title: Synthesis of Orthorhombic Perovskite-Type ZnSnO3Single-Crystal Nanoplates and Their Application in Energy Harvesting.
abstract: In recent years, lead-free piezoelectric nanogenerators have attracted much attention because of their great potential for harvesting energy from the environment. Here, we report the first synthesis of two-dimensional (2D) single-crystal ZnSnO3hexagon nanoplates and the fabrication of ZnSnO3nanoplate-based nanogenerators. The orthorhombic perovskite-structured ZnSnO3nanoplates with (111) facets of the exposed plate surface are successfully synthesized via a one-step hydrothermal reaction. Piezoelectric nanogenerators are then fabricated using the as-synthesized single-crystal ZnSnO3nanoplates and poly(dimethylsiloxane) (PDMS). A d33value as high as 49 pC/N for the ZnSnO3@PDMS composite was obtained without any electrical poling process, which demonstrates that the single-crystal ZnSnO3nanoplates have a single-domain structure. To the best of our knowledge, this d33value is also the highest among lead-free piezoelectric composites. A bending strain can induce the piezoelectric nanogenerator (PENG) to generate a large, stable, and sustainable output open circuit voltage of 20 V and a short circuit current of 0.6 μA, which are higher than many other PENGs. The output signals are sufficient to light a single light-emitting diode (LED), which shows the great potential of the material for scavenging mechanical energy from moving entities, such as road vehicles, railway vehicles, and humans.
authors.affiliation: State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiaotong University , Shanghai 200240, People's Republic of China.
authors.forename: Runjiang
authors.initials: R
authors.lastname: Guo
authors.affiliation: State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiaotong University , Shanghai 200240, People's Republic of China.
authors.forename: Yiping
authors.identifier: http://orcid.org/0000-0003-0251-450X
authors.initials: Y
authors.lastname: Guo
authors.affiliation: State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiaotong University , Shanghai 200240, People's Republic of China.
authors.forename: Huanan
authors.initials: H
authors.lastname: Duan
authors.affiliation: State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiaotong University , Shanghai 200240, People's Republic of China.
authors.forename: Hua
authors.initials: H
authors.lastname: Li
authors.affiliation: State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiaotong University , Shanghai 200240, People's Republic of China.
authors.forename: Hezhou
authors.initials: H
authors.lastname: Liu
keywords: energy harvesting; flexible composite; lead-free ZnSnO3; piezoelectric nanogenerator (PENG); two-dimensional (2D) material