title: Dual role of Cu2O nanocubes as templates and networking catalysts for hollow and microporous Fe-porphyrin networks.
abstract: Cu2O nanocubes were used for the synthesis of hollow and microporous Fe porphyrin networks (H-MFePN). In this synthesis, Cu2O nanocubes performed not only as networking catalysts but also as shape controlling templates. MFePN were formed on the surface of the Cu2O nanocubes through azide-alkyne cycloaddition of tetrakis(4-ethynylphenyl) Fe-porphyrin with 1,4-diazidobenzene. H-MFePN showed excellent catalytic activities in carbene insertion into N-H bonds, maintaining their activities during five recycle tests.
authors.affiliation: Department of Chemistry, Sungkyunkwan University, Suwon 16419, Korea. sson@skku.edu.
authors.forename: Daye
authors.initials: D
authors.lastname: Kang
authors.affiliation: Department of Chemistry, Sungkyunkwan University, Suwon 16419, Korea. sson@skku.edu.
authors.forename: Ju Hong
authors.initials: JH
authors.lastname: Ko
authors.affiliation: Department of Chemistry, Sungkyunkwan University, Suwon 16419, Korea. sson@skku.edu.
authors.forename: Jaewon
authors.initials: J
authors.lastname: Choi
authors.affiliation: Department of Chemistry, Sungkyunkwan University, Suwon 16419, Korea. sson@skku.edu.
authors.forename: Kyoungil
authors.initials: K
authors.lastname: Cho
authors.affiliation: Korea Basic Science Institute, Daejeon 350-333, Korea.
authors.forename: Sang Moon
authors.initials: SM
authors.lastname: Lee
authors.affiliation: Korea Basic Science Institute, Daejeon 350-333, Korea.
authors.forename: Hae Jin
authors.initials: HJ
authors.lastname: Kim
authors.affiliation: Laboratory of Nuclear Magnetic Resonance, National Center for Inter-University Research Facilities (NCIRF), Seoul National University, Seoul 08826, Korea.
authors.forename: Yoon-Joo
authors.initials: YJ
authors.lastname: Ko
authors.affiliation: Department of Chemistry, Pusan National University, Busan 46241, Korea.
authors.forename: Kang Hyun
authors.initials: KH
authors.lastname: Park
authors.affiliation: Department of Chemistry, Sungkyunkwan University, Suwon 16419, Korea. sson@skku.edu.
authors.forename: Seung Uk
authors.identifier: http://orcid.org/0000-0002-4779-9302
authors.initials: SU
authors.lastname: Son