title: Preparation and evaluation of magnetic core-shell mesoporous molecularly imprinted polymers for selective adsorption of tetrabromobisphenol S.
abstract: Novel magnetic mesoporous molecularly imprinted polymers (MMIPs) with core-shell structure were prepared by simple surface molecular imprinting polymerization using tetrabromobisphenol-S (TBBPS) as the template. The MMIPs-TBBPS were characterized by fourier-transform infrared spectrometry (FTIR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), N2adsorption-desorption transmission, and vibrating sample magnetometry. The resultant MMIPs-TBBPS were successfully applied magnetic solid-phase extraction (MSPE) coupled with HPLC determination of TBBPS in spiked real water samples with recoveries of 77.8-88.9%. The adsorption experiments showed that the binding capacity of MMIPs-TBBPS to TBBPS and six structural analogs were significantly higher than that of the magnetic nonimprinted polymers (MNIPs). Meanwhile, the MMIPs-TBBPS possessed rapid binding affinity, excellent magnetic response, specific selectivity and high adsorption capacity toward TBBPS with a maximum adsorption capacity of 1626.8µgg-1. The analytical results indicate that the MMIPs-TBBPS are promising materials for selective separation and fast enrichment of TBBPS from complicated enviromental samples.
authors.affiliation: College of Chemistry and Chemical Engineering, Northwest Normal University, PR China; Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, Lanzhou 730070, PR China. Electronic address: wxm98@163.com.
authors.forename: Xuemei
authors.initials: X
authors.lastname: Wang
authors.affiliation: College of Chemistry and Chemical Engineering, Northwest Normal University, PR China.
authors.forename: Pengfei
authors.initials: P
authors.lastname: Huang
authors.affiliation: College of Chemistry and Chemical Engineering, Northwest Normal University, PR China.
authors.forename: Xiaomin
authors.initials: X
authors.lastname: Ma
authors.affiliation: College of Chemistry and Chemical Engineering, Northwest Normal University, PR China.
authors.forename: Huan
authors.initials: H
authors.lastname: Wang
authors.affiliation: College of Chemistry and Chemical Engineering, Northwest Normal University, PR China; Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, Lanzhou 730070, PR China.
authors.forename: Xiaoquan
authors.initials: X
authors.lastname: Lu
authors.affiliation: College of Chemistry and Chemical Engineering, Northwest Normal University, PR China; Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, Lanzhou 730070, PR China.
authors.forename: Xinzhen
authors.initials: X
authors.lastname: Du
keywords: Adsorption; Brominated flame retardants; Magnetic materials; Magnetic solid-phase extraction; Molecularly imprinted polymers