title: A D3h-symmetry hexaazatriphenylene-tris-N-heterocyclic carbene ligand and its coordination to iridium and gold: preliminary catalytic studies.
abstract: A new D3h-symmetry tris-N-heterocyclic carbene ligand has been prepared and coordinated to iridium and gold. The ligand contains an electron-poor hexaazatriphenylene core; thus, the resulting tris-NHC ligand is a poor electron donor. The tris-Au(i) complex was tested in the hydroamination of terminal alkynes and in the three-component Strecker reaction.
authors.affiliation: Institute of Advanced Materials (INAM), Universitat Jaume I, Av. Vicente Sos Baynat s/n, Castellón 12071, Spain. poyatosd@uji.es eperis@uji.es.
authors.forename: S
authors.initials: S
authors.lastname: Ibáñez
authors.affiliation: Institute of Advanced Materials (INAM), Universitat Jaume I, Av. Vicente Sos Baynat s/n, Castellón 12071, Spain. poyatosd@uji.es eperis@uji.es.
authors.forename: M
authors.initials: M
authors.lastname: Poyatos
authors.affiliation: Institute of Advanced Materials (INAM), Universitat Jaume I, Av. Vicente Sos Baynat s/n, Castellón 12071, Spain. poyatosd@uji.es eperis@uji.es.
authors.forename: E
authors.identifier: http://orcid.org/0000-0001-9022-2392
authors.initials: E
authors.lastname: Peris