title: Iron Oxide Films Prepared by Rapid Thermal Processing for Solar Energy Conversion.
abstract: Hematite is a promising and extensively investigated material for various photoelectrochemical (PEC) processes for energy conversion and storage, in particular for oxidation reactions. Thermal treatments during synthesis of hematite are found to affect the performance of hematite electrodes considerably. Herein, we present hematite thin films fabricated via one-step oxidation of Fe by rapid thermal processing (RTP). In particular, we investigate the effect of oxidation temperature on the PEC properties of hematite. Films prepared at 750 °C show the highest activity towards water oxidation. These films show the largest average grain size and the highest charge carrier density, as determined from electron microscopy and impedance spectroscopy analysis. We believe that the fast processing enabled by RTP makes this technique a preferred method for investigation of novel materials and architectures, potentially also on nanostructured electrodes, where retaining high surface area is crucial to maximize performance.
authors.affiliation: Department of Physics, Chalmers University of Technology, SE-42196 Göteborg, Sweden.
authors.forename: B
authors.initials: B
authors.lastname: Wickman
authors.affiliation: Center for electron nanoscopy, Technical University of Denmark, DK-2800 Kgs. Lyngby, Denmark.
authors.forename: A
authors.initials: A
authors.lastname: Bastos Fanta
authors.affiliation: Center for electron nanoscopy, Technical University of Denmark, DK-2800 Kgs. Lyngby, Denmark.
authors.forename: A
authors.initials: A
authors.lastname: Burrows
authors.affiliation: Department of Physics, Chalmers University of Technology, SE-42196 Göteborg, Sweden.
authors.forename: A
authors.initials: A
authors.lastname: Hellman
authors.affiliation: Center for electron nanoscopy, Technical University of Denmark, DK-2800 Kgs. Lyngby, Denmark.
authors.forename: J B
authors.initials: JB
authors.lastname: Wagner
authors.affiliation: Center for electron nanoscopy, Technical University of Denmark, DK-2800 Kgs. Lyngby, Denmark.
authors.forename: B
authors.initials: B
authors.lastname: Iandolo