title: Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol-yne reaction.
abstract: Herein we report the syntheses of two porous hyper-crosslinked polymers (HCPs) via thiol-yne reaction with rigid tetrahedral andpseudo-octahedral core structures. Sorption measurements with nitrogen gas at 77 K revealed BET-surface areas up to 650 m²/g. Those networks also showed a high thermal stability as well as insolubility in common organic solvents.
authors.affiliation: Institute of Organic Chemistry, Karlsruhe Institute of Technology - Campus South, Fritz-Haber-Weg 6, 76131 Karlsruhe, Germany.
authors.forename: Mathias
authors.initials: M
authors.lastname: Lang
authors.affiliation: Institute of Organic Chemistry, Karlsruhe Institute of Technology - Campus South, Fritz-Haber-Weg 6, 76131 Karlsruhe, Germany.
authors.forename: Alexandra
authors.initials: A
authors.lastname: Schade
authors.affiliation: Institute of Organic Chemistry, Karlsruhe Institute of Technology - Campus South, Fritz-Haber-Weg 6, 76131 Karlsruhe, Germany; Institute of Toxicology and Genetics, Karlsruhe Institute of Technology - Campus North, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany.
authors.forename: Stefan
authors.initials: S
authors.lastname: Bräse
keywords: porous hyper-crosslinked polymers; thiol–yne; three-dimensional