title: Reaction of Arynes with Vinyl Sulfoxides: Highly Stereospecific Synthesis of ortho-Sulfinylaryl Vinyl Ethers.
abstract: The reaction of in situ generated arynes with aryl vinyl sulfoxides provides ortho-arylsulfinylaryl vinyl ethers via aryne σ-bond insertion into the S-O-bond and concomitant stereospecific S-O-vinyl migration. The cascade allows preparing di- or trisubstituted vinyl ethers with excellent stereospecificity. The reactions proceed under mild conditions, the substrate scope is broad, and the products obtained are valuable.
authors.affiliation: Organisch-Chemisches Institut, Westfälische Wilhelms-Universität , Corrensstraβe 40, 48149 Münster, Germany.
authors.forename: Yuanming
authors.initials: Y
authors.lastname: Li
authors.affiliation: Organisch-Chemisches Institut, Westfälische Wilhelms-Universität , Corrensstraβe 40, 48149 Münster, Germany.
authors.forename: Armido
authors.identifier: 0000-0002-1706-513X
authors.initials: A
authors.lastname: Studer