title: Zeolitic imidazolate framework-8 for efficient adsorption and removal of Cr(VI) ions from aqueous solution.
abstract: Heavy metals are emerging toxic pollutants in which the development of advanced materials for their efficient adsorption and separation is thus of great significance in environmental sciences point of view. In this study, one of the zinc-based zeolitic imidazolate framework materials, known as ZIF-8, has been synthesized and used for chromium(VI) contaminant removal from water for the first time. The as-synthesized ZIF-8 adsorbent was characterized with different methodologies such as powder X-ray diffraction (XRD), thermo-gravimetric analysis, FT-IR, nuclear magnetic resonance spectroscopy, and UV-Vis spectra of solid state. Various factors affecting removal percentage (efficiency) are experimentally investigated including pH of solution, adsorbent dosage, contact time and initial concentration of Cr(VI) to achieve the optimal condition. The obtained results indicate that the ZIF-8 shows good performance for the Cr(VI) removal from aqueous solution so that 60 min mixing of 2 g of ZIF-8 adsorbent with the 2.5 ppm of Cr(VI) solution in a neutral environment will result in the highest separation efficiency around 70%. The time needed to reach the equilibrium (maximum separation efficiency) is only 60 min for a concentration of 5 mg L-1. Structure stability in the presence of water is also carefully examined by XRD determination of ZIF-8 under different contact times in aqueous solution, which suggests that the structure is going to be destructed after 60 min immersed in solution. Electrostatic interaction of Cr(VI) anions by positively charged ZIF-8 is responsible for Cr(VI) adsorption and separation. Moreover, equilibrium adsorption study reveals that the Cr(VI) removal process using ZIF-8 nicely fits the Langmuir and Toth isotherm models which mean the adsorbent has low heterogeneous surface with different distributions of adsorption energies during Cr(VI) adsorption. Equilibrium adsorption capacity is observed around 0.25 for 20 mg L-1of initial Cr(VI) solutions.
authors.affiliation: Department of Chemical Engineering, Quchan University of Advanced Technology, Quchan, Iran. M.Niknam.sh@qiet.ac.ir.
authors.forename: Mahdi
authors.initials: M
authors.lastname: Niknam Shahrak
authors.affiliation: Department of Chemical Engineering, Quchan University of Advanced Technology, Quchan, Iran.
authors.forename: Mahboube
authors.initials: M
authors.lastname: Ghahramaninezhad
authors.affiliation: Department of Chemical Engineering, Quchan University of Advanced Technology, Quchan, Iran.
authors.forename: Mohsen
authors.initials: M
authors.lastname: Eydifarash
mesh_terms: D000327:Adsorption; D002857:Chromium / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D007477:Ions; D007700:Kinetics; D017550:Spectroscopy, Fourier Transform Infrared; D014874:Water Pollutants, Chemical / Q000737:chemistry; D017641:Zeolites / Q000737:chemistry*
chemical_list: D007477:Ions; D014874:Water Pollutants, Chemical; D002857:Chromium; D017641:Zeolites; C074702:chromium hexavalent ion
keywords: Adsorption; Chromium(VI) ions; Heavy metals; ZIF-8