title: Multifunctional Nano-engineered Polymer Surfaces with Enhanced Mechanical Resistance and Superhydrophobicity.
abstract: This paper presents a multifunctional polymer surface that provides superhydrophobicity and self-cleaning functions together with an enhancement in mechanical and electrical performance. These functionalities are produced by nanoimprinting high aspect ratio pillar arrays on polymeric matrix incorporating functional reinforcing elements. Two distinct matrix-filler systems are investigated specifically, Carbon Nanotube reinforced Polystyrene (CNT-PS) and Reduced Graphene Oxide reinforced Polyvinylidene Difluoride (RGO-PVDF). Mechanical characterization of the topographies by quantitative nanoindentation and nanoscratch tests are performed to evidence a considerable increase in stiffness, Young's modulus and critical failure load with respect to the pristine polymers. The improvement on the mechanical properties is rationalized in terms of effective dispersion and penetration of the fillers into the imprinted structures as determined by confocal Raman and SEM studies. In addition, an increase in the degree of crystallization for the PVDF-RGO imprinted nanocomposite possibly accounts for the larger enhancement observed. Improvement of the mechanical ruggedness of functional textured surfaces with appropriate fillers will enable the implementation of multifunctional nanotextured materials in real applications.
authors.affiliation: Madrid Institute for Advanced Studies in Nanoscience (IMDEA Nanoscience), C/Faraday 9, Ciudad Universitaria de Cantoblanco. 28049 Madrid, Spain.
authors.forename: Jaime J
authors.initials: JJ
authors.lastname: Hernández
authors.affiliation: Madrid Institute for Advanced Studies in Materials (IMDEA Materials), C/ Eric Kandel, 2, Tecnogetafe, Getafe. 28906 Madrid, Spain.
authors.forename: Miguel A
authors.initials: MA
authors.lastname: Monclús
authors.affiliation: Madrid Institute for Advanced Studies in Nanoscience (IMDEA Nanoscience), C/Faraday 9, Ciudad Universitaria de Cantoblanco. 28049 Madrid, Spain.
authors.forename: Iván
authors.initials: I
authors.lastname: Navarro-Baena
authors.affiliation: Madrid Institute for Advanced Studies in Nanoscience (IMDEA Nanoscience), C/Faraday 9, Ciudad Universitaria de Cantoblanco. 28049 Madrid, Spain.
authors.forename: Felipe
authors.initials: F
authors.lastname: Viela
authors.affiliation: Madrid Institute for Advanced Studies in Materials (IMDEA Materials), C/ Eric Kandel, 2, Tecnogetafe, Getafe. 28906 Madrid, Spain.
authors.forename: Jon M
authors.initials: JM
authors.lastname: Molina-Aldareguia
authors.affiliation: Madrid Institute for Advanced Studies in Nanoscience (IMDEA Nanoscience), C/Faraday 9, Ciudad Universitaria de Cantoblanco. 28049 Madrid, Spain.
authors.forename: Isabel
authors.initials: I
authors.lastname: Rodríguez