title: Diastereoselective Electrophilic α-Hydroxyamination of N-tert-Butanesulfinyl Imidates.
abstract: Diastereoselective α-hydroxyamination of N-tert-butanesulfinyl imidates using nitrosoarenes is reported. A catalytic amount of base effectively promotes the hydroxyamination reaction of α-aryl-substituted imidates, and the resulting α-hydroxyamino imidates can be transformed into a range of synthetically useful intermediates.
authors.affiliation: Key Laboratory of Plant Resources and Chemistry of Arid Zones, Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences , Urumqi 830011, China.|University of Chinese Academy of Sciences , Beijing 100049, China.
authors.forename: Peng-Ju
authors.initials: PJ
authors.lastname: Ma
authors.affiliation: Key Laboratory of Plant Resources and Chemistry of Arid Zones, Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences , Urumqi 830011, China.
authors.forename: Hui
authors.initials: H
authors.lastname: Liu
authors.affiliation: Key Laboratory of Plant Resources and Chemistry of Arid Zones, Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences , Urumqi 830011, China.
authors.forename: Chong-Dao
authors.identifier: 0000-0001-8968-0134
authors.initials: CD
authors.lastname: Lu
authors.affiliation: Key Laboratory of Plant Resources and Chemistry of Arid Zones, Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences , Urumqi 830011, China.
authors.forename: Yan-Jun
authors.initials: YJ
authors.lastname: Xu