title: Well-to-wake analysis of ethanol-to-jet and sugar-to-jet pathways.
abstract: BACKGROUND
  To reduce the environmental impacts of the aviation sector as air traffic grows steadily, the aviation industry has paid increasing attention to bio-based alternative jet fuels (AJFs), which may provide lower life-cycle petroleum consumption and greenhouse gas (GHG) emissions than petroleum jet fuel. This study presents well-to-wake (WTWa) results for four emerging AJFs: ethanol-to-jet (ETJ) from corn and corn stover, and sugar-to-jet (STJ) from corn stover via both biological and catalytic conversion. For the ETJ pathways, two plant designs were examined: integrated (processing corn or corn stover as feedstock) and distributed (processing ethanol as feedstock). Also, three H2options for STJ via catalytic conversion are investigated: external H2from natural gas (NG) steam methane reforming (SMR), in situ H2, and H2from biomass gasification.
  
  
  RESULTS
  Results demonstrate that the feedstock is a key factor in the WTWa GHG emissions of ETJ: corn- and corn stover-based ETJ are estimated to produce WTWa GHG emissions that are 16 and 73%, respectively, less than those of petroleum jet. As for the STJ pathways, this study shows that STJ via biological conversion could generate WTWa GHG emissions 59% below those of petroleum jet. STJ via catalytic conversion could reduce the WTWa GHG emissions by 28% with H2from NG SMR or 71% with H2from biomass gasification than those of petroleum jet. This study also examines the impacts of co-product handling methods, and shows that the WTWa GHG emissions of corn stover-based ETJ, when estimated with a displacement method, are lower by 11 g CO2e/MJ than those estimated with an energy allocation method.
  
  
  CONCLUSIONS
  Corn- and corn stover-based ETJ as well as corn stover-based STJ show potentials to reduce WTWa GHG emissions compared to petroleum jet. Particularly, WTWa GHG emissions of STJ via catalytic conversion depend highly on the hydrogen source. On the other hand, ETJ offers unique opportunities to exploit extensive existing corn ethanol plants and infrastructure, and to provide a boost to staggering ethanol demand, which is largely being used as gasoline blendstock.
authors.affiliation: Systems Assessment Group, Energy Systems Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439 USA.
authors.forename: Jeongwoo
authors.identifier: 0000-0002-0604-3496
authors.initials: J
authors.lastname: Han
authors.affiliation: National Renewable Energy Laboratory, 15013 Denver West Parkway, Golden, CO 80401 USA.
authors.forename: Ling
authors.initials: L
authors.lastname: Tao
authors.affiliation: Systems Assessment Group, Energy Systems Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439 USA.
authors.forename: Michael
authors.initials: M
authors.lastname: Wang
keywords: Ethanol-to-jet; Fossil fuel use; Greenhouse gas emissions; Life-cycle analysis; Sugar-to-jet; Water consumption; Well-to-wake analysis