title: Free-Radical Bromotrifluoromethylation of Olefin via Single-Electron Oxidation of NaSO2CF3by NaBrO3.
abstract: A free-radical bromotrifluoromethylation of olefin by using NaSO2CF3and NaBrO3has been achieved. Sodium bromate acts not only as a single-electron oxidant but also as a bromine source. A radical-clock experiment and electron-spin-resonance detection support a radical process.
authors.affiliation: School of Petrochemical Engineering, Institute for Natural and Synthetic Organic Chemistry, Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Changzhou University , Changzhou 213164, P. R. China.|State Key Laboratory of Applied Organic Chemistry, Lanzhou University , Lanzhou, Gansu 730000, P. R. China.
authors.forename: Zhong-Quan
authors.identifier: 0000-0001-6961-0585
authors.initials: ZQ
authors.lastname: Liu
authors.affiliation: State Key Laboratory of Applied Organic Chemistry, Lanzhou University , Lanzhou, Gansu 730000, P. R. China.
authors.forename: Dong
authors.initials: D
authors.lastname: Liu