title: Unraveling the structure and exciton coupling for multichromophoric merocyanine dye molecules.
abstract: The relative orientation of chromophores is a key factor in determining the relationship between the structure and the functionality in molecular multichromophore ensembles. In the case of structurally flexible molecular systems in solution, the task to clarify the relevant effects of accessible chromophore orientations with spectroscopic observations is very demanding. In this study, we address this issue by investigating a series of differently connected multichromophoric systems composed of highly dipolar merocyanine dyes that are systematically varied in their substitution pattern and the number of chromophores attached to a bridging benzene ring. Combining electro-optical absorption (EOA) and UV/Vis spectroscopy with density functional theory (DFT) as well as exciton theory discloses conformational preferences and rationalizes the optical properties of the interacting chromophores. Our findings suggest for all multichromophoric systems there is a relative orientation of the chromophores which compensates for the individual dipole moments of the merocyanine dyes by pointing preferably in opposing directions. These orientations furthermore rationalize the observed spectral properties by partly excitonically-coupled subunits.
authors.affiliation: Institut für Physikalische und Theoretische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany. brixner@phys-chemie.uni-wuerzburg.de.
authors.forename: Federico
authors.initials: F
authors.lastname: Koch
authors.affiliation: Center for Nanosystems Chemistry (CNC), Universität Würzburg, Theodor-Boveri-Weg, 97074 Würzburg, Germany and Institut für Organische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany. wuerthner@chemie.uni-wuerzburg.de.
authors.forename: Matthias
authors.initials: M
authors.lastname: Stolte
authors.affiliation: Institut für Organische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany. wuerthner@chemie.uni-wuerzburg.de.
authors.forename: André
authors.initials: A
authors.lastname: Zitzler-Kunkel
authors.affiliation: Institut für Organische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany. wuerthner@chemie.uni-wuerzburg.de.
authors.forename: David
authors.initials: D
authors.lastname: Bialas
authors.affiliation: Institut für Physikalische und Theoretische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany. brixner@phys-chemie.uni-wuerzburg.de.
authors.forename: Andreas
authors.initials: A
authors.lastname: Steinbacher
authors.affiliation: Institut für Physikalische und Theoretische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany. brixner@phys-chemie.uni-wuerzburg.de and Center for Nanosystems Chemistry (CNC), Universität Würzburg, Theodor-Boveri-Weg, 97074 Würzburg, Germany.
authors.forename: Tobias
authors.identifier: http://orcid.org/0000-0002-6529-704X
authors.initials: T
authors.lastname: Brixner
authors.affiliation: Center for Nanosystems Chemistry (CNC), Universität Würzburg, Theodor-Boveri-Weg, 97074 Würzburg, Germany and Institut für Organische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany. wuerthner@chemie.uni-wuerzburg.de.
authors.forename: Frank
authors.identifier: http://orcid.org/0000-0001-7245-0471
authors.initials: F
authors.lastname: Würthner