title: Unprecedented Li+Exchange in an Anionic Metal-Organic Framework: Significantly Enhanced Gas Uptake Capacity.
abstract: We herein report the first example of Li+exchanged with both the guest H2N(Me)2+cations located in the channels and the coordinated metal ions from an anionic metal-organic framework (MOF), leading to significant enhancement of the pore volume and gas sorption abilities of the exchanged MOF. Furthermore, both MOFs before and after Li+exchange show good selective adsorption for CO2over CH4.
authors.affiliation: School of Light Industry and Chemical Engineering, Guangdong University of Technology , Guangzhou 510006, China.|Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Suzhou Nano Science and Technology, Department of Chemistry, University of Science and Technology of China , Hefei, Anhui 230026, P. R. China.
authors.forename: Bo
authors.initials: B
authors.lastname: Liu
authors.affiliation: Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Suzhou Nano Science and Technology, Department of Chemistry, University of Science and Technology of China , Hefei, Anhui 230026, P. R. China.
authors.forename: Rui
authors.initials: R
authors.lastname: Zhang
authors.affiliation: School of Light Industry and Chemical Engineering, Guangdong University of Technology , Guangzhou 510006, China.
authors.forename: Chun-Yang
authors.initials: CY
authors.lastname: Pan
authors.affiliation: Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Suzhou Nano Science and Technology, Department of Chemistry, University of Science and Technology of China , Hefei, Anhui 230026, P. R. China.
authors.forename: Hai-Long
authors.identifier: http://orcid.org/0000-0002-2975-7977
authors.initials: HL
authors.lastname: Jiang