title: Comments on "Evidence of the hydrogen release mechanism in bulk MgH2".
abstract: The effect of an electron beam induced dehydrogenation of MgH2in the transmission electron microscope (TEM) is largely underestimated by Nogita et al., and led the authors to a misinterpretation of their TEM observations. Firstly, the selected area diffraction (SAD) pattern is falsely interpreted. A re-evaluation of the SAD pattern reveals that no MgH2is present in the sample, but that it rather consists of Mg and MgO only. Secondly, the transformation of the sample upon in-situ heating in the TEM cannot be ascribed to dehydrogenation, but is rather to be explained by the (nanoscale) Kirkendall effect, which leads to the formation of hollow MgO shells without any metallic Mg in their cores. Hence, the conclusions drawn from the TEM investigation are invalid, as the authors apparently have never studied MgH2.
authors.affiliation: IFW Dresden, Institute for Metallic Materials, Dresden, D-01171, Germany.|Technische Universität Dresden, Institut für Festkörperphysik, Dresden, D-01062, Germany.
authors.forename: Alexander
authors.initials: A
authors.lastname: Surrey
authors.affiliation: IFW Dresden, Institute for Metallic Materials, Dresden, D-01171, Germany.
authors.forename: Kornelius
authors.initials: K
authors.lastname: Nielsch
authors.affiliation: IFW Dresden, Institute for Metallic Materials, Dresden, D-01171, Germany.
authors.forename: Bernd
authors.initials: B
authors.lastname: Rellinghaus