title: Gallium(III) and Indium(III) Complexes with meso-Monophosphorylated Porphyrins: Synthesis and Structure. A First Example of Dimers Formed by the Self-Assembly of meso-Porphyrinylphosphonic Acid Monoester.
abstract: The synthesis and structural characterization, both in solution by means of1H and31P NMR and UV-vis spectroscopies and in the solid state by X-ray diffraction on single crystal, of a series of gallium(III) and indium(III) meso-mono(diethoxyphosphoryl)porphyrins bearing different peripheral substituents as well as the corresponding monoesters and phosphonic acids are reported. This work describes the first example of the X-ray structure of a self-assembled dimer formed via strong binding between the oxygen atom of the phosphonate substituent and the gallium(III) cations of adjacent porphyrin molecules [Ga-O = 1.9708(13) Å].
authors.affiliation: Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences , Leninskii pr. 31, Building 4, Moscow 119071, Russia.
authors.forename: Yulia Yu
authors.initials: YY
authors.lastname: Enakieva
authors.affiliation: Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences , Leninskii pr. 31, Building 4, Moscow 119071, Russia.|Université de Bourgogne Franche-Comté, ICMUB (UMR CNRS 6302) , 9 Avenue Alain Savary, BP 47870, 21078 Dijon Cedex, France.
authors.forename: Marina V
authors.initials: MV
authors.lastname: Volostnykh
authors.affiliation: Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences , Leninskii pr. 31, Moscow 119991, Russia.
authors.forename: Sergey E
authors.initials: SE
authors.lastname: Nefedov
authors.affiliation: Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences , Leninskii pr. 31, Building 4, Moscow 119071, Russia.|Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences , Leninskii pr. 31, Moscow 119991, Russia.
authors.forename: Gayane A
authors.initials: GA
authors.lastname: Kirakosyan
authors.affiliation: Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences , Leninskii pr. 31, Building 4, Moscow 119071, Russia.|Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences , Leninskii pr. 31, Moscow 119991, Russia.
authors.forename: Yulia G
authors.identifier: http://orcid.org/0000-0002-2333-4033
authors.initials: YG
authors.lastname: Gorbunova
authors.affiliation: Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences , Leninskii pr. 31, Building 4, Moscow 119071, Russia.|Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences , Leninskii pr. 31, Moscow 119991, Russia.
authors.forename: Aslan Yu
authors.initials: AY
authors.lastname: Tsivadze
authors.affiliation: Université de Bourgogne Franche-Comté, ICMUB (UMR CNRS 6302) , 9 Avenue Alain Savary, BP 47870, 21078 Dijon Cedex, France.
authors.forename: Alla G
authors.initials: AG
authors.lastname: Bessmertnykh-Lemeune
authors.affiliation: Université de Bourgogne Franche-Comté, ICMUB (UMR CNRS 6302) , 9 Avenue Alain Savary, BP 47870, 21078 Dijon Cedex, France.
authors.forename: Christine
authors.initials: C
authors.lastname: Stern
authors.affiliation: Université de Bourgogne Franche-Comté, ICMUB (UMR CNRS 6302) , 9 Avenue Alain Savary, BP 47870, 21078 Dijon Cedex, France.
authors.forename: Roger
authors.identifier: http://orcid.org/0000-0001-7328-3695
authors.initials: R
authors.lastname: Guilard