title: Palladium-Catalyzed Oxidative Carbonylation of Aryl Hydrazines with CO and O2at Atmospheric Pressure.
abstract: Palladium-catalyzed aerobic oxidative aminocarbonylation and alkoxycarbonylation reactions with aryl hydrazines as coupling partners have been developed. The oxidative carbonylation of aryl hydrazines proceeded smoothly at atmospheric pressure CO, employing molecular oxygen as the terminal oxidant. The only byproducts were nitrogen gas and water for both reactions. Notably, no double carbonylation was detected. Furthermore, aryl-halogen bonds, which are normally reactive in conventional Pd-catalyzed carbonylation reactions, remained intact.
authors.affiliation: National Research Center for Carbohydrate Synthesis and Key Laboratory of Chemical Biology of Jiangxi Province, College of Chemistry and Chemical Engineering, Jiangxi Normal University , Nanchang 330022, P.R. China.
authors.forename: Yongliang
authors.initials: Y
authors.lastname: Tu
authors.affiliation: National Research Center for Carbohydrate Synthesis and Key Laboratory of Chemical Biology of Jiangxi Province, College of Chemistry and Chemical Engineering, Jiangxi Normal University , Nanchang 330022, P.R. China.
authors.forename: Lin
authors.initials: L
authors.lastname: Yuan
authors.affiliation: National Research Center for Carbohydrate Synthesis and Key Laboratory of Chemical Biology of Jiangxi Province, College of Chemistry and Chemical Engineering, Jiangxi Normal University , Nanchang 330022, P.R. China.
authors.forename: Tao
authors.initials: T
authors.lastname: Wang
authors.affiliation: National Research Center for Carbohydrate Synthesis and Key Laboratory of Chemical Biology of Jiangxi Province, College of Chemistry and Chemical Engineering, Jiangxi Normal University , Nanchang 330022, P.R. China.
authors.forename: Changliu
authors.initials: C
authors.lastname: Wang
authors.affiliation: National Research Center for Carbohydrate Synthesis and Key Laboratory of Chemical Biology of Jiangxi Province, College of Chemistry and Chemical Engineering, Jiangxi Normal University , Nanchang 330022, P.R. China.
authors.forename: Jiamei
authors.initials: J
authors.lastname: Ke
authors.affiliation: National Research Center for Carbohydrate Synthesis and Key Laboratory of Chemical Biology of Jiangxi Province, College of Chemistry and Chemical Engineering, Jiangxi Normal University , Nanchang 330022, P.R. China.
authors.forename: Junfeng
authors.identifier: 0000-0003-4843-4871
authors.initials: J
authors.lastname: Zhao