title: Biomimetic Synthesis and Structural Revision of Chaxine B and Its Analogues.
abstract: Chaxine B and its analogues were synthesized from ergosterol in eight steps on the basis of our proposed biosynthetic pathway, which includes a highly site-selective and regioselective Baeyer-Villiger oxidation as the key step. This synthesis enabled the revision of the structures of chaxine B and its analogues.
authors.affiliation: Graduate School of Bioagricultural Sciences, Nagoya University , Chikusa-ku, Nagoya 464-8601, Japan.
authors.forename: Yushi
authors.initials: Y
authors.lastname: Hirata
authors.affiliation: Graduate School of Bioagricultural Sciences, Nagoya University , Chikusa-ku, Nagoya 464-8601, Japan.
authors.forename: Atsuo
authors.identifier: 0000-0002-0025-0523
authors.initials: A
authors.lastname: Nakazaki
authors.affiliation: Research Institute of Green Science and Technology, Shizuoka University , 836, Ohya, Suruga-ku, Shizuoka, 422-8529, Japan.
authors.forename: Hirokazu
authors.initials: H
authors.lastname: Kawagishi
authors.affiliation: Graduate School of Bioagricultural Sciences, Nagoya University , Chikusa-ku, Nagoya 464-8601, Japan.
authors.forename: Toshio
authors.initials: T
authors.lastname: Nishikawa