title: Pd-Catalyzed oxidative annulation of enamides with diazabicyclic olefins: rapid access to cyclopentene fused 2-pyrrolines.
abstract: An efficient stereoselective route for the synthesis of cyclopentene fused 2-pyrrolines has been established via a Pd-catalyzed C-H activation/oxidative coupling of aryl enamides with diazabicyclic olefins. The proposed two-stage mechanism was successfully proven by isolating the intermediate trans-disubstituted cyclopentene.
authors.affiliation: Academy of Scientific and Innovative Research (AcSIR), New Delhi 110001, India and Organic Chemistry Section, CSIR-National Institute for Interdisciplinary Science and Technology, Thiruvananthapuram 695019, India. radhu2005@gmail.com jubijohn@niist.res.in.
authors.forename: P V
authors.initials: PV
authors.lastname: Santhini
authors.affiliation: Academy of Scientific and Innovative Research (AcSIR), New Delhi 110001, India and Organic Chemistry Section, CSIR-National Institute for Interdisciplinary Science and Technology, Thiruvananthapuram 695019, India. radhu2005@gmail.com jubijohn@niist.res.in.
authors.forename: G
authors.initials: G
authors.lastname: Nimisha
authors.affiliation: Academy of Scientific and Innovative Research (AcSIR), New Delhi 110001, India and Organic Chemistry Section, CSIR-National Institute for Interdisciplinary Science and Technology, Thiruvananthapuram 695019, India. radhu2005@gmail.com jubijohn@niist.res.in.
authors.forename: Jubi
authors.initials: J
authors.lastname: John
authors.affiliation: Central Salt and Marine Chemicals Research Institute, Bhavnagar 364 002, India.
authors.forename: E
authors.identifier: http://orcid.org/0000-0002-1934-6832
authors.initials: E
authors.lastname: Suresh
authors.affiliation: Academy of Scientific and Innovative Research (AcSIR), New Delhi 110001, India and Organic Chemistry Section, CSIR-National Institute for Interdisciplinary Science and Technology, Thiruvananthapuram 695019, India. radhu2005@gmail.com jubijohn@niist.res.in.
authors.forename: R Luxmi
authors.initials: RL
authors.lastname: Varma
authors.affiliation: Academy of Scientific and Innovative Research (AcSIR), New Delhi 110001, India and Organic Chemistry Section, CSIR-National Institute for Interdisciplinary Science and Technology, Thiruvananthapuram 695019, India. radhu2005@gmail.com jubijohn@niist.res.in.
authors.forename: K V
authors.initials: KV
authors.lastname: Radhakrishnan