title: Photoacoustic Spectroscopy for the Quantification of N2O in the Off-Gas of Wastewater Treatment Plants.
abstract: Different configurations of photoacoustic (PA) setups for the online-measurement of gaseous N2O, employing semiconductor lasers at 2.9 and 4.5 μm, were developed and tested. Their performance was assessed with respect to the analysis of N2O emissions from wastewater treatment plants. For this purpose, the local N2O emissions of a wastewater treatment bioreactor was sampled by a dedicated mobile sampling device, and the total N2O emissions were analyzed in the gastight headspace of the bioreactor. We found that the use of a quantum-cascade laser emitting at about 4.53 μm, operated in a wavelength modulation mode, in combination with a conventional longitudinal PA cell yielded the highest sensitivity (<100 ppbv). However, we also observed a strong cross-sensitivity to humidity, which can be explained by increased V-T relaxation. This observation in combination with the limited dynamic range (max conc. ∼ 3000 ppmv) led us to the use of the less-sensitive but spectroscopically more robust 2.9 μm laser. A detection limit below 1 ppmv, a dynamic range of more than 4 orders of magnitude, no influence of humidity or any other substance relevant to the off-gas analysis, as well as a comparable low price of the laser source made it the ideal tool for N2O analyses of the off-gas of a wastewater treatment plant. Such a system was implemented successfully in a full-scale wastewater treatment plant. The results regarding the comparison of different PA setups can be transferred to other systems, and the optimum performance can be selected according to the specific demands.
authors.affiliation: Chair of Analytical Chemistry, Institute of Hydrochemistry, Technical University of Munich , Marchioninistrasse 17, 81377 Munich, Germany.
authors.forename: Klemens M
authors.initials: KM
authors.lastname: Thaler
authors.affiliation: Chair of Analytical Chemistry, Institute of Hydrochemistry, Technical University of Munich , Marchioninistrasse 17, 81377 Munich, Germany.
authors.forename: Christoph
authors.initials: C
authors.lastname: Berger
authors.affiliation: Chair of Urban Water Systems Engineering, Technical University of Munich , Am Coulombwall 3, 85748 Garching, Germany.
authors.forename: Carmen
authors.initials: C
authors.lastname: Leix
authors.affiliation: Chair of Urban Water Systems Engineering, Technical University of Munich , Am Coulombwall 3, 85748 Garching, Germany.
authors.forename: Jörg
authors.initials: J
authors.lastname: Drewes
authors.affiliation: Chair of Analytical Chemistry, Institute of Hydrochemistry, Technical University of Munich , Marchioninistrasse 17, 81377 Munich, Germany.
authors.forename: Reinhard
authors.initials: R
authors.lastname: Niessner
authors.affiliation: Chair of Analytical Chemistry, Institute of Hydrochemistry, Technical University of Munich , Marchioninistrasse 17, 81377 Munich, Germany.
authors.forename: Christoph
authors.initials: C
authors.lastname: Haisch