title: Stereoselective Synthesis of Alkenyl Silanes, Sulfones, Phosphine Oxides, and Nitroolefins by Radical C-S Bond Cleavage of Arylalkenyl Sulfides.
abstract: A radical-mediated approach has been introduced for the C-S bond activation of arylalkenyl sulfides. The protocol provides an efficient approach for the generation of various alkenes including alkenyl silanes, sulfones, phosphine oxides, and nitroolefins. In most cases, these radical substitutions are performed under metal-free conditions with stereospecificity.
authors.affiliation: Chemical Engineering College, Nanjing University of Science and Technology , Nanjing, 210094, China.
authors.forename: Ya-Mei
authors.initials: YM
authors.lastname: Lin
authors.affiliation: Chemical Engineering College, Nanjing University of Science and Technology , Nanjing, 210094, China.
authors.forename: Guo-Ping
authors.identifier: 0000-0003-4476-964X
authors.initials: GP
authors.lastname: Lu
authors.affiliation: Chemical Engineering College, Nanjing University of Science and Technology , Nanjing, 210094, China.
authors.forename: Rong-Kang
authors.initials: RK
authors.lastname: Wang
authors.affiliation: Chemical Engineering College, Nanjing University of Science and Technology , Nanjing, 210094, China.
authors.forename: Wen-Bin
authors.identifier: 0000-0003-4606-7668
authors.initials: WB
authors.lastname: Yi