title: Facile Route to Rare Heterobimetallic Aluminum-Copper and Aluminum-Zinc Selenide Clusters.
abstract: Heterobimetallic aluminum-copper and aluminum-zinc clusters were prepared from the reaction of LAl(SeH)2[1; L = HC(CMeNAr)2and Ar = 2,6-iPr2C6H3] with (MesCu)4and ZnEt2, respectively. The resulting clusters with the core structures of Al2Se4Cu4and Al2Se4Zn3exhibit unique metal-organic frameworks. This is a novel pathway for the synthesis of aluminum-copper and aluminum-zinc selenides. The products have been characterized by spectroscopic methods and single-crystal X-ray structural characterization.
authors.affiliation: State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005, China.
authors.forename: Bin
authors.initials: B
authors.lastname: Li
authors.affiliation: State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005, China.
authors.forename: Jiancheng
authors.initials: J
authors.lastname: Li
authors.affiliation: State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005, China.
authors.forename: Rui
authors.initials: R
authors.lastname: Liu
authors.affiliation: State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005, China.
authors.forename: Hongping
authors.identifier: http://orcid.org/0000-0002-9777-6731
authors.initials: H
authors.lastname: Zhu
authors.affiliation: Institut für Anorganische Chemie, Georg-August-Universität , Tammannstraβe 4, 37077 Göttingen, Germany.
authors.forename: Herbert W
authors.identifier: http://orcid.org/0000-0003-4454-1434
authors.initials: HW
authors.lastname: Roesky