Tailoring a compact and stable Langmuir bi-dimensional PbX-based layered perovskite film at the air-water interface and on solid support.
The present work studies the stability of Langmuir organic-inorganic superlattice materials thin films consisting of layered perovskite-based films with controlled 2D framework as well as to design experimental conditions for increasing the efficiency of the organic-inorganic perovskite motif by mechanical stimulus. Therefore, a whole covering of the air/water interface by a compact and stable lead-based layered perovskite structure is pursued. A 2D layered perovskite-type hybrid structure of the form [(CH3(CH2)19NH3)2(PbX4)], X=Cl, and Br, in which, two-dimensional sheets stabilized by a inner bilayer of organic monoammonium cation matrix, is mechanically tailored by successive compression-expansion cycles. The formation of 2D molecular patterns has been characterized by ΔR, BAM, XRD and XPS.
Institute of Fine Chemistry and Nanochemistry, Department of Physical Chemistry and Applied Thermodynamics, University of Córdoba, Campus Universitario de Rabanales, Edificio Marie Curie, Córdoba E-14014, Spain.
Luisa
L
Ariza-Carmona
Institute of Fine Chemistry and Nanochemistry, Department of Physical Chemistry and Applied Thermodynamics, University of Córdoba, Campus Universitario de Rabanales, Edificio Marie Curie, Córdoba E-14014, Spain.
Gonzalo
G
García-Espejo
Institute of Fine Chemistry and Nanochemistry, Department of Physical Chemistry and Applied Thermodynamics, University of Córdoba, Campus Universitario de Rabanales, Edificio Marie Curie, Córdoba E-14014, Spain. Electronic address: mtmartin@uco.es.
María T
MT
Martín-Romero
Institute of Fine Chemistry and Nanochemistry, Department of Physical Chemistry and Applied Thermodynamics, University of Córdoba, Campus Universitario de Rabanales, Edificio Marie Curie, Córdoba E-14014, Spain.
Luis
L
Camacho
2D layered perovskite-type hybrid structure; Air/water interface; BAM morphology; Compact and stable film; [(CH(3)(CH(2))(19)NH(3))(2)(PbX(4))], X=Cl, and Br