STED properties of Ce3+, Tb3+, and Eu3+doped inorganic scintillators.
Scintillator-based X-ray imaging is a powerful technique for noninvasive real-space microscopic structural investigation such as synchrotron-based computed tomography. The resolution of an optical image formed by scintillation emission is fundamentally diffraction limited. To overcome this limit, stimulated scintillation emission depletion (SSED) X-ray imaging, based on stimulated emission depletion (STED) microscopy, has been recently developed. This technique imposes new requirements on the scintillator material: efficient de-excitation by the STED-laser and negligible STED-laser excited luminescence. In this work, luminescence depletion was measured in several commonly-used Ce3+, Tb3+, and Eu3+- doped scintillators using various STED lasers. The depletion of Tb3+and Eu3+via 4f-4f transitions was more efficient (Ps= 8…19 mW) than Ce3+depletion via 5d-4f transitions (Ps= 43…45 mW). Main origins of STED-laser excited luminescence were one- and two-photon excitation, and scintillator impurities. LSO:Tb scintillator and a 628 nm cw STED-laser is the most promising combination for SSED satisfying the above-mentioned requirements.
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MS
Alekhin
J
J
Renger
M
M
Kasperczyk
P-A
PA
Douissard
T
T
Martin
Y
Y
Zorenko
D A
DA
Vasil'ev
M
M
Stiefel
L
L
Novotny
M
M
Stampanoni