title: Hydroboration of CO2catalyzed by bis(phosphinite) pincer ligated nickel thiolate complexes.
abstract: We report the hydroboration of CO2with catecholborane catalyzed by a series of bis(phosphinite) pincer ligated nickel thiolate complexes. Turnover frequencies (TOFs) up to 2400 h-1were achieved at room temperature under an atmospheric pressure of CO2. This represents the highest TOF value known to date for the reduction of CO2to the methoxide level under mild conditions.
authors.affiliation: School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang, Henan 453007, China. jie.zhang@htu.edu.cn xnchen@htu.edu.cn.
authors.forename: Ting
authors.initials: T
authors.lastname: Liu
authors.affiliation: School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang, Henan 453007, China. jie.zhang@htu.edu.cn xnchen@htu.edu.cn.
authors.forename: Wenjuan
authors.initials: W
authors.lastname: Meng
authors.affiliation: School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang, Henan 453007, China. jie.zhang@htu.edu.cn xnchen@htu.edu.cn.
authors.forename: Qiang-Qiang
authors.initials: QQ
authors.lastname: Ma
authors.affiliation: School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang, Henan 453007, China. jie.zhang@htu.edu.cn xnchen@htu.edu.cn.
authors.forename: Jie
authors.identifier: http://orcid.org/0000-0002-7693-6388
authors.initials: J
authors.lastname: Zhang
authors.affiliation: School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang, Henan 453007, China. jie.zhang@htu.edu.cn xnchen@htu.edu.cn.
authors.forename: Huizhen
authors.initials: H
authors.lastname: Li
authors.affiliation: School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang, Henan 453007, China. jie.zhang@htu.edu.cn xnchen@htu.edu.cn.
authors.forename: Shujun
authors.identifier: http://orcid.org/0000-0002-6230-4806
authors.initials: S
authors.lastname: Li
authors.affiliation: School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang, Henan 453007, China. jie.zhang@htu.edu.cn xnchen@htu.edu.cn.
authors.forename: Qianyi
authors.initials: Q
authors.lastname: Zhao
authors.affiliation: School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang, Henan 453007, China. jie.zhang@htu.edu.cn xnchen@htu.edu.cn.
authors.forename: Xuenian
authors.initials: X
authors.lastname: Chen