title: Charge-transfer dynamics at the dye-semiconductor interface of photocathodes for solar energy applications.
abstract: This article describes a comparison between the photophysical properties of two charge-transfer dyes adsorbed onto NiO via two different binding moieties. Transient spectroscopy measurements suggest that the structure of the anchoring group affects both the rate of charge recombination between the dye and NiO surface and the rate of dye regeneration by an iodide/triiodide redox couple. This is consistent with the performance of the dyes in p-type dye sensitised solar cells. A key finding was that the recombination rate differed in the presence of the redox couple. These results have important implications on the study of electron transfer at dye|semiconductor interfaces for solar energy applications.
authors.affiliation: School of Chemistry, Newcastle University, Newcastle Upon Tyne, NE1 7RU, UK. elizabeth.gibson@newcastle.ac.uk.
authors.forename: Fiona A
authors.initials: FA
authors.lastname: Black
authors.forename: Christopher J
authors.initials: CJ
authors.lastname: Wood
authors.forename: Simbarashe
authors.initials: S
authors.lastname: Ngwerume
authors.forename: Gareth H
authors.initials: GH
authors.lastname: Summers
authors.forename: Ian P
authors.initials: IP
authors.lastname: Clark
authors.forename: Michael
authors.initials: M
authors.lastname: Towrie
authors.forename: Jason E
authors.initials: JE
authors.lastname: Camp
authors.forename: Elizabeth A
authors.initials: EA
authors.lastname: Gibson