title: Titanium(III) Member of the Family of Trigonal Building Blocks with Scorpionate and Cyanide Ligands.
abstract: The titanium(III) cyanide compound [Et4N][Tp*Ti(CN)3] ([Et4N] = tetraethylamonium; Tp* = 3,5-dimethyltrispyrazolylhydroborate) is reported, which exhibits a trigonally distorted geometry. Magnetic data and ab initio calculations verified that the molecule is an S =1/2paramagnet and that it exhibits significant temperature-independent paramagnetism.
authors.affiliation: Department of Chemistry, Texas A&M University , College Station, Texas 77843, United States.
authors.forename: Andrew
authors.initials: A
authors.lastname: Brown
authors.affiliation: Department of Chemistry, Texas A&M University , College Station, Texas 77843, United States.
authors.forename: Mohamed
authors.initials: M
authors.lastname: Saber
authors.affiliation: School of Chemistry, University of Melbourne , Parkville, Victoria 3010, Australia.
authors.forename: Willem
authors.identifier: http://orcid.org/0000-0003-4880-4449
authors.initials: W
authors.lastname: Van den Heuvel
authors.affiliation: Department of Chemistry, Texas A&M University , College Station, Texas 77843, United States.
authors.forename: Kelsey
authors.initials: K
authors.lastname: Schulte
authors.affiliation: School of Chemistry, University of Melbourne , Parkville, Victoria 3010, Australia.
authors.forename: Alessandro
authors.initials: A
authors.lastname: Soncini
authors.affiliation: Department of Chemistry, Texas A&M University , College Station, Texas 77843, United States.
authors.forename: Kim R
authors.identifier: http://orcid.org/0000-0001-5728-7805
authors.initials: KR
authors.lastname: Dunbar