title: Rhodium(III)-Catalyzed Ortho Halogenations of N-Acylsulfoximines and Synthetic Applications toward Functionalized Sulfoximine Derivatives.
abstract: Rhodium(III)-catalyzed ortho brominations and iodinations of N-acylsulfoximines by C-H bond activations have been developed. Subsequent product functionalizations involving cross-coupling reactions provide alkynylated sulfoximine derivatives and benzothiazines with wide potential for further synthetic applications.
authors.affiliation: Institute of Organic Chemistry, RWTH Aachen University , Landoltweg 1, D-52074 Aachen, Germany.
authors.forename: Ying
authors.initials: Y
authors.lastname: Cheng
authors.affiliation: Institute of Organic Chemistry, RWTH Aachen University , Landoltweg 1, D-52074 Aachen, Germany.
authors.forename: Wanrong
authors.initials: W
authors.lastname: Dong
authors.affiliation: Institute of Organic Chemistry, RWTH Aachen University , Landoltweg 1, D-52074 Aachen, Germany.
authors.forename: Kanniyappan
authors.initials: K
authors.lastname: Parthasarathy
authors.affiliation: Institute of Organic Chemistry, RWTH Aachen University , Landoltweg 1, D-52074 Aachen, Germany.
authors.forename: Carsten
authors.identifier: 0000-0001-9415-9917
authors.initials: C
authors.lastname: Bolm