Copper-Catalyzed B(dan)-Installing Carboboration of Alkenes.
Carboboration of alkenes was found to occur readily with an unsymmetrical diboron [(pin)B-B(dan)] and alkyl halides under copper catalysis, leading to the direct formation of protected alkylboron compounds via synchronous C-C and C-B bond-forming processes. The B(dan) moiety was solely installed into the organic frameworks with the regioselective attachment to a terminal carbon of alkenes employed.
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University , Higashi-Hiroshima 739-8527, Japan.
Ikuo
I
Kageyuki
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University , Higashi-Hiroshima 739-8527, Japan.
Itaru
I
Osaka
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University , Higashi-Hiroshima 739-8527, Japan.
Ken
K
Takaki
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University , Higashi-Hiroshima 739-8527, Japan.
Hiroto
0000-0001-6890-4397
H
Yoshida