title: Pilot-scale removal of pharmaceuticals in municipal wastewater: Comparison of granular and powdered activated carbon treatment at three wastewater treatment plants.
abstract: Adsorption with activated carbon is widely suggested as an option for the removal of organic micropollutants including pharmaceutically active compounds (PhACs) in wastewater. In this study adsorption with granular activated carbon (GAC) and powdered activated carbon (PAC) was analyzed and compared in parallel operation at three Swedish wastewater treatment plants with the goal to achieve a 95% PhAC removal. Initially, mapping of the prevalence of over 100 substances was performed at each plant and due to low concentrations a final 22 were selected for further evaluation. These include carbamazepine, clarithromycin and diclofenac, which currently are discussed for regulation internationally. A number of commercially available activated carbon products were initially screened using effluent wastewater. Of these, a reduced set was selected based on adsorption characteristics and cost. Experiments designed with the selected carbons in pilot-scale showed that most products could indeed remove PhACs to the target level, both on total and individual basis. In a setup using internal recirculation the PAC system achieved a 95% removal applying a fresh dose of 15-20 mg/L, while carbon usage rates for the GAC application were much broader and ranged from <28 to 230 mg/L depending on the carbon product. The performance of the PAC products generally gave better results for individual PhACs in regards to carbon availability. All carbon products showed a specific adsorption for a specific PhAC meaning that knowledge of the target pollutants must be acquired before successful design of a treatment system. In spite of different configurations and operating conditions of the different wastewater treatment plants no considerable differences regarding pharmaceutical removal were observed.
authors.affiliation: Division of Industrial Biotechnology, KTH Royal Institute of Technology, AlbaNova University Center, SE-106 91 Stockholm, Sweden. Electronic address: karelid@kth.se.
authors.forename: Victor
authors.initials: V
authors.lastname: Kårelid
authors.affiliation: Division of Industrial Biotechnology, KTH Royal Institute of Technology, AlbaNova University Center, SE-106 91 Stockholm, Sweden. Electronic address: gen@biotech.kth.se.
authors.forename: Gen
authors.initials: G
authors.lastname: Larsson
authors.affiliation: Division of Industrial Biotechnology, KTH Royal Institute of Technology, AlbaNova University Center, SE-106 91 Stockholm, Sweden. Electronic address: berndtb@kth.se.
authors.forename: Berndt
authors.initials: B
authors.lastname: Björlenius
mesh_terms: D000327:Adsorption; D002244:Carbon; D014865:Waste Disposal, Fluid; D062065:Wastewater; D014874:Water Pollutants, Chemical; D018508:Water Purification
chemical_list: D002244:Carbon; D062065:Wastewater; D014874:Water Pollutants, Chemical
keywords: Adsorption; Advanced wastewater treatment; GAC; PAC; Pharmaceutical removal