Recent Advances in Chiral Nematic Structure and Iridescent Color of Cellulose Nanocrystal Films.
One unique property of cellulose nanocrystals (CNC) is their property of forming suspensions with chiral nematic order. This order can be preserved in films cast from the suspensions, raising the possibility of applications as photonic materials and templates. However, it has proved difficult to generate uniform, well-ordered chiral nematic materials from CNC. Recently, the importance of kinetic arrest due to gel formation in the later stages of evaporation has been recognized as a key step in film formation. In this brief review, recent developments regarding the structure of chiral nematic suspensions and films as monitored by polarized light microscopy are outlined, and attention is drawn to the importance of shear forces on the self-organization process.
Department of Chemistry, McGill University, Montreal, QC H3A 2A7, Canada. derek.gray@mcgill.ca.
Derek G
DG
Gray
cellulose nanocrystals; chiral nematic; polarized light microscopy