title: Palladium-catalyzed C-H olefination of uracils and caffeines using molecular oxygen as the sole oxidant.
abstract: The palladium-catalyzed oxidative C-H olefination of uracils or caffeines with alkenes using an atmospheric pressure of molecular oxygen as the sole oxidant has been disclosed. This novel strategy offers an efficient and environmentally friendly method to biologically important C5-alkene uracil derivatives or C8-alkene caffeine derivatives.
authors.affiliation: College of Chemistry & Chemical Engineering, Fujian Normal University, Fuzhou 350007, People's Republic of China.
authors.forename: Xinyu
authors.initials: X
authors.lastname: Zhang
authors.forename: Lv
authors.initials: L
authors.lastname: Su
authors.forename: Lin
authors.initials: L
authors.lastname: Qiu
authors.forename: Zhenwei
authors.initials: Z
authors.lastname: Fan
authors.forename: Xiaofeng
authors.initials: X
authors.lastname: Zhang
authors.forename: Shen
authors.initials: S
authors.lastname: Lin
authors.forename: Qiufeng
authors.initials: Q
authors.lastname: Huang
mesh_terms: D002110:Caffeine / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D006859:Hydrogen / Q000737:chemistry*; D016877:Oxidants / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D014498:Uracil / Q000737:chemistry*
chemical_list: D016877:Oxidants; D002110:Caffeine; D014498:Uracil; D010165:Palladium; D002244:Carbon; D006859:Hydrogen; D010100:Oxygen