title: Accuracy Enhancement of Raman Spectroscopy Using Complementary Laser-Induced Breakdown Spectroscopy (LIBS) with Geologically Mixed Samples.
abstract: Quantitative Raman analysis was carried out with geologically mixed samples that have various matrices. In order to compensate the matrix effect in Raman shift, laser-induced breakdown spectroscopy (LIBS) analysis was performed. Raman spectroscopy revealed the geological materials contained in the mixed samples. However, the analysis of a mixture containing different matrices was inaccurate due to the weak signal of the Raman shift, interference, and the strong matrix effect. On the other hand, the LIBS quantitative analysis of atomic carbon and calcium in mixed samples showed high accuracy. In the case of the calcite and gypsum mixture, the coefficient of determination of atomic carbon using LIBS was 0.99, while the signal using Raman was less than 0.9. Therefore, the geological composition of the mixed samples is first obtained using Raman and the LIBS-based quantitative analysis is then applied to the Raman outcome in order to construct highly accurate univariate calibration curves. The study also focuses on a method to overcome matrix effects through the two complementary spectroscopic techniques of Raman spectroscopy and LIBS.
authors.affiliation: Department of Mechanical and Aerospace Engineering, Seoul National University, Seoul, Republic of Korea.
authors.forename: Soojin
authors.initials: S
authors.lastname: Choi
authors.affiliation: Department of Mechanical and Aerospace Engineering, Seoul National University, Seoul, Republic of Korea.
authors.forename: Dongyoung
authors.initials: D
authors.lastname: Kim
authors.affiliation: Department of Mechanical and Aerospace Engineering, Seoul National University, Seoul, Republic of Korea.
authors.forename: Junho
authors.initials: J
authors.lastname: Yang
authors.affiliation: Department of Mechanical and Aerospace Engineering, Seoul National University, Seoul, Republic of Korea.
authors.forename: Jack J
authors.initials: JJ
authors.lastname: Yoh
keywords: LIBS; Raman; geological samples; laser-induced breakdown spectroscopy; matrix effect