Metal-Organic Framework-Templated Catalyst: Synergy in Multiple Sites for Catalytic CO2Fixation.
The types and quantities of active sites play a critical role in catalysis. Herein, ZnO nanoparticles encapsulated into N-doped porous carbon has been rationally prepared by the pyrolysis of a metal-organic framework (MOF) followed by a moderate oxidation treatment. The resulting catalyst exhibits excellent activity, selectivity, and recyclability in the CO2cycloaddtion reactions with epoxides owing to the synergy of multiple sites inherited from the MOF and generated by the oxidation process.
Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Soft Matter Chemistry, Collaborative Innovation Center of Suzhou Nano Science and Technology, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China.
Meili
M
Ding
Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Soft Matter Chemistry, Collaborative Innovation Center of Suzhou Nano Science and Technology, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China.
Si
S
Chen
State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing Tech University, Nanjing, Jiangsu, 210009, P. R. China.
Xiao-Qin
XQ
Liu
State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing Tech University, Nanjing, Jiangsu, 210009, P. R. China.
Lin-Bing
LB
Sun
Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Soft Matter Chemistry, Collaborative Innovation Center of Suzhou Nano Science and Technology, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China.
Junling
J
Lu
Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Soft Matter Chemistry, Collaborative Innovation Center of Suzhou Nano Science and Technology, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China.|State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing Tech University, Nanjing, Jiangsu, 210009, P. R. China.
Hai-Long
0000-0002-2975-7977
HL
Jiang
D002244:Carbon / Q000737:chemistry; D002245:Carbon Dioxide / Q000737:chemistry*; D002384:Catalysis; D004852:Epoxy Compounds / Q000737:chemistry*; D008670:Metals / Q000737:chemistry*; D010084:Oxidation-Reduction; D016062:Porosity; D015034:Zinc Oxide / Q000737:chemistry
D004852:Epoxy Compounds; D008670:Metals; D002245:Carbon Dioxide; D002244:Carbon; D015034:Zinc Oxide
carbon; co2 fixation; doping; heterogeneous catalysis; metal-organic frameworks