title: The first nucleophilic C-H perfluoroalkylation of aromatic compounds via (arene)tricarbonylchromium complexes.
abstract: The first nucleophilic perfluoroalkylation of arenes is based on the arene π-system activation via (η6-arene)tricarbonylchromium complexes. Perfluoroalkyl anions generated from Me3SiRFand a fluoride ion source [Me4N]F exclusively attack the arene ligand under mild conditions. The formed negatively charged analogs of Meisenheimer adducts readily undergo a one-pot oxidation to perfluoroalkyl arenes.
authors.affiliation: Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanskaya Street, 02660, Kiev, Ukraine. yagupolskii@ioch.kiev.ua.
authors.forename: Natalia V
authors.initials: NV
authors.lastname: Kirij
authors.affiliation: Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanskaya Street, 02660, Kiev, Ukraine. yagupolskii@ioch.kiev.ua.
authors.forename: Andrey A
authors.initials: AA
authors.lastname: Filatov
authors.affiliation: Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanskaya Street, 02660, Kiev, Ukraine. yagupolskii@ioch.kiev.ua.
authors.forename: Gleb Yu
authors.identifier: http://orcid.org/0000-0002-4200-5454
authors.initials: GY
authors.lastname: Khrapach
authors.affiliation: Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanskaya Street, 02660, Kiev, Ukraine. yagupolskii@ioch.kiev.ua.
authors.forename: Yurii L
authors.identifier: http://orcid.org/0000-0002-5179-4096
authors.initials: YL
authors.lastname: Yagupolskii