title: Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(ii) compounds.
abstract: Self-assembled hybrid supramolecular architectures formed between amphiphilic anions and long alkylated cationic cobalt(ii) complexes of type [Co(Cn-terpy)2](C12-Glu)2(n = 15-20) have been synthesized and characterized by TEM, PXRD and magnetic susceptibility measurements. The hybrids display wire or rolled sheet supramolecular arrangements with odd and even alkyl chain dependence, with the cobalt(ii) centres exhibiting gradual spin-crossover behaviours.
authors.affiliation: Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan. hayami@sci.kumamoto-u.ac.jp.
authors.forename: Ryohei
authors.initials: R
authors.lastname: Akiyoshi
authors.forename: Keita
authors.initials: K
authors.lastname: Kuroiwa
authors.forename: Saliu
authors.initials: S
authors.lastname: Alao Amolegbe
authors.forename: Manabu
authors.initials: M
authors.lastname: Nakaya
authors.forename: Ryo
authors.initials: R
authors.lastname: Ohtani
authors.forename: Masaaki
authors.initials: M
authors.lastname: Nakamura
authors.forename: Leonard F
authors.initials: LF
authors.lastname: Lindoy
authors.forename: Shinya
authors.initials: S
authors.lastname: Hayami