title: Surface-mounted MOF templated fabrication of homochiral polymer thin film for enantioselective adsorption of drugs.
abstract: A self-polymerized chiral monomer 3,4-dihydroxy-l-phenylalanine (l-DOPA) has been introduced into the pores of an achiral surface-mounted metal organic framework (SURMOF), and then the homochiral poly(l-DOPA) thin film has been successfully formed after UV light irradiation and etching of the SURMOF. Remarkably, such a poly(l-DOPA) thin film exhibited enantioselective adsorption of naproxen. This study opened a SURMOF-templated approach for preparing porous polymer thin films.
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002, Fuzhou, P. R. China. zggu@fjirsm.ac.cn zhj@fjirsm.ac.cn.
authors.forename: Zhi-Gang
authors.identifier: http://orcid.org/0000-0001-6538-2917
authors.initials: ZG
authors.lastname: Gu
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002, Fuzhou, P. R. China. zggu@fjirsm.ac.cn zhj@fjirsm.ac.cn.
authors.forename: Wen-Qiang
authors.initials: WQ
authors.lastname: Fu
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002, Fuzhou, P. R. China. zggu@fjirsm.ac.cn zhj@fjirsm.ac.cn.
authors.forename: Min
authors.initials: M
authors.lastname: Liu
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002, Fuzhou, P. R. China. zggu@fjirsm.ac.cn zhj@fjirsm.ac.cn.
authors.forename: Jian
authors.initials: J
authors.lastname: Zhang
mesh_terms: D000327:Adsorption; D004295:Dihydroxyphenylalanine / Q000031:analogs & derivatives* / Q000737:chemistry; D000073396:Metal-Organic Frameworks / Q000737:chemistry*; D009288:Naproxen / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D016062:Porosity; D013237:Stereoisomerism; D013499:Surface Properties; D014466:Ultraviolet Rays
chemical_list: D000073396:Metal-Organic Frameworks; D011108:Polymers; C539838:poly(3,4-dihydroxyphenylalanine); D009288:Naproxen; D004295:Dihydroxyphenylalanine