title: Crystal structure ofcatena-poly[[bis-(N-acethyl-thio-morpholine-κS)copper(I)]-μ-iodido].
abstract: The reaction of copper(I) iodide withN-acetyl-thio-morpholine (L, C6H11NOS) in aceto-nitrile results in a coordination polymer with composition [CuI(L)2]n. The CuIatom is coordinated by two S atoms and two I atoms, adopting a distorted tetra-hedral environment. The μ2-bridging mode of the I atoms gives rise to chains extending parallel to [010]. C-H⋯O hydrogen-bonding inter-actions between the chains lead to a three-dimensional network.
authors.affiliation: Department of Chemistry (BK21 plus) and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 52828, Republic of Korea.
authors.forename: Hojae
authors.initials: H
authors.lastname: Chiang
authors.affiliation: Department of Chemistry (BK21 plus) and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 52828, Republic of Korea.
authors.forename: Tae Ho
authors.initials: TH
authors.lastname: Kim
authors.affiliation: Department of Chemistry (BK21 plus) and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 52828, Republic of Korea.
authors.forename: Hyunjin
authors.initials: H
authors.lastname: Park
authors.affiliation: Department of Chemistry (BK21 plus) and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 52828, Republic of Korea.
authors.forename: Jineun
authors.initials: J
authors.lastname: Kim
keywords: N-acetyl­thio­morpholine; coordination polymer; copper(I) iodide; crystal structure