title: Crystal structure of bis-[cis-(1,4,8,11-tetra-aza-cyclo-tetra-deca-ne-κ4N)bis(thio-cyanato-κN)chrom-ium(III)] dichromate monohydrate from synchrotron X-ray diffraction data.
abstract: The structure of the complex salt,cis-[Cr(NCS)2(cyclam)]2[Cr2O7]·H2O (cyclam = 1,4,8,11-tetra-aza-cyclo-tetra-decane, C10H24N4), has been determined from synchrotron data. The asymmetric unit comprises of one [Cr(NCS)2(cyclam)]+cation, one half of a Cr2O72-anion (completed by inversion symmetry) and one half of a water mol-ecule (completed by twofold rotation symmetry). The CrIIIion is coordinated by the four cyclam N atoms and by two N atoms ofcis-arranged thio-cyanate anions, displaying a distorted octa-hedral coordination sphere. The Cr-N(cyclam) bond lengths are in the range 2.080 (2) to 2.097 (2) Å while the average Cr-N(NCS) bond length is 1.985 (4) Å. The macrocyclic cyclam moiety adopts thecis-V conformation. The bridging O atom of the dichromate anion is disordered around an inversion centre, leading to a bending of the Cr-O-Cr bridging angle [157.7 (3)°]; the anion has a staggered conformation. The crystal structure is stabilized by inter-molecular hydrogen bonds involving the cyclam N-H groups and water O-H groups as donor groups, and the O atoms of the Cr2O72-anion and water mol-ecules as acceptor groups, giving rise to a three-dimensional network.
authors.affiliation: Pohang Accelerator Laboratory, POSTECH, Pohang 37673, Republic of Korea.
authors.forename: Dohyun
authors.initials: D
authors.lastname: Moon
authors.affiliation: Department of Chemistry, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan.
authors.forename: Masahiro
authors.initials: M
authors.lastname: Takase
authors.affiliation: Department of Chemistry, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan.
authors.forename: Takashiro
authors.initials: T
authors.lastname: Akitsu
authors.affiliation: Department of Chemistry, Andong National University, Andong 36729, Republic of Korea.
authors.forename: Jong-Ha
authors.initials: JH
authors.lastname: Choi
keywords: chrom­ium(III) complex; cis-V conformation; crystal structure; cyclam; dichromate anion; hydrogen bonding; synchrotron radiation; thio­cyanate ligand