title: Trichloramine Removal with Activated Carbon Is Governed by Two Reductive Reactions: A Theoretical Approach with Diffusion-Reaction Models.
abstract: Mechanisms underlying trichloramine removal with activated carbon treatment were proven by batch experiments and theoretical analysis with diffusion-reaction models. The observed values of trichloramine and free chlorine were explained only by the model in which (1) both trichloramine and free chlorine were involved as reactants, (2) the removals of reactants were affected both by the intraparticle diffusion and by the reaction with activated carbon, and (3) trichloramine decomposition was governed by two distinct reductive reactions. One reductive reaction was expressed as a first-order reaction: the reductive reaction of trichloramine with the basal plane of PAC, which consists of graphene sheets. The other reaction was expressed as a second-order reaction: the reductive reaction of trichloramine with active functional groups located on the edge of the basal plane. Free chlorine competitively reacted with both the basal plane and the active functional groups. The fact that the model prediction succeeded even in experiments with different activated carbon doses, with different initial trichloramine concentrations, and with different sizes of activated carbon particles clearly proved that the mechanisms described in the model were reasonable for explaining trichloramine removal with activated carbon treatment.
authors.affiliation: Graduate School of Engineering, Hokkaido University , N13W8, Sapporo 060-8628, Japan.
authors.forename: Taku
authors.identifier: 0000-0003-0819-0796
authors.initials: T
authors.lastname: Matsushita
authors.affiliation: Graduate School of Engineering, Hokkaido University , N13W8, Sapporo 060-8628, Japan.
authors.forename: Yoshihiko
authors.initials: Y
authors.lastname: Matsui
authors.affiliation: Graduate School of Engineering, Hokkaido University , N13W8, Sapporo 060-8628, Japan.
authors.forename: Shohei
authors.initials: S
authors.lastname: Ikekame
authors.affiliation: National Institute of Technology, Kisarazu College , 2-11-1 Kiyomidai Higashi, Kisarazu 292-0041, Japan.
authors.forename: Miki
authors.initials: M
authors.lastname: Sakuma
authors.affiliation: Graduate School of Engineering, Hokkaido University , N13W8, Sapporo 060-8628, Japan.
authors.forename: Nobutaka
authors.initials: N
authors.lastname: Shirasaki
mesh_terms: D000327:Adsorption; D002606:Charcoal; D002713:Chlorine; D004058:Diffusion; D007700:Kinetics; D008962:Models, Theoretical
chemical_list: D002606:Charcoal; D002713:Chlorine