title: Syntheses of Bipyricorroles and Their Meso-Meso Coupled Dimers.
abstract: The metal-templated condensation strategy has been developed for the synthesis of meso-free bipyricorrole complexes. The reactive meso-CH in the monomer complex is further treated with various oxidative coupling reagents such as AgPF6, AgOTf, and FeCl3. Unlike Ag(I) salts, the FeCl3resulted in a meso-meso-linked corrole homologue dimer. The synthetic methodologies successfully introduce the PdIImonomer as well as PdII-PdIIdimeric complexes in the corrole chemistry.
authors.affiliation: School of Chemical Sciences, National Institute of Science Education and Research (NISER), Homi Bhabha National Institute , Bhubaneswar, 752050 Odisha, India.
authors.forename: B
authors.initials: B
authors.lastname: Adinarayana
authors.affiliation: School of Chemical Sciences, National Institute of Science Education and Research (NISER), Homi Bhabha National Institute , Bhubaneswar, 752050 Odisha, India.
authors.forename: Ajesh P
authors.initials: AP
authors.lastname: Thomas
authors.affiliation: School of Chemical Sciences, National Institute of Science Education and Research (NISER), Homi Bhabha National Institute , Bhubaneswar, 752050 Odisha, India.
authors.forename: Pardhasaradhi
authors.initials: P
authors.lastname: Satha
authors.affiliation: School of Chemical Sciences, National Institute of Science Education and Research (NISER), Homi Bhabha National Institute , Bhubaneswar, 752050 Odisha, India.
authors.forename: A
authors.identifier: 0000-0001-8467-1538
authors.initials: A
authors.lastname: Srinivasan