title: An unexpected pathway for hydrodesulfurization of gazole over a CoMoS active phase supported on a mesoporous TiO2catalyst.
abstract: Using dual mesoporous titania as a support, due to the presence of intrinsic Brönsted acid sites, the main approach to 4,6-dimethylbenzothiophene (46DMDBT) hydrodesulfurization (HDS) becomes the direct desulfurization (DDS) route through isomerization and dismutation reactions, instead of the hydrogenation (HYD) pathway usually observed with a conventional promoted (by Ni or Co) MoS2/Al2O3catalyst.
authors.affiliation: Université de Lorraine/CNRS, SRSMC, UMR7565, F-54506 Vandoeuvre-lès-Nancy cedex, France. Jean-Luc.Blin@univ-lorraine.fr.
authors.forename: I
authors.initials: I
authors.lastname: Naboulsi
authors.affiliation: Institut de Chimie des Milieux et Matériaux de Poitiers (IC2MP) CNRS 7285, Université de Poitiers, B27-4 rue Michel Brunet TSA 51106 86073, Poitiers Cedex 9, France.
authors.forename: C
authors.initials: C
authors.lastname: Felipe Linares Aponte
authors.affiliation: Université de Haute Alsace (UHA)/CNRS, Equipe Matériaux à Porosité Contrôlée (MPC), Institut de Science des Matériaux de Mulhouse (IS2M), UMR 7361, F-68093 Mulhouse cedex, France.
authors.forename: B
authors.initials: B
authors.lastname: Lebeau
authors.affiliation: Institut de Chimie des Milieux et Matériaux de Poitiers (IC2MP) CNRS 7285, Université de Poitiers, B27-4 rue Michel Brunet TSA 51106 86073, Poitiers Cedex 9, France.
authors.forename: S
authors.initials: S
authors.lastname: Brunet
authors.affiliation: Université de Haute Alsace (UHA)/CNRS, Equipe Matériaux à Porosité Contrôlée (MPC), Institut de Science des Matériaux de Mulhouse (IS2M), UMR 7361, F-68093 Mulhouse cedex, France.
authors.forename: L
authors.initials: L
authors.lastname: Michelin
authors.affiliation: Université de Haute Alsace (UHA)/CNRS, Equipe Matériaux à Porosité Contrôlée (MPC), Institut de Science des Matériaux de Mulhouse (IS2M), UMR 7361, F-68093 Mulhouse cedex, France.
authors.forename: M
authors.initials: M
authors.lastname: Bonne
authors.affiliation: Université de Lorraine/CNRS, SRSMC, UMR7565, F-54506 Vandoeuvre-lès-Nancy cedex, France. Jean-Luc.Blin@univ-lorraine.fr.
authors.forename: J L
authors.identifier: http://orcid.org/0000-0002-0947-2552
authors.initials: JL
authors.lastname: Blin