title: Synthesis of Cu/Cu2O hydrides for enhanced removal of iodide from water.
abstract: In order to improve the removal capacity of Cu2O for I-anions from water, Cu/Cu2O hybrids have been synthesized through a facile hydrothermal route, characterized by using SEM, XRD, XPS, and applied to remove I-anions under different experimental environments. The results demonstrate that the Cu content and morphology of samples can be tuned by the adding amount of ammonia. Meanwhile, the possible crystalline mechanism, Cu2O formed firstly and then metallic Cu generated, was presented. With the increasing of Cu doped amount, the removal capacity of Cu/Cu2O hybrids increased significantly from 0.02mmolg-1to 0.18mmolg-1. Furthermore, a reaction mechanism of I-anions and Cu2O, which generated from the disproportionation reaction of metallic Cu and CuO, has been proposed according to the characterization analyses of the composites before and after adsorption, explaining the highly efficient removal of I-anions. In addition, Cu/Cu2O hybrids showed excellent selectivity for I-anions in the presence of large concentrations of competitive anions such as SO42-and NO3-and could work in an acidic and neutral environment. This study is hopefully to prompt Cu2O to grow up to be a new and highly efficient adsorbent for the removal of iodide from solutions.
authors.affiliation: School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
authors.forename: Ping
authors.initials: P
authors.lastname: Mao
authors.affiliation: Beijing National Laboratory for Molecular Sciences, Fundamental Science Laboratory on Radiochemistry & Radiation Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
authors.forename: Liye
authors.initials: L
authors.lastname: Qi
authors.affiliation: School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China. Electronic address: liuxd@njust.edu.cn.
authors.forename: Xiaodong
authors.initials: X
authors.lastname: Liu
authors.affiliation: School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
authors.forename: Ying
authors.initials: Y
authors.lastname: Liu
authors.affiliation: Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials (CEM), School of Environmental Sciences and Engineering, Nanjing University of Information Science and Technology, Nanjing 210004, China.
authors.forename: Yan
authors.initials: Y
authors.lastname: Jiao
authors.affiliation: School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
authors.forename: Shouwen
authors.initials: S
authors.lastname: Chen
authors.affiliation: School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China. Electronic address: yyi301@163.com.
authors.forename: Yi
authors.initials: Y
authors.lastname: Yang
keywords: Chemical adsorption; Cu/Cu(2)O; Hydrothermal route; Radioactive iodide; Removal capacity