title: Heterogeneous Nucleation of Trichloroethylene Ozonation Products in the Formation of New Fine Particles.
abstract: Free radicals in atmosphere have played an important role in the atmospheric chemistry. The chloro-Criegee free radicals are produced easily in the decomposition of primary ozonide (POZ) of the trichloroethylene, and can react with O2, NO, NO2,SO2and H2O subsequently. Then the inorganic salts, polar organic nitrogen and organic sulfur compounds, oxygen-containing heterocyclic intermediates and polyhydroxy compounds can be obtained. The heterogeneous nucleation of oxidation intermediates in the formation of fine particles is investigated using molecular dynamics simulation. The detailed nucleation processes are reported. According to molecular dynamics simulation, the nucleation with a diameter of 2 nm is formed in the Organic Compounds-(NH4)2SO4-H2O system. The spontaneous nucleation is an important process in the formation of fine particles in atmosphere. The model study gives a good example from volatile organic compounds to new fine particles.
authors.affiliation: Environment Research Institute, Shandong University, Jinan 250100, P. R. China.
authors.forename: Ning
authors.initials: N
authors.lastname: Wang
authors.affiliation: Environment Research Institute, Shandong University, Jinan 250100, P. R. China.
authors.forename: Xiaomin
authors.initials: X
authors.lastname: Sun
authors.affiliation: Department of Environmental Science and Engineering, Fudan University, China.
authors.forename: Jianmin
authors.initials: J
authors.lastname: Chen
authors.affiliation: Department of Environmental Science and Engineering, Fudan University, China.
authors.forename: Xiang
authors.initials: X
authors.lastname: Li