title: SnS2Nanowall Arrays toward High-Performance Sodium Storage.
abstract: Cost-effective sodium ion batteries (SIBs) are emerging as a desirable alternative choice to lithium ion batteries in terms of application in large-scale energy storage devices. SnS2is regarded as a potential anode material for SIBs because of its unique layered structure and high theoretical specific capacity. However, the development of SnS2was hindered by the sluggish kinetics of the diffusion process and the inevitable volume change during repeated sodiation-desodiation processes. In this work, SnS2with a unique nanowall array (NWA) structure is fabricated by one-step pulsed spray evaporation chemical vapor deposition (PSE-CVD), which could be used directly as binder-free and carbon-free anodes for SIBs. The SnS2NWA electrode achieves a high reversible capacity of 576 mAh g-1at 500 mA g-1and enhanced cycling stability. Attractively, an excellent rate capability is demonstrated with ∼370 mAh g-1at 5 A g-1, corresponding to a capacity retention of 64.2% at 500 mA g-1. The superior sodium storage capability of the SnS2NWA electrode could be attributed to outstanding electrode design and a rational growth process, which favor fast electron and Na-ion transport, as well as provide steady structure for elongated cycling.
authors.affiliation: State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province and School of Materials Science and Engineering, Zhejiang University , Hangzhou, Zhejiang 310027, PR China.
authors.forename: Peng
authors.initials: P
authors.lastname: Zhou
authors.affiliation: State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province and School of Materials Science and Engineering, Zhejiang University , Hangzhou, Zhejiang 310027, PR China.
authors.forename: Xiao
authors.initials: X
authors.lastname: Wang
authors.affiliation: State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province and School of Materials Science and Engineering, Zhejiang University , Hangzhou, Zhejiang 310027, PR China.
authors.forename: Wenhao
authors.initials: W
authors.lastname: Guan
authors.affiliation: State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province and School of Materials Science and Engineering, Zhejiang University , Hangzhou, Zhejiang 310027, PR China.
authors.forename: Dan
authors.initials: D
authors.lastname: Zhang
authors.affiliation: State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province and School of Materials Science and Engineering, Zhejiang University , Hangzhou, Zhejiang 310027, PR China.
authors.forename: Libin
authors.initials: L
authors.lastname: Fang
authors.affiliation: State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province and School of Materials Science and Engineering, Zhejiang University , Hangzhou, Zhejiang 310027, PR China.|State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science , Fuzhou, Fujian 350002, PR China.
authors.forename: Yinzhu
authors.identifier: http://orcid.org/0000-0003-0639-2562
authors.initials: Y
authors.lastname: Jiang
keywords: PSE-CVD; SnS2 nanowall arrays; anode; rate capability; sodium ion batteries