Three-component difunctionalization of alkenes leading to β-acetamido sulfides and β-acetoxy sulfides.
A novel method for the synthesis of β-acetamido sulfides via NBS-mediated aminosulfenylation of alkenes with thiophenols and nitriles under metal-free conditions has been described. And β-acetamido sulfides were also synthesized with 1-(arylthio)pyrrolidine-2,5-diones as substrates and HBr as an additive. On the other hand, iodine-catalyzed 1,2-acetoxysulfenylation of alkenes by using (diacetoxyiodo)benzene as an oxygen source to synthesise various β-acetoxy sulfides was described as well.
College of Chemistry, Nanchang University, Nanchang, Jiangxi 330031, China. senlin@ncu.edu.cn yuanxingwang@ncu.edu.cn.
Dingyi
http://orcid.org/0000-0003-0103-4088
D
Wang
College of Chemistry, Nanchang University, Nanchang, Jiangxi 330031, China. senlin@ncu.edu.cn yuanxingwang@ncu.edu.cn.
Zhaohua
Z
Yan
College of Chemistry, Nanchang University, Nanchang, Jiangxi 330031, China. senlin@ncu.edu.cn yuanxingwang@ncu.edu.cn.
Qihuang
Q
Xie
College of Chemistry, Nanchang University, Nanchang, Jiangxi 330031, China. senlin@ncu.edu.cn yuanxingwang@ncu.edu.cn.
Rongxing
R
Zhang
College of Chemistry, Nanchang University, Nanchang, Jiangxi 330031, China. senlin@ncu.edu.cn yuanxingwang@ncu.edu.cn.
Sen
S
Lin
School of Food Science & Technology, Nanchang University, Nanchang, Jiangxi 330031, China.
Yuanxing
Y
Wang