title: Selective gas adsorption and fluorescence sensing response of a Zn(ii) metal-organic framework constructed by a mixed-ligand strategy.
abstract: By means of a mixed-ligand strategy, a novel bi-functional metal-organic framework, [H2N(CH3)2]·Zn(NDC)(atz)·H2O (NDC = 2,6-naphthalenedicarboxylic acid, Hatz = 1H-tetrazol-5-amine), was synthesized, which displays a three-dimensional two-fold interpenetrated framework. Owing to the introduction of two different functional organic ligands, this complex exhibits bi-functional properties, i.e., selective gas adsorption of CO2over CH4and fluorescence sensing response for nitrobenzene.
authors.affiliation: School of Materials Science and Engineering, National Institute for Advanced Materials, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300350, P. R. China. jxu@nankai.edu.cn.
authors.forename: Xiao-Jing
authors.initials: XJ
authors.lastname: Liu
authors.forename: Xi
authors.initials: X
authors.lastname: Wang
authors.forename: Jia-Li
authors.initials: JL
authors.lastname: Xu
authors.forename: Dan
authors.initials: D
authors.lastname: Tian
authors.forename: Rong-Ying
authors.initials: RY
authors.lastname: Chen
authors.forename: Jian
authors.initials: J
authors.lastname: Xu
authors.forename: Xian-He
authors.initials: XH
authors.lastname: Bu