Two microporous Fe-based MOFs with multiple active sites for selective gas adsorption.
Two Fe-based porous MOFs have been constructed from dimeric Fe-clusters and rod-shaped heterobimetallic {Fe2Na3}nchains as SBUs, respectively. Both of them exhibit highly selective CO2adsorption over CH4and N2, owing to their abundant multiple active sites.
School of Chemistry and Chemical Engineering, School of Materials Science and Engineering, School of Pharmacy, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, P. R. China. dougroup@163.com and School of Materials Science and Engineering, College of Chemistry, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, P. R. China. jxu@nankai.edu.cn buxh@nankai.edu.cn.
Yun-Wu
http://orcid.org/0000-0001-7673-7787
YW
Li
School of Chemistry and Chemical Engineering, School of Materials Science and Engineering, School of Pharmacy, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, P. R. China. dougroup@163.com.
Hui
H
Yan
School of Materials Science and Engineering, College of Chemistry, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, P. R. China. jxu@nankai.edu.cn buxh@nankai.edu.cn.
Tong-Liang
TL
Hu
School of Chemistry and Chemical Engineering, School of Materials Science and Engineering, School of Pharmacy, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, P. R. China. dougroup@163.com.
Hui-Yan
HY
Ma
School of Chemistry and Chemical Engineering, School of Materials Science and Engineering, School of Pharmacy, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, P. R. China. dougroup@163.com.
Da-Cheng
DC
Li
School of Chemistry and Chemical Engineering, School of Materials Science and Engineering, School of Pharmacy, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, P. R. China. dougroup@163.com.
Su-Na
http://orcid.org/0000-0002-3791-1786
SN
Wang
School of Chemistry and Chemical Engineering, School of Materials Science and Engineering, School of Pharmacy, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, P. R. China. dougroup@163.com.
Qing-Xia
QX
Yao
School of Chemistry and Chemical Engineering, School of Materials Science and Engineering, School of Pharmacy, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, P. R. China. dougroup@163.com.
Jian-Min
JM
Dou
School of Materials Science and Engineering, College of Chemistry, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, P. R. China. jxu@nankai.edu.cn buxh@nankai.edu.cn.
Jian
J
Xu
School of Materials Science and Engineering, College of Chemistry, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, P. R. China. jxu@nankai.edu.cn buxh@nankai.edu.cn.
Xian-He
http://orcid.org/0000-0002-2646-7974
XH
Bu