title: Ruthenium-catalyzed regioselective allylic amination of 2,3,3-trifluoroallylic carbonates.
abstract: We demonstrated the ruthenium-catalyzed allylic amination of 2,3,3-trifluoroallylic carbonates with several types of amines. The reactions proceeded with several types of amines, and succeeded in obtaining polyfluorinated terminal alkenes possessing branched allylic amines as a single regioisomer.
authors.affiliation: Department of Chemistry, College of Humanities & Sciences, Nihon University, Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan. kawatsur@chs.nihon-u.ac.jp.
authors.forename: Shin-Ichi
authors.initials: SI
authors.lastname: Isobe
authors.affiliation: Department of Chemistry, College of Humanities & Sciences, Nihon University, Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan. kawatsur@chs.nihon-u.ac.jp.
authors.forename: Shou
authors.initials: S
authors.lastname: Terasaki
authors.affiliation: Department of Chemistry, College of Humanities & Sciences, Nihon University, Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan. kawatsur@chs.nihon-u.ac.jp.
authors.forename: Taisyun
authors.initials: T
authors.lastname: Hanakawa
authors.affiliation: Department of Chemistry, College of Humanities & Sciences, Nihon University, Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan. kawatsur@chs.nihon-u.ac.jp.
authors.forename: Shota
authors.initials: S
authors.lastname: Mizuno
authors.affiliation: Department of Chemistry, College of Humanities & Sciences, Nihon University, Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan. kawatsur@chs.nihon-u.ac.jp.
authors.forename: Motoi
authors.identifier: http://orcid.org/0000-0002-8341-6866
authors.initials: M
authors.lastname: Kawatsura