title: Construction of a bicontinuous donor-acceptor hybrid material at the molecular level by inserting inorganic nanowires into porous MOFs.
abstract: Herein, we report an unprecedented hybrid structure of electron-rich iodoplumbate nanowires precisely inserted into the periodic pores of electron-deficient pyridinium metal-organic frameworks (MOFs). To the best of our knowledge, this is the first example of semiconductive MOFs in situ loaded with inorganic semiconductive nanowires via a simple self-assembly method. Due to the dissimilar semiconductivities between the host and guest components, this hybrid also represents the first bicontinuous donor-acceptor hybrid at the molecular level based on host-guest interactions.
authors.affiliation: College of Chemistry, Fuzhou University, 350116, China. meijin_lin@fzu.edu.cn cchuang@fzu.edu.cn.
authors.forename: Jian-Jun
authors.initials: JJ
authors.lastname: Liu
authors.forename: Ying-Fang
authors.initials: YF
authors.lastname: Guan
authors.forename: Ling
authors.initials: L
authors.lastname: Li
authors.forename: Yong
authors.initials: Y
authors.lastname: Chen
authors.forename: Wen-Xin
authors.initials: WX
authors.lastname: Dai
authors.forename: Chang-Cang
authors.initials: CC
authors.lastname: Huang
authors.forename: Mei-Jin
authors.initials: MJ
authors.lastname: Lin