Assembly of titanium-oxo cations with copper-halide anions to form supersalt-type cluster-based materials.
A series of binary cluster-based crystalline materials consisting of the same cationic polyoxotitanium cluster (PTC) and different anionic copper halide clusters (CuX) have been prepared. Interestingly, these complexes display analogous structure types to inorganic salts and present various light absorption properties.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China. LZhang@fjirsm.ac.cn zhj@fjirsm.ac.cn.
Wei-Hui
WH
Fang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China. LZhang@fjirsm.ac.cn zhj@fjirsm.ac.cn.
Lei
http://orcid.org/0000-0001-7720-4667
L
Zhang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China. LZhang@fjirsm.ac.cn zhj@fjirsm.ac.cn.
Jian
J
Zhang