title: Oscillatory hydraulic testing as a strategy for NAPL source zone monitoring: Laboratory experiments.
abstract: Non-aqueous phase liquids (NAPLs) have a complex mode of transport in heterogeneous aquifers, which can result in pools and lenses of NAPLs (the "source zone") that are difficult to detect and can cause long-term contamination via slow dissolution into groundwater (the "dissolved plume"). Characterizing the extent and evolution of NAPL contamination within the source zone is a useful strategy for designing and adapting appropriate remedial actions at many contaminated sites. As a NAPL flows into a given aquifer volume, the effective hydraulic conductivity (K) and specific storage (Ss) of the volume changes associated with the viscosity and compressibility of the impinging fluid, meaning that NAPL movement may be detectable with hydraulic testing. Recently, the use of oscillatory pumping tests - in which sinusoidal pumping variations are implemented and oscillatory pressure changes are detected at monitoring locations - has been suggested as a low-impact hydraulic testing strategy for characterizing aquifer properties (Cardiff et al., 2013; Zhou et al., 2016). Here, we investigate this strategy in an experimental laboratory sandbox where dyed vegetable oil is injected and allowed to migrate as a NAPL. Initial qualitative analyses demonstrate that measurable changes in pressure signal amplitude and phase provide clear evidence for NAPL plume emplacement and migration. Using the approach developed in Zhou et al. (2016), we then apply tomographic analyses to estimate the location of effective K changes (representing fluid changes) and their movement throughout time. This approach provides a method for monitoring ongoing NAPL movement without net extraction or injection of fluid, making it advantageous in field remediation applications.
authors.affiliation: Department of Geoscience, University of Wisconsin-Madison, Madison, WI, USA. Electronic address: zhou86@wisc.edu.
authors.forename: YaoQuan
authors.initials: Y
authors.lastname: Zhou
authors.affiliation: Department of Geoscience, University of Wisconsin-Madison, Madison, WI, USA.
authors.forename: Michael
authors.initials: M
authors.lastname: Cardiff
mesh_terms: D060587:Groundwater / Q000032:analysis / Q000737:chemistry; D062070:Hydrology / Q000379:methods*; D007753:Laboratories; D014054:Tomography / Q000379:methods; D014873:Water Pollutants / Q000032:analysis; D014874:Water Pollutants, Chemical / Q000032:analysis*; D014876:Water Pollution / Q000032:analysis*
chemical_list: D014873:Water Pollutants; D014874:Water Pollutants, Chemical
keywords: Inverse modeling; Laboratory sandbox; NAPL characterization; Oscillatory hydraulic tomography