title: Active gas replenishment and sensing of the wetting state in a submerged superhydrophobic surface.
abstract: Previously superhydrophobic surfaces have demonstrated effective drag reduction by trapping a lubricious gas layer on the surface with micron-sized hydrophobic features. However, prolonged reduction of drag is hindered by the dissolution of the gas into the surrounding water. This paper demonstrates a novel combination of superhydrophobic surface design and electrochemical control methods which allow quick determination of the wetted area and a gas replenishment mechanism to maintain the desirable gas filled state. Electrochemical impedance spectroscopy is used to measure the capacitance of the surface which is shown to be proportional to the solid/liquid interface area. To maintain a full gas coverage for prolonged periods the surface is held at an electrical potential which leads to hydrogen evolution. In the desired gas filled state the water does not touch the metallic area of the surface, however after gas has dissolved the water touches the metal which closes the electrochemical circuit causing hydrogen to be produced replenishing the gas in the surface and returning to the gas filled state; in this way the system is self-actuating. This type of surface and electrochemical control shows promise for applications where the gas filled state of superhydrophobic surfaces must be maintained when submerged for long periods of time.
authors.affiliation: National Centre for Advanced Tribology at Southampton (nCATS), University of Southampton, SO17 1BJ, UK. ben.lloyd@soton.ac.uk.
authors.forename: Ben P
authors.initials: BP
authors.lastname: Lloyd
authors.affiliation: Chemistry, University of Southampton, SO17 1BJ, UK.
authors.forename: Philip N
authors.initials: PN
authors.lastname: Bartlett
authors.affiliation: National Centre for Advanced Tribology at Southampton (nCATS), University of Southampton, SO17 1BJ, UK. ben.lloyd@soton.ac.uk.
authors.forename: Robert J K
authors.initials: RJ
authors.lastname: Wood