title: Ni-Catalyzed Stannylation of Aryl Esters via C-O Bond Cleavage.
abstract: A Ni-catalyzed stannylation of aryl esters with air- and moisture-insensitive silylstannyl reagents via Csp2 -O cleavage is described. This protocol is characterized by its wide scope, including challenging combinations, thus enabling access to versatile building blocks and orthogonal C-heteroatom bond formations.
authors.affiliation: Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology, Av. Països Catalans 16, 43007, Tarragona, Spain.
authors.forename: Yiting
authors.initials: Y
authors.lastname: Gu
authors.affiliation: Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology, Av. Països Catalans 16, 43007, Tarragona, Spain.|ICREA, Passeig Lluïs Companys 23, 08010, Barcelona, Spain.
authors.forename: Rúben
authors.identifier: 0000-0002-2543-0221
authors.initials: R
authors.lastname: Martín
keywords: C−O cleavage; aryl esters; cross-coupling; nickel