title: Palladium-Catalyzed Formylation of Arylzinc Reagents with S-Phenyl Thioformate.
abstract: The first example of palladium-catalyzed direct formylation of arylzinc reagents using S-phenyl thioformate is reported. The reaction proceeded under mild conditions, allowing high functional group tolerance. In addition, the developed formylation method was used to prepare deuterated and13C-labeled aryl aldehydes from isotope-labeled S-phenyl thioformates. Moreover, this procedure was applied to an alkenylzinc halide, affording the corresponding enal.
authors.affiliation: Department of Applied Chemistry, Institute of Science and Engineering, Chuo University , 1-13-27 Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan.
authors.forename: Ryosuke
authors.identifier: 0000-0001-6703-8036
authors.initials: R
authors.lastname: Haraguchi
authors.affiliation: Department of Applied Chemistry, Institute of Science and Engineering, Chuo University , 1-13-27 Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan.
authors.forename: Sho-Go
authors.initials: SG
authors.lastname: Tanazawa
authors.affiliation: Department of Applied Chemistry, Institute of Science and Engineering, Chuo University , 1-13-27 Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan.
authors.forename: Naoya
authors.initials: N
authors.lastname: Tokunaga
authors.affiliation: Department of Applied Chemistry, Institute of Science and Engineering, Chuo University , 1-13-27 Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan.
authors.forename: Shin-Ichi
authors.initials: SI
authors.lastname: Fukuzawa