title: endo-Cyclization of unsaturated RO2radicals from the gas-phase ozonolysis of cyclohexadienes.
abstract: Unsaturated RO2radicals from the ozonolysis of cyclodienes can readily undergo an endo-cyclization step under atmospheric conditions forming a new ring-containing RO2radical after further O2addition. This path represents an extension of the atmospheric autoxidation scheme forming highly oxidized multifunctional organic compounds (HOMs). HOMs play an important role for Earth's organic aerosol burden.
authors.affiliation: Leibniz-Institut für Troposphärenforschung, TROPOS, 04318 Leipzig, Germany. berndt@tropos.de.
authors.forename: Stefanie
authors.initials: S
authors.lastname: Richters
authors.affiliation: Institut für Physikalische Chemie, Karlsruher Institut für Technologie (KIT), 76131 Karlsruhe, Germany.
authors.forename: Mark
authors.identifier: http://orcid.org/0000-0003-1825-0086
authors.initials: M
authors.lastname: Pfeifle
authors.affiliation: Institut für Physikalische Chemie, Karlsruher Institut für Technologie (KIT), 76131 Karlsruhe, Germany.
authors.forename: Matthias
authors.identifier: http://orcid.org/0000-0002-9932-4261
authors.initials: M
authors.lastname: Olzmann
authors.affiliation: Leibniz-Institut für Troposphärenforschung, TROPOS, 04318 Leipzig, Germany. berndt@tropos.de.
authors.forename: Torsten
authors.identifier: http://orcid.org/0000-0003-2014-6018
authors.initials: T
authors.lastname: Berndt