title: Synthetic Architecture of MgO/C Nanocomposite from Hierarchical-Structured Coordination Polymer toward Enhanced CO2Capture.
abstract: Highly efficient, durable, and earth-abundant solid sorbents are of paramount importance for practical carbon capture, storage, and utilization. Here, we report a novel and facile two-step strategy to synthesize a group of hierarchically structured porous MgO/C nanocomposites using flowerlike Mg-containing coordination polymer as a precursor. The new nanocomposites exhibit superb CO2capture performance with sorption capacity up to 30.9 wt % (at 27 °C, 1 bar CO2), fast sorption kinetics, and long cycling life. Importantly, the achieved capacity is >14 times higher than that of commercial MgO, and favorably exceeds the highest value recorded to date for MgO-based sorbents under similar operating conditions. On the basis of the morphological and textural property analysis, together with CO2sorption mechanism study using CO2-TPD and DRIFT techniques, the outstanding performance in CO2uptake originates from unique features of this type of sorbent materials, which include hierarchical architecture, porous building blocks of nanosheets, high specific surface area (ca. 300 m2/g), evenly dispersed MgO nanocrystallites (ca. 3 nm) providing abundant active sites, and the in situ generated carbon matrix that acts as a stabilizer to prevent the growth and agglomeration of MgO crystallites. The nanocomposite system developed in this work shows good potential for future low-cost CO2abatement and utilization.
authors.affiliation: Department of Chemical and Biomolecular Engineering, Faculty of Engineering, National University of Singapore , 10 Kent Ridge Crescent, Singapore 119260, Singapore.|Cambridge Centre for Advanced Research in Energy Efficiency in Singapore , 1 Create Way, Singapore 138602, Singapore.
authors.forename: Ping
authors.initials: P
authors.lastname: Li
authors.affiliation: Cambridge Centre for Advanced Research in Energy Efficiency in Singapore , 1 Create Way, Singapore 138602, Singapore.
authors.forename: Wen
authors.initials: W
authors.lastname: Liu
authors.affiliation: Department of Chemical Engineering and Biotechnology, University of Cambridge , Pembroke Street, Cambridge CB2 3RA, United Kingdom.
authors.forename: John S
authors.initials: JS
authors.lastname: Dennis
authors.affiliation: Department of Chemical and Biomolecular Engineering, Faculty of Engineering, National University of Singapore , 10 Kent Ridge Crescent, Singapore 119260, Singapore.|Cambridge Centre for Advanced Research in Energy Efficiency in Singapore , 1 Create Way, Singapore 138602, Singapore.
authors.forename: Hua Chun
authors.identifier: http://orcid.org/0000-0002-0215-7760
authors.initials: HC
authors.lastname: Zeng
keywords: CO2 capture; MgO-based nanocomposite; carbon; coordination polymer; hierarchical structure; pyrolysis