Synthetic Study on Carthamin. 2. Stereoselective Approach to C-Glycosyl Quinochalcone via Desymmetrization.
Toward the total synthesis of carthamin, a stereoselective approach to the C-glycosyl quinochalcone intermediate is reported via the desymmetrization of a pseudo-Cs-symmetric C-glycosyl cyclohexadienone.
Department of Chemistry, Tokyo Institute of Technology , O-okayama, Meguro-ku, Tokyo 152-8551, Japan.
Taiki
T
Hayashi
Department of Chemistry, Tokyo Institute of Technology , O-okayama, Meguro-ku, Tokyo 152-8551, Japan.
Ken
K
Ohmori
Department of Chemistry, Tokyo Institute of Technology , O-okayama, Meguro-ku, Tokyo 152-8551, Japan.
Keisuke
0000-0001-7935-3762
K
Suzuki