title: High fluorescence emission silver nano particles coated with poly (styrene-g-soybean oil) graft copolymers: Antibacterial activity and polymerization kinetics.
abstract: Autoxidation of poly unsaturated fatty acids makes negative effect on foods. In this work, this negative effect was turned to a great advantage using autoxidized soybean oil as a macroperoxide nanocomposite initiator containing silver nano particles in free radical polymerization of vinyl monomers. The synthesis of soybean oil macro peroxide was carried out by exposing soybean oil to air oxygen with the presence of silver nanoparticles (Ag NPs) at room temperature. Autoxidized soybean oil macroperoxide containing silver nanoparticles (Agsbox) successfully initiated the free radical polymerization of styrene in order to obtain Polystyrene (PS)-g-soybean oil graft copolymer containing Ag NPs. Both autoxidized soybean oil and PS-g-sbox with Ag NPs showed a surface plasmon resonance and high fluorescence emission. Overall rate constant (K) of styrene polymerization initiated by autoxidized soybean oil macroperoxide with Ag NPs was found to be K=1.95.10-4Lmol-1s-1at 95°C. Antibacterial efficiency was observed in the PS-g-soybean oil graft copolymer film samples containing Ag NPs.1H NMR and GPC techniques were used for the structural analysis of the fractionated polymeric oils.
authors.affiliation: Bülent Ecevit University, Department of Chemistry, 67100 Zonguldak, Turkey. Electronic address: bkhazer@beun.edu.tr.
authors.forename: Baki
authors.initials: B
authors.lastname: Hazer
authors.affiliation: Bülent Ecevit University, Department of Physics, 67100 Zonguldak, Turkey.
authors.forename: Özlem A
authors.initials: ÖA
authors.lastname: Kalaycı
mesh_terms: D000900:Anti-Bacterial Agents / Q000737:chemistry* / Q000494:pharmacology; D002152:Calorimetry, Differential Scanning; D004926:Escherichia coli / Q000187:drug effects; D007700:Kinetics; D009682:Magnetic Resonance Spectroscopy; D053768:Metal Nanoparticles / Q000737:chemistry*; D046529:Microscopy, Electron, Transmission; D010316:Particle Size; D058105:Polymerization; D011137:Polystyrenes / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D013024:Soybean Oil / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared; D020349:Surface Plasmon Resonance; D013696:Temperature
chemical_list: D000900:Anti-Bacterial Agents; D011137:Polystyrenes; D012834:Silver; D013024:Soybean Oil
keywords: Ag nano particles; Autoxidation; Fluorescence emission; Polymerization kinetics; Soybean oil