title: Self-Assembled Hierarchical Interfaces of ZnO Nanotubes/Graphene Heterostructures for Efficient Room Temperature Hydrogen Sensors.
abstract: Herein, we report the novel nanostructural interfaces of self-assembled hierarchical ZnO nanotubes/graphene (ZNT/G) with three different growing times of ZNTs on graphene substrates (namely, SH1, SH2, and SH3). Each sample was fabricated with interdigitated electrodes to form hydrogen sensors, and their hydrogen sensing properties were comprehensively studied. The systematic investigation revealed that SH1sensor exhibits an ultrahigh sensor response even at a low detection level of 10 ppm (14.3%) to 100 ppm (28.1%) compared to those of the SH2and SH3sensors. The SH1sensor was also found to be well-retained with repeatability, reliability, and long-term stability of 90 days under hydrogenation/dehydrogenation processes. This outstanding enhancement in sensing properties of SH1is attributed to the formation of a strong metalized region in the ZNT/G interface due to the inner/outer surfaces of ZNTs, establishing a multiple depletion layer. Furthermore, the respective band models of each nanostructure were also purposed to describe their heterostructure, which illustrates the hydrogen sensing properties. Moreover, the long-term stability can be ascribed by the heterostructured combination of ZNTs and graphene via a spillover effect. The salient features of this self-assembled nanostructure are its reliability, simple synthesis method, and long-term stability, which makes it a promising candidate for new generation hydrogen sensors and hydrogen storage materials.
authors.affiliation: Graduate Institute of Electro-Optical Engineering and Department of Electronic and Computer Engineering, National Taiwan University of Science and Technology , Taipei, 106 Taiwan, R.O.C.
authors.forename: Deepa
authors.initials: D
authors.lastname: Kathiravan
authors.affiliation: Graduate Institute of Electro-Optical Engineering and Department of Electronic and Computer Engineering, National Taiwan University of Science and Technology , Taipei, 106 Taiwan, R.O.C.
authors.forename: Bohr-Ran
authors.identifier: http://orcid.org/0000-0001-9187-9177
authors.initials: BR
authors.lastname: Huang
authors.affiliation: Graduate Institute of Electro-Optical Engineering and Department of Electronic and Computer Engineering, National Taiwan University of Science and Technology , Taipei, 106 Taiwan, R.O.C.
authors.forename: Adhimoorthy
authors.identifier: http://orcid.org/0000-0002-1982-1736
authors.initials: A
authors.lastname: Saravanan
keywords: graphene hydrogen sensor; hydrogen storage; self-assembled ZNT/G nanostructures; spillover effect