SrCl2Derived Perovskite Facilitating a High Efficiency of 16% in Hole-Conductor-Free Fully Printable Mesoscopic Perovskite Solar Cells.
Despite the breakthrough of over 22% power conversion efficiency demonstrated in organic-inorganic hybrid perovskite solar cells (PVSCs), critical concerns pertaining to the instability and toxicity still remain that may potentially hinder their commercialization. In this study, a new chemical approach using environmentally friendly strontium chloride (SrCl2) as a precursor for perovskite preparation is demonstrated to result in enhanced device performance and stability of the derived hole-conductor-free printable mesoscopic PVSCs. The CH3NH3PbI3perovskite is chemically modified by introducing SrCl2in the precursor solution. The results from structural, elemental, and morphological analyses show that the incorporation of SrCl2affords the formation of CH3NH3PbI3(SrCl2)xperovskites endowed with lower defect concentration and better pore filling in the derived mesoscopic PVSCs. The optimized compositional CH3NH3PbI3(SrCl2)0.1perovskite can substantially enhance the photovoltaic performance of the derived hole-conductor-free device to 15.9%, outperforming the value (13.0%) of the pristine CH3NH3PbI3device. More importantly, the stability of the device in ambient air under illumination is also improved.
Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Luoyu Road, 1037, Wuhan, 430074, China.
Hua
H
Zhang
Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Luoyu Road, 1037, Wuhan, 430074, China.|Department of Materials Science and Engineering, University of Washington, Seattle, WA, 98195, USA.
Huan
H
Wang
Department of Materials Science and Engineering, University of Washington, Seattle, WA, 98195, USA.
Spencer T
ST
Williams
Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Luoyu Road, 1037, Wuhan, 430074, China.
Dehua
D
Xiong
Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Luoyu Road, 1037, Wuhan, 430074, China.
Wenjun
W
Zhang
Department of Materials Science and Engineering, University of Washington, Seattle, WA, 98195, USA.
Chu-Chen
CC
Chueh
Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Luoyu Road, 1037, Wuhan, 430074, China.
Wei
W
Chen
Department of Materials Science and Engineering, University of Washington, Seattle, WA, 98195, USA.|Department of Physics & Materials Science, City University of Hong Kong, Kowloon, 999077, Hong Kong.
Alex K-Y
AK
Jen
ambient stability; hole-conductor free; mesoscopic perovskite solar cells; power conversion efficiency; strontium chloride