title: Preparation of Single-Crystalline Heterojunctions for Organic Electronics.
abstract: Organic single-crystalline heterojunctions are composed of different single crystals interfaced together. The intrinsic highly ordered heterostructure in these multicomponent solids holds the capacity for multifunctions, as well as superior charge-transporting properties, promising high-performance electronic applications such as ambipolar transistors and solar cells. However, this kind of heterojunction is not easily available and the preparation methods need to be developed. Recent advances in the efficient strategies that have emerged in yielding high-quality single-crystalline heterojunctions are highlighted here. The advantages and limitations of each strategy are also discussed. The obtained single-crystalline heterojunctions have started to exhibit rich physical properties, including metallic conduction, photovoltaic effects, and so on. Further structural optimization of the heterojunctions to accommodate the electronic device configuration is necessary to significantly advance this research direction.
authors.affiliation: MOE Key Laboratory of Macromolecular Synthesis and Functionalization, State Key Laboratory of Silicon Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027, P. R. China.
authors.forename: Jiake
authors.initials: J
authors.lastname: Wu
authors.affiliation: MOE Key Laboratory of Macromolecular Synthesis and Functionalization, State Key Laboratory of Silicon Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027, P. R. China.
authors.forename: Qinfen
authors.initials: Q
authors.lastname: Li
authors.affiliation: MOE Key Laboratory of Macromolecular Synthesis and Functionalization, State Key Laboratory of Silicon Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027, P. R. China.
authors.forename: Guobiao
authors.initials: G
authors.lastname: Xue
authors.affiliation: MOE Key Laboratory of Macromolecular Synthesis and Functionalization, State Key Laboratory of Silicon Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027, P. R. China.
authors.forename: Hongzheng
authors.initials: H
authors.lastname: Chen
authors.affiliation: MOE Key Laboratory of Macromolecular Synthesis and Functionalization, State Key Laboratory of Silicon Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027, P. R. China.
authors.forename: Hanying
authors.initials: H
authors.lastname: Li
keywords: heterojunctions; organic electronics; organic semiconductors; single crystals