title: Metal-free decarbonylative alkylation-aminoxidation of styrene derivatives with aliphatic aldehydes and N-hydroxyphthalimide.
abstract: A convenient metal-free decarbonylative alkylation-aminoxidation of styrene derivatives with aliphatic aldehydes and N-hydroxyphthalimide (NHPI) to yield phthalimide protected alkoxyamines is developed. With DTBP as an oxidant and radical-initiator, this reaction smoothly converts aliphatic aldehydes into alkyl radicals and subsequently allows the cascade construction of C(sp3)-C(sp3) and C(sp3)-O bonds via radical-radical coupling.
authors.affiliation: Key Laboratory for Environmentally Friendly Chemistry and Application of the Ministry of Education, College of Chemistry, Xiangtan University, Hunan, 411105, PR China. yangluo@xtu.edu.cn.
authors.forename: Yu-Xia
authors.initials: YX
authors.lastname: Li
authors.affiliation: Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, PR China.
authors.forename: Qi-Qiang
authors.initials: QQ
authors.lastname: Wang
authors.affiliation: Key Laboratory for Environmentally Friendly Chemistry and Application of the Ministry of Education, College of Chemistry, Xiangtan University, Hunan, 411105, PR China. yangluo@xtu.edu.cn and Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, PR China.
authors.forename: Luo
authors.identifier: http://orcid.org/0000-0002-0061-0816
authors.initials: L
authors.lastname: Yang