title: UV protective poly(lactic acid)/rosin films for sustainable packaging.
abstract: Recently, biopolymer based plastic materials are regarded as potential alternative for conventional plastics of fossil fuel origin in order to compensate depleting petroleum resources and address environmental pollution issues. Poly(lactic acid) (PLA) is one among the biopolymers which is rapidly commercialized for food packaging application. However, the demerits accompanied with PLA like brittle nature, slower crystallization rate, poor gas barrier and high ultraviolet radiation transmission properties confines its commercial application in food packaging sector. Studies on the improvement of ductility, crystallization rate and gas barrier properties are markedly reported. Much emphasis is not given in the literature on improving UV shielding properties which plays important role in preventing oxidation degradation of PLA. Therefore, the current work is focused on fabrication of eco-friendly poly(lactic acid)/rosin (RS) based biocomposite films with improved UV shielding along with ductility and oxygen barrier properties. The PLA-RS biocomposite films containing different loadings (1, 3, 5, 10 and 20wt%) of RS with an average thickness of 50μm are fabricated via solution casting technique. The PLA-RS film demonstrated noteworthy light barrier feature by shielding the passage of ∼98%, 92% and 53% in UV-B, UV-A and visible light regime, respectively. In case of UV-C region, complete blockage of UV transmission through the PLA-RS biocomposite film is noticed. In addition to this, the presence of RS in the PLA matrix brought considerable improvement in terms of ductility and oxygen barrier characteristics. This in turn indicates PLA-RS biocomposite films hold significant potential for sustainable food packaging application.
authors.affiliation: Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology, Kochi, Kerala, India.
authors.forename: Meenu
authors.initials: M
authors.lastname: Narayanan
authors.affiliation: School of Chemical Sciences, Mahatma Gandhi University, Kottayam, Kerala, India. Electronic address: lsravanthi09@gmail.com.
authors.forename: Sravanthi
authors.initials: S
authors.lastname: Loganathan
authors.affiliation: Centre for Biopolymer Science and Technology, A Unit of Central Institute of Plastics Engineering and Technology (CIPET), Kochi, Kerala, India. Electronic address: valaparavi@gmail.com.
authors.forename: Ravi Babu
authors.initials: RB
authors.lastname: Valapa
authors.affiliation: School of Chemical Sciences, Mahatma Gandhi University, Kottayam, Kerala, India.
authors.forename: Sabu
authors.initials: S
authors.lastname: Thomas
authors.affiliation: Centre for Biopolymer Science and Technology, A Unit of Central Institute of Plastics Engineering and Technology (CIPET), Kochi, Kerala, India.
authors.forename: T O
authors.initials: TO
authors.lastname: Varghese
mesh_terms: D018857:Food Packaging / Q000379:methods*; D055595:Mechanical Phenomena; D055620:Optical Phenomena; D010100:Oxygen / Q000737:chemistry; D010539:Permeability; D011091:Polyesters / Q000737:chemistry*; D012116:Resins, Plant / Q000737:chemistry*; D013696:Temperature; D014466:Ultraviolet Rays
chemical_list: D011091:Polyesters; D012116:Resins, Plant; C033616:poly(lactide); C013893:rosin; D010100:Oxygen
keywords: Oxygen barrier; Packaging; Poly (lactic acid); Rosin; Sustainable films; UV protection