title: Thermoresponsive Polyoxometalate/Ionic Liquid Supramolecular Gel Electrolytes for Supercapacitors: Fabrication, Structure, and Heteropolyanion Structure Effect.
abstract: We report the fabrication, structure, and heteropolyanion structure effect of polyoxometalate (POM)/ionic liquid (IL) supramolecular gels. These supramolecular gels exhibit ordered structures, as a result of their excellent reversible self-assembly, and they show various physicochemical properties, determined by the heteropolyanion structure effect of POM anions. Specifically, the formation of POM/IL supramolecular gels results in a highly ordered layer-shape structure, which has been calculated using X-ray powder diffraction patterns and proven by transmission electron microscopy images for the first time. When these POM/IL supramolecular gels are heated, they become viscous liquid sols, with melting isotropic drops and even flowerlike structures on microscopic scales, while it undergoes a reversible gel-sol phase transformation from gel to sol. The heteropolyanion structure effect in these two IL gels, [TBTP]5PW10V2O40and [TBTP]8P2W16V2O62, on their physicochemical properties is demonstrated. The POM structures have a strong structure effect on the physicochemical properties. As the size of heteropolyanions increases, there is a significant improvement in the conductivity, thermal performance, and oxidizability, with a lower phase inversion temperature, which means that the Dawson-type compound, [TBTP]8P2W16V2O62, has a higher conductivity, lower melting point, stronger oxidizability, and better thermal performance than the Keggin-type compound, [TBTP]5PW10V2O40, under the same conditions.
authors.affiliation: Department of Chemistry, Zhejiang University , Hangzhou 310027, PR China.
authors.forename: Xuefei
authors.initials: X
authors.lastname: Wu
authors.affiliation: Department of Chemistry, Zhejiang University , Hangzhou 310027, PR China.
authors.forename: Wen
authors.initials: W
authors.lastname: Wu
authors.affiliation: Department of Chemistry, Zhejiang University , Hangzhou 310027, PR China.
authors.forename: Qingyin
authors.identifier: 0000-0002-3026-1186
authors.initials: Q
authors.lastname: Wu
authors.affiliation: State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University , Changchun 130012, PR China.
authors.forename: Wenfu
authors.initials: W
authors.lastname: Yan