Mechanical performance of polymer-infiltrated zirconia ceramics.
OBJECTIVE
The aim of this study was to evaluate the microstructure and mechanical behavior of polymer-infiltrated zirconia ceramics as a function of pre-sintering temperature (1000-1150°C).


METHODS
Polymer-infiltrated zirconia ceramics were prepared by combining the porous zirconia networks and polymer through infiltration and polymerization. XRD was employed to determine phase structure. The microstructure and fracture mechanism were observed by SEM. Flexural strength and fracture toughness were measured by three-point bending method and single-edge-notched beam method, respectively. A nanoindentation system was employed to determine elastic modulus and hardness.


RESULTS
Different porosities and polymer contents can be obtained by tuning the pre-sintered temperature of zirconia ceramic precursors. Zirconia network porosity varies from 46.3% to 34.7% and the relevant polymer content ranges from 18.4wt.% to 12.3wt.% when the pre-sintered temperature is set from 1000°C to 1150°C. The flexural strength, fracture toughness, hardness, and elastic modulus values of the specimen pre-sintered at 1150°C are 240.9MPa, 3.69MPam1/2, 3.1GPa, and 58.8GPa, respectively.


CONCLUSIONS
The pre-sintering temperature has a significant effect on the microstructure and mechanical properties of polymer-infiltrated zirconia ceramics and the optimal pre-sintering temperature is 1150°C.


CONCLUSIONS
Specimen pre-sintered at 1150°C shows tooth-like mechanical properties, suggesting a promising restorative material in dental clinic. Moreover, the synthesis process is simple and can be easily performed in a prosthesis laboratory.
State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing, 100084, PR China. Electronic address: ljing12@mails.tsinghua.edu.cn.
Jing
J
Li
School & Hospital of Stomatology, Department of Geriatric Dentistry, Peking University, Beijing, 100081, PR China.
Xue-Hui
XH
Zhang
State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing, 100084, PR China.
Ben-Cang
BC
Cui
State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing, 100084, PR China. Electronic address: linyh@tsinghua.edu.cn.
Yuan-Hua
YH
Lin
School & Hospital of Stomatology, Department of Geriatric Dentistry, Peking University, Beijing, 100081, PR China.
Xu-Liang
XL
Deng
State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing, 100084, PR China.
Ming
M
Li
State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing, 100084, PR China.
Ce-Wen
CW
Nan
D000537:Aluminum Oxide / Q000737:chemistry; D017438:Bisphenol A-Glycidyl Methacrylate / Q000737:chemistry; D002516:Ceramics / Q000737:chemistry*; D003764:Dental Materials / Q000737:chemistry*; D003776:Dental Porcelain / Q000737:chemistry*; D055119:Elastic Modulus; D006244:Hardness; D006358:Hot Temperature; D008422:Materials Testing; D055595:Mechanical Phenomena; D053761:Nanocomposites; D018583:Pliability; D011108:Polymers / Q000737:chemistry*; D016062:Porosity; D013314:Stress, Mechanical; D013718:Tensile Strength; D015040:Zirconium / Q000737:chemistry*
D003764:Dental Materials; D011108:Polymers; D003776:Dental Porcelain; D017438:Bisphenol A-Glycidyl Methacrylate; D015040:Zirconium; D000537:Aluminum Oxide; C028541:zirconium oxide
3Y-TZP; Bis-GMA; Crack bridging; Dental materials; Weibull distribution