title: Alignment of Carbon Nanotubes in Carbon Nanotube Fibers Through Nanoparticles: A Route for Controlling Mechanical and Electrical Properties.
abstract: This is the first study that describes how semiconducting ZnO can act as an alignment agent in carbon nanotubes (CNTs) fibers. Because of the alignment of CNTs through the ZnO nanoparticles linking groups, the CNTs inside the fibers were equally distributed by the attraction of bonding forces into sheetlike bunches, such that any applied mechanical breaking load was equally distributed to each CNT inside the fiber, making them mechanically robust against breaking loads. Although semiconductive ZnO nanoparticles were used here, the electrical conductivity of the aligned CNT fiber was comparable to bare CNT fibers, suggesting that the total electron movement through the CNTs inside the aligned CNT fiber is not disrupted by the insulating behavior of ZnO nanoparticles. A high degree of control over the electrical conductivity was also demonstrated by the ZnO nanoparticles, working as electron movement bridges between CNTs in the longitudinal and crosswise directions. Well-organized surface interface chemistry was also observed, which supports the notion of CNT alignment inside the fibers. This research represents a new area of surface interface chemistry for interfacially linked CNTs and ZnO nanomaterials with improved mechanical properties and electrical conductivity within aligned CNT fibers.
authors.forename: Muhammad Mohsin
authors.initials: MM
authors.lastname: Hossain
authors.affiliation: Department of Pharmacy, Atish Dipankar University of Science & Technology , Banani, Dhaka 1213, Bangladesh.
authors.forename: Md Akherul
authors.initials: MA
authors.lastname: Islam
authors.affiliation: Department of Chemistry, Rajshahi Univesity , Rajshahi 6205, Bangladesh.
authors.forename: Hossain
authors.initials: H
authors.lastname: Shima
authors.affiliation: Department of Chemical Engineering, King Khalid University , Abha 61411, Kingdom of Saudi Arabia.
authors.forename: Mudassir
authors.initials: M
authors.lastname: Hasan
authors.forename: Moonyong
authors.identifier: http://orcid.org/0000-0002-3218-1454
authors.initials: M
authors.lastname: Lee
keywords: ZnO nanoparticles; carbon nanotube fiber; electrical conductivity; interface chemistry; mechanical properties