title: Separator Membrane from Crosslinked Poly(Vinyl Alcohol) and Poly(Methyl Vinyl Ether-alt-Maleic Anhydride).
abstract: In this work, we report separator membranes from crosslinking of two polymers, such as poly vinyl alcohol (PVA) with an ionic polymer poly(methyl vinyl ether-alt-maleic anhydride) (PMVE-MA). Such interpolymer-networked systems were extensively used for biomedical and desalination applications but they were not examined for their potential use as membranes or separators for batteries. Therefore, the chemical interactions between these two polymers and the influence of such crosslinking on physicochemical properties of the membrane are systematically investigated through rheology and by critical gel point study. The hydrogen bonding and the chemical interaction between PMVE-MA and PVA resulted in highly cross-linked membranes. Effect of the molecular weight of PVA on the membrane properties was also examined. The developed membranes were extensively characterized by studying their physicochemical properties (water uptake, swelling ratio, and conductivity), thermal and electrochemical properties using differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), thermo-gravimetric analysis (TGA) and electrochemical impedance spectroscopy (EIS). The DSC study shows the presence of a singleTgin the membranes indicating compatibility of the two polymers in flexible and transparent films. The membranes show good stability and ion conductivity suitable for separator applications.
authors.affiliation: Ian Wark Institute, University of South Australia, Mawson Lakes 5095, Australia. charuvashisthrohatgi@gmail.com.
authors.forename: Charu Vashisth
authors.initials: CV
authors.lastname: Rohatgi
authors.affiliation: Ian Wark Institute, University of South Australia, Mawson Lakes 5095, Australia. naba.dutta@unisa.edu.au.
authors.forename: Naba K
authors.initials: NK
authors.lastname: Dutta
authors.affiliation: Ian Wark Institute, University of South Australia, Mawson Lakes 5095, Australia. namita.choudhury@unisa.edu.au.
authors.forename: Namita Roy
authors.initials: NR
authors.lastname: Choudhury
keywords: battery separator; dynamic mechanical analysis; electrochemical impedance spectroscopy; hydrogen bonding; interpolymer-networked systems; ionic polymer; poly vinyl alcohol; separator membrane; thermal analysis