title: A solvent-free dense energetic metal-organic framework (EMOF): to improve stability and energetic performance via in situ microcalorimetry.
abstract: It is a tremendous challenge to prepare solvent-free dense energetic metal-organic frameworks (EMOFs), hence also to improve their stability and energetic performance. In this study, based on in situ microcalorimetry, an interpenetrating EMOF without solvent molecules, [Cu(tztr)]n(1, H2tztr = 3-(tetrazol-5-yl)triazole) was obtained, possessing high stability (Tdec= 360 °C) and outstanding energetic properties (ΔHdet= 7.53 kcal cm-3, D = 8.429 km s-1, P = 40.02 GPa).
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China. sanpingchen@126.com and Department of Chemistry, Xianyang Normal University, Xian'yang, Shaanxi 712000, P. R. China.
authors.forename: Yinli
authors.initials: Y
authors.lastname: Zhang
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China. sanpingchen@126.com and College of Chemistry and Chemical Engineering, Baoji University of Arts and Science, 1 Hi-Tech Avenue, Baoji, Shaanxi 721013, China.
authors.forename: Sheng
authors.initials: S
authors.lastname: Zhang
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China. sanpingchen@126.com.
authors.forename: Lin
authors.initials: L
authors.lastname: Sun
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China. sanpingchen@126.com.
authors.forename: Qi
authors.initials: Q
authors.lastname: Yang
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China. sanpingchen@126.com.
authors.forename: Jing
authors.initials: J
authors.lastname: Han
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China. sanpingchen@126.com.
authors.forename: Qing
authors.initials: Q
authors.lastname: Wei
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China. sanpingchen@126.com.
authors.forename: Gang
authors.initials: G
authors.lastname: Xie
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China. sanpingchen@126.com.
authors.forename: Sanping
authors.identifier: http://orcid.org/0000-0002-6851-7386
authors.initials: S
authors.lastname: Chen
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China. sanpingchen@126.com.
authors.forename: Shengli
authors.initials: S
authors.lastname: Gao