title: Switchable divergent asymmetric synthesis via organocatalysis.
abstract: The development of switchable chemo-, regio-, or diastereodivergent reactions, in which two or more structurally and stereogenically different types of chiral products could be produced efficiently from an identical set of starting materials under readily tunable catalytic conditions, is one of the ultimate goals in asymmetric catalysis. This tutorial review will focus on the application of a variety of chiral organic catalysts, including Lewis bases, and Brønsted bases and acids, in a diverse range of stereoselective reactions in a switchable manner. Meanwhile, a few examples of divergent reactions through synergistic activation of organocatalysis and metal catalysis will also be discussed.
authors.affiliation: Department of Medicinal Chemistry, West China School of Pharmacy, Sichuan University, Chengdu 610041, China. ycchen@scu.edu.cn.
authors.forename: Gu
authors.initials: G
authors.lastname: Zhan
authors.affiliation: Department of Medicinal Chemistry, West China School of Pharmacy, Sichuan University, Chengdu 610041, China. ycchen@scu.edu.cn.
authors.forename: Wei
authors.initials: W
authors.lastname: Du
authors.affiliation: Department of Medicinal Chemistry, West China School of Pharmacy, Sichuan University, Chengdu 610041, China. ycchen@scu.edu.cn and College of Pharmacy, Third Military Medical University, Chongqing 400038, China.
authors.forename: Ying-Chun
authors.identifier: http://orcid.org/0000-0003-1902-0979
authors.initials: YC
authors.lastname: Chen