title: Ultrathin Iron-Cobalt Oxide Nanosheets with Abundant Oxygen Vacancies for the Oxygen Evolution Reaction.
abstract: Electrochemical water splitting is a promising method for storing light/electrical energy in the form of H2fuel; however, it is limited by the sluggish anodic oxygen evolution reaction (OER). To improve the accessibility of H2production, it is necessary to develop an efficient OER catalyst with large surface area, abundant active sites, and good stability, through a low-cost fabrication route. Herein, a facile solution reduction method using NaBH4as a reductant is developed to prepare iron-cobalt oxide nanosheets (FexCoy-ONSs) with a large specific surface area (up to 261.1 m2g-1), ultrathin thickness (1.2 nm), and, importantly, abundant oxygen vacancies. The mass activity of Fe1Co1-ONS measured at an overpotential of 350 mV reaches up to 54.9 A g-1, while its Tafel slope is 36.8 mV dec-1; both of which are superior to those of commercial RuO2, crystalline Fe1Co1-ONP, and most reported OER catalysts. The excellent OER catalytic activity of Fe1Co1-ONS can be attributed to its specific structure, e.g., ultrathin nanosheets that could facilitate mass diffusion/transport of OH-ions and provide more active sites for OER catalysis, and oxygen vacancies that could improve electronic conductivity and facilitate adsorption of H2O onto nearby Co3+sites.
authors.affiliation: School of Chemical Engineering, The University of Queensland, Brisbane, 4072, Australia.
authors.forename: Linzhou
authors.initials: L
authors.lastname: Zhuang
authors.affiliation: School of Chemical Engineering, The University of Queensland, Brisbane, 4072, Australia.
authors.forename: Lei
authors.initials: L
authors.lastname: Ge
authors.affiliation: School of Chemical Engineering, The University of Queensland, Brisbane, 4072, Australia.
authors.forename: Yisu
authors.initials: Y
authors.lastname: Yang
authors.affiliation: School of Chemical Engineering, The University of Queensland, Brisbane, 4072, Australia.
authors.forename: Mengran
authors.initials: M
authors.lastname: Li
authors.affiliation: School of Natural Sciences and Queensland Micro- and Nanotechnology Centre, Griffith University, Nathan Campus, 4111, Australia.
authors.forename: Yi
authors.initials: Y
authors.lastname: Jia
authors.affiliation: School of Natural Sciences and Queensland Micro- and Nanotechnology Centre, Griffith University, Nathan Campus, 4111, Australia.
authors.forename: Xiangdong
authors.initials: X
authors.lastname: Yao
authors.affiliation: School of Chemical Engineering, The University of Queensland, Brisbane, 4072, Australia.
authors.forename: Zhonghua
authors.initials: Z
authors.lastname: Zhu
keywords: oxygen evolution reaction; oxygen vacancies; sodium borohydride; ultrathin nanosheets