title: Study on the noncoincidence effect phenomenon using matrix isolated Raman spectra and the proposed structural organization model of acetone in condense phase.
abstract: The isotropic and anisotropic Raman spectra of acetone and deuterated acetone isolated in an argon matrix have been recorded for the understanding of noncoincidence effect (NCE) phenomenon. According to the matrix isolated Raman spectra and DFT calculations, we proposed aggregated model for the explanations of the acetone C=O vibration NCE phenomenon and its concentration effect. The experimental data were in consistence with the DFT calculations performed at the B3LYP-D3/6-311 G (d,p) levels based on the proposed model. The experimental identification of the monomer, dimer and trimer are reported here, and the dynamic of the transformation from monomer to aggregated structure can be easily controlled by tuning annealing temperature.
authors.affiliation: Department of Chemistry and Engineering Research Center for Eco-dyeing and Finishing of Textiles, MOE, Zhejiang Sci-Tech University, Hangzhou 310018, China.
authors.forename: Wenwen
authors.initials: W
authors.lastname: Xu
authors.affiliation: Department of Chemistry and Engineering Research Center for Eco-dyeing and Finishing of Textiles, MOE, Zhejiang Sci-Tech University, Hangzhou 310018, China.
authors.forename: Fengqi
authors.initials: F
authors.lastname: Wu
authors.affiliation: Department of Chemistry and Engineering Research Center for Eco-dyeing and Finishing of Textiles, MOE, Zhejiang Sci-Tech University, Hangzhou 310018, China.
authors.forename: Yanying
authors.initials: Y
authors.lastname: Zhao
authors.affiliation: Department of Chemistry and Engineering Research Center for Eco-dyeing and Finishing of Textiles, MOE, Zhejiang Sci-Tech University, Hangzhou 310018, China.
authors.forename: Ran
authors.initials: R
authors.lastname: Zhou
authors.affiliation: Department of Chemistry and Engineering Research Center for Eco-dyeing and Finishing of Textiles, MOE, Zhejiang Sci-Tech University, Hangzhou 310018, China.
authors.forename: Huigang
authors.initials: H
authors.lastname: Wang
authors.affiliation: Department of Chemistry and Engineering Research Center for Eco-dyeing and Finishing of Textiles, MOE, Zhejiang Sci-Tech University, Hangzhou 310018, China.
authors.forename: Xuming
authors.initials: X
authors.lastname: Zheng
authors.affiliation: Texas A&M Univ, Dept Chem, Commerce, TX 75429, USA.
authors.forename: Bukuo
authors.initials: B
authors.lastname: Ni