title: 1,2-Difunctionalization-type (hetero)arylation of unactivated alkenes triggered by radical addition/remote (hetero)aryl migration.
abstract: A novel difunctionalization-type (hetero)arylation of unactivated alkenes has been developed via remote 1,4(5)-(hetero)aryl migration triggered by radical alkene azidation, trifluoromethylation, or phosphonylation. The overall process serves as an unusual and reliable approach for straightforward access to diversely substituted ketones with broad functional group compatibility from readily available substrates and reagents.
authors.affiliation: Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055, China. liuxy3@sustc.edu.cn.
authors.forename: Lei
authors.initials: L
authors.lastname: Li
authors.affiliation: Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055, China. liuxy3@sustc.edu.cn.
authors.forename: Qiang-Shuai
authors.identifier: http://orcid.org/0000-0002-3840-425X
authors.initials: QS
authors.lastname: Gu
authors.affiliation: Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055, China. liuxy3@sustc.edu.cn.
authors.forename: Na
authors.initials: N
authors.lastname: Wang
authors.affiliation: Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055, China. liuxy3@sustc.edu.cn.
authors.forename: Ping
authors.initials: P
authors.lastname: Song
authors.affiliation: Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055, China. liuxy3@sustc.edu.cn.
authors.forename: Zhong-Liang
authors.initials: ZL
authors.lastname: Li
authors.affiliation: Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055, China. liuxy3@sustc.edu.cn.
authors.forename: Xiao-Hua
authors.initials: XH
authors.lastname: Li
authors.affiliation: Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055, China. liuxy3@sustc.edu.cn.
authors.forename: Fu-Li
authors.initials: FL
authors.lastname: Wang
authors.affiliation: Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055, China. liuxy3@sustc.edu.cn.
authors.forename: Xin-Yuan
authors.identifier: http://orcid.org/0000-0002-6978-6465
authors.initials: XY
authors.lastname: Liu