Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations.
Stereoconvergent catalysis is an important subset of asymmetric synthesis that encompasses stereoablative transformations, dynamic kinetic resolutions, and dynamic kinetic asymmetric transformations. Initially, only enzymes were known to catalyze dynamic kinetic processes, but recently various synthetic catalysts have been developed. This Review summarizes major advances in nonenzymatic, transition-metal-promoted dynamic asymmetric transformations reported between 2005 and 2015.
AbbVie, Inc., and ‡The Warren and Katharine Schlinger Laboratory of Chemistry and Chemical Engineering, California Institute of Technology , Pasadena, California 91125, United States.
Vikram
http://orcid.org/0000-0001-5621-5121
V
Bhat
AbbVie, Inc., and ‡The Warren and Katharine Schlinger Laboratory of Chemistry and Chemical Engineering, California Institute of Technology , Pasadena, California 91125, United States.
Eric R
http://orcid.org/0000-0002-1760-4121
ER
Welin
AbbVie, Inc., and ‡The Warren and Katharine Schlinger Laboratory of Chemistry and Chemical Engineering, California Institute of Technology , Pasadena, California 91125, United States.
Xuelei
X
Guo
AbbVie, Inc., and ‡The Warren and Katharine Schlinger Laboratory of Chemistry and Chemical Engineering, California Institute of Technology , Pasadena, California 91125, United States.
Brian M
http://orcid.org/0000-0001-9837-1528
BM
Stoltz