title: ortho-Quinol Acetate Chemistry: Reactivity toward Aryl-Based Nucleophiles and Applications to the Synthesis of Natural Products.
abstract: Two model ortho-quinol acetates were easily prepared by iodane-mediated acetoxylative phenol dearomatization and evaluated for their reactivity toward various aryl-based nucleophiles, i.e., aryl metallic reagents and phenolic derivatives. Novel modes of reactivity, allowing the formation of biaryl linkages, were revealed and here exploited for the synthesis of two natural phenolics.
authors.affiliation: Institut des Sciences Moléculaires, Univ. Bordeaux, ISM (CNRS-UMR 5255) , 351 cours de la Libération, 33405 Talence, France.|ITAV, Université de Toulouse, CNRS, UPS , Toulouse, France.
authors.forename: Simon
authors.initials: S
authors.lastname: Companys
authors.affiliation: Institut des Sciences Moléculaires, Univ. Bordeaux, ISM (CNRS-UMR 5255) , 351 cours de la Libération, 33405 Talence, France.
authors.forename: Laurent
authors.initials: L
authors.lastname: Pouységu
authors.affiliation: Institut des Sciences Moléculaires, Univ. Bordeaux, ISM (CNRS-UMR 5255) , 351 cours de la Libération, 33405 Talence, France.
authors.forename: Philippe A
authors.initials: PA
authors.lastname: Peixoto
authors.affiliation: ITAV, Université de Toulouse, CNRS, UPS , Toulouse, France.
authors.forename: Stefan
authors.initials: S
authors.lastname: Chassaing
authors.affiliation: Institut des Sciences Moléculaires, Univ. Bordeaux, ISM (CNRS-UMR 5255) , 351 cours de la Libération, 33405 Talence, France.
authors.forename: Stéphane
authors.identifier: 0000-0002-7079-9757
authors.initials: S
authors.lastname: Quideau
mesh_terms: D000085:Acetates / Q000737:chemistry*; D001688:Biological Products / Q000138:chemical synthesis*; D006873:Hydroquinones / Q000737:chemistry*
chemical_list: D000085:Acetates; D001688:Biological Products; D006873:Hydroquinones