title: Photochemical Carboxylation of Activated C(sp3)-H Bonds with CO2.
abstract: From ugly duckling to beautiful C1: Although CO2may represent an ideal C1 source, it is challenging to use it as a raw material and direct carboxylation with CO2has mainly been confined to highly reactive species. However, recent significant breakthroughs have been made in photochemical carboxylation of challenging, un-acidic, C(sp3)-H bonds, including benzylic, allylic and amine C-H bonds.
authors.affiliation: Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu, 610064, PR China.
authors.forename: Yong-Yuan
authors.identifier: 0000-0002-0753-7519
authors.initials: YY
authors.lastname: Gui
authors.affiliation: Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu, 610064, PR China.|College of Chemistry and Chemical Engineering, Neijiang Normal University, Neijiang, 641112, PR China.
authors.forename: Wen-Jun
authors.identifier: 0000-0001-5933-4679
authors.initials: WJ
authors.lastname: Zhou
authors.affiliation: Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu, 610064, PR China.
authors.forename: Jian-Heng
authors.identifier: 0000-0002-4932-0414
authors.initials: JH
authors.lastname: Ye
authors.affiliation: Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu, 610064, PR China.
authors.forename: Da-Gang
authors.identifier: 0000-0001-5888-1494
authors.initials: DG
authors.lastname: Yu
mesh_terms: D002244:Carbon / Q000737:chemistry*; D002245:Carbon Dioxide / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry*; D002384:Catalysis; D006859:Hydrogen / Q000737:chemistry*; D055668:Photochemical Processes
chemical_list: D002264:Carboxylic Acids; D002245:Carbon Dioxide; D002244:Carbon; D006859:Hydrogen
keywords: C1 building blocks; C−H activation; carbon dioxide; carboxylation; photochemistry