title: Stereochemically Defined Various Multisubstituted Alkenes Bearing a Tetrafluoroethylene (-CF2CF2-) Fragment.
abstract: Highly regio- and stereoselective transformation of commercially available 4-bromo-3,3,4,4-tetrafluoro-1-butene into multisubstituted alkenes having a tetrafluoroethylene fragment through Heck reactions and/or Suzuki-Miyaura cross-coupling reactions was established. Thus, the obtained alkenes underwent a smooth reductive coupling reaction with aldehydes under the influence of MeLi/LiBr-free, affording structurally unprecedented fluorinated materials.
authors.affiliation: Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology , Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan.
authors.forename: Yukiho
authors.initials: Y
authors.lastname: Sakaguchi
authors.affiliation: Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology , Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan.
authors.forename: Shigeyuki
authors.initials: S
authors.lastname: Yamada
authors.affiliation: Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology , Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan.
authors.forename: Tsutomu
authors.identifier: 0000-0002-5146-9840
authors.initials: T
authors.lastname: Konno
authors.affiliation: Department of Materials Science, Ibaraki University , 4-12-1 Nakanarusawa, Hitachi 316-8511, Japan.
authors.forename: Tomohiro
authors.initials: T
authors.lastname: Agou
authors.affiliation: Department of Materials Science, Ibaraki University , 4-12-1 Nakanarusawa, Hitachi 316-8511, Japan.
authors.forename: Toshio
authors.initials: T
authors.lastname: Kubota