title: Molecular magnesium hydrides supported by an anionic triazacyclononane-type ligand.
abstract: Molecular magnesium hydride with a terminal metal-hydrogen bond [Mg(iPr2TACN·AliBu3)H]2supported by a monoanionic TACN-type ligand (TACN = 1,4-di-isopropyl-1,4,7-triazacyclononane) rearranges to form the dinuclear magnesium hydride [Mg(iPr2TACN·AlHiBu2)(μ-H)]2, exhibiting a rare MgH-Al interaction.
authors.affiliation: Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany. jun.okuda@ac.rwth-aachen.de.
authors.forename: S
authors.initials: S
authors.lastname: Schnitzler
authors.affiliation: Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany. jun.okuda@ac.rwth-aachen.de.
authors.forename: P
authors.initials: P
authors.lastname: Cui
authors.affiliation: Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany. jun.okuda@ac.rwth-aachen.de.
authors.forename: T P
authors.initials: TP
authors.lastname: Spaniol
authors.affiliation: Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany. jun.okuda@ac.rwth-aachen.de.
authors.forename: J
authors.identifier: http://orcid.org/0000-0002-1636-5464
authors.initials: J
authors.lastname: Okuda