Order of magnitude enhancement of monolayer MoS2photoluminescence due to near-field energy influx from nanocrystal films.
Two-dimensional transition metal dichalcogenides (TMDCs) like MoS2are promising candidates for various optoelectronic applications. The typical photoluminescence (PL) of monolayer MoS2is however known to suffer very low quantum yields. We demonstrate a 10-fold increase of MoS2excitonic PL enabled by nonradiative energy transfer (NRET) from adjacent nanocrystal quantum dot (NQD) films. The understanding of this effect is facilitated by our application of transient absorption (TA) spectroscopy to monitor the energy influx into the monolayer MoS2in the process of ET from photoexcited CdSe/ZnS nanocrystals. In contrast to PL spectroscopy, TA can detect even non-emissive excitons, and we register an order of magnitude enhancement of the MoS2excitonic TA signatures in hybrids with NQDs. The appearance of ET-induced nanosecond-scale kinetics in TA features is consistent with PL dynamics of energy-accepting MoS2and PL quenching data of the energy-donating NQDs. The observed enhancement is attributed to the reduction of recombination losses for excitons gradually transferred into MoS2under quasi-resonant conditions as compared with their direct photoproduction. The TA and PL data clearly illustrate the efficacy of MoS2and likely other TMDC materials as energy acceptors and the possibility of their practical utilization in NRET-coupled hybrid nanostructures.
Department of Physics, The University of Texas at Dallas, Richardson, TX, 75080, USA.
Tianle
T
Guo
Department of Physics, The University of Texas at Dallas, Richardson, TX, 75080, USA.
Siddharth
S
Sampat
Department of Materials Science and Engineering, The Pennsylvania State University, PA, University Park, 16802, USA.
Kehao
K
Zhang
Department of Materials Science and Engineering, The Pennsylvania State University, PA, University Park, 16802, USA.
Joshua A
JA
Robinson
Department of Materials Science and Engineering, The University of Texas at Dallas, Richardson, TX, 75080, USA.
Sara M
SM
Rupich
Department of Materials Science and Engineering, The University of Texas at Dallas, Richardson, TX, 75080, USA.
Yves J
YJ
Chabal
Department of Physics, The University of Texas at Dallas, Richardson, TX, 75080, USA.
Yuri N
YN
Gartstein
Department of Physics, The University of Texas at Dallas, Richardson, TX, 75080, USA.
Anton V
AV
Malko