title: Asymmetric cinnamylation of N-tert-butanesulfinyl imines with cinnamyl acetates: total syntheses of (+)-lycoricidine and (+)-7-deoxypancratistatin.
abstract: Highly diastereoselective palladium catalyzed cinnamylation of N-tert-butanesulfinyl imines with cinnamyl acetates has been established to provide enantioenriched β-aryl homoallylic amines. The synthetic application of this stragety has been successfully demonstrated in the concise total syntheses of antitumor natural products (+)-lycoricidine and (+)-7-deoxypancratistatin.
authors.affiliation: Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China. sunxingwen@fudan.edu.cn.
authors.forename: Sen-Lin
authors.identifier: http://orcid.org/0000-0002-9539-6014
authors.initials: SL
authors.lastname: Cai
authors.affiliation: Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China. sunxingwen@fudan.edu.cn.
authors.forename: Bin-Hua
authors.initials: BH
authors.lastname: Yuan
authors.affiliation: Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China. sunxingwen@fudan.edu.cn.
authors.forename: Yi-Xiang
authors.initials: YX
authors.lastname: Jiang
authors.affiliation: Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China. sunxingwen@fudan.edu.cn.
authors.forename: Guo-Qiang
authors.initials: GQ
authors.lastname: Lin
authors.affiliation: Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China. sunxingwen@fudan.edu.cn.
authors.forename: Xing-Wen
authors.identifier: http://orcid.org/0000-0003-0432-7935
authors.initials: XW
authors.lastname: Sun