title: Amide-Ligand-Controlled Highly para-Selective Arylation of Monosubstituted Simple Arenes with Arylboronic Acids.
abstract: Pd-catalyzed highly para-selective arylations of monosubstituted simple arenes with arylboronic acids to widely existed biaryls have been developed. Inspired by requisite amide-directing groups in reported selective oxidative couplings, amide ligands, especially DMF, are designed and found to be critical for the selectivity control in current arylations.
authors.affiliation: State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University , Tianjin 300071, China.
authors.forename: Yu-Xin
authors.initials: YX
authors.lastname: Luan
authors.affiliation: State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University , Tianjin 300071, China.
authors.forename: Tao
authors.initials: T
authors.lastname: Zhang
authors.affiliation: State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University , Tianjin 300071, China.
authors.forename: Wei-Wei
authors.initials: WW
authors.lastname: Yao
authors.affiliation: State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University , Tianjin 300071, China.
authors.forename: Ke
authors.initials: K
authors.lastname: Lu
authors.affiliation: State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University , Tianjin 300071, China.
authors.forename: Lu-Yao
authors.initials: LY
authors.lastname: Kong
authors.affiliation: State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University , Tianjin 300071, China.
authors.forename: Yu-Tong
authors.initials: YT
authors.lastname: Lin
authors.affiliation: State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University , Tianjin 300071, China.|Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University , Tianjin 300071, China.
authors.forename: Mengchun
authors.identifier: 0000-0002-2019-5365
authors.initials: M
authors.lastname: Ye