title: Pd-Catalyzed Conversion of Aryl Iodides to Sulfonyl Fluorides Using SO2Surrogate DABSO and Selectfluor.
abstract: A one-pot Pd-catalyzed conversion of aryl iodide to aryl sulfonyl fluorides using DABSO and Selectfluor has been developed generating aryl sulfonyl fluorides in good to excellent yields. The reaction results in the generation of electronically and sterically diverse sulfonyl fluorides. Additionally, sulfonyl fluorides can be converted to aryl sulfonamides and sulfonic esters using Cs2CO3under mild conditions.
authors.affiliation: Department of Chemistry, Pomona College , 645 North College Avenue, Claremont, California 91711, United States.
authors.forename: Ariana L
authors.initials: AL
authors.lastname: Tribby
authors.affiliation: Department of Chemistry, Pomona College , 645 North College Avenue, Claremont, California 91711, United States.
authors.forename: Ismeraí
authors.initials: I
authors.lastname: Rodríguez
authors.affiliation: Department of Chemistry, Amherst College , AC #2243, Amherst, Massachusetts 01002-5000, United States.
authors.forename: Shamira
authors.initials: S
authors.lastname: Shariffudin
authors.affiliation: Department of Chemistry, Pomona College , 645 North College Avenue, Claremont, California 91711, United States.
authors.forename: Nicholas D
authors.identifier: 0000-0002-6816-1113
authors.initials: ND
authors.lastname: Ball