title: Room-Temperature Activation of Hydrogen by Semi-immobilized Frustrated Lewis Pairs in Microporous Polymer Networks.
abstract: Porous polymer networks based on sterically encumbered triphenylphosphine motifs, mimicking the basic sites employed in frustrated Lewis pair (FLP) chemistry, were synthesized via Yamamoto polymerization and their interactions with the strong Lewis acid B(C6F5)3probed. The combinations yield semi-immobilized FLPs, which are able to cleave dihydrogen heterolytically at ambient temperature and low hydrogen pressure.
authors.affiliation: Department of Chemistry, Functional Materials, Technische Universität Berlin , Hardenbergstraße 40, 10623 Berlin, Germany.
authors.forename: Matthias
authors.initials: M
authors.lastname: Trunk
authors.affiliation: Department of Chemistry, Organic Chemistry/Sustainable Synthetic Methods, Technische Universität Berlin , Straße des 17. Juni 115, 10623 Berlin, Germany.
authors.forename: Johannes F
authors.identifier: 0000-0003-1043-8092
authors.initials: JF
authors.lastname: Teichert
authors.affiliation: Department of Chemistry, Functional Materials, Technische Universität Berlin , Hardenbergstraße 40, 10623 Berlin, Germany.
authors.forename: Arne
authors.identifier: 0000-0002-2130-4930
authors.initials: A
authors.lastname: Thomas