title: Synthesis of spiro-oxoindoles through Pd-catalyzed remote C-H alkylation using α-diazocarbonyl compounds.
abstract: In this communication we describe a new route to spiro-oxoindole derivatives through a novel Pd-catalyzed cascade process. This reaction is based on the remote C-H activation performed by σ-alkyl Pd(ii) species generated in situ via intramolecular carbopalladation of alkenes, followed by insertion of a carbenoid coupling partner.
authors.affiliation: Grupo de Química Organometálica. Dpto. Química Inorgánica, Universidad de Murcia, Campus de Espinardo, 30100, Murcia, Spain. joangalo@um.es.
authors.forename: Marta
authors.initials: M
authors.lastname: Pérez-Gómez
authors.affiliation: Grupo de Química Organometálica. Dpto. Química Inorgánica, Universidad de Murcia, Campus de Espinardo, 30100, Murcia, Spain. joangalo@um.es.
authors.forename: Sergio
authors.initials: S
authors.lastname: Hernández-Ponte
authors.affiliation: SAI, Universidad de Murcia, Apartado 4021, 30071, Murcia, Spain.
authors.forename: Delia
authors.initials: D
authors.lastname: Bautista
authors.affiliation: Grupo de Química Organometálica. Dpto. Química Inorgánica, Universidad de Murcia, Campus de Espinardo, 30100, Murcia, Spain. joangalo@um.es.
authors.forename: José-Antonio
authors.identifier: http://orcid.org/0000-0002-8143-7081
authors.initials: JA
authors.lastname: García-López