title: Synthesis and Crystal Structures of the First Antimony(III) Aziridinides.
abstract: The first antimony(III) aziridinyl derivatives are reported. Treatment of anhydrous SbCl3with N-lithioaziridine Li(Azn) (Azn = NC2H4) afforded the structurally unique heterobimetallic lithium/antimony(III) amide complex [Li3Sb(μ3-Cl)2(μ-Azn)4(THF)2]∞(1). Homoleptic Sb2(Azn)6(2) has become available for the first time through an amide group exchange reaction between Sb(NMe2)3and 3 equiv of aziridine. The low-melting Sb2(Azn)6exhibits a "weak dimer" structure in the crystal.
authors.affiliation: Chemisches Institut der Otto-von-Guericke-Universität , Universitätsplatz 2, 39106 Magdeburg, Germany.
authors.forename: Nicole
authors.initials: N
authors.lastname: Harmgarth
authors.affiliation: Chemisches Institut der Otto-von-Guericke-Universität , Universitätsplatz 2, 39106 Magdeburg, Germany.
authors.forename: Phil
authors.initials: P
authors.lastname: Liebing
authors.affiliation: Chemisches Institut der Otto-von-Guericke-Universität , Universitätsplatz 2, 39106 Magdeburg, Germany.
authors.forename: Florian
authors.initials: F
authors.lastname: Zörner
authors.affiliation: Institut für Mikro- und Sensorsysteme, Otto-von-Guericke-Universität , Universitätsplatz 2, 39106 Magdeburg, Germany.
authors.forename: Mindaugas
authors.initials: M
authors.lastname: Silinskas
authors.affiliation: Institut für Mikro- und Sensorsysteme, Otto-von-Guericke-Universität , Universitätsplatz 2, 39106 Magdeburg, Germany.
authors.forename: Edmund P
authors.initials: EP
authors.lastname: Burte
authors.affiliation: Chemisches Institut der Otto-von-Guericke-Universität , Universitätsplatz 2, 39106 Magdeburg, Germany.
authors.forename: Frank T
authors.identifier: http://orcid.org/0000-0001-5209-0018
authors.initials: FT
authors.lastname: Edelmann