title: Integrated Extraction Chromatographic Separation of the Lithophile Elements Involved in Long-Lived Radiogenic Isotope Systems (Rb-Sr, U-Th-Pb, Sm-Nd, La-Ce, and Lu-Hf) Useful in Geochemical and Environmental Sciences.
abstract: A fast and efficient sample preparation method in view of isotope ratio measurements is described, allowing the separation of 11 elements involved, either as "parent" or as "daughter" isotopes, in six radiogenic isotope systems used as chronometers and tracers in earth, planetary, and environmental sciences. The protocol is based on small extraction chromatographic columns, used either alone or in tandem, through which a single nitric acid solution is passed, without any intervening evaporation step. The columns use commercially available extraction resins (Sr resin, TRU resin, Ln resin, RE resin, and again Ln resin for isolating Sr and Pb, LREE then La-Ce-Nd-Sm, Lu(Yb), and Hf, Th, and U, respectively) along with an additional, in-house prepared resin for separating Rb. A simplified scheme is proposed for samples requiring the separation of Sr, Pb, Nd, and Hf only. Adverse effects of troublesome major elements (Fe3+, Ti) are circumvented by masking with ascorbic acid and hydrofluoric acid, respectively. Typical recoveries in the 85-95% range are achieved, with procedural blanks of 10-100 pg, negligible with regard to the amounts of analytes processed. The fractions separated are suitable for high precision isotope ratio measurements by TIMS or MC-ICP-MS, as demonstrated by the repeat analyses of several international reference materials of basaltic composition for87Sr/86Sr,208,207,206Pb/204Pb,143Nd/144Nd,176Hf/177Hf, and230Th/232Th. Concentration data could be obtained by spiking and equilibrating the sample with appropriate isotopic tracers before the onset of the separation process and, finally, measuring the isotope ratios modified by the isotope dilution process.
authors.affiliation: Département de Géologie, C.N.R.S and Université Blaise Pascal , 5 rue Kessler, 63038 Clermont-Ferrand, Cedex, France.
authors.forename: Christian
authors.initials: C
authors.lastname: Pin
authors.affiliation: Laboratoire Magmas et Volcans, Université Blaise Pascal, CNRS UMR 6524 , 6 Avenue Blaise Pascal, 63178 Aubière, Cedex, France.
authors.forename: Abdelmouhcine
authors.identifier: 0000-0003-4059-730X
authors.initials: A
authors.lastname: Gannoun