title: Asymmetric Ring-Opening Reactions of Aza- and Oxa-bicyclic Alkenes with Boronic Acids Using a Palladium/Zinc Co-catalytic System.
abstract: The asymmetric ring opening reactions of bicyclic alkenes with boronic acids were accomplished by using a highly active palladium/zinc co-catalytic system that was suitable for both azabenzonorbornadienes and oxabenzonorbornadienes, which were transformed to the corresponding chiral hydronaphthalene products in high yields (up to 99%) and high optical purities (up to 98% ee). The reaction protocol is general and mild and displays good functional group tolerance.
authors.affiliation: YMU-HKBU Joint Laboratory of Traditional Natural Medicine and ‡Key Laboratory of Chemistry in Ethnic Medicinal Resources, Yunnan Minzu University , Kunming, Yunnan People's Republic of China.
authors.forename: Wei
authors.initials: W
authors.lastname: Zhang
authors.affiliation: YMU-HKBU Joint Laboratory of Traditional Natural Medicine and ‡Key Laboratory of Chemistry in Ethnic Medicinal Resources, Yunnan Minzu University , Kunming, Yunnan People's Republic of China.
authors.forename: Jingchao
authors.initials: J
authors.lastname: Chen
authors.affiliation: YMU-HKBU Joint Laboratory of Traditional Natural Medicine and ‡Key Laboratory of Chemistry in Ethnic Medicinal Resources, Yunnan Minzu University , Kunming, Yunnan People's Republic of China.
authors.forename: Guangzhi
authors.initials: G
authors.lastname: Zeng
authors.affiliation: YMU-HKBU Joint Laboratory of Traditional Natural Medicine and ‡Key Laboratory of Chemistry in Ethnic Medicinal Resources, Yunnan Minzu University , Kunming, Yunnan People's Republic of China.
authors.forename: Fan
authors.initials: F
authors.lastname: Yang
authors.affiliation: YMU-HKBU Joint Laboratory of Traditional Natural Medicine and ‡Key Laboratory of Chemistry in Ethnic Medicinal Resources, Yunnan Minzu University , Kunming, Yunnan People's Republic of China.
authors.forename: Jianbin
authors.initials: J
authors.lastname: Xu
authors.affiliation: YMU-HKBU Joint Laboratory of Traditional Natural Medicine and ‡Key Laboratory of Chemistry in Ethnic Medicinal Resources, Yunnan Minzu University , Kunming, Yunnan People's Republic of China.
authors.forename: Weiqing
authors.initials: W
authors.lastname: Sun
authors.affiliation: YMU-HKBU Joint Laboratory of Traditional Natural Medicine and ‡Key Laboratory of Chemistry in Ethnic Medicinal Resources, Yunnan Minzu University , Kunming, Yunnan People's Republic of China.
authors.forename: Madhuri Vikas
authors.initials: MV
authors.lastname: Shinde
authors.affiliation: YMU-HKBU Joint Laboratory of Traditional Natural Medicine and ‡Key Laboratory of Chemistry in Ethnic Medicinal Resources, Yunnan Minzu University , Kunming, Yunnan People's Republic of China.
authors.forename: Baomin
authors.identifier: 0000-0003-1789-3741
authors.initials: B
authors.lastname: Fan