title: The impact of nanoparticles on aerobic degradation of municipal solid waste.
abstract: The amount of nanoparticles released from industrial and consumer products has increased rapidly in the last decade. These products may enter landfills directly or indirectly after the end of their useful life. In order to determine the impact of TiO2and Ag nanoparticles on aerobic landfilling processes, municipal solid waste was loaded to three pilot-scale aerobic landfill bioreactors (80 cm diameter and 350 cm height) and exposed to TiO2(AT) and Ag (AA) nanoparticles at total concentrations of 100 mg kg-1of solid waste. Aerobic landfill bioreactors were operated under the conditions about 0.03 L min-1kg-1aeration rate for 250 days, during which the leachate, solid waste, and gas characteristics were measured. The results indicate that there was no significant difference in the leachate characteristics, gas constituents, solid quality parameters, and temperature variations, which are the most important indicators of landfill operations, and overall aerobic degradation performance between the reactors containing TiO2and Ag nanoparticles, and control (AC) reactor. The data also indicate that the pH levels, ionic strength, and the complex formation capacity of nanoparticles with Cl-ions can reduce the toxicity effects of nanoparticles on aerobic degradation processes. The results suggest that TiO2and Ag nanoparticles at concentrations of 100 mg kg-1of solid waste do not have significant impacts on aerobic biological processes and waste management systems.
authors.affiliation: Department of Environmental Engineering, Yıldız Technical University, Istanbul, Turkey.
authors.forename: Senem
authors.initials: S
authors.lastname: Yazici Guvenc
authors.affiliation: Department of Environmental Engineering, Yıldız Technical University, Istanbul, Turkey.
authors.forename: Burcu
authors.initials: B
authors.lastname: Alan
authors.affiliation: Department of Environmental Engineering, Yıldız Technical University, Istanbul, Turkey.
authors.forename: Elanur
authors.initials: E
authors.lastname: Adar
authors.affiliation: Department of Environmental Engineering, Yıldız Technical University, Istanbul, Turkey.
authors.forename: Mehmet Sinan
authors.initials: MS
authors.lastname: Bilgili
mesh_terms: D000332:Aerobiosis; D057919:Biological Oxygen Demand Analysis; D019149:Bioreactors; D002244:Carbon / Q000032:analysis / Q000378:metabolism; D002245:Carbon Dioxide; D004867:Equipment Design; D006863:Hydrogen-Ion Concentration; D008697:Methane; D053758:Nanoparticles / Q000737:chemistry; D009584:Nitrogen / Q000032:analysis / Q000378:metabolism; D010100:Oxygen; D010865:Pilot Projects; D012037:Refuse Disposal / Q000295:instrumentation / Q000379:methods*; D012834:Silver; D062611:Solid Waste; D013696:Temperature; D014025:Titanium
chemical_list: D062611:Solid Waste; D002245:Carbon Dioxide; C009495:titanium dioxide; D012834:Silver; D002244:Carbon; D014025:Titanium; D009584:Nitrogen; D008697:Methane; D010100:Oxygen
keywords: Nanoparticles; aerobic landfill; bioreactors; leachate; municipal solid waste