title: Palladium-catalyzed synthesis of monofluoroalkenes from 3,3-difluoropropenes using dimethylmalonate and derivatives as nucleophiles.
abstract: The synthesis of monofluoroalkenes bearing a malonate or its derivatives at the β position is presented. The reaction can be performed with various 3,3-difluoropropenes. A preliminary result for an enantioselective variant is also reported. Further synthetic transformations of a monofluoroalkene were also accomplished.
authors.affiliation: CCVC, PROTEO, Département de chimie, 1045 avenue de la Médecine, Université Laval, Québec, Québec, CanadaG1V 0A6. jean-francois.paquin@chm.ulaval.ca.
authors.forename: Myriam
authors.initials: M
authors.lastname: Drouin
authors.forename: Sébastien
authors.initials: S
authors.lastname: Tremblay
authors.forename: Jean-François
authors.initials: JF
authors.lastname: Paquin