title: Unusual binding selectivity with non-selective homoditopic pillar[5]arene oxime: serendipitous discovery of a unique approach to heterobinuclear metalation in solution.
abstract: A heterobinuclear complexation strategy on homoditopic pillar[5]arene was developed by using a pillar[5]arene with two rims decorated with benzaldehyde oximes. The unique selective recognition process was found to result from vesicular formation based on a controllable self-assembly, leading to binding of thorium(iv) only onto one rim, with the other rim being unoccupied for subsequent complexation of a second different metal ion.
authors.affiliation: Institute of Nuclear Science and Technology, Key Laboratory for Radiation Physics and Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China. wfeng9510@scu.edu.cn lhyuan@scu.edu.cn.
authors.forename: Xiangyang
authors.initials: X
authors.lastname: Yuan
authors.affiliation: Institute of Nuclear Science and Technology, Key Laboratory for Radiation Physics and Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China. wfeng9510@scu.edu.cn lhyuan@scu.edu.cn.
authors.forename: Yiming
authors.initials: Y
authors.lastname: Jia
authors.affiliation: Institute of Nuclear Science and Technology, Key Laboratory for Radiation Physics and Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China. wfeng9510@scu.edu.cn lhyuan@scu.edu.cn.
authors.forename: Yimin
authors.initials: Y
authors.lastname: Cai
authors.affiliation: Institute of Nuclear Science and Technology, Key Laboratory for Radiation Physics and Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China. wfeng9510@scu.edu.cn lhyuan@scu.edu.cn.
authors.forename: Wen
authors.initials: W
authors.lastname: Feng
authors.affiliation: Department of Chemistry, University of South Florida, East Fowler Ave, Florida 4202, USA. xiaopengli1@usf.edu.
authors.forename: Yiming
authors.initials: Y
authors.lastname: Li
authors.affiliation: Department of Chemistry, University of South Florida, East Fowler Ave, Florida 4202, USA. xiaopengli1@usf.edu.
authors.forename: Xiaopeng
authors.initials: X
authors.lastname: Li
authors.affiliation: Institute of Nuclear Science and Technology, Key Laboratory for Radiation Physics and Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China. wfeng9510@scu.edu.cn lhyuan@scu.edu.cn.
authors.forename: Lihua
authors.identifier: http://orcid.org/0000-0003-0578-4214
authors.initials: L
authors.lastname: Yuan