title: One Versatile Route to Three-Dimensional Graphene Wrapped Metal Cyanide Aerogels for Enhanced Sodium Ion Storage.
abstract: Facile and controllable integration of metal cyanides (MCs) into three-dimensional graphene (3DG) with advantageous structures is of fundamental importance for the development of superior MC-based electrode materials for electrochemical energy storage and catalysis. Here a facile and versatile spatially-confined Ostwald ripening strategy was developed to synthesize a series of 3DG wrapped MC aerogels with different compositions, size, and structure based on the chemical instability of MC in the reaction system. Remarkably, the integration of Prussian blue (PB) into 3DG, with such unique architecture, largely improves the rate performance and long-term cycling stability of PB as a cathode material for sodium ion batteries.
authors.affiliation: State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200433, P. R. China.
authors.forename: Fanxing
authors.initials: F
authors.lastname: Bu
authors.affiliation: State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200433, P. R. China.
authors.forename: Xiaoxiang
authors.initials: X
authors.lastname: Feng
authors.affiliation: State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200433, P. R. China.
authors.forename: Tiancai
authors.initials: T
authors.lastname: Jiang
authors.affiliation: Sustainable Energy Technologies Center, College of Engineering, King Saud University, Riyadh, 11421, Kingdom of Saudi Arabia.
authors.forename: Imran
authors.initials: I
authors.lastname: Shakir
authors.affiliation: State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200433, P. R. China.
authors.forename: Yuxi
authors.initials: Y
authors.lastname: Xu
keywords: encapsulated structure; graphene; metal cyanides; prussian blue; sodium-ion battery; three-dimensional graphene