title: Laser Synthesis and Processing of Colloids: Fundamentals and Applications.
abstract: Driven by functionality and purity demand for applications of inorganic nanoparticle colloids in optics, biology, and energy, their surface chemistry has become a topic of intensive research interest. Consequently, ligand-free colloids are ideal reference materials for evaluating the effects of surface adsorbates from the initial state for application-oriented nanointegration purposes. After two decades of development, laser synthesis and processing of colloids (LSPC) has emerged as a convenient and scalable technique for the synthesis of ligand-free nanomaterials in sealed environments. In addition to the high-purity surface of LSPC-generated nanoparticles, other strengths of LSPC include its high throughput, convenience for preparing alloys or series of doped nanomaterials, and its continuous operation mode, suitable for downstream processing. Unscreened surface charge of LSPC-synthesized colloids is the key to achieving colloidal stability and high affinity to biomolecules as well as support materials, thereby enabling the fabrication of bioconjugates and heterogeneous catalysts. Accurate size control of LSPC-synthesized materials ranging from quantum dots to submicrometer spheres and recent upscaling advancement toward the multiple-gram scale are helpful for extending the applicability of LSPC-synthesized nanomaterials to various fields. By discussing key reports on both the fundamentals and the applications related to laser ablation, fragmentation, and melting in liquids, this Article presents a timely and critical review of this emerging topic.
authors.affiliation: Technical Chemistry I and Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen , Universitaetsstrasse 7, 45141 Essen, Germany.
authors.forename: Dongshi
authors.initials: D
authors.lastname: Zhang
authors.affiliation: Technical Chemistry I and Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen , Universitaetsstrasse 7, 45141 Essen, Germany.
authors.forename: Bilal
authors.identifier: http://orcid.org/0000-0001-6368-9659
authors.initials: B
authors.lastname: Gökce
authors.affiliation: Technical Chemistry I and Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen , Universitaetsstrasse 7, 45141 Essen, Germany.
authors.forename: Stephan
authors.identifier: http://orcid.org/0000-0002-9739-7272
authors.initials: S
authors.lastname: Barcikowski
mesh_terms: D003102:Colloids / Q000737:chemistry*; D007834:Lasers; D053758:Nanoparticles
chemical_list: D003102:Colloids