title: Expedient and modular access to 2-azabicyclic architectures by iron-catalyzed dehydrative coupling of alcohol-bearing allylic lactams.
abstract: A high-yielding, cost-effective, modular and environmentally benign approach to [5,5]- or [6,5]-2-azabicyclic architectures bearing vicinal stereocenters, by Fe-catalyzed intramolecular dehydrative coupling of readily affordable alcohol-bearing allylic lactams is presented.
authors.affiliation: Department of Chemistry, Central Washington University, Ellensburg, WA 98926, USA. TimothyB@cwu.edu.
authors.forename: Katie
authors.initials: K
authors.lastname: Hovenkotter
authors.affiliation: Department of Chemistry, Central Washington University, Ellensburg, WA 98926, USA. TimothyB@cwu.edu.
authors.forename: Hannah
authors.initials: H
authors.lastname: Braunstein
authors.affiliation: Department of Chemistry, Central Washington University, Ellensburg, WA 98926, USA. TimothyB@cwu.edu.
authors.forename: Spencer
authors.initials: S
authors.lastname: Langevin
authors.affiliation: Department of Chemistry, Central Washington University, Ellensburg, WA 98926, USA. TimothyB@cwu.edu.
authors.forename: Timothy K
authors.identifier: http://orcid.org/0000-0002-4364-5664
authors.initials: TK
authors.lastname: Beng
mesh_terms: D000438:Alcohols / Q000737:chemistry*; D001108:Architecture; D001372:Aza Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D001643:Bridged Bicyclo Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D003681:Dehydration; D007501:Iron / Q000737:chemistry*; D007769:Lactams / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D000438:Alcohols; D001372:Aza Compounds; D001643:Bridged Bicyclo Compounds; D007769:Lactams; D007501:Iron