title: Assessing impact of effluent discharge on irrigation water quality in southern region of Khyber Pakhtunkhwa, Pakistan.
abstract: Chemical quality and extent of pollution in effluent-contaminated irrigation water collected from two sectors (X and Y) of peri-urban southern regions of Khyber Pakhtunkhwa, Pakistan, were investigated. Various physico-chemical parameters like pH, EC, TS, TSS, TDS, TH, cations (Na1+, K1+, Li1+, Ca2+, Mg2+), anions (Cl1-, F1-, HCO31-, NO31-, SO42-), and heavy metals (Cr, Fe, Cu, Zn, Pb, Cd) were determined. The data indicated wide ranges of variation in all the parameters. Concentration of physico-chemical properties such as EC, TS, TSS, TH, Li1+, Ca2+, Mg2+, and HCO31-and heavy metals (Cr, Fe, Cu, and Cd) exceeded WHO permissible limits. The distribution of heavy metals in two sampling areas followed the increasing order as Fe > Cr > Cd > Cu > Pb > Zn. The Piper diagram showed that water in the region was of alkaline type. Strong positive correlations were observed among most of the parameters; however, pH was negatively correlated with most of the parameters. According to principle component analysis, parameters causing variations in water quality were mainly EC, TDS, TS, TSS, TH, Na1+, K1+, Ca2+, Mg2+, F1-, NO31-, SO42-, Cr, Fe, Cu, and Zn. Linear regression analysis revealed that heavy metals like Cr, Fe, and Cu concentrations were strongly correlated having an R2value of 0.92 at P ≤ 0.001 with pH. Overall, the results suggested that irrigation water of the area was not fit for irrigation purposes and might cause serious threats for safe, healthy food and feed production. Proper monitoring of water of the said area should be carried out, and quality of irrigation water should be checked from time to time.
authors.affiliation: Institute of Chemical Sciences, Gomal University, Dera Ismail Khan, Pakistan.
authors.forename: Shabnam
authors.initials: S
authors.lastname: Zafar
authors.affiliation: Institute of Chemical Sciences, Gomal University, Dera Ismail Khan, Pakistan.
authors.forename: Azim
authors.initials: A
authors.lastname: Khan
authors.affiliation: Institute of Chemical Sciences, Gomal University, Dera Ismail Khan, Pakistan. hidayatk2@yahoo.com.
authors.forename: Hidayat
authors.initials: H
authors.lastname: Ullah
authors.affiliation: Faculty of Agriculture, Gomal University, Dera Ismail Khan, Pakistan.
authors.forename: Muhammad Sohail
authors.initials: MS
authors.lastname: Khan
authors.affiliation: Institute of Chemical Sciences, Gomal University, Dera Ismail Khan, Pakistan.
authors.forename: Ilham
authors.initials: I
authors.lastname: Khan
authors.affiliation: Institute of Chemical Sciences, Gomal University, Dera Ismail Khan, Pakistan.
authors.forename: Asma
authors.initials: A
authors.lastname: Hameed
authors.affiliation: Pakistan Council of Research in Water Resources, Dera Ismail Khan, Pakistan.
authors.forename: Shafeeq Ur
authors.initials: SU
authors.lastname: Rehman
authors.affiliation: Department of Chemistry, Bahauddin Zakariya University Multan, Multan, Pakistan.
authors.forename: Ghazala
authors.initials: G
authors.lastname: Yasmeen
mesh_terms: D057914:Agricultural Irrigation; D004784:Environmental Monitoring; D005618:Fresh Water / Q000737:chemistry*; D019216:Metals, Heavy / Q000032:analysis; D010154:Pakistan; D014874:Water Pollutants, Chemical / Q000032:analysis*; D060753:Water Quality
chemical_list: D019216:Metals, Heavy; D014874:Water Pollutants, Chemical
keywords: Effluents; Heavy metals; Irrigation; Peri-urban; Pollution; Wastewater; Water quality