title: One-pot synthesis of α-aminophosphonates via a cascade sequence of allylamine isomerization/hydrophosphonylation.
abstract: A Rh/Ni-catalyzed cascade sequence of allylamine isomerization and hydrophosphonylation to synthesize α-aminophosphonates has been disclosed. The reaction, which not only allows the generation of widespread valuable α-aminophosphonates under simple systems and mild conditions, but also enriches the process of olefin isomerization-addition both in catalytic systems and various reaction types.
authors.affiliation: State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China. yangshd@lzu.edu.cn.
authors.forename: Liu-Liang
authors.initials: LL
authors.lastname: Mao
authors.forename: Chen-Chen
authors.initials: CC
authors.lastname: Li
authors.forename: Qiang
authors.initials: Q
authors.lastname: Yang
authors.forename: Ming-Xing
authors.initials: MX
authors.lastname: Cheng
authors.forename: Shang-Dong
authors.initials: SD
authors.lastname: Yang