title: Cavity Born-Oppenheimer Approximation for Correlated Electron-Nuclear-Photon Systems.
abstract: In this work, we illustrate the recently introduced concept of the cavity Born-Oppenheimer approximation [ Flick et al. PNAS 2017 , 10.1073/pnas.1615509114 ] for correlated electron-nuclear-photon problems in detail. We demonstrate how an expansion in terms of conditional electronic and photon-nuclear wave functions accurately describes eigenstates of strongly correlated light-matter systems. For a GaAs quantum ring model in resonance with a photon mode we highlight how the ground-state electronic potential-energy surface changes the usual harmonic potential of the free photon mode to a dressed mode with a double-well structure. This change is accompanied by a splitting of the electronic ground-state density. For a model where the photon mode is in resonance with a vibrational transition, we observe in the excited-state electronic potential-energy surface a splitting from a single minimum to a double minimum. Furthermore, for a time-dependent setup, we show how the dynamics in correlated light-matter systems can be understood in terms of population transfer between potential energy surfaces. This work at the interface of quantum chemistry and quantum optics paves the way for the full ab initio description of matter-photon systems.
authors.affiliation: Department of Physics, Max Planck Institute for the Structure and Dynamics of Matter and Center for Free-Electron Laser Science , Luruper Chaussee 149, 22761 Hamburg, Germany.
authors.forename: Johannes
authors.identifier: http://orcid.org/0000-0003-0273-7797
authors.initials: J
authors.lastname: Flick
authors.affiliation: Department of Physics, Max Planck Institute for the Structure and Dynamics of Matter and Center for Free-Electron Laser Science , Luruper Chaussee 149, 22761 Hamburg, Germany.
authors.forename: Heiko
authors.initials: H
authors.lastname: Appel
authors.affiliation: Department of Physics, Max Planck Institute for the Structure and Dynamics of Matter and Center for Free-Electron Laser Science , Luruper Chaussee 149, 22761 Hamburg, Germany.
authors.forename: Michael
authors.initials: M
authors.lastname: Ruggenthaler
authors.affiliation: Department of Physics, Max Planck Institute for the Structure and Dynamics of Matter and Center for Free-Electron Laser Science , Luruper Chaussee 149, 22761 Hamburg, Germany.|Nano-Bio Spectroscopy Group and ETSF, Departamento Fisica de Materiales, Universidad del País Vasco , 20018 San Sebastián, Spain.
authors.forename: Angel
authors.initials: A
authors.lastname: Rubio