title: Experimental and theoretical study of hydroxyquinolines: hydroxyl group position dependent dipole moment and charge-separation in the photoexcited state leading to fluorescence.
abstract: Optical absorption and fluorescence (FL) spectra of 2-, 6-, 7-, 8-hydroxyquinolines (2-,6-,7- and 8-HQs) have been measured at room temperature in the wide range of solvents of different polarities, dielectric constant and refractive index. The ground state dipole moment (µg) and excited state dipole moment (µe) of 2-, 6-, 7- and 8-HQs were obtained using solvatochromic shift (SS) methods and microscopic solvent polarity parameters (MSPP). Change in the dipole moment (Δµ) between the ground and photo-excited states was estimated from SS and MSPP methods. DFT and TDDFT based theoretical calculations were performed for the ground and excited states dipole moments, and for vertical transitions. A significant enhancement in the excited state dipole moment was observed following photo-excitation. The large value of Δµ clearly indicates to the charge-separation in the photo-excited states, which in turn depends on the position of the hydroxyl group in the ring.
authors.affiliation: Laser-Spectroscopy Lab, Department of Applied Physics, Delhi Technological University, Bawana Road, Delhi 110042, India.
authors.forename: Mohan Singh
authors.initials: MS
authors.lastname: Mehata
authors.forename: Ajay K
authors.initials: AK
authors.lastname: Singh
authors.forename: Ravindra Kumar
authors.initials: RK
authors.lastname: Sinha