title: Simple modification of basic dyes with bulky &symmetric WCAs for improving their solubilities in organic solvents without color change.
abstract: A simple and easy solubility enhancement of basic dyes was performed with bulky and symmetric weakly coordinating anions (WCAs). The WCAs decreased the ionic character of the dyes by broadening the partial charge distribution and causing a screening effect on the ionic bonding. This new modification with WCAs has advantages in that it has no influence on the optical properties of the dyes. The solubilities of unmodified and modified dyes were tested in several organic solvents. X-ray powder diffraction patterns of the dyes were measured. Color films were prepared with the dyes and their color loci were analyzed to evaluate the optical properties. By the modification with WCAs, commercial basic dyes showed sufficient solubilities for be applied to various applications while preserving their superior optical properties.
authors.affiliation: Lab. of Organic Photo-functional Materials, Department of Materials Science and Engineering, Seoul National University, Seoul 08826, Republic of Korea.
authors.forename: Jeong Yun
authors.initials: JY
authors.lastname: Kim
authors.affiliation: Lab. of Organic Photo-functional Materials, Department of Materials Science and Engineering, Seoul National University, Seoul 08826, Republic of Korea.
authors.forename: Tae Gyu
authors.initials: TG
authors.lastname: Hwang
authors.affiliation: Lab. of Organic Photo-functional Materials, Department of Materials Science and Engineering, Seoul National University, Seoul 08826, Republic of Korea.
authors.forename: Sung Wun
authors.initials: SW
authors.lastname: Woo
authors.affiliation: Lab. of Organic Photo-functional Materials, Department of Materials Science and Engineering, Seoul National University, Seoul 08826, Republic of Korea.
authors.forename: Jae Moon
authors.initials: JM
authors.lastname: Lee
authors.affiliation: Lab. of Organic Photo-functional Materials, Department of Materials Science and Engineering, Seoul National University, Seoul 08826, Republic of Korea.
authors.forename: Jin Woong
authors.initials: JW
authors.lastname: Namgoong
authors.affiliation: Lab. of Organic Photo-functional Materials, Department of Materials Science and Engineering, Seoul National University, Seoul 08826, Republic of Korea.
authors.forename: Sim Bum
authors.initials: SB
authors.lastname: Yuk
authors.affiliation: Samsung Electronics Co., Ltd., 1 Samsungjeonja-ro, Hwaseong-si, Gyeonggi-do 18448, Republic of Korea.
authors.forename: Sei-Won
authors.initials: SW
authors.lastname: Chung
authors.affiliation: Lab. of Organic Photo-functional Materials, Department of Materials Science and Engineering, Seoul National University, Seoul 08826, Republic of Korea.
authors.forename: Jae Pil
authors.initials: JP
authors.lastname: Kim