title: A Diheteroatom Fluoroalkylation Reagent for Preparation of S- and N-Containing Fluoroalkyl Compounds and Sulfonic Acid Polymer.
abstract: The first stable diheteroatom fluoroalkylation reagent, 2-((2-azido-1-chloro-1,2,2-trifluoroethyl)thio)pyrimidine (ACTP), has been prepared by a novel method. By using this reagent, various fluorinated thioethers and sulfones have been successfully prepared. The dearylation and dearylation-oxidation of fluoroalkyl 2-pyrimidyl sulfone in one-pot reaction were investigated systematically, and the results demonstrated that both fluoroalkyl sulfinates and sulfonates could be obtained in high yields. In addition, ACTP proved to be useful for the preparation of a fluorinated sulfonic acid proton-exchange membrane.
authors.affiliation: CAS Key Laboratory of Soft Matter Chemistry and Department of Polymer Science and Engineering, University of Science and Technology of China , Jinzhai Road 96, Hefei, Anhui Province, People's Republic of China.
authors.forename: Jingwen
authors.initials: J
authors.lastname: Dai
authors.affiliation: CAS Key Laboratory of Soft Matter Chemistry and Department of Polymer Science and Engineering, University of Science and Technology of China , Jinzhai Road 96, Hefei, Anhui Province, People's Republic of China.
authors.forename: Zili
authors.initials: Z
authors.lastname: Li
authors.affiliation: CAS Key Laboratory of Soft Matter Chemistry and Department of Polymer Science and Engineering, University of Science and Technology of China , Jinzhai Road 96, Hefei, Anhui Province, People's Republic of China.
authors.forename: Taisheng
authors.initials: T
authors.lastname: Wang
authors.affiliation: Department of Chemistry, University of Tennessee , Knoxville, Tennessee 37996, United States.
authors.forename: Wei
authors.initials: W
authors.lastname: Bai
authors.affiliation: CAS Key Laboratory of Soft Matter Chemistry and Department of Polymer Science and Engineering, University of Science and Technology of China , Jinzhai Road 96, Hefei, Anhui Province, People's Republic of China.
authors.forename: Ruke
authors.identifier: 0000-0002-1310-316X
authors.initials: R
authors.lastname: Bai