Adsorption and kinetic studies on the removal of chromium and copper onto Chitosan-g-maliec anhydride-g-ethylene dimethacrylate.
The present work was designed to remove toxic metals chromium and copper using the double grafted copolymer Chitosan-g-Maleic anhydride-g-ethylene dimethacrylate. The graft copolymer was synthesized through chain polymerization reaction using ceric ammonium nitrate as the initiator. Prepared Chitosan-g-Maleic anhydride-g-ethylene dimethacrylate was used in order to remove the heavy metals chromium and copper from aqueous solutions of 200ppm/L concentration proceeding batch adsorption process by varying the parameters such as adsorbent dose, contact time, pH and initial concentration of the metal solution. The experimental data were equipped with isotherm models such as Langmuir and Freundlich and pseudo-first order and pseudo-second order kinetics. The calculated results revealed that the adsorption favours Freundlich isotherm and follows pseudo-second order kinetics.
Department of Chemistry, Bharathiar University, Coimbatore 641 046, Tamilnadu, India.
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Gopal Reddi
PG and Research Department of Chemistry, D.K.M College for Women, Vellore 632 001, Tamilnadu, India.
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Gomathi
PG and Research Department of Chemistry, D.K.M College for Women, Vellore 632 001, Tamilnadu, India.
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M
Saranya
PG and Research Department of Chemistry, D.K.M College for Women, Vellore 632 001, Tamilnadu, India. Electronic address: drparsu8@gmail.com.
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Sudha
D000327:Adsorption; D048271:Chitosan / Q000737:chemistry*; D002857:Chromium / Q000737:chemistry* / Q000302:isolation & purification*; D003300:Copper / Q000737:chemistry* / Q000302:isolation & purification*; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D008293:Malates / Q000737:chemistry*; D008689:Methacrylates / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000302:isolation & purification; D018508:Water Purification
D008293:Malates; D008689:Methacrylates; D014874:Water Pollutants, Chemical; D002857:Chromium; D003300:Copper; C004919:ethylene dimethacrylate; C030298:malic acid; D048271:Chitosan
Adsorption; Chitosan-g-MA; Ethylene dimethacrylate; Graft polymerization