title: Regioselective Construction of α,α-Disubstituted Allylic Amines by the Ruthenium-Catalyzed Allylic Amination of Tertiary Allylic Acetates.
abstract: The ruthenium-catalyzed regioselective allylic amination of tertiary allylic acetates with several types of amines has been accomplished. The reaction was effectively catalyzed by Cp*RuCl2/5,5'-dimethyl-2,2'-bipyridine or its related ruthenium catalyst systems, and α,α-disubstituted allylic amines were formed as a single regioisomer in moderate to high yields.
authors.affiliation: Department of Chemistry, College of Humanities & Sciences, Nihon University , Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan.
authors.forename: Shota
authors.initials: S
authors.lastname: Mizuno
authors.affiliation: Department of Chemistry, College of Humanities & Sciences, Nihon University , Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan.
authors.forename: Shou
authors.initials: S
authors.lastname: Terasaki
authors.affiliation: Department of Chemistry, College of Humanities & Sciences, Nihon University , Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan.
authors.forename: Toru
authors.initials: T
authors.lastname: Shinozawa
authors.affiliation: Department of Chemistry, College of Humanities & Sciences, Nihon University , Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan.
authors.forename: Motoi
authors.identifier: 0000-0002-8341-6866
authors.initials: M
authors.lastname: Kawatsura