title: Enhancing the low-energy absorption band and charge mobility of antiaromatic NiIInorcorroles by their substituent effects.
abstract: Dissymmetrical substitution of norcorrole enables the preparation of various norcorrole derivatives as air- and moisture-stable species. Intramolecular charge transfer interactions between electron-donating substituents and the norcorrole core in these norcorroles significantly enhanced their low-energy absorption bands, which were forbidden in symmetrical NiIIdimesitylnorcorrole.
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan. hshino@apchem.nagoya-u.ac.jp.
authors.forename: Takuya
authors.initials: T
authors.lastname: Yoshida
authors.affiliation: Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan.
authors.forename: Daisuke
authors.initials: D
authors.lastname: Sakamaki
authors.affiliation: Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan.
authors.forename: Shu
authors.identifier: http://orcid.org/0000-0001-7851-4405
authors.initials: S
authors.lastname: Seki
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan. hshino@apchem.nagoya-u.ac.jp.
authors.forename: Hiroshi
authors.identifier: http://orcid.org/0000-0002-5321-2205
authors.initials: H
authors.lastname: Shinokubo