title: Improved synthesis of aluminium nanoparticles using ultrasound assisted approach and subsequent dispersion studies in di-octyl adipate.
abstract: The present work reports on an efficient and simple one pot synthetic approach for aluminium nanoflakes and nanoparticles based on the intensification using ultrasound and provides a comparison with the conventional approach to establish the cutting edge process benefits. In situ passivation of aluminium particles with oleic acid was used as the method of synthesis in both the conventional and ultrasound assisted approaches. The aluminium nanoflakes prepared using the ultrasound assisted approach were subsequently dispersed in di-octyl adipate (DOA) and it was demonstrated that a stable dispersion of aluminium nanoflakes into di-octyl adipate (DOA) is achieved. The morphology of the synthesized material was established using the transmission electron microscopy (TEM) analysis and energy dispersive X-ray analysis (EDX) and the obtained results confirmed the metal state and nano size range of the obtained aluminium nanoflakes and particles. The stability of the aluminium nanoflakes obtained using ultrasound assisted approach and nanoparticles using conventional approach were characterized using the zeta potential analysis and the obtained values were in the range of -50 to +50mV and -100 to +30mV respectively. The obtained samples from both the approaches were also characterized using X-ray diffraction (XRD) and particle size analysis (PSA) to establish the crystallite size and particle distribution. It was observed that the particle size of the aluminium nanoflakes obtained using ultrasound assisted approach was in the range of 7-11nm whereas the size of aluminium nanoparticles obtained using conventional approach was much higher in the range of 1000-3000nm. Overall it was demonstrated that the aluminium nanoflakes obtained using the ultrasound assisted approach showed excellent morphological characteristics and dispersion stability in DOA showing promise for the high energy applications.
authors.affiliation: Chemical Engineering Department, National Institute of Technology, Warangal 506 004, India.
authors.forename: S
authors.initials: S
authors.lastname: Shabana
authors.affiliation: Chemical Engineering Department, National Institute of Technology, Warangal 506 004, India.
authors.forename: S H
authors.initials: SH
authors.lastname: Sonawane
authors.affiliation: Soild Propellant Plant, Satish Dhawan Space Centre-SHAR, ISRO, Sriharikota, India.
authors.forename: V
authors.initials: V
authors.lastname: Ranganathan
authors.affiliation: Respond/R&D, Satish Dhawan Space Centre -SHAR, ISRO, Sriharikota, India.
authors.forename: P H
authors.initials: PH
authors.lastname: Pujjalwar
authors.affiliation: Chemical Engineering Department, Institute of Chemical Technology, Mumbai, India.
authors.forename: D V
authors.initials: DV
authors.lastname: Pinjari
authors.affiliation: Department of Chemical Engineering, Laxminarayan Institute of Technology, Rashtrasant Tukadoji Maharaj Nagpur University, Nagpur 440033, MS, India.
authors.forename: B A
authors.initials: BA
authors.lastname: Bhanvase
authors.affiliation: Chemical Engineering Department, Institute of Chemical Technology, Mumbai, India.
authors.forename: P R
authors.initials: PR
authors.lastname: Gogate
authors.affiliation: Department of Chemistry, University of Melbourne, VIC, Australia.
authors.forename: Muthupandian
authors.initials: M
authors.lastname: Ashokkumar
keywords: Aluminium nanoparticles; Di-octyl adipate; Dispersion; Oleic acid; Process intensification; Ultrasound