Proton Conductance of a Superior Water-Stable Metal-Organic Framework and Its Composite Membrane with Poly(vinylidene fluoride).
Proton-exchange membranes (PEMs) as separators have important technological applications in electrochemical devices, including fuel cells, electrochemical sensors, electrochemical reactors, and electrochromic displays. The composite membrane of a proton-conducting metal-organic framework (MOF) and an organic polymer combines the unique physical and chemical nature of the polymer and the high proton conductivity of the MOF, bringing together the best of both components to potentially fabricate high-performance PEMs. In this study, we have investigated the proton-transport nature of a zirconium(IV) MOF, MOF-808 (1). This superior-water-stability MOF shows striking proton conductivity with σ = 7.58 × 10-3S·cm-1at 315 K and 99% relative humidity. The composite membranes of 1 and poly(vinylidene fluoride) (PVDF) have further been fabricated and are labeled as 1@PVDF-X, where X represents the mass percentage of 1 (as X%) in 1@PVDF-X and X = 10-55%. The composite membranes exhibit good mechanical features and durability for practical application and a considerable proton conductivity of 1.56 × 10-4S·cm-1in deionized water at 338 K as well. Thus, the composite membranes show promising applications as alternative PEMs in diverse electrochemical devices.
Hong-Bin
HB
Luo
Mei
M
Wang
Shao-Xian
SX
Liu
Chen
C
Xue
Hubei Key Laboratory for Processing and Application of Catalytic Materials, Huanggang Normal University , Huanggang 438000, P. R. China.
Zheng-Fang
ZF
Tian
Yang
Y
Zou
State Key Laboratory of Coordination Chemistry, Nanjing University , Nanjing 210093, P. R. China.
Xiao-Ming
http://orcid.org/0000-0003-0848-6503
XM
Ren