title: Thermal effects in guest-host systems: [Zn2(bdc)(S-lac)(dmf)]•PhEtOH: A DSC and NMR study.
abstract: Differential scanning calorimetry and nuclear magnetic resonance were used to investigate thermal effects in the guest-host systems where homochiral metal-organic sorbent [Zn2(bdc)(S-lac)(dmf)] is considered as a host while 1-phenylethanol enantiomers and their racemic mixture serve as guest molecules. A maximum energy gain from the guest-host interaction was observed in the system with the racemic mixture. The effect of host-guest recognition was revealed for the case of the host and guest having a similar type of chirality in the presence of antipode guest molecules.
authors.affiliation: A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia.|Novosibirsk State University, Novosibirsk, Russia.
authors.forename: Svetlana G
authors.identifier: http://orcid.org/0000-0001-7114-8676
authors.initials: SG
authors.lastname: Kozlova
authors.affiliation: A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia.
authors.forename: Denis P
authors.initials: DP
authors.lastname: Pishchur
authors.affiliation: A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia.
authors.forename: Marsel R
authors.initials: MR
authors.lastname: Gallyamov
keywords: 1-phenylethanol; DSC; MOF; NMR; enantiomers; racemate