title: Organic-inorganic hybrid three-dimensional metal sulfite-oxalates with honeycomb-like structures.
abstract: The crystallographic signatures and characterization of two novel mixed metal hybrid open-frameworks [Na2Mn2(C2O4)(SO3)2(H2O)2] 1 and [NaEu(C2O4)(SO3)(H2O)3] 2 are reported for the first time; they are synthesized under hydrothermal conditions to generate 3D assemblies and honeycomb-like structures. They were further characterized by complementary techniques like PXRD, TGA and DSC. The magnetic properties of 1 show antiferromagnetic interactions between the metal centers and compound 2 shows good photoluminescence properties.
authors.affiliation: School of Chemical Sciences, National Institute of Science Education and Research (NISER), Bhubaneswar 751005, India. jnbehera@niser.ac.in.
authors.forename: Ranjay K
authors.initials: RK
authors.lastname: Tiwari
authors.forename: J N
authors.initials: JN
authors.lastname: Behera