title: A stereoselective synthesis of (E)- or (Z)-β-arylvinyl halides via a borylative coupling/halodeborylation protocol.
abstract: A new stereoselective method for the synthesis of (E)-β-arylvinyl iodides and (E)- or (Z)-β-arylvinyl bromides from styrenes and vinyl boronates on the basis of a one-pot procedure via borylative coupling/halodeborylation is reported. Depending on the halogenating agent as well as the mode of the halodeborylation reaction, (E) or (Z) isomers are selectively formed.
authors.affiliation: Centre for Advanced Technologies, Adam Mickiewicz University in Poznan, Umultowska 89c, 61-614 Poznan, Poland. jedrzejw@amu.edu.pl and Faculty of Chemistry, Adam Mickiewicz University in Poznan, Umultowska 89b, 61-614 Poznan, Poland.
authors.forename: Jakub
authors.initials: J
authors.lastname: Szyling
authors.affiliation: Centre for Advanced Technologies, Adam Mickiewicz University in Poznan, Umultowska 89c, 61-614 Poznan, Poland. jedrzejw@amu.edu.pl.
authors.forename: Adrian
authors.initials: A
authors.lastname: Franczyk
authors.affiliation: Faculty of Chemistry, Adam Mickiewicz University in Poznan, Umultowska 89b, 61-614 Poznan, Poland.
authors.forename: Piotr
authors.initials: P
authors.lastname: Pawluć
authors.affiliation: Centre for Advanced Technologies, Adam Mickiewicz University in Poznan, Umultowska 89c, 61-614 Poznan, Poland. jedrzejw@amu.edu.pl and Faculty of Chemistry, Adam Mickiewicz University in Poznan, Umultowska 89b, 61-614 Poznan, Poland.
authors.forename: Bogdan
authors.initials: B
authors.lastname: Marciniec
authors.affiliation: Centre for Advanced Technologies, Adam Mickiewicz University in Poznan, Umultowska 89c, 61-614 Poznan, Poland. jedrzejw@amu.edu.pl.
authors.forename: Jędrzej
authors.identifier: http://orcid.org/0000-0003-3683-8836
authors.initials: J
authors.lastname: Walkowiak