title: Reversible dinitrogen binding to [Cp'Fe(NHC)] associated with an N2-induced spin state change.
abstract: The 15-valence electron (VE), high-spin (S = 3/2) half-sandwich complex [Cp'Fe(IiPr2Me2)] (3; IiPr2Me2= 1,3-di-iso-propyl-4,5-dimethylimidazol-2-yildene) reversibly coordinates N2to form the 17VE, low-spin (S = 1/2) compound [Cp'Fe(IiPr2Me2)(η1-N2)] (4).
authors.affiliation: Institut für Anorganische und Analytische Chemie, Technische Universität, Braunschweig, Hagenring 30, 38106 Braunschweig, Germany. mwalter@tu-bs.de.
authors.forename: Matthias
authors.initials: M
authors.lastname: Reiners
authors.forename: Dirk
authors.initials: D
authors.lastname: Baabe
authors.forename: Marc-Kevin
authors.initials: MK
authors.lastname: Zaretzke
authors.forename: Matthias
authors.initials: M
authors.lastname: Freytag
authors.forename: Marc D
authors.initials: MD
authors.lastname: Walter