title: Silver(i)-promoted insertion into X-H (X = Si, Sn, and Ge) bonds with N-nosylhydrazones.
abstract: Silver(i)-promoted carbene insertion into X-H (X = Si, Sn, and Ge) bonds has been realized by using unstable diazo compounds, which are generated in situ from N-nosylhydrazones as carbene precursors. The reaction tolerates a wide range of functional groups and delivers a number of valuable silicon-containing compounds in very high yields (up to 96%). Moreover, organostannanes and organogermanes were as well effectively obtained in very good yields under optimal conditions.
authors.affiliation: Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University, 5268 Renmin Street, 130024 Changchun, China. bixh507@nenu.edu.cn.
authors.forename: Zhaohong
authors.initials: Z
authors.lastname: Liu
authors.affiliation: Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University, 5268 Renmin Street, 130024 Changchun, China. bixh507@nenu.edu.cn.
authors.forename: Qiangqiang
authors.initials: Q
authors.lastname: Li
authors.affiliation: Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University, 5268 Renmin Street, 130024 Changchun, China. bixh507@nenu.edu.cn.
authors.forename: Yang
authors.initials: Y
authors.lastname: Yang
authors.affiliation: Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University, 5268 Renmin Street, 130024 Changchun, China. bixh507@nenu.edu.cn and State Key Laboratory of Elemento-Organic Chemistry, Nankai University, 300071 Tianjin, China.
authors.forename: Xihe
authors.identifier: http://orcid.org/0000-0002-6694-6742
authors.initials: X
authors.lastname: Bi