title: Magnetic-epichlorohydrin crosslinked chitosan schiff's base (m-ECCSB) as a novel adsorbent for the removal of Cu(II) ions from aqueous environment.
abstract: Metal ions cause a serious public health problem. It is a great challenge to find an effective and efficient adsorbent to remove heavy metals from wastewater. Chitosan-based adsorbents are potential and effective for heavy metal ion removal. Hence a novel m-ECCSB was synthesized, characterized and utilized as an adsorbent for the removal of Cu(II) ions from aqueous solution. Various factors affecting the uptake behavior such as pH, adsorbent dosage, contact time, initial concentration of Cu(II) and temperature effect were investigated. Maximum adsorption capability (123.10mg/g) was obtained at pH=6, adsorbent dose of=250mg, rotational speed=200rpm, contact time=60min, and temperature of 323K. The result of the kinetic study shows that the adsorption of Cu(II) could be described by the pseudo-second-order equation. Equilibrium data were analysed with the Langmuir, Freundlich and Dubinin-Radushkevich isotherms and Langmuir model was found to provide the best fit of the experimental data. The thermodynamic parameters showed that the adsorption of Cu(II) onto m-ECCSB was spontaneous (ΔG°=-8.990, -10.00 and -10.593kJ/mol), endothermic (ΔH°=15.674, 15.478 and 15.699kJ/mol) and ΔS° (0.0814J/molK) suggests an increased randomness at the solid/solution interface under the studied conditions.
authors.affiliation: School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, PR China.
authors.forename: Yuvaraja
authors.initials: Y
authors.lastname: Gutha
authors.affiliation: School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, PR China.
authors.forename: Yaping
authors.initials: Y
authors.lastname: Zhang
authors.affiliation: School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, PR China.
authors.forename: Weijiang
authors.initials: W
authors.lastname: Zhang
authors.affiliation: School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, PR China. Electronic address: 158047@tju.edu.cn.
authors.forename: Xu
authors.initials: X
authors.lastname: Jiao
mesh_terms: D000327:Adsorption; D048271:Chitosan / Q000737:chemistry*; D003300:Copper / Q000737:chemistry* / Q000302:isolation & purification*; D004811:Epichlorohydrin / Q000737:chemistry*; D005290:Ferric Compounds / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D059346:Magnets / Q000737:chemistry*; D012545:Schiff Bases / Q000737:chemistry; D013696:Temperature; D062065:Wastewater / Q000737:chemistry; D014867:Water / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000302:isolation & purification; D018508:Water Purification
chemical_list: D048271:Chitosan; D003300:Copper; D004811:Epichlorohydrin; D005290:Ferric Compounds; D012545:Schiff Bases; D062065:Wastewater; D014867:Water; D014874:Water Pollutants, Chemical; C000499:ferric oxide
keywords: Chitosan; Cu(II) removal; Epichlorohydrin; Fe(3)O(4); thiophene-2-carboxaldehyde