title: Ultrathin Al2O3interface achieving an 11.46% efficiency in planar n-Si/PEDOT:PSS hybrid solar cells.
abstract: Hybrid organic-inorganic photovoltaic devices consisting of poly(3,4-etyhlenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) and n-type silicon have recently been investigated for their cost-efficiency and ease of fabrication. We demonstrate that the insertion of an ultrathin Al2O3layer between n-Si and PEDOT:PSS significantly improves photovoltaic performance in comparison to the conventional interfacial oxide employing SiO2. A power-conversion efficiency of 11.46% was recorded at the optimal Al2O3thickness of 2.3 nm. This result was achieved based upon increased built-in potential and improved charge collection via the electron blocking effect of Al2O3. In addition, the hydrophilicity enhanced by Al2O3improved the coating uniformity of the PEDOT:PSS layer, resulting in a further reduction in surface recombination.
authors.affiliation: Department of Materials and Chemical Engineering, Hanyang University, Ansan, Kyounggi 426-791, Republic of Korea.
authors.forename: Yoon-Ho
authors.initials: YH
authors.lastname: Nam
authors.forename: Jae-Won
authors.initials: JW
authors.lastname: Song
authors.forename: Min-Joon
authors.initials: MJ
authors.lastname: Park
authors.forename: Abdul
authors.initials: A
authors.lastname: Sami
authors.forename: Jung-Ho
authors.initials: JH
authors.lastname: Lee