title: Metal-Organic Frameworks for Thin-Layer Chromatographic Applications.
abstract: Preparation of thin-layer chromatographic (TLC) plates based on metal-organic frameworks (MOFs) as porous stationary phases is described. DUT-67 (DUT = Dresden University of Technology), a zirconium based MOF, was used in combination with a fluorescent indicator as stationary phase for analyzing a small selection of a wide spectrum of relevant analytes. The successful separation of benzaldehyde from trans-cinnamaldehyde and 4-aminophenol from 2-aminotoluene is reported as a model system using optimized eluent mixtures containing acetic acid.
authors.affiliation: Inorganic Chemistry I, Technische Universität Dresden , Bergstrasse 66, 01062 Dresden, Germany.
authors.forename: Claudia
authors.initials: C
authors.lastname: Schenk
authors.affiliation: Inorganic Chemistry I, Technische Universität Dresden , Bergstrasse 66, 01062 Dresden, Germany.
authors.forename: Christel
authors.initials: C
authors.lastname: Kutzscher
authors.affiliation: Inorganic Chemistry I, Technische Universität Dresden , Bergstrasse 66, 01062 Dresden, Germany.
authors.forename: Franziska
authors.initials: F
authors.lastname: Drache
authors.affiliation: Inorganic Chemistry I, Technische Universität Dresden , Bergstrasse 66, 01062 Dresden, Germany.
authors.forename: Stella
authors.initials: S
authors.lastname: Helten
authors.affiliation: Inorganic Chemistry I, Technische Universität Dresden , Bergstrasse 66, 01062 Dresden, Germany.
authors.forename: Irena
authors.identifier: http://orcid.org/0000-0001-7052-1029
authors.initials: I
authors.lastname: Senkovska
authors.affiliation: Inorganic Chemistry I, Technische Universität Dresden , Bergstrasse 66, 01062 Dresden, Germany.
authors.forename: Stefan
authors.initials: S
authors.lastname: Kaskel
keywords: DUT-67; TLC; metal−organic frameworks; planar chromatography; zirconium-based MOFs