title: Mn(iv) and Mn(v)-radical species supported by the redox non-innocent bis(2-amino-3,5-di-tert-butylphenyl)amine pincer ligand.
abstract: The electron-rich pincer ligand 1 has been synthesized and chelated to manganese. The octahedral Mn(iv) bis(diiminosemiquinonate) and Mn(v) (diiminobenzoquinone) (diiminosemiquinonate) radicals were structurally characterized.
authors.affiliation: Département de Chimie Moléculaire - Chimie Inorganique Redox (CIRE) - UMR CNRS 5250, UniversitéJoseph Fourier, B. P. 53, 38041 Grenoble cedex 9, France. nicolas.leconte@univ-grenoble-alpes.fr fabrice.thomas@univ-grenoble-alpes.fr.
authors.forename: Nicolas
authors.initials: N
authors.lastname: Leconte
authors.affiliation: Département de Chimie Moléculaire - Chimie Inorganique Redox (CIRE) - UMR CNRS 5250, UniversitéJoseph Fourier, B. P. 53, 38041 Grenoble cedex 9, France. nicolas.leconte@univ-grenoble-alpes.fr fabrice.thomas@univ-grenoble-alpes.fr.
authors.forename: Jules
authors.initials: J
authors.lastname: Moutet
authors.affiliation: Department of Chemistry, Simon Fraser University, Burnaby, British Columbia V5A 1S6, Canada.
authors.forename: Khrystyna
authors.initials: K
authors.lastname: Herasymchuk
authors.affiliation: Department of Chemistry, Simon Fraser University, Burnaby, British Columbia V5A 1S6, Canada.
authors.forename: Ryan M
authors.initials: RM
authors.lastname: Clarke
authors.affiliation: Département de Chimie Moléculaire - Chimie Inorganique Redox (CIRE) - UMR CNRS 5250, UniversitéJoseph Fourier, B. P. 53, 38041 Grenoble cedex 9, France. nicolas.leconte@univ-grenoble-alpes.fr fabrice.thomas@univ-grenoble-alpes.fr.
authors.forename: Christian
authors.initials: C
authors.lastname: Philouze
authors.affiliation: Laboratoire des Multimatériaux et Interfaces (UMR CNRS 5615), Université Claude Bernard Lyon 1, 69622 Villeurbanne cedex, France.
authors.forename: Dominique
authors.initials: D
authors.lastname: Luneau
authors.affiliation: Department of Chemistry, Simon Fraser University, Burnaby, British Columbia V5A 1S6, Canada.
authors.forename: Tim
authors.initials: T
authors.lastname: Storr
authors.affiliation: Département de Chimie Moléculaire - Chimie Inorganique Redox (CIRE) - UMR CNRS 5250, UniversitéJoseph Fourier, B. P. 53, 38041 Grenoble cedex 9, France. nicolas.leconte@univ-grenoble-alpes.fr fabrice.thomas@univ-grenoble-alpes.fr.
authors.forename: Fabrice
authors.identifier: http://orcid.org/0000-0002-6977-5192
authors.initials: F
authors.lastname: Thomas