title: Self-repairing metal-organic hybrid complexes for reinforcing immobilized chloroperoxidase reusability.
abstract: A self-repairing metal-enzyme hybrid nanocatalyst with a sodium alginate (SA) coating was reported in this study. Compared with free CPO, immobilized chloroperoxidase (CPO) has similar Kmand Kcatvalues. SA-coated CPO@Ca3(PO4)2hybrid composites displayed robust reusability under acidic conditions, maintaining more than 85% of the catalytic activity after 12 recycles.
authors.affiliation: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, P. R. China. lianghao@mail.buct.edu.cn.
authors.forename: Yan
authors.initials: Y
authors.lastname: Liu
authors.affiliation: Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, P. R. China.
authors.forename: Yumei
authors.initials: Y
authors.lastname: Zhang
authors.affiliation: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, P. R. China. lianghao@mail.buct.edu.cn.
authors.forename: Xuejian
authors.initials: X
authors.lastname: Li
authors.affiliation: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, P. R. China. lianghao@mail.buct.edu.cn and Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, P. R. China.
authors.forename: Qipeng
authors.initials: Q
authors.lastname: Yuan
authors.affiliation: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, P. R. China. lianghao@mail.buct.edu.cn and Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, P. R. China.
authors.forename: Hao
authors.identifier: http://orcid.org/0000-0002-4799-882X
authors.initials: H
authors.lastname: Liang
mesh_terms: D000464:Alginates / Q000737:chemistry / Q000494:pharmacology*; D002118:Calcium / Q000737:chemistry / Q000494:pharmacology*; D002711:Chloride Peroxidase / Q000378:metabolism*; D004795:Enzyme Stability / Q000187:drug effects; D004800:Enzymes, Immobilized / Q000378:metabolism*; D020723:Glucuronic Acid / Q000737:chemistry / Q000494:pharmacology; D006603:Hexuronic Acids / Q000737:chemistry / Q000494:pharmacology; D006801:Humans; D009942:Organometallic Compounds / Q000737:chemistry / Q000494:pharmacology*
chemical_list: D000464:Alginates; D004800:Enzymes, Immobilized; D006603:Hexuronic Acids; D009942:Organometallic Compounds; D020723:Glucuronic Acid; D002711:Chloride Peroxidase; D002118:Calcium