title: Metal-free and light-promoted radical iodotrifluoromethylation of alkenes with Togni reagent as the source of CF3and iodine.
abstract: A light-promoted methodology for the iodotrifluoromethylation of alkenes was developed. For the first time a Togni reagent was exploited as the source of both the CF3group and iodine atom. Preliminary mechanistic studies suggest that both CF3I and 2-iodobenzoic acid are direct sources of the iodine atom that is transferred to the products.
authors.affiliation: Institut des Sciences Moléculaires, CNRS UMR 5255, Univ. Bordeaux, 33405 Talence, France. jm.vincent@ism.u-bordeaux1.fr.
authors.forename: Redouane
authors.initials: R
authors.lastname: Beniazza
authors.affiliation: Institut des Sciences Moléculaires, CNRS UMR 5255, Univ. Bordeaux, 33405 Talence, France. jm.vincent@ism.u-bordeaux1.fr.
authors.forename: Maxime
authors.initials: M
authors.lastname: Douarre
authors.affiliation: Institut des Sciences Moléculaires, CNRS UMR 5255, Univ. Bordeaux, 33405 Talence, France. jm.vincent@ism.u-bordeaux1.fr.
authors.forename: Dominique
authors.initials: D
authors.lastname: Lastécouères
authors.affiliation: Institut des Sciences Moléculaires, CNRS UMR 5255, Univ. Bordeaux, 33405 Talence, France. jm.vincent@ism.u-bordeaux1.fr.
authors.forename: Jean-Marc
authors.identifier: http://orcid.org/0000-0002-3122-9014
authors.initials: JM
authors.lastname: Vincent