sulfide nanoparticles anchored in three-dimensional carbon nanosheet networks for lithium and sodium ion batteries with enhanced electrochemical performance.
abstract: In order to improve the conductivity and electrochemical activity, Co9S8nanoparticles anchored in three-dimensional carbon nanosheet networks (3D Co9S8@CNNs) are fabricated by a simple strategy with the assistance of NaCl. Combining the advantages of nanoscale and porous structure, 3D Co9S8@CNNs can retard the aggregation of Co9S8nanoparticles, provide abundant electrochemical active sites, as well as accommodate the mechanical stress during the cycling of lithium ion batteries (LIBs) or sodium ion batteries (SIBs). Thus, when evaluated as an anode for LIBs, the as-prepared 3D Co9S8@CNNs electrode exhibits outstanding electrochemical performance with a high reversible capacity of 935mAhg-1after 200 cycles at 0.25Ag-1. As for SIBs, it also delivers superior cycling stability with a capacity of 249mAhg-1after 50 cycles at 0.1Ag-1. These results demonstrate that 3D Co9S8@CNNs composite has potential to be utilized as an anode material for LIBs/SIBs with enhanced electrochemical performance.
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), College of Chemistry & Materials Science, Northwest University, Xi'an 710069, PR China.
authors.forename: Xing
authors.initials: X
authors.lastname: Zhang
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), College of Chemistry & Materials Science, Northwest University, Xi'an 710069, PR China. Electronic address: huiwang@nwu.edu.cn.
authors.forename: Hui
authors.initials: H
authors.lastname: Wang
authors.affiliation: National Key Laboratory of Photoelectric Technology and Functional Materials (Culture Base), National Photoelectric Technology and Functional Materials & Application International Cooperation Base, Institute of Photonics & Photon-Technology, Northwest University, Xi'an 710069, PR China. Electronic address: gangwang@nwu.edu.cn.
authors.forename: Gang
authors.initials: G
authors.lastname: Wang
keywords: 3D networks; Anode material; Batteries; Co(9)S(8); Electrochemical performance