title: Rhodium-Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids.
abstract: Transformation of aromatic thioesters into arylboronic esters was achieved efficiently using a rhodium catalyst. The broad functional-group tolerance and mild conditions of the method have allowed for the two-step decarboxylative borylation of a wide range of aromatic carboxylic acids, including commercially available drugs.
authors.affiliation: Chemical Biology Team, Division of Bio-Function Imaging, RIKEN Center for Life Science Technologies, 6-7-3 Minatojima-minamimachi, Chuo-ku, Kobe, 650-0047, Japan.
authors.forename: Hidenori
authors.initials: H
authors.lastname: Ochiai
authors.affiliation: Chemical Biology Team, Division of Bio-Function Imaging, RIKEN Center for Life Science Technologies, 6-7-3 Minatojima-minamimachi, Chuo-ku, Kobe, 650-0047, Japan.
authors.forename: Yuta
authors.initials: Y
authors.lastname: Uetake
authors.affiliation: Chemical Biology Team, Division of Bio-Function Imaging, RIKEN Center for Life Science Technologies, 6-7-3 Minatojima-minamimachi, Chuo-ku, Kobe, 650-0047, Japan.
authors.forename: Takashi
authors.identifier: 0000-0002-6209-5362
authors.initials: T
authors.lastname: Niwa
authors.affiliation: Chemical Biology Team, Division of Bio-Function Imaging, RIKEN Center for Life Science Technologies, 6-7-3 Minatojima-minamimachi, Chuo-ku, Kobe, 650-0047, Japan.
authors.forename: Takamitsu
authors.identifier: 0000-0002-7270-351X
authors.initials: T
authors.lastname: Hosoya
keywords: borylation; carboxylic acids; decarbonylation; rhodium catalysts; thioesters