Synthesis Characterization and Photocatalytic Studies of Cobalt Ferrite-Silica-Titania Nanocomposites.
In this work, CoFe₂O₄@SiO₂@TiO₂ core-shell magnetic nanostructures have been prepared by coating of cobalt ferrite nanoparticles with the double SiO₂/TiO₂ layer using metallorganic precursors. The Transmission Electron Microscopy (TEM), Energy Dispersive X-Ray Analysis (EDX), Vibrational Sample Magnetometer (VSM) measurements and Raman spectroscopy results confirm the presence both of the silica and very thin TiO₂ layers. The core-shell nanoparticles have been sintered at 600 °C and used as a catalyst in photo-oxidation reactions of methylene blue under UV light. Despite the additional non-magnetic coatings result in a lower value of the magnetic moment, the particles can still easily be retrieved from reaction mixtures by magnetic separation. This retention of magnetism was of particular importance allowing magnetic recovery and re-use of the catalyst.
School of Chemistry and CRANN, Trinity College Dublin, Dublin 2, Ireland. greenedj@tcd.ie.
David
D
Greene
School of Chemistry and CRANN, Trinity College Dublin, Dublin 2, Ireland. serranr@tcd.ie.
Raquel
R
Serrano-Garcia
School of Chemistry and CRANN, Trinity College Dublin, Dublin 2, Ireland. govanj@tcd.ie.
Joseph
J
Govan
School of Chemistry and CRANN, Trinity College Dublin, Dublin 2, Ireland. igounko@tcd.ie.|St. Petersburg National Research University of Information Technologies, Mechanics and Optics, St. Petersburg 197101, Russia. igounko@tcd.ie.
Yurii K
YK
Gun'ko
core-shell; magnetic nanoparticles; magnetic separation; photocatalysis; silica; titanium dioxide