title: Ultrasonic-assisted synthesis of phosphorus graphene oxide/poly (vinyl alcohol) polymer and surface resistivity research of phosphorus graphene oxide/poly (vinyl alcohol) film.
abstract: In this paper, phosphorus graphene oxide/poly (vinyl alcohol) polymer (PGO/PVA polymer) was synthesized by PGO and PVA via the esterification in the case of faint acidity and the ultrasound irradiation and characterized; moreover, phosphorus graphene oxide/poly (vinyl alcohol) film (PGO/PVA film) was prepared by PGO/PVA polymer and characterized; also, the surface resistivity of PGO/PVA film was investigated in the case of the different amount of PGO. Based on those, it had been found that PGO reacted with PVA to produce PGO/PVA polymer via the esterification under the ultrasonic-assisted condition, and PGO/PVA polymer was structured by 2D lattice of PGO and the chain of PVA connected in the form of six-member lactone ring and phosphonic ester, and PGO/PVA film was constituted by PGO/PVA polymer, and surface resistivity of 0.00, 0.75, 1.50, 2.25 and 3.00wt% of PGO/PVA film were 6.85×108, 2.98×108, 1.42×106, 7.66×104and 1.29×105Ω/sq, respectively.
authors.affiliation: College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang 050024, PR China.
authors.forename: Jihui
authors.initials: J
authors.lastname: Li
authors.affiliation: College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang 050024, PR China. Electronic address: chemliys@163.com.
authors.forename: Yongshen
authors.initials: Y
authors.lastname: Li
authors.affiliation: College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang 050024, PR China.
authors.forename: Shuai
authors.initials: S
authors.lastname: Niu
authors.affiliation: The Real Estate CO., Ltd. of CSCEC Beijing, 100070, PR China.
authors.forename: Ning
authors.initials: N
authors.lastname: Li
keywords: Phosphorus graphene oxide poly (vinyl alcohol) polymer (PGO/PVA polymer); Phosphorus graphene oxide/poly (vinyl alcohol) film (PGO/PVA film); Surface resistivity; Ultrasound-assisted condition