title: Niobium(v)-catalyzed defluorinative triallylation of α,α,α-trifluorotoluene derivatives by triple C-F bond activation.
abstract: The catalytic defluorinative triallylation of α,α,α-trifluorotoluene derivatives via C-F bond activation has been achieved by the use of the NbCl5catalyst and allyltrimethylsilane as a nucleophile. Several control experiments have suggested the importance of the conjugation between the fluorine atoms and the carbocation center in this reaction.
authors.affiliation: Department of Chemistry, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo 171-8588, Japan. takahiko.akiyama@gakushuin.ac.jp.
authors.forename: Kodai
authors.initials: K
authors.lastname: Saito
authors.affiliation: Department of Chemistry, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo 171-8588, Japan. takahiko.akiyama@gakushuin.ac.jp.
authors.forename: Taishi
authors.initials: T
authors.lastname: Umi
authors.affiliation: Department of Chemistry, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo 171-8588, Japan. takahiko.akiyama@gakushuin.ac.jp.
authors.forename: Takayuki
authors.initials: T
authors.lastname: Yamada
authors.affiliation: Department of Chemistry, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo 171-8588, Japan. takahiko.akiyama@gakushuin.ac.jp.
authors.forename: Takuya
authors.initials: T
authors.lastname: Suga
authors.affiliation: Department of Chemistry, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo 171-8588, Japan. takahiko.akiyama@gakushuin.ac.jp.
authors.forename: Takahiko
authors.identifier: http://orcid.org/0000-0003-4709-4107
authors.initials: T
authors.lastname: Akiyama