title: Partial delignification of wood and membrane preparation using a quaternary ammonium ionic liquid.
abstract: This work determined that southern yellow pine wood can almost be completely dissolved in the quaternary ammonium ionic liquid tetrabutylammonium acetate with dimethyl sulfoxide (in a 2:8 mass ratio), after minimal grinding, upon heating at 85 °C for three dissolution/reconstitution cycles, each 1.5 h. Approximately 34.6% of the native lignin and 67.4% of the native carbohydrates present in the original wood can subsequently be extracted, respectively, and were assessed. A gradual decrease in lignin with increased extraction cycles resulted in increased crystallinity index of the cellulose II in the cellulose-rich residue, as confirmed by X-ray diffraction. An increasingly homogeneous macrostructure in the cellulose-rich residue was also evident from scanning electron microscopy images. Membranes cast directly from either wood or cellulose-rich residue solutions in the same tetrabutylammonium acetate/dimethyl sulfoxide system, were prepared using a papermaking-like process. Morphological and mechanical studies indicated that lignin extraction made the membranes more uniform and flexible. Systematic increases in the fibril lengths and orientations of the recovered materials were also found with decreasing lignin contents on the basis of atomic force microscopy analysis. This work demonstrates that relatively efficient partial separation of pine wood and subsequent membrane preparation are possible using a quaternary ammonium ionic liquid.
authors.affiliation: MOE Key Laboratory of Wooden Material Science and Application, College of Materials Science and Technology, Beijing Forestry University, Beijing 100083, PR China.
authors.forename: Jiaojiao
authors.initials: J
authors.lastname: Miao
authors.affiliation: MOE Key Laboratory of Wooden Material Science and Application, College of Materials Science and Technology, Beijing Forestry University, Beijing 100083, PR China.
authors.forename: Yongqi
authors.initials: Y
authors.lastname: Yu
authors.affiliation: MOE Key Laboratory of Wooden Material Science and Application, College of Materials Science and Technology, Beijing Forestry University, Beijing 100083, PR China.
authors.forename: Zeming
authors.initials: Z
authors.lastname: Jiang
authors.affiliation: MOE Key Laboratory of Wooden Material Science and Application, College of Materials Science and Technology, Beijing Forestry University, Beijing 100083, PR China.
authors.forename: Lan
authors.initials: L
authors.lastname: Tang
authors.affiliation: MOE Key Laboratory of Wooden Material Science and Application, College of Materials Science and Technology, Beijing Forestry University, Beijing 100083, PR China.
authors.forename: Liping
authors.initials: L
authors.lastname: Zhang