title: Electronic perturbation of supramolecular conjugates of porphyrins and phthalocyanines.
abstract: The redox potential of a supramolecular porphyrin-phthalocyanine heterodimer was perturbed by the stacking of an extra metalloporphyrin to the phthalocyanine. This stacking gave rise to π-π and electrostatic interactions between the tetracationic dimer and the tetraanionic metalloporphyrin, with a Au(iii) metalloporphyrin exhibiting a larger effect than Cu(ii) and Pd(ii) complexes among square planar complexes.
authors.affiliation: Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan. kentaro@chem.nagoya-u.ac.jp.
authors.forename: Nozomi
authors.initials: N
authors.lastname: Mihara
authors.affiliation: Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan. kentaro@chem.nagoya-u.ac.jp and Research Center for Materials Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan.
authors.forename: Yasuyuki
authors.initials: Y
authors.lastname: Yamada
authors.affiliation: Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan.
authors.forename: Shigehisa
authors.initials: S
authors.lastname: Akine
authors.affiliation: Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, Japan.
authors.forename: Kunihisa
authors.initials: K
authors.lastname: Sugimoto
authors.affiliation: Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan. kentaro@chem.nagoya-u.ac.jp.
authors.forename: Kentaro
authors.identifier: http://orcid.org/0000-0002-6395-4536
authors.initials: K
authors.lastname: Tanaka