title: Cluster Organic Frameworks Constructed from Heterometallic Supertetrahedral Cluster Secondary Building Units.
abstract: The two novel cluster organic frameworks based on heterometallic supertetrahedral cluster secondary building units (SBUs) [Cd4Cu6(L)4(Ac)7(H2O)4](Ac)·7H2O (1) and [Mn4Cu6(L)4(Ac)4.5(H2O)9]CuCN(Ac)3.5·H2O (2), where H3L = 2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol and Ac = CH3COO-, have been prepared under solvothermal conditions. 1 and 2 are the first cases of cluster organic frameworks containing Cd-Cu/Mn-Cu heterometallic supertetrahedral cluster SBUs. Furthermore, 1 and 2 show an integration of magnetic properties and adsorption properties from both the heterometallic cluster secondary building units and the framework in a porous material.
authors.affiliation: State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University , Fuzhou, Fujian 350108, People's Republic of China.
authors.forename: Li-Dan
authors.initials: LD
authors.lastname: Lin
authors.affiliation: State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University , Fuzhou, Fujian 350108, People's Republic of China.|State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350108, People's Republic of China.
authors.forename: Xin-Xiong
authors.identifier: http://orcid.org/0000-0002-9903-2699
authors.initials: XX
authors.lastname: Li
authors.affiliation: State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University , Fuzhou, Fujian 350108, People's Republic of China.
authors.forename: Yan-Jie
authors.initials: YJ
authors.lastname: Qi
authors.affiliation: State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University , Fuzhou, Fujian 350108, People's Republic of China.
authors.forename: Xiang
authors.initials: X
authors.lastname: Ma
authors.affiliation: State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University , Fuzhou, Fujian 350108, People's Republic of China.|State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350108, People's Republic of China.
authors.forename: Shou-Tian
authors.identifier: http://orcid.org/0000-0002-3365-9747
authors.initials: ST
authors.lastname: Zheng