title: Sequential Oxidative and Reductive Radical Cyclization Approach toward Asperparaline C and Synthesis of Its 8-Oxo Analogue.
abstract: The most advanced approach, so far, to the asperparalines is developed. Consecutive oxidative and reductive radical cyclizations serve as the key steps to stereoselectively access the complex fully elaborated skeleton containing the cyclopentane and spiro-succinimide units.
authors.affiliation: Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences , Flemingovo namesti 2, 16610 Prague 6, Czech Republic.
authors.forename: Tynchtyk
authors.initials: T
authors.lastname: Amatov
authors.affiliation: Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences , Flemingovo namesti 2, 16610 Prague 6, Czech Republic.
authors.forename: Radek
authors.initials: R
authors.lastname: Pohl
authors.affiliation: Department of Inorganic Chemistry, Faculty of Science, Charles University in Prague , Hlavova 8, 12843 Prague 2, Czech Republic.
authors.forename: Ivana
authors.initials: I
authors.lastname: Cisařová
authors.affiliation: Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences , Flemingovo namesti 2, 16610 Prague 6, Czech Republic.
authors.forename: Ullrich
authors.identifier: 0000-0001-8386-1348
authors.initials: U
authors.lastname: Jahn