title: Composite System of Ag Nanoparticles and Metal-Organic Frameworks for the Capture and Conversion of Carbon Dioxide under Mild Conditions.
abstract: The materials Ag@MIL-100(Fe) and Ag@UIO-66(Zr) are obtained for the capture and transformation of CO2into alkynyl carboxylic acids, which are environmental friendly, facile to synthesize, and exhibit excellent efficiency and reusability. The influence on the catalytic activity of such Ag@MOF systems by metal-organic frameworks' (MOFs) surface area, thermal, and chemical stability, especially the acid-base characteristics of the pores, are compared and discussed systematically.
authors.affiliation: Department of Chemistry and Key Laboratory of Advanced Energy Material Chemistry, Nankai University , Tianjin 300071, China.
authors.forename: Ning-Ning
authors.initials: NN
authors.lastname: Zhu
authors.affiliation: Department of Chemistry and Key Laboratory of Advanced Energy Material Chemistry, Nankai University , Tianjin 300071, China.|College of Materials Science and Engineering, Hebei University of Engineering , Handan, Hebei 056038, China.
authors.forename: Xiao-Huan
authors.initials: XH
authors.lastname: Liu
authors.affiliation: Department of Chemistry and Key Laboratory of Advanced Energy Material Chemistry, Nankai University , Tianjin 300071, China.
authors.forename: Tao
authors.initials: T
authors.lastname: Li
authors.affiliation: Department of Chemistry and Key Laboratory of Advanced Energy Material Chemistry, Nankai University , Tianjin 300071, China.
authors.forename: Jian-Gong
authors.identifier: http://orcid.org/0000-0001-7407-5521
authors.initials: JG
authors.lastname: Ma
authors.affiliation: Department of Chemistry and Key Laboratory of Advanced Energy Material Chemistry, Nankai University , Tianjin 300071, China.|Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) , Tianjin 300071, China.
authors.forename: Peng
authors.identifier: http://orcid.org/0000-0003-0396-1846
authors.initials: P
authors.lastname: Cheng
authors.affiliation: Department of Chemistry and Key Laboratory of Advanced Energy Material Chemistry, Nankai University , Tianjin 300071, China.
authors.forename: Guang-Ming
authors.initials: GM
authors.lastname: Yang