title: Synthesis of Multisubstituted Allenes, Furans, and Pyrroles via Tandem Palladium-Catalyzed Substitution and Cycloisomerization.
abstract: A palladium-catalyzed propargyl substitution reaction of propargyl acetates with indium organothiolates is developed for the synthesis of multisubstituted allenyl sulfides. This procedure can be applied to the synthesis of multisubstituted furans and pyrroles via tandem palladium-catalyzed propargyl substitution and cycloisomerization reaction in one pot.
authors.affiliation: Department of Chemistry, Kangwon National University , Chuncheon 24341, Republic of Korea.
authors.forename: Taekyu
authors.initials: T
authors.lastname: Ryu
authors.affiliation: Department of Chemistry, Kangwon National University , Chuncheon 24341, Republic of Korea.
authors.forename: Dahan
authors.initials: D
authors.lastname: Eom
authors.affiliation: Department of Chemistry, Kangwon National University , Chuncheon 24341, Republic of Korea.
authors.forename: Seohyun
authors.initials: S
authors.lastname: Shin
authors.affiliation: Department of Chemistry, Kangwon National University , Chuncheon 24341, Republic of Korea.
authors.forename: Jeong-Yu
authors.initials: JY
authors.lastname: Son
authors.affiliation: Department of Chemistry, Kangwon National University , Chuncheon 24341, Republic of Korea.
authors.forename: Phil Ho
authors.identifier: 0000-0001-8377-1107
authors.initials: PH
authors.lastname: Lee