title: Molecular Tuning of the Vibrational Thermal Transport Mechanisms in Fullerene Derivative Solutions.
abstract: Control over the thermal conductance from excited molecules into an external environment is essential for the development of customized photothermal therapies and chemical processes. This control could be achieved through molecule tuning of the chemical moieties in fullerene derivatives. For example, the thermal transport properties in the fullerene derivatives indene-C60monoadduct (ICMA), indene-C60bisadduct (ICBA), [6,6]-phenyl C61butyric acid methyl ester (PCBM), [6,6]-phenyl C61butyric acid butyl ester (PCBB), and [6,6]-phenyl C61butyric acid octyl ester (PCBO) could be tuned by choosing a functional group such that its intrinsic vibrational density of states bridge that of the parent molecule and a liquid. However, this effect has never been experimentally realized for molecular interfaces in liquid suspensions. Using the pump-probe technique time domain thermotransmittance, we measure the vibrational relaxation times of photoexcited fullerene derivatives in solutions and calculate an effective thermal boundary conductance from the opto-thermally excited molecule into the liquid. We relate the thermal boundary conductance to the vibrational modes of the functional groups using density of states calculations from molecular dynamics. Our findings indicate that the attachment of an ester group to a C60molecule, such as in PCBM, PCBB, and PCBO, provides low-frequency modes which facilitate thermal coupling with the liquid. This offers a channel for heat flow in addition to direct coupling between the buckyball and the liquid. In contrast, the attachment of indene rings to C60does not supply the same low-frequency modes and, thus, does not generate the same enhancement in thermal boundary conductance. Understanding how chemical functionalization of C60affects the vibrational thermal transport in molecule/liquid systems allows the thermal boundary conductance to be manipulated and adapted for medical and chemical applications.
authors.forename: Chester J
authors.identifier: 0000-0002-1354-4416
authors.initials: CJ
authors.lastname: Szwejkowski
authors.forename: Ashutosh
authors.initials: A
authors.lastname: Giri
authors.affiliation: Mechanical Engineering Department, United States Naval Academy , Annapolis, Maryland 21402, United States.
authors.forename: Ronald
authors.initials: R
authors.lastname: Warzoha
authors.forename: Brian F
authors.initials: BF
authors.lastname: Donovan
authors.affiliation: Advanced Materials Laboratory, Sandia National Laboratories , Albuquerque, New Mexico 87185, United States.|Department of Chemical and Biological Engineering, University of New Mexico , Albuquerque, New Mexico 87131, United States.
authors.forename: Bryan
authors.initials: B
authors.lastname: Kaehr
authors.forename: Patrick E
authors.initials: PE
authors.lastname: Hopkins
keywords: functionalized fullerene derivatives; molecule/liquid interfaces; thermal boundary conductance; time domain thermotransmittance; vibrational bridging