title: Microwave-Assisted Cp*CoIII-Catalyzed C-H Activation/Double C-N Bond Formation Reactions to Thiadiazine 1-Oxides.
abstract: A microwave-assisted, Cp*CoIII-catalyzed direct C-H activation/double C-N bond formation reaction of simple NH-sulfoximines with 1,4,2-dioxazol-5-ones to produce diverse thiadiazine-1-oxides is reported. The reaction tolerates a broad range of functional groups under external oxidant-free conditions and only releases CO2and H2O as the sole byproducts. The preliminary mechanistic studies revealed an electrophilic metalation pathway is likely involved in the reaction.
authors.affiliation: Key Laboratory of Functional Small Organic Molecules, Ministry of Education, and College of Chemistry & Chemical Engineering, Jiangxi Normal University , 99 Ziyang Road, Nanchang, Jiangxi 330022, P. R. China.
authors.forename: Jiapian
authors.initials: J
authors.lastname: Huang
authors.affiliation: Key Laboratory of Functional Small Organic Molecules, Ministry of Education, and College of Chemistry & Chemical Engineering, Jiangxi Normal University , 99 Ziyang Road, Nanchang, Jiangxi 330022, P. R. China.
authors.forename: Yangfei
authors.initials: Y
authors.lastname: Huang
authors.affiliation: Key Laboratory of Functional Small Organic Molecules, Ministry of Education, and College of Chemistry & Chemical Engineering, Jiangxi Normal University , 99 Ziyang Road, Nanchang, Jiangxi 330022, P. R. China.
authors.forename: Tao
authors.initials: T
authors.lastname: Wang
authors.affiliation: Key Laboratory of Functional Small Organic Molecules, Ministry of Education, and College of Chemistry & Chemical Engineering, Jiangxi Normal University , 99 Ziyang Road, Nanchang, Jiangxi 330022, P. R. China.
authors.forename: Qin
authors.initials: Q
authors.lastname: Huang
authors.affiliation: Key Laboratory of Functional Small Organic Molecules, Ministry of Education, and College of Chemistry & Chemical Engineering, Jiangxi Normal University , 99 Ziyang Road, Nanchang, Jiangxi 330022, P. R. China.
authors.forename: Zhihua
authors.initials: Z
authors.lastname: Wang
authors.affiliation: Key Laboratory of Functional Small Organic Molecules, Ministry of Education, and College of Chemistry & Chemical Engineering, Jiangxi Normal University , 99 Ziyang Road, Nanchang, Jiangxi 330022, P. R. China.
authors.forename: Zhiyuan
authors.identifier: 0000-0002-5159-7287
authors.initials: Z
authors.lastname: Chen