Twisted Aromatic Frameworks: Readily Exfoliable and Solution-Processable Two-Dimensional Conjugated Microporous Polymers.
Twisted two-dimensional aromatic frameworks have been prepared by overcrowding the nodes with bulky and rigid substituents. The highly distorted aromatic framework with alternating out-of-plane substituents results in diminished interlayer interactions that favor the exfoliation and dispersion of individual layers in organic media.
POLYMAT, University of the Basque Country UPV/EHU, Avenida de Tolosa 72, 20018, Donostia-San Sebastian, Spain.
A Belen
AB
Marco
POLYMAT, University of the Basque Country UPV/EHU, Avenida de Tolosa 72, 20018, Donostia-San Sebastian, Spain.
Diego
D
Cortizo-Lacalle
Grupo de Ingeniería Química, Dto. de Química Aplicada Fac. de C. Químicas, UPV/EHU, Apdo 1072, 20080, San Sebastián, Spain.
Iñigo
I
Perez-Miqueo
Dipartimento di Chimica "Giacomo Ciamician", Via Selmi 2, 40126, Bologna, Italy.
Giovanni
G
Valenti
Dipartimento di Chimica "Giacomo Ciamician", Via Selmi 2, 40126, Bologna, Italy.
Alessandro
A
Boni
KU Leuven, Department of Chemistry, Division of Molecular Imaging and Photonics, Celestijnenlaan 200F, 3001, Leuven, Belgium.
Jan
J
Plas
CICECO-Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193, Aveiro, Portugal.
Karol
K
Strutyński
KU Leuven, Department of Chemistry, Division of Molecular Imaging and Photonics, Celestijnenlaan 200F, 3001, Leuven, Belgium.
Steven
S
De Feyter
Dipartimento di Chimica "Giacomo Ciamician", Via Selmi 2, 40126, Bologna, Italy.
Francesco
F
Paolucci
Grupo de Ingeniería Química, Dto. de Química Aplicada Fac. de C. Químicas, UPV/EHU, Apdo 1072, 20080, San Sebastián, Spain.
Mario
M
Montes
School of Chemistry, University of Nottingham, University Park, Nottingham, UK.
Andrei N
AN
Khlobystov
CICECO-Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193, Aveiro, Portugal.
Manuel
M
Melle-Franco
POLYMAT, University of the Basque Country UPV/EHU, Avenida de Tolosa 72, 20018, Donostia-San Sebastian, Spain.|Ikerbasque, Basque Foundation for Science, 48011, Bilbao, Spain.
Aurelio
A
Mateo-Alonso
carbon nanostructures; materials science; nanocarbons; organic frameworks; twisted aromatic systems