title: Tetradecanuclearity in 3d-4f chemistry: relaxation and magnetocaloric effects in [NiLn] species.
abstract: The employment of 2-amino-isobutyric acid, Haib, and 2-hydroxy-1-naphthaldehyde, Hnaphth, in NiII/LnIIIchemistry has led to the isolation and characterization of two new isostructural 3d-4f tetradecanuclear [NiLn] clusters (Ln = GdIII, DyIII), with the Dy analogue displaying temperature and frequency dependent out-of-phase signals, and the Gd analogue showing interesting magnetocaloric properties.
authors.affiliation: Department of Chemistry, University of Crete, Voutes 71003, Herakleion, Greece. komil@uoc.gr.
authors.forename: Angelos B
authors.initials: AB
authors.lastname: Canaj
authors.affiliation: Department of Chemistry, University of Crete, Voutes 71003, Herakleion, Greece. komil@uoc.gr.
authors.forename: Dimitris A
authors.initials: DA
authors.lastname: Kalofolias
authors.affiliation: Faculty of Chemistry, University of Wroclaw, Joliot-Curie 14, Wroclaw 50-383, Poland.
authors.forename: Milosz
authors.initials: M
authors.lastname: Siczek
authors.affiliation: Faculty of Chemistry, University of Wroclaw, Joliot-Curie 14, Wroclaw 50-383, Poland.
authors.forename: Tadeusz
authors.initials: T
authors.lastname: Lis
authors.affiliation: EaStCHEM School of Chemistry, The University of Edinburgh, David Brewster Road, EH9 3FJ, Edinburgh, UK.
authors.forename: Robbie
authors.initials: R
authors.lastname: McNab
authors.affiliation: Instituto de Ciencia de Materiales de Aragón (ICMA), CSIC - Universidad de Zaragoza, 50009 Zaragoza, Spain.
authors.forename: Giulia
authors.initials: G
authors.lastname: Lorusso
authors.affiliation: EaStCHEM School of Chemistry, The University of Edinburgh, David Brewster Road, EH9 3FJ, Edinburgh, UK.
authors.forename: Ross
authors.identifier: http://orcid.org/0000-0001-9467-4150
authors.initials: R
authors.lastname: Inglis
authors.affiliation: Instituto de Ciencia de Materiales de Aragón (ICMA), CSIC - Universidad de Zaragoza, 50009 Zaragoza, Spain.
authors.forename: Marco
authors.identifier: http://orcid.org/0000-0002-8028-9064
authors.initials: M
authors.lastname: Evangelisti
authors.affiliation: Department of Chemistry, University of Crete, Voutes 71003, Herakleion, Greece. komil@uoc.gr.
authors.forename: Constantinos J
authors.initials: CJ
authors.lastname: Milios