title: Green synthesis, characterization and catalytic activity of silver nanoparticles using Cassia auriculata flower extract separated fraction.
abstract: Cassia auriculata L., the flower aqueous extract was fractionated by separating funnel using n-hexane (A1), chloroform (A2), ethyl acetate (A3) and triple distilled water (A4). The A4 fraction was concentrated and determined the presence of preliminary phytochemicals such as tannins, flavonoids, glycosides, carbohydrates and polyphenolic compounds. These phytochemical compounds acted as reducing as well as a stabilizing agent in the green synthesis of Ag NPs from aqueous silver ions. Initially, the colour change and UV-vis absorbance surface Plasmon resonance strong, wide band located at 435nm has confirmed the synthesis of Ag NPs. The X-ray diffraction (XRD) pattern of Ag NPs shows a face-centered cubic crystal structure. The observed values were calculated by Debye-Scherrer equation to theoretical confirms the particle size of 18nm. The surface morphology of Ag NPs was viewed by HRTEM, the particles are spherical and triangle shapes with sizes from 10 to 35nm. Further, the Ag NPs was effective catalytic activity in the reduction of highly environmental polluted organic compounds of 4-nitrophenol and methyl orange. The green synthesis of Ag NPs seems to eco-friendly, cost-effective, conventional one spot synthesis and greater performance of catalytic degradation of environmentally polluted organic dyes.
authors.affiliation: Department of Chemistry, Manonmaniam Sundaranar University, Tirunelveli 627012, TN, India. Electronic address: karu.muthu@yahoo.com.
authors.forename: Karuppiah
authors.initials: K
authors.lastname: Muthu
authors.affiliation: Department of Chemistry, Manonmaniam Sundaranar University, Tirunelveli 627012, TN, India.
authors.forename: Sethuraman
authors.initials: S
authors.lastname: Priya
mesh_terms: D002366:Cassia / Q000737:chemistry*; D002384:Catalysis; D035264:Flowers / Q000737:chemistry*; D055772:Green Chemistry Technology / Q000379:methods*; D006863:Hydrogen-Ion Concentration; D007477:Ions; D053768:Metal Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D008670:Metals / Q000737:chemistry; D010936:Plant Extracts / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D012996:Solutions; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D014867:Water / Q000737:chemistry; D014961:X-Ray Diffraction
chemical_list: D007477:Ions; D008670:Metals; D010936:Plant Extracts; D012996:Solutions; D014867:Water; D012834:Silver
keywords: Cassia auriculata; Catalytic activity; Green synthesis; Silver nanoparticles