title: An efficient noble-metal-free supported copper catalyst for selective nitrocyclohexane hydrogenation to cyclohexanone oxime.
abstract: It was shown for the first time that cyclohexanone oxime (CHO) can be selectively produced by heterogeneous copper-catalyzed hydrogenative transformation of nitrocyclohexane (NC). The combination of Cu0and Cu+and their cooperative interaction with weakly acidic SiO2supports elicited a significantly unique and selective catalysis in the hydrogenation of NC to CHO.
authors.affiliation: Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, P. R. China. ymliu@fudan.edu.cn.
authors.forename: Qian-Qian
authors.initials: QQ
authors.lastname: Zhang
authors.affiliation: Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, P. R. China. ymliu@fudan.edu.cn and SINOPEC Shanghai Research Institute of Petrochemical Technology, Shanghai 201208, P. R. China. wangyd.sshy@sinopec.com.
authors.forename: Jing
authors.initials: J
authors.lastname: Dong
authors.affiliation: Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, P. R. China. ymliu@fudan.edu.cn.
authors.forename: Yong-Mei
authors.identifier: http://orcid.org/0000-0001-6810-3450
authors.initials: YM
authors.lastname: Liu
authors.affiliation: Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, P. R. China. ymliu@fudan.edu.cn.
authors.forename: Yong
authors.initials: Y
authors.lastname: Cao
authors.affiliation: Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, P. R. China. ymliu@fudan.edu.cn.
authors.forename: He-Yong
authors.initials: HY
authors.lastname: He
authors.affiliation: SINOPEC Shanghai Research Institute of Petrochemical Technology, Shanghai 201208, P. R. China. wangyd.sshy@sinopec.com.
authors.forename: Yang-Dong
authors.initials: YD
authors.lastname: Wang