title: [V4Mo3O14(NAr)3(μ2-NAr)3]2-: the first polyarylimido-stabilized molybdovanadate cluster.
abstract: The first molybdovanadate cluster with a polyarylimido trimetal fragment, [V4Mo3O14(NAr)3(μ2-NAr)3]2-, was in situ synthesized by using (TBA)3[H3V10O28] as proton and vanadium sources. Additional aniline hydrochlorides will give rise to the formation of phenyl guanidines, which will serve as cations and proton donors to form chain-like and dimeric supermolecules via H-bonding.
authors.affiliation: Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China. yonggewei@mail.tsinghua.edu.cn and Analysis and Test Center, Beijing University of Chemical Technology, Beijing 100029, P. R. China. xhaojian@163.com and State Key Laboratory of Natural and Biomimetic Drugs, Peking University, Beijing 100191, P. R. China.
authors.forename: Yichao
authors.initials: Y
authors.lastname: Huang
authors.affiliation: Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China. yonggewei@mail.tsinghua.edu.cn.
authors.forename: Jiangwei
authors.identifier: http://orcid.org/0000-0002-1221-3033
authors.initials: J
authors.lastname: Zhang
authors.affiliation: Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China. yonggewei@mail.tsinghua.edu.cn.
authors.forename: Jingxuan
authors.initials: J
authors.lastname: Ge
authors.affiliation: Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China. yonggewei@mail.tsinghua.edu.cn.
authors.forename: Chong
authors.initials: C
authors.lastname: Sui
authors.affiliation: Analysis and Test Center, Beijing University of Chemical Technology, Beijing 100029, P. R. China. xhaojian@163.com.
authors.forename: Jian
authors.initials: J
authors.lastname: Hao
authors.affiliation: Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China. yonggewei@mail.tsinghua.edu.cn and State Key Laboratory of Natural and Biomimetic Drugs, Peking University, Beijing 100191, P. R. China.
authors.forename: Yongge
authors.initials: Y
authors.lastname: Wei