title: Interactional effect of cerium and manganese on NO catalytic oxidation.
abstract: To preferably catalyze the oxidation of NO to NO2in diesel after-treatment system, a series of CeO2-MnOxcomposite oxides was supported on silica-alumina material by the co-impregnation method. The maximum conversion of NO of the catalyst with a Ce/Mn weight ratio of 5:5 was improved by around 40%, compared to the supported manganese-only or cerium-only sample. And its maximum reaction rate was 0.056 μmol g-1s-1at 250 °C at the gas hourly space velocity of 30,000 h-1. The experimental results suggested that Ce-Mn solid solution was formed, which could modulate the valence state of cerium and manganese and exhibit great redox properties. Moreover, the strong interaction between ceria and manganese resulted in the largest desorption amount of strong chemical oxygen and oxygen vacancies, leading to the maximum Oαarea ratio of 62.26% from the O 1s result. These effective oxygen species could be continually transferred to the surface, leading to the best NO catalytic activity of 5Ce5Mn/SA catalyst. Graphical abstract.
authors.affiliation: Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Wangjiang Road 29, Chengdu, Sichuan, 610064, China.
authors.forename: Yanli
authors.initials: Y
authors.lastname: Liang
authors.affiliation: Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Wangjiang Road 29, Chengdu, Sichuan, 610064, China.
authors.forename: Yufen
authors.initials: Y
authors.lastname: Huang
authors.affiliation: Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Wangjiang Road 29, Chengdu, Sichuan, 610064, China.
authors.forename: Hailong
authors.initials: H
authors.lastname: Zhang
authors.affiliation: Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Wangjiang Road 29, Chengdu, Sichuan, 610064, China.
authors.forename: Li
authors.initials: L
authors.lastname: Lan
authors.affiliation: Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Wangjiang Road 29, Chengdu, Sichuan, 610064, China.
authors.forename: Ming
authors.initials: M
authors.lastname: Zhao
authors.affiliation: Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Wangjiang Road 29, Chengdu, Sichuan, 610064, China.
authors.forename: Maochu
authors.initials: M
authors.lastname: Gong
authors.affiliation: Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Wangjiang Road 29, Chengdu, Sichuan, 610064, China.
authors.forename: Yaoqiang
authors.initials: Y
authors.lastname: Chen
authors.affiliation: Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Wangjiang Road 29, Chengdu, Sichuan, 610064, China. wangjianli@scu.edu.cn.
authors.forename: Jianli
authors.initials: J
authors.lastname: Wang
mesh_terms: D002384:Catalysis; D002563:Cerium / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry*; D010084:Oxidation-Reduction; D010087:Oxides / Q000737:chemistry
chemical_list: D010087:Oxides; D002563:Cerium; D008345:Manganese
keywords: Ceria; Interaction; Manganese; NO oxidation; Redox property; Valence state