Tape Casting of High-Performance Low-Temperature Solid Oxide Cells with Thin La0.8Sr0.2Ga0.8Mg0.2O3-δElectrolytes and Impregnated Nano Anodes.
Low-temperature solid oxide cells (LT-SOCs), operating at 400 to 650 °C, have great potential for commercialization since they can provide lower cost and improved long-term durability. Low operating temperature can also enable high round-trip efficiency of SOCs as reversible energy storage devices. This paper describes Sr0.8La0.2TiO3-α(SLT) anode supported LT-SOC with thin La0.8Sr0.2Ga0.8Mg0.2O3-δ(LSGM) electrolyte made by tape casting, with screen printed La0.6Sr0.4Fe0.8Co0.2O3-δ(LSCF) cathode and impregnated Ni anode. Optimization of the anode functional layers is described; the best anodes had 68 vol % LSGM and 12.3 vol % Ni and yielded maximum power density of 1.6 Wcm-2with a cell area specific resistance (ASR) of 0.21 Ωcm2at 650 °C. Most of the cell ASR was associated with the cathode. Reversible electrolysis and fuel cell operation yielded similar characteristics with both 50% H2-50% H2O and syngas fuel. Life testing over 500 h showed that the cathode impedance stabilized after an initial break-in period; the ohmic and anode resistances, though relatively small, increased slightly with time.
Department of Materials Science and Engineering, Northwestern University , 2220 Campus Drive, Evanston, Illinois 60208, United States.
Zhan
http://orcid.org/0000-0003-2653-3369
Z
Gao
Department of Materials Science and Engineering, Northwestern University , 2220 Campus Drive, Evanston, Illinois 60208, United States.
Hongqian
H
Wang
Department of Materials Science and Engineering, Northwestern University , 2220 Campus Drive, Evanston, Illinois 60208, United States.
Elizabeth
E
Miller
Department of Materials Science and Engineering, Northwestern University , 2220 Campus Drive, Evanston, Illinois 60208, United States.
Qinyuan
Q
Liu
Department of Materials Science and Engineering, Northwestern University , 2220 Campus Drive, Evanston, Illinois 60208, United States.
Daniel
D
Senn
Department of Materials Science and Engineering, Northwestern University , 2220 Campus Drive, Evanston, Illinois 60208, United States.
Scott
S
Barnett
LSGM electrolyte; electrolysis; impregnated nano anodes; solid oxide cells; tape casting