Hollow Nitrogen-Doped Carbon Spheres with Fe3O4Nanoparticles Encapsulated as a Highly Active Oxygen-Reduction Catalyst.
The development of nonprecious electrocatalyst with low cost and high efficiency for the oxygen reduction reaction (ORR) is a main challenge for electrochemical energy technology. In this work, a hierarchical hollow core-shell structured N-doped carbon spheres (N-HSCS), in which Fe3O4nanoparticles are encapsulated (Fe3O4/N-HCSC) has been successfully prepared. The Fe3O4/N-HCSC electrocatalyst exhibits a remarkable catalytic performance toward ORR. The porous hollow core-shell structure and synergistic effect between Fe3O4and protective nitrogen-doped graphitic layers are mainly responsible for such an excellent ORR catalytic property and stability. This work demonstrates a promising strategy of nanostructure-engineering to the future design and preparation of highly efficient non-noble metal electrocatalysts.
Key laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology (HUST) , Wuhan 430074, China.
Haitao
H
Wang
Key laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology (HUST) , Wuhan 430074, China.
Wei
W
Wang
Key laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology (HUST) , Wuhan 430074, China.
Yang Yang
YY
Xu
Key laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology (HUST) , Wuhan 430074, China.
Shuang
S
Dong
Key laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology (HUST) , Wuhan 430074, China.
Junwu
J
Xiao
Key laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology (HUST) , Wuhan 430074, China.
Feng
F
Wang
Key laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology (HUST) , Wuhan 430074, China.
Hongfang
http://orcid.org/0000-0002-9180-6629
H
Liu
Key laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology (HUST) , Wuhan 430074, China.|Shenzhen Institute of Huazhong University of Science and Technology , Shenzhen 518000, P. R. China.
Bao Yu
http://orcid.org/0000-0002-2054-908X
BY
Xia
Fe3O4 nanoparticle; core−shell; hollow; oxygen reduction; synergistic effect