title: Direct Measurements of Magnetic Polarons in Cd1-xMnxSe Nanocrystals from Resonant Photoluminescence.
abstract: In semiconductors, quantum confinement can greatly enhance the interaction between band carriers (electrons and holes) and dopant atoms. One manifestation of this enhancement is the increased stability of exciton magnetic polarons in magnetically doped nanostructures. In the limit of very strong 0D confinement that is realized in colloidal semiconductor nanocrystals, a single exciton can exert an effective exchange field Bexon the embedded magnetic dopants that exceeds several tesla. Here we use the very sensitive method of resonant photoluminescence (PL) to directly measure the presence and properties of exciton magnetic polarons in colloidal Cd1-xMnxSe nanocrystals. Despite small Mn2+concentrations (x = 0.4-1.6%), large polaron binding energies up to ∼26 meV are observed at low temperatures via the substantial Stokes shift between the pump laser and the resonant PL maximum, indicating nearly complete alignment of all Mn2+spins by Bex. Temperature and magnetic field-dependent studies reveal that Bex≈ 10 T in these nanocrystals, in good agreement with theoretical estimates. Further, the emission line widths provide direct insight into the statistical fluctuations of the Mn2+spins. These resonant PL studies provide detailed insight into collective magnetic phenomena, especially in lightly doped nanocrystals where conventional techniques such as nonresonant PL or time-resolved PL provide ambiguous results.
authors.affiliation: Department of Physics and Astronomy, University of Wyoming , Laramie, Wyoming 82071, United States.
authors.forename: W D
authors.initials: WD
authors.lastname: Rice
authors.forename: W
authors.initials: W
authors.lastname: Liu
authors.affiliation: Dipartimento di Scienza dei Materiali, Università degli Studi di Milano-Bicocca , Via Cozzi 55, IT-20125 Milano, Italy.
authors.forename: V
authors.identifier: 0000-0003-3792-3661
authors.initials: V
authors.lastname: Pinchetti
authors.affiliation: Experimentelle Physik 2, Technische Universität Dortmund , D-44221 Dortmund, Germany.|Ioffe Institute, Russian Academy of Sciences , 194021 St. Petersburg, Russia.
authors.forename: D R
authors.initials: DR
authors.lastname: Yakovlev
authors.forename: V I
authors.identifier: 0000-0003-1158-3179
authors.initials: VI
authors.lastname: Klimov
authors.forename: S A
authors.identifier: 0000-0001-7553-4718
authors.initials: SA
authors.lastname: Crooker
keywords: Nanocrystal; diluted magnetic semiconductor; magnetic polaron; photoluminescence; quantum dot