title: A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting.
abstract: The reaction of appropriate copper and vanadium salts with tetratopic methane tetra-p-phenylphosphonic acid (MTPPA) in the presence of 2,2':6':2''-terpyridine (terpy) yielded the three-dimensional bimetallic copper vanadium phosphonate framework [{Cu(terpy)}4Cu(VO2)4(MTPPA-H)2]·4H2O (1). Terpy has no net contribution to the three-dimensional structure providing a potential platform for void space formation via mold-casting. The structure was characterized by single-crystal X-ray diffraction and thermogravimetric analysis (TGA). Magnetic measurements were performed using a SQUID magnetometer. The crystal structure of the methanol solvate of the free ligand, MTPPA·MeOH, was analysed using Hirshfeld surfaces and fingerprint plots.
authors.affiliation: Faculty of Pharmacy, Istanbul Kemerburgaz University, Bakirkoy, Istanbul, Turkey.
authors.forename: Aysun
authors.initials: A
authors.lastname: Bulut
authors.affiliation: Laboratory of Inorganic Chemistry, ETH Zürich, HCI H103 Vladimir-Prelog-Weg 1, CH-8093, Switzerland.
authors.forename: Michael
authors.initials: M
authors.lastname: Wörle
authors.affiliation: Department of Chemistry, Gebze Technical University, Kocaeli, Turkey.
authors.forename: Yunus
authors.initials: Y
authors.lastname: Zorlu
authors.affiliation: Department of Chemistry, Yildiz Technical University, Esenler, Istanbul, Turkey.
authors.forename: Erdogan
authors.initials: E
authors.lastname: Kirpi
authors.affiliation: Department of Engineering Physics, Istanbul Medeniyet University, Kadikoy, Istanbul, Turkey.
authors.forename: Huseyin
authors.initials: H
authors.lastname: Kurt
authors.affiliation: Center for Science and Technology, Syracuse University, 1-014, Syracuse, New York 13244-4100, USA.
authors.forename: Jon
authors.initials: J
authors.lastname: Zubieta
authors.affiliation: Institute of Inorganic Chemistry and Crystallography, Bremen University, Bremen, Germany.
authors.forename: Simon
authors.initials: S
authors.lastname: Grabowsky
authors.affiliation: Institute of Inorganic Chemistry and Crystallography, Bremen University, Bremen, Germany.
authors.forename: Jens
authors.initials: J
authors.lastname: Beckmann
authors.affiliation: Department of Food Chemistry and Toxicology, Berlin Institute of Technology, Gustav-Meyer-Allee 25, 13355, Germany.
authors.forename: Gündoğ
authors.initials: G
authors.lastname: Yücesan
keywords: Hirshfeld surfaces; bimetallic Cu–V frameworks; metal organic frameworks (MOFs); organophosphonate complexes; void space formation