title: Hierarchical structure and porosity in UiO-66 polyMOFs.
abstract: The first polymer-MOF hybrid material (polyMOF) with a UiO-66 architecture is reported, prepared from polymers with varying alkyl spacers, molecular weights, and dispersities. With appropriate spacing, mesoporous UiO-66 polyMOF can be obtained having an uncommon, interlaced crystal morphology, suggesting that polyMOFs can be used to generate MOF materials with hierarchical architectures.
authors.affiliation: Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92023-0358, USA. scohen@ucsd.edu.
authors.forename: Sergio
authors.initials: S
authors.lastname: Ayala
authors.affiliation: Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92023-0358, USA. scohen@ucsd.edu.
authors.forename: Zhenjie
authors.initials: Z
authors.lastname: Zhang
authors.affiliation: Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92023-0358, USA. scohen@ucsd.edu.
authors.forename: Seth M
authors.identifier: http://orcid.org/0000-0002-5233-2280
authors.initials: SM
authors.lastname: Cohen