title: Visible-Light Driven Photocascade Catalysis: Union of N,N-Dimethylanilines and α-Azidochalcones in Flow Microreactors.
abstract: N,N-Dimethylanilines were coupled with α-azidochalcones using visible-light driven Ru(bpy)3(PF6)2catalyzed photocascade continuous flow microfluidic approach that involves the creation of one C-C and two C-N new bonds. The reaction involves dual photocatalysis ensuing two sp3C-H bond functionalization of N,N-dimethylanilines. To explore the scope of the reaction, 20 different 1,3-diazabicyclo[3.1.0]hexanes were synthesized in good yields (55-71%).
authors.affiliation: Applied Organic Chemistry Group, Chemical Science &Technology Division, CSIR-North East Institute of Science and Technology , Jorhat, Assam 785006, India.|Academy of Scientific and Innovative Research (AcSIR) , New Delhi 110025, India.
authors.forename: Satheesh
authors.initials: S
authors.lastname: Borra
authors.affiliation: Applied Organic Chemistry Group, Chemical Science &Technology Division, CSIR-North East Institute of Science and Technology , Jorhat, Assam 785006, India.|Academy of Scientific and Innovative Research (AcSIR) , New Delhi 110025, India.
authors.forename: D
authors.initials: D
authors.lastname: Chandrasekhar
authors.affiliation: Department of Medicinal Chemistry and Pharmacology, CSIR-Indian Institute of Chemical Technology , Hyderabad 500007, India.|Department of Medicinal Chemistry, National Institute of Pharmaceutical Education and Research , Kolkata 700032, India.
authors.forename: Susanta
authors.initials: S
authors.lastname: Adhikary
authors.affiliation: Department of Medicinal Chemistry and Pharmacology, CSIR-Indian Institute of Chemical Technology , Hyderabad 500007, India.
authors.forename: Sandeep
authors.initials: S
authors.lastname: Rasala
authors.affiliation: School of Chemistry, Indian Institute of Science Education and Research , Thiruvananthapuram 695016, India.
authors.forename: Sabapathi
authors.initials: S
authors.lastname: Gokulnath
authors.affiliation: Applied Organic Chemistry Group, Chemical Science &Technology Division, CSIR-North East Institute of Science and Technology , Jorhat, Assam 785006, India.|Academy of Scientific and Innovative Research (AcSIR) , New Delhi 110025, India.
authors.forename: Ram Awatar
authors.identifier: 0000-0003-2431-8614
authors.initials: RA
authors.lastname: Maurya