title: Three Different Reactions, One Catalyst: A Cu(I) PNP Pincer Complex as Catalyst for C-C and C-N Cross-Couplings.
abstract: An air-stable, thermally robust, and well-defined Cu(I) PNP pincer complex based on the 2,6-diaminopyridine scaffold is described. This complex is an active catalyst for the cross-couplings of a range of aryl and heteroaryl (including benzoxazole, thiazole, pyridine, and thiophene) halides with different organomagnesium reagents, alkynes, and aryl-amines giving excellent to good isolated yields.
authors.affiliation: Institute of Applied Synthetic Chemistry and ‡Institute of Chemical Technologies and Analytics, Vienna University of Technology , Getreidemarkt 9/163-AC, A-1060 Wien, Austria.
authors.forename: Matthias
authors.identifier: 0000-0002-8969-7902
authors.initials: M
authors.lastname: Mastalir
authors.forename: Ernst
authors.identifier: 0000-0002-8409-802X
authors.initials: E
authors.lastname: Pittenauer
authors.forename: Berthold
authors.identifier: 0000-0002-0087-474X
authors.initials: B
authors.lastname: Stöger
authors.forename: Günter
authors.identifier: 0000-0002-1438-9462
authors.initials: G
authors.lastname: Allmaier
authors.affiliation: Institute of Applied Synthetic Chemistry and ‡Institute of Chemical Technologies and Analytics, Vienna University of Technology , Getreidemarkt 9/163-AC, A-1060 Wien, Austria.
authors.forename: Karl
authors.identifier: 0000-0003-0872-6159
authors.initials: K
authors.lastname: Kirchner