title: Isatin functionalized nanoporous SBA-15 as a selective fluorescent probe for the detection of Hg(II) in water.
abstract: A highly ordered mesoporous silica material functionalized with isatin (SBA-Pr-IS) was designed and synthesized. Characterization techniques including XRD, TGA, BET, SEM, and FT-IR were employed to characterize the pore structure, textural properties, microscopic morphology, and molecular composition of grafted organic moieties of SBA-Pr-IS. The successful attachment of the organic moiety (0.34 mmol g-1) without the SBA-15 structure collapsing after the modification steps was confirmed. Fluorescence characterization of SBA-Pr-IS was examined upon addition of a wide variety of cations in aqueous medium and it showed high sensitivity toward Hg2+ions. During testing in an ion competition experiment, it was observed that the fluorescence changes of the probe were remarkably specific for Hg2+ions. Furthermore, a good linearity between the fluorescence intensity of this material and the concentration of Hg2+ions was constructed with a suitable detection limit of 3.7 × 10-6M. Finally, the applicability of the proposed method was successfully evaluated for the determination of Hg2+ions in real samples. Therefore, SBA-Pr-IS can be used as an efficient fluorescence probe for Hg2+ions. Graphical Abstract A novel organic-inorganic hybrid material was designed and synthesized by functionalization of SBA-15 mesoporous silica material with isatin. The evaluation of the sensing ability of SBA-Pr-IS using fluorescence spectroscopy revealed that the SBA-Pr-IS was a selective fluorescent probe for Hg2+ion in water in the presence of a wide range of metal cations.
authors.affiliation: School of Chemistry, College of Science, University of Tehran, 16th Azar St., Enghelab Sq., 1417466191, Tehran, Iran.
authors.forename: Negar
authors.initials: N
authors.lastname: Lashgari
authors.affiliation: School of Chemistry, College of Science, University of Tehran, 16th Azar St., Enghelab Sq., 1417466191, Tehran, Iran. abadiei@khayam.ut.ac.ir.|Nanobiomedicine Center of Excellence, Nanoscience and Nanotechnology Research Center, University of Tehran, 16th Azar St., Enghelab Sq., 1417466191, Tehran, Iran. abadiei@khayam.ut.ac.ir.
authors.forename: Alireza
authors.initials: A
authors.lastname: Badiei
authors.affiliation: Department of Chemistry, Alzahra University, 1993891176, Tehran, Iran.
authors.forename: Ghodsi
authors.initials: G
authors.lastname: Mohammadi Ziarani
authors.affiliation: Center of Excellence in Electrochemistry, School of Chemistry, College of Science, University of Tehran, 16th Azar St., Enghelab Sq., 1417466191, Tehran, Iran.
authors.forename: Farnoush
authors.initials: F
authors.lastname: Faridbod
keywords: Fluorescent probe; Hg2+ ion; Isatin; Nanoporous silica; SBA-15