title: Computation of adsorption parameters for the removal of dye from wastewater by microwave assisted sawdust: Theoretical and experimental analysis.
abstract: In this research, the microwave assistance has been employed for the preparation of novel material from agro/natural bio-waste i.e. sawdust, for the effective removal of methylene blue (MB) dye from aqueous solution. The characterization of the newly prepared microwave assisted sawdust (MASD) material was performed by using FTIR, SEM and XRD analyses. In order to obtain the maximum removal of MB dye from wastewater, the adsorption experimental parameters such as initial dye concentration, contact time, solution pH and adsorbent dosage were optimized by trial and error approach. The obtained experimental results were applied to the different theoretical models to predict the system behaviour. The optimum conditions for the maximum removal MB dye from aqueous solution for an initial MB dye concentration of 25mg/L was calculated as: adsorbent dose of 3g/L, contact time of 90min, solution pH of 7.0 and at the temperature of 30°C. Freundlich and pseudo-second order models was best obeyed with the studied experimental data. Langmuir maximum monolayer adsorption capacity of MASD for MB dye removal was calculated as 58.14mg of MB dye/g of MASD. Adsorption diffusion model stated that the present adsorption system was controlled by intraparticle diffusion model. The obtained results proposed that, novel MASD was considered to be an effective and low-cost adsorbent material for the removal of dye from wastewater.
authors.affiliation: Department of Chemical Engineering, SSN College of Engineering, Chennai 603110, India.
authors.forename: Suganya
authors.initials: S
authors.lastname: S
authors.affiliation: Department of Chemical Engineering, SSN College of Engineering, Chennai 603110, India. Electronic address: senthilkumarp@ssn.edu.in.
authors.forename: Senthil Kumar
authors.initials: SK
authors.lastname: P
authors.affiliation: Department of Chemical Engineering, SSN College of Engineering, Chennai 603110, India.
authors.forename: Saravanan
authors.initials: S
authors.lastname: A
authors.affiliation: Department of Chemical Engineering, SSN College of Engineering, Chennai 603110, India.
authors.forename: Sundar Rajan
authors.initials: SR
authors.lastname: P
authors.affiliation: Department of Chemical Engineering, Visvesvaraya National Institute of Technology, Nagpur 440010, Maharashtra, India.
authors.forename: Ravikumar
authors.initials: R
authors.lastname: C
mesh_terms: D000327:Adsorption; D004396:Coloring Agents / Q000302:isolation & purification*; D004391:Dust / Q000032:analysis; D004784:Environmental Monitoring; D008751:Methylene Blue / Q000302:isolation & purification*; D008872:Microwaves; D062065:Wastewater / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods*; D014934:Wood
chemical_list: D004396:Coloring Agents; D004391:Dust; D008751:Methylene Blue; D062065:Wastewater; D014874:Water Pollutants, Chemical
keywords: Agro bio-waste; Analysis; Computation; Kinetics; Methylene blue; Modeling